Abstract: The present invention relates to a method for preparing hierarchical zeolites, including the steps of preparing a first mixture solution including a structure-directing agent, an alumina precursor and a pH controller; preparing a second mixture solution by injecting a silica precursor into the first mixture solution; preparing an aqueous solution including a surfactant; preparing a third mixture solution by injecting the aqueous solution into the second mixture solution; and drying and heat-treating the third mixture solution. According to the present invention, hierarchical zeolites having a uniform morphology can be prepared, and thus hierarchical zeolites having improved activity are provided.

Abstract: The method for recycling carbon dioxide according to the present invention includes: injecting a reaction gas containing carbon dioxide and a carbon raw material into a rotary heating furnace; reacting the reaction gas and the carbon raw material with each other in the rotary heating furnace to generate a hydrocarbon precursor containing carbon monoxide; and converting the hydrocarbon precursor into a hydrocarbon compound, thereby exhibiting excellent conversion rate of carbon dioxide.

Abstract: A method for producing a polishing composition including: preparing a first dispersion liquid by mixing a dispersing element containing abrasive grains and a dispersing medium with a pH adjusting agent, and changing the pH of the dispersing element so as to pass an isoelectric point of the abrasive grains; and preparing a second dispersion liquid by mixing the first dispersion liquid with an electrical conductivity adjusting agent.

Abstract: Products derived from and methods of micelle templating that allow for orthogonal control over structural features.

Abstract: Catalyst and use of the catalyst comprising a molecular sieve belonging to the ABC-6 framework family with disorder in the ABC stacking sequence essentially composed of double-six-ring periodic building units and having a mole ratio of silicon oxide to aluminum oxide from about 8 to about 60.

Abstract: A method for the preparation of a molecular sieve belonging to the ABC-6 framework family with disorder in the ABC stacking sequence essentially composed of double-six-ring periodic building units and having a mole ratio of silicon oxide to aluminum oxide from about 8 to about 60.

Abstract: A molecular sieve belonging to the ABC-6 framework family with disorder in the ABC stacking sequence essentially composed of double-six-ring periodic building units and having a mole ratio of silicon oxide to aluminum oxide from about 8 to about 60.5.

Abstract: The present invention relates to a hydrocracking catalyst based on hierarchically porous beta-zeolite, a method of preparing the same, and a method of producing bio-jet fuel from triglyceride-containing biomass by use of the hydrocracking catalyst, and includes methods comprising preparing a hydrocracking catalyst by supporting a metallic active component on a hierarchically porous beta-zeolite support, and converting n-paraffins, produced from triglyceride-containing biomass, into bio-jet fuel by hydrocracking in the presence of the prepared hydrocracking catalyst. When the hydrocracking catalyst based on hierarchically porous beta-zeolite is used, the residence time of the reactant and the product in the zeolite crystals may be reduced due to additional mesopores formed in the zeolite, and thus bio-jet fuel may be produced in high yield from n-paraffin feedstock produced from triglyceride-containing biomass.

Abstract: Disclosed are method for synthesizing zeolites by using structure directing agent having benzyl groups and zeolites synthesized therefrom. A zeolite having various effects can be produced by using a material including a structure directing agent containing various benzyl groups, and raw material with various SiO2/Al2O3 molar ratios as alumina and silica source.

Abstract: Provided are a novel form of AFX zeolite, a novel synthesis technique for producing pure phase small pore zeolites, a novel synthesis method for producing a zeolite with an increased Al pair content, a catalyst comprising the AFX zeolite in combination with a metal, and methods of using the same.

Abstract: The present invention provides a barium sulfate spherical composite powder that has significantly high strength and excellent texture, and achieves high haze while maintaining high total light transmittance, and a method for producing such a composite powder. The present invention relates to a method for producing a barium sulfate spherical composite powder, which is a method for producing a spherical composite powder of barium sulfate and silica, the method comprising the steps of (1) preparing a slurry containing particulate barium sulfate and a silica sol, (2) spray-drying the slurry, and (3) firing a dry substance obtained in the step (2).

