Means Injecting Internal Quench Stream Into Reaction Stream Downstream Of Reaction Stage Patents (Class 422/207)
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Patent number: 7341610Abstract: A fuel cell system includes a fuel cell unit and a gas-generating system containing at least one reforming unit for obtaining a hydrogen-rich reformate from a fuel. It is possible to supply the reformate at least partly to the anode side of the fuel cell unit. The system may include a first reforming reactor for producing a first reformate with a high outlet temperature; a second reforming reactor for producing a second reformate with a second outlet temperature which is below the first outlet temperature; a mixing element for mixing the first reformate with at least one fuel and located between an outlet of the first reforming reactor and an inlet of the second reforming reactor. The second reformate may be supplied to a gas-purification system and the purified reformate supplied to the fuel cell unit.Type: GrantFiled: June 3, 2005Date of Patent: March 11, 2008Assignee: NuCellSys GmbHInventor: Uwe Griesmeier
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Patent number: 7332138Abstract: A fixed bed catalytic reactor for converting process fluids having an upper catalyst bed and a lower catalyst bed below the upper catalyst bed for converting process fluids flowing through the upper and lower beds. A mixing zone is located between the upper bed and lower beds, and at least one jet is provided for injecting an inclined fluid jet into the mixing zone against the flow of the process fluids to entrain process fluids within the jet and to radially mix the process fluids across the mixing zone.Type: GrantFiled: July 26, 2002Date of Patent: February 19, 2008Assignee: ExxonMobil Research and Engineering CompanyInventors: Ramesh Gupta, Robert Koros, Ramesh R. Hemrajani
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Patent number: 7217302Abstract: Process for the recovery of chemicals and energy from spent liquor obtained in the chemical pulping process, in which the spent liquor is gasified under sub-stoichiometric conditions to produce partly one phase of solid and/or fused material, together with partly one phase of a flammable gaseous material, whereafter the said phases are cooled by direct contact with a cooling medium (9), is separated from the said phase of flammable gaseous material in order to be dissolved and collected up as a product liquid in a product liquid receiver (11). According to the invention, the said cooling medium (9) consists of an essentially water-free cooling medium, which after vaporizing/cracking increases the calorific value of the flammable gaseous material drawn off. At the same time, the process is improved in this way since the flammable gases can be used more effectively for the purpose of e.g. generating energy.Type: GrantFiled: March 22, 2000Date of Patent: May 15, 2007Assignee: Chemrec AktiebolagInventor: Bengt Nilsson
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Patent number: 7211194Abstract: A gravity pressure vessel (GPV) for processing a fluid stream containing organic materials provides several improvements to the art. In one embodiment, a GPV of the present invention sustains the heat energy requirements of a hydrolysis GPV by including therein, a first reaction chamber for conducting an exothermic reaction, and subsequently providing a second reaction chamber for hydrolysis of certain organic materials refractory to the exothermic reaction. Another embodiment provides for the perpetual cleaning of the heat transfer surfaces of the GPV. Still another embodiment provides for selective alteration of a hydrolysis reaction within a GPV independent of the flow of the fluid stream through the GPV.Type: GrantFiled: October 27, 2004Date of Patent: May 1, 2007Assignee: Eau-Viron, Inc.Inventor: James A. Titmas
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Patent number: 7033552Abstract: A process for upgrading at least one of a Fischer-Tropsch naphtha and a Fischer-Tropsch distillate to produce at least one of a gasoline component, a distillate fuel or a lube base feedstock component. The process includes reforming a Fischer-Tropsch naphtha to produce hydrogen by-product and a gasoline component with a research octane rating of at least about 80. The process further includes upgrading a Fischer-Tropsch distillate using the hydrogen by-product to produce a distillate fuel and/or a lube base feedstock component.Type: GrantFiled: January 31, 2002Date of Patent: April 25, 2006Assignee: Chevron U.S.A. Inc.Inventors: Dennis J. O'Rear, Lawrence W. Jossens
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Patent number: 6852215Abstract: A method for upgrading a hydrocarbon in which an oxygen source and a hydrogen source are ignited and the resulting synthetic gas is used to initiate a predominantly gas phase heavy oil upgrade reaction. The upgrade reaction is quenched with an additional source of un-upgraded hydrocarbon.Type: GrantFiled: April 18, 2002Date of Patent: February 8, 2005Assignee: ExxonMobil Upstream Research CompanyInventors: Michael Y. Wen, Eric D. Nelson
