Abstract: This invention relates to a corrosion inhibiting composition for use in commercial, institutional, and industrial water systems. The compositions comprise a mixture of (1) a fatty acid ester, and (2) a polyethylene glycol ester. These compositions are useful in inhibiting the corrosion of metals such as steel, copper, and brass, which are exposed to water.

Abstract: A method for mitigating stress corrosion cracking in high temperature water includes introducing catalytic nanoparticles and dielectric nanoparticles to the high temperature water in an amount effective to reduce a electrochemical corrosion potential of the high temperature water.

Abstract: A composition for lubricating, preventing mineral deposit buildup, and expelling any standing water from the internal parts of a pressure washer, as well as a pressurized container for applying such composition across the internal parts of the pressure washer through the water inlet valve is provided.

Abstract: Stabilized bromine solutions are prepared by combining a bromine source and a stabilizer to form a mixture, and then adding an oxidizer to the mixture.

Abstract: This invention relates to a process for scale inhibition using random copolymers of acrylic acid and a monomer that is hydrophobic.

Abstract: In a method of reducing corrosion of a metal material, a substance such as semiconductor for generating an electric current by thermal excitation is coated or adhered on a metal material surface, to be exposed to a water having a high temperature of 150° C. or more, of a boiler and ducts or pipes, to which hot water heated by the boiler contacts, of a thermal electric power plant or a nuclear reactor structural material or ducts or pipes surrounding the reactor in a nuclear power plant.

Abstract: This invention relates to a corrosion inhibiting composition for use in commercial, institutional, and industrial water systems. The compositions comprise a mixture of (1) a fatty acid ester, and (2) a polyalkylene glycol, preferably polyethylene glycol. These compositions are useful in inhibiting the corrosion of metals such as steel, copper, and brass, which are exposed to water.

Abstract: The invention concerns a method for the reducing the formation of slime and deposits in industrial plants, in which water or aqueous process liquids are circulated, sulphur-free lignin or a derivative thereof being added to the system in a quantity proportional to the quantity of the slime and deposit-causing substances present in the water.

Abstract: A method is disclosed to dissolve cupric oxide (CuO) deposits on a strainer in a stator water cooling system (SWCS) of an industrial electrical power generator. The method injects carbon dioxide (CO2) into the coolant to increase the CuO solubility of the coolant. By increasing the solubility, the CuO level in the coolant is less than saturated. The unsaturated coolant dissolves the CuO deposits on the strainer.

Abstract: The present invention relates to a method for inhibiting stress corrosion cracking occurring on steam generator tubes in the secondary side of nuclear power plants and an inhibitor therefor. The method comprises supplying cerium boride as an inhibitor for stress corrosion cracking into the secondary feed water of the nuclear power plants. The method according to the present invention improves resistance of stress corrosion cracking three times or higher than no inhibitor, and two times or higher than the conventional inhibitor. In particular, the method according to the present invention shows a superior inhibiting effect in the lead-contaminated environment such that the complete inhibition of stress corrosion cracking can be achieved. As thus, the method can reduce the unexpected stop of operating nuclear power plants caused by the stress corrosion cracking on steam generator tubes, thereby reducing the cost required for maintaining and repairing the tubes.

Abstract: A treatment for a dental water unit system comprises a shock treatment including silver colloid and hydrogen peroxide that stays in the system for an extended period, followed by a flushing of the system and the addition of a maintenance solution comprising at least silver colloid in an amount safe for human consumption.

Abstract: Provided are compositions and methods for releasing oxygen scavengers into a coolant. The compositions include a controlled release component and an oxygen scavenger component which includes at least one oxygen scavenger. Methods and devices for releasing oxygen scavengers into a coolant are also provided.