Abstract: A reactor system may comprise a housing; and a condensation catalyst layer within the housing comprising a condensation catalyst comprised of at least one of a base-substituted zeolite, a stannous salt, or a phosphonitrile chloride. The condensation catalyst layer may be configured to catalyze a condensation reaction of a plurality of silane diols in water flowing through the housing into a plurality of siloxanes.

Abstract: This invention describes the self-assembly of meso(nano)porous silica particles from inorganic an inexpensive silica precursor, sodium silicate. The particles have a well defined shape, high surface area, and high uniformity of the pore size, the properties that are typically found for high quality mesoporous material synthesized from organic silica precursors. The disclosure illustrates a synthesis of hard spheres, discoids, and a mixture comprising discoids, gyroids and fibers, termed as origami.

Abstract: A novel synthetic crystalline molecular sieve material, designated SSZ-113, can be synthesized using 1,3-bis(2,3-dimethyl-1H-imidazolium)propane dications as a structure directing agent. SSZ-113 may be used in organic compound conversion and/or sorptive processes.

Abstract: The exhaust gas cleaning catalyst according to the present invention is provided with a cylindrical substrate 10 and a catalyst coat layer 20 formed on the surface of the substrate 10. A ratio of the length L in the cylindrical axis direction of the substrate 10 and the diameter D of a cross section orthogonal to the cylindrical axis direction is denoted by (L/D)?0.8. The coat density of the catalyst coat layer 20 differs between an upstream side portion 10a that includes the exhaust gas inlet-side end 16 of the substrate 10 and a downstream side portion 10b that includes the exhaust gas outlet-side end 18 of the substrate 10. The coat density A in the upstream side portion 10a is lower than the coat density B in the downstream side portion 10b (A<B).

Abstract: The invention provides mixed matrix membranes (MMMs) for olefin/paraffin separation and methodes of making and using the same. The MMMs comprise a continuous polymer matrix with metal doped zeolite nano-particles. A separation technology based upon the composite membranes is effective for propylene and other olefin separation from olefin/paraffin mixtures, and the separation is more energy-efficient than the conventional cryogenic technique.

Abstract: The present application includes iron catalysts promoted with Mo, K and optionally Cu on a multi-walled carbon nanotube (MWCNT) support for high molecular weight hydrocarbon synthesis from synthesis gas.

Abstract: An isoalkane alkylate base oil and a process to make an isoalkane alkylate base oil having a VI higher than 90, comprising: a. selecting an isoalkane feed containing at least one isoalkane and an olefin feed containing at least one linear olefin such that a combined carbon number of the isoalkane feed and the olefin feed is from 20 to 60; and b. alkylating the isoalkane feed with the olefin feed in the presence of an acidic alkylation catalyst under alkylation conditions to make the isoalkane alkylate base oil having the VI higher than 90; wherein the isoalkane alkylate base oil has a kinematic viscosity at 100° C. from 2 to 30 mm2/s, a pour point less than 0° C., and a bromine index less than 2000 mg Br/100 g.

Abstract: A method for preparing a composition includes silico/germano-metal particles functionalized by at least one organic group, which involves:—carrying out a hydrothermal treatment of a hydrogel precursor of the silico/germano-metal mineral particles, and—preparing a hydrogel including silico/germano-metal particles having at least one organic group by co-precipitation in an aqueous medium. A composition including functionalized silico/germano-metal mineral particles of which 1% to 75% of the silicon atoms and/or of the germanium atoms are covalently bonded to at least one organic group is also described.

Abstract: A method is provided for the synthesis of AFX framework type molecular sieves using a structure directing agent selected from one or more of hexamethonium dications, 1,6-bis(N-methylpyrrolidinium)hexane dications, and 1,4-bis(N-methylpyrrolidinium)butane dications.

