Including Means Providing Sequential Purification Stages Patents (Class 422/169)
  • Publication number: 20110076216
    Abstract: The present invention discloses a carbon dioxide capture power generation system provided with a boiler to combust a fuel in the oxygen atmosphere, a carbon dioxide capture equipment to remove carbon dioxide in the wake flow of the boiler, a piping branching from the wake flow of the boiler to recycle the combustion exhaust gas to the boiler, and a desulfurization equipment to remove sulfur oxides and a sulfuric acid removal equipment to remove a sulfuric acid gas in the upstream of carbon dioxide capture equipment and in the wake flow of the boiler.
    Type: Application
    Filed: August 19, 2010
    Publication date: March 31, 2011
    Applicant: Hitachi, Ltd.
    Inventors: Hisayuki Orita, Masaaki Mukaide, Nobuyuki Hokari, Tsuyoshi Shibata, Masayuki Taniguchi
  • Publication number: 20110076215
    Abstract: An air pollution control system includes an emission treatment system configured to receive flue gas, to reduce at least one pollutant therefrom, and to output emission treated flue gas. A first air heater in fluid communication with the emission treatment system includes a heat exchanger for heating forced air introduced thereto above a base temperature and thereby cooling emission treated flue gas from the emission treatment system to a stack discharge temperature. A second air heater in fluid communication with the first air heater to receive heated forced air therefrom includes a heat exchanger for heating forced air introduced thereto to a preheat temperature for combustion in a boiler and thereby cooling flue gas introduced from a boiler to the second air heater to an emission treatment temperature. The second air heater is in fluid communication with the emission treatment system to introduce cooled flue gas thereto.
    Type: Application
    Filed: September 25, 2009
    Publication date: March 31, 2011
    Applicant: Babcock Power Environmental Inc.
    Inventors: Richard F. Abrams, Mark Lewis, Jeffrey Penterson
  • Patent number: 7909904
    Abstract: A method for producing a ceramic honeycomb structure comprises providing a honeycomb body having a side surface, a first cut end surface, a second cut end surface opposite the first end surface, and a maximum width (W), and removing material from at least one of the cut end surfaces of the honeycomb body to reduce the length (L), wherein the step of removing material comprises abrasively removing material from at least one of the ends with a rotating abrasive tool, such as by grinding, and wherein L/W is greater than 0.75. The method may achieve end flatness, parallelism, surface roughness and length accuracy, or combinations thereof which heretofore, were unachievable. Face finished ceramic honeycomb structures having low surface roughness (Ra), high degree of parallelism and accurate lengths are also disclosed.
    Type: Grant
    Filed: March 19, 2007
    Date of Patent: March 22, 2011
    Assignee: Corning Incorporated
    Inventor: Bruce Patrick Allen
  • Patent number: 7910075
    Abstract: A method of protecting a NOx reducing catalyst 140 from fouling, where the NOx reducing catalyst 140 is downstream of a circulating fluidized bed (CFB) boiler 120 and upstream of a particulate removal device 150. The method includes introducing a SOx removing reagent 212 in a calcium to sulfur molar ratio greater than that required for SO2 removal from a flue gas 122 generated by a CFB 120, thereby preventing SO3 formation and fouling of the NOx reducing catalyst 140.
    Type: Grant
    Filed: July 22, 2009
    Date of Patent: March 22, 2011
    Assignee: ALSTOM Technologies Ltd.
    Inventors: Lawrence J. Czarnecki, Mikael Larsson
  • Patent number: 7910077
    Abstract: Sulfur oxides are removed from an oxygen-containing acid gas in configurations and methods in which oxygen is removed from the acid gas using reducing gases at relatively high temperature. The so treated acid gas is then fed to a direct reduction reactor in which the sulfur species are converted to elemental sulfur. Contemplated configurations are particularly effective and economically attractive as they are generally not limited by reaction equilibrium as present in a Claus reaction and do not require solvent and solvent-associated equipment.
    Type: Grant
    Filed: October 20, 2005
    Date of Patent: March 22, 2011
    Assignee: Fluor Technologies Corporation
    Inventors: Thomas King Chow, Vincent Wai Wong, John Gebur
  • Publication number: 20110064636
    Abstract: The invention relates to a method of removing carbon dioxide from a process gas, the method comprising: a) allowing an ammoniated solution to enter an absorption arrangement, said absorption arrangement comprising at least a first absorber; b) contacting the ammoniated solution with the process gas in said first absorber, the ammoniated solution capturing at least a part of the carbon dioxide of the process gas; c) allowing the ammoniated solution to exit the absorption arrangement; d) cooling the ammoniated solution, wherein at least a part of the captured carbon dioxide is precipitated as solid salt; e) allowing the cooled ammoniated solution to enter a separator, in which separator at least a part of the precipitated solids are removed from the ammoniated solution, after which the ammoniated solution is allowed to exit the separator; f) heating the ammoniated solution; and g) allowing the heated ammoniated solution to re-enter the absorption arrangement.
    Type: Application
    Filed: September 15, 2009
    Publication date: March 17, 2011
    Applicant: ALSTOM TECHNOLOGY LTD
    Inventors: Arlyn V. Petig, Frederic Z. Kozak
  • Patent number: 7906087
    Abstract: Apparatus comprising an absorber device provided with a plurality of sequentially adjacent sections for flowing a gas stream therethrough. A solvent reactable with components of the gas stream is ingressed into and egressed from each section of the absorber device by a conduit infrastructure. The conduit infrastructure has a plurality of heat exchange and cooling equipment, and communicates with solvent recovery and regeneration equipment. A process wherein a liquid solvent selected for reacting with gaseous components, is counter-flowed against the gas stream. The liquid solvent temperature is controllably manipulated between each section of the absorber device to provide: (a) thermodynamic-driven mass transfer at the front end of the absorber device, and (b) kinetic-driven mass transfer at the back end of the absorber device. Heat generated during recovery of gaseous components from the liquid solvent is recovered for use in regenerating the solvent system.
