Group Ivb Metal (ti, Zr, Or Hf) Patents (Class 423/608)
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Patent number: 7901657Abstract: The invention relates to amphiphilic, nanoscalar particles comprising lipophilic hydrolyzable groups on their surface. The invention also relates to methods for producing amphiphilic, nanoscalar particles and to compositions containing said particles.Type: GrantFiled: February 25, 2005Date of Patent: March 8, 2011Assignee: Leibniz-Institut Fuer Neue Materialien Gemeinnuetzige GmbHInventors: Ertugrul Arpac, Helmut Schmidt, Murat Akarsu
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Patent number: 7892447Abstract: Nanoplatelet forms of metal hydroxide and metal oxide are provided, as well as methods for preparing same. The nanoplatelets are suitable for use as fire retardants and as agents for chemical or biological decontamination.Type: GrantFiled: August 9, 2007Date of Patent: February 22, 2011Assignee: Aqua Resources CorporationInventor: Orville Lee Maddan
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Publication number: 20110020213Abstract: An object is to provide a novel anatase titanium oxide having especially high photocatalytic activity as a photocatalyst useful as a material for environmental clean-up, such as removal of toxic substances, deodorization and decomposition of malodorous substances, prevention of fouling and sterilization, and a method of producing such an anatase titanium oxide. There is provided a titanium oxide having a reflectance of 80% or lower with respect to light having a wavelength of 400 nm to 700 nm. There is also provided a method of producing an anatase titanium oxide, comprising creating pulsed plasma by an electric current of lower than 5 amperes between titanium electrodes in water to oxidize a titanium. Preferably, the titanium oxide has a percentage weight loss of 1.0% or lower when heated at a temperature within the range of 400° C. to 800° C., and has the anatase structure or the anatase and rutile structures.Type: ApplicationFiled: December 26, 2008Publication date: January 27, 2011Applicants: NATIONAL UNIVERSITY CORP KUMAMOTO UNIVERSITY, KURARAY CO., LTD.Inventors: Tsutomu Mashimo, Omurzak Uulu Emil, Sulaimankulova Saadat, Makoto Okamoto, Hideharu Iwasaki
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Patent number: 7871956Abstract: This invention relates to a cerium-zirconium-base composite oxide, which is useful, e.g., for the purification of exhaust gas discharged from combustion engines such as internal combustion engines and boilers and can release a high level of oxygen in a low temperature region, a method for producing the same, an oxygen storage/release component using the same, an exhaust gas purification catalyst, and an exhaust gas purification method. The cerium-zirconium-base composite oxide satisfies requirements (1) that the oxygen release initiation temperature is 380° C. or below, (2) that the oxygen release amount is not less than 485 ?mol/g, and further (3) that the oxygen release amount at 400° C. is not less than 15 ?mol/g.Type: GrantFiled: March 13, 2007Date of Patent: January 18, 2011Assignees: Daiichi Kigenso Kagaku Kogyo Co., Ltd., N.E. Chemcat CorporationInventors: Takahiro Wakita, Akira Kohara, Yasuharu Kanno, Hiroaki Omoto
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Patent number: 7867471Abstract: A process of producing a ceramic powder including providing a plurality of precursor materials in solution, wherein each of the plurality of precursor materials in solution further comprises at least one constituent ionic species of a ceramic powder, combining the plurality of precursor materials in solution with an onium dicarboxylate precipitant solution to cause co-precipitation of the ceramic powder precursor in a combined solution; and separating the ceramic powder precursor from the combined solution. The process may further include calcining the ceramic powder precursor.Type: GrantFiled: April 3, 2009Date of Patent: January 11, 2011Assignee: SACHEM, Inc.Inventor: Wilfred Wayne Wilson
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Publication number: 20110003085Abstract: A porous metal oxide is formed by creating a metal oxide material with a hydrolysis reaction in solution. The hydrolysis reaction or reaction products of a metal oxide precursor react simultaneously or in conjunction with a metal salt or a disassociation species of a metal salt. The metal oxide material is conditioned, and is refined to produce metal oxide particles having a porous structure containing crystallites.Type: ApplicationFiled: September 7, 2010Publication date: January 6, 2011Applicant: CARRIER CORPORATIONInventors: Treese Hugener-Campbell, Thomas Henry Vanderspurt, Wayde R. Schmidt, Steven M. Zhitnik
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Patent number: 7863215Abstract: Disclosed is a photocatalyst comprising a photocatalytically active base, and a silicon oxide film covering the base and substantially having no pores. The alkali metal content of the photocatalyst is not less than 1 ppm but not more than 1,000 ppm. Also disclosed is a method for producing such a photocatalyst wherein when a photocatalytically active base present in an aqueous medium is coated with a silicon oxide film by using a silicate, the pH of the aqueous medium containing both the photocatalytically active base and the silicate is maintained at 5 or below.Type: GrantFiled: February 14, 2006Date of Patent: January 4, 2011Assignee: Mitsui Chemicals, Inc.Inventors: Satoru Miyazoe, Takashi Nabeta, Nobuhiko Horiuchi