Abstract: A method and system for reducing stress corrosion cracking in a hot water system, such as a nuclear reactor, by reducing the electrochemical corrosion potential of components exposed to high temperature water within the structure. The method comprises the steps of: providing a reducing species to the high temperature water; and providing a plurality of noble metal nanoparticles having a mean particle size of up to about 100 nm to the high temperature water during operation of the hot water system. The catalytic nanoparticles, which may comprise at least one noble metal, form a colloidal suspension in the high temperature water and provide a catalytic surface on which a reducing species reacts with least one oxidizing species present in the high temperature water. The concentration of the oxidizing species is reduced by reaction with the reducing species on the catalytic surface, thereby reducing the electrochemical corrosion potential of the component.

Abstract: A method for inhibiting or retarding the corrosion of metals in contact with water solutions containing lithium halide comprises introducing into the solution a crystal habit modifier and lithium molybdate.

Abstract: Input water is preheated in a heat exchanger (2), pumped (4) through another heat exchanger (5) into a heating unit (6). The heating unit heats the water to a temperature of above 100° C., preferably 140-150° C., while maintaining the water in a liquid state without vaporization. A pump (8) feeds the heated water under sufficient pressure to prevent vaporization to at least one crossflow filtration unit (9). A portion of the heated water passes through a thermally stable filtration material having a pore size of 1-20 nanometers for filtering endotoxins and pyrogens, 4-10 nanometers for filtering viruses, or 100 nanometers−30 &mgr;m for filtering bacteria. Heated water which has passed through the filtration material is fed through a pure water product outlet of the filtration unit to a pure water outlet (16). A retenate portion of the heated water flows past the filtration material to carry filtered impurities through a retenate output line (10).

Abstract: Non-halogen substituted, nitrogen containing, aromatic compounds are disclosed which are effective copper corrosion inhibitors in aqueous systems being treated with a halogen biocide. The materials of the present invention exhibit copper corrosion inhibition comparable to tolyltriazole in the absence of halogen, copper corrosion rates of less than about 2.5 mills per year in aqueous systems where halogen is present; and do not exhibit a detrimental effect on halogen demand in an aqueous system being treated.

Abstract: A synergistic composition and method for controlling biological growth in industrial fluids are disclosed, wherein the composition comprises stabilized sodium hypobromite and at least one compound selected from the group consisting of coco alkyldimethylamine oxide, n-coco alkyltrimethylenediamine, tetra-alkyl phosphonium chloride, 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid and 4,5-dichloro-2-n-octyl-4-isothiazoline-3-one.

Abstract: Heat exchange water for cooling an object of heat exchange such as machinery, air, or liquid, which serves to prevent oxidation and deterioration of metal materials used in pipes for supplying/circulating the heat exchange water or in the liquid ends of the heat exchanger, to suppress growth of algae and microorganisms, and to reduce influence on the environment. The heat exchange water is reductive water having zero or negative standard oxidation-reduction potential as determined on the basis of the hydrogen electrode standard.

Abstract: Effective corrosion inhibitors having minimal organic content, particularly suitable for use in municipal drinking water systems, are described. The corrosion inhibiting additive is a stannous salt of a non-carbon acid.

Abstract: The invention concerns inhibitor compositions based on fatty sulphydryl acid and poly(ethyleneamino)imidazoline salts for considerably reducing the corrosive effect of carbon brine on iron and ferrous metals. These compositions are as efficient when the corrosive medium is driven with a high flowrate and in biphasic brine/oil medium.

Abstract: A dissolved oxygen removal method using an activated carbon fiber catalyst thereof which includes the steps of a reducing agent injection step for injecting a reducing agent into the water, a reactor entrance dissolved oxygen measuring step for measuring a concentration of a dissolved oxygen contained in a water, a water flow rate control step for controlling the supplied amount of the water, an activated carbon fiber catalyst reaction step for removing a dissolved oxygen contained in the water with the reaction between the reducing agent and the dissolved oxygen in an activated carbon fiber reactor in which an activated carbon fiber catalyst is packed, and a control step for controlling the feeding rate of the reducing agent in accordance with the water flow rate and the reactor entrance dissolved oxygen, for thereby extending the life time of the facility and decreasing the operational and maintenance costs by fully removing a dissolved oxygen in water used for an steam generator or cooling system.

