Having Metal Particles Patents (Class 428/546)
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Patent number: 5695691Abstract: The present invention concerns finely divided particles of compounds that provide flame retardancy and/or smoke suppressant properties to fibers, textiles, polymeric articles, paper, paint, coating and insulation. More particularly, the present invention concerns colloidal-sized particles of hydrated salts, organic phosphates, metal borates, polyamides, solid halogenated flame retardants with a melting point greater than 250.degree. C., molybdenum compounds, metallocenes, antimony compounds, zinc compounds, bismuth compounds and other solid chemicals which act as flame retardants or smoke suppressants. The present invention also concerns various milling processes to reduce these materials to colloidal sizes and to disperse them in water, organic liquids and meltable solids.Type: GrantFiled: June 7, 1995Date of Patent: December 9, 1997Assignee: Anzon, Inc.Inventors: John McLaughlin, Philip S. Podwirny, John C. Morley
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Patent number: 5679466Abstract: A particle dispersed glassy material includes ultrafine metal particles that are present in a high concentration. The particles are surrounded by a fixation component and, optionally, can be surrounded by a skeleton forming component. The glassy material is produced by firing a substrate having a film thereon that includes a polymer composite having the ultrafine particles uniformly dispersed therein, a fixation reagent and, optionally, a skeleton forming reagent under relatively mild conditions that do not damage the substrate. A method of making the glassy material includes the steps of making a film-forming composition that includes the polymer composite, the fixation reagent and, optionally, the skeleton forming reagent, applying the composition to a substrate, drying the applied composition to produce a film and firing the film to produce the glassy material.Type: GrantFiled: March 13, 1996Date of Patent: October 21, 1997Assignee: Mitsuboshi Belting, Ltd.Inventors: Toru Noguchi, Kazuo Goto, Sigehiko Hayashi, Masahito Kawahara, Susumu Murakami, Yoshio Yamaguchi, Shigehito Deki
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Patent number: 5678168Abstract: A system of two thick film pastes containing gold, in which the first paste is deposited directly onto a substrate, and the second is deposited directly onto the first, contain Cr.sub.2 O.sub.3 and Bi.sub.2 O.sub.3, which enhance the adhesion to the substrate of the first deposited paste and the solderability of the second deposited paste.Type: GrantFiled: November 13, 1995Date of Patent: October 14, 1997Assignee: National Starch and Chemical Investment Holding CorporationInventors: Orville W. Brown, David J. Nabatian
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Patent number: 5618397Abstract: Metal silicide targets are provided for sputtering which have a density of at least 99%, no more than one coarse silicon phase 10 .mu.m or larger in size that appears, per square millimeter, on the sputter surface, and an oxygen content of at most 150 ppm. They are made by a method which comprises finely grinding a synthesized silicide powder, vacuum annealing the finely ground powder in a hot press die without the application of pressure, and thereafter compacting and sintering the compact to a density of at least 99% by hot pressing. Alternatively, the finely ground powder is vacuum annealed as a presintered body at a density ratio of 50 to 75%, and thereafter is compacted and sintered.Type: GrantFiled: April 17, 1995Date of Patent: April 8, 1997Assignee: Japan Energy CorporationInventors: Osamu Kano, Yasuhiro Yamakoshi, Junichi Anan, Koichi Yasui
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Patent number: 5594933Abstract: The invention relates to a magnetoresistance material, i.e. a conductive material that exhibits magnetoresistance, which is an inhomogeneous system consisting of a nonmagnetic matrix and ultrafine particles of a ferromagnetic material such as Co or Ni--Fe--Co dispersed in the nonmagnetic matrix. With the aim of reducing deterioration of the magnetoresistance effect, an alloy or mixture of at least two metal elements selected from Cu, Ag, Au and Pt is used as the material of the nonmagnetic matrix. Optionally, the nonmagnetic matrix may contain a limited quantity of a supplementary element selected from Al, Cr, In, Mn, Mo, Nb, Pd, Ta, Ti, W, V, Zr and Ir. A film of the magnetoresistance material can be formed on a substrate, and it is optional to interpose a buffer layer between the film and the substrate and/or cover the film with a protective layer.Type: GrantFiled: June 30, 1995Date of Patent: January 14, 1997Assignee: NEC CorporationInventors: Kazuhiko Hayashi, Hidefumi Yamamoto, Junichi Fujikata, Kunihiko Ishihara
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Patent number: 5589118Abstract: Iron-rich-material waste products, such as electric arc furnace dust, are formed with an organic binder into discrete shapes, such as briquettes. The shapes can then be used in iron and steel making processes and the iron and heavy metal values in the waste product recovered.Type: GrantFiled: June 6, 1995Date of Patent: December 31, 1996Assignee: Covol Technologies, Inc.Inventors: George W. Ford, Jr., Richard C. Lambert, Russell G. Madsen