    Type: Grant
    Filed: March 23, 2007
    Date of Patent: March 15, 2011
    Assignee: University of Regina
    Inventors: Adisorn Aroonwilas, Amornvadee Veawab
  • Patent number: 7905933
    Abstract: An exhaust gas cleaning apparatus and a filter regeneration apparatus that are capable of cleaning a large volume of exhaust gas without any increase in size of a nonmagnetic member around which a working coil for induction heating is wound. The exhaust gas cleaning apparatus includes a particulate collecting section and a filter regenerating section placed next to each other in the flow direction of an exhaust gas, and a movable frame. The movable frame holds an extension of a filter unit extending from a casing of the particulate collecting section beyond the support frame of the filter regenerating section, and can move the filter unit in the axial direction of the casing. When the filter unit moved by the movable frame passes through the filter regenerating section, a corresponding part of a holding frame disposed in the filter unit is continuously induction-heated to burn collected particulates, such that the filter unit can be regenerated.
    Type: Grant
    Filed: March 2, 2007
    Date of Patent: March 15, 2011
    Assignee: National University Corporation, Tokyo University of Marine Science and Technology
    Inventor: Yoshihiro Hatanaka
  • Patent number: 7906090
    Abstract: A mercury reduction system according to the present embodiment is a mercury reduction system that reduces NOx and Hg in flue gas discharged from a boiler, and includes an NH4Cl solution spraying unit that sprays an NH4Cl solution into a flue of the boiler in a liquid state, a mixed gas spraying unit that is provided downstream of the NH4Cl solution spraying unit and sprays mixed gas containing NH3 gas and HCl gas into the flue, a reduction denitration apparatus that includes a denitration catalyst reducing NOx in the flue gas with NH3 and oxidizing Hg in the presence of HCl, and a wet desulfurization apparatus that reduces Hg oxidized in the reduction denitration apparatus with a limestone-gypsum slurry.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: March 15, 2011
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Nobuyuki Ukai, Moritoshi Murakami, Susumu Okino, Tatsuto Nagayasu, Seiji Kagawa
  • Patent number: 7901475
    Abstract: A diesel particulate filter assembly comprises a diesel particulate filter (DPF) and a heater assembly. The DPF filters a particulate from exhaust produced by an engine. The heater assembly has a first metallic layer that is applied to the DPF, a resistive layer that is applied to the first metallic layer, and a second metallic layer that is applied to the resistive layer. The second metallic layer is etched to form a plurality of zones.
    Type: Grant
    Filed: March 20, 2008
    Date of Patent: March 8, 2011
    Inventors: Eugene V. Gonze, Michael J. Paratore, Jr.
  • Patent number: 7901645
    Abstract: A mercury reduction system according to the present embodiment is a mercury reduction system that reduces NOx and Hg in flue gas discharged from a boiler, and includes a chemical supplying unit that mixes an NH4Cl solution, an NH3 solution, and an HCl solution in liquid states, and supplies a mixed solution into a flue provided downstream of the boiler, a reduction denitration apparatus that includes a denitration catalyst reducing NOx in the flue gas with NH3 and oxidizing Hg in the presence of HCl, and a wet desulfurization apparatus that reduces Hg oxidized in the reduction denitration apparatus with limestone-gypsum slurry.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: March 8, 2011
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Nobuyuki Ukai, Moritoshi Murakami, Susumu Okino, Tatsuto Nagayasu, Seiji Kagawa
  • Publication number: 20110052469
    Abstract: A system for treating an air stream exhausted from a firing kiln utilized to heat a ceramic substrates includes an outlet assembly and a thermal oxidizer. The outlet assembly may be in fluid communication with the firing kiln, and may be operational to receive an exhaust gas stream and a waste heat stream from the firing kiln. A temperature of the waste heat stream may be greater than the exhaust gas stream such that a temperature of an air stream comprising the waste heat stream and the exhaust gas stream within the outlet assembly is greater than the exhaust gas stream. The thermal oxidizer may be in fluid communication with the outlet assembly to receive the air stream and remove pollutants from the air stream.
    Type: Application
    Filed: August 25, 2010
    Publication date: March 3, 2011
    Inventors: Renee Rochelle Sewalt, Michael James Vayansky
  • Publication number: 20110052470
    Abstract: An air pollution control system for a coal combustion boiler according to the present invention includes: a NOx removing apparatus (13) that reduces nitrogen oxide contained in flue gas emitted from this coal combustion boiler (11), an air pre-heater (14) that recovers heat in the gas, a precipitator 15 that reduces particulates from the gas, a liquid-gas contact type desulfurizer (16) that removes sulfur oxide by way of a limestone-gypsum method and reduces mercury oxide in the gas, a stack (17) that releases the gas after SOx removal to the exterior, and a solid-liquid separator (22) that extracts limestone-gypsum containing slurry (21) from the desulfurizer (16) to the exterior and performs a solid-liquid separation, where water (23) separated in the solid-liquid separator (22) is removed, and concentrated slurry (24) is sent back to the bottom of the desulfurizer (16) to make the gypsum concentration of slurry (25) equal to or higher than 10 percent in the desulfurizer (16).