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Patent number: 6821411Abstract: A method is provided to inject steam into a hydrocarbon effluent passing through a transfer line exchanger (TLE) of a hydrocarbon cracking furnace to reduce the formation of a coke material on the TLE tubesheet. The apparatus that injects the steam is also provided to deliver a distributed steam flow in the low resonance area of the TLE cone.Type: GrantFiled: August 16, 2001Date of Patent: November 23, 2004Assignee: Chevron Phillips Chemical Company LPInventors: Brian D. Baca, Danna L. Kutach
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Patent number: 6821500Abstract: An apparatus for thermal conversion of one or more reactants to desired end products includes an insulated reactor chamber having a high temperature heater such as a plasma torch at its inlet end and, optionally, a restrictive convergent-divergent nozzle at its outlet end. In a thermal conversion method, reactants are injected upstream from the reactor chamber and thoroughly mixed with the plasma stream before entering the reactor chamber. The reactor chamber has a reaction zone that is maintained at a substantially uniform temperature. The resulting heated gaseous stream is then rapidly cooled by passage through the nozzle, which “freezes” the desired end product(s) in the heated equilibrium reaction stage, or is discharged through an outlet pipe without the convergent-divergent nozzle. The desired end products are then separated from the gaseous stream.Type: GrantFiled: February 12, 2001Date of Patent: November 23, 2004Assignee: Bechtel BWXT Idaho, LLCInventors: James R. Fincke, Brent A. Detering
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Publication number: 20040039239Abstract: Disclosed is a method and reactor system for converting oxygenate and/or olefin contaminants in a methanol to olefin reactor system product effluent to hydrocarbons, including paraffin compounds, preferably over a sulphided catalyst of the type Nickel or Cobalt combined with Molybdenum or Tungsten. In one embodiment, the oxygenate-containing stream to be hydrogenated comprises one or more of the following streams, alone or in combination: a quench tower bottoms stream, a water absorption unit bottoms stream, a C4+ stream, and/or a C5+ stream.Type: ApplicationFiled: August 20, 2002Publication date: February 26, 2004Inventor: John Richard Shutt
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Publication number: 20040013602Abstract: Apparatus for producing nano-particles according to the present invention may comprise a furnace defimng a vapor region therein. A precipitation conduit having an inlet end and an outlet end is positioned with respect to the furnace so that the inlet end is open to the vapor region. A quench fluid supply apparatus supplies quench fluid in a gas state and quench fluid in a liquid state. A quench fluid port positioned within the precipitation conduit is fluidically connected to the quench fluid supply apparatus so that an inlet to the quench fluid port receives quench fluid in the gas state and quench fluid in the liquid state. The quench fluid port provides a quench fluid stream to the precipitation conduit to precipitate nano-particles within the precipitation conduit. A product collection apparatus connected to the outlet end of the precipitation conduit collects the nano-particles produced within the precipitation conduit.Type: ApplicationFiled: May 15, 2003Publication date: January 22, 2004Inventor: Joel A. Taube
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Patent number: 6652817Abstract: An apparatus for processing an organohalogen compounds includes a catalyst container containing a catalyst layer, a supplying path for supplying a carrier gas containing organohalogen compounds and steam through the catalyst container, a cooling chamber arranged at a lower portion of the catalyst container, a spraying apparatus mounted in the cooling chamber for spraying a cooling liquid to cool exhaust gas containing a decomposed gas of the organohalogen compounds exhausted from the catalyst layer and a baffle member forming a bent path which introduces the exhaust gas containing the decomposed gas into the cooling chamber from the catalyst layer and mounted in the cooling chamber for preventing mists generated by spraying cooling liquid from the spraying apparatus from back flowing into the catalyst container.Type: GrantFiled: October 29, 1998Date of Patent: November 25, 2003Assignees: Hitachi, Ltd., Hitachi Engineering Co., Ltd.Inventors: Shin Tamata, Satoru Ohashi, Toshihide Takano, Hisao Yokoyama, Toshihiro Mori
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Patent number: 6613127Abstract: Methods and apparatus for processing and cooling a hot gaseous stream exiting a gasification reactor vessel at temperatures in excess of 1300° C. where the gas will come into contact with a corrosive aqueous liquid, including methods and apparatus for cooling the gaseous stream prior to quenching the gaseous stream as well as methods and apparatus for providing vessel construction able to provide for the contact of a hot gaseous stream at temperatures in excess of 1100° C. with a corrosive aqueous liquid.Type: GrantFiled: May 5, 2000Date of Patent: September 2, 2003Assignee: Dow Global Technologies Inc.Inventors: Connie M. Galloway, Kenneth W. Mall, Dennis W. Jewell, William M. Eckert, Leopoldo L. Salinas, III, Ed E. Timm
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Publication number: 20030035766Abstract: A method is provided to inject steam into a hydrocarbon effluent passing through a transfer line exchanger (TLE) of a hydrocarbon cracking furnace to reduce the formation of a coke material on the TLE tubesheet. The apparatus that injects the steam is also provided to deliver a distributed steam flow in the low resonance area of the TLE cone.Type: ApplicationFiled: August 16, 2001Publication date: February 20, 2003Inventors: Brian D. Baca, Danna L. Kutach
