Abstract: An article is coated with a multi-layer decorative and protective coating having the appearance of stainless steel. The coating comprises one or more electroplated layers on the surface of said article and vapor deposited on the electroplated layers a stack layer containing layers of refractory metal or metal alloy alternating with layers containing the reaction products of refractory metal or refractory metal alloy, nitrogen and oxygen wherein the total nitrogen and oxygen content of these reaction products is from about 4 to about 32 atomic percent with the nitrogen content being at least about 3 atomic percent.

Abstract: A method of making cookware and bakeware having a stick resistant and mar resistant cook surface comprising the steps of providing a cooking utensil having a cook surface, and cryogenically treating the cooking utensil at one or more selected temperatures comprising −100° F. to −300° F. or lower to harden said cook surface. The cooking utensil may have a bare metal cook surface, or it may be coated with a stick resistant coating such as one of a PTFE, metal nitride or sulfide coating or combinations thereof prior to the cryogenic hardening treatment.

Abstract: A drill resistant plate, which presents a rough surface of hardened particles to drilling attack, and which tends to snap or destroy drill bits before they can began drilling. The plate is made by brazing hard particles into a matrix of brazing material attached to a steel plate. Nickel-Silver brazing material is used to form the matrix on the steel plate, and tungsten carbide particles of 8-10 mesh are secured within the matrix, with the hard particles of tungsten carbide partially exposed, presenting a roughened surface with angular pieces of tungsten carbide to the drilling attack.

Abstract: The invention relates to a ball limiting metallurgy stack for an electrical device that contains a tin diffusion barrier and thermo-mechanical buffer layer disposed upon a refractory metal first layer. The multi-diffusion barrier layer stack resists tin migration toward the upper metallization of the device.

Abstract: A composite material has SiC produced by preliminarily sintering a porous body having a coefficient of thermal expansion lower than the coefficient of thermal expansion of copper to construct a network therein, the SiC being impregnated with a copper alloy. The copper alloy comprises copper and one or more additive elements which are prepared to impart a coefficient of thermal conductivity of 160 W/mK or higher to the composite material. The additive elements comprise up to 5% of at least one element selected from Be, Al, Si, Mg, Ti, Ni, Bi, Te, Zn, Pb, Sn, and mish metal, and also contains unavoidable impurities and gas components.

Abstract: The present invention relates to articles, having an extended useful life, which are used in contact with high temperature molten aluminum or molten zinc baths. One aspect of the invention encompasses articles, such as bearings, bushings, couplings or rollers, used in contact with molten aluminum or molten zinc which is coated with a high density coating consisting of a metal selected from Groups Vb, VIb, or VIIb metals (preferably molybdenum or tungsten), in pure or alloyed form. These coatings generally have a thickness of from about 0.06 to about 0.30 inch. Another aspect of the present invention encompasses a roll for guiding steel strip through a high temperature aluminizing bath, which utilizes a multi-layer structure, the first primer layer being a Group Vb, VIb or VIIb metal, preferably tungsten or molybdenum (in pure or alloyed form), the second layer comprising MCrAlY in which M is either nickel or cobalt, and the third layer comprising a refractory metal oxide of Al, Zr, Si or Cr.

Abstract: In order to form a novel article of manufacture, a nickel or cobalt-based superalloy substrate is covered with a protective system resistant to thermal, corrosive and erosive attack. A bonding layer is disposed on the substrate and an anchoring layer on the bonding layer. The anchoring layer is formed as a nitride compound. The nitride compound is aluminum nitride in particular. A ceramic coating is disposed on the anchoring layer. The anchoring layer prevents transmission of diffusion active elements through the anchoring layer to the thermal barrier layer, reduces oxidation of layers therebelow and provides for good heat transmission therethrough.

Abstract: Often, metal matrix composites (MMC's) lack adequate machinability and possess excessive abrasiveness because hard ceramic materials, such as silicon carbide, are used as the reinforcement phase. To make a metal matrix composite body having a more machinable and less abrasive surface, an MMC comprising an aluminum nitride reinforcement is formed on the surface of the body. In one embodiment, a layer is provided to a permeable mass or preform at the surface at issue, the layer featuring at least a reduced loading of ceramic filler material, and sometimes no ceramic material at all. The reduced loading is achieved by incorporating a fugitive material into the coating layer. Molten matrix metal is caused to infiltrate the permeable mass or preform and the coating layer to produce a macrocomposite body comprising a metal matrix composite coating and substrate.

Abstract: A neutral blue-green heat treatable and matchable glass laminate or I.G. unit employs a layer system whose visible transmittance increases by at least 4% during heat treatment and whose &Dgr;E*ab is less than about 3.0 and &Dgr;a* is less than about 0.7. The sputter coated layer system includes a silver layer sandwiched between nichrome layers and thereafter layers of Si3N4.

Abstract: The coated device contains a coating for use with corrosive environments at high temperatures. The device has a bond coat consisting essentially of, by weight percent, 0 to 5 carbon, 20 to 40 chromium, 0 to 5 nickel, 0 to 5 iron, 2 to 25 total molybdenum plus tungsten, 0 to 3 silicon 0 to 3 boron and balance cobalt and essential impurities to provide sulfidation resistance at high temperatures. A zirconia-base ceramic coating covers the bond coat for heat resistance. Optionally, a boride or carbide coating covers the zirconia for additional resistance to erosion.

