Means Injecting Internal Quench Stream Into Reaction Stream Downstream Of Reaction Stage Patents (Class 422/207)
  • Patent number: 11338262
    Abstract: In a catalytic reaction, after a reaction product leaves a catalyst bed, an inert substance with a low temperature is sprayed, and through heat absorption and vaporization processes of the inert substance, the temperature of the reaction product drops rapidly when staying in a catalyst cushion layer at a discharge end of a fixed bed reactor, or in a space formed by the catalyst cushion layer at the discharge end of the fixed bed reactor and a reactor head, or in a space formed by a tube plate at the discharge end of the fixed bed reactor and the reactor head. The residence time of the reaction product is shortened due to the entrance of the inert substance in a gaseous state.
    Type: Grant
    Filed: March 11, 2020
    Date of Patent: May 24, 2022
    Assignee: NOVASHIN CO., LTD.
    Inventors: Jianchun Yang, Kai Han, Dongmei Yang
  • Patent number: 10166526
    Abstract: Provided is a reactor in which a catalyst to accelerate reaction of a reactant is allowed to act on a reaction fluid having the reactant. The reactor has a partition that defines, in a parallel form, a plurality of reaction flow passages through which the reaction fluid flows, and a plurality of catalyst structures, each having a catalyst and being respectively provided in each of the plurality of reaction flow passages. The partition has a communicating portion allowing the plurality of reaction flow passages to communicate mutually.
    Type: Grant
    Filed: February 3, 2016
    Date of Patent: January 1, 2019
    Assignee: IHI CORPORATION
    Inventors: Koki Hamada, Hiroyuki Kamata, Takuya Yoshinoya
  • Patent number: 9567268
    Abstract: A quench system and process for cooling high temperature gases is presented. The quench system includes a frustum, or conic, shaped section having an inlet at the smaller end of the quench section and the outlet at the larger end of the quench section. The system includes spray nozzles having openings flush with the wall of the quench section. The process includes spraying a large volume of liquid in small droplets for rapid heat transfer and vaporization of the quench liquid.
    Type: Grant
    Filed: June 26, 2014
    Date of Patent: February 14, 2017
    Assignee: UOP LLC
    Inventors: Peter Shafe, Aziz Sattar, Mohammad Reza Mostofi-Ashtiani, Laura E. Leonard, Rajeswar Gattupalli
  • Patent number: 9057030
    Abstract: A system includes a gasifier, which includes a reaction chamber configured to convert a feedstock into a synthetic gas, a quench chamber configured to cool the synthetic gas, a quench ring configured to provide a water flow to the quench chamber, and a quench ring protection system configured to protect the quench ring from the synthetic gas or a molten slag. The quench ring protection system includes a protective barrier disposed within an inner circumferential surface of the quench ring. The protective barrier substantially overlaps the inner circumferential surface in an axial direction along an axis of the quench ring.
    Type: Grant
    Filed: October 30, 2010
    Date of Patent: June 16, 2015
    Assignee: General Electric Company
    Inventors: Judeth Brannon Corry, James Michael Storey, Paul Stephen Dimascio, Wei Chen, Wade Albert Taber, Delome Diane Fair
  • Patent number: 9034273
    Abstract: A system includes a quench ring assembly, which includes a quench ring, a throat ring coupled to the quench ring, and a dip tube coupled to the quench ring. The quench ring assembly is self-retained as a unit. The system also includes a support assembly configured to support the quench ring assembly. The support assembly includes a removable mount.
    Type: Grant
    Filed: June 4, 2012
    Date of Patent: May 19, 2015
    Assignee: General Electric Company
    Inventors: Karol Rzepniewski, Allyson Joy Jimenez-Huyke, Anna Renata Ziombra, Slawomir Jozef Golec
  • Patent number: 8999257
    Abstract: Methods and systems for the dehydrogenation of hydrocarbons include a direct contact condenser to remove compounds from an offgas process stream. The reduction of compounds can decrease duty on the offgas compressor by removing steam and aromatics from the offgas. The dehydrogenation reaction system can be applicable for reactions such as the dehydrogenation of ethylbenzene to produce styrene, the dehydrogenation of isoamiline to produce isoprene, or the dehydrogenation of n-pentene to produce piperylene.
    Type: Grant
    Filed: September 22, 2009
    Date of Patent: April 7, 2015
    Assignee: Fina Technology, Inc.
    Inventors: Vincent A. Welch, James R. Butler
  • Patent number: 8986405
    Abstract: A gas generator and process for converting a fuel into an oxygen-depleted gas and/or hydrogen-enriched gas. The gas generator is preferably used for generating protection gas or reducing gas for start up, shut down or emergency shut down of a SOFC or SOEC. The process for converting fuel into oxygen-depleted gas and/or a hydrogen-enriched gas includes combusting the fuel in a primary catalytic burner with an oxygen-containing gas to produce a flue gas with oxygen, combusting or partially oxidizing the flue gas comprising oxygen with excess fuel in a secondary catalytic burner to produce a gas with hydrogen and carbon monoxide, and reducing the trace amounts of oxygen from the gas comprising traces of oxygen and obtaining an oxygen-depleted gas, or reducing the carbon monoxide present in the gas by conversion to carbon dioxide or methane to obtain a hydrogen-enriched gas.
