Abstract: Continuous flow synthetic methods are used to make single phase magnetic metal alloy nanoparticles that do not contain rare earth metals. Soft and hard magnets made from the magnetic nanoparticles are used for a variety of purposes, e.g. in electric motors, communication devices, etc.

Abstract: One exemplary embodiment can be a process for removing gases from a sweetened hydrocarbon stream. The process can include passing the sweetened hydrocarbon stream to a gas removal zone, contacting the sweetened hydrocarbon stream with an aqueous stream, passing the aqueous stream to the degassing drum, and removing gases including at least one of oxygen and nitrogen from the aqueous stream. Often, the gas removal zone includes a degassing drum.

Abstract: A process and apparatus is disclosed for pretreating a hydrocarbon stream in a hydrotreating reactor and separating the diesel materials from the pretreated effluent before the heavier liquid materials are fed to a hydrocracking unit. Thus diesel materials are preserved but recovered along with the hydrocracked effluent. A recovered diesel stream can be sent to a hydrotreating unit to improve its cetane rating.

Abstract: An olefin hydration process and reactor are provided, where an integrated membrane selectively removes alcohol product from the reactor, thereby allowing for increased yields.

Abstract: Petroleum coke or coal coke is gasified to produce a gas stream containing carbon monoxide, hydrogen, hydrogen sulfide, and optionally ammonia, carbon dioxide, water, and nitrogen. Carbon monoxide, hydrogen, and hydrogen sulfide, and optionally ammonia, carbon dioxide, water, and nitrogen are separated from the gas stream. The separated carbon monoxide and hydrogen are reacted to produce methanol, and the methanol is reacted with the separated hydrogen sulfide to produce dimethyl sulfide.

Abstract: The present disclosure is directed to systems and methods for actively controlling the steam-to-carbon ratio in hydrogen-producing fuel processing systems that include a feedstock delivery system. The feedstock delivery system supplies a combined feedstock stream including steam and carbon-containing feedstock to a hydrogen-producing region, which produces a mixed gas stream including hydrogen gas as a majority component therefrom. The systems and methods may include measuring a thermodynamic property of a steam stream, a carbon-containing feedstock stream, and/or the combined feedstock stream and controlling the flow rate and/or pressure of a water stream, the steam stream, and/or the carbon-containing feedstock stream based on a desired steam-to-carbon ratio in the combined feedstock stream and/or a desired flow rate of the mixed gas stream and may include feedforward and/or feedback control strategies.

Abstract: Methods for converting an HF alkylation unit to an ionic liquid alkylation system configured for performing ionic liquid catalyzed alkylation processes may comprise connecting at least one component configured for ionic liquid catalyzed alkylation to at least one component of the HF alkylation unit, wherein the at least one component of the HF alkylation unit is retained, modified or adapted for use in the ionic liquid alkylation system. An ionic liquid alkylation system derived from an existing or prior HF alkylation unit is also disclosed.

Abstract: A loop seal for a fluidized bed reactor comprising a vertical downcomer segment connected to a dipleg for receiving solids particles from the dipleg, a horizontal segment downstream of the downcomer, a riser segment downstream of the horizontal segment, and a downwardly inclined segment downstream of the riser, whereby the solids are entrained to the fluidized bed reactor. An eductor is added to the angled leg to induce the underflow gas from the cyclone; one of the preferred motive fluids to the eductor is the fines from fuel preparation and the carrying gas for the fines. Also provided are a fluidized bed reactor comprising the loop seal, and a method for producing syngas from coal and steam using the same.