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Patent number: 7858064Abstract: The invention relates to a titanium aquo-oxo chloride and to a method for its preparation. The compound is in the form of crystals and has the following composition by weight: 26.91% Ti; 21.36% Cl; and 4.41% H, which corresponds to the formula [Ti8O12(H2O)24]Cl8.HCl.7H2O. The method of preparation consists in hydrolyzing TiOCl2 either in an atmosphere whose moisture content is maintained between 50 and 60%, or by an alkali metal carbonate A2CO3, in order to obtain a titanium aquo-oxo chloride. The compound is useful as a semiconductor element of a photovoltaic cell or as a photocatalyst in air or water purification treatments.Type: GrantFiled: April 29, 2004Date of Patent: December 28, 2010Assignee: Centre National de la Recherche ScientifiqueInventors: Luc Brohan, Hari Sutrisno, Eric Puzenat, Annabelle Rouet, Hélène Terrisse
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Publication number: 20100322836Abstract: The present invention discloses a continuous calcination vessel which can be used to prepare calcined chemically-treated solid oxides from solid oxides and chemically-treated solid oxides. A process for the continuous preparation of calcined chemically-treated solid oxides is also provided. Calcined chemically-treated solid oxides disclosed herein can be used in catalyst compositions for the polymerization of olefins.Type: ApplicationFiled: June 23, 2009Publication date: December 23, 2010Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LPInventors: Elizabeth A. Benham, Max P. McDaniel
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Patent number: 7851407Abstract: A method for producing a titanium dioxide photocatalyst is provided. The method uses a sol-gel process wherein acid and base catalysts are added in two separate steps. According to the method, a titanium dioxide photocatalyst with increased mesoporosity can be produced without the use of any particular additive. Further, an anatase structure is formed upon drying and is maintained even after high-temperature calcination. Further provided is a titanium dioxide photocatalyst produced by the method. Further provided is a titanium dioxide photocatalyst doped with sulfur and zirconium, which is produced by using the method. The doped titanium dioxide photocatalyst exhibits catalytic activity even under visible light and excellent surface characteristics to achieve improved photocatalytic activity.Type: GrantFiled: May 19, 2008Date of Patent: December 14, 2010Assignee: Kyungpook National University Industry-Academic Cooperation FoundationInventors: Tae Jeong Kim, Wha Jung Kim, Sun Woo Kim
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Patent number: 7846249Abstract: A pigment aqueous-medium dispersion and coating material which have no particle feeling and exhibit a highly excellent silky feeling, the pigment aqueous-medium dispersion is a dispersion of a photoluminescent pigment in an aqueous medium, characterized in that the photoluminescent pigment is flaky titanic acid obtained by treating layered titanate with acid and then reacting an organic basic compound with the treated layered titanate to delaminate, and the flaky titanic acid has an average longer diameter of 5 to 30 ?m and an average thickness of 0.5 to 300 nm.Type: GrantFiled: March 14, 2006Date of Patent: December 7, 2010Assignees: Otsuka Chemical Co., Ltd., Toyota Jidosha Kabushiki KaishaInventors: Kenji Kawazu, Susumu Umemura, Hiroyoshi Mori, Daisuke Suzuki, Minoru Yamamoto
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Patent number: 7842199Abstract: A proton conducting titanate includes titanate and a sulfonic acid group-containing moiety having proton conductivity introduced into the surface of the titanate, in which the sulfonic acid group-containing moiety is directly bound to the titanate via an ether bond (—O). A polymer nano-composite membrane includes the proton conducting titanate, and a fuel cell includes the polymer nano-composite membrane. The proton conducting titanate is provided with a sulfonic acid functional group having proton conductivity, which increases the proton conductivity of the polymer nano-composite membrane. The polymer nano-composite membrane includes the proton conducting titanate, and thus can have a controllable degree of swelling in a methanol solution, and the transmittance of the polymer nano-composite membrane can be reduced. The polymer nano-composite membrane can be used as a proton conducting membrane in fuel cells to improve the thermal stability, energy density, and fuel efficiency of the fuel cells.Type: GrantFiled: May 23, 2006Date of Patent: November 30, 2010Assignee: Samsung SDI Co., Ltd.Inventors: Hae-kyoung Kim, Jae-sung Lee, Young-kwon Kim, Hyuk Chang
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Publication number: 20100290945Abstract: Oxygen free, solution based zirconium precursors for use in ALD processes are disclosed for growing ZrO2 or other Zr compound films in a self-limiting and conformal manner. An oxygen free, solution based ALD precursor of (t-BuCp)2ZrMC2 is particular useful for depositing ZrO2 or other Zr compound films.Type: ApplicationFiled: May 13, 2009Publication date: November 18, 2010Inventors: Ce MA, Kee-Chan Kim, Graham Anthony McFarlane