    Type: Grant
    Filed: December 1, 2010
    Date of Patent: March 24, 2015
    Assignee: Topsoe Fuel Cell A/S
    Inventor: Hassan Modarresi
  • Publication number: 20150045601
    Abstract: The present invention, a unique method and means of thermal cracking the molecular structure of short chain hydrocarbon vapor for reforming into long chain molecular structure and conversion of a portion to hydrocarbon liquid, much less complicated and complex than presently employed methods and means, combines partial oxidation, fast pyrolysis, and rapid cooling in a unique sequence of events incorporating components, of unique configuration, compact and much more cost effective than the presently employed methods and means of performing gas to liquid conversion that requires a great difference between the cost of the gas vapor feedstock and the selling price of the liquid to justify capital investment in gas to liquid conversion systems. Relatively few conversion systems are operating now and/or under construction.
    Type: Application
    Filed: August 9, 2013
    Publication date: February 12, 2015
    Inventor: Jerry M. Edmondson
  • Patent number: 8865086
    Abstract: A quenching apparatus for a reactor is disclosed. The quenching apparatus includes a quenching unit (31) and a mixing unit (41). The quenching unit includes fluid distribution pipes (33) which branch off from a central portion of the quenching unit in radial directions and eject quenching fluid, and one or more first fluid outlets (35) which are formed through the bottom of the quenching unit. The mixing unit includes inclined baffles (43), one or more partitions (42) and a second fluid outlet (45). The inclined baffles are respectively disposed under the first fluid outlets. The partitions partition a space between inner and outer sidewalls of the mixing unit into a plurality of separated spaces in which the inclined baffles are respectively disposed. Fluid guided by the inclined baffles and the partitions is discharged out of the mixing unit through the second fluid outlet.
    Type: Grant
    Filed: December 29, 2009
    Date of Patent: October 21, 2014
    Assignee: SK Innovation Co., Ltd.
    Inventors: Tae Young Jang, Min Ki Ahn, Sun Hyuk Bae, Gyung Rok Kim, Yoon Mang Hwang, Kyoo Sung Park, Sun Choi, Myung Jun Kim
  • Publication number: 20140170035
    Abstract: A gasification system includes a reaction chamber having an inlet for receiving a feedstock for conversion to a gas. Also included is a quench chamber configured to cool the gas. Further included is a quench ring operably coupled to a water supply pipe for receiving water therein, the quench ring configured to provide a water flow to the quench chamber. Yet further included is a sealing component disposed at a coupling interface between the quench ring and the water supply pipe.
    Type: Application
    Filed: December 17, 2012
    Publication date: June 19, 2014
    Applicant: GENERAL ELECTRIC COMPANY
    Inventor: Jerrold Samuel Kassman
  • Publication number: 20140014186
    Abstract: A system includes a gasifier. The gasifier includes a reaction chamber configured to convert a feedstock into a synthetic gas, a quench chamber configured to cool the synthetic gas, and a transition section between the reaction chamber and the quench chamber. The gasifier also includes a quench ring configured to provide a first flow of a coolant to the quench chamber and a shielding gas system configured to provide a second flow of a shielding gas to protect at least one of the quench ring or the transition section.
    Type: Application
    Filed: July 13, 2012
    Publication date: January 16, 2014
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Paromita Bhattacharya, Atul Kumar Vij, Rajeshwar Sripada
  • Patent number: 8613896
    Abstract: A process is disclosed for the removal of nitrous oxide from a gas stream having a contaminating concentration of nitrous oxide to provide a gas stream with a significantly reduced concentration of nitrous oxide. The process includes passing the feed gas stream through a first heat transfer zone that is in heat exchange relationship with a product stream whereby heat is transferred from the product stream to the feed gas stream to thereby provide a heated gas stream; passing said heated gas stream to a reaction zone containing a N2O decomposition catalyst and optionally a combination of other catalyst that provides for the decomposition of nitrous oxide or other contaminants and yielding therefrom a product stream having a reduced concentration of nitrous oxide; and passing the product stream to the first heat transfer zone to provide a cooled product stream.
    Type: Grant
    Filed: May 17, 2011
    Date of Patent: December 24, 2013
    Assignee: Shell Oil Company
    Inventors: Christos Odyssea Angelides, Bradley Douglas Morello
  • Patent number: 8434505
    Abstract: In this disclosure, a reactor system is described. The reaction system comprises (a) a reaction vessel having an inner wall, wherein said reaction vessel is configured to receive reactants and export products and byproducts; (b) a primary quench device (PQD) configured to receive a coolant and disperse said coolant into said reaction vessel; and (c) a secondary quench device (SQD) configured to receive a coolant and disperse said coolant into said reaction vessel; wherein said PQD comprises an array of spray nozzles fixed on the inner wall of said reaction vessel at a first axial position; and wherein said SQD comprises (1) an axially movable pipe having a coolant entry end and a nozzle end, wherein said pipe is configured to be removably fixed inside said reaction vessel; and (2) a spray nozzle that is fluidly connected to said pipe at its nozzle end via a fluid tight seal connection.
    Type: Grant
    Filed: February 15, 2012
    Date of Patent: May 7, 2013
    Assignee: Synfuels International, Inc.