    Type: Application
    Filed: January 20, 2009
    Publication date: March 3, 2011
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Nobuyuki Ukai, Shintaro Honjo, Susumu Okino
  • Publication number: 20110052452
    Abstract: A NOx reduction device for diesel vehicles includes an Lean NOx Trap (LNT) serving as a NOx filter, a Diesel Particulate Filter (DPF) located downstream of the LNT, and a Hydrocarbon-Selective Catalyst Reduction (HC-SCR) catalyst provided on the LNT. The HC-SCR catalyst can remove NOx in the regeneration of the DPF even if an additional post injector is not provided to promote an active reaction of the HC-SCR catalyst.
    Type: Application
    Filed: November 20, 2009
    Publication date: March 3, 2011
    Applicant: Hyundai Motor Company
    Inventor: Sung Mu Choi
  • Publication number: 20110044872
    Abstract: A flue gas control system of a coal combustion boiler according to the present invention includes: an HCI atomizer (32) that sprays hydrogen chloride (33) to flue gas from a coal combustion boiler (11) that uses coal as a fuel (F); NOx removing apparatus (13) that removes nitrogen oxides by ammonia denitration by adding ammonia (12) to the flue gas after spraying hydrogen chloride and oxidizes mercury; an air preheater (14) that recovers heat in the gas after removal of nitrogen oxides; a precipitator (15) that removes particulates in the gas; an activated carbon atomizer (22) that sprays activated carbon (22a) into the gas after particulate collection; a bag filter (21) that collects activated carbon having adsorbed mercury; a desulfurizer (16) that removes sulfur oxides in the flue gas after removal of activated carbon; a stack (17) that discharges the gas which has undergone desulfurization to outside; and an ORP meter (19) that measures an oxidation reduction potential for feeding air to a slurry absorben
    Type: Application
    Filed: January 20, 2009
    Publication date: February 24, 2011
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Nobuyuki Ukai, Shintaro Honjo, Susumu Okino
  • Patent number: 7892308
    Abstract: A filling percentage of a central portion is larger than that of a peripheral portion at the inlet end surface of an exhaust gas of a honeycomb segment (2) constituting a ceramic filter due to additional filling (13). Thus, an amount of soot accumulated in vents (5) in the central portion of each honeycomb segment (2) is less relative to that in the peripheral portion. This decreases a quantity of heat generated by burning of soot in the central portion, and reduces temperature rise during recycling, thus limiting the maximum temperature of the ceramic filter (1).
    Type: Grant
    Filed: August 11, 2004
    Date of Patent: February 22, 2011
    Assignee: NGK Insulators, Ltd.
    Inventor: Takashi Mizutani
  • Patent number: 7892309
    Abstract: A method for producing a honeycomb filter from a honeycomb structure having large numbers of flow paths partitioned by cell walls, comprising inserting a tubular member into each of the flow paths, and injecting a plugging material into each of the flow paths from the tubular member to form a plug in each of the flow paths at a position separate from the end surface of the honeycomb structure, the tubular member having an outer diameter that is 40-90% of the opening size of the flow path, the plugging material comprising at least a ceramic material having a maximum particle size that is 85% or less of the inner diameter of the tubular member, and an average particle size of 1 ?m or more.
    Type: Grant
    Filed: December 22, 2005
    Date of Patent: February 22, 2011
    Assignee: Hitachi Metals, Ltd.
    Inventors: Shunji Okazaki, Yasuhiko Otsubo, Shinya Tokumaru, Hirohisa Suwabe, Toshitaka Ishizawa
  • Patent number: 7879126
    Abstract: An improved particulate filtration system has an inlet, for the fluid to be filtered, connected to a housing containing a filter medium such that the fluid passes through the filter medium, and an outlet for the filtered fluid to exit. The filtration system's improvement is the filter medium being comprised of a porous ceramic of fused platelet grains. In a particular embodiment, the porous ceramic is a celsian porous ceramic, where the celsian grains have a hexagonal morphology and display a continuous volume thermal expansion coefficient from 100° C. to 1000° C.
    Type: Grant
    Filed: July 20, 2007
    Date of Patent: February 1, 2011
    Assignee: Dow Global Technologies Inc.
    Inventors: Aleksander J. Pyzik, Robert A. Newman, Nicholas M. Shinkel
  • Publication number: 20110020188
    Abstract: An integrated gasification combined cycle (IGCC) system involving CO2 capture is provided comprising a CO2-selective membrane, a pre-compressor, and a sulfur gas removal system to selectively remove H2S and CO2 from shifted syngas, wherein the pre-compressor increases the permeate stream from the CO2-selective membrane from a first pressure to a second pressure prior to entering the sulfur removal system. Also provided herein is a method of maintaining a substantially constant pressure in a sulfur removal system, comprising introducing a feed gas stream to a CO2-selective membrane for separation into a syngas rich stream and a permeate gas stream, wherein the permeate gas stream is at a first pressure; increasing the permeate gas stream from the first pressure to a second pressure; and introducing the permeate gas stream at the second pressure to a sulfur removal system downstream of the pre-compressor.
    Type: Application
    Filed: July 24, 2009
    Publication date: January 27, 2011
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Mahendhra Muthuramalingam, Ashok Kumar Anand, Anthony Yu-Chung Ku, Chetan Madhav Joshi, Joseph J.