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Patent number: 7829061Abstract: The zirconium oxide hydrate particles of the present invention are represented by the formula ZrO2.nH2O and have a mean primary particle size of 0.5 nm or more and 5 nm or less, and “n” in the formula represents a number greater than 2.5. Moreover, the method for producing of zirconium oxide hydrate particles of the present invention includes the step of preparing zirconium oxide hydrate particles by adding an aqueous zirconium salt solution to an aqueous alkaline solution while controlling the pH to 7.0 or more and 13.0 or less, and the step of subjecting the zirconium oxide hydrate particles to a hydrothermal treatment in the presence of water at a temperature of 50° C. or more and less than 110° C. for 3 hours or more.Type: GrantFiled: July 2, 2008Date of Patent: November 9, 2010Assignees: Hitachi Maxwell, Ltd., Hitachi, Ltd.Inventors: Yuko Sawaki, Kazutaka Matsuo, Mikio Kishimoto, Takayuki Hirashige, Makoto Morishima
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Publication number: 20100276374Abstract: A method of preparing zirconia-containing nanoparticles and a method of preparing a composite material that includes the zirconia-containing nanoparticles are provided. A method of treating a zirconium carboxylate salt solution to remove alkali metal ions and alkaline earth ions is provided. The treated solution can be used as a feedstock to prepare the zirconia-containing nanoparticles. Additionally, a continuous hydrothermal reactor system is provided that can be used, for example, to prepare the zirconia-containing nanoparticles.Type: ApplicationFiled: December 18, 2008Publication date: November 4, 2010Inventors: Brant U. Kolb, Danny B. Anderson, Robert S. Davidson, Mark J. Hendrickson, James J. Leach, Taun L. McKenzie
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Publication number: 20100270517Abstract: The present disclosure provides a solid dopant for doping a conductive polymer, which has a high dispersibility in a solvent by a plasma treatment, a method and an apparatus for preparing the solid dopants, a solid doping method of a conductive polymer using the solid dopants, and a solid doping method of a conductive polymer using plasma.Type: ApplicationFiled: April 23, 2010Publication date: October 28, 2010Applicants: ELPANI CO., LTD., AJOU UNIVERSITY INDUSTRY-ACADEMIC COOPERATION FOUNDATIONInventors: Yong Cheol Hong, Suck Hyun Lee, O. Pil Kwon, Tae Ja Kim
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Patent number: 7820124Abstract: A material comprising a plurality of nanoparticles. Each of the plurality of nanoparticles includes at least one of a metal phosphate, a metal silicate, a metal oxide, a metal borate, a metal aluminate, and combinations thereof. The plurality of nanoparticles is substantially monodisperse. Also disclosed is a method of making a plurality of substantially monodisperse nanoparticles. The method includes providing a slurry of at least one metal precursor, maintaining the pH of the slurry at a predetermined value, mechanically milling the slurry, drying the slurry to form a powder; and calcining the powder at a predetermined temperature to form the plurality of nanoparticles.Type: GrantFiled: October 5, 2006Date of Patent: October 26, 2010Assignee: General Electric CompanyInventors: Kalaga Murali Krishna, Sergio Paulo Martins Loureiro, Mohan Manoharan, Geetha Karavoor, Shweta Saraswat
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Patent number: 7820586Abstract: The invention concerns a composition based on zirconium and cerium oxides in an atomic ratio Zr/Ce>1, and further comprising lanthanum oxide or an oxide of a rare earth other than cerium and lanthanum. The invention is characterized in that after calcination for 6 hours at 1150 .C it has a specific surface area of not less than 10 m;/g. The composition is obtained by forming a mixture containing a sol of a zirconium compound and cerium, lanthanum, said rare earth compounds, contacting said mixture with a basic compound solution, while heating and calcining the resulting precipitate. The composition can be used as catalyst.Type: GrantFiled: June 26, 2003Date of Patent: October 26, 2010Assignee: Rhodia OperationsInventor: Catherine Hedouin
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Publication number: 20100266485Abstract: A process comprises (a) combining (1) at least one base and (2) at least one metal carboxylate salt comprising (i) a metal cation selected from metal cations that form amphoteric metal oxides or oxyhydroxides and (ii) a lactate or thiolactate anion, or metal carboxylate salt precursors comprising (i) at least one metal salt comprising the metal cation and a non-interfering anion and (ii) lactic or thiolactic acid, a lactate or thiolactate salt of a non-interfering, non-metal cation, or a mixture thereof; and (b) allowing the base and the metal carboxylate salt or metal carboxylate salt precursors to react.Type: ApplicationFiled: December 16, 2008Publication date: October 21, 2010Inventor: Timothy D. Dunbar
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Publication number: 20100255404Abstract: Electrocatalyst layers include an electrocatalyst having high oxygen reduction activity that is useful as an alternative material to platinum catalysts. Uses of the electrocatalyst layers are also disclosed. The electrocatalyst layer includes an electrocatalyst that is formed of a metal oxide obtained by thermally decomposing a metal organic compound. The metal element forming the electrocatalyst is preferably one selected from the group consisting of niobium, titanium, tantalum and zirconium.Type: ApplicationFiled: August 22, 2008Publication date: October 7, 2010Applicant: SHOWA DENKO K.K.Inventors: Tadatoshi Kurozumi, Toshikazu Shishikura, Ryuji Monden