Abstract: An object of the present invention is to provide an AFX zeolite having a novel structure. An AFX zeolite having a lattice spacing d of a (004) plane being not less than 4.84 ? and not greater than 5.00 ?, and a molar ratio of silica to alumina being not less than 10 and not higher than 32. Such an AFX zeolite can be produced by a production method comprising a crystallization step of crystallizing a composition at a temperature of not lower than 160° C.; the composition containing a silicon source, an aluminum source, a 1,3-di(1-adamantyl)imidazolium cation, and an alkali metal; a molar ratio of hydroxide ions to silica being less than 0.25 or a molar ratio of silica to alumina being not higher than 27; and a molar ratio of the 1,3-di(1-adamantyl)imidazolium cation to silica being less than 0.20.

Abstract: The invention relates to a method of preparing SAPO-56, (AFX) using a lower alkyl amine, preferably trimethylamine, and a 1,4-diazabicyclo [2.2.2]octane derivative, preferably comprising either 1,4-(1,4-diazabicyclo[2.2.2]octane)butyl cations or 1,5-(1,4-diazabicyclo[2.2.2]octane)pentyl cations, as structure directing agents (SDAs). A lower alkyl ammonium hydroxide, such as tetrabutylammonium hydroxide (TBAOH), can be used to control the pH. The invention also relates to SAPO-56 comprising a lower alkyl amine, such as trimethylamine, and a 1,4-diazabicyclo [2.2.2]octane derivative, such as a compound comprising either 1,4-(1,4-diazabicyclo[2.2.2]octane)butyl cations or 1,5-(1,4-diazabicyclo[2.2.2]octane) pentyl cations.

Abstract: The present specification provides a conductive structure body and a method for manufacturing the same.

Abstract: Monolithic nanoporous material, which is self-standing (i.e. self-supported or cohesive), solid and transparent, essentially devoid of cracks, transparent to UV radiation, obtained by the Sol-Gel process, the material having a basic nature and including a reagent capable of generating a stained product by forming a bond with phenol, a basic compound or mixture of basic compounds and a compound or mixture of oxidant compounds, method for preparation and use in the detection and in the selective depollution of phenol or one of its derivatives.

Abstract: The present invention relates to a cosmetic or dermatological composition of sol/gel type for making up and/or caring for keratin materials characterized in that it comprises the product resulting from the reaction: (a) of at least one alkoxysilane monomer or oligomer of formula (I) R1xSi(OR2)(4-x) or of formula (II) [R1y (OR2)z SiO ((4-?-?)/2)]? in which R1 represents, independently, a nucleophilic group other than a hydroxyl, or a (Ci-C2o)alkyl group, R2 represents, independently, a (Ci-Cio)alkyl group, and (b) of an amount of water corresponding to a number of moles of water, determined according to the following equation: X?(llAlkoxysilanes×llbAlkoxy groups)/nH2o with nH2o=Number of moles of water, nAikoxysiianes=Number of moles of alkoxysilane compounds, nbAikoxy groups=Weighted mean of the number of alkoxysilane groups per alkoxysilane compound, and X is a number greater than 2. It also relates to an associated cosmetic process and an associated kit for coating keratin materials.

Abstract: Silica particles, and methods of making and using silica particles are disclosed herein. In some embodiments, the silica particles are hollow, include an outer shell portion having a mesoporous structure, and have a pore volume of at least 4 cm3/g. In some embodiments, the silica particles include an outer shell portion having a mesoporous structure forming a cavity, the silica particles have an average pore diameter of 3 to 100 nm, and at least a portion of the silica particles include one or more core nanoparticles within the cavity. Silica particles as disclosed herein can be useful in a wide variety of applications such as selective separations (e.g., gas separations or purifications) based on structure.

Abstract: An AFX framework type zeolite having a SiO2/Al2O3 molar ratio of greater than 50 is disclosed. The high-silica AFX framework type zeolite is synthesized from a reaction mixture having high silica and low hydroxide concentrations in the presence of an organic structure directing agent comprising 1,3-bis(1-adamantyl)imidazolium cations.