  • Patent number: 7870724
    Abstract: The present invention provides a thermally stable catalyst for treating automobile exhaust by-products is provided. The catalyst of the invention comprises a first section that includes a precious metal present in a first concentration and a second section that includes a precious metal present in a second concentration. The catalyst of the invention is characterized by a unique precious metal concentration profile in which the first concentration of the precious metal is lower than the second concentration of the precious metal. When placed with an automobile exhaust system, the second section is positioned downstream of the first section. The present invention also provides a lean NOx trap utilizing the unique precious metal concentration profile. The NOx trap is found to possess improved NOx conversion performance relative to a NOx trap with the same total amount of precious metal deposited uniformly over the volume of the trap.
    Type: Grant
    Filed: November 9, 2004
    Date of Patent: January 18, 2011
    Assignee: Ford Global Technologies, LLC
    Inventors: Justin Ura, Joseph Theis, Christian Goralski, Jr.
  • Patent number: 7871587
    Abstract: A small scale, but effective, reactive chemical containment system includes apparatus and methods for reaction of process gases exhausted from reaction furnaces with a reactant gas in a non-combustible manner to produce and contain particulate or powder byproducts, thereby removing the process gas from the exhaust gas flow. The apparatus provides process gas inlet, treatment reactive gas diffusion, process gas and treatment reactive gas pre-mixing, primary containment, secondary containment, and outlet zones.
    Type: Grant
    Filed: December 22, 2009
    Date of Patent: January 18, 2011
    Assignee: MKS Instruments, Inc.
    Inventors: Youfan Gu, Paul Dozoretz
  • Patent number: 7867313
    Abstract: The invention concerns a process for the production of a porous ?-SiC-bearing ceramic molded body that includes an aluminum oxide layer at the surface of the pores and passages of the porous ?-SiC-bearing ceramic molded body. The invention further concerns a porous ?-SiC-bearing ceramic molded body which has pores of a mean pore size in the range of between 0.1 urn and 50 ?m and an aluminum oxide layer at the surface of the open pores and passages.
    Type: Grant
    Filed: July 5, 2006
    Date of Patent: January 11, 2011
    Assignee: Helsa-Automotive GmbH & Co. KG
    Inventors: Nahum Travitzky, Daniel Galsterer, Peter Greil, Thomas Wolff, Heino Sieber, Lars Weisensel
  • Patent number: 7862789
    Abstract: A circulating fluidized bed power plant 100 includes; a circulating fluidized bed boiler 110 which generates flue gases, a flash dry absorber scrubber 140 configured to receive the flue gases from the circulating fluidized bed boiler 110, and a lime feed 150 configured to introduce lime into the flash dry absorber scrubber 140.
    Type: Grant
    Filed: August 22, 2008
    Date of Patent: January 4, 2011
    Assignee: Alstom Technology Ltd.
    Inventors: Lawrence H. Gatton, Jr., George D. Mylchreest
  • Patent number: 7862645
    Abstract: Method for argon recovery that comprises (a) providing a feed gas mixture comprising argon and nitrogen; (b) contacting at least a portion of the feed gas mixture with a nitrogen-selective adsorbent in a cyclic pressure swing adsorption process and adsorbing at least a portion of the nitrogen on the adsorbent in a first pressure range above 100 psia to provide a purified argon product and an adsorbent comprising adsorbed nitrogen; and (c) desorbing the adsorbed nitrogen in one or more regeneration steps effected in a second pressure range between atmospheric pressure and a super-atmospheric pressure below any pressure in the first pressure range, inclusive; wherein the cyclic pressure swing adsorption process is effected at an average operating temperature of at least about 0° C.
    Type: Grant
    Filed: February 1, 2008
    Date of Patent: January 4, 2011
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Roger Dean Whitley, Edward Landis Weist, Jr., Annemarie Ott Weist, Steven Ray Auvil
  • Publication number: 20100329956
    Abstract: An exhaust gas treatment system treats exhaust gases collected from at least one PFC dealing device that deals with a PFC gas. The exhaust gas treatment system includes: an exhaust emission line through which the exhaust gases collected from the PFC dealing device; an external exhaust gas disposal device connected to the exhaust emission line so as to purify the exhaust gases for exhaust emission; a gas treatment device for eliminating the PFC gas from the exhaust gases; a gas treatment line branched from the exhaust emission line to supply the exhaust gases to the gas treatment device; and an intermediate line for discharge the treated exhaust gases from the gas treatment device to the external exhaust gas disposal device.
    Type: Application
    Filed: June 2, 2010
    Publication date: December 30, 2010
    Applicant: OKI SEMICONDUCTOR CO., LTD.
    Inventor: Takayoshi Sawayama
  • Publication number: 20100329957
    Abstract: An object is to provide an exhaust-gas treatment apparatus capable of realizing a dissolved-salt spray method easily and at low cost. An exhaust-gas treatment apparatus that removes SO2 and SO3 contained in combustion exhaust gas includes a desulfurization apparatus based on the lime-gypsum method. Desulfurizing effluent, containing dissolved salt, from the desulfurization apparatus is sprayed to an upstream side of the desulfurization apparatus to remove SO3. A wet electrical dust precipitator may be provided downstream of the desulfurization apparatus. Furthermore, effluent from the wet electrical dust precipitator may be made to merge with the desulfurizing effluent from the desulfurization apparatus.
    Type: Application
    Filed: August 31, 2010
    Publication date: December 30, 2010
    Applicant: MITSUBISHI HEAVY INDUSTRIES ENVIRONMENT ENGINEERING CO., LTD.