Abstract: A water treating agent which has a high safety and is to be used for preventing corrosion and scale formation in the feed water lines and steam generation system and for preventing corrosion in the steam condensate lines in plants, boilers and steam generators.

Abstract: Methods and acidizing compositions for reducing the corrosion of the metal surfaces of tubular goods and the like and reducing the precipitation of metal sulfide from the acidizing compositions are provided. The methods basically comprise the steps of combining an aldol-amine adduct with an aqueous acid solution to preferentially react with sulfide ions subsequently dissolved by the aqueous acid solution and thereby prevent subsequently dissolved metal ions from reacting therewith and precipitating, and then introducing the aqueous acid solution containing the aldol-amine adduct into a well or other location to be acidized.

Abstract: Heat exchange water for cooling an object of heat exchange such as machinery, air, or liquid, which serves to prevent oxidation and deterioration of metal materials used in pipes for supplying/circulating the heat exchange water or in the liquid ends of the heat exchanger, to suppress growth of algae and microorganisms, and to reduce influence on the environment. The heat exchange water is reductive water having zero or negative standard oxidation-reduction potential as determined on the basis of the hydrogen electrode standard.

Abstract: The method of the present invention is to pump contaminated water, either by pushing or drawing, through a particulate filter and then through a contact chamber containing firstly copper wool and secondly brass wool. This method may be applied to a wide number of applications in which water is subject to either algae or bacterial contamination.

Abstract: Described and claimed is a method of controlling a cooling water system in which control is based on information from a control Matrix applicable to the specific operating parameters of the cooling water system including: (i) providing a suitable fluorometer, sufficient analytical devices and a suitable controller; (ii) programming the suitable fluorometer and controller using planning information from a control Matrix for cooling water systems being treated with treatment programs selected from the group consisting of: (d) stabilized phosphate, (e) zinc, and (f) all organic; (iii) using the fluorometer and sufficient analytical devices to determine the status of system factors; (iv) determining the pattern of changes in the readings from step (iii) over time; (v) comparing the changes in readings in steps (iii) and (iv), with the information listed in the control Matrix to determine what corrective action(s) is recommended; and (vi) using the controller to automatically implement the corrective acti

Abstract: Fluorescent monomers of the formula wherein M is selected from the group consisting of hydrogen, sodium, potassium, cesium, rubidium, lithium and ammonium, and n is selected from the group consisting of 1, 2, 3, 4, 6 and 9; are provided which are useful in the production of pyranine-tagged polymers which can be detected using a fluorometer and can be used in industrial water systems as treatment polymers.

Abstract: A method for reducing the level of hydrogen sulfide in water containing sulfur-reducing bacteria and hydrogen sulfide-metabolizing bacteria by addition of an aqueous solution of metallic nitrogen oxides and small particles of water-insoluble polycyclic quinones.

Abstract: A structure comprises, as the major component, a molded member of a thermoplastic resin composition or a fibrous material which may be a fiber of the thermoplastic resin composition, a yarn coated with the thermoplastic resin composition, a rope coated with the thermoplastic resin composition or a woven fabric coated with the thermoplastic resin composition. The thermoplastic resin composition contains an antifouling compound represented by the following formula (1): wherein Y represents hydrogen atom, an alkyl group, an alkenyl group or an aralkyl group, R represents hydrogen atom, a halogen atom or an alkyl group, R′ represents hydrogen atom, a halogen atom or an alkyl group and R and R′ may be bonded to each other to form a benzene ring. The leaching amount of the antifouling compound into an artificial sea water is controlled to 30 mg/cm3 or less at 25° C. and 3 mg/cm3 or more at 15° C.

Abstract: Effective corrosion inhibitors having minimal organic content, particularly suitable for use in municipal drinking water systems, are described. The corrosion inhibiting additive is a stannous salt of a non-carbon acid.