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Patent number: 5590392Abstract: A corrosion-resistant material for the construction of a member destined to contact molten metal comprises a matrix of a refractory metal and a powder of the oxide of at least one metallic element selected from the group consisting of the same metallic element as the molten metal and metallic elements having lower levels of free energy for the formation of an oxide than the molten metal, the powder of the oxide being dispersed and disposed in the matrix. The refractory metal is W, Mo, Ta, Nb, or Re. The metal oxide is selected from the rare earth metal oxides, namely the oxides of the same metallic elements as the molten metals, and the oxides of Ti, Cr, and Zr.Type: GrantFiled: February 22, 1995Date of Patent: December 31, 1996Assignee: Kabushiki Kaisha ToshibaInventors: Yutaka Ishiwata, Yoshiyasu Itoh
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Patent number: 5590393Abstract: The invention relates to a neutron-absorbing material and to its production process.This material comprises a homogeneous, boron carbide matrix 1 in which are dispersed e.g. pseudospherical, 150 to 500 .mu.m , calibrated clusters 3 of boride such as HfB.sub.2, in order to prevent the propagation of cracks F in the material and improve its thermal shock resistance.Type: GrantFiled: February 7, 1995Date of Patent: December 31, 1996Assignee: Commissariat a l'Energie AtomiqueInventors: Guy M. Decroix, Dominique Gosset, Bernard Kryger
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Patent number: 5585195Abstract: A metal insert at least partially embedded in a molded resin mass comprises a metal insert blank, and a substantial amount of nickel or nickel alloy granulations produced over a surface of the metal insert blank, and the size of the granulations is at most 1.0 .mu.m. The metal insert blank is treated by a first electrolytic plating process such that a substantial quantity of copper nuclei spreaded over the surface, and the copper nuclei are grown up as the nickel or nickel alloy granulations by a second electrolytic-plating process. The first electrolytic-plating process is controlled such that an average thickness of plating is from about 0.5 to about 1.0 .mu.m, and the second electrolytic-plating process is controlled such that an average thickness of plating is from about 0.5 to about 1.5 .mu.m.Type: GrantFiled: July 12, 1993Date of Patent: December 17, 1996Assignee: Shinko Electric Industries Company, LimitedInventor: Toshihiko Shimada
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Patent number: 5581799Abstract: A brazeable aluminum material is composed of an aluminum core and a brazing agent layer consisting of a brazing agent thermally sprayed onto and covering a surface of the core. A number of unmolten minute particles of the brazing agent are present in the brazing agent layer, which contains at least an aluminum-silicon alloy and/or a mixture of aluminum and silicon. Characteristic features of a method of producing the brazeable aluminum material are the steps of: preparing a powder composed of minute particles; and thermally spraying the powder onto the aluminum core in such a state that only a surface of each minute particle is molten, with a pith of the particle remaining unmolten. The powder is an Al-Si alloy and/or a mixture of Al powder and Si powder.Type: GrantFiled: May 15, 1995Date of Patent: December 3, 1996Assignee: Showa Aluminum CorporationInventors: Takashi Terada, Masahiro Kojima, Taizo Morita, Katsuyuki Arakawa, Ichiro Iwai, Masakazu Furuta
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Patent number: 5580665Abstract: An article essentially consisting of one or more of Ti-Al intermetallic compounds is fabricated so as to have a volume ratio of voids no more than 3.5%, by preparing a mixture of materials selected from a group consisting of Ti, Ti alloys, Al, Al alloys, and Ti-Al compounds, having a composition suitable for forming a desired Ti-Al intermetallic compound, and heating said mixture so that said mixture may be sintered. Typically, the temperature and pressure for the heating or sintering process is appropriately selected so that the desired porosity may be obtained. The mechanical strength of an article according to the present invention is not only improved but is highly predictable, or, in other word, highly reliable. The fabrication costs can be reduced because the fabrication process involves only relatively low temperatures when pressing and heating the work at the same time.Type: GrantFiled: June 6, 1995Date of Patent: December 3, 1996Assignee: NHK Spring Co., Ltd.Inventors: Kohei Taguchi, Michihiko Ayada, Hideo Shingu
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Patent number: 5580666Abstract: A multi-phase cemented ceramic article, method of making same, and the material thereof is disclosed which is useful for machining and forming of metals, including ferrous metals, titanium, aluminum and other metals. The article and its material preferably includes novel microstructures including platelets, a range of grain sizes which yields superior hardness and other characteristics, and a lower tungsten concentration within the binder phase than has been seen in the prior art. The preferred composition includes ultrafine WC, an ultrafine solid solution of (Ti, Ta, W)C, and a cobalt binder. Platelets are formed in-situ, eliminating the need to add them during manufacture for improving toughness.Type: GrantFiled: January 20, 1995Date of Patent: December 3, 1996Assignee: The Dow Chemical CompanyInventors: Ellen M. Dubensky, Stephen D. Dunmead, Daniel F. Carroll