Abstract: The invention is directed to processes for treating biosolids that result in high-value, nitrogen-containing, slow-release, organically-augmented inorganic fertilizer that are competitive with less valuable or more costly conventional commercially manufactured fertilizers. The process involves conditioning traditional waste-water biosolids and processing the conditioned biosolids continuously in a high throughput manufacturing facility. The exothermic design and closed loop control of the primary reaction vessel decreases significantly the amount of power necessary to run a manufacturing facility. The process utilizes green technologies to facilitate decreased waste and enhanced air quality standards over traditional processing plants. The fertilizer produced from recovered biosolid waste is safe and meets or exceeds the United States Environment Protection Agency (USEPA) Class A and Exceptional Quality standards and is not subject to restrictions or regulations.

Abstract: Methods for converting an H2SO4 alkylation unit to an ionic liquid alkylation system configured for performing ionic liquid catalyzed alkylation processes may comprise connecting at least one component configured for ionic liquid catalyzed alkylation to at least one component of the H2SO4 alkylation unit, wherein the at least one component of the H2SO4 alkylation unit is retained, modified or adapted for use in the ionic liquid alkylation system. Ionic liquid catalyzed alkylation systems derived from existing conventional alkylation units, and ionic liquid catalyzed alkylation processes are also disclosed.

Abstract: A method and system of fixing carbon dioxide is provided. After metal ion components are extracted from, e.g., natural mineral or steel slag through acid treatment, carbon dioxide is injected to fix carbon dioxide by carbonating the same. Since the procedure of pH adjustment is unnecessary, the reaction is carried out effectively and a continuous process is enabled. Accordingly, the disclosed method of fixing carbon dioxide enables effective removal of carbon dioxide produced from the steelmaking industry, thereby significantly reducing greenhouse gas emission and allowing recycling of the discarded steel slag.

Abstract: Hydrocarbon oil obtained by Fischer-Tropsch synthesis reaction using a slurry bed reactor holding a slurry of a liquid hydrocarbon in which a catalyst is suspended; the hydrocarbon oil is fractionated into a distilled oil and a column bottom oil containing the catalyst fine powder by a rectifying column; at least part of the column bottom oil is transferred to a storage tank, and the catalyst fine powder is sedimented to the bottom of the storage tank to capture the catalyst fine powder; a residue of the column bottom oil is transferred from the rectifying column to a hydrocracker, and/or the supernatant of the column bottom oil from which the catalyst fine powder is captured by the storage tank is transferred from the storage tank to the hydrocracker; and using the hydrocracker, the residue of the column bottom oil and/or the supernatant of the column bottom oil is hydrocracked.

Abstract: A vertically oriented sulfur condenser may employ a plurality of condenser tubes arranged longitudinally within an exterior casing, a liquid sulfur reservoir at a longitudinal end of the sulfur condenser, and a condenser tube wall of at least one of the plurality of condenser tubes that protrudes into and below a liquid sulfur reservoir. A catalyst may be located within the liquid sulfur reservoir. A liquid sulfur outlet may be located at the liquid sulfur surface. A Claus process gas inlet may be proximate a first end of the plurality of condenser tubes. A first tube sheet may connect to and seal an end of the plurality of condenser tubes proximate a first end of the plurality of condenser tubes. A second tube sheet may connect to and seals with the plurality of condenser tubes and the exterior casing proximate a second end of the plurality of condenser tubes.

Abstract: A process and apparatus are disclosed for hydrotreating a hydrocarbon feed in a hydrotreating unit and hydrocracking a liquid hydrotreating effluent stream in a hydrocracking unit. A hot separator separates the diesel in a liquid hot hydrotreating effluent stream that serves as feed to the hydrocracking unit. Low sulfur diesel product can be saturated to further upgrade its cetane rating.

Abstract: A hydrogen generator includes: a reformer configured to generate a hydrogen-containing gas by using a raw material; a hydro-desulfurizer configured to remove a sulfur compound in the raw material; a recycle passage through which the hydrogen-containing gas is supplied to the raw material before the raw material flows into the hydro-desulfurizer; a booster configured to supply the raw material to the reformer; a raw material supply passage through which the raw material to be supplied to the reformer flows; and an ejector which is disposed on the raw material supply passage provided downstream of the booster and upstream of the hydro-desulfurizer and into which the hydrogen-containing gas flows from the recycle passage.