Abstract: The present invention relates to a titanium silicalite molecular sieve, wherein the crystal grain of the titanium silicalite molecular sieve has a ratio of (surface Si/Ti ratio):(bulk Si/Ti ratio) being larger than 1.1 and less than 5.

Abstract: A process for preparing a composition including synthetic mineral particles, in which a hydrogel which is a precursor of the synthetic mineral particles is prepared via a coprecipitation reaction between at least one compound including silicon, and at least one compound including at least one metal element, characterized in that the coprecipitation reaction takes place in the presence of at least one carboxylate salt of formula R2—COOM? in which: —M? denotes a metal chosen from the group made up of Na and K, and —R2 is chosen from H and alkyl groups including fewer than 5 carbon atoms. A composition including synthetic mineral particles which is obtained by such a process is also described.

Abstract: The present disclosure is directed to processing for preparing crystalline pure-silica and heteroatom-substituted LTA frameworks in fluoride media using a simple organic structure-directing agent (OSDA), having a structure of Formula (I): where substituents R1 to R9 are defined herein. Aluminosilicate LTA is an active catalyst for the methanol to olefins reaction with higher product selectivities to butenes as well as C5 and C6 products than the commercialized catalysts. Titanosilicate LTA is an active catalyst for the epoxidation of allyl alcohol using aqueous H2O2.

Abstract: This invention describes the encapsulation of and self-assembly of meso (nano) porous silica particles from inorganic an inexpensive silica precursor, sodium silicate. The particles have a well defined shape, high surface area, and high uniformity of the pore size, the properties that are typically found for high quality mesoporous material synthesized from organic silica precursors. The disclosure illustrates a synthesis of hard spheres, discoids, and a mixture comprising discoids, gyroids and fibers, termed as origami.

Abstract: In a process for the synthesis of a crystalline molecular sieve material having the EUO framework type, a synthesis mixture is provided suitable for the formation of an EUO framework type molecular sieve and comprising N,N,N,N?,N?,N?-hexamethylhexanediammonium, Q, cations and a colloidal suspension of seed crystals of an EUO framework type molecular sieve. The synthesis mixture is crystallized and an EUO framework type molecular sieve in the form individual crystals and/or aggregates of crystals having an average size, d50, as measured by laser scattering, of less than 15 ?m is recovered from the synthesis mixture.

Abstract: Catalyst composition useful in the catalytic dewaxing of a waxy hydrocarbon feedstock which catalyst composition includes a mixture of zeolite EU-2 and titania and may further include a noble metal. The zeolite EU-2 has a molar bulk ratio of silica-to-alumina (SAR) of greater than 100:1. The zeolite or mixture may have been dealuminated such as by acid leaching using a fluorosilicate salt or by steam treating.

Abstract: A method for preparing a NaY molecular sieve having a high silica-to-alumina ratio, wherein deionized water, a silicon source, an aluminum source, an alkali source, and ILs as a template agent are mixed to obtain an initial gel mixture; the initial gel mixture is maintained at a proper temperature and aged, then fed into a high pressure synthesis kettle for crystallization; the solid product is separated and dried, to obtain the NaY molecular sieve having a high silica-to-alumina ratio, wherein the ILs is a short-chain alkylimidazolium ionic liquid, the template agent is less volatile, and the resultant high-silicon Y molecular sieve has a high crystallinity and a silica-to-alumina ratio of 6 or more.

Abstract: Described is a process for the production of a zeolitic material having an MFI, MEL, and/or MWW-type framework structure comprising YO2 and X2O3. The process comprises (1) preparing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and one or more solvents; (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material having an MFI, MEL and/or MWW-type framework structure; and (3) impregnating the zeolitic material obtained in step (2) with one or more elements selected from the group of alkaline earth metals. Y is a tetravalent element, and X is a trivalent element. The mixture crystallized in step (2) contains 3 wt.-% or less of one or more elements M based on 100 wt-% of YO2, wherein M stands for sodium.

Abstract: A method for making a new crystalline molecular sieve designated SSZ-27 is disclosed. SSZ-27 is synthesized using a hexamethyl [4.3.3.0] propellane-8,11-diammonium cation as a structure directing agent.