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Patent number: 5577263Abstract: A method for producing a composite element by causing a stream of gaseous rhenium hexafluoride to flow onto a carbon substrate in a chemical vapor deposition reaction. A flow of hydrogen gas causes a reduction of the rhenium hexafluoride to rhenium metal to thereby deposit a uniform layer of rhenium metal onto the surface of the carbon substrate. A fine grain rhenium coating on carbon is produced having an average particle diameter of from about 0.1 to about 25 micrometers. The elements may be used alone or several of them may be bonded together into various articles. Such elements and articles are useful as light weight, high temperature strength, corrosive gas resistant structural elements.Type: GrantFiled: March 22, 1995Date of Patent: November 19, 1996Assignee: AlliedSignal Inc.Inventor: Gary A. West
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Patent number: 5573607Abstract: A metal matrix composite of aluminum, magnesium or titanium, and their alloys, containing particles of a silicon boride composition. A preferred form of the boride is silicon hexaboride. A small amount of carbon can be present in the silicon boride composition as Si--B--C. The particles can be pre-blended with particles of the metal prior to melting, or can be added after the melting of the metal. Because of the similar specific gravity of silicon boron compounds and aluminum, very little stirring is required to achieve a homogeneous mixture in the melt. This substantially reduces formation of oxide and hydrogen inclusions. Improved machinability is achieved through utilization of rounded particles. The composite has improved strength, stiffness and reduced thermal coefficient of expansion, thus making the composite composition more useful in industry.Type: GrantFiled: May 6, 1995Date of Patent: November 12, 1996Assignee: Millennium Materials, Inc.Inventor: Samuel C. Weaver
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Patent number: 5564066Abstract: To manufacture a reflector formed by a reflective metallic layer on a metallic matrix composite support, a metallic layer having a reflective surface whose shape is at least approximately identical to the required geometrical shape is disposed on a mold surface having a geometrical shape complementary to the required geometrical shape of the reflector. Fibers to constitute the composite support are draped on the metallic layer. They are metallized by the metallic or intermetallic material to form the metallic matrix. This layer and the metallized fibers are subjected to temperature and pressure conditions adapted to press the reflective surface strongly against the mold surface and to cause diffusion welding of the layer with the metallized fibers and of the metallized fibers with themselves so as to integrate the layer to the composite support during consolidation of the latter.Type: GrantFiled: May 25, 1995Date of Patent: October 8, 1996Assignee: Societe Nationale Industrielle et AerospatialeInventor: Henri Abiven
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Patent number: 5551997Abstract: Disclosed is a practical aluminum based alloy containing 1 to 99 weight percent beryllium, and improved methods of semi-solid processing of aluminum alloys containing beryllium. The present methods avoid molten beryllium, agitation of molten aluminum-beryllium alloys and the need for introducing shear forces by utilizing atomized or ground particles of beryllium mixed with solid, particulate or liquidus aluminum.Type: GrantFiled: March 31, 1994Date of Patent: September 3, 1996Assignee: Brush Wellman, Inc.Inventors: James M. Marder, Warren J. Haws
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Patent number: 5549975Abstract: A coated tool consisting of a cermet body and a refining layer thereon. The refining layer is a wear resistant layer of (Ti, Me) N, wherein Me is at least one metal which forms a stable oxide at a temperature above 700.degree. C.Type: GrantFiled: July 20, 1994Date of Patent: August 27, 1996Assignee: Balzers AktiengesellschaftInventors: Hans Schulz, Josef Maushart
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Patent number: 5549951Abstract: Ultrafine whiskery or columnar ceramic particles, a method for producing the ultrafine particles, and a sintered article obtained by sintering the ultrafine ceramic particles are disclosed. The ultrafine ceramic particles are produced by thermally melting a matrix alloy of a composition of Al--M.sup.1, wherein M.sup.1 stands for at least one metallic element selected from the group consisting of Cr, Co, and Fe, or Al--M.sup.1 --M.sup.2, wherein M.sup.2 stands for at least one metallic element selected from the group consisting of Au, Cu, Dy, Er, Ga, Ge, Gd, Hf, Ho, Lu, Mn, Mo, Nb, Nd, Ni, Pr, Re, Sb, Sc, Si, Sn, Ta, Tb, Ti, Tm, V, W, Y, Zn, or Zr, in a nitriding atmosphere containing nitrogen and causing the vaporized raw material to react with the nitrogen in the atmosphere.Type: GrantFiled: September 7, 1994Date of Patent: August 27, 1996Assignees: YKK Corporation, Tsuyoshi Masumoto, Akihisa Inoue, Honda Giken Kogyo Kabushiki KaishaInventors: Tadashi Yamaguchi, Katsutoshi Nosaki, Inoue Akihisa, Tsuyoshi Masumoto