    Inventors: Hiromitsu Nagayasu, Yasutoshi Ueda, Ryokichi Hamaguchi, Susumu Okino, Morio Kagami
  • Publication number: 20100316546
    Abstract: Disclosed is a method for the reduction of mercury emissions from an industrial plant utilizing a cement or minerals kiln that has a high level of mercury. The invention allows for the repeated treatment of a gas stream to reduce the level of mercury and other pollutants through reduction steps, allowing targeted treatment of specific compounds. The invention utilizes multiple sorbent injections for the step-wise reduction in pollutants. Utilizing the multiple stages of reaction, very high levels of mercury emissions may be controlled to greater reduction percentages than existing methods.
    Type: Application
    Filed: June 12, 2009
    Publication date: December 16, 2010
    Inventor: Peter T. Paone, III
  • Publication number: 20100316537
    Abstract: An exhaust gas-treating device (1) for an exhaust system of an internal combustion engine, especially of a motor vehicle, which is provided with an insert (3), which has a plurality of ducts (5, 5?), through which parallel flow is possible. The insert has, in an inflow-side, first section (6), an oxidation catalyst coating, which forms an oxidation catalytic converter (K1). The insert comprises on an outflow-side a second section (7) with a particle filter (K3) with inlet ducts (12) closed on the outflow side and with outflow ducts (13) closed on the inflow side after the first section (6). Greater integration of a plurality of catalyst components of the exhaust gas-treating device (1) is possible.
    Type: Application
    Filed: June 9, 2010
    Publication date: December 16, 2010
    Inventors: Georg Wirth, Silvia Calvo
  • Publication number: 20100316547
    Abstract: Embodiments of the present disclosure include a catalyst for the conversion of CO and/or hydrocarbons in an exhaust stream including a Sn compound selected from the group consisting of a binary composition comprising Sn and Ti, a ternary composition comprising Sn, Ti and Zr, and mixtures of any thereof. In those embodiments, the binary composition may include Sn(X)Ti(y)O2, wherein x+y=1, 0.85>y>0. In other embodiments of the present disclosure, the Sn compound includes a ternary composition including Sn(a)Ti(b)Zr(c)O2, wherein a is 0.25, b is 0.25 and c is 0.5. Certain embodiments of this disclosure include a method for the conversion of CO in an exhaust stream, including contacting an exhaust stream containing CO with the catalyst described above containing a Sn compound. In other embodiments, the exhaust stream includes hydrocarbons.
    Type: Application
    Filed: May 20, 2010
    Publication date: December 16, 2010
    Inventors: Rachelle Justice, Rajashekharam V. Malyala, Svetlana Iretskaya, Dylan Trandal, Dien To, Jason Pless, Stephen Golden, Jiho Yoo
  • Patent number: 7846406
    Abstract: A scrubber for scrubbing at least one pollutant from flue gas includes a first stage configured to provide a chemical oxidant to a stream of flue gas, and a second stage configured to provide a chemical or chemicals to the stream of flue gas, a scrubbing medium recirculation feature configured to continuously recirculate a slurry used in the second stage, and a by-product processing portion configured to remove a by-product from a stream of slurry withdrawn from the scrubber. The by-product includes reaction products of at least one pollutant.
    Type: Grant
    Filed: August 17, 2009
    Date of Patent: December 7, 2010
    Inventors: Kevin P. Furnary, William Ellison
  • Publication number: 20100303676
    Abstract: Apparatus for treating gas comprises a casing (100) containing a gas scrubber section (118) and an electrostatic precipitator section (120) located above the scrubber section. A partition (136) may be located within the casing (100) to separate the precipitator section (120) from the scrubber section (118). The casing has a gas inlet (102) for supplying gas to the scrubber section, a gas outlet (104) for exhausting gas from the precipitator section, a scrubbing liquid inlet (106) for supplying scrubbing liquid to the precipitator section, and a scrubbing liquid outlet (126) for draining scrubbing liquid from the scrubber section. In one embodiment the partition comprises a set of apertures (138) through which scrubbing liquid drains from the precipitator section into the scrubber section, and a set of gas passages (140) for conveying gas from the scrubber section to the precipitator section.
    Type: Application
    Filed: May 15, 2008
    Publication date: December 2, 2010
    Inventors: Andrew James Seeley, Andrew James Wakefield
  • Patent number: 7842264
    Abstract: A multiple stage apparatus and process using aerodynamic reactors and aero-coalescers in sequence for the selective capture and removal of purified carbon dioxide gas, the sequential capture and removal of mercury, metal and particulate aerosols by a recycling chemical generation-regeneration system using alkali metal chloride solution following multiple oxidations of mercury vapor, and nitric oxide in sequence, selective capture and removal of sulfur dioxide and nitrogen dioxide by two stage absorption by a recycling chemical generation-regeneration system using alkali metal hydroxide-carbonate-bicarbonate solution together with sequential oxidation to alkali metal sulfate and alkali metal nitrate compounds through evaporation and crystallization. Carbon dioxide capture and recovery is achieved in sequence by selective thermal decarbonation from an alkaline liquid followed by recovery as a purified gas stream.