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Publication number: 20030009943Abstract: The invention concerns a method for producing a gas mixture containing hydrogen and carbon monoxide, and optionally nitrogen, from at least a hydrocarbon such as methane, propane, butane or LPG or natural gas, which consists in performing a partial catalytic oxidation (1) of one or several hydrocarbons, at a temperature of 500° C., at a pressure of 3 to 20 bars, in the pre of oxygen or a gas containing oxygen, such as air, to produce hydrogen and carbon monoxide; then in recuperating the gas mixture which can subsequently be purified or separated, by pressure swing adsorption, temperature swing adsorption of by permeation (3), to produce hydrogen having a purity of at least 80% and a residue gas capable of supplying a cogeneration unit In another embodiment, the gas mixture can subsequently be purified of its water vapour impurities and carbon dioxide to obtain a thermal treatment atmosphere containing hydrogen, carbon monoxide and nitrogen.Type: ApplicationFiled: August 21, 2002Publication date: January 16, 2003Inventors: Cyrille Millet, Daniel Gary, Philippe Arpentinier
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Publication number: 20020187086Abstract: Reaction chamber (4) elongated along an essentially vertical axis in which at least one reaction fluid is circulated from top to bottom of said chamber (4) through at least one catalyst bed (5), whereby downstream from catalyst bed (5) in the direction of circulation of the reaction fluid, the chamber contains at least one means (1) for introducing at least one quenching fluid, and downstream from means (1) for introducing quenching fluid, the chamber contains at least one box (8) for contact, mixing and quenching of said fluids. The box (8) has a primary dimension (D) and height (H1), and at least one passage section (9) for entry of the fluids into the box (8). Downstream from the passage section (9) in the direction of circulation of said reaction fluid, the box (8) contains a means (11) that puts fluids into vortex motion in the box (8) in a direction essentially non-radial and non-parallel to the axis of the chamber.Type: ApplicationFiled: May 9, 2002Publication date: December 12, 2002Applicant: Institut Francais du PetroleInventors: Ludovic Raynal, Isabelle Harter, Francis Aubry
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Patent number: 6486371Abstract: Vapor phase alkylation of an aromatic substrate in a multi-stage alkylation reaction zone having a plurality of series-connected catalyst beds providing mixing zones between adjacent catalyst beds. An aromatic substrate and a C2-C4 alkylating agent is supplied to an inlet side of a gas phase reaction zone causing vapor phase alkylation of the aromatic substrate as the aromatic substrate and the alkylating agent flow through the reaction zone from one catalyst bed to the next. A quench fluid comprising one or both of the aromatic substrate and the alkylating agent is supplied into the interior of the mixing zone through a plurality of flow paths. One portion of the flow paths is directed upwardly and another portion downwardly within the mixing zone. The quench fluid is supplied to the mixing zone through a plurality of dispersion channels spaced laterally from one another.Type: GrantFiled: November 28, 2000Date of Patent: November 26, 2002Assignee: Fina Technology, Inc.Inventors: James R. Butler, Denis Mignon
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Patent number: 6464949Abstract: A steam-cracking unit comprises at least one multitube quenching exchanger, equipped with a non-obstructive impact separator for preventing the erosion of the tubular input plate. The impact separator is at least 50% opaque when viewed from transfer pipe. It is arranged inside of an input cone in such a way that there is free passage of at least 40 mm between the periphery of the impact separator and the cone.Type: GrantFiled: March 8, 1999Date of Patent: October 15, 2002Assignee: Institut Francais du PetroleInventors: Eric Lenglet, Jean-Pierre Burzynski, Gérard Courteheuse, Roland Huin, Yves Gougne
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Patent number: 6455015Abstract: An apparatus and method for contacting fluids in a fluid-solids contacting chamber is disclosed. The fluid-solid contacting chamber has a plurality of beds, and the chamber comprises a plurality of conduits and outlet ports that are capable of providing improved fluid distribution of fluids that are introduced above or between the beds. One or more conduits are arranged within a single conduit, which provides a compact and inexpensive assembly for conveying the fluids to each conduit's outlet port. In operation, the fluid flow to the outlet port of each conduit is regulated within that outlet port's most efficient operating range, and since the flows can regulated simply by hand, the method of this invention can be practiced readily. Catalytic condensation and other hydrocarbon process units that employ this invention will have increased on-stream efficiencies and realize significant economic benefits.Type: GrantFiled: February 16, 2000Date of Patent: September 24, 2002Assignee: UOP LLCInventor: James W. Kilroy