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Patent number: 5545487Abstract: The Al-Si sintered alloy having good mechanical strength and elongation and is especially excellent in wear resistance, and a method for producing the same. The sintered alloy consists of 2.4-23.5% Si, 2-5% Cu, 0.2-1.5% Mg, 0.01-1% of transition metals and the balance of aluminum and unavoidable impurities, and has a dapple grain structure of an Al-solid solution phase and an Al-Si alloy phase containing dispersed pro-eutectic Si crystals having a maximum diameter of 5-60 .mu.m either in the whole body or in the surface contact portion, and the area ratio of the Al-solid solution phase in the grain structure is in the range of 20-80%.Type: GrantFiled: February 9, 1995Date of Patent: August 13, 1996Assignees: Hitachi Powdered Metals Co., Ltd., Honda Giken Kogyo Kabushiki KaishaInventors: Zenzo Ishijima, Jun-ichi Ichikawa, Shuji Sasaki, Hideo Shikata, Hideo Urata, Shoji Kawase, Jun-ichi Ueda
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Patent number: 5534353Abstract: A composite sintered material of a mixed-phase structure comprising fine particles of hard compound compactly and uniformly dispersed in grains of matrix of titanium or titanium alloy. The material is outstanding in abrasion resistance, strength, toughness, etc., and also has high resistance to corrosion by molten nonferrous metals and is therefore reduced in the likelihood of dissolving out into the melt.The sintered material is produced by uniformly mixing together a metal powder for forming the matrix of the desired sintered material and a powder for forming particles of hard compound to be dispersed, molding the powder mixture into a block under pressure, atomizing the block while melting the block and sintering the resulting powder.Type: GrantFiled: February 1, 1994Date of Patent: July 9, 1996Assignee: Kubota CorporationInventors: Takahiro Kaba, Takashi Nishi, Tsuyoshi Mitsuhashi
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Patent number: 5525428Abstract: This invention relates to a substrate for semiconductor apparatus loading a semiconductor chip in an integrated circuit apparatus and is characterized in that a sintered compact containing copper of 2 to 30 wt. % in tungsten and/or molybdenum is used as the substrate having the heat radiation capable of efficiently radiating heat developed from the loaded semiconductor chip and thermal expansion coefficient similar to those of semiconductor chip and other enclosure material except for the substrate.Type: GrantFiled: January 4, 1995Date of Patent: June 11, 1996Assignee: Sumitomo Electric Industries, Ltd.Inventors: Mituo Osada, Yoshinari Amano, Nobuo Ogasa, Akira Ohtsuka
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Patent number: 5521015Abstract: A metal matrix composite component e.g. a brake disc, is provided with a protective coating to prevent displacement of the reinforcing filler in the matrix when the component is placed under load. Preferably the protective coating is metal, alloy, composite, refractory or ceramic applied e.g. by electro-plating.Type: GrantFiled: December 5, 1994Date of Patent: May 28, 1996Inventor: Martin J. M. Murphy
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Patent number: 5518822Abstract: A TiCN-based cermet cutting insert superior in toughness with improved wear resistance includes a binding phase and at least two hard dispersion phases. One of the hard dispersion phases includes one of a duplex and triplex structure having a core structure containing at least one of titanium carbonitride and a carbonitride solid solution of Ti and one of a V, Cr, Ti, Nb, Zr, W and Mo (hereinafter referred to as a (Ti,M)CN. The other hard dispersion phase includes a single structure wherein the core structure is composed of at least one of (Ti,M)CN or (Ti,M)CN and TiCN.Type: GrantFiled: October 12, 1994Date of Patent: May 21, 1996Assignee: Mitsubishi Materials CorporationInventors: Kiyohiro Teruuchi, Katsuhiko Yano, Niro Odani
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Patent number: 5514479Abstract: Disclosed herein is process method and articles of plated coating having functions ranging from wear resistance, lubricity, corrosion resistance, and further incorporating therein particulate matter having light emitting properties. Having this codeposited light emitting particles within the functional layer provides a signal for the determination of the presence of the coating and its stage of deterioration.Type: GrantFiled: June 5, 1995Date of Patent: May 7, 1996Inventor: Nathan Feldstein
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Patent number: 5508114Abstract: A method of manufacturing a lead-provided porous metal sheet comprises the steps of: forming a porous metal material having a metal layer on a surface of a framework of a porous base material comprising a foamed sheet and the like, by plating the porous base material and/or applying fine metal powders thereto; passing the porous metal material through a pair of rolls having a plurality of projections formed thereon to compress the porous metal material against the projections and reduce or eliminate pores so as to form one or more recesses extending; and forming solid metal portions by applying fine metal powders to the entire recesses.Type: GrantFiled: December 9, 1994Date of Patent: April 16, 1996Assignee: Katayama Special Industries, Inc.Inventor: Hirofumi Sugikawa
