Abstract: A process for synthesizing single crystalline beryl out of a molten salt is disclosed. The process comprises the steps of providing at least one flux to which is added the component oxides of beryl and optionally a colorant. The mixture thus obtained is heated at a temperature higher than the melting point of the flux to thereby form a molten salt. After the formation of the molten salt, the salt is cooled below the temperature sphere of beryl formation and is thereafter reheatd and again melted. At this point beryl crystals are added to the molten salt which thereby form single crystalline beryl from the molten salt. By the use of the process of the present invention, superior quality single crystalline beryl is produced economically and at a high yield rate.

Abstract: A method for producing high purity gallium oxide by reacting gallium and water vapor at elevated temperatures and pressure in a sealed autoclave lined with a fluorinated hydrocarbon polymer such as polytetrafluoroethylene to form gallium hydroxide. The hydroxide thus formed is recovered and calcined above 600.degree. C to yield high purity gallium oxide.

Abstract: In an aqueous alkaline solution having a pH greater than 11.9, thallous isobutyrate is oxidized by air in a temperature within a range from about 90.degree. C to about 250.degree. C to prepare a slurry of thallic oxide from which thallic oxide can be recovered. The alkaline isobutyrate solution can be treated with carbon dioxide under pressure to form a carbonate salt and isobutyric acid, which can be solvent extracted from the aqueous system. Such isobutyric acid can be employed in a 30 percent aqueous solution at 90.degree.-150.degree. C to dissolve thallic oxide and to prepare thallic triisobutyrate. This aqueous solution of thallic triisobutyrate can be employed for the oxidation of an organic compound susceptible to oxidation to desirable partially oxidized organic compounds, such as the oxidation of propylene to propylene oxide. The carbonate salt can be thermally decomposed to regenerate an alkaline metal hydroxide and carbon dioxide.