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Publication number: 20020018737Abstract: An effluent gas stream treatment system for treatment of gaseous effluents such as waste gases from semiconductor manufacturing operations. The effluent gas stream treatment system comprises a pre-oxidation treatment unit, which may for example comprise a scrubber, an oxidation unit such an electrothermal oxidizer, and a post-oxidation treatment unit, such as a wet or dry scrubber. The effluent gas stream treatment system of the invention may utilize an integrated oxidizer, quench and wet scrubber assembly, for abatement of hazardous or otherwise undesired components from the effluent gas stream. Gas or liquid shrouding of gas streams in the treatment system may be provided by high efficiency inlet structures.Type: ApplicationFiled: October 4, 2001Publication date: February 14, 2002Inventors: Mark Holst, Kent Carpenter, Scott Lane, Prakash V. Arya
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Patent number: 6333010Abstract: An effluent gas stream treatment system for treatment of gaseous effluents such as waste gases from semiconductor manufacturing operations. The effluent gas stream treatment system comprises a pre-oxidation treatment unit, which may for example comprise a scrubber, an oxidation unit such an electrothermal oxidizer, and a post-oxidation treatment unit, such as a wet or dry scrubber. The effluent gas stream treatment system of the invention may utilize an integrated oxidizer, quench and wet scrubber assembly, for abatement of hazardous or otherwise undesired components from the effluent gas stream. Gas or liquid shrouding of gas streams in the treatment system may be provided by high efficiency inlet structures.Type: GrantFiled: September 20, 1999Date of Patent: December 25, 2001Assignee: Advanced Technology Materials, Inc.Inventors: Mark Holst, Kent Carpenter, Scott Lane, Prakash V. Arya
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Patent number: 6303088Abstract: A process for the production of hydrogen bromide gas by direct combustion of bromine in hydrogen involves carrying out the combustion reaction in an apparatus chamber made of impregnated graphite and a cooling zone composed of a steel jacket in which are piled blocks of impregnated graphite.Type: GrantFiled: March 13, 2000Date of Patent: October 16, 2001Assignee: AtofinaInventors: Sylvie Daire, Gilles Drivon, Thlerry Nodari, Michel Leydecker
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Patent number: 6165353Abstract: An arrangement for the controlled production of an essentially linear array of hydrocarbon feed injection jets maintains stable and reliable jets by passing individual piping for each jet through a support shroud that is located in a contacting vessel. Controlled atomization is provided by independently injecting a uniform quantity of gas medium into each of the plurality of uniformly created feed injection streams upstream of a discharge nozzle that separately discharges each mixed stream of hydrocarbons and gas medium into a stream of catalyst particles at or about the inner end of the support shroud. The feed injection jets are suitable for positioning in an inner location of a large contacting vessel. Uniformity of distribution is obtained by dividing the hydrocarbons streams from an oil chamber into an individual oil conduit for each spray injection nozzle. The individual oil conduits receive separate streams of a gas phase fluid that mixes with feed to pass the mixture to a spray nozzle.Type: GrantFiled: October 8, 1998Date of Patent: December 26, 2000Assignee: UOP LLCInventors: Brandon Scott Carpenter, Daniel N. Myers
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Patent number: 6160192Abstract: A steam-cracking unit and a steam-cracking process with controlled injection of solid particles in a quenching exchanger (3) is described. The particles are injected through a single axial injection pipe that is arranged on the axis of input cone (2) of the quenching exchanger, just upstream from an impact separator-diffuser (6) that comprises solid surfaces that are arranged opposite the transfer pipe of the cracked gases toward the exchanger; this impact separator-distributor is located in input cone (2) of the exchanger and is gas-permeable along a number of passages and at least 70% opaque when viewed from the transfer pipe.Type: GrantFiled: March 8, 1999Date of Patent: December 12, 2000Assignee: Institut Francais du PetroleInventors: Eric Lenglet, Jean-Pierre Burzynski, Gerard Courteheuse, Roland Huin, Yves Gougne
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Patent number: 6110429Abstract: The high temperature combustion of hydrogen and oxygen is used to transform halogenated refrigerant gases (HRGs) and halons to produce calcium fluoride salts. Calcium carbonate is also produced by a series of chemical processes. Calcium chloride is partially consumed by the process by reaction with fluoride released during the high temperature combustion of the HRGs. Calcium chloride is also produced in the process during scrubbing of chlorine and during the recovery of ammonia used to remove carbon dioxide. The calcium chloride produced during the process can be used in the combustion reaction to further produce calcium fluoride.Type: GrantFiled: November 12, 1997Date of Patent: August 29, 2000Inventor: P. G. Johansing, Jr.