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Publication number: 20100254875Abstract: A material comprising a plurality of nanoparticles. Each of the plurality of nanoparticles includes at least one of a metal phosphate, a metal silicate, a metal oxide, a metal borate, a metal aluminate, and combinations thereof. The plurality of nanoparticles is substantially monodisperse. Also disclosed is a method of making a plurality of substantially monodisperse nanoparticles. The method includes providing a slurry of at least one metal precursor, maintaining the pH of the slurry at a predetermined value, mechanically milling the slurry, drying the slurry to form a powder; and calcining the powder at a predetermined temperature to form the plurality of nanoparticles.Type: ApplicationFiled: October 5, 2006Publication date: October 7, 2010Inventors: Kalaga Murali Krishna, Sergio Paulo Martins Loureiro, Mohan Manoharan, Geetha Karavoor, Shweta Saraswat
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Publication number: 20100248297Abstract: Particles and manufacturing methods thereof are provided. The manufacturing method of the particle includes providing a precursor solution containing a precursor dissolved in a solution, and irradiating the precursor solution with a high energy and high flux radiation beam to convert the precursor to nano-particles. Particles with desired dispersion, shape, and size are manufactured without adding a stabilizer or surfactant to the precursor solution.Type: ApplicationFiled: August 22, 2009Publication date: September 30, 2010Inventors: Yeu-Kuang Hwu, Chang-Hai Wang, Chi-Jen Liu, Cheng-Liang Wang, Chi-Hsiung Chen, Chung-Shi Yang, Hong-Ming Lin, Jung-Ho Je, Giorgio Margartondo
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Publication number: 20100243968Abstract: This invention provides a titanic acid compound-type electrode active material having a high battery capacity and, at the same time, having excellent cycle characteristics. The titanic acid compound exhibits an X-ray diffraction pattern corresponding to a bronze-type titanium dioxide except for a peak for a (003) face and a (?601) face and having a lattice spacing difference between the (003) face and the (?601) face, i.e., d(003)?d(?601), of not more than 0.0040 nm. The titanic acid compound may be produced by reacting a layered alkali metal titanate, represented by a compositional formula MxM?x/3Ti2-x/3O4 wherein M and M?, which may be the same or different, represent an alkali metal; and x is in the range of 0.50 to 1.0, with an acidic compound and then heating the reaction product at a temperature in the range of 250 to 450° C.Type: ApplicationFiled: August 27, 2008Publication date: September 30, 2010Inventors: Hirofumi Taniguchi, Masatoshi Honma
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Patent number: 7799731Abstract: A photocatalyst according to the invention comprises a photocatalytic film of a compound of titanium and oxygen and is characterized in that the photocatalytic film is made porous and has 0.02 or higher value as a value calculated by dividing the arithmetical mean deviation of profile Ra with the film thickness. The photocatalytic film can also be specified by the intensity ratio between x-ray diffraction peaks of the anatase structure of titanium oxide. Such a porous photocatalytic material can be obtained by a reactive sputtering method in conditions of adjusting film formation parameters such as the film formation rate, the sputtering pressure, the substrate temperature, the oxygen partial pressure and the like in proper ranges, respectively, and the photocatalyst material is provided with excellent decomposition and hydrophilization capability.Type: GrantFiled: September 27, 2002Date of Patent: September 21, 2010Assignee: Shibaura Mechatronics CorporationInventors: Junji Hiraoka, Takahiro Doke, Hisato Haraga, Daisuke Noguchi, Yoshio Kawamata
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Patent number: 7794687Abstract: This invention relates to an improved amorphous zirconium hydroxide and a method for its production. The hydroxide has a surface area of at least 300 m2/g, a total pore volume of at least 0.70 cm3/g and an average pore size of between 5 nm and 15 nm, and is prepared by a process which comprises the steps of: a) preparing an aqueous solution comprising sulphate anions and a zirconium salt such that the ZrO2:SO3 ratio is 1:0.40 to 1:0.52, (b) chilling the solution to below 25° C., (c) adding an alkali in order to precipitate the amorphous zirconium hydroxide, (d) filtering and washing the precipitated zirconium hydroxide with water or an alkali to remove residual sulphate and chloride, (e) hydrothermally treating the zirconium hydroxide at a pressure of less than 3 barg, and (f) drying the zirconium hydroxide. The zirconium hydroxide of the present invention, which can be doped, is particularly useful in catalytic applications.Type: GrantFiled: January 24, 2007Date of Patent: September 14, 2010Assignee: Magnesium Elektron LimitedInventors: Heather Bradshaw, Clive Butler, Hazel Stephenson