    Type: Grant
    Filed: April 2, 2008
    Date of Patent: November 30, 2010
    Assignee: Cefco, LLC
    Inventors: Hal B. H. Cooper, Robert E. Tang, Donald E. Degling, Thomas K. Ewan, Sam M. Ewan
  • Patent number: 7842265
    Abstract: Disclosed is a method for the reduction of mercury emissions from an industrial plant utilizing a cement or minerals kiln that has a high level of mercury. The invention allows for the repeated treatment of a gas stream to reduce the level of mercury and other pollutants through reduction steps, allowing targeted treatment of specific compounds. The invention utilizes multiple sorbent injections for the step-wise reduction in pollutants. Utilizing the multiple stages of reaction, very high levels of mercury emissions may be controlled to greater reduction percentages than existing methods.
    Type: Grant
    Filed: June 12, 2009
    Date of Patent: November 30, 2010
    Assignee: FLSmidth A/S
    Inventor: Peter T. Paone, III
  • Patent number: 7837962
    Abstract: A method of reducing particulate matter and mercury emissions in a combustion flue gas includes, in an exemplary embodiment, combusting a fuel resulting in generation a flue gas flow, cooling the flue gas flow within a duct, positioning a flow conditioning apparatus within the duct, enhancing a reaction rate of the mercury and carbon-containing fly ash particles by directing the flue gas flow through the flow conditioning apparatus to mix the carbon-containing fly ash particles and mercury within the flue gas flow and to facilitate at least one of oxidation of the mercury and binding the mercury to the carbon-containing fly ash particles, collecting a portion of the carbon-containing fly ash particles in the flow conditioning apparatus, and directing the flue gas flow to a particulate collection device to remove the remaining portion of the fly ash particles from flue gas flow.
    Type: Grant
    Filed: March 24, 2008
    Date of Patent: November 23, 2010
    Assignee: General Electric Company
    Inventors: Boris Nikolaevich Eiteneer, Robert Warren Taylor, Vitali Lissianski, James Easel Roberts
  • Patent number: 7833501
    Abstract: A method and apparatus for treating an exhaust gas comprising heavy metals, wherein the apparatus comprises a heat recovery unit, recovering exhaust gas heat at an exit of the air preheater; a precipitator, collecting soot/dust contained in an exhaust gas at an exit of the heat recovery unit; a wet flue gas desulfurizer, removing sulfur oxides contained in the exhaust gas at the exit of the precipitator; and a reheater, heating the exhaust gas at the exit of the wet flue gas desulfurizer. Each of the heat recovery unit and the reheater has a heat exchanger tube, and a circulation line is disposed to connect the heat exchanger tubes. A sulfur trioxide (SO3) removing agent is supplied to the upstream side of the heat recovery unit, and the temperature of the exhaust gas at the exit of the heat recovery unit is adjusted to not more than a dew point of sulfur trioxide.
    Type: Grant
    Filed: December 24, 2007
    Date of Patent: November 16, 2010
    Assignee: Babcock-Hitachi Kabushiki Kaisha
    Inventors: Kazuki Kobayashi, Hirofumi Kikkawa, Hiroshi Ishizaka, Goki Sasaki, Hiroyuki Nosaka
  • Publication number: 20100284878
    Abstract: An air pollution control system for a coal combustion boiler according to the present invention includes: a NOx removing apparatus (13) that removes nitrogen oxide contained in flue gas emitted from this coal combustion boiler (11) by adding ammonia (12) thereto, an air pre-heater (14) that recovers heat in the gas after the nitrogen oxide is removed, a precipitator (15) that reduces particulates from the gas after the heat is recovered, a gas-liquid contact type SOx removing apparatus (16) that removes sulfur oxide by way of a limestone-gypsum method and reduces mercury oxide in the gas after the particulates are reduced, and a stack (17) that releases purified gas after the sulfur and the mercury are reduced, where an oxidant is added to limestone-gypsum containing slurry (21) in or extracted from the SOx removing apparatus (16).
    Type: Application
    Filed: January 20, 2009
    Publication date: November 11, 2010
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Nobuyuki Ukai, Shintaro Honjo, Susumu Okino
  • Publication number: 20100284866
    Abstract: A system for reducing a carbon compound of a heat engine includes: an outlet pipe transferring and outputting an exhaust gas from the heat engine; a removal reacting tank connected to the outlet pipe, the removal reacting tank generating a strong alkaline solution by a reaction of a resource material and a water and removing the carbon compound from the exhaust gas by a contact of the carbon compound and the strong alkaline solution; a sludge storing tank storing a sludge generated by a removal reaction in the removal reacting tank; and a decomposing tank generating the resource material for the removal reacting tank by decomposing the sludge from the sludge storing tank with a heat. Accordingly, since the carbon compound such as carbon dioxide is effectively removed from the exhaust gas emitted from a heat engine equipped in an industrial plant and a vehicle, atmospheric environmental pollution is prevented and regulation on carbon dioxide emission is satisfied.
    Type: Application
    Filed: December 29, 2008
    Publication date: November 11, 2010
    Inventors: Yong-Sik Jang, Byung Chan Lee
  • Patent number: 7819959
    Abstract: A gas desulfurization scrubbing system for removing sulfur oxides from gases, such as those of fossil fuel burning operations or other manufacturing process emitting sulfur oxides, and for collecting reaction products of the desulfurization chemical reactions. A quenching section is disposed in a gas duct upstream of a gas desulfurization scrubbing tower and a scrubbing slurry is provided at that section for quenching and chemically reacting with the gas. A quench reaction product is collected, at a location between the quenching section and the scrubbing tower, for use in making commercial by-products, such as gypsum.