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Patent number: 6098965Abstract: A quench zone mixing apparatus that occupies a low vertical height and has an improved mixing efficiency and fluid distribution across the catalyst surface includes a swirl chamber, a rough distribution network, and a distribution apparatus. In the swirl chamber, reactant fluid from a catalyst bed above is thoroughly mixed with a quench fluid by a swirling action. The mixed fluids exit the swirl chamber through an aperture to the rough distribution system where the fluids are radially distributed outward across the vessel to the distribution apparatus. The distribution apparatus includes a plate with a number of bubble caps and associated drip trays that multiply the liquid drip stream from the bubble caps to further symmetrically distribute the fluids across the catalyst surface. Alternatively, deflector baffles may be associated with the bubble caps to provide a wider and more uniform liquid distribution below the plate.Type: GrantFiled: October 23, 1998Date of Patent: August 8, 2000Assignee: Fluor CorporationInventors: Garry E. Jacobs, Steven W. Stupin, Robert W. Kuskie, Robert A. Logman
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Patent number: 6062547Abstract: Provided is a quench vessel containing at least two separate internal vessels. A receiving liquor is contained in the first internal vessel and a washing liquid bath is contained in a second internal vessel.Type: GrantFiled: June 12, 1998Date of Patent: May 16, 2000Assignee: Kvaerner Pulping ABInventor: Bengt Nilsson
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Patent number: 6059961Abstract: A process and arrangement for contacting a moving bed of compact particulate material, usually catalyst, with a radial flow of fluid maintains an unconfined surface of catalyst particles in place by passing fluid axially into the upper surface of the bed and maintaining radial gas flow across an inlet screen at an elevation that is above the upper most elevation of perforations for withdrawing gas flow from the particulate bed. Two vertical screens confine the bed of catalyst. Perforations cover substantially the entire length of the inlet screen. The outlet portion of the screen has perforations that end below the top of the free surface of the catalyst bed and define an upper bed portion therebetween. The inlet screen directs gas flow radially across the inlet screen into an upper portion of the bed and cause at least partial axial flow of gas through the upper portion of the particle bed.Type: GrantFiled: April 27, 1998Date of Patent: May 9, 2000Assignee: UOP LLCInventors: William John Koves, Gary Alan Schulz, Robert John Sanger
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Patent number: 6054057Abstract: A system and method for treatment of a feed material includes a reactor chamber in a reactor vessel. The reactor vessel has a longitudinal axis which is vertically oriented so that gravitational forces act generally in a direction along the axis between a top and a bottom of the vessel. A feed material is introduced by a nozzle into the reactor chamber as a jet stream through the top end of the vessel. This jet stream causes back-mixing in the reactor chamber, contributing to rapid initiation of reaction and general down flow of material through the reactor chamber. The material in the reactor chamber can be quenched to dissolve sticky solids in the effluent before the effluent is discharged from the lower end of the vessel. Further, the reactor vessel can include a plug flow section to carry out additional reaction of the feed material.Type: GrantFiled: September 26, 1997Date of Patent: April 25, 2000Assignee: General AtomicsInventors: David A. Hazlebeck, Kevin W. Downey, Michael H. Spritzer
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Patent number: 6027609Abstract: A Pulp Mill Recovery installation for producing liquors containing different concentrations of recovered process chemicals or combustion gasses containing different concentrations of process chemicals from a spent liquor obtained from the production of pulp.Type: GrantFiled: May 2, 1997Date of Patent: February 22, 2000Assignee: Kvaener Pulping ABInventor: Bengt Nilsson
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Patent number: 6017497Abstract: An atomization roasting furnace for producing ferrite raw material powder includes an elongated roasting furnace body with a center burner located at the top end thereof. At least three liquid spray nozzles are located in an expansion slope portion below the center burner circumferentially with respect to the center burner. A quencher, located below the elongated roasting furnace body, has a top end connected to a bottom end of the elongated roasting furnace body. Quencher nozzles are located adjacent the top end of the quencher.Type: GrantFiled: August 22, 1997Date of Patent: January 25, 2000Assignee: Nippon Steel CorporationInventors: Katsushige Matsuzaki, Tatsunori Sunagawa, Kenji Kawahito, Junji Omori, Yoshitaka Yamana, Shoichi Osada, Kiyoshi Aritome, Yoshimasa Ikeda, Izumi Matsushita, Wataru Ohashi, Kaoru Ito, Fumihiko Hasegawa, Shinya Nariki, Michimasa Sasaki, Noritane Tsugane, Toshiaki Kurihara