Abstract: A submerged burner for a glass- or rock-melting furnace, including a plurality of in-line injectors, each injector including a cylinder-shaped mixing chamber, with an ejection orifice, a fuel-supply duct and an oxidant-supply duct opening into the mixing chamber at the cylinder jacket in a direction causing a tangential flow of the fuel and of the oxidant relative to the cylinder jacket, and a duct system making it possible for a coolant to flow inside the burner, and, preferably on either side of the alignment of injectors, placed parallel to and all along the latter, solid metal sides rising from the injectors, and protective partitions situated on the top of the solid metal sides.

Abstract: A new crystalline molecular sieve designated SSZ-27 is disclosed. SSZ-27 is synthesized using a hexamethyl [4.3.3.0] propellane-8,11-diammonium cation as a structure directing agent.

Abstract: Described is an iron-containing zeolite wherein the number of iron sites, based on the zeolite, is greater than the number of cationic positions in the zeolite. Also described is an iron-containing zeolite preparable by gas phase reaction with iron pentacarbonyl, said zeolite having a greater specific surface area than iron-containing zeolites prepared analogously by ion exchange and/or being more hydrothermally stable than iron-containing zeolites prepared analogously by ion exchange, or wherein the number of iron clusters larger than 10 nm is less than 15% by weight, based on the total amount of iron. Further described is a process for preparing an iron-containing zeolitic material, which comprises doping with iron by means of a gas phase reaction using iron pentacarbonyl. Further described is a process for catalytic reduction of nitrogen oxides using catalysts comprising said iron-containing zeolitic materials.

Abstract: An article including a polymer element including a polymer, and inorganic particles having a concentration gradient which decreases in concentration from at least one surface of the polymer element to the inside thereof, wherein the inorganic particles have a refractive index that is greater than or equal to the refractive index of air and less than the refractive index of the polymer.

Abstract: The invention provides a stable oxide material system for a capacitor, electronic device or a memory device having an effective high-k value with an effective zero alpha while exhibiting low leakage current density. The stable oxide material comprises Mx-Si1-xO2, wherein the elements M & Si are mixed such that the insulator layer comprises staggered edge-linked SiO2-MO2 bonding chains to provide a stable 3-dimensional single crystal system.

Abstract: Disclosed herein are a catalyst, a preparation process thereof, and a process of epoxidizing olefin using the catalyst. The catalyst contains a binder and a titanium silicate as specified. The catalyst disclosed herein has high strength, and shows high catalytic activity in the epoxidation of olefins.

Abstract: Metal silicates or phosphates are deposited on a heated substrate by the reaction of vapors of alkoxysilanols or alkylphosphates along with reactive metal amides, alkyls or alkoxides. For example, vapors of tris(tert-butoxy)silanol react with vapors of tetrakis(ethylmethylamido)hafnium to deposit hafnium silicate on surfaces heated to 300° C. The product film has a very uniform stoichiometry throughout the reactor. Similarly, vapors of diisopropylphosphate react with vapors of lithium bis(ethyldimethylsilyl)amide to deposit lithium phosphate films on substrates heated to 250° C. Supplying the vapors in alternating pulses produces these same compositions with a very uniform distribution of thickness and excellent step coverage.

Abstract: A method for preparing crystalline cobalt nitrate. The method includes: 1) calcining a spent Co/SiO2 catalyst, cooling the calcined material to room temperature, and grinding it to yield a powder; 2) heating the powder in a fluidized bed reactor; 3) adding the heated powder into excess dilute nitric acid solution and filtering to obtain a cobalt nitrate solution; 4) adjusting the pH value of the cobalt nitrate solution to 1.5, adding a preheated oxalic acid solution, adjusting a pH value of the resulting solution to 1.5, immediately filtering the resulting solution to yield a precipitate of cobalt oxalate, washing the precipitate of cobalt oxalate to yield a neutral filtrate; 5) drying the precipitate and calcining to yield cobalt oxide; 6) dissolving the cobalt oxide in nitric acid to yield a second cobalt nitrate solution; and 7) evaporating the second cobalt nitrate solution to obtain crystalline cobalt nitrate.