Abstract: Effective corrosion inhibitors having minimal organic content, particularly suitable for use in municipal drinking water systems, are described. The preferred corrosion inhibiting additive is an aqueous solution of a stannous halide, preferably stannous chloride.

Abstract: An agent for preventing scale formation and a method for preventing scale formation include a polymer which has at least 50% of N-vinyl formamide units or N-vinyl acetamide units and a phosphorus compound added to water in a cooling water system, a boiler water system, or the like. The scale preventing agent and scale preventing method of the present invention are effective in preventing the adherence of various types of scales which are generated in cooling water systems, boiler water systems, and the like. In particular, the present invention is effective in preventing the adherence of silica and calcium scale.

Abstract: The invention is a method for preparing a stabilized aqueous alkali or alkaline earth metal hypobromite solution. The method comprises the steps of:a. Mixing an aqueous solution of alkali or alkaline earth metal hypochlorite having from about 5 percent to about 70 percent available halogen as chlorine with a water soluble bromide ion source;b. Allowing the bromide ion source and the alkali or alkaline earth metal hypochlorite to react to form a 0.5 to 70 percent by weight aqueous solution of unstabilized alkali or alkaline earth metal hypobromite;c. Adding to the unstabilized solution of alkali or alkaline earth metal hypobromite an aqueous solution of an alkali metal sulfamate in a quantity to provide a molar ratio of alkali metal sulfamate to alkali or alkaline earth metal hypobromite is from about 0.5 to about 7; and,d. Recovering a stabilized aqueous alkali or alkaline earth metal hypobromite solution.

Abstract: A portable system and method for softening and disinfecting dental waterlines is disclosed. The portable system and method combines a routing valve, a water supply, and a portable device capable of delivering a descaling and an anti-microbial agent. The routing valve has an inlet and an outlet. The outlet is attached to a water supply line of sufficient volume to deliver water throughout the system. The inlet is attached to a portable device capable of delivering a descaling agent and an anti-microbial agent.

Abstract: Non-halogen substituted, nitrogen containing, aromatic compounds are disclosed which are effective copper corrosion inhibitors in aqueous systems being treated with a halogen biocide. The materials of the present invention exhibit copper corrosion inhibition comparable to tolyltriazole in the absence of halogen, copper corrosion rates of less than about 2.5 mills per year in aqueous systems where halogen is present; and do not exhibit a detrimental effect on halogen demand in an aqueous system being treated.

Abstract: Corrosion in aqueous alkanolamine, physical solvents, or combination of alkanolamine and physical solvent solutions used to remove acid gases from natural gas, synthetic gas, or light hydrocarbon streams can be reduced by addition of mixtures of oxygen scavengers or mixtures of oxygen scavengers and sodium molybdate. The oxygen scavengers must be promoted to reduce metal surfaces in contact with the solutions to a more passive, harder, and insoluble form at the operating temperature of the treating system. The sodium molybdate provides additional passivation especially in the imperfections on the surface of the metal where corrosion accelerates.

Abstract: The invention effectively prevents occurrence of corrosion in water tubes or the like of boilers. The invention provides a method for operating a boiler, including regulating a concentration of sulfate ions SO.sub.4.sup.2- in boiler water to under 500 ppm, and a method for injecting a sulfite base oxygen scavenger, including setting a concentration of residual dissolved oxygen in boiler feed water to 2-4 ppm. The invention further provides a sulfite base oxygen scavenger composition comprising: 3-30 weight % of at least one selected from a group consisting of Na.sub.2 SO.sub.3, K.sub.2 SO.sub.3, NaHSO.sub.3 and KHSO.sub.3 ; 1-20 weight % of NaOH or KOH; 0.2-2 weight % of potassium sorbate; and 5-500 ppm of CoSO.sub.4.