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Patent number: 7785501Abstract: A black resin composition for a display device, which can achieve a high optical density even when its light-blocking agent content is relatively low and can achieve a high optical density even when it is formed into a thin film, and a member for display device which can reduce unevenness of display caused by a level difference in a pixel part resulting from the film thickness of the black resin composition. The black resin composition for a display device has a black titanium oxynitride represented by composition formula: TiNxOy-nSiO2 (wherein x and y each are a real number of larger than 0 but less than 2, and n is a real number within the range of 0 less than or equal to n less than or equal to 0.05), containing a nitrogen atom represented by N in an amount of 17 wt % or more but less than 23 wt %, and having a specific surface area of 5 to 30 m2/g and a crystalline size as measured with an X-ray diffractometer of 17 to 25 nm, and a curable binder system.Type: GrantFiled: December 27, 2005Date of Patent: August 31, 2010Assignees: Dai Nippon Printing Co., Ltd., Ishihara Sangyo Kaisha, Ltd.Inventors: Hiroaki Segawa, Kei Ikegami, Sachie Furukawa, Hideo Takahashi, Kaoru Isobe, Katsuichi Chiba, Yuichi Yasuda
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Patent number: 7781365Abstract: The present invention provides a zirconia-based mixed oxide which, together with improving the heat resistance of specific surface area at a high temperature (1000° C. for 3 hours), has a ceria reduction rate of 80% or more, or in other words, improves the heat resistance of specific surface area and the reduction rate of ceria. The zirconia-based mixed oxide has zirconia for the main component thereof and contains 5% or more of ceria and 1 to 30% of a rare earth metal oxide other than ceria, wherein the specific surface area after heat treating for 3 hours at 1000° C. is 50 m2/g or more, the reduction rate of the ceria contained in the mixed oxide is 80% or more, and preferably the specific surface area after heat treating for 3 hours at 1100° C. is 20 m2/g or more.Type: GrantFiled: June 14, 2007Date of Patent: August 24, 2010Assignee: Daiichi Kigenso Kagaku Kogyo Co., Ltd.Inventor: Hiroshi Okamoto
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Publication number: 20100209334Abstract: Titanium oxide particles having a particle having a decahedral box-shape and a particle size in a range of from 1 nm to 100 nm can be selectively and efficiently produced by carrying out a method in which in a case of oxidizing titanium tetrachloride in vapor at high temperatures, it is rapidly heated and cooled, and a method, in which water vapor is used as an oxidizing gas, in combination under certain conditions.Type: ApplicationFiled: August 29, 2008Publication date: August 19, 2010Inventors: Yasushi Kuroda, Noriyuki Sugishita, Bunsho Ohtani
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Publication number: 20100209809Abstract: Catalyst layers include an electrocatalyst having high oxygen reduction activity that is useful as an alternative material to platinum catalysts. Uses of the catalyst layers are also disclosed. A catalyst layer of the invention includes an electrode substrate and an electrocatalyst on the surface of the electrode substrate, and the electrocatalyst is formed of a metal compound obtained by hydrolyzing a metal salt or a metal complex.Type: ApplicationFiled: July 23, 2008Publication date: August 19, 2010Applicant: Showa Denkok K.K.Inventors: Tadatoshi Kurozumi, Toshikazu Shishikura
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Publication number: 20100204033Abstract: Zirconium dioxide powder in the form of aggregated primary particles, having a BET surface area of 30 to 150 m2/g and a Berger whiteness of at least 88%. It is prepared by atomizing a solution which comprises an organic zirconium compound and mixing it with a combustion gas and air and allowing the mixture to burn in a flame into a reaction chamber surrounded by a casing, where the temperature in the reaction chamber and along the side of the wall of the casing facing the reaction chamber is at least 500° C. Dispersion comprising the zirconium dioxide powder. Use of the zirconium dioxide powder and of the dispersion for producing ceramics.Type: ApplicationFiled: October 6, 2008Publication date: August 12, 2010Applicant: EVONIK DEGUSSA GmbHInventors: Stipan Katusic, Christoph Tontrup, Martin Moerters, Witold Katerinak
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Publication number: 20100197484Abstract: The present invention relates to a process for preparing mineral particles (p) from mineral species precursors, said process comprising a step (E) in which a fluid medium (F) containing said precursors in solution and/or dispersed in a solvent is injected into a reactor containing CO2 in the supercritical state by way of an injection nozzle opening into a zone where the supercritical CO2 is at a temperature greater than or equal to the temperature for conversion of the precursors into corresponding mineral species. The invention also relates to the particles (p) as obtained by the process, as well as uses thereof.Type: ApplicationFiled: April 23, 2008Publication date: August 5, 2010Applicants: AREVA NP, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUEInventors: Beatrice Sala, Stephanie Willemin, Joel Mazoyer, Thierry Muller, Nathalie Masquelez, Didier Cot, Anne Julbe, Pierre Guillermier