Abstract: Provided are a method for producing paraffins and an apparatus for producing paraffins, in which each high-purity paraffin can be produced with high efficiency while complicated operations such as distillation are not carried out. An apparatus for producing paraffins includes a separation and recovery unit and a hydrogenation unit. The separation and recovery unit has a separator containing silver ions, and separates impurities from raw material olefins containing olefins as main components and recovers the olefins, by bringing the raw material olefins into contact with the separator. The hydrogenation unit brings the olefins recovered by the separation and recovery unit into contact with hydrogen in a presence of a catalyst and subjects the recovered olefins to a hydrogenation reaction, thereby obtaining high-purity paraffins.

Abstract: An approach is provided for generating red mercury (II) sulfide from elemental mercury. Elemental mercury is combined with sulfur and heated until vaporized. At least a portion of the elemental mercury reacts with the vaporized sulfur to form the mercury (II) sulfide. Un-reacted elemental mercury is drawn off and condensed by a condenser.

Abstract: A multi-stage hydrotreating process obtains ultra-low sulfur diesel boiling range hydrocarbon having less than 10 ppm sulfur with elimination of external hot high pressure separator and avoids the formation of recombinant mercaptans by removing excess hydrogen sulfide formed during hydroprocessing reaction. The process includes mixing a diesel boiling range hydrocarbon feedstock with hydrogen and sending to the first predominantly liquid phase hydroprocessing reaction stage. Effluent from the first hydroprocessing reaction stage is sent to first separator zone of open and empty space in the upper part of the second hydroprocessing reaction stage to flash off the dissolved reaction products hydrogen sulfide and ammonia. Liquid part of the effluent of first hydroprocessing reaction stage is passed to the second predominantly liquid phase hydroprocessing reaction stage.

Abstract: Provided is a multi-stack cure system. The system includes a chamber having an inlet port and an outlet port. A magazine is mounted in the chamber. A plurality of substrates having encapsulants are loaded in the magazine. A heater is mounted at the chamber and serves to heat the plurality of substrates having the encapsulants. A loading unit is positioned adjacent the inlet port. The loading unit has a transfer device and a push bar. A substrate recognition device is mounted in the loading unit. A control device is connected to the substrate recognition device. The inlet port has a size larger than each of the plurality of substrates having the encapsulants and smaller than the magazine.

Abstract: A nickel recovery loss reduction method that makes it possible to reduce nickel recovery loss by lowering the concentration of fine floating solid components in overflow liquid in precipitating and separating treatments, and consequently to further reduce a nickel recovery loss, a hydrometallurgical method for nickel oxidized ore to which the nickel recovery loss reduction method is applied, and a sulfurizing treatment system. The present invention is a nickel recovery loss reduction method in a sulfurizing step for blowing hydrogen sulfide gas into a nickel containing sulfuric acid aqueous solution to generate nickel-containing sulfides and a barren liquid, and the nickel-containing sulfides with the average particle size adjusted to a predetermined size or larger are added as seed crystals to the sulfuric acid aqueous solution. It is more preferable to adjust the average particle size of the nickel sulfides to be added as seed crystals to 55 ?m or more.

Abstract: One exemplary embodiment can be a process for producing a chemical feedstock. The process can include passing a feed to a hydrotreatment zone, passing an effluent from the hydrotreatment zone to a fractionation zone, passing a stream including one or more C5-C25 hydrocarbons from the fractionation zone to a fluid catalytic cracking zone to obtain an another stream including one or more C6-C10 hydrocarbons, and passing the another stream to an adsorption zone for removing at least one heteroatom compound having a sulfur or a nitrogen atom.

Abstract: Silane and hydrohalosilanes of the general formula HySiX4-y (y=1, 2, or 3) are produced by reactive distillation in a system that includes a fixed-bed catalytic redistribution reactor that can be back-flushed during operation.