    Type: Grant
    Filed: May 3, 2006
    Date of Patent: October 26, 2010
    Assignees: S.A. SNC-Lavalin Europe N.V., Carmeuse Lime, Inc
    Inventors: Benoit Englebert, Gerard Blaure, Kevin J. Smith
  • Publication number: 20100247395
    Abstract: This gas purifying process removes trace constituents from a mixed gas that includes a rare gas and nitrogen as main components, and at least one from among hydrogen, nitrogen and hydrogen reaction products, and water vapor as the trace constituent. This process sequentially carries out an adsorbing step for removing water vapor and nitrogen and hydrogen reaction products; a hydrogen oxidation step for converting the hydrogen into water vapor by means of a hydrogen oxidation catalytic reaction in the presence of oxygen; and a drying step for removing water vapor generated in the hydrogen oxidation step. When nitrogen oxides are included as a trace constituent, then a denitration step is carried out prior to the adsorbing step, to convert nitrogen oxides into nitrogen and water vapor by means of a catalytic denitration reaction in the presence of a reducing substance.
    Type: Application
    Filed: May 19, 2010
    Publication date: September 30, 2010
    Applicants: TAIYO NIPPON SANSO CORPORATION
    Inventors: Tadahiro Ohmi, Ryuichi Yazaki, Masato Kawai, Tetsuya Kimijima, Kunio Matsuda
  • Publication number: 20100247396
    Abstract: A Selective Catalytic Reduction (SCR) filter is provided for use in emission control systems, for example, on the exhaust gas from an internal combustion engine. The SCR filter has a substrate constructed using bonded fiber structures, which cooperate to form a highly uniform open cell network, as well as to provide a uniform arrangement of pores. The substrate typically is provided as a wall-flow honeycomb structure, and in one example, is manufactured using an extrusion process. In this way, the substrate has many channel walls, each having an inlet surface and an outlet surface. The inlet surface has a uniform arrangement of pores that form a soot capture zone, where soot and other particulate matter is captured from an exhaust gas. A NOx conversion catalyst is disposed inside the channel wall, where NOx and ammonia in the exhaust gas are reacted to less harmful substances.
    Type: Application
    Filed: April 5, 2010
    Publication date: September 30, 2010
    Applicant: GEO2 TECHNOLOGIES, INC.
    Inventor: Bilal Zuberi
  • Publication number: 20100247394
    Abstract: A system and method is proposed for removing mercury from a process gas stream containing mercury. The proposed invention provides for contacting an aqueous desulphurization liquor with a flue gas stream to capture mercury that may be contained in the flue gas stream. A promoter is mixed with the liquor to prevent oxidized mercury in the liquor from reducing into elemental mercury.
    Type: Application
    Filed: June 8, 2010
    Publication date: September 30, 2010
    Inventor: Donald C. Borio
  • Patent number: 7799297
    Abstract: This combustion exhaust gas processing device comprises a dust collector collecting dust in combustion exhaust gas, a wet dust collector collecting water soluble components and dust in the combustion exhaust gas passed through the dust collector, and a catalyst tower decomposing and removing NOx and/or dioxins in the combustion exhaust gas passed through the wet dust collector. The device also comprises a reheater heating the combustion exhaust gas discharged from the wet dust collector at the front stage of the catalyst tower, an oxidizer adding device adding an oxidizer to the combustion exhaust gas passed through the dust collector, a solid/liquid separator separating slurry discharged from the wet dust collector into solid and liquid phases, a mercury adsorbing tower adsorbing mercury in liquid separated in the solid/liquid separator, and a heat recovering device heating the combustion exhaust gas discharged from the catalyst tower at the rear stage thereof.
    Type: Grant
    Filed: June 28, 2004
    Date of Patent: September 21, 2010
    Inventor: Shinichiro Saito
  • Publication number: 20100233055
    Abstract: An air quality control system (AQCS) (4) useful for processing a gas stream (DG), such as a flue gas stream emitted from a fossil fuel fired boiler (2), combustion process or the like, for at least partial removal of acidic and like contaminants. The air quality control system (4) includes a plurality of integrated components (12) equipped with both a dry scrubber system (8) and a fabric filter (10). The air quality control system (4) such as described possesses increased “turn down” capabilities thus increasing the efficiency thereof.
    Type: Application
    Filed: February 10, 2010
    Publication date: September 16, 2010
    Applicant: ALSTOM TECHNOLOGY LTD
    Inventors: Lawrence H. Gatton, JR., Alan W. Ferguson, Per H. F. Landmer
  • Patent number: 7794678
    Abstract: An effluent gas scrubber and a method of scrubbing effluent gases are provided. An inlet port receives an effluent gas. The gas passes through successive chambers in which it is sprayed with a scrubbing fluid. An oxidizer within the scrubbing fluid is effective to oxidize non-water soluble gases within the effluent gas. An oxidation-reduction potential probe measures the oxidation-reduction potential of the scrubbing fluid and adds the oxidizer to the scrubbing fluid as needed. A pH probe measures the pH of the scrubbing fluid and adds a base to the scrubbing fluid as needed to maintain the pH at or above a threshold such as pH 7, or pH 12.
    Type: Grant
    Filed: September 25, 2009
    Date of Patent: September 14, 2010
    Assignee: Airgard, Inc.