    Inventors: Duane Morrow, Joel Cantrell, Edward R. Peterson
  • Publication number: 20130011307
    Abstract: A gasifier includes a combustion chamber in which a fuel is burned to produce a syngas and a particulated solid residue. A quench chamber having a liquid coolant is disposed downstream of the combustion chamber. A dip tube couples the combustion chamber to the quench chamber. The syngas is directed from the combustion chamber to the quench chamber via the dip tube to contact the liquid coolant and produce a cooled syngas. A draft tube surrounds the dip tube such that an annular passage is formed between the draft tube and the dip tube. An asymmetric or symmetric faceted baffle is disposed proximate to an exit path of the quench chamber. The cooled syngas is directed through the annular passage and impacted against the baffle so as to remove entrained liquid content from the cooled syngas before the cooled syngas is directed through the exit path.
    Type: Application
    Filed: September 14, 2012
    Publication date: January 10, 2013
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Prashant Tiwari, Gregory Michael Laskowski, Judeth Brannon Corry, Helge Burghard Herwig Klockow, Allyson Joy Jimenez-Huyke, Shailesh Singh Bhaisora, Steven Craig Russell, Karl Hardcastle, Jennifer Lynn Moyer, Scott Reginald Parent, Yulianto Salahuddin Mohsin
  • Publication number: 20130011308
    Abstract: A gasifier includes a combustion chamber in which a fuel is burned to produce a syngas and a particulated solid residue. A quench chamber is disposed downstream of the combustion chamber. A dip tube is disposed coupling the combustion chamber to the quench chamber. The syngas is directed to contact liquid coolant in the quench chamber and produce a cooled syngas. A draft tube is disposed surrounding the dip tube such that an annular passage is formed. A baffle is disposed proximate to an exit path of the quench chamber. The cooled syngas is directed through the annular passage and impacted against the baffle so as to remove entrained liquid content from the cooled syngas before it is directed through the exit path. A cross sectional area of the annular passage is smaller towards the bottom of the quench chamber and larger towards the top of the quench chamber.
    Type: Application
    Filed: September 14, 2012
    Publication date: January 10, 2013
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Prashant Tiwari, Gregory Michael Laskowski, Judeth Brannon Corry, Helge Burghard Herwig Klockow, Allyson Joy Jimenez-Huyke, Shailesh Singh Bhaisora, Steven Craig Russell, Karl Hardcastle, Jennifer Lynn Moyer, Scott Reginald Parent, Yulianto Salahuddin Mohsin
  • Publication number: 20120294775
    Abstract: A novel tar-free gasification process and system is disclosed that involves the partial combustion of recycled dry solids and the drying of a slurry feedstock comprising carbonaceous material in two separate reactor zones in a two stage gasifier, thereby producing mixture products comprising synthesis gas. The synthesis gas produced from the high temperature first stage reaction zone is then quenched in the second stage reaction zone of the gasifier prior to introduction of a slurry feedstock. The temperature of the final syngas exiting the second stage reaction zone of the gasifier is thereby moderated to be in the range of about 350-900° F., which is below the temperature range at which tar is readily formed, depending upon the type of carbonaceous feedstock utilized.
    Type: Application
    Filed: August 1, 2012
    Publication date: November 22, 2012
    Applicant: PHILLIPS 66 COMPANY
    Inventors: Albert C. Tsang, David L. Breton
  • Patent number: 8313700
    Abstract: The water gas shift reactor includes a gas reaction tank including a reaction chamber formed in the shape of a hollow body provided with a porous plate installed therein to divide the inside of the reaction chamber into an upper reaction space and a lower collection space and a catalyst stacked on the upper surface of the porous plate to convert carbon monoxide into hydrogen, and an insulating layer provided at the outer surface of the reaction chamber, a syngas storage tank to store the syngas, a syngas supply pipe to supply the syngas to the gas reaction tank, after the syngas is heated by a preheater, a steam supply pipe to supply steam generated from a steam generator to the gas reaction tank such that the steam reacts with the syngas, after the steam is heated by a preheater, and a reaction gas discharge pipe.
    Type: Grant
    Filed: July 29, 2009
    Date of Patent: November 20, 2012
    Assignee: Korea Institute of Energy Research
    Inventors: See Hoon Lee, Jae Ho Kim, Jae Goo Lee
  • Patent number: 8298490
    Abstract: The present invention is directed to systems and methods of synthesizing trichlorosilane. The disclosed systems and methods can involve increasing the concentration of the solids in the slurry to recover or separate the volatilized metal salts and reduce the obstructions created by the solidification of the metal salts in downstream operations of the during trichlorosilane synthesis. Rather than heating to raise the temperature to vaporize chlorosilane compounds, and subsequently condensing the volatilized chlorosilane compounds, the present invention can involve increasing the solids concentration in the slurry stream by utilizing a non-condensable gas, such as hydrogen, to volatilize the chlorosilane components, which can consequently promote evaporative conditions that can reduce the slurry temperature. The lower slurry temperature results in a lower volatility of the metal salts, which reduces the likelihood of carryover to downstream unit operations.
