Monochromator Or Focusing Device Patents (Class 378/84)
  • Patent number: 5737137
    Abstract: A critical illumination condenser system, particularly adapted for use in extreme ultraviolet (EUV) projection lithography based on a ring field imaging system and a laser produced plasma source. The system uses three spherical mirrors and is capable of illuminating the extent of the mask plane by scanning either the primary mirror or the laser plasma source. The angles of radiation incident upon each mirror of the critical illumination condenser vary by less than eight (8) degrees. For example, the imaging system in which the critical illumination condenser is utilized has a 200 .mu.m source and requires a magnification of 26.times.. The three spherical mirror system constitutes a two mirror inverse Cassegrain, or Schwarzschild configuration, with a 25% area obstruction (50% linear obstruction). The third mirror provides the final pupil and image relay. The mirrors include a multilayer reflective coating which is reflective over a narrow bandwidth.
    Type: Grant
    Filed: April 1, 1996
    Date of Patent: April 7, 1998
    Assignee: The Regents of the University of California
    Inventors: Simon J. Cohen, Lynn G. Seppala
  • Patent number: 5727044
    Abstract: A tapered, spherically slumped, microchannel plate.
    Type: Grant
    Filed: April 17, 1997
    Date of Patent: March 10, 1998
    Assignee: University of Leicester
    Inventors: George William Fraser, Adam North Brunton, Adam Medley, Carl Jonathan Metcalf
  • Patent number: 5719915
    Abstract: Two kinds of substances are deposited on the surface of a substrate with their thicknesses being gradually decreased according to a Fresnel pattern to form a deposited material. The material is sliced in a direction parallel to the direction of deposition of the two kinds of substance. The slice is fixed as an interference plate on the surface of a dispersing crystal in order to obtain an X-ray dispersing/focusing device. The interference plate fixed on the surface of the dispersing crystal focuses photons by the Fresnel diffraction during the incidence and reflection of X-rays to and from the dispersing crystal, and acts as a dispersing/focusing device as a whole. The dispersing crystal also acts as a base plate supporting the interference plate. Since an interference plate with an outermost zone width of the Fresnel pattern of 1 nm or less is producible, the focusing of X-rays to small regions can be realized.
    Type: Grant
    Filed: March 6, 1996
    Date of Patent: February 17, 1998
    Assignee: Agency of Industrial Science and Technology
    Inventors: Masaki Koike, Isao Suzuki
  • Patent number: 5715291
    Abstract: A phase-contrast X-ray CT apparatus is provided with an X-ray source for generating an X-ray beam, a crystal for generating a diffracted beam by irradiation with the X-ray beam, an object arranging section provided in the direction of propagation of the diffracted beam so that it is rotatable relative to the diffracted beam, an analyzer crystal for receiving a beam transmitted through the object arranging section to extract only a specified refraction angle component, and a sensor for detecting a beam extracted by the analyzer crystal.
    Type: Grant
    Filed: January 8, 1997
    Date of Patent: February 3, 1998
    Assignee: Hitachi, Ltd.
    Inventor: Atsushi Momose
  • Patent number: 5684852
    Abstract: An X-ray lens includes a plurality of hollow cylinders of prescribed radius bored in a lens material piece having a phase lag coefficient appropriate for the wavelength of the X-rays to be focused such that the axes of the hollow cylinders are parallel and perpendicularly intersect a straight array axis.
    Type: Grant
    Filed: October 25, 1996
    Date of Patent: November 4, 1997
    Assignee: Agency of Industrial Science & Technology, Ministry of International Trade & Industry
    Inventor: Toshihisa Tomie
  • Patent number: 5677939
    Abstract: The present invention relates to an illuminating apparatus for illuminating an illuminated object in an arcuate pattern and, more particularly, to an illuminating apparatus suitably applicable to exposure apparatus suitably used in transferring a circuit pattern on a photomask (mask or reticle) through a reflection type imaging apparatus onto a substrate such as a wafer by the mirror projection method, for example of an X-ray optical system. The illuminating apparatus of the present invention can illuminate the illuminated surface in an arcuate pattern with uniform intensity. Exposure apparatus provided with the illuminating apparatus of the present invention can obtain an image with uniform exposure over the entire arcuate surface as the illuminated surface, so that the pattern on the mask located on the illuminated surface can be accurately transferred with high throughput onto the substrate.
    Type: Grant
    Filed: February 23, 1995
    Date of Patent: October 14, 1997
    Assignee: Nikon Corporation
    Inventor: Tetsuya Oshino
  • Patent number: 5669708
    Abstract: An optical element for X-ray reflection according to the present invention is provided with a number of fine convex surfaces or concave surfaces regularly arranged on a substrate. Multilayer films reflecting X-rays are formed over the convex surfaces or concave surfaces. The convex surfaces or concave surfaces have such a shape that when X-rays enter each concave surface or convex surface, they are reflected with a certain diverging angle by the multilayer films and as a result that a plurality of secondary X-ray sources having the diverging angle are formed on a same plane located a certain distance apart from the concave surfaces or convex surfaces. By this, a number of secondary X-ray sources are formed to enable uniform irradiation of X-rays in a wide region.
    Type: Grant
    Filed: February 28, 1996
    Date of Patent: September 23, 1997
    Assignee: Nikon Corporation
    Inventors: Kiyoto Mashima, Takashi Mori, Osamu Tanitsu
  • Patent number: 5646976
    Abstract: This invention relates to novel methods of producing flat and curved optical elements with laterally and depth graded multilayer thin films, in particular multilayers of extremely high precision, for use with soft and hard x-rays and neutrons and the optical elements achieved by these methods. In order to improve the performance of an optical element, errors in d spacing and curvature are isolated and subsequently compensated.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: July 8, 1997
    Assignee: Osmic, Inc.
    Inventor: George Gutman
  • Patent number: 5633908
    Abstract: The invention relates to a measuring element for a portable micro-X-ray spectrometer, said element comprising a radiation protected housing, at least an X-ray source, a detector, cooling parts for the detector and means for activating the X-ray source and the detector. In accordance with the invention, in order to advantageously guide the X-rays obtained by the X-ray source away from the radiation protected housing (1), at least one capillary tube (3) has been mounted in the X-ray source (4), said capillary tube (3), at the opposite end of the tube as seen from the X-ray source, being connected to a hole formed in the detector (5) for conducting the X-rays out of the radiation protected housing (1). The inner section of the capillary tube (3) is smaller at the end which, seen from the X-ray source, is opposite than at the end at the X-ray source (4).
    Type: Grant
    Filed: November 28, 1995
    Date of Patent: May 27, 1997
    Assignees: Metorex International Oy, X-ray Capillary Optics AB
    Inventors: Anders Rindby, Panu Jalas
  • Patent number: 5619382
    Abstract: A reflection type imaging optical system is provided with at least one reflecting mirror, whose reflecting surface is constructed of a plurality of zone areas different from each other in spectral reflectance characteristics. Further, in the optical system, the spectral reflectance characteristics of each zone area are selected so that an incident angle providing the maximum reflectance when a ray of light of a predetermined wavelength is incident on each zone area has a value between the maximum and the minimum of the incident angle in the zone area. The reflection type imaging optical system thus provides an important advantage in practical use in that the reflection efficiency of each reflecting surface is enhanced to bring about the brightness necessary for the imaging surface.
    Type: Grant
    Filed: June 25, 1993
    Date of Patent: April 8, 1997
    Assignee: Olympus Optical Co., Ltd.
    Inventors: Mikiko Kato, Yoshinori Iketaki
  • Patent number: 5619548
    Abstract: A monochromator positioned in the path of a plurality of X-rays to simultaneously impinge the plurality of X-rays onto a thin-film at various angles of incidence, typically greater than a critical angle .psi..sub.c. The monochromator may be cylindrically or toroidally shaped, defining two focal areas with a source of X-rays positioned at the first focal point and a sample containing the thin-film layer positioned at the second focal point. A position sensitive detector is positioned to sense monochromatic X-rays reflected from the thin-film and produce a signal corresponding to both intensity and an angle of reflection of the monochromatic X-rays sensed. A processor is connected to receive signals produced by the detector to determine, as a function of intensity and angle of reflection of the monochromatic X-rays impinging on the detector, various properties of the structure of the thin-film layer, including the thickness, density and smoothness.
    Type: Grant
    Filed: August 11, 1995
    Date of Patent: April 8, 1997
    Assignee: Oryx Instruments and Materials Corp.
    Inventor: Louis N. Koppel
  • Patent number: 5615245
    Abstract: A monochromator for radiant X-rays is composed of a first crystal which has a first surface of incidence having a concave letter V-shaped groove and cooling means for flowing a cooling material behind the first surface of incidence along the letter V-shaped groove, and a second crystal which has a second surface of incidence having a letter V-shaped convex. A parallel pencil of X-rays which impinges on the first surface of incidence elongates to a half-ellipse on the first surface of incidence and reflects in parallel therefrom to the second surface of incidence. Then, a pencil of emissive X-rays having the same size as the initial parallel pencil of X-rays exits the second surface of incidence to become useful light. The monochromator for radiant X-rays which has a high cooling efficiency, is easy to adjust, provides a pencil of emissive X-rays stably and highly accurately. The monochromator is easy to use and economical, and allows easy maintenance.
    Type: Grant
    Filed: February 26, 1996
    Date of Patent: March 25, 1997
    Assignee: Japan Atomic Energy Research Institute
    Inventor: Shinya Hashimoto
  • Patent number: 5596620
    Abstract: An apparatus which allows monochromatic radiographs to be produced using conventional "table top" Coolidge tube generated x-rays, comprises of the use of known bent crystal x-ray diffractive optics to produce radiographic images. The apparatus for producing the desirable x-ray radiation in a predetermined maximum intensity includes a crystal of the type mentioned above which focuses the x-rays emitted from the tube, the crystal and tube being mounted on a linear translation table. In addition, a method of mammography and differential angiography employing that device are presented. Resolution of mammographs are improved and the method which uses images obtained with radiation above and below the absorption edge of the dye being used to detect anomalies in a circulatory system allows the use of dramatically reduced dye concentrations.
    Type: Grant
    Filed: January 27, 1995
    Date of Patent: January 21, 1997
    Assignee: The University of Connecticut
    Inventors: Howard A. Canistraro, Eric H. Jordan, Douglas M. Pease
  • Patent number: 5594773
    Abstract: An X-ray lens includes a plurality of hollow cylinders of prescribed radius bored in a lens material piece having a phase lag coefficient appropriate for the wavelength of the X-rays to be focused such that the axes of the hollow cylinders are parallel and perpendicularly intersect a straight array axis.
    Type: Grant
    Filed: February 16, 1995
    Date of Patent: January 14, 1997
    Assignee: Agency of Industrial Science & Technology, Ministry of International Trade & Industry
    Inventor: Toshihisa Tomie
  • Patent number: 5581605
    Abstract: An optical element for X-ray reflection according to the present invention is provided with a number of fine convex surfaces or concave surfaces regularly arranged on a substrate. Multilayer films reflecting X-rays are formed over the convex surfaces or concave surfaces. The convex surfaces or concave surfaces have such a shape that when X-rays enter each concave surface or convex surface, they are reflected with a certain diverging angle by the multilayer films and as a result that a plurality of secondary X-ray sources having the diverging angle are formed on a same plane located a certain distance apart from the concave surfaces or convex surfaces. By this, a number of secondary X-ray sources are formed to enable uniform irradiation of X-rays in a wide region.
    Type: Grant
    Filed: March 7, 1995
    Date of Patent: December 3, 1996
    Assignee: Nikon Corporation
    Inventors: Katsuhiko Murakami, Kiyoto Mashima, Takashi Mori, Osamu Tanitsu
  • Patent number: 5579363
    Abstract: This invention relates to nondestructive testing of the internal structure of objects.The method for obtaining the image of The internal structure of an object consists in that the flux of a penetrating radiation emitted by a source (1) is collimated by a single-crystal monochromator (4), an object (7) is irradiated with the thus-collimated radiation, the radiation transmitted through the object (7) is collimated by a single-crystal (8) and then registered by a detector (9). According to the invention, use is made for irradiating the object, of an asymmetrical reflection of the radiation from the single-crystal monochromator (4), a pseudosheet-like beam (5) is formed, having a wide wavefront and a divergence in the Bragg diffraction plane at least twice as little as the width of the Bragg reflection of the single-crystal (8), which is set in the position of Bragg reflection with respect to the pseudosheet-like beam (5) formed by the single-crystal monochromator (4).
    Type: Grant
    Filed: July 11, 1995
    Date of Patent: November 26, 1996
    Assignee: V-Ray Imaging Corporation
    Inventors: Viktor N. Ingal, Elena A. Belyaevskaya, Valery P. Efanov
  • Patent number: 5570408
    Abstract: A system comprising a novel combination of a multiple-channel monolithic capillary optic and an x-ray source with a spot size of less than 300 microns to produce a high intensity small diameter x-ray beam is described. A system of this invention can be easily adapted for use in the analysis of small samples where an intense quasi-parallel, or converging x-ray beam is required.
    Type: Grant
    Filed: February 28, 1995
    Date of Patent: October 29, 1996
    Assignee: X-Ray Optical Systems, Inc.
    Inventor: David M. Gibson
  • Patent number: 5569919
    Abstract: An X-ray analytical apparatus of a wavelength dispersion type having a construction of essential parts improved using a microprobe of ion beam. An ion beam 10 is controlled to be deflected to scan in a fine region of a sample 3, a characteristic X-ray generated by irradiation of the ion beam is subjected spectro-process by a analyzing element 5 set to a predetermined radius of curvature by a curvature changing mechanism, and an X-ray having a specific wavelength selected by the spectro-process is detected by a proportional counter 7. When an angle of the analyzing element is set by a rotational stage to an incident angle of a specific X-ray determined by a detection element on the sample 3, a wide range of wavelength can be subjected to spectro-measured while the sample 3, the analyzing element 5 and the proportional counter 7 remain fixed in position.
    Type: Grant
    Filed: September 19, 1995
    Date of Patent: October 29, 1996
    Assignee: Kabushiki Kaisha Kobe Seiko Sho
    Inventors: Kazushi Yokoyama, Norio Suzuki, Kenichi Inoue, Yukito Furukawa
  • Patent number: 5528654
    Abstract: A multilayer film for X-rays comprising two kinds of films having different refractive indices, deposited alternately, wherein one of said two kinds of films which has smaller refractive index consists of an alloy containing Co and Cr. The multilayer film is capable of being utilized as an optical element such as a reflection mirror or a reflection-type X-ray mask.
    Type: Grant
    Filed: June 10, 1994
    Date of Patent: June 18, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masahito Niibe, Yasuaki Fukuda
  • Patent number: 5524040
    Abstract: A 4-bounce dispersive crystal monochromator reduces the bandpass of synchrotron radiation to a 10-50 meV range without sacrificing angular acceptance. The monochromator includes the combination of an asymmetrical channel-cut single crystal of lower order reflection and a symmetrical channel-cut single crystal of higher order reflection in a nested geometric configuration. In the disclosed embodiment, a highly asymmetrically cut (.alpha.=20) outer silicon crystal (4 2 2) with low order reflection is combined with a symmetrically cut inner silicon crystal (10 6 4) with high order reflection to condition a hard x-ray component (5-30 keV) of synchrotron radiation down to the .mu.eV-neV level. Each of the crystals is coupled to the combination of a positioning inchworm and angle encoder via a respective rotation stage for accurate relative positioning of the crystals and precise energy tuning of the monochromator.
    Type: Grant
    Filed: December 17, 1993
    Date of Patent: June 4, 1996
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Ercan E. Alp, Timothy M. Mooney, Thomas Toellner
  • Patent number: 5509043
    Abstract: An X-ray analysis apparatus comprises a dispersive system of crystals for monochromatizing an incoming beam in a diffractometer or for analyzing an X-ray beam in an X-ray spectrometer. The system of crystals comprises crystals whose crystal lattice planes do not extend parallel to effectively reflective crystal surfaces. As a result, a substantially higher effective radiation intensity can be obtained, for example notably for (220) crystal faces in germanium.
    Type: Grant
    Filed: July 18, 1994
    Date of Patent: April 16, 1996
    Assignee: U.S. Philips Corporation
    Inventor: Paul Van Der Sluis
  • Patent number: 5485498
    Abstract: An x-ray interface (40) provides increased x-ray collection efficiency for use in x-ray photolithography. The interface (40) comprises a housing (44) having a plurality of mirrored funnels (46) for collecting the x-rays. The mirrored funnels (46) are shaped to partially collimate and focus the x-rays. The interface (40) collects a greater percentage of the available x-rays from an x-ray source, and the interface (40) also permits a greater number of beamlines to be coupled to the x-ray source.
    Type: Grant
    Filed: July 1, 1994
    Date of Patent: January 16, 1996
    Assignee: Motorola, Inc.
    Inventors: Whitson G. Waldo, III, Eric Brodsky, Franco Cerrina
  • Patent number: 5485499
    Abstract: X-ray dispersive and reflective structures utilizing special materials which exhibit improved performance in the specific ranges of interest. The structures are formed of alternating thin layers of uranium, uranium compound or uranium alloy and another spacer material consisting of elements or compounds with low absorptance chosen to match the wavelength of interest. These low index of refraction elements or compounds are those best suited for water window microscopy and nitrogen analysis, or are similar elements or compounds best suited for carbon analysis, boron analysis, and x-ray lithography. The structures are constructed using standard thin layer deposition techniques such as evaporation, sputtering, and CVD, or by novel methods which allow thinner and smoother layers to be deposited.
    Type: Grant
    Filed: August 5, 1994
    Date of Patent: January 16, 1996
    Assignee: Moxtek, Inc.
    Inventors: Hans K. Pew, David D. Allred
  • Patent number: 5485497
    Abstract: An optical element which allows replication of a refined pattern and a projection exposure apparatus employing the optical element are disposed so that side face portions of predetermined patterns which create shadows from oblique incident exposure radiation may be minimized at a predetermined incidence angle of vacuum ultrasonic radiation or X-radiation, or the patterns of the optical element are formed such that the direction in which incident radiation is reflected regularly and the direction of side faces of the patterns may extend in parallel to each other. When the optical element is irradiated to replicate or image the patterns of the optical element, refined patterns can be replicated or imaged.
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: January 16, 1996
    Assignee: Hitachi, Ltd.
    Inventors: Hiroaki Oizumi, Masaaki Ito, Takashi Soga, Taro Ogawa, Kozo Mochiji, Eiji Takeda
  • Patent number: 5461657
    Abstract: An X-ray mirror has a silicon carbide substrate having a convex cylindrical surface, and a carbon layer coated on a surface of said substrate to a thickness ranging from 10 nm to 1 .mu.m by evaporation, such as CVD. In the X-ray mirror in which the carbon layer is coated thereon beforehand, changes in the intensity of reflected light, caused by a contaminating carbon layer attached to the surface of the mirror, can be restricted. When such a mirror is used in an X-ray lithographic apparatus, the number of times the intensity of X-rays is measured or corrected or the mirror is cleaned can be greatly reduced.
    Type: Grant
    Filed: June 28, 1994
    Date of Patent: October 24, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masami Hayashida, Yutaka Watanabe
  • Patent number: 5458084
    Abstract: X-ray wave diffraction devices are constructed using atomic layer epetaxy. A crystalline substrate is prepared with one or more surface areas on which multiple pairs of layers of material are to be deposited. These layers are then formed by atomic layer epetaxy on the surface areas of the substrate, one on top of another, with the material of each layer of each pair being selected to have a different index of refraction from that of the material of the other layer of each pair. The layers are formed so that the thickness of each layer of a pair is substantially the same as that of the corresponding layer of every other pair and so that x-ray waves impinging on the layers may be reflected therefrom. Layer pairs having a thickness of about 20 angstroms or less are formed on the substrate.
    Type: Grant
    Filed: December 9, 1993
    Date of Patent: October 17, 1995
    Assignee: Moxtek, Inc.
    Inventors: James M. Thorne, James K. Shurtleff, David D. Allred, Raymond T. Perkins
  • Patent number: 5454021
    Abstract: An x-ray mirror material of high reflectance with a surface roughness which is very small and a high film density, the material being a Pt alloy film provided as a mirror surface for reflecting x-ray radiation. The composition of the mirror material is expressed by the general formula: Pt.sub.1-x M.sub.x. This material is deposited on a substrate surface which has been polished to a level form, where M is at least one substance selected from Mo, Ru, Rh, Pd, Ta, W, and Au, and x satisfies the formula: 0.005.ltoreq..times..ltoreq.0.10.
    Type: Grant
    Filed: November 9, 1993
    Date of Patent: September 26, 1995
    Assignee: Seiko Instruments, Inc.
    Inventors: Kunio Nakajima, Shuzo Sudo
  • Patent number: 5448612
    Abstract: An X-ray apparatus is disclosed which includes a mirror having a reflection surface, for expanding an X-ray beam in a predetermined direction, a detecting device for detecting a relative positional relationship between the X-ray beam and the reflection surface with respect to a direction perpendicular to the reflection surface, and an adjusting device for adjusting the relative position of the X-ray beam and the reflection surface on the basis of the detection. Also disclosed is an exposure apparatus and a semiconductor device manufacturing method using the X-ray apparatus.
    Type: Grant
    Filed: July 15, 1994
    Date of Patent: September 5, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kazuyuki Kasumi, Naoto Abe, Ryuichi Ebinuma, Takayuki Hasegawa
  • Patent number: 5406609
    Abstract: An X-ray analysis apparatus including an artificial multi-layered grating for rendering X-ray beams to be monochromatic before they are incident on a specimen to be analyzed. This artificial multi-layered grating operates to diffract the X-ray beam, generated from an X-ray radiation source and subsequently impinging on a reflective surface of the artificial multi-layered grating, at a predetermined angle of diffraction to provide the monochromatic X-ray beams. The periodicity of the spacing of lattice planes of the artificial multi-layered grating is so chosen as to be of a value progressively varying along the reflective surface thereof with an increase in distance from the X-ray radiation source. The X-ray analysis apparatus herein disclosed is designed to avoid any possible reduction of the intensity of the X-ray beams which would occur when they are rendered to be monochromatic, and to increase the intensity of the X-ray beams to ensure an improved accuracy in spectroscopic analysis.
    Type: Grant
    Filed: April 9, 1993
    Date of Patent: April 11, 1995
    Assignee: Rigaku Industrial Corporation
    Inventors: Tomoya Arai, Takashi Shoji
  • Patent number: 5394451
    Abstract: An optical arrangement includes an optical system for transforming synchrotron radiation light emitted from an emission point of a synchrotron ring into a substantially parallel beam, with respect to a first direction which is parallel to an orbit plane of the synchrotron ring and with respect to a second direction which is perpendicular to the orbit plane, wherein an absolute value of a focal length of the optical system in the first direction is smaller than that in the second direction.
    Type: Grant
    Filed: October 2, 1992
    Date of Patent: February 28, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Akira Miyake, Yutaka Watanabe
  • Patent number: 5390228
    Abstract: A temperature distribution of an object, such as an optical element, onto which radiation energy is irradiated, is measured. The change of the shape of the object is controlled by varying the temperature of a part of the object on the basis of the measured temperature distribution to stabilize the shape of the object. Also, the shape of the object being irradiated is stabilized by causing the same temperature distribution in the object when in the thermally stable condition to be generated in the object while it is being irradiated. If the shapes of masks used to manufacture semiconductor devices are stabilized by using the above methods, highly integrated semiconductor devices can be manufactured.
    Type: Grant
    Filed: July 5, 1994
    Date of Patent: February 14, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masahito Niibe, Yasuaki Fukuda, Masami Hayashida
  • Patent number: 5384817
    Abstract: X-ray dispersive elements comprise a stacked array of layer pairs of boron nitride and either nickel, tungsten, chromium, vanadium, iron, manganese, cobalt and combinations thereof. The boron nitride is preferably deposited through a planar magnetron sputtering process.
    Type: Grant
    Filed: July 12, 1993
    Date of Patent: January 24, 1995
    Assignee: Ovonic Synthetic Materials Company
    Inventors: David J. Crowther, George Gutman
  • Patent number: 5371774
    Abstract: An X-ray lithography beamline imaging system has a single condenser mirror with an aspherical reflecting surface, with symmetry only about a plane, without axial symmetry. For an X-ray beam emitted along a y axis and diverging along x and z axes, the reflecting surface is asymmetrical about the y axis and has different focusing power in directions along the x and z axes in an imaging plane orthogonal to the y axis and spaced from the mirror along the y axis such that the mirror reflects and focuses the X-ray beam to a point along the y axis in the imaging plane and to a line along the x axis in the imaging plane.This invention was made with United States Government support awarded by the National Science Foundation (NSF), Grant No. ECS-8921165, and the Naval Research Laboratory (NRL), Grant No. N00014-91-J-1876. The United States Government has certain rights in this invention.
    Type: Grant
    Filed: June 24, 1993
    Date of Patent: December 6, 1994
    Assignee: Wisconsin Alumni Research Foundation
    Inventors: Franco Cerrina, Jaibei Xiao
  • Patent number: 5353324
    Abstract: A method for detecting and evaluating crystal defects existing in the extreme neighborhood of the surface of a crystal specimen through the use of X-ray analyzing micrography. Synchrotron radiation is used as the X-ray source. A monochromatic X-ray beam generated from the synchrotron radiation is directed into the crystal specimen at a glancing angle smaller than the critical angle of said crystal specimen relative to said monochromatic X-ray beam. The diffracted X-rays from the crystal specimen due to asymmetrical reflection are detected in order to observe the resulting diffracted image.
    Type: Grant
    Filed: April 8, 1992
    Date of Patent: October 4, 1994
    Assignee: NEC Corporation
    Inventor: Tomohisa Kitano
  • Patent number: 5349192
    Abstract: A solid state x-ray detector has a set of bilayers formed on its front surface. Each bilayer includes a spacing layer and an absorbing layer which have different indexes of refraction, and the impinging x-rays strike the bilayers at an angle which satisfies the Bragg condition. As a result, x-rays polarized in one direction are substantially reflected while x-rays polarized in an orthogonal direction pass through the bilayers for detection by the solid state x-ray detector.
    Type: Grant
    Filed: May 20, 1993
    Date of Patent: September 20, 1994
    Assignee: Wisconsin Alumni Research Foundation
    Inventor: James F. Mackay
  • Patent number: 5333166
    Abstract: A self-apodizing collimator for collimating X-rays for use in VLSI lithography. The paraboloidal collimator uses a graded ML coating to collimate a range of wavelengths along the surface of the paraboloid such that a uniform resist response is provided. In addition, the collimated X-rays have a higher intensity than possible with a system using additional apodizing films.
    Type: Grant
    Filed: August 28, 1992
    Date of Patent: July 26, 1994
    Assignee: Intel Corporation
    Inventors: Daniel Seligson, Jeffrey Kidder
  • Patent number: 5319694
    Abstract: This invention relates to nondestructive testing of the internal structure of objects.The method for obtaining the image of the internal structure of an object consists in that the flux of a penetrating radiation emitted by a source (1) is collimated by a single-crystal monochromator (4), an object (7) is irradiated with the thus-collimated radiation, the radiation transmitted through the object (7) is collimated by a single-crystal (8) and then registered by a detector (9). According to the invention, use is made for irradiating the object, of an asymmetrical reflection of the radiation from the single-crystal monochromator (b 4), a pseudosheet-like beam (5) is formed, having a wide wavefront and a divergence in the Bragg diffraction plane at least twice as little as the width of the Bragg reflection of the single-crystal (8), which is set in the position of Bragg reflection with respect to the pseudosheet-like beam (5) formed by the single-crystal monochromator (4).
    Type: Grant
    Filed: December 11, 1992
    Date of Patent: June 7, 1994
    Inventors: Viktor N. Ingal, Elena A. Belyaevskaya, Valery P. Efanov
  • Patent number: 5319695
    Abstract: On a substrate materials of different X-ray refractive indexes, for example, silicon (si) and molybdenum (Mo), are alternately deposited to form a multilayer film composed of silicon nd molybdenum layers and a hydrogenated interface layer is formed between each pair of adjacent layers.
    Type: Grant
    Filed: April 14, 1993
    Date of Patent: June 7, 1994
    Assignee: Japan Aviation Electronics Industry Limited
    Inventors: Kazuhiko Itoh, Izumi Kataoka
  • Patent number: 5315113
    Abstract: An instrument for surface analysis includes a gun for selectively focusing an electron beam on an anode spot, or rastering the beam across an array of such spots, to generate x-rays. A concave monochromator focuses an energy peak of the x-rays to a specimen surface, in a spot on a selected pixel area or across an array of pixel areas on the surface to emit photoelectrons. An analyzer with a detector provides information on the photoelectrons and thereby chemical species in the surface. A second detector of low energy photoelectrons is cooperative with the rastering to produce a scanning photoelectron image of the surface, for viewing of a specimen to be positioned, or for imaging an insulator surface. The monochromator is formed of platelets produced by cutting an array of platelets from a single crystal member, and bonding the platelets to a concave face of a base plate juxtaposed in crystalline alignment in a positioned array identical to that of the initial array.
    Type: Grant
    Filed: September 29, 1992
    Date of Patent: May 24, 1994
    Assignee: The Perkin-Elmer Corporation
    Inventors: Paul E. Larson, Paul W. Palmberg
  • Patent number: 5311565
    Abstract: A soft X-ray microscope comprising a soft X-ray radiation source which is substantially a spot radiation source, a condenser for leading soft X-rays from the radiation source to a sample, a reflecting mirror for grazing incidence which is disposed between the radiation source and the condenser, and has a rough reflecting surface, an objective optical system for forming a magnified image of the sample, and a soft X-ray detector for receiving the soft X-rays from the objective optical system. This microscope exhibits excellent imaging characteristic even when it uses a spot radiation source.
    Type: Grant
    Filed: May 29, 1992
    Date of Patent: May 10, 1994
    Assignee: Olympus Optical Co., Ltd.
    Inventor: Yoshiaki Horikawa
  • Patent number: 5307395
    Abstract: A mirror for reflecting radiation at a desired wavelength in the soft x-ray region, comprises a substrate and a coating on the substrate. The coating contains a first section and a second section. The first section comprises at least one layer made up of at least a spacer sublayer and a nodal sublayer. The optical thickness of each spacer sublayer is selected so that, upon application of the radiation of desired wavelength, the mirror generates a standing wave having a node in the middle of each nodal sublayer. The second section is disposed between the first section and the substrate, and comprises a plurality of optically absorptive layers.
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: April 26, 1994
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: John F. Seely, William R. Hunter
  • Patent number: 5305364
    Abstract: Reduction projection type X-ray lithography with an exposing beam wavelength of 40-150A, longer than in conventional 1:1 proximity exposure, has a high-vacuum space. This would reduce wafer replacement work efficiency and contaminate optical mirrors with substances released by a resist decomposed during exposure except for separating an optical system chamber and a wafer exposing chamber by a differential pumping section and a thin-film window. Wafer exposure is under atmospheric pressure, improving productivity, accuracy of exposure and longevity of the optical devices.
    Type: Grant
    Filed: September 15, 1992
    Date of Patent: April 19, 1994
    Assignee: Hitachi, Ltd.
    Inventors: Kozo Mochiji, Hiroaki Oizumi, Shigeo Moriyama, Shinji Okazaki, Tsuneo Terasawa, Masaaki Itou
  • Patent number: 5274435
    Abstract: An optical system and method comprising a diffraction grating which rotates about its surface normal to change the magnitude of the wavelength diffracted to an image location. At grazing incidence, such a rotation is determined to maintain the diffracted image in focus over a wide range in scanned wavelength. Monochromator and spectrometer embodiments include plane and curved surface gratings with both classical and varied-spaced groove patterns, and a variety of illumination geometries. In the simplest case, a grazing incidence monochromator is constructed in which a self-focusing classical spherical grating scans the value in wavelength which is transmitted between fixed slits located on the Rowland circle of the grating. The diffracted image remains in perfect focus over two octaves in wavelength at high efficiency, with both entrance and exit slits fixed in position, and the radiation aperture is constant.
    Type: Grant
    Filed: February 26, 1992
    Date of Patent: December 28, 1993
    Inventor: Michael C. Hettrick
  • Patent number: 5268954
    Abstract: A mounting mechanism for a double crystal monochromator or the like has a parallelogram based mounting mechanism in which two of the vertices of the parallelogram are fixed in position, and two vertices are free to translate back and forth in a straight line parallel to the fixed base of the parallelogram. One diffractor is mounting for pivoting at one of the fixed vertices, and the second diffractor is mounted for pivoting at an adjacent movable vertex. The surfaces of the diffractors are maintained parallel as the angle of the diffractors with respect to input and output beams to the monochromator is changed to change the wavelength being passed. The diffractor mounted at the fixed pivot may be connected to a large diameter wheel which in turn is connected by a band to a smaller diameter wheel mounted for rotation at the other fixed vertex of the parallelogram, with a pivotable arm connected to the smaller wheel to rotate therewith.
    Type: Grant
    Filed: October 14, 1992
    Date of Patent: December 7, 1993
    Assignee: Wisconsin Alumni Research Foundation
    Inventor: Frederic H. Middleton
  • Patent number: 5265143
    Abstract: In one aspect, the invention involves an optical element in an x-ray imaging system. The element comprises a substrate overlain by a multilayer coating. The multilayer coating comprises plural first and at least second material layers in alternation. This coating is soluble in at least one etchant solution at an etching temperature less than 100.degree. C. The optical element further comprises a barrier layer intermediate the substrate and the multilayer coating. The barrier layer is relatively insoluble in the etchant solution at the etching temperature. In a second aspect of the invention, the optical element comprises a substrate and a multilayer coating as described above, and further comprises a release layer that underlies the multilayer coating. The release layer comprises a material that is relatively soluble in at least one etchant solution at an etching temperature less than 100.degree. C. In contrast to release layers of the prior art, the inventive release layer comprises germanium.
    Type: Grant
    Filed: January 5, 1993
    Date of Patent: November 23, 1993
    Assignee: AT&T Bell Laboratories
    Inventors: Kathleen R. Early, Richard E. Howard, Donald M. Tennant, Warren K. Waskiewicz, David L. Windt
  • Patent number: 5263073
    Abstract: Novel methods and apparatus for high resolution electron beam and X-ray lithography. For electron-beam lithography, a novel 1:1 imaging system is disclosed. For X-ray lithography, novel 1:1 imaging and n:1 reduction imaging systems are disclosed.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: November 16, 1993
    Assignee: Board of Supervisors of Louisiana State University and Agricultural and Mechanical College
    Inventor: Martin Feldman
  • Patent number: 5257303
    Abstract: A beam generating apparatus the combination comprising a first binary alloy target crystal consisting essentially of an alloy of copper and silver, for producing a primary x-ray beam; a second target crystal consisting essentially of copper in the path of the first x-ray beam and oriented to produce a CuK.alpha., radiation in response to impingement of the primary beam.
    Type: Grant
    Filed: August 3, 1992
    Date of Patent: October 26, 1993
    Inventor: Kamalaksha Das Gupta
  • Patent number: 5249215
    Abstract: X-ray exposure equipment which can effectively converge a synchrotron radiation, which tends to diverge to a great extent in a horizontal direction, to assure a sufficiently high intensity on a lithographic plane and can irradiate X-rays perpendicularly to a full lateral extent of the lithographic plane over an entire exposure area. The X-ray exposure equipment comprises a point X-ray source and a first reflecting mirror having first and second point focuses and disposed such that the first focal point coincides with the location of the X-ray source so as to focus X-rays to the second focal point. A second reflecting mirror is disposed such that the focus thereof substantially coincides with the second focal point of the first reflecting mirror so as to collimate X-rays received from the first reflecting mirror by way of the focusing property thereof in parallel to a principal optical axis of an optical system for X-rays which includes the first and second reflecting mirrors.
    Type: Grant
    Filed: March 9, 1992
    Date of Patent: September 28, 1993
    Assignee: Mitsubishi Denki Kabushiki Kaisha
    Inventor: Hiroki Shimano
  • Patent number: 5249216
    Abstract: A total reflection X-ray fluorescence apparatus comprises a base material having an optically flat surface for totally reflecting X-rays radiated at a small glancing angle, a first detector such as an SSD for detecting fluorescent X-rays emerging from a specimen located near the optically flat surface of the base material and a second detector such as a scintillation counter for detecting an intensity of an X-rays coming from the base material.
    Type: Grant
    Filed: October 15, 1990
    Date of Patent: September 28, 1993
    Assignees: Sumitomo Electric Industries, Ltd., Technos Co., Ltd.
    Inventors: Tetsuya Ohsugi, Michihisa Kyoto, Kazuo Nishihagi
  • Patent number: 5241426
    Abstract: A condenser optical system is provided for bringing a beam of light from a light source to a focus at a desired position. The condenser optical system has a reflecting surface including a quadric surface of revolution represented by Equation (1) described below. The reflecting surface satisfies the conditions of Equations (2) and (3) described below when the condenser optical system is disposed so that the light beam from the light source is incident, substantially parallel to a rotary axis of the quadric surface, on the reflecting surface:z=Cy.sup.2 /{1+(1-pC.sup.2 y.sup.2).sup.1/2 } (1)Ch<22 (2)78-4.theta..sub.
    Type: Grant
    Filed: April 22, 1992
    Date of Patent: August 31, 1993
    Assignee: Olympus Optical Co., Ltd.
    Inventors: Shoichiro Mochimaru, Yoshiaki Horikawa