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Patent number: 7763565Abstract: A method of preparing stable, transparent photocatalytic titanium dioxide sols is disclosed which involves thermal treatment of a suspension of amorphous titanium dioxide in the presence of certain alpha-hydroxy acids. The sots comprise titanium dioxide particles in the anatase form having a crystallite size less than about 10 nm and exhibit excellent stability and transparency at basic, neutral, and acid pH.Type: GrantFiled: August 31, 2007Date of Patent: July 27, 2010Assignee: Millennium Inorganic Chemicals, Inc.Inventors: Guoyi Fu, BillieJo M. Monk, Robert McIntyre
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Patent number: 7763113Abstract: The present invention provides a photocatalyst material, which can comprise a photocatalyst with an excellent adherence to a substrate and a high photocatalytic activity, and a production method thereof. The photocatalyst material (20) obtained by reacting crystal nuclei with a sol solution containing an organic metallic compound or the like and then carrying out gelation, solidification and heat treatment has a structure where more than one basic structures (10) are fixed to the surface of the substrate (1). The basic structure consists of abase portion (2) comprising crystal nuclei fixed to the surface of the substrate (1) and a photocatalyst crystalline body (3), which connects to and is extended from the base portion (2) and has a columnar structure having a hollow portion (5) formed therein. A cylindrical substrate may be used for the substrate (1). The above photocatalytic activity is further enhanced by the formation of an interior-exposing structure (8) in a shell portion (4).Type: GrantFiled: June 14, 2002Date of Patent: July 27, 2010Assignee: Andre Andes Electric Co., Ltd.Inventors: Azuma Ruike, Takeshi Kudo, Yuko Nakamura, Kazuhito Kudo, Fumie Kawanami, Akira Ikegami
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Patent number: 7763232Abstract: The invention provides a method for the formation of small-size titanium oxide particles, comprising the steps of a) preparing a starting aqueous solution comprising at least one of titanic ions and complexes thereof, at a concentration of at least 0.1% w/w titanium; b) maintaining the solution at a temperature lower than 70° C. for a retention time in which hydrolysis takes place, the extent of the hydrolysis being sufficient to produce O.i mmol protons per mmol of titanium present in solution, wherein the time does not exceed 14 days, to form a system containing a retained solution; and c) adjusting the conditions in the system by at least one of the steps of: i) heating the retained solution to elevate the temperature thereof by at least 1° C.; ii) changing the pH of the retained solution by at least 0.1 units; and iii) diluting the retained solution by at least 20% whereby there are formed particles, wherein the majority of the particles formed are between about 2 nm and about 500 nm in size.Type: GrantFiled: December 21, 2006Date of Patent: July 27, 2010Assignee: Joma International ASInventors: Asher Vitner, Aharon Eyal
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Publication number: 20100184580Abstract: Glass-ceramic sealant is disclosed for planar solid oxide fuel cells. The glass-ceramic sealant includes 0 to 40 mol % of silicon oxide, 0 to 15 mol % boron oxide, 0 to 10 mol % of aluminum oxide, 0 to 40 mol % of barium oxide, 0 to 15 mol % of calcium oxide, 0 to 15 mol % of lanthanum oxide and 0 to 5 mol % of zirconium dioxide. At 0° C. to 600° C., the thermal expansion coefficient of the sealant is 8 to 10 ppm/° C.Type: ApplicationFiled: January 14, 2008Publication date: July 22, 2010Applicant: ATOMIC ENERGY COUNCIL - INSTITUTE OF NUCLEAR ENERGY RESEARCHInventors: Chien-Kuo Liu, Tung-Yuan Yung, Kin-Fu Lin, Ruey-Yi Lee, Tzang-Sheng Lee
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Patent number: 7758977Abstract: Novel, monodispersed, spherical ZrO2 particles in the size range of approximately 10 to approximately 600 nm exhibiting metastable tetragonal crystal structure at room temperature and novel methods of preparation. The ZrO2 particles are approximately 100% in the tetragonal phase at room temperature and can be pure and free of foreign oxides. The novel method can include mixing zirconium-alkoxide and an alcohol, forming preparation one, followed by separately dissolving completely de-ionized water and a polymeric steric stabilizer in an alcohol forming preparation two. Next the preparations can be mixed with vigorous stirring while subjecting the materials to hydrolysis and condensation reactions with very slow stirring. Next, there is waiting for the formation of a sol from the mixture, followed by drying at approximately 80 degrees C. to form resultant material followed by crushing the resultant material.Type: GrantFiled: September 7, 2007Date of Patent: July 20, 2010Assignee: University of Central Florida Research Foundation, Inc.Inventors: Sudipta Seal, Satyajit Shukla
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Patent number: 7754383Abstract: A negative electrode material for a non-aqueous electrolyte secondary battery comprising an alloy including silicon and a transition metal selected from the group consisting of titanium, zirconium, vanadium, molybdenum, tungsten, iron, and nickel; and a silicon oxide film and an oxide film of the transition metal formed on a surface of the alloy wherein the alloy includes an A phase including silicon and a B phase including a crystalline alloy of silicon and the transition metal. The negative electrode material has a silicon oxide film and an oxide film of the transition metal on the surface of the alloy wherein the thickness ratio of the transition metal oxide film to the silicon oxide film is at least 0.44 and smaller than 1.Type: GrantFiled: December 12, 2006Date of Patent: July 13, 2010Assignee: Panasonic CorporationInventors: Teruaki Yamamoto, Masaki Hasegawa, Yasuhiko Bito