    Type: Grant
    Filed: November 6, 2009
    Date of Patent: October 30, 2012
    Assignee: GTAT Corporation
    Inventors: Scott Fahrenbruck, Bruce Hazeltine
  • Patent number: 8293186
    Abstract: An apparatus and method of producing methanol includes reacting a heated hydrocarbon-containing gas and an oxygen-containing gas in a reactor; to provide a product stream comprising methanol; and transferring heat from the product stream to the hydrocarbon-containing gas to heat the hydrocarbon containing gas. After removing methanol and CO2 from the product stream, unprocessed hydrocarbons are mixed with the hydrocarbon containing gas fro reprocessing through the reactor.
    Type: Grant
    Filed: May 11, 2006
    Date of Patent: October 23, 2012
    Assignee: Gas Technologies LLC
    Inventors: Nathan A. Pawlak, Vladimir Ivanovich Vedeneev, Robert W. Carr
  • Patent number: 8236071
    Abstract: A quench ring for use with a gasifier system. The quench ring including an annular manifold having a radius, an annular channel coupled in flow communication with said manifold, and at least one inlet coupled in flow communication with said manifold, said at least one inlet having a center line aligned substantially tangentially to said annular manifold.
    Type: Grant
    Filed: August 15, 2007
    Date of Patent: August 7, 2012
    Assignee: General Electric Company
    Inventors: Judeth Helen Brannon Corry, Yulianto Salahuddin Mohsin
  • Patent number: 8202916
    Abstract: An apparatus and method of producing methanol includes reacting a heated hydrocarbon-containing gas and an oxygen-containing gas in a reactor; and adding a relatively cold hydrocarbon-containing gas, to be mixed directly with a mixture of the heated hydrocarbon-containing gas and the oxygen-containing gas, after formaldehyde is formed to inhibit decomposition of formaldehyde in the reactor, to provide a product stream comprising methanol and formaldehyde; and transferring heat from the product stream to the hydrocarbon-containing gas to heat the hydrocarbon containing gas.
    Type: Grant
    Filed: December 27, 2005
    Date of Patent: June 19, 2012
    Assignee: Gas Technologies LLC
    Inventors: Nathan A. Pawlak, Vladimir I. Vedeneev, Alexander L. Tots
  • Patent number: 8197564
    Abstract: A method of assembling a synthesis gas (syngas) cooler for a gasification system includes positioning a dip tube within a shell of the syngas cooler. The dip tube is configured to quench the syngas flowing through the shell and/or at least partially channel the syngas through the dip tube. The method also includes coupling an isolation tube to the dip tube such that the isolation tube is substantially concentrically aligned with, and radially outward of, the dip tube. The isolation tube is coupled in flow communication with a purge gas source and is configured to at least partially form a dynamic pressure seal. The method further includes coupling at least one of the isolation tube and the dip tube in fluid communication with a fluid retention chamber. The method also include at least partially filling the fluid retention chamber with fluid, thereby further forming the dynamic pressure seal.
    Type: Grant
    Filed: February 13, 2008
    Date of Patent: June 12, 2012
    Assignee: General Electric Company
    Inventors: Allyson Joy Jimenez-Huyke, James Michael Storey, John Saunders Stevenson, Aaron John Avagliano, Thomas Frederick Leininger, Judeth Brannon Corry
  • Patent number: 8192688
    Abstract: A thermally diluted exothermic reactor system is comprised of numerous orifices distributed within a combustor by distributed perforated contactor tubes or ducts. The perforated contactors deliver and mix diluent fluid and one or more reactant fluids with an oxidant fluid. Numerous micro-jets about the perforated tubes deliver, mix and control the composition of reactant fluid, oxidant fluid and diluent fluid. The reactor controls one or more of composition profiles, composition ratio profiles and temperature profiles in one or more of the axial direction and one or two transverse directions, reduces temperature gradients and improves power, efficiency and emissions.
    Type: Grant
    Filed: March 26, 2009
    Date of Patent: June 5, 2012
    Assignee: Vast Power Portfolio LLC
    Inventors: David L. Hagen, Gary Ginter, Bill Goheen, L. Allan McGuire, Janet Rankin
  • Patent number: 8057641
    Abstract: A method and apparatus for effective pyrolysis of a biomass utilizing rapid heat transfer from a solid heat carrier or catalyst. Particularly, various embodiments of the present invention provide methods and apparatuses which incorporate progressive temperature quenching and rapid disengagement of the heat carrier material and reaction product.
    Type: Grant
    Filed: July 19, 2010
    Date of Patent: November 15, 2011
    Assignee: Kior Inc.
    Inventors: Robert Bartek, Ronald Lee Cordle
  • Patent number: 8043587
    Abstract: A reactor cools humidifies gases produced by combustion or the like. The reactor has a chamber with an inlet at a lower end to receive a flow of gas, and an outlet at a upper end. The gas flows in a generally upward direction through the reactor. The horizontal cross-section of the chamber increases with height and the flow velocity of the gas decreases as it flows upwardly. The reactor includes at least one device for injecting water droplets into the upper region of the chamber, counter to the gas flow. As the water droplets fall, they gradually evaporate and lose mass and encounter a counterflow of increasingly higher velocity and temperature until the force of the upwardly flowing gas is sufficient to reverse their flow and carry them in an upward direction.