Abstract: One exemplary embodiment can be a process for removing carbonyl sulfide in a gas phase hydrocarbon stream. The process may include combining the gas phase hydrocarbon stream with another stream including an alkali and an alkanolamine, and passing the combined stream to a prewash zone including a vessel. The gas phase hydrocarbon may include carbonyl sulfide, and the alkali can include at least one of potassium hydroxide, sodium hydroxide, and ammonia. Usually, the vessel contains a contacting zone and a coalescing zone for removing the carbonyl sulfide.

Abstract: The present invention provides an improved method for solvent liquefaction of biomass to produce liquid products such as transportation fuel. The method uses a novel solvent combination that promotes liquefaction relatively quickly, and it reduces the need to transport large amounts of hydrogen or hydrogen-carrying solvents. It operates at lower pressure than previous methods, does not require a catalyst or hydrogen gas or CO input, and provides very high conversion of biomass into a bio-oil that can be further processed in a petroleum refinery. It also beneficially provides a way to recycle a portion of the crude liquefaction product for use as part of the solvent combination for the biomass liquefaction reaction.

Abstract: A process is described for the preparation of 5-hydroxymethylfurfural (HMF), which comprises the following steps: provision or preparation of a starting mixture, comprising one, two or more starting compounds selected from the group consisting of hexoses, oligosaccharides comprising hexose units, and polysaccharides comprising hexose units, one, two or more organic salts with a melting point <180° C. and a boiling point >200° C. at 1013.25 hPa, optionally additionally one or more catalysts for the conversion of the one starting compound or at least one of the two or more starting compounds to 5-hydroxymethylfurfural (HMF), optionally water, optionally further substances, adjustment of reaction conditions such that an amount of the starting compound or starting compounds converts to HMF.

Abstract: The present disclosure is directed to systems and methods for reducing and/or harvesting drag energy from transport vehicles. A system in accordance with a particular embodiment includes a mobile transport platform, a donor substance source carried by the platform, and a thermochemical reactor carried by the platform and coupled to the donor substance. The reactor is configured to carry out a non-combustion dissociation process that dissociates the donor substance into a first constituent and a second constituent. An energy extraction system carried by the transport platform and positioned to extract energy from an airstream passing the transport platform is coupled to the reactor to provide energy for the dissociation process.

Abstract: Apparatuses, systems and methods for producing Pips stream for manufacturing catalytic C5 hydrocarbon resins containing all the key reactive monomers that are already present in the C5 fraction of the pyrolysis gasoline, which is otherwise lost with the crude isoprene stream, are disclosed herein. Embodiments of the invention are directed to producing a hydrocarbon resin grade DCPD stream consisting of dimers and codimers of isoprene which are of value in manufacturing thermal hydrocarbon resins, either polymer grade isoprene and gasoline quality raffinate (free or sulfur and acetylenes) or a relatively small crude isoprene stream with maximum utilization of isoprene by moving some of the isoprene to a DCPD stream used to manufacture thermal hydrocarbon resins.

Abstract: An objective of the present invention is to provide an energy conversion and storage equipment which is capable of efficiently generating hydrogen using varying electric power generated from renewable energy and is capable of storing the hydrogen. The invention is an apparatus for converting and storing renewable energy in which hydrogen is produced with a water electrolysis device using the varying electric power generated in renewable-energy equipment and the hydrogen is stored, the apparatus being characterized in that the water electrolysis device includes an oxygen generation electrode which comprises an Ir—Mn alloy oxide. Due to the application of the electrode, with which water can be electrolyzed using the varying electric power generated from renewable energy, the system suffers little electrode deterioration even when the varying electric power is used, and it is possible to highly efficiently produce and store hydrogen for a long period.