Abstract: A coating is described. The coating includes a metal oxide layer, which in turn includes a surface having a water contact angle greater than 90 degrees. A metal-oxide coating composition is also described. The composition includes effective amounts of a first type and a second of metals and an effective amount of oxygen to react with the first type and the second type of metals to produce a first type and a second type of metal oxides, both of which produce a structure that is greater than about 50% (by volume) amorphous.

Abstract: Provided is a method that enables a calcium silicate-based material to be produced more efficiently. The method of producing a calcium silicate-based material comprises: (1) a step of obtaining a reaction product by reacting raw materials containing a calcium component, a silicon component and an aluminum component in an aqueous medium; and (2) a step of forming calcium silicate by subjecting the reaction product to hydrothermal treatment.

Abstract: Techniques for controlling resistivity in the formation of a silicon ingot from compensated feedstock silicon material prepares a compensated, upgraded metallurgical silicon feedstock for being melted to form a silicon melt. The compensated, upgraded metallurgical silicon feedstock provides semiconductor predominantly of a single type (p-type or n-type) for which the process assesses the concentrations of boron and phosphorus and adds a predetermined amount of boron, phosphorus, aluminum and/or gallium. The process further melts the silicon feedstock with the boron, phosphorus, aluminum and/or gallium to form a molten silicon solution from which to perform directional solidification and maintains the homogeneity of the resistivity of the silicon throughout the ingot. A balanced amount of phosphorus can be optionally added to the aluminum and/or gallium. Resistivity may also be measured repeatedly during ingot formation, and additional dopant may be added in response, either repeatedly or continuously.

Abstract: The present invention relates to a method for producing inorganic oxide particles, comprising at least the following steps of: coagulating a dispersion obtained by carrying out the hydrolysis reaction and the polycondensation reaction of a metal alkoxide in the presence of a basic catalyst; filtering the dispersion to obtain particles; and drying the particles, wherein the step of coagulating the dispersion is carried out by adding a coagulant comprising at least one compound selected from the group consisting of carbon dioxide, ammonium carbonate, ammonium hydrogen carbonate and ammonium carbamate to the dispersion. The inorganic oxide particles obtained by the method of the present invention have high purity and are excellent in flowability.

Abstract: A process of treating a gas stream containing mercury and acid gas pollutants is disclosed. The process includes applying a sorbent composition into a gas stream in order to adsorb mercury containing compounds and acid gas pollutants. The sorbent composition includes a compound having the formula (SiO2)x(OH)yMzSaF.B. The combination of basic inorganic solids for the adsorption of acid gases, and metal sulfide-doped silica for the adsorption of mercury provides dual sorbent functionality, along with additional benefits for each individual sorbent: silica for moisture retention on the surface of the basic inorganic particle and adsorption of acid gas, which will improve metal sulfide performance at higher operating temperatures. The use of a hygroscopic solid effectively dries the metal sulfide-doped silica slurry without the use of filtration of drying equipment, providing significant economic benefit for the manufacture of metal sulfide-doped silica material.

Abstract: A method is provided for the synthesis of a mesoporous lithium transition metal compound, the method comprising the steps of (i) reacting a lithium salt with one or more transition metal salts in the presence of a surfactant, the surfactant being present in an amount sufficient to form a liquid crystal phase in the reaction mixture (ii) heating the reaction mixture so as to form a sol-gel and (iii) removing the surfactant to leave a mesoporous product. The mesoporous product can be an oxide, a phosphate, a borate or a silicate and optionally, an additional phosphate, borate or silicate reagent can be added at step (i). The reaction mixture can comprise an optional chelating agent and preferably, the reaction conditions at steps (i) and (ii) are controlled so as to prevent destabilization of the liquid crystal phase. The invention is particularly suitable for producing mesoporous lithium cobalt oxide and lithium iron phosphate.