    Type: Grant
    Filed: July 11, 2008
    Date of Patent: October 25, 2011
    Assignee: Indigo Technologies Group Pty Ltd
    Inventors: Rodney John Truce, Mieczyslaw Adam Gostomczyk
  • Patent number: 8003067
    Abstract: An abatement system is provided which includes 1) an abatement unit adapted to abate effluent; and 2) an ambient air supply system. The ambient air supply system includes an air moving device, wherein the ambient air supply system is adapted to supply ambient air to the abatement unit for use as an oxidant. Numerous other aspects are provided.
    Type: Grant
    Filed: March 21, 2008
    Date of Patent: August 23, 2011
    Assignee: Applied Materials, Inc.
    Inventors: Mark W. Curry, Barry Page, Shaun W. Crawford, Robbert Vermeulen, William D. Pyzel, Youssef Loldj, Rene T. Correa, Daniel S. Brown, Allen Fox
  • Patent number: 7981373
    Abstract: A reaction device can raise heat use efficiency. The reaction device includes a carbon monoxide remover removing carbon monoxide, and a vaporizer provided inside the carbon monoxide remover to vaporize fuel.
    Type: Grant
    Filed: September 26, 2007
    Date of Patent: July 19, 2011
    Assignee: Casio Computer Co., Ltd.
    Inventors: Kaoru Saito, Naotomo Miyamoto
  • Patent number: 7976800
    Abstract: An integrated exhaust gas cooling system and method, including an expansion joint linking the system to an upstream source of exhaust gas and a pre-oxidation section through which exhaust gas travels. A hot temperature zone in which the exhaust gas is maintained at a temperature optimal for an oxidation process extends through the pre-oxidation section. An oxidation catalyst in the hot temperature zone is provided. The exhaust gas passes through the oxidation catalyst. Oxidized exhaust gas passes a post-oxidation section downstream of the oxidation catalyst. A tempering air stream is injected into the post-oxidation section to create a cool temperature zone in which the oxidized exhaust gas is cooled below the temperature in the hot temperature zone and to a temperature optimal for a reduction process. The system includes a reduction catalyst in the cool temperature zone through which the oxidized exhaust gas passes.
    Type: Grant
    Filed: December 30, 2009
    Date of Patent: July 12, 2011
    Assignee: Peerless MFG. Co.
    Inventors: Mark A. Buzanowski, Sean P. McMenamin
  • Patent number: 7951339
    Abstract: A closed cycle Brayton direct contact reactor/storage tank uses an afterburner to assist in removing metal vapors from the working fluid. The direct contact reactor/storage tank operates by bubbling an inert gas through liquid metal fuel. The inert gas picks up metal vapors from the fuel. The afterburner comprises a predetermined amount of oxygen, O2, being fed to a filter cavity within the reactor/storage tank and having the metal vapors react directly with the O2 forming a solid oxide that remains and does not circulate as part of the working fluid throughout the external parts of the Brayton cycle outside of the reactor/storage tank causing damage to system components.
    Type: Grant
    Filed: August 7, 1992
    Date of Patent: May 31, 2011
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventor: Paul M. Dunn
  • Publication number: 20110092748
    Abstract: Disclosed are a process and an apparatus for synthesizing nitroalkanes by reaction of a hydrocarbon feedstock with aqueous nitric acid. Energy and capital costs may be reduced by recycling a majority of the aqueous phase back to the reactor.
    Type: Application
    Filed: September 10, 2010
    Publication date: April 21, 2011
    Applicants: DOW GLOBAL TECHNOLOGIES INC., ANGUS CHEMICAL COMPANY
    Inventors: Mahesh Sawant, Daniel M. Trauth, John G. Pendergast, JR.
  • Patent number: 7883673
    Abstract: Apparatus for producing nano-particles includes a furnace defining a vapor region therein. A precipitation conduit having an inlet end and an outlet end is positioned with respect to the furnace so that the inlet end is open to the vapor region. A quench fluid supply apparatus supplies quench fluid in a gas state and quench fluid in a liquid state. A quench fluid port positioned within the precipitation conduit is fluidically connected to the quench fluid supply apparatus so that an inlet to the quench fluid port receives quench fluid in the gas state and quench fluid in the liquid state. The quench fluid port provides a quench fluid stream to the precipitation conduit to precipitate nano-particles within the precipitation conduit. A product collection apparatus connected to the outlet end of the precipitation conduit collects nano-particles produced within the precipitation conduit.
    Type: Grant
    Filed: November 21, 2008
    Date of Patent: February 8, 2011
    Assignee: Cyprus Amax Minerals Company
    Inventors: Joel A. Taube, Mohamed H. Khan, James A. Cole
  • Patent number: 7879296
    Abstract: A reactor system for gas phase reacting of at least two fluid feed streams, where the reactor system has an injectively-mixed backmixing reaction chamber in fluid communication with a tubular-flow reactor. The injectively-mixed backmixing reaction chamber has a bulkhead that slides during real-time operation to either diminish or expand the internal volume of the backmixing reaction chamber. In one embodiment, the effective passageway space through the bulkhead is also variably adjustable. In another embodiment, the tubular-flow reactor shares the bulkhead so that axial bulkhead movement commensurately expands one reaction space while diminishing the other reaction space. Input gas streams enter the backmixing reaction chamber with sufficient velocity to turbulently agitate the contents of the injectively-mixed backmixing reaction chamber by injective intermixing of the alkane-containing gas feed stream and the oxygen-containing gas feed stream.