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Patent number: 5976319Abstract: The intensity of explosions as a result of hot (750-820 degrees C.) smelt from a pulp mill recovery boiler impacting cool (70-100 degrees C.) liquid in a dissolving tank is minimized by more effectively disrupting the flow of smelt from a spout free end tip into the tank. First and second nozzles which issue jets of disrupting fluid (such as steam or green liquor) are positioned on opposite sides of the center line of the spout, and are positioned and spaced from the spout tip and each other so that the jet emanating from at least one of the nozzles always intersects the flow of smelt from the spout even though the smelt flow path varies during normal operation of the recovery boiler.Type: GrantFiled: November 26, 1997Date of Patent: November 2, 1999Assignee: Ahlstrom Machinery OyInventors: Raimo Paju, Jukka Savolainen, Markku Tanttu
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Patent number: 5976203Abstract: A synthesis gas generator with a combustion chamber and quench chamber for generating, cooling and cleaning gases, which are generated by partial oxidation in the combustion chamber of the synthesis gas generator. The combustion chamber (3) and the quench chamber (7) are separate chambers connected by a flow channel (6). Nozzle assemblies (10, 11) with nozzle heads (9, 34), which spray in a quenching medium (8), are arranged in the gas inlet area of the quench chamber (7). The quench zone within the quench chamber (7) is joined by a useful gas-quenching medium-mixing zone. A cone (20) is located at the outlet of the quench chamber. This cone is followed by a water bath (21). The useful gas leaves the synthesis gas generator after deflection by 180.degree. in the rear-side area of the cone (20) via gas outlet openings (23).Type: GrantFiled: April 7, 1998Date of Patent: November 2, 1999Assignee: Metallgesellschaft AktiengellschaftInventors: Wolfgang Deeke, Wolfram Gruhlke, Jurgen Heering, Klaus Kohnen
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Patent number: 5972206Abstract: A flexible steam cracking process for hydrocarbon feeds comprises injection of particles with an average size of between 0.02 mm and 4 mm, at a circulation rate in indirect transfer line exchangers (4) of 20 to 180 m/s, and in a sufficient quantity to limit the increase in temperature at the outlet to the exchangers (4) to a value of less than 100.degree. C. per month, into at least one point upstream of an indirect transfer line exchanger (4), cracking zone (2) remaining in communication with downstream means (6) for the treatment of cooled effluents. At least 70% by weight of the quantity of injected particles is introduced between the outlet to the cracking zone (2) and the tubes of the indirect transfer line exchanger (4). Chemical decoking is carried out in the tubes of the cracking zone at time intervals of less than 4 months by establishing accelerated coke gasification conditions, for example by injecting compounds which catalyse gasification by steam, or by decoking in air and/or steam.Type: GrantFiled: June 25, 1997Date of Patent: October 26, 1999Assignees: Institut Francais du Petrole, Procedes Petroliers et Petrochimiques, Eric LengletInventors: Eric Lenglet, Paul Broutin, Jean-Pierre Burzynski, Herve Cazor, Roland Huin
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Patent number: 5965013Abstract: A facility and a process for steam cracking include controlled injection of solid particles into a transfer line exchanger (3). The particles are injected via injection lines, numbering between 1 and 8, just upstream of an impact-diffuser (6) comprising solid surfaces disposed on either side of the line for transfer of the cracked gases to the exchanger; this impact-diffuser is located in the inlet cone (2) of the exchanger, is permeable to the gases via a plurality of passages and at least 70% opaque viewed from the transfer line.Type: GrantFiled: June 25, 1997Date of Patent: October 12, 1999Assignee: Institut Francais Du Petrole Procedes Petroliers et Petrochimques Eric LengletInventors: Eric Lenglet, Paul Broutin, Jean-Pierre Burzynski, Herve Cazor, Roland Huin
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Patent number: 5899241Abstract: A linked multilayer woven fabric for use in the production of structural composite materials has a base weave comprising twenty-eight weft yarns which are distributed in eight columns containing alternately four superimposed yarns and three superimposed yarns such that they are in a staggered arrangement on seven levels, and twelve warp yarns which are arranged in four parallel planes each containing three superimposed parallel warp yarns.Type: GrantFiled: February 3, 1998Date of Patent: May 4, 1999Assignees: Societe Nationale D'Etude et de Construction de Moteurs D'Aviation "Snecma", Societe Cotton Textiles Pour Materiaux Innovants "CTMI"Inventors: Laurent Jean Pierre David, Jean Pierre Marie Dessinges, Fran.cedilla.ois Billaut
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Patent number: 5851497Abstract: A gasifier (10) for partially combusting a carbonaceous fuel mixture in the combustion chamber (13) of the gasifier (10). The latter includes a water bath (26) into which the hot effluent or the products of combustion are immersed, including a synthetic gas. The products of combustion are directed into the bath (26) by way of a constricted throat section (31). To avoid excessive erosion action and/or thermal shock to the throat section (31) as a result of exposure to the effluent's high temperatures, the throat section (31) is structured with an internal framework of pipes (32). The flamework (32) is communicated with a pressurized source of a cooling fluid (42), preferably water, whereby to cool the throat section (31) sufficiently to counteract the ill effects of exposure to contact with the high temperature effluent.Type: GrantFiled: July 17, 1996Date of Patent: December 22, 1998Assignee: Texaco Inc.Inventors: Donald Duane Brooker, James Samuel Falsetti, James Kenneth Wolfenbarger, Dinh-Cuong Vuong