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Patent number: 7744845Abstract: A process is disclosed for the preparation of lithium zirconate and doped lithium zirconates for use as regenerable carbon dioxide sorbants by wet mixing zirconium hydroxide with lithium carbonate and then calcining the mixture. Due to the improved physical properties resulting from the disclosed preparation process, the lithium zirconates produced by this process are capable of absorbing carbon dioxide at high rates and in large amounts.Type: GrantFiled: August 25, 2006Date of Patent: June 29, 2010Assignee: Magnesium Elektron LimitedInventor: Hazel Stephenson
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Patent number: 7744847Abstract: A process for upgrading an inferior grade of zircon to a superior grade thereof includes mixing the inferior grade of zircon, in comminuted form, with at least one mineralizer, to obtain a zircon/mineralizer mixture, which is a calcined product. The calcined product is washed, and thereafter, in a comminution step, the washed calcined product is comminuted to obtain a superior grade of zircon, which is suitable for use as a glaze opacifier.Type: GrantFiled: May 24, 2005Date of Patent: June 29, 2010Assignee: The South African Nuclear Energy Corporation LimitedInventor: Ettienne Snyders
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Patent number: 7741376Abstract: A dispersed ingredient having metal-oxygen bonds which is obtained by hydrolyzing a metal alkoxide in an organic solvent in the absence of an acid, a base, and/or a dispersion stabilizer, either with 0.5 to less than 1 mol of water per mol of the metal alkoxide or at ?20° C. or lower with 1.0 to less than 2.0 mol of water per mol of the metal alkoxide. In the organic solvent, the dispersed ingredient is stably dispersed without aggregating. Use of the dispersed ingredient enables a thin metal oxide film and a homogeneous organic/inorganic composite to be produced at a temperature as low as 200° C. or below.Type: GrantFiled: December 11, 2008Date of Patent: June 22, 2010Assignee: Nippon Soda Co., Ltd.Inventors: Motoyuki Toki, Akiji Higuchi, Nobuo Kimura, Yoshitaka Fujita
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Patent number: 7727500Abstract: Disclosed are adhesive coating compositions containing a metal peroxide for producing clear colorless adhesive coatings on substrates, particularly micro particulate substrates. In one preferred embodiment the nanoparticle coatings are chemically active and function at a high level of efficiency due to the high total surface area of the micro particulate substrate. Also disclosed are coated substrates and compositions having nanoparticles bound to a substrate by the coating compositions.Type: GrantFiled: March 8, 2007Date of Patent: June 1, 2010Assignee: PURETI, Inc.Inventor: John W. Andrews
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Patent number: 7723610Abstract: The invention relates to a titanium oxide-based polymer composition. The inventive composition comprises a TiOx(OH)y(H2O)z(x+y?+z=3) titanium oxide-based polymer in the form of a gel or sol. Said polymer, which has a one-dimensional (1D) structure, is made from concentrically-wound fibers having a periodicity which is deduced from the spacing between said fibers, of between 3.5 ? and 4 ?. Each fiber comprises TiO6octahedrons and each TiO6octahedron shares two opposite edges with two adjacent octahedrons (2.times.2.92 ?) in order to form infinite chains which develop along the axis of a fiber. According to the invention, two adjacent chains form double lines as a result of the shared edges (2.times.3.27 ?). The inventive polymer is suitable for use as a photosensitive element in a photovoltaic cell, such as a sunscreen for a window.Type: GrantFiled: March 18, 2009Date of Patent: May 25, 2010Assignee: Centre National de la Recherche Scientifique (C.N.R.S.)Inventors: Luc Brohan, Hari Sutrisno, Yves Piffard, Maria Teresa Caldes-Rouillon, Olivier Joubert, Eric Puzenat, Annabelle Rouet
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Patent number: 7708969Abstract: In a method and an apparatus for forming metal oxide on a substrate, a source gas including metal precursor flows along a surface of the substrate to form a metal precursor layer on the substrate. An oxidizing gas including ozone flows along a surface of the metal precursor layer to oxidize the metal precursor layer so that the metal oxide is formed on the substrate. A radio frequency power is applied to the oxidizing gas flowing along the surface of the metal precursor layer to accelerate a reaction between the metal precursor layer and the oxidizing gas. Acceleration of the oxidation reaction may improve electrical characteristics and uniformity of the metal oxide.Type: GrantFiled: July 9, 2007Date of Patent: May 4, 2010Assignee: Samsung Electronics Co., Ltd.Inventors: Seok-Jun Won, Yong-Min Yoo, Min-Woo Song, Dae-Youn Kim, Young-Hoon Kim, Weon-Hong Kim, Jung-Min Park, Sun-Mi Song