    Inventors: Mark Johnsgard, Kris Johnsgard
  • Patent number: 7790127
    Abstract: A method of reducing NOx in a lean burn engine exhaust stream from a hydrocarbon burning engine may be first passing the exhaust stream over a thrifted diesel oxidation catalyst that substantially completes the oxidation of carbon monoxide to carbon dioxide and the oxidation of hydrocarbons (HC) to carbon dioxide and water. Next, separate additions of ozone and ammonia or urea may be introduced to the exhaust gas stream upstream of the catalytic reduction reactor at temperatures below 250 degrees Celsius. The additions of ozone and ammonia or urea modify the exhaust gas composition to improve the performance of NOx reduction catalysts in the catalytic reduction reactor. At temperatures above 250 degrees, the ozone addition may be reduced or eliminated, while the ammonia addition can be controlled as a function of the amount of NOx in the exhaust stream and the temperature of the catalytic reduction reactor.
    Type: Grant
    Filed: March 2, 2009
    Date of Patent: September 7, 2010
    Assignee: GM Global Technology Operations, Inc.
    Inventors: Jong H. Lee, Byong Kwon Cho
  • Publication number: 20100221162
    Abstract: A method and system for purifying flue gases from power plants fired with fossil fuels has an absorber with at least one contact installation level arranged in an upper region, impinged with a suspension, and flowed through by untreated gas. The lower region has an absorption suspension sump, above which the inflow for the untreated gas is disposed. A separate reaction container includes two chambers separated by a partition wall with an overflow. The first chamber is connected with the sump, receives oxidation air, and has in a lower region an opening for discharging suspension. The second chamber is connected with a lime/limestone suspension container. A gas exhaust hood above the reaction container draws exhaust vapors into an exhaust vapor hood. A line for absorption suspension extends between at least one spraying level of the absorber and the reaction container, and a process water feed lies above the spraying level.
    Type: Application
    Filed: April 7, 2010
    Publication date: September 2, 2010
    Inventors: Helmut Welp, Thomas Schmidt
  • Patent number: 7785540
    Abstract: For an exhaust emission control device of an internal combustion engine with a support which has a catalytically active coating for absorbing oxygen (O2) in the reduction of the exhaust gas and for releasing oxygen in the oxidation of the exhaust gas, it is proposed that the catalytically active coating comprises different materials (A, B, C) which can store oxygen and which each form a component storage unit (MA, MB, MC) for the oxygen (O2), the first material (A) at lambda ?<1 changing its oxidation stage and constituting a first component storage unit (MA) for oxygen (O2), the second material (B) at lambda ?=1 changing its oxidation stage and constituting a second component storage unit (MB) for oxygen (O2), and the third material (C) at lambda ?>1 changing its oxidation stage and constituting a third component storage unit (MC) for oxygen (O2).
    Type: Grant
    Filed: July 31, 2007
    Date of Patent: August 31, 2010
    Assignee: Audi AG
    Inventor: Bodo Odendall
  • Patent number: 7780942
    Abstract: A catalytic method for treating an H2S/SO2 mixture for producing liquid sulphur including the following steps: a) at least one step of heating the mixture containing H2S/SO2 to a temperature Tc; b) at least one step of catalytically reacting the heated mixture obtained in a) in the presence of at least one catalyst and at least one step of recovering the exiting mixture containing gaseous sulphur; and c) at least one step of converting the gaseous sulphur contained in the exiting mixture obtained at step b) into liquid sulphur, wherein between step b) and step c), the temperature Ts of said exiting mixture and the dew point Tr of the gaseous sulphur contained in said exiting mixture are measured and in that the heating temperature Tc of step a) is adjusted so that the temperature Ts is 5° C. to 30° C. above the dew point Tr.
    Type: Grant
    Filed: February 19, 2007
    Date of Patent: August 24, 2010
    Assignee: Total Raffinage Marketing
    Inventor: Pierre Kaplan
  • Patent number: 7776293
    Abstract: An apparatus for low-temperature NOx-reduction is disclosed, which is useful in boiler installations used at electric-generating plants. The apparatus employs one or a plurality of moving-bed reactors wherein a moving bed of common base-metal catalyst is used for selective catalytic reduction of NOx present in flue gas. The moving bed permits continuous introduction of fresh or regenerated catalyst, thus obviating the conventional problems of sulfur-poisoning and consequent reduction in catalytic activity with such catalysts. Due to the lower activation energies of such catalysts, an SCR utilizing the moving-bed reactors disclosed herein can be located downstream of the air heater, further improving electric-generating efficiency. Methods for low-temperature NOx reduction are also disclosed.
    Type: Grant
    Filed: July 18, 2008
    Date of Patent: August 17, 2010
    Assignee: Babcock & Wilcox Power Generation Group, Inc.
    Inventors: William Downs, Seyed B. Ghorishi, Ralph T. Bailey, Kevin J. Rogers
  • Publication number: 20100202949
    Abstract: The present invention provides a biomass dryer/burner having an air cleaning apparatus adapted to accept emissions from the biomass dryer/burner and to convert said emissions to clean air to meet government emission standards. The biomass dryer/burner unit includes a dryer adapted to dry biomass, such as demolition waste or cut trees. The biomass dryer/burner unit optionally including a burner adapted to burn biomass. The biomass dryer/burner further producing emissions requiring cleaning before exhausting to the atmosphere. The air cleaning apparatus including a spray scrubber fluidly connected to the biomass dryer/burner adapted to moisten emissions, a recirculation tank in fluid communication with a collection tank, and the recirculation tank further having a sensor adapted to measure contaminant levels contained within the recirculation air filtration system. The sensor contained within the recirculation tank measures levels of carbon monoxide.
    Type: Application
    Filed: February 8, 2010
    Publication date: August 12, 2010
    Inventor: Peter Valente