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Patent number: 5824121Abstract: A gasification reactor has a mixing tube above it in a common pressure vessel and the mixing tube is provided with a gas cooling heat exchanger. A driving gas feeder draws a portion of the mixture of quenching gas and raw gas from the mixing tube, passes it through the gas cooling heat exchanger and feeds it as a quenching gas to the raw gas at the inlet side of the mixing tube. At least one further heat exchanger in the same pressure vessel or in another pressure vessel, receives the mixture of raw and quenching gas beyond the mixing tube.Type: GrantFiled: September 20, 1995Date of Patent: October 20, 1998Assignee: Krupp Koppers GmbHInventor: Johannes Kowoll
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Patent number: 5763544Abstract: Method and apparatus for effectively and safely using cryogenic liquid to cool a reactor vessel housing an exothermic reaction wherein the cryogenic liquid is subcooled, valved into the reactor in a downward direction, and shielded by annular coaxial shielding gas upon injection into the reactor.Type: GrantFiled: January 16, 1997Date of Patent: June 9, 1998Assignee: Praxair Technology, Inc.Inventors: Alan Tat Yan Cheng, Deepak Lumba
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Patent number: 5749937Abstract: A fast quench reaction includes a reactor chamber having a high temperature heating means such as a plasma torch at its inlet and a restrictive convergent-divergent nozzle at its outlet end. Reactants are injected into the reactor chamber. The resulting heated gaseous stream is then rapidly cooled by passage through the nozzle. This "freezes" the desired end product(s) in the heated equilibrium reaction stage.Type: GrantFiled: March 14, 1995Date of Patent: May 12, 1998Assignee: Lockheed Idaho Technologies CompanyInventors: Brent A. Detering, Alan D. Donaldson, James R. Fincke, Peter C. Kong
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Patent number: 5648051Abstract: An apparatus for quenching in hydroprocessing of a hydrocarbon feed stream, which provides a substantially continuous flow of uniformly distributed hydrogen and hydrocarbon liquid across a densely packed catalyst bed which substantially fills the entire volume of a reactor vessel. Catalyst are selected to be essentially the same density, shape and size at a design feed rate of liquids and gas to prevent ebullation of the packed catalyst bed at the design feed rates. The liquid and gas components of the hydrocarbon feed stream flow into the bed of catalyst and a quenching medium, which is preferably a liquid, is injected into the bed of catalyst. Injection of a liquid quench reduces the gas component of the hydrocarbon feed stream while simultaneously increasing the residence time and reducing the liquid velocity of the liquid component of the hydrocarbon feed stream within the substantially packed bed of catalyst.Type: GrantFiled: June 6, 1995Date of Patent: July 15, 1997Assignee: Chevron U.S.A. Inc.Inventors: Harold J. Trimble, Bruce E. Reynolds, Robert W. Bachtel, Robert J. Klett, David N. Brossard, David E. Earls
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Patent number: 5589144Abstract: The present invention relates to a thermal barrier coating applied to the inside surface of a catalytic converter and intake pipe between the manifold of an internal combustion engine and the catalytic converter. The catalytic converter and intake pipes are generally formed in two halves to facilitate an effective means by which the thermal barrier coating can be sprayed onto the inside surface by an arc plasma source prior to combining the individual halves of the catalytic converter or intake pipe.Type: GrantFiled: May 1, 1990Date of Patent: December 31, 1996Inventors: John E. Filippi, John A. Golen
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Patent number: 5554347Abstract: The invention relates to an apparatus comprising a reactor, elongated along one axis, preferably of square or rectangular cross section. The reactor has, at one extremity, at least one supply line for at least one reactant and at least one evacuation outlet at the other extremity for removal of produced effluents. In a first zone (near the first extremity of the reactor), a plurality of heat exchangers, substantially parallel to each other, are disposed in substantially parallel layers perpendicular to the reactor axis, thereby defining spaces or passages for circulation of reactant(s) and/or effluents between the heat exchangers and/or layers formed by the heat exchanger. The heat exchangers are adapted to exchange heat in the passages through successive transverse sections, which are independent and substantially perpendicular to the reactor axis.Type: GrantFiled: February 2, 1995Date of Patent: September 10, 1996Assignees: Institut Francais Du Petrole, Gaz De FranceInventors: Christian Busson, Henri Delhomme, Laure Gollion, Jean Pierre Cassagne
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Patent number: 5552039Abstract: A high pressure and high temperature reactor, especially operating under supercritical water conditions combined with corrosive atmosphere. The reactor comprises a reaction chamber and a pressure vessel, which surrounds the reaction chamber. It has high integrity since it has only one penetration in the pressure vessel, and its size is minimized due to induced turbulent flow of the ignited reaction mixture.Type: GrantFiled: July 13, 1994Date of Patent: September 3, 1996Assignee: RPC Waste Management Services, Inc.Inventors: Roy N. McBrayer, Jr., James E. Deaton, James M. Eller