    Type: Grant
    Filed: March 14, 2007
    Date of Patent: February 1, 2011
    Assignee: Gas Technologies LLC
    Inventors: Nathan A. Pawlak, Robert W. Carr, Roger J Grunch
  • Patent number: 7749463
    Abstract: Apparatus for producing nano-particles comprises a furnace defining a vapor region therein. A precipitation conduit having an inlet end and an outlet end is positioned with respect to the furnace so that the inlet end is open to the vapor region. A quench fluid port positioned within the precipitation conduit provides a quench fluid stream to the precipitation conduit to precipitate nano-particles within the precipitation conduit. A product collection apparatus connected to the outlet end of the precipitation conduit collects the nano-particles produced within the precipitation conduit.
    Type: Grant
    Filed: August 16, 2002
    Date of Patent: July 6, 2010
    Assignee: Cyprus Amax Minerals Company
    Inventors: Mohamed H. Khan, James A. Cole, Joel A. Taube
  • Publication number: 20100143216
    Abstract: A reactor vessel for preparing a syngas comprising a tubular syngas collection chamber, a quench chamber and a dipleg connecting the syngas collection chamber with the quench chamber, wherein the syngas collection chamber is connected to the dipleg via a slag tap, comprising a frusto-conical part starting from the lower end of the tubular wall of the syngas collection chamber and diverging to an opening fluidly connected to the interior of the dipleg, wherein the diameter of said opening is smaller than the diameter of the dipleg, and wherein the frusto-conical part comprises one or more conduits having in inlet for cooling medium and an outlet for used cooling medium wherein the slag tap also comprises a first tubular part connected to the opening of the frusto-conical part and extending in the direction of the dipleg, wherein a second tubular part is connected to the frusto-conical part or to the tubular part and extending in the direction of the dipleg and having a diameter smaller than the diameter of
    Type: Application
    Filed: December 2, 2009
    Publication date: June 10, 2010
    Inventors: Benedict Ignatius Maria TEN BOSCH, Thomas Ebner, Wouter Koen Harteveld, Hans Joachim Heinen, Manfred Heinrich Schmitz-Goeb
  • Publication number: 20100125157
    Abstract: A method and system for producing dispersed waxes, including a high shear mechanical device. In one embodiment, the method comprises forming a dispersion of wax globules in a carrier liquid in a high shear device prior to implementation in a waxy product. In another instance the system for producing waxy products comprises a high shear device for dispersing wax in a carrier liquid.
    Type: Application
    Filed: November 6, 2009
    Publication date: May 20, 2010
    Applicant: H R D CORPORATION
    Inventors: Abbas Hassan, Aziz Hassan
  • Publication number: 20090324477
    Abstract: An apparatus comprising: a reaction chamber 2 into which silicon tetrachloride and hydrogen is introduced for producing a reaction product gas containing trichlorosilane and hydrogen chloride by a reductive reaction at a temperature of not lower than 800° C.; a reaction product gas discharging device 4 that discharges the reaction product gas in the reaction chamber 2 to the outside; a cooling gas introducing device 5 that mixes hydrogen, silicon tetrachloride, or hydrogen chloride in the reaction product gas being discharged by the reaction product gas discharging device 4 to cool the reaction product gas.
    Type: Application
    Filed: October 26, 2007
    Publication date: December 31, 2009
    Applicant: Mitsubishi Materials Corporation
    Inventors: Kazuki Mizushima, Makoto Urushihara
  • Publication number: 20090326301
    Abstract: Systems and methods are provided herein for cooling an olefin cracking reactor effluent stream. One provided method includes reacting a hydrocarbon feedstock including C4+ olefins in an olefin cracking reactor to produce an olefin cracking reactor effluent stream, providing the olefin cracking reactor effluent stream to an inlet of a contact cooler, contacting the olefin cracking reactor effluent stream with a first quench liquid in a first contact zone in the contact cooler to produce a first bottoms stream and an intermediate vapor stream, contacting the intermediate vapor stream with a second quench liquid in a second contact zone in the contact cooler to produce a second bottoms stream and a cooled vapor stream, and removing the cooled vapor stream from an outlet of the contact cooler. The method can also include cooling the first bottoms stream to provide a cooled first bottoms stream, and cooling the second bottoms stream to provide a cooled second bottoms stream.
    Type: Application
    Filed: June 30, 2008
    Publication date: December 31, 2009
    Inventor: ADAM KANYUH
  • Patent number: 7611625
    Abstract: A system and method for oxidizing a feed material includes a reactor vessel that forms an enclosed chamber. The vessel includes a port for introducing the feed material into the chamber where it can be oxidized to create salts and particulates, together with a fluid effluent. After their creation, the salts and particulates flow into a brine pool maintained within the chamber. Thereafter, brine, including salts and particulates, can be removed from the chamber through a vessel outlet. Further, the vessel includes a fluid effluent discharge pipe extending from outside the vessel, through the brine pool, into the chamber. As a result of this structure, the fluid effluent can be separated from the salts and particulates and discharged from the chamber through the pipe, passing through the brine pool.