Abstract: Aspects of this disclosure enhance elimination problems that freezing sulfur creates with gas-liquid parallel plate separators by integrally heating the parallel plate gas-liquid separator assembly. Through integral heating the duration of time that the separator apparatus remains above the freezing temperature of elemental sulfur is prolonged, thereby, allowing the opportunity for residual liquid sulfur to drain from the parallel plate assembly during upsets in unit operations and after a sulfur recovery unit shutdown event, thereby reducing or eliminating the operation and maintenance problems that may occur with existing separator designs.

Abstract: A production apparatus of composite silver nanoparticle including: a device for arranging a silver salt microparticle and at least an alcohol solvent selected from alcohols having a carbon number of 1 to 12; a raw material mixer for preparing an alcohol solution by mixing the silver salt microparticle into the alcohol solvent added more excessively than the mol number of the silver salt microparticle to make an excess alcohol solution; a reactor for generating a composite silver nanoparticle by heating the excess alcohol solution at a generation temperature PT generating an aldehyde for a generation time with a heater, in which a silver core is formed by reducing the silver salt microparticle by the alcohol solvent and/or the aldehyde and the composite silver nanoparticle having an organic coating layer originated from the alcohol solvent around the silver core is formed, and a chiller for cooling the alcohol solution.

Abstract: A system is described that includes a pyrolyzer and a primary condenser. The primary condenser is coupled to the pyrolyzer and includes an input to receive pyrolytic vapors from the pyrolyzer and a solvent. The condenser is further configured to condense the pyrolytic vapors by contacting the pyrolytic vapors with the solvent to form a condensed liquid that exits the primary condenser via an output. A capture vessel receives the condensed liquid from the condenser output. A recirculator couples the capture vessel to the primary condenser input and is configured to receive the condensed liquid from the primary condenser, and to provide at least a portion of the condensed liquid as the solvent in the primary condenser. The solvent from the bio-oil component/solvent mixture is then extracted in a solvent extraction system and returned to the quenching system.

Abstract: A process for removing sulfur compounds from a liquid hydrocarbon stream includes the steps of feeding the hydrocarbon stream to a recirculation section of an extraction vessel wherein the recirculation section contains a first alkaline solution; passing the hydrocarbon stream through the recirculation section; recirculating at least a part of a first alkaline stream to a top deck of one or more liquid-liquid contacting decks of the recirculation section; passing the hydrocarbon stream from the recirculation section to an extraction section of the extraction vessel wherein the extraction section includes one or more liquid-liquid contacting decks; feeding a second alkaline stream to an upper deck of the one or more liquid-liquid contacting decks of the extraction section wherein the second alkaline stream includes a second alkaline solution; and withdrawing a hydrocarbon product stream from the extraction vessel. An apparatus for removing sulfur compounds from the hydrocarbon stream is also disclosed.

Abstract: The present invention relates to a process and a plant for the production, in particular the continuous production, of nitrobenzene by means of adiabatic nitration of benzene with nitric acid in the presence of sulfuric acid, in which, following the nitration, a multi-stage concentration of the sulfuric acid is carried out by means of heating at a pressure that is reduced as compared with ambient pressure, and wherein the heating takes place using the heat generated in the adiabatic nitration of benzene.

Abstract: A process that includes: mixing a hydrocarbon composition that includes at least one organic sulfur-containing compound with an extraction solvent in a film-shear reactor under conditions wherein the extraction solvent extracts the at least one organic sulfur-containing compound from the hydrocarbon composition; separating a first phase comprising the at least one organic sulfur-containing compound and the extraction solvent from a second phase comprising the hydrocarbon composition; oxidizing with ozone the at least one organic sulfur-containing compound in the first phase to produce at least one oxidized organic sulfur-containing compound; and separating the at least one oxidized organic sulfur-containing compound from the extraction solvent.