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Patent number: 5498483Abstract: A wear-resistant sintered ferrous alloy for use as a valve seat, the alloy comprising an iron-based matrix having a sorbite or pearlite structure consisting of 0.5 to 1.5% by weight of C, 0.5 to 3% by weight of Ni, 0.5 to 2% by weight of Mo, 0.1 to 8% by weight of Co, 0.05 to 1% by weight of Mn, and the balance of Fe, with unavoidable impurities, and having a Vickers hardness of from 300 to 450; hard particles A consisting of 1.5 to 2.5% by weight of C, 38 to 45% by weight of Cr, 18 to 30% by weight of W, 5 to 15% by weight of Co, 0.5 to 3% by weight of Mo, 0.03 to 0.5% by weight of Ti, and the balance of Fe, with unavoidable impurities, and having an average particle diameter of from 30 to 80.mu.m; and hard particles B consisting of 60 to 70% by weight of Mo, 0.5 to 2% by weight of Si, and the balance of Fe, with unavoidable impurities, and having an average particle diameter of from 30 to 80 .mu.Type: GrantFiled: April 28, 1995Date of Patent: March 12, 1996Assignee: Sumitomo Electric Industries, Ltd.Inventors: Kozo Ito, Yoshishige Takano
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Patent number: 5496650Abstract: Process of imparting conductivity to a three-dimensional net-shaped porous sheet can be performed efficiently before carrying out electroplating process. Fine metallic powders are applied to the porous sheet made of a foamed sheet, a nonwoven sheet, a mesh sheet or a plurality of sheets layered one on the other, so that a conductive metallic layer is formed on the porous sheet. Then, an electroplated layer is formed on the surface of the conductive metallic layer. The conductive metallic layer remains when the porous sheet burned out. Consequently, a metallic layer of the conductive metallic layer and the electroplated layer forms the metallic framework of the metallic porous sheet.Type: GrantFiled: September 13, 1994Date of Patent: March 5, 1996Assignee: Katayama Special Industries, Ltd.Inventor: Hirofumi Sugikawa
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Patent number: 5492771Abstract: An improved method of making a monolayer abrasive tool using a relatively low melting point, soft filler metal alloy braze which possesses sufficiently high yield strength combined with a relatively high ductility and low elastic modulus to produce an exceptional bond between a monolayer of superabrasive particles and the tool substrate. The steps of the brazing process include applying a layer of the filler metal alloy including a an active metal in either pre-alloyed or as a mixture with the metal alloy and a monolayer of superabrasive crystals over the filler metal layer. This assembly is heated in a mon-oxidizing atmosphere such as a vacuum to melt the alloy and braze bond the superabrasive particles to the tool substrate. The alloy bond formed possess the properties of a ductility of at least 20 percent elongation, an elastic modulus of less than 15.times.10.sup.6 or less, and a yield strength preferably at least about 45,000 to 50,000 psi.Type: GrantFiled: September 7, 1994Date of Patent: February 20, 1996Assignee: Abrasive Technology, Inc.Inventors: James T. Lowder, Roy F. Wielonski, Kosta L. George
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Patent number: 5489487Abstract: A multi-layer bearing consists of a backing steel plate, a layer of Cu--Pb bearing alloy comprising, by weight, 1 to 20% of Ni and containing Pb-phase grains dispersed in the matrix, and an overlay of Pb alloy containing In. In in the overlay is diffused into the Pb-phase grains in the bearing alloy layer and forms a diffusion layer of high corrosion resistance in which In coexists with the Pb-phase grains, in an area of 30 to 200 .mu.m from the interface to the overlay. Even if the overlay is worn and the Cu--Pb bearing alloy layer is exposed, high corrosion resistance will be maintained.Type: GrantFiled: October 5, 1994Date of Patent: February 6, 1996Assignee: Daido Metal Company Ltd.Inventors: Tadashi Tanaka, Masaaki Sakamoto, Koichi Yamamoto, Tsukimitsu Higuchi
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Patent number: 5486427Abstract: The present invention provides a method for providing an array of metal microbeads on a substrate, preferably in a regular pattern of very fine, uniform size microspheres or microbeads at precise spacing or scale previously unachievable. The method of the present invention comprises the steps of providing a metal layer on a substrate that is partitioned into metal regions; heating the metal layer to a temperature sufficient to melt the metal and to permit beading of the layer into discrete microbeads.Type: GrantFiled: August 19, 1994Date of Patent: January 23, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: David C. Koskenmaki, Clyde D. Calhoun