    Type: Grant
    Filed: April 12, 2006
    Date of Patent: November 3, 2009
    Assignee: General Atomics
    Inventors: David A. Hazlebeck, John L. Perlman
  • Patent number: 7582201
    Abstract: In a system for thermal cracking gaseous feedstocks, the system including a gas cracker for producing an effluent comprising olefins, at least one transfer line exchanger for the recovery of process energy from the effluent and a water quench tower system, a process for extending the range of system feedstocks to include liquid feedstocks that yield tar is provided. The process includes the steps of injecting a first quench fluid downstream of a primary transfer line exchanger to quench the process effluent comprising olefins, separating in a first separation vessel a cracked product and a first byproduct stream comprising tar from the quenched effluent, directing the separated cracked product to a water quench tower system and quenching the separated cracked product with a second quench fluid to produce a cracked gas effluent for recovery and a second byproduct stream comprising tar. An apparatus for carrying out such process is also provided.
    Type: Grant
    Filed: December 5, 2006
    Date of Patent: September 1, 2009
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: James N. McCoy, Barrington M. Hammond, David J. Duhon, Mark A. Rooney, Robert D. Strack, John R. Messinger
  • Publication number: 20090194458
    Abstract: A process and apparatus are provided for upgrading steam cracked tars. The invention also relates to a steam cracking process and apparatus for reducing the yields of tars produced from steam cracking while increasing yields of higher value products, heating cooled steam cracker tar containing asphaltenes, to a temperature, e.g., above about 300° C., which is sufficient to convert at least a portion of the steam cracked tar to lower boiling molecules. The resulting heat-treated tar can be separated into gas oil, fuel oil and tar streams.
    Type: Application
    Filed: January 31, 2008
    Publication date: August 6, 2009
    Inventors: John D.Y. Ou, Glenn A. Heeter
  • Publication number: 20090169437
    Abstract: Apparatus for producing nano-particles includes a furnace defining a vapor region therein. A precipitation conduit having an inlet end and an outlet end is positioned with respect to the furnace so that the inlet end is open to the vapor region. A quench fluid supply apparatus supplies quench fluid in a gas state and quench fluid in a liquid state. A quench fluid port positioned within the precipitation conduit is fluidically connected to the quench fluid supply apparatus so that an inlet to the quench fluid port receives quench fluid in the gas state and quench fluid in the liquid state. The quench fluid port provides a quench fluid stream to the precipitation conduit to precipitate nano-particles within the precipitation conduit. A product collection apparatus connected to the outlet end of the precipitation conduit collects nano-particles produced within the precipitation conduit.
    Type: Application
    Filed: November 21, 2008
    Publication date: July 2, 2009
    Applicant: CYPRUS AMAX MINERALS COMPANY
    Inventors: Joel A. Taube, Mohamed H. Khan, James A. Cole
  • Publication number: 20090149679
    Abstract: A process for depolymerizing fluoropolymers includes continuously feeding a solid fluoropolymer, in particulate form, into a horizontal cylindrical first reaction zone. The fluoropolymer particles enter the first reaction zone at one end. Within the first reaction zone, a central axle from which protrudes at least one paddle, continuously rotates. The rotating paddle serves to advance the fluoropolymer particles along the reaction zone while agitating them. As the fluoropolymer particles pass along the reaction zone, they are subjected to an elevated temperature, thereby depolymerizing the fluoropolymer into a fluoro-containing compound-rich gas phase. A residual solids phase is withdrawn at the other end of the first reaction zone, as is the gas phase. Optionally, the gas phase is passed through a second reaction zone which is also at an elevated temperature. The gas phase is quenched, thereby to recover the fluoro-containing compounds as gaseous products.
    Type: Application
    Filed: November 24, 2006
    Publication date: June 11, 2009
    Inventors: Izak Jacobus Van Der Walt, Alfred Teo Grunenberg, Johannes Theodorus Nel
  • Patent number: 7500998
    Abstract: A gas mixture containing a fuel, water and air is supplied to one end of a reforming room, and a reformed gas containing hydrogen is discharged from the other end thereof. Two or more such reforming units are connected in series, and the upstream part of each reforming room is filled with a first catalyst which catalyzes a partial oxidation reaction in an oxygen-rich environment, and the downstream part is filled with a second catalyst which performs the reforming reaction. The gas mixture which has been heated in a heating unit passes through a distribution tube and is distributed evenly to the reforming units. The reforming room is composed of a reforming tube in which a reforming catalyst is charged, or two or more such reforming tubes, parallel to each other. After being reformed the high-temperature reformed gas is passed around the reforming tubes, and fed back to a manifold.
    Type: Grant
    Filed: February 13, 2004
    Date of Patent: March 10, 2009
    Assignee: IHI Corp.
    Inventors: Hideaki Komaki, Kunio Matsui
  • Publication number: 20090047193
    Abstract: A method for operating a syngas cooler is provided. The method includes channeling a flow of syngas into an annular cooling chamber having a longitudinal axis, injecting a cooling fluid into a manifold such that the cooling fluid is channeled substantially circumferentially about the annular cooling chamber, and discharging the cooling fluid from the manifold such that the cooling fluid contacts a surface of the cooling chamber at a predetermined angle relative to the axis of the cooling chamber.