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Patent number: 7708975Abstract: There is described a process for preparing metal oxide particles which are substantially free of coarse tail from an oxidizing agent and a vaporous metal reactant in a flow reactor; comprising, (a) directing a flow of the metal reactant into a contacting region of the flow reactor; comprising (a) passing a flow of oxidizing agent through a high temperature zone of the flow reactor to form a flow of hot oxidizing agent and directing the flow of the hot oxidizing agent onto the contacting region of the flow reactor at a flow condition sufficient to form a reaction stream comprising a flow of hot oxidizing agent, a flow of metal reactant and a diffusive flow of the hot oxidizing agent and the metal reactant, the temperature of the hot oxidizing agent being at least sufficient to initiate oxidation of the metal reactant in the diffusive flow; (c) passing the reaction stream into a reaction zone of the flow reactor, while simultaneously introducing a flow of an upper cooling fluid substantially coaxially with theType: GrantFiled: July 18, 2005Date of Patent: May 4, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: Juergen Kurt Plischke, Stephan Claude de la Veaux, Scott Rickbeil Frerichs, Jodi Lynn Witt, Christian Normand
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Publication number: 20100104652Abstract: Disclosed herein are methodologies and compositions for enhancing cellular functions, which can be used in a variety of biological applications.Type: ApplicationFiled: October 23, 2009Publication date: April 29, 2010Inventors: Alexandru S. Biris, Meena Mahmood, Peder Jensen
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Patent number: 7704483Abstract: A zirconia-containing composition and processes for synthesizing same. The composition comprises least about 99.9 percent tetragonal phase zirconia, based on the total crystalline zirconia in the zirconia-containing composition as determined by x-ray diffraction (XRD). The composition also has a substantially spherical morphology and comprises less than 100 wppm chlorine, based on the total weight of the zirconia-containing composition. The zirconia-containing composition has an average surface area of at least 80 m2/g and an average particle size of less than about 10 microns.Type: GrantFiled: April 29, 2005Date of Patent: April 27, 2010Assignee: Cabot CorporationInventors: Jian-Ping Shen, Qi Fu, Jian Zheng, Paolina Atanassova, Mark J. Hampden-Smith
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Patent number: 7704918Abstract: The invention relates to platinum-metal oxide composite particles and their use as electrocatalysts in oxygen-reducing cathodes and fuel cells. The invention particularly relates to methods for preventing the oxidation of the platinum electrocatalyst in the cathodes of fuel cells by use of these platinum-metal oxide composite particles. The invention additionally relates to methods for producing electrical energy by supplying such a fuel cell with an oxidant, such as oxygen, and a fuel source, such as hydrogen. The invention also relates to methods of making the metal-metal oxide composites.Type: GrantFiled: June 8, 2007Date of Patent: April 27, 2010Assignee: Brookhaven Science Associates, LLCInventors: Radoslav Adzic, Miomir Vukmirovic, Kotaro Sasaki
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Publication number: 20100068625Abstract: The present invention relates to a novel compound characterized by having a one-dimensional tunnel structure and being represented by the chemical formula H2Ti12O25, a method for manufacturing the same, and a lithium secondary battery containing, as a constituent thereof, an electrode produced by using the novel titanium oxide as an active material, and expected to demonstrate superior charge/discharge cycle characteristics over a long period of time as well as high capacity.Type: ApplicationFiled: March 5, 2008Publication date: March 18, 2010Inventors: Junji AKIMOTO, Norihito KIJIMA, Hiroshi HAYAKAWA, Yasuhiko TAKAHASHI, Yasushi IDEMOTO
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Publication number: 20100069229Abstract: A method for the synthesis of nano-products, such as atomic titanium oxide wires. The method allows wires of anatase titanium oxide wires to be formed in a range of tunable diameters and aspect ratios in the nanometer and subnanometer size scales. The method also allows the titanium wires to be capped by oleic acid to enhance dispersing and solubility. The method allows the titanium wires to be surface doped with nitrogen species to enhance stability and functionality such as enhanced absorption in the visible wavelength region, which is useful for photodegradation of organic wastes in water by sunlight.Type: ApplicationFiled: August 28, 2009Publication date: March 18, 2010Applicant: THE HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGYInventors: Shihe YANG, Chenmin LIU
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Patent number: 7674450Abstract: A process for the production of a valve metal oxide powder, in particular an Nb2O5 or Ta2O5 powder by continuous reaction of a fluoride-containing valve metal compound with a base in the presence of water and calcination of the resultant product, wherein the reaction is performed in just one reaction vessel and at a temperature of at least 45° C. Valve metal oxide powders obtainable in said manner which exhibit a spherical morphology, a D50 value of 10 to 80 ?m and an elevated BET surface area.Type: GrantFiled: August 31, 2004Date of Patent: March 9, 2010Assignee: H. C. Starck GmbHInventors: Karsten Beck, Hady Seyeda, Klaus Lerch, Bianca Agnes Balan