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Patent number: 5484662Abstract: A solid lubricant coating system for use with a metal interface subject to high temperatures and wet lubrication, comprising agglomerates of particles of (i) solid lubricant particles selected from the group consisting of graphite, boron nitride, molybdenum disulfide, lithium fluoride, NaF, WS.sub.2, and calcium fluoride; and (ii) steel particles fused together and bounding said solid lubricant particles at least at certain intersections, certain portions of said steel particles being air-hardened to a high hardness upon exposure of the coating to the interface at high temperatures.Type: GrantFiled: May 6, 1994Date of Patent: January 16, 1996Assignee: Ford Motor CompanyInventor: V. Durga N. Rao
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Patent number: 5482531Abstract: A powder-metallurgy-produced, essentially titanium-free, nickel-containing maraging steel article such as for use in the manufacture of die casting die components and other hot work tooling components. The article preferably contains an intentional addition of niobium. The article may be produced as a hot-isostatically-compacted, solution annealed, fully dense mass of prealloyed particles, or alternately, as a hot-isostatically-compacted, plastically deformed and solution annealed, fully dense mass of prealloyed particles.Type: GrantFiled: June 5, 1995Date of Patent: January 9, 1996Assignee: Crucible Materials CorporationInventors: Kenneth E. Pinnow, Carl J. Dorsch
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Patent number: 5482530Abstract: The invention relates to cobalt metal powders as a binder metal for the production of diamond and/or hard-metal tools and/or wear-resistant coatings and to composite sintered articles produced therefrom.Type: GrantFiled: December 2, 1994Date of Patent: January 9, 1996Assignee: H,C. Starck GmbH & Co. KGInventor: Matthias Hohne
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Patent number: 5482782Abstract: A sliding-contact material comprising a backing steel plate optionally plated with Cu, and a layer of sintered copper alloy formed on one of the surfaces of the backing steel plate, wherein the layer of sintered copper alloy consists essentially of 4 to 20 wt % Sn, 1 to 10 wt % Ni, 0.05 to 1 wt % B, and balance of Cu and incidented impurities, and does not practically include P, and the sintered copper alloy has a Vickers hardness not less than Hv 100.Type: GrantFiled: November 29, 1994Date of Patent: January 9, 1996Assignee: Daido Metal Company Ltd.Inventors: Tadashi Tanaka, Masaaki Sakamoto, Koichi Yamamoto, Tsukimitsu Higuchi, Kouki Ozaki
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Patent number: 5480472Abstract: A method for forming an electrical contact material comprises the steps of melting a mixture of Cu and Cr into a molten alloy, atomizing the molten alloy into fine particles to obtain alloyed particles. Cr particles in the alloyed powder disintegrate to less than 5 .mu.m in mean particle diameter. The alloyed powder is sintered thereafter and a mean particle diameter of chromium in the sintered article is fined in a range of 2 to 20 .mu.m. An electrical contact material is composed of a copper matrix and chromium particles having a mean particle diameter of 2 to 20 .mu.m. The chromium particles are homogeneously dispersed in the copper matrix.Type: GrantFiled: July 30, 1991Date of Patent: January 2, 1996Assignee: Kabushiki Kaisha MeidenshaInventors: Yasushi Noda, Nobuyuki Yoshioka, Nobutaka Suzuki, Toshimasa Fukai, Tetsuo Yoshihara, Koichi Koshiro
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Patent number: 5480728Abstract: A conductive contact for use with metal oxide superconductors is described. The conductive contact comprises a metal contact which is attached by a diffusion bonding means to a superconductive metal oxide substrate. In a preferred embodiment, diffusion bonding means comprises a metal paint which includes metal particles and an organic binder which is heated to pyrolized the organic binder and form metallic diffusion bonds to the metal contact and metal oxide substrate. The invention also comprises a method for forming the conductive contact which includes selecting the superconducting metal oxide substrate, coating the substrate with a metal paint, placing the metal contact in touching contact with the metal paint and heating the combination of materials described above to pyrolized the organic binder and coalesce the metal particles.Type: GrantFiled: January 3, 1994Date of Patent: January 2, 1996Assignee: General Electric CompanyInventor: John E. Tkaczyk
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Patent number: 5472793Abstract: A composite spray coating comprises an iron base material, a spray coating film applied thereon and a diffusion layer of aluminum or aluminum-zinc alloy, and is used for hot-dip galvanization.Type: GrantFiled: December 12, 1994Date of Patent: December 5, 1995Assignee: Tocalo Co., Ltd.Inventors: Yoshio Harada, Kazumi Tani, Yoshihumi Kobayashi
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Patent number: 5472661Abstract: Method of distributing and retaining insoluble additive particles uniformly throughout a mass of moldable metal particles. The additive particles are suspended in a solution of a polymeric binder and spray-coated onto the metal particles. When the solvent evaporates, the additives remain glued to the metal particles by the binder.Type: GrantFiled: December 16, 1994Date of Patent: December 5, 1995Assignee: General Motors CorporationInventor: David E. Gay