Abstract: The present invention relates to composite electroless coatings with varying densities of codeposited particles in the plated layer along the surface of the substrate where said variation of densities is directed by the angle of rotation of the substrate during the coating process.

Abstract: A turbine engine component includes a substrate and a wear coating on the substrate. The wear coating includes wear-resistant particles in a matrix phase, the wear-resistant particles being formed of chrome carbide or a cobalt alloy. Methods for forming a turbine engine component are also disclosed.

Abstract: A heat treatable coated article including an infrared (IR) reflecting layer (e.g., of or including Ag), the coated article being able to attain a &Dgr;E*ab (glass side) no greater than about 3.0, more preferably no greater than 2.5, and even more preferably no greater than 2.0, following or due to heat treatment (e.g., thermal tempering). Accordingly, low-E (i.e., low emissivity) coated articles of certain embodiments of this invention appear from the glass side thereof visually similar to the naked eye both before and after heat treatment. Coated articles herein may be used in the context of insulating glass (IG) window units, vehicle windshields, or any other suitable applications. In certain embodiments of this invention, an exemplary layer stack includes: glass/Si3N4/NiCr/Ag/NiCr/Si3N4. Other materials may instead be used without departing from the scope and/or spirit of the instant invention which is a low-E matchable product.

Abstract: A thermal barrier coating (TBC) and method for forming the coating on a component intended for use in a hostile environment. The coating and method are particularly directed to inhibiting sintering, grain coarsening/growth and pore redistribution in the coating during high temperature excursions by providing limited amounts of extremely fine carbide-based and/or nitride-based precipitates preferably formed at defects and pores at and between the grain boundaries of the TBC microstructure. The precipitates pin the TBC grain boundaries and pores during high temperature excursions, with the effect that the TBC microstructure is thermally stabilized. A coating containing the carbides and/or nitrides can be formed using a physical vapor deposition technique in an atmosphere that contains carbon and/or nitride gases or compounds thereof, or by evaporating a source material that contains carbon, carbon-containing compounds, carbides and/or nitrides.

Abstract: An organic antireflection coating is formed on a semiconductor substrate. A resist film is formed on the semiconductor substrate through the organic antireflection coating. The resist film is patterned for forming a resist pattern having an opening. A part of the organic antireflection coating exposed on the bottom of the opening of the resist pattern is removed with atomic oxygen. Thus provided is a method of forming a resist pattern so improved as to increase the dimensional accuracy of the resist pattern.

Abstract: A thermal barrier coating for superalloy articles such as turbine engine vanes and blades that are exposed to high temperature gas is disclosed. The coating includes a columnar grained ceramic layer applied to an aluminide or MCrAlY bond coat by electron beam physical vapor deposition. The ceramic layer is comprised a plurality of layers of zirconia stabilized with 20 percent yttria and the interfaces between the layers are decorated with particles selected from a group consisting of Ta2O5 and alumina. Though not essential to the invention a layer of tetragonal zirconia may be deposited both under and over the ceramic coat. An improved electron physical beam vapor deposition process for applying this ceramic layer is also disclosed.

Abstract: A heat treatable coated article including an infrared (IR) reflecting layer (e.g., of or including Ag), the coated article being able to attain a &Dgr;E* (glass side) no greater than about 3.0, more preferably no greater than 2.5, and even more preferably no greater than 2.0, following or due to heat treatment (e.g., thermal tempering). Accordingly, low-E (i.e., low emissivity) coated articles of certain embodiments of this invention appear from the glass side thereof visually similar to the naked eye both before and after heat treatment. Coated articles herein may be used in the context of insulating glass (IG) window units, vehicle windshields, or any other suitable applications. In certain embodiments of this invention, an exemplary layer stack includes: glass/Si3N4/NiCr/Ag/NiCr/Si3N4. Other materials may instead be used without departing from the scope and/or spirit of the instant invention which is a low-E matchable product.

Abstract: A method of coating of steel products such as plate and sheet using an aluminum-zinc coating alloy includes modifying the coating bath with a particulate compound constituent in effective amounts to decrease the spangle facet size of the coated product, improve tension bend rust stain performance, and coated product paintability. Constituents include borides such as titanium boride and aluminum borides, carbides such as titanium carbide, and aluminides such as titanium aluminide. The method produces a coated steel product that does not require temper rolling for painting.

Abstract: An article is coated with a multi-layer decorative and protective coating having the appearance of stainless steel. The coating comprises one or more electroplated layers on the surface of said article and vapor deposited on the electroplated layers a refractory metal nitride, refractory metal alloy nitride, or reaction products of refractory metal or refractory metal alloy, nitrogen and oxygen wherein the nitrogen content of the refractory metal nitride, refractory metal alloy nitride or reaction products of refractory metal or refractory metal alloy, nitrogen and oxygen is from about 3 to about 22 atomic percent.

Abstract: An article is coated with a multi-layer decorative and protective coating having the appearance of stainless steel. The coating comprises one or more electroplated layers on the surface of said article and vapor deposited on the electroplated layers a stack layer containing layers of refractory metal or metal alloy alternating with layers containing refractory metal nitrogen containing compounds and refractory metal alloy nitrogen containing compounds