Abstract: The invention provides for the treatment of raw water having a pH of 2.5 to 9, an alkalinity of at most 50 mg/l expressed as calcium carbonate, a calcium content of at most 100 mg/l expressed as calcium carbonate, and a positive calcium carbonate dissolution potential. The process comprises separating part of the water from the remainder thereof and acidifying the part to increase its calcium carbonate dissolution potential. The acidified water is then fed through a bed of particles comprising calcium carbonate where the water consumes part of the calcium carbonate thereby increasing the calcium content and the alkalinity of the water which issues from the bed. The water issuing from the bed is then mixed with the remainder of the raw water to obtain an at least partially treated product water having a positive calcium carbonate dissolution potential which is at least 2 mg/l calcium carbonate less than that of the raw water.

Abstract: Ca ion is removed by a cation exchange resin and silica and corrosive ions are removed by an anion exchange resin. Even after the anion exchange resin reaches the silica break through point or after the cation exchange resin reaches the Ca ion break through point, the supply of water is continued until the average of silica concentration or Ca ion concentration reaches a predetermined value. By supplying both treated water before the break through point and treated water after the break through point, water containing silica or Ca ion of suitable concentration can be supplied to the water system with only one anion exchange column or cation exchange column.

Abstract: The use of halo-benzotriazoles as corrosion inhibitors in aqueous systems is disclosed. Specific isomers of chloro-methylbenzotriazole were found to be more effective corrosion inhibitors than tolyltriazole in the presence of chlorine.

Abstract: An apparatus (A) for sterilizing medical instruments and other articles includes a tray (12) with an article receiving area (14). An article to be microbially decontaminated is positioned in the receiving area (14) and a microbe blocking lid (10) is closed. A water electrolysis apparatus (30) receives water, splits the water into two separate streams that pass respectively through an anode chamber (34) and a cathode chamber (36), and exposes the streams to an electric field that results in the production of a catholyte solution for cleaning and an anolyte solution for sterilization. The anolyte and catholyte are selectively circulated through the article receiving area (14) by a pump (66) to clean and microbially decontaminate the external surfaces and internal passages of an article located therein. The anolyte or deactivated anolyte provides a sterile rinse solution. A reagent dispensing well (60) receives an ampule (80) or the like.

Abstract: The present invention relates to a method to inhibit bacteria from adhering to a submergible surface. The method contacts the submergible surface with an effective amount of at least one fluorosurfactant to inhibit bacterial adhesion to the submergible surface. The present invention also relates to a method for controlling biofouling of an aqueous system. This method adds an effective amount of at least one fluorosurfactant to inhibit bacteria from adhering to a submerged surface within the aqueous system. This method effectively controls biofouling without substantially killing the bacteria fouling organisms. The fluorosurfactant used in the method of the invention is an anionic or nonionic fluorosurfactant selected from: R.sub.f CH.sub.2 CH.sub.2 SCH.sub.2 CH.sub.2 CO.sub.2 Li, (R.sub.f CH.sub.2 CH.sub.2 O)P(O) (ONH.sub.4).sub.2, (R.sub.f CH.sub.2 CH.sub.2 O).sub.2 P(O) (ONH.sub.4), (R.sub.f CH.sub.2 CH.sub.2 O)P(O) (OH).sub.2, (R.sub.f CH.sub.2 CH.sub.2 O).sub.2 P(O) (OH), R.sub.f CH.sub.2 CH.sub.2 O (CH.

Abstract: A method of use of a composition including either or both isomers of hydrogenated methylbenzotriazole, namely, 5-Methyl-1H-Benzotriazole or 4-Methyl-1H-Benzotriazole which have been at least about 50% hydrogenated, to form corrosion inhibiting films on metal surfaces in an aqueous environment. The hydrogenated methylbenzotriazole compositions provide both improved passivation and improved film persistence when charged to aqueous industrial systems either on a continuous or on an intermittent basis. Continuous dosing is generally kept at a constant >0.5, typically 1-2 ppm in the aqueous system to be treated; intermittent doses are generally 10-20 ppm once every week or two or more.