    Type: Application
    Filed: August 15, 2007
    Publication date: February 19, 2009
    Inventors: Judeth Helen Brannon Corry, Yulianto Salahuddin Mohsin
  • Publication number: 20080277268
    Abstract: A method of and system for recirculating a fluid in a particle production system. A reactor produces a reactive particle-gas mixture. A quench chamber mixes a conditioning fluid with the reactive particle-gas mixture, producing a cooled particle-gas mixture that comprises a plurality of precursor material particles and an output fluid. A filter element filters the output fluid, producing a filtered output. A temperature control module controls the temperature of the filtered output, producing a temperature-controlled, filtered output. A content ratio control module modulates the content of the temperature-controlled, filtered output, thereby producing a content-controlled, temperature-controlled, filtered output. A channeling element supplies the content-controlled, temperature-controlled, filtered output to the quench chamber, wherein the content-controlled, filtered output is provided to the quench chamber as the conditioning fluid to be used in cooling the reactive particle-gas mixture.
    Type: Application
    Filed: May 8, 2008
    Publication date: November 13, 2008
    Inventor: Fredrick P. Layman
  • Publication number: 20080274023
    Abstract: Hydrocarbon feedstock containing resid is cracked by a process comprising: (a) heating said hydrocarbon feedstock; (b) mixing the heated hydrocarbon feedstock with steam to form a mixture stream; (c) introducing the mixture stream to a flash/separation apparatus to form i) a vapor phase comprising coke precursors existing as uncoalesced condensate, and ii) a liquid phase; (d) removing the vapor phase as overhead and the liquid phase as bottoms from the flash/separation apparatus; (e) treating the overhead by contacting with a condensing means downstream of the flash/separation apparatus to at least partially coalesce the coke precursors to provide residue hydrocarbon liquid, and subsequently removing the hydrocarbon liquid; (f) heating the treated overhead to provide a heated vapor phase (g) cracking the heated vapor phase in a radiant section of a pyrolysis furnace to produce an effluent comprising olefins, the pyrolysis furnace comprising a radiant section and a convection section; and (h) quenching the eff
    Type: Application
    Filed: July 2, 2008
    Publication date: November 6, 2008
    Inventors: Richard C. Stell, Nicholas G. Vidonic
  • Publication number: 20080221378
    Abstract: An apparatus and process are provided for cracking hydrocarbons. Hot, cracked effluent is removed to a quench header where it is pre-quenched with an oil containing crackable components, e.g., 1000° F.+ (538° C.+) boiling range bottoms taken from a vapor/liquid separator, cracking the bottoms to more valuable products, e.g., steam crack naphtha. The overhead of the separator is fed to a cracker, and then quenched with a quenching oil.
    Type: Application
    Filed: February 12, 2008
    Publication date: September 11, 2008
    Inventors: Richard C. Stell, Megan Renstrom Bleckinger, James N. McCoy, Arthur R. Di Nicolantonio
  • Patent number: 7402188
    Abstract: A method and apparatus for efficiently forming a gaseous material from a solid starting material. The produced gaseous material includes a CGE HHV having a high percentage of an original HHV of the starting material. The gaseous product may be used to form a plurality of materials for various purposes.
    Type: Grant
    Filed: August 31, 2004
    Date of Patent: July 22, 2008
    Assignee: Pratt & Whitney Rocketdyne, Inc.
    Inventor: Kenneth M. Sprouse
  • Publication number: 20080128323
    Abstract: In a system for thermal cracking gaseous feedstocks, the system including a gas cracker for producing an effluent comprising olefins, at least one transfer line exchanger for the recovery of process energy from the effluent and a water quench tower system, a process for extending the range of system feedstocks to include liquid feedstocks that yield tar is provided. The process includes the steps of injecting a first quench fluid downstream of a primary transfer line exchanger to quench the process effluent comprising olefins, separating in a first separation vessel a cracked product and a first byproduct stream comprising tar from the quenched effluent, directing the separated cracked product to a water quench tower system and quenching the separated cracked product with a second quench fluid to produce a cracked gas effluent for recovery and a second byproduct stream comprising tar. An apparatus for carrying out such process is also provided.
    Type: Application
    Filed: December 5, 2006
    Publication date: June 5, 2008
    Inventors: James N. McCoy, Barrington M. Hammond, David J. Duhon, Mark A. Rooney, Robert D. Strack, John R. Messinger
  • Patent number: 7381384
    Abstract: Insulating members are provided for use in nozzles of elevated temperature process vessels employing a structural metal shell (24), an insulating refractory lining (14) and a corrosion-resistant membrane (18) lining between the structural shell and refractory lining. The insulating members comprise pre-formed insulating sleeves and inserts and are made of a thermally insulating material having sufficient thickness and sufficiently low thermal conductivity such that, when the sleeve or insert is heated by the process temperature during operation of the vessel, the thermal energy transmitted through the sleeve or insert to the membrane is insufficient to raise the temperature of the membrane above a target temperature. The most preferred thermally insulating materials are fluoropolymers such as poly(tetrafluoroethylene) flouropolymer resins.
    Type: Grant
    Filed: August 9, 2002
    Date of Patent: June 3, 2008
    Assignee: Hatch Ltd.
    Inventors: Kevin S. Fraser, Patrick Henry Lauzon, Arthur W Cooper, Albert J. Koning