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Patent number: 5464592Abstract: A gasifier for partially combusting a carbonaceous fuel mixture in the combustion chamber of the gasifier. The latter includes a water bath into which the hot effluent or products of combustion are immersed, including a synthetic gas. The products of combustion are directed into the bath by way of a constricted throat section. To avoid excessive erosion action and/or thermal shock to the throat section as a result of exposure to the effluent's high temperatures, the throat section is structured with an internal framework of pipes. The framework is communicated with a pressurized source of a cooling fluid, preferably water, whereby to cool the throat section sufficiently to counteract the ill effects of exposure to contact with the high temperature effluent.Type: GrantFiled: November 22, 1993Date of Patent: November 7, 1995Assignee: Texaco Inc.Inventors: Donald D. Brooker, James S. Falsetti, James K. Wolfenbarger, Dinh-Cuong Vuong
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Patent number: 5401472Abstract: An apparatus for producing high surface area active carbons in a safe and commercially advantageous manner by the alkali metal hydroxide-based activation method is provided. Using pushers (9a-k), the apparatus circulates containers (C) along a container travel line (8) connecting the elements: material feeding section (1).fwdarw.inlet side gas replacement chamber (2).fwdarw.tunnel kiln (3).fwdarw.cooling zone (4).fwdarw.water injection chamber (5).fwdarw.outlet side gas replacement chamber (6).fwdarw.reaction mixture discharge port (7) to form a closed circuit. During the travel of the containers, a series of steps is performed, namely the steps of charging of the containers with raw materials (carbonaceous material and alkali metal hydroxide-water mixture), dehydration, activation of the carbonaceous material with the alkali metal hydroxide, cooling, water injection and discharge of the reaction mixture.Type: GrantFiled: April 29, 1993Date of Patent: March 28, 1995Assignee: Kansai Netsukagaku Kabushiki KaishaInventors: Masahiro Kawakami, Toshiro Otowa, Mamoru Shiraishi, Kazuhiko Higuchi
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Patent number: 5380500Abstract: A process and apparatus for the separation of vaporous heavy metal compounds from a carrier gas wherein the heavy metal compounds are cooled and desublimed. An apparatus for carrying out this process has a melting furnace with a discharge opening for a gas/vapor mixture, which leads to a cooling device. Vaporous heavy metal compounds can be separated from a carrier gas on a large industrial scale. In addition, the apparatus for carrying out this process is easy to operate. The gas/vapor mixture is turbulently mixed immediately after the discharge from the furnace in a mixing section with cold air and is thus cooled. During this cooling, the vaporous heavy metal compounds desublime and are filtered as particles in a filter.Type: GrantFiled: November 12, 1993Date of Patent: January 10, 1995Assignee: ABB Gadelius KKInventors: Michael Hirth, Joachim Jochum, Harald Jodeit, Christian Wieckert
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Patent number: 5352428Abstract: A process and apparatus are disclosed to achieve high per-pass synthesis conversion of ammonia. A nitrogen/hydrogen synthesis gas mixture is passed sequentially through a plurality of catalyst beds. The effluent from a subsequent catalyst bed is cooled by direct quench with a partially reacted gas which has passed through at least a first catalyst bed.Type: GrantFiled: August 21, 1992Date of Patent: October 4, 1994Assignee: C.F. Braun, Inc.Inventors: Mukund L. Bhakta, Bernard J. Grotz
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Patent number: 5324486Abstract: Apparatus and process for compressing and quenching a cracked gas stream from a hydrocarbon cracking furnace including the step of feeding furnace output directly into an ejector in the effluent line, the ejector acting to quench and compress the effluent by injection of pressurized motive fluid into the ejector thereby rapidly mixing the motive fluid with the effluent for quick quenching and compression to prevent coke build-up and allow efficient heat exchanger and low pressure furnace operation.Type: GrantFiled: January 29, 1992Date of Patent: June 28, 1994Inventor: Gaetano Russo
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Patent number: 5204069Abstract: Nozzles for directing a jet of steam against a spout flow stream of sodium recovery boiler smelt are secured to an articulating anchor mount for the purpose of maximizing the shattering impact of the steam jet upon the smelt flow stream under a wide range of boiler operating conditions.Type: GrantFiled: October 7, 1991Date of Patent: April 20, 1993Assignee: Westvaco CorporationInventors: Wendell L. Paxton, Gary W. Waddell
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Patent number: RE37853Abstract: A fast quench reaction includes a reactor chamber having a high temperature heating means such as a plasma torch at its inlet and a restrictive convergent-divergent nozzle at its outlet end. Reactants are injected into the reactor chamber. The resulting heated gaseous stream is then rapidly cooled by passage through the nozzle. This “freezes” the desired end product(s) in the heated equilibrium reaction stage.Type: GrantFiled: May 11, 2000Date of Patent: September 24, 2002Assignee: Betchel BWXT Idaho, LLCInventors: Brent A. Detering, Alan D. Donaldson, James R. Fincke, Peter C. Kong