Abstract: Primary amines, ammonia, or mixtures thereof can be detected using a reagent comprising from about 650 ppm to about 25 percent by weight of phthalic dicarboxyaldehyde; from about 74 to about 99.88 percent by weight of an alkali metal borate; and, from about 550 ppm to about 22 percent by weight of a nucleophile.

Abstract: A corrosion inhibiting composition for use in inhibiting corrosion of metallic surfaces, the composition comprising a first surfactant wherein the first surfactant includes at least one sorbitan fatty acid ester and a second surfactant wherein the second surfactant includes at least one polyoxyethylene derivative of a sorbitan fatty acid ester.

Abstract: A method for reducing corrosion of metal components in a water-cooled nuclear reactor. A compound containing a platinum group metal, e.g. palladium, is injected alone in small amounts into the high temperature water of the reactor in the form of a solution or suspension. This compound decomposes under reactor thermal conditions to release atoms of the metal in an amount sufficient when present on the metal components to reduce the electrochemical corrosion potential of the metal components to a level below the critical potential to protect against intergranular stress corrosion cracking.

Abstract: The invention is a method for preparing a stabilized aqueous alkali or alkaline earth metal hypobromite solution. The method comprises the steps of:a. Mixing an aqueous solution of alkali or alkaline earth metal hypochlorite having from about 5 percent to about 70 percent available halogen as chlorine with a water soluble bromide ion source;b. Allowing the bromide ion source and the alkali or alkaline earth metal hypochlorite to react to form a 0.5 to 70 percent by weight aqueous solution of unstabilized alkali or alkaline earth metal hypobromite;c. Adding to the unstabilized solution of alkali or alkaline earth metal hypobromite an aqueous solution of an alkali metal sulfamate in a quantity to provide a molar ratio of alkali metal sulfamate to alkali or alkaline earth metal hypobromite is from about 0.5 to about 7; and,d. Recovering a stabilized aqueous alkali or alkaline earth metal hypobromite solution.

Abstract: A method for mitigating crack initiation and propagation on the surface of metal components in a water-cooled nuclear reactor. A metal coating having an electrically insulating outer layer is applied on the surfaces of IGSCC-susceptible reactor components. The preferred metal coating is a zirconium alloy with a zirconia outer layer. The presence of an electrically insulating layer on the surface of the metal components shifts the corrosion potential in the negative direction without the addition of hydrogen and in the absence of a noble metal catalyst. Corrosion potentials.ltoreq.-0.5 V.sub.SHE can be achieved even at high oxidant concentrations and in the absence of hydrogen.

Abstract: A method for mitigating general corrosion and crack initiation and growth on the surface of a metal components in a water-cooled nuclear reactor. A compound containing a non-noble metal such as zirconium or titanium is injected into the water of the reactor in the form of a solution or suspension. This compound decomposes under reactor thermal conditions to release ions or atoms of the non-noble metal which incorporate in the surfaces of the components, including the interior surfaces of any cracks formed therein. The preferred compounds are zirconium compounds such as zirconium acetylacetonate, zirconium nitrate and zirconyl nitrate. Zirconium incorporated in the oxided surface of a metal component will reduce the electrochemical corrosion potential at the surface to a level below the critical potential to protect against intergranular stress corrosion cracking without the addition of hydrogen.

Abstract: A method of depositing noble metals on surfaces or matrices to manufacture industrial catalysts that can be used in a variety of applications. Such deposition of noble metals can be achieved by treating the surfaces in high-temperature (150.degree. C. or higher) water containing dissolved noble metal ions or its colloidal suspensions. The method consists of the steps of placing the surface of a metal substrate in contact with a volume filled with high-temperature water; injecting a solution of a noble metal compound into the volume for a predetermined duration; and removing the surface of the metal substrate from contact with the high-temperature water after expiration of said predetermined duration. The noble metal compound has the property that it releases species of the noble metal in high-temperature water. These noble metal species deposit on or incorporate in the oxide film on the surface of the metal substrate.