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Patent number: 5468566Abstract: An article and method of manufacture of (Bi, Pb)-Sr-Ca-Cu-O superconductor. The superconductor is manufactured by preparing a first powdered mixture of bismuth oxide, lead oxide, strontium carbonate, calcium carbonate and copper oxide. A second powdered mixture is then prepared of strontium carbonate, calcium carbonate and copper oxide. The mixtures are calcined separately with the two mixtures then combined. The resulting combined mixture is then subjected to a powder in tube deformation and thermal processing to produce a substantially phase pure (Bi, Pb)-Sr-Ca-Cu-O superconductor.Type: GrantFiled: September 13, 1994Date of Patent: November 21, 1995Assignee: University of ChicagoInventors: Stephen E. Dorris, Roger B. Poeppel, Barton C. Prorok, Michael T. Lanagan, Victor A. Maroni
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Patent number: 5462809Abstract: A single layer film is deposited onto a substrate at room temperature from two sources, one source being a magnetic material, the other being a non-magnetic or weakly-magnetic material. The film is annealed for predetermined time in order to induce phase separation between the magnetic clusters and the non-magnetic matrix, and to form stable clusters of a size such that each magnetic particle, or cluster, comprises a single domain and has no dimensions greater than the mean free path within the particle.Type: GrantFiled: January 10, 1994Date of Patent: October 31, 1995Assignee: The Regents of the University of CaliforniaInventor: Ami Berkowitz
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Patent number: 5460893Abstract: A TiCN-based cermet cutting insert superior in toughness with improved wear resistance includes a binding phase and at least two of four hard dispersion phases. One of the two hard dispersion phases includes at least one of a duplex or triplex phase structure with a core of a composite carbonitride solid solution and a single-phase structure of a composite carbonitride solid solution. The other hard dispersion phase includes one of a hard dispersion phase of titanium carbonitride and a hard dispersion phase which includes a single-phase structure of titanium carbonitride.Type: GrantFiled: March 8, 1994Date of Patent: October 24, 1995Assignee: Mitsubishi Materials CorporationInventors: Kiyohiro Teruuchi, Katsuhiko Yano, Niro Odani
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Patent number: 5455117Abstract: An electromagnetic wave reflection-preventing material having a structure formed by successively laminating (A) an electromagnetic have reflecting metallic material layer, if needed, (B) a substrate layer, (C) a resin layer containing a powder of at least one selected from ferrite, carbon, metal powder and an electrically conductive metallic oxide, and, if needed, a good dielectric material, if needed, (D) a supporting film layer, and (E) a pattern coating layer prepared in the form of a geometrical pattern, containing a metal powder and having a volume resistivity of 10.sup.-3 to 10.sup.10 .OMEGA..multidot.Type: GrantFiled: October 25, 1993Date of Patent: October 3, 1995Assignee: Kansai Paint Co., Ltd.Inventors: Toshiaki Nagano, Hideo Kogure, Naozumi Iwasawa, Tetsu Maki
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Patent number: 5455116Abstract: An electromagnetic wave reflection-preventing material having a structure formed by successively laminating (A) an electromagnetic wave reflecting material layer, if needed, (B) a supporting layer, (C) a resin layer, if needed, (D) a supporting layer, and (E) a metallic pattern layer prepared by arranging at least one of a pattern unit comprising a geometrical pattern formed by use of a continuous metallic band, or comprising a multi-figured structure formed by combining a plurality of band-shaped metallic figures so as not to contact with each other; and an electromagnetic wave reflection-preventing method by use of the electromagnetic wave reflection-preventing material.Type: GrantFiled: October 25, 1993Date of Patent: October 3, 1995Assignee: Kansai Paint Co., Ltd.Inventors: Toshiaki Nagano, Hideo Kogure, Tetsu Maki, Naozumi Iwasawa
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Patent number: 5455118Abstract: The present invention describes a plated component and plating method in which the plating adheres to the reinforcement particles on the surface of a composite component. This allows the component to be processed above 400.degree. C. without blistering. The plating method allows brazing, such as gold/tin and gold/germanium brazing, maintains hermeticity, and prevents corrosion over a sustained period of time. By utilizing an activator such as palladium, which can produce catalytic sites on which electroless nickel can be deposited, a component with a surface of exposed reinforcement particles can be plated to form a uniform surface without voids. It has been found that by using a combination of nickel-boron and a palladium activator, that Al/SiC composites can be plated with good adhesion when exposed to temperatures above 400.degree. C.Type: GrantFiled: February 1, 1994Date of Patent: October 3, 1995Assignee: PCC Composites, Inc.Inventor: Arnold J. Cook