Abstract: Methods and systems for producing a moisture swing sorbent for carbon dioxide capture from air are disclosed. In some embodiments, the methods include the following: providing a heterogeneous ion-exchange material; soaking the material in deionized water; washing the material in hydroxide or carbonate solutions; rinsing the material in deionized water; collecting and titrating residuals of the soaking and the washing steps into a residual solution; measuring an amount of chloride in the residual solution; repeating all of the steps if the amount of chloride measured in the residual solution is greater than zero; and drying the material with either dry nitrogen gas or air free of carbon dioxide and water.

Abstract: According to one aspect of the invention, a riser includes a cylindrical housing defined by a sidewall having an interior surface and an exterior surface. A baffle is defined by a first segment and a second segment, wherein the baffle is designed to be positioned on the interior surface of the riser and wherein the first segment and second segment are releasably interlockable.

Abstract: Systems and methods are provided for filtering a fluid containing nanoparticles. The systems and methods generally include introducing a stream of the nanoparticle-containing fluid into a holding vessel, and extracting at least a part of a nanoparticle-containing fluid accumulated in the holding vessel. The extracted nanoparticle-containing fluid is passed through a filtration module to separate a nanoparticle-containing retentate from a permeate, and the retentate is returned to the vessel. The filtration cycle can be repeated until a desired concentration of the nanoparticles is achieved in the holding vessel. In many embodiments, the generation of the nanoparticle-containing fluid and its filtration are performed concurrently.

Abstract: The present invention relates to a process for the oxidative regeneration of a deactivated catalyst comprising molecular sieve to provide a regenerated molecular sieve catalyst, wherein said deactivated catalyst is from one or both of an oxygenate to olefin process and a olefin cracking process, said regeneration process comprising at least the steps of providing a regeneration gas stream comprising oxidant; treating the regeneration gas stream with a liquid adsorbent stream comprising an ethylene glycol in a contaminant absorption zone to remove at least a part of one or more of any water, any alkali metal ion and any alkaline earth metal ion present in the regeneration gas stream to provide a treated regeneration gas stream comprising oxidant; regenerating a deactivated catalyst comprising molecular sieve with the treated regeneration gas stream to provide a regenerated catalyst comprising regenerated molecular sieve.

Abstract: We provide a catalytic process to reduce an organic halide in a hydrocarbon, comprising: a. producing the hydrocarbon comprising the organic halide in a process unit; and b. contacting the hydrocarbon comprising the organic halide with a metal chloride under anhydrous conditions in a halide removal vessel to produce a contacted hydrocarbon having from 50-100 wt % of a total halide in the hydrocarbon removed. We also provide an apparatus for performing this process.

Abstract: Digestion of cellulosic biomass to produce a hydrolysate may be accompanied by the formation of cellulosic fines which may be damaging to system components. Biomass conversion systems that may address the issue of cellulosic fines may comprise a fluid circulation loop comprising: a hydrothermal digestion unit; a solids separation unit that is in fluid communication with an outlet of the hydrothermal digestion unit; where the solids separation unit comprises a plurality of filters and the filters are in fluid communication with the fluid circulation loop in both a forward and a reverse flow direction; and a catalytic reduction reactor unit that is in fluid communication with an outlet of the solids separation unit and an inlet of the hydrothermal digestion unit; where at least one of the plurality of filters is in fluid communication with an inlet of the catalytic reduction reactor unit.

Abstract: The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.

Abstract: A separation membrane including an alloy, the alloy including at least one Group 5 element, and at least one selected from Pt and Ir.

Abstract: Provided is a hydrogen station that supplies hydrogen, including: a shaft power generation unit that generates shaft power and heat; a reactor that obtains hydrogen by causing a reaction in a raw material using the heat supplied from the shaft power generation unit; and a compressor that compresses the hydrogen obtained by the reactor, wherein the shaft power generation unit drives the other devices and drives the compressor by applying the shaft power thereto.

Abstract: Systems and methods for extracting and processing gases from submerged sources are disclosed. A system for removing and processing a gas from a submerged area in accordance with a particular embodiment includes a membrane or other open-bottom structure having a port and being disposed over at least a portion of the submerged area so as to at least partially enclose a volume of the gas. The system can further include a chemical reactor coupled to the open-bottom structure to receive the gas, and positioned to conduct a non-combustion reaction to dissociate a constituent from a donor substance of the gas.

Abstract: An alcohol such as methanol is reacted with carbon monoxide in a liquid reaction medium including a catalyst, an alkyl iodide such as methyl iodide, alkyl acetate such as methyl acetate in specified proportions, an additive, and an effective amount of water, where the additive increases an ionic character of the hydrogen iodide bond and the effective amount of water is sufficient to facilitate carboxylic acid release after carbonylation at the catalyst and to reduce anhydride formation. The present reaction system not only provides an acid product at water levels considerable below levels currently used, but also provides unexpected reaction rates and unexpected high catalyst stability.

Abstract: An apparatus for the catalytic reaction of gaseous hydrocarbons into synthesis gas by means of oxygen is disclosed. In order to improve the apparatus it is provided for the catalyst chamber containing the gas and the catalyst particle to be separated from the oxygen chamber containing the oxygen by a gas-permeable wall.

Abstract: Disclosed are an apparatus and method for preparing alcohol from olefin. A reactor for hydroformylating olefin comprises a loop reactor for reducing high-boiling point components, a post-treatment device for separating aldehyde comprises a catalyst/aldehyde separator and a divided wall column (DWC) for removing remaining high-boiling point components, and a post-treatment device for separating alcohol comprises a divided wall column (DWC) for removing remaining high-boiling point components. The apparatus and method for preparing alcohol reduce production of high-boiling point components in the preparation of alcohols and efficiently remove remaining high-boiling point components, thus obtaining alcohol containing no high-boiling point components.

Abstract: The invention relates to a process and apparatus for recovering sulfur (9). In a sour gas scrubbing apparatus (S) comprises a scrubbing part (SP) and a regeneration part (RP), wherein sulfur components and carbon dioxide are selectively removed from a crude synthesis gas (2) with the aid of a circulating scrubbing agent (3). A sulfur-containing gas fraction (8) produced during the regeneration of loaded scrubbing agent is supplied to a sulfur recovery system (SR) in which an off-gas (10) comprising carbon dioxide and also sulfur components is formed. The off-gas is hydrogenated (H) and subsequently subjected to a gas scrubbing operation (Z). The hydrogenated off-gas (12) is scrubbed, independently of the crude synthesis gas (2), and scrubbing agent (13) removed from the scrubbing agent circuit of the sour gas scrubbing apparatus (S) is used to scrub out sulfur components from the hydrogenated off-gas (12).

Abstract: A reactor for carrying out a chemical reaction in a three phase slurry system providing a horizontal reaction vessel with a cross sectional area which is dependent on the vessel length, vessel diameter, and axial position. The vessel has a gas inlet at or near the bottom of the reaction vessel and a gas distributor. The gas product exits the vessel by conduit means at or near the top of the reaction vessel. The vessel includes a plurality of horizontal cooling coils to provide a cooling medium to the slurry. In the reaction vessel, the synthesis gas has an average linear velocity which is a function of the vessel cross sectional area.

Abstract: The invention relates to a device for the continuous, homogeneous-catalysis reaction of a liquid with a gas and optionally an additional fluid, wherein the device comprises at least one reactor having an external liquid circulation driven by a pump, and wherein the device has at least one membrane separation stage that preferably holds back the homogeneous catalyst. The aim of the invention is to specify a device that allows homogeneous-catalysis gas/liquid phase reactions, in particular hydroformylations, which operate with membrane separation of the catalyst to be performed economically at an industrially relevant scale. Said aim is achieved in that a jet loop reactor is provided as the reactor, and that the pump and the membrane separation stage are arranged in the same external liquid circuit.