Liquid Electrolytic Capacitor Patents (Class 361/503)
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Patent number: 7317607Abstract: In an electric double layer capacitor including two plate-like polarizable electrodes stacked in layers via a separator and constituted by housing these in an outer packaging member, a contact area between a first polarizable electrode and the separator is different from a contact area between a second polarizable electrode and the separator, and the polarizable electrode with a smaller contact area is formed thicker than the polarizable electrode with a larger contact area. In addition, it is preferable that the first polarizable electrode and the second polarizable electrode have a generally equal volume.Type: GrantFiled: September 27, 2004Date of Patent: January 8, 2008Assignee: Sanyo Electric Co., Ltd.Inventors: Seiji Omura, Hiroshi Nakajima
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Patent number: 7312976Abstract: The present invention relates to a double electric layer heterogeneous electrochemical supercapacitor (HES) and a method of manufacture. Single-cell or multi-cell versions of the HES can be produced. Output characteristics of the HES are optimized by carefully controlling particular parameters of the HES' design and construction.Type: GrantFiled: February 22, 2006Date of Patent: December 25, 2007Assignee: Universal Supercapacitors LLCInventors: Samvel Avakovich Kazaryan, Gamir Galievich Kharisov, Vladimir Alexandrovich Kazarov, Sergey Vitalievich Litvinenko, Sergey Nikolaevich Razumov
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Patent number: 7310219Abstract: The present invention relates to an electrochemical capacitor, and provides an electrochemical capacitor which has a fully lowered internal resistance and can yield excellent charging/discharging characteristics. The electrochemical capacitor of the present invention is mainly constituted by an anode and a cathode which oppose each other, an insulating separator disposed between the anode and cathode adjacent thereto, an electrolytic solution, and a casing accommodating them in a closed state. The anode contains a substantially spherical carbon material having an electronic conductivity as a constituent material, whereas the cathode contains a fibrous carbon material having an electronic conductivity as a constituent material.Type: GrantFiled: May 7, 2004Date of Patent: December 18, 2007Assignee: TDK CorporationInventors: Atsuko Kosuda, Satoshi Maruyama
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Patent number: 7307831Abstract: A method of manufacturing an electrode includes a preparatory step of preparing an electrode matrix comprising a collector and an active material containing layer formed on at least one face of the collector, at least one edge part of the collector including an exposed surface free of the active material containing layer, an edge part of the active material containing layer on a side close to the exposed surface including a thinner part having a thickness smaller than a maximum thickness of the active material containing layer; and a roll-pressing step of pressing the electrode matrix with a roll press.Type: GrantFiled: July 5, 2005Date of Patent: December 11, 2007Assignee: TDK CorporationInventors: Hideki Tanaka, Yousuke Miyaki, Kazuo Katai, Kiyonori Hinoki
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Patent number: 7307830Abstract: High reliable energy density capability of double-layer capacitor electrode technology now enables the use of capacitors as supplements to, or replacements for, battery technologies. In one application, when sized to a standard battery form factor, the large end terminal surface areas of such form factors enable that the energy density of capacitors can now be safely used as direct drop-in replacements for batteries.Type: GrantFiled: January 27, 2004Date of Patent: December 11, 2007Assignee: Maxwell Technologies, Inc.Inventors: Rolland Gallay, Daniel Schlunke, Richard Smith
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Publication number: 20070279840Abstract: Apparatuses, methods, and systems associated with and/or having capacitors are disclosed herein. In various embodiments, a capacitor may be formed within a substrate having an interwoven-fiber material. In various ones of these embodiments, a capacitor may have a first electrode including an activation material disposed on a surface of an interwoven-fiber material, a second electrode including an electrolytic solution, and an insulating material disposed between the first electrode and the second electrode.Type: ApplicationFiled: May 31, 2006Publication date: December 6, 2007Inventors: Xing Jin, Lei Hua, Yaling Zhao
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Patent number: 7303974Abstract: A method is provided for optimizing the physical characteristics of a coating solution for an undercoat layer formed between a polarizable electrode layer and surface-roughened collector. A first step is carried out to form an undercoat layer on a collector whose surface has been roughened, and a second step is carried out to form a polarizable electrode layer on the undercoat layer. The first step is performed by coating the collector with a coating solution for the undercoat layer that includes electroconductive particles, a binder, and a solvent; the viscosity of the coating solution for the undercoat layer is set to from 0.15 to 0.75 Pa·s, and the weight ratio (P/B) of the electroconductive particles (P) and binder (B) is set to from 20/80 to 40/60. The coating area of the undercoat layer can thereby be adjusted with high precision, and the resistance of the undercoat layer can be reduced.Type: GrantFiled: May 16, 2006Date of Patent: December 4, 2007Assignee: TDK Corporation and Honda Motor Co., Ltd.Inventors: Kiyonori Hinoki, Tsuyoshi Ichiki, Kazutoshi Emoto, Takehiko Sasaki, Kenichi Murakami, Shigeki Oyama, Manabu Iwaida
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Patent number: 7303975Abstract: A method is provided for optimizing the physical characteristics of a coating solution for a polarizable electrode layer formed on a collector. A first step is carried out to prepare a coating solution that includes porous particles, a fluorine-based binder, a good solvent that dissolves said fluorine-based binder, and a poor solvent that does not dissolve said fluorine-based binder. A second step is carried out to coat a collector with said coating solution to form the polarizable electrode layer on the collector. The viscosity of said coating solution for the polarizable electrode layer is set to between 0.5 to 3.5 Pa·s and a weight ratio (GS/PS) of said good solvent (GS) and said poor solvent (PS) is set to between 60/40 to 80/20. The occurrence of cracks in the polarizable electrode layer and large nonuniformities in the thickness of the polarizable electrode layer can thus be prevented.Type: GrantFiled: May 16, 2006Date of Patent: December 4, 2007Assignee: TDK Corporation and Honda Motor Co., Ltd.Inventors: Kiyonori Hinoki, Tsuyoshi Ichiki, Kazutoshi Emoto, Takehiko Sasaki, Kenichi Murakami, Shigeki Oyama, Manabu Iwaida
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Publication number: 20070274024Abstract: The present invention provides an electric double layer capacitor that has less chance for internal resistance increase. For this objective, in this electric double layer capacitor, an electric double layer capacitor element sandwiches a separator between a cathode and an anode, arranged inside a container comprising a lid and a concave shaped containing portion. On the inner bottom face in the containing portion, an insulating layer having a first conductive layer connected to a connecting terminal, and an opening portion penetrates to the first conductive layer are formed, wherein a second conductive layer fills inside the opening portion. Onto the insulating layer and the second conductive layer, a third conductive layer which laminates a first layer comprised of aluminum and a second layer comprised of carbon, is formed and connected to the cathode. The fourth conductive layer is connected to the anode, and also connected to the connecting terminal.Type: ApplicationFiled: January 31, 2007Publication date: November 29, 2007Applicant: Sanyo Electric Co., Ltd.Inventors: Masaaki Nemoto, Koji Endo, Kikuko Kato, Yasuo Nakahara, Hiroshi Nonoue
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Patent number: 7301753Abstract: The present subject matter includes a first capacitor stack including a first plurality of anode layers and a first plurality of cathode layers and a second capacitor stack including a second plurality of anode layers and a second plurality of cathode layers. In various embodiments, a flexible bus is welded to the first capacitor stack and to the second capacitor stack. The flexible bus is adapted to conduct electricity between the first capacitor stack and the second capacitor stack. Also, the present subject matter includes embodiments where the first capacitor stack and the second capacitor stack are disposed in a case filled with an electrolyte.Type: GrantFiled: May 9, 2005Date of Patent: November 27, 2007Assignee: Cardiac Pacemakers, Inc.Inventor: Gregory J. Sherwood
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Patent number: 7295424Abstract: There are provided an aluminum electrolytic capacitor comprising an anode, a cathode comprising aluminum and an electrolytic solution containing an onium salt of fluorine-containing anion, wherein the electrolytic solution has a water concentration of 1% by weight or less, or wherein the cathode has a peak top of Al2p spectrum of 74.0 to 75.8 eV as measured by a method in which the surface of the cathode in the aluminum electrolytic capacitor heated at 125° C. for 50 hours is analyzed by X-ray photoelectron spectroscopy (XPS); an electrolytic solution for electrolytic capacitor comprising a quaternary cyclic amidinium tetrafluoroaluminate and a solvent and containing specific impurity compounds in a total amount of 0.6% by weight or less, and an electrolytic capacitor using the electrolytic solution; and a method for preparing an organic onium tetrafluoroaluminate which is advantageously used in an aluminum electrolytic capacitor.Type: GrantFiled: April 11, 2007Date of Patent: November 13, 2007Assignee: Mitsubishi Chemical CorporationInventors: Masayuki Takeda, Hiroo Miyauchi, Makoto Ue
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Patent number: 7295423Abstract: A dry process based capacitor and method for making a self-supporting dry adhesive electrode film for use therein is disclosed.Type: GrantFiled: April 2, 2004Date of Patent: November 13, 2007Assignee: Maxwell Technologies, Inc.Inventors: Porter Mitchell, Xiaomei Xi, Linda Zhong, Bin Zou
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Patent number: 7292431Abstract: The invention is an electrochemical capacitor with its electrodes made on a conducting substrate with a layer of a redox polymer of the poly[Me(R-Salen)] type deposited onto the substrate. Me is a transition metal (for example, Ni, Pd, Co, Cu, Fe), R is an electron-donating substituent (for example, CH3O—, C2H5O—, HO—, —CH3), Salen is a residue of bis(salicylaldehyde)-ethylendiamine in Schiff's base. The electrolyte comprises of an organic solvent, compounds capable of dissolving in such solvents with the resulting concentration of no less than 0.01 mol/l and dissociating with the formation of ions, which are electrochemically inactive within the range of potentials from ?3.0 V to +1.5 V (for example, salts of tetramethyl ammonium, tetrapropyl ammonium, tetrabutyl ammonium), and a dissolved metal complex [Me(R-Salen)]. The method of using the capacitor contemplates periodically alternating the connection polarity of the electrodes, causing the electrochemical characteristics of the electrodes to regenerate.Type: GrantFiled: April 4, 2005Date of Patent: November 6, 2007Assignee: Gen 3 Partners, Inc.Inventors: Alexander Mikhailovich Timonov, Sergey Anatolijevich Logvinov, Dmitriy Ivanovich Pivunov, Svetlana Viktorovna Vasiljeva, Nik Shkolnik, Sam Kogan
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Patent number: 7289312Abstract: The present invention relates generally to an electrical charge storage device (ECSD) with enhanced power characteristics. More particularly, the present invention relates to enhancing the current density, voltage rating, power transfer characteristics, frequency response and charge storage density of various devices, such as capacitors, batteries, fuel cells and other electrical charge storage devices. For example, one aspect of the present invention is solid state and electrolytic capacitors where the conductor surface area is increased with smooth structures, thereby reducing the distance separating the conductors, and improving the effective dielectric characteristics by employing construction techniques on atomic, molecular, and macroscopic levels.Type: GrantFiled: March 4, 2004Date of Patent: October 30, 2007Inventor: William B. Duff, Jr.
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Patent number: 7286334Abstract: The invention is intended to reduce expansion proportion of electric double layer capacitors by combining nonporous carbonaceous electrodes produced by a specific method with an electrolyte of a specific structure. Provided is an electric double layer capacitor comprising nonporous carbonaceous electrodes soaked in an organic electrolytic solution, wherein the organic electrolytic solution contains a pyrrolidinium compound salt as a solute, and wherein the carbonaceous electrodes are electrodes obtained by the method comprising a step of obtaining a carbon powder by prebaking a needle coke green powder under an inert atmosphere, baking the prebaked needle coke powder in the presence of alkali hydroxide under an inert atmosphere, and removing the alkali hydroxide; and a step of shaping the carbon powder.Type: GrantFiled: March 21, 2005Date of Patent: October 23, 2007Assignee: Power Systems Co., Ltd.Inventors: Hitoshi Nakamura, Michio Okamura
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Patent number: 7268205Abstract: Devices formed of or including biocompatible polyhydroxyalkanoates are provided with controlled degradation rates, preferably less than one year under physiological conditions. Preferred devices include sutures, suture fasteners, meniscus repair devices, rivets, tacks, staples, screws (including interference screws), bone plates and bone plating systems, surgical mesh, repair patches, slings, cardiovascular patches, orthopedic pins (including bone filling augmentation material), adhesion barriers, stents, guided tissue repair/regeneration devices, articular cartilage repair devices, nerve guides, tendon repair devices, atrial septal defect repair devices, pericardial patches, bulking and filling agents, vein valves, bone marrow scaffolds, meniscus regeneration devices, ligament and tendon grafts, ocular cell implants, spinal fusion cages, skin substitutes, dural substitutes, bone graft substitutes, bone dowels, wound dressings, and hemostats.Type: GrantFiled: January 16, 2007Date of Patent: September 11, 2007Assignee: Metabolix, Inc.Inventors: Simon F. Williams, David P. Martin, Frank A. Skraly
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Patent number: 7268996Abstract: The present invention is directed to an electrolyte for use in very high voltage electrolytic capacitors and to an electrolytic capacitor impregnated with the electrolyte of the present invention for use in an implantable cardioverter defibrillator (ICD). The electrolyte according to the present invention is composed of a mixture of an alkoxy-substituted alcohol, such as 2-methoxyethanol, 2-ethoxyethanol, or 2-butoxyethanol, and a long chain dicarboxylic acid, where the acid functional groups are separated by 34 carbons (referred to as “dimer acid”) or 54 carbons (referred to as “trimer acid”). The solution is then neutralized with ammonium hydroxide or other amine, such as ammonia, dimethylamine, trimethylamine, diethylamine, triethylamine, ethanolamine, diethanolamine, triethanolamine, diisopropylethylamine and N-methylimidazole.Type: GrantFiled: January 10, 2003Date of Patent: September 11, 2007Assignee: Pacesetter, Inc.Inventors: Roland Francis Dapo, Christopher Feger
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Patent number: 7262953Abstract: An electrolytic capacitor having a low impedance characteristic, having a high withstand voltage characteristic of 100V class, wherein the electrolytic capacitor provides an excellent high temperature life characteristic and an excellent leakage characteristic. The electrolyte solution containing the aluminum tetrafluoride salt is used. The electrolytic capacitor of the present invention has a low impedance characteristic, a high withstand voltage characteristic, and an excellent high temperature life characteristic. Moreover, the aforementioned electrolyte solution is used, and a foil showing noble potential at least in the electrolyte solution than the electrode potential of the cathode tab, or a cathode electrode foil subjected to chemical treatment is used as the cathode electrode foil, so as to obtain an excellent leakage characteristic.Type: GrantFiled: November 7, 2003Date of Patent: August 28, 2007Assignees: Nippon Chemi-Con Corporation, Mitsubishi Chemical CorporationInventors: Masashi Ozawa, Masayuki Takeda, Makoto Ue
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Publication number: 20070195488Abstract: An active material of the present invention has fine pores formed in the interlayer of a carbon material capable of exhibiting electrochemical double layer capacitance. The fine pores are formed by forming an oxidized graphite structure combined with oxygen in the interlayer of a part or whole of the carbon material containing soft carbon and then removing a part or whole of oxygen in the interlayer. A method for producing an energy storage active material for use in an electrochemical double layer capacitor comprises pre-treating a carbon material through heat treatment and oxidizing the pre-treated carbon material using an oxidant. The method further comprises reducing the oxidized carbon material through heat treatment. The interlayer distances of an active material for respective steps, measured by a powder X-ray diffraction method, are 0.33˜0.36 nm in the pre-treatment step, 0.5˜2.1 nm in the oxidation step, and 0.34˜0.5 nm in the reduction step.Type: ApplicationFiled: February 9, 2007Publication date: August 23, 2007Applicant: KOREA ELECTROTECHNOLOGY RESEARCH INSTITUTEInventors: Ick Jun KIM, Sun Hye YANG, Seong In MOON, Hyun Soo KIM, Min Jae JEON
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Patent number: 7256099Abstract: A first electrode and a second electrode to be used are electrodes each of which has a collector, and a porous material layer with electron conductivity placed between the collector and a separator, and each of which has a configuration wherein the porous material layer includes at least particles of a porous material with electron conductivity, and a thermoplastic resin being capable of binding the particles of the porous material together and having a softening point TB lower than a softening point TS of the separator. A production method includes a thermal treatment step of thermally treating a laminate at a thermal treatment temperature T1 satisfying a condition represented by Formula (1): TB?T1<TS, thereby bringing the collector of the first electrode, the porous material layer of the first electrode, the separator, the porous material layer of the second electrode, and the collector of the second electrode in the laminate into an integrated state.Type: GrantFiled: November 18, 2004Date of Patent: August 14, 2007Assignee: TDK CorporationInventors: Tetsuya Takahashi, Kazuo Katai, Yousuke Miyaki
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Patent number: 7256982Abstract: A capacitor is provided which includes a plurality of electrodes and a fluid electrolyte provided to electrically associate the plurality of electrodes. One of the plurality of electrodes includes poly (ethylene 3,4-dioxythiophene) or a titanate.Type: GrantFiled: May 30, 2003Date of Patent: August 14, 2007Inventors: Philip Michael Lessner, Brian Melody, John Tony Kinard, Joachim Hossick Schott
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Patent number: 7251122Abstract: An electric chemical capacitor includes first and second electrodes each including a collector 111, 121, a polarized electrode layer 112, 122 and an undercoat layer 113, 123 for bonding the collector and the polarized electrode layer with each other, and a separator put between the first and second electrodes so that the polarized electrode layers 112 and 122 face each other, wherein an end portion of each undercoat layer 113, 123 is located in the same position as or on the outer side of an end portion of the corresponding polarized electrode layer 112, 122, and located on the inner side of an end portion of the separator 130. Thus, the polarized electrode layers can be prevented from peeling from the collector. Further, the undercoat layers can be prevented from abutting against each other, and the undercoat layer of one electrode and the collector of the other electrode can be prevented from abutting against each other.Type: GrantFiled: December 21, 2004Date of Patent: July 31, 2007Assignee: TDK CorporationInventors: Kiyonori Hinoki, Yousuke Miyaki, Kazuo Katai, Hideki Tanaka, Tsuyoshi Ichiki
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Patent number: 7248460Abstract: An electric double layer capacitor includes: a cell which includes a pair of polarizable electrodes impregnated with an electrolytic solution and disposed in opposed relation with a separator interposed therebetween; collector electrodes respectively attached to the polarizable electrodes; and a sealing member of a synthetic resin which seals a periphery of the cell. The collector electrodes extend outward of the sealing member through the sealing member in contact with the sealing member. The collector electrodes each have a rough surface portion which extends through the sealing member.Type: GrantFiled: May 27, 2004Date of Patent: July 24, 2007Assignee: Sanyo Electric Co., Ltd.Inventors: Seiji Omura, Yasuhiro Kishimoto, Mamoru Kimoto, Kikuko Kato, Hiroshi Nakajima
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Patent number: 7245478Abstract: Particles of active electrode material are made by blending and fibrillizing (i.e., fibrillating) a mixture of activated carbon, conductive carbon, and fibrillizable binder. In selected embodiments, chloride level in the activated carbon is relatively low, a small amount of conductive carbon with low impurity levels and high conductivity is used, and the binder is inert. For example, chloride content of the activated carbon is below 50 ppm, and total impurities in the conductive carbon are below 120 ppm. The mixture may include about 10% of PTFE and 0.5% or less of conductive carbon. Blending and fibrillization may be performed without solvents. The fibrillized particles are dried, blended again to reduce clumping, and used to make active electrode material film. The film is attached to a current collector to obtain an electrode for use in various electrical devices, including double layer capacitors. The electrode increases breakdown voltage of the capacitor electrolyte.Type: GrantFiled: July 8, 2005Date of Patent: July 17, 2007Assignee: Maxwell Technologies, Inc.Inventors: Linda Zhong, Xiaomei Xi
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Patent number: 7242572Abstract: A sealed electrode enclosed in separator material is provided for use in a capacitor cell. The separator may either be adhered to the electrode in sheets, or may be formed into a pouch, which is used to enclose the electrode. A method of preparing the electrode sealed with separator is described in which an adhesive is used to secure the pouch to the electrode before sealing it. The prefabricated electrode and separator combination may be used in both coiled capacitor cells and flat capacitor cells that are often used in implantable medical devices. Electrodes prepared in this fashion can be efficiently and reliably aligned within the case of a capacitor cell, and have no exposed electrode surfaces that could lead to short-circuiting within the cell.Type: GrantFiled: July 11, 2003Date of Patent: July 10, 2007Assignee: Medtronic, Inc.Inventors: John D. Norton, Anthony W. Rorvick, Mark D. Breyen, Paul A. Pignato, Thomas P. Miltich
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Patent number: 7236348Abstract: A reinforcing material-having functional sheet of a sheet-like functional material including a functional powder and a binder resin and, laminated thereon, a reinforcing sheet comprising a woven fabric or a non-woven fabric, which are bonded, wherein the basis weight of the reinforcing sheet, the fiber diameter of the fiber constituting the reinforcing sheet and the functional sheet thickness are in specific ranges. A sheet-like electrode for electric double layer capacitors, which electrode comprises a sheet-like electrode of carbon fine powder and a fluorine-containing polymer resin and, laminated thereon, the reinforcing sheet, and an electric double layer capacitor having this electrode. The functional sheet has strength and no elimination of the functional material powder, and also efficiently exhibits high functional properties.Type: GrantFiled: August 19, 2003Date of Patent: June 26, 2007Assignee: Nippon Valqua Industries, Ltd.Inventors: Yoshitaka Asano, Toru Sugitani, Michinao Hayashi, Daijirou Akiyama
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Patent number: 7236349Abstract: The present invention is an electrode for an electrochemical capacitor provided with a collector having electronic conductivity and a porous body layer having electronic conductivity, the porous body layer containing porous particles having electronic conductivity and a binder which is able to bind the porous particles with one another, wherein the content of the porous particles in the porous body layer is in a range from 88 to 92% by mass on the basis of the total amount of the porous body layer, and the porous body layer has an apparent density in a range from 0.62 to 0.70 g/cm3.Type: GrantFiled: November 18, 2004Date of Patent: June 26, 2007Assignee: TDK CorporationInventors: Yousuke Miyaki, Kazuo Katai, Hideki Tanaka, Kiyonori Hinoki
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Patent number: 7233481Abstract: An electric double layer capacitor has a pair of activated carbon electrodes and an organic solution in which an electrolyte is dissolved in an organic solvent. An electrolyte solution is also provided. In the electric double layer capacitor, at least one of cycloalkane, cycloalkene, or derivatives thereof is contained in at least one of the activated carbon and the organic electrolyte solution. The organic solvent contains a main solvent and an additive solvent. The main solvent contains propylenecarbonate in a range of from 99.9 to 70 wt %, and at least one of ethylenecarbonate and dimethylcarbonate in a range of from 0.1 to 30 wt %, and the additive solvent contains cycloalkane in a range of from 5 to 30 wt % to the total amount of the organic solvent.Type: GrantFiled: January 27, 2005Date of Patent: June 19, 2007Assignee: Honda Motor Co., Ltd.Inventor: Takeshi Fujino
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Patent number: 7227738Abstract: There are provided an aluminum electrolytic capacitor comprising an anode, a cathode comprising aluminum and an electrolytic solution containing an onium salt of fluorine-containing anion, wherein the electrolytic solution has a water concentration of 1% by weight or less, or wherein the cathode has a peak top of Al2p spectrum of 74.0 to 75.8 eV as measured by a method in which the surface of the cathode in the aluminum electrolytic capacitor heated at 125° C. for 50 hours is analyzed by X-ray photoelectron spectroscopy (XPS); an electrolytic solution for electrolytic capacitor comprising a quaternary cyclic amidinium tetrafluoroaluminate and a solvent and containing specific impurity compounds in a total amount of 0.6% by weight or less, and an electrolytic capacitor using the electrolytic solution; and a method for preparing an organic onium tetrafluoroaluminate which is advantageously used in an aluminum electrolytic capacitor.Type: GrantFiled: October 31, 2003Date of Patent: June 5, 2007Assignee: Mitsubishi Chemical CorporationInventors: Masayuki Takeda, Hiroo Miyauchi, Makoto Ue
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Patent number: 7227737Abstract: Electrodes of a double-layer capacitor are designed so that sub-capacitors formed at each electrode are stressed substantially equally at the rated voltage of the double-layer capacitor. In an exemplary embodiment, each electrode includes a current collector and an active electrode layer, such as a layer of activated carbon. The electrodes are held apart by a porous separator, and the assembly is immersed in an electrolyte. The thicknesses of the active electrode layers differ, resulting in asymmetrical construction of the capacitor. Different thicknesses cause the sub-capacitors to have different capacitances. When voltage is applied to the double-layer capacitor, the voltage is divided unequally between the unequal sub-capacitors. Properly selected thicknesses allow the voltages at the sub-capacitors to stress equally each sub-capacitor. The rated voltage of the double-layer capacitor can then be increased without overstressing the sub-capacitors.Type: GrantFiled: October 27, 2004Date of Patent: June 5, 2007Assignee: Maxwell Technologies, Inc.Inventors: Porter Mitchell, Xiaomei Xi, Linda Zhong, Bin Zou
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Patent number: 7224574Abstract: An electric double layer capacitor in which gas generation due to decomposition of a solvent of an electrolyte solution in the capacitor is reduced and performance maintaining ratio is superior, is provided by a method which is different from a method of adding additives to the electrolyte solution. The electric double layer capacitor has activated carbon polarizing electrodes and a non-water-based solvent, and a positive electrode of the activated carbon polarizing electrodes contains an antacid agent.Type: GrantFiled: March 13, 2006Date of Patent: May 29, 2007Assignee: Honda Motor Co., Ltd.Inventors: Takeshi Fujino, Byoungju Lee
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Patent number: 7224576Abstract: The present invention provides improved cathodes and methods for producing such cathodes for ultimate use in conjunction with valve metal capacitors. A family of titanium carbide cathodes according to the present invention can be produced so that they inhabit a pre-existing metallic surface such as an inner surface of a titanium casing adjacent but insulated from direct electrical communication from an anode. Foil-type valve metal anodes as well as porous valve metal anodes formed from metallic powders may be used in conjunction with the titanium cathodes of the present invention.Type: GrantFiled: April 2, 2004Date of Patent: May 29, 2007Assignee: Medtronic, Inc.Inventor: Joachim Hossick-Schott
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Patent number: 7214328Abstract: An electrolytic solution for operating electrolytic capacitors which deteriorates extremely little in electrical properties even when used in a high-tension capacitor. The electrolytic solution comprises a compound expressed by general formula (1) below and a compound expressed by general formula (2) below or their salts: where each R is a same or different alkyl group, and R? is hydrogen, a methyl group or an ethyl group, and n is an integer of 0 to 14.Type: GrantFiled: December 9, 2002Date of Patent: May 8, 2007Assignee: Okamura Oil Mill, Ltd.Inventors: Noritaka Miyoshi, Masashi Nakagawa, Yasuyuki Yamagawa, Kazuhisa Takii
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Patent number: 7212397Abstract: The invention relates to an electrochemical cell including: at least a pair of current collector plates that are placed in parallel to each other, flat electrodes containing aqueous electrolyte printed on opposing faces of said current collectors, such that a peripheral region is defined on each of said faces of said current collectors, which region is not covered by said electrode, and a separating medium interposed between said electrodes, the geometric form and size of said separating medium being identical to the form and size of said current collector plates, said separating medium having a central region permeable to said electrolyte, surrounded by a peripheral masked region which is non-permeable to said electrolyte, such that the permeable region of said separating medium coincide with the electrodes printed on the opposing faces of said current collectors, with respect to position, geometric form and size; wherein the pores in the peripheral region of the separating medium are impregnated with a suitType: GrantFiled: August 30, 2004Date of Patent: May 1, 2007Assignee: Cellergy Ltd.Inventor: Joel Lang
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Patent number: 7209341Abstract: An electric double-layer capacitor includes a carbon composite electrode which serves as a polarizing electrode and made of a single-layer carbon nanohorn aggregate having a specific structure and a very large surface area. The single carbon nanohorn aggregate is mixed with a phenol resin, the mixture is formed and heated to produce a carbon composite electrode. The carbon composite electrode is impregnated with an electrolyte to become a polarizing electrode. An electric double-layer capacitor includes this polarizing electrode has a large capacitance and is capable of discharging with large current.Type: GrantFiled: March 26, 2004Date of Patent: April 24, 2007Assignees: Japan Science and Technology Agency, NEC CorporationInventors: Tsutomu Yoshitake, Sumio Iijima, Masako Yudasaka
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Patent number: 7209342Abstract: A phosphazene compound and an ionic liquid are added to a non-aqueous electrolyte to provide a less flammable electric double layer capacitor in which decline in storage characteristics under a high temperature and deterioration under a high charging voltage are suppressed.Type: GrantFiled: October 5, 2005Date of Patent: April 24, 2007Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Tooru Matsui, Masaki Deguchi, Hiroshi Yoshizawa
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Patent number: 7206189Abstract: Composite electrode/current collectors for capacitors, e.g., a flow-through capacitor or electric double layer capacitor are disclosed. Also disclosed are methods for making a composite electrode/current collectors and capacitors having at least one composite electrode/current collector.Type: GrantFiled: August 27, 2004Date of Patent: April 17, 2007Assignee: Advanced Energy Technology Inc.Inventor: Robert A. Reynolds, III
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Patent number: 7206191Abstract: The present subject matter includes a capacitor stack having a plurality of cathode layers, and a plurality of anode layers. Separator paper is shaped and sized to separate the anode and the cathode and prevent breakdown. The capacitor stack is compact, and is adapted for use in compact devices. For example, the capacitor stack is adapted for use in cardiac rhythm management devices which are implanted.Type: GrantFiled: May 9, 2005Date of Patent: April 17, 2007Assignee: Cardiac Pacemakers, Inc.Inventors: Gregory J. Sherwood, Brian V. Waytashek
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Patent number: 7206190Abstract: In an electrode for an electric double layer capacitor of the present invention, the peak value of particle size distribution of graphite particles added to a conductive adhesive is in a range of 2.6 to 3.2 ?m, not less than 100,000 dimples having a largest outer diameter in a range of 4 to 10 ?m and a depth in a range of 4 to 15 ?m are formed on the surface of the collector sheet per 1 cm2, and the occupied area of the dimples to the entire surface area of the collector sheet is not more than 50%. By determining the saponification value of polyvinylalcohol which is used as a binder component of the conductive adhesive in a range of 90.0 to 98.5, adhesiveness of the collector sheet and the electrode forming sheet is improved. Furthermore, by substituting H atoms contained in the polyvinylalcohol with Si atoms, adhesiveness of the collector sheet and the electrode forming sheet can be further improved.Type: GrantFiled: June 21, 2005Date of Patent: April 17, 2007Assignees: Honda Motor Co., Ltd., No-Tape Industrial Co., Ltd., Daido Metal Company Ltd.Inventors: Kenichi Murakami, Manabu Iwaida, Shigeki Oyama, Toshiaki Fukushima, Tomohiko Kawaguchi, Kouki Ozaki, Masanori Tsutsui
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Patent number: 7198654Abstract: A separator sheet for manufacturing an electric double layer capacitor, and a method for manufacturing the electric double layer capacitor using the same, are provided. According to an embodiment, the separator sheet for manufacturing the electric double layer capacitor comprises: a plurality of separators; and a resin film holding the plurality of separators, wherein the separators are disposed in the resin film at a predetermined interval.Type: GrantFiled: December 21, 2005Date of Patent: April 3, 2007Assignee: LG Electronics Inc.Inventors: Kang Yoon Kim, Sang Gon Lee, Young Kee Seo, Jung Hoon Lee
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Patent number: 7179883Abstract: Devices formed of or including biocompatible polyhydroxyalkanoates are provided with controlled degradation rates, preferably less than one year under physiological conditions. Preferred devices include sutures, suture fasteners, meniscus repair devices, rivets, tacks, staples, screws (including interference screws), bone plates and bone plating systems, surgical mesh, repair patches, slings, cardiovascular patches, orthopedic pins (including bone filling augmentation material), adhesion barriers, stents, guided tissue repair/regeneration devices, articular cartilage repair devices, nerve guides, tendon repair devices, atrial septal defect repair devices, pericardial patches, bulking and filling agents, vein valves, bone marrow scaffolds, meniscus regeneration devices, ligament and tendon grafts, ocular cell implants, spinal fusion cages, skin substitutes, dural substitutes, bone graft substitutes, bone dowels, wound dressings, and hemostats.Type: GrantFiled: December 22, 2004Date of Patent: February 20, 2007Assignee: Metabolix, Inc.Inventors: Simon F. Williams, David P. Martin, Frank A. Skraly
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Patent number: 7180725Abstract: Present invention relates to an electric double-layer capacitor having positive and negative electrodes containing nonporous carbon as an electrode active material. In the nonporous carbon, multiple layers of graphene having an average interplanar spacing d002 of 0.350 to 0.380 nm have been grown well. The positive and negative electrodes are impregnated with an electrolyte solution. The nonporous carbon is obtained by activating easily graphitizable carbon, which in turn is obtained by calcining needle coke or pitch made infusible. The elctrolyte solution is either a liquid electrolyte having a planar molecular structure or an electrolyte solution consisting of a liquid electrolyte dissolved in an organic solvent.Type: GrantFiled: March 3, 2004Date of Patent: February 20, 2007Assignee: Advanced Capacitor Technologies, Inc.Inventors: Makoto Takeuchi, Akinori Mogami, Katsumi Koike
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Patent number: 7177139Abstract: An electrical double layer capacitor is provided which is capable of ensuring its reliability and providing increased energy density per unit volume of a capacitor. A negative electrode is so configured as to cover all surfaces of a positive electrode and, therefore, there is no portion in which the positive electrode does not face the negative electrode, which enables generation of gas within the capacitor to be suppressed and ensures reliability of the capacitor. Portions in which the negative electrode do not face the positive electrode serve as non-covered portions and, therefore, electrostatic capacitance per unit volume of electrodes is made to increase, and energy density is improved.Type: GrantFiled: August 17, 2005Date of Patent: February 13, 2007Assignee: NEC Tokin CorporationInventor: Wataru Oizumi
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Patent number: 7173806Abstract: An electrode for an electrochemical capacitor includes a sheet-like current collector and a polarizable electrode layer. The polarizable electrode layer is provided on the current collector with a predetermined bare portion left. The polarizable electrode layer has undergone an embossment work and at least part of the bare portion of the current collector has not undergone any embossment work.Type: GrantFiled: December 21, 2004Date of Patent: February 6, 2007Assignee: TDK CorporationInventors: Kiyonori Hinoki, Kazuo Katai, Yosuke Miyaki, Hideki Tanaka
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Patent number: 7167353Abstract: The water present within an ionic liquid that is in a liquid state at 25° C. or an organic solution containing at least one ionic compound is decomposed by bringing electrodes into contact with the ionic liquid or organic solution within an atmosphere having a dew-point temperature not higher than ?40° C. or under a reduced pressure of not more than 75 torr, thereby reducing the water content. This process makes it possible to obtain highly dehydrated ionic liquids.Type: GrantFiled: April 24, 2003Date of Patent: January 23, 2007Assignee: Nisshinbo Industries, Inc.Inventors: Kanako Yuyama, Ryutaro Nozu, Gen Masuda, Takaya Sato
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Patent number: 7160615Abstract: An electrode sheet of an electric double layer capacitor is produced by using granules for formation of an electrode of an electric double layer capacitor which are obtained by kneading and then crushing materials including an activated material, a conductive filler, and a binder at 50 to 97 mass-%, 1 to 30 mass-%, and 2 to 20 mass-%, respectively, and which are essentially granules whose diameter is in a range of 47 to 840 ?m. A method for manufacturing a sheet-like electrode by mixing and kneading materials including an activated carbon, carbon black, and PTFE into a kneaded material, producing a forming material by converting the kneaded material into granules, and forming and rolling the forming material.Type: GrantFiled: November 26, 2003Date of Patent: January 9, 2007Assignees: Honda Motor Co., Ltd., Daido Metal Company Ltd.Inventors: Manabu Iwaida, Shigeki Oyama, Kenichi Murakami, Kouki Ozaki, Masanori Tsutsui
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Patent number: 7154738Abstract: A polarizing electrode for an electric double layer capacitor has good moldability and is capable of achieving higher density of electrode and higher capacity. An electric double layer capacitor employs the same. The polarizing electrode for an electric double layer capacitor is made of an activated carbon obtained by activating a hard-to-graphitize material (for example, phenol resin) with water vapor, and the activated carbon has a median particle size within a range from 4 ?m to 8 ?m in the particle size distribution as measured by a laser diffraction method and a benzene adsorption ratio of not less than 47.0% and not more than 60% by weight of activated carbon.Type: GrantFiled: November 26, 2003Date of Patent: December 26, 2006Assignees: Honda Motor Co., Ltd., Kuraray Chemical Co., Ltd.Inventors: Shigeki Oyama, Manabu Iwaida, Kenichi Murakami
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Patent number: 7154737Abstract: Secondary cells and electrical double-layer capacitors of excellent charge-discharge efficiency, stability and low-temperature properties can be obtained using nonaqueous electrolytes which contain an ionic liquid that has general formula (1) below and is liquid at not higher than 50° C. and an ion-conductive polymer. In formula (1), R1 to R4 are each independently an alkyl group of 1 to 5 carbons or an alkoxyalkyl group of the formula R?—O—(CH2)n— (R? being methyl or ethyl, and the letter n being an integer from 1 to 4), and any two from among R1, R2, R3 and R4 may together form a ring, with the proviso that at least one of R1 to R4 is an alkoxyalkyl group of the above formula. X is a nitrogen atom or a phosphorus atom, and Y is a monovalent anion.Type: GrantFiled: September 19, 2003Date of Patent: December 26, 2006Assignee: Nisshinbo Industries, Inc.Inventors: Tatsuya Maruo, Shoko Marukane, Gen Masuda, Takaya Sato
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Patent number: 7110242Abstract: A novel electrode and method of making the same. The electrode may be used in electric double layer capacitors. The electrodes include activated carbon that has been mixed with a thermosetting polymer binder. Activated carbon cloth may also be used. The method of modifying the activated carbon helps produce an electrode with considerably higher electric capacity, higher durability, and low resistance, while maintaining high conductivity. Additionally, the electrodes may be produced more quickly and inexpensively.Type: GrantFiled: February 26, 2001Date of Patent: September 19, 2006Assignee: C and T Company, Inc.Inventors: Michail N. Adrianov, Vera V. Litvinskaya, Vitaly P. Popov, Valentin V. Chebykin, Pavel A. Shmatko, Gennady V. Dvoretskiy
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Patent number: 7102877Abstract: A method for making an electrode including a particle based film is disclosed in which the film is coated and/or impregnated with veins of conductive material. A support backing is placed adjacent to one side of the film to provide support and prevent damaging the film while the conductive material is applied onto the opposite side of the film. The film is bonded directly to a current collector of an energy storage device.Type: GrantFiled: July 28, 2004Date of Patent: September 5, 2006Assignee: Maxwell Technologies, Inc.Inventors: Porter Mitchell, Xiaomei Xi, Linda Zhong, Vincent Hermann