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Patent number: 5453328Abstract: An electromagnetic wave reflection-preventing material having a structure formed by a process which comprises successively laminating (A) a pattern layer formed in the form of a geometrical pattern having a volume resistivity of 10.sup.3 .OMEGA. .Type: GrantFiled: January 21, 1994Date of Patent: September 26, 1995Assignee: Kansai Paint Co., Ltd.Inventors: Toshiaki Nagano, Hideo Kogure, Naozumi Iwasawa, Tetsu Maki
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Patent number: 5447801Abstract: A target for magneto-optical recording media having a microstructure having a matrix phase of a eutectic structure of a rare earth metal and an iron-group metal, particles I made of a pure iron-group metal or an alloy thereof and having an average diameter of 200 .mu.m or less and particles II made of a corrosion resistance-improving metal and an iron-group metal and having an average diameter of 200 .mu.m or less is produced by mixing rapidly-quenched powder A made of the rare earth metal and the iron-group metal and having a eutectic structure with powder B made of a pure iron-group metal or an alloy thereof and having an average diameter of 200 .mu.m or less, and powder C made of the corrosion resistance-improving metal and the iron-group metal and having an average diameter of 200 .mu.m or less, and pressure-sintering the resulting mixed powder at a temperature lower than a liquid phase-appearing temperature.Type: GrantFiled: December 9, 1993Date of Patent: September 5, 1995Assignee: Hitachi Metals, Ltd.Inventors: Kaoru Masuda, Shunichiro Matsumoto
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Patent number: 5447774Abstract: There is disclosed a composite slide member which suppresses the exposure of a porous metal layer even when the amount of cutting from a surface of the slide member increases, thereby enhancing an anti-seizing property without adversely affecting a rear resistance. The composite slide member includes a back plate, and a slide layer including a porous metal layer with a porosity of 50% to 80% and a composite synthetic resin composition impregnated and coated in pores of the porous metal layer. The porous metal layer is joined to a surface of the back plate. The porous metal layer is formed by sintering metal powder without applying pressure thereto, and an apparent density of the metal powder is 20% to 40% of its theoretical density. The porous metal and the composite synthetic resin are dispersed on a sliding surface of the slide layer in a substantially mixed condition.Type: GrantFiled: January 13, 1993Date of Patent: September 5, 1995Assignee: Daido Metal Company, Ltd.Inventors: Tadashi Tanaka, Hidehiko Tamura, Shigemasa Hakakoshi, Takahiro Niwa
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Patent number: 5447800Abstract: A martensitic hot work tool steel die block for use in the manufacture of die casting die components and other hot work tooling components and a method for manufacturing the same. The article has a hardness within the range of 35 to 50 HRC and a minimum transverse Charpy V-notch impact toughness of 5 foot pounds when heat treated to a hardness of 44 to 46 HRC and when tested at both 72.degree. F. and 600.degree. F. The article is a hot worked, heat treated and fully dense consolidated mass of prealloyed particles of the composition, in weight percent, 0.32 to 0.45 carbon, 0.20 to 2.00 manganese, 0.05 to 0.30 sulfur, up to 0.03 phosphorous, 0.80 to 1.20 silicon, 4.75 to 5.70 chromium, 1.10 to 1.75 molybdenum, 0.80 to 1.20 vanadium, and balance iron. The alloy may be any conventional wrought AISI hot work tool steel or wrought maraging or precipitation-hardening steel having 0.05 to 0.30 percent sulfur, and having sulfide particles which exhibit a maximum size of 50 microns in their longest dimension.Type: GrantFiled: September 27, 1993Date of Patent: September 5, 1995Assignee: Crucible Materials CorporationInventors: Carl J. Dorsch, Kenneth E. Pinnow, William Stasko
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Patent number: 5445895Abstract: A powder-metallaurgically produced material or extruded semi-finished product for electric contacts of silver or a silver-based metal material with 0.5 to 10 wt. % carbon and 0 to 2 wt. % of an additional metal. The material contains powdered carbon in combination with carbon fibers in the mass ratio of 10:1 to 1:10, whereby the diameter of the powder particles is on average smaller than half the length of the fibers.Type: GrantFiled: February 14, 1994Date of Patent: August 29, 1995Assignee: Doduco GmbH & Co. Dr. Eugen DurrwachterInventors: Volker Behrens, Carl L. Meyer, Karl Saeger, Thomas Honig, Roland Michal
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Patent number: 5443917Abstract: A densified ceramic or cermet armor material comprises greater than fifty percent by weight titanium nitride or greater than eight percent by weight of a mixture of titanium nitride and aluminum nitride to impart low compressive strength to said armor material and may additionally comprise components suitable for densification with said titanium nitride or titanium nitride-aluminum nitride mixture where the resulting armor material has high density and low porosity with a Young's modulus greater than 200 GPa and a compressive strength of less than 5.5 GPa.Type: GrantFiled: May 24, 1991Date of Patent: August 22, 1995Assignee: GTE Products CorporationInventor: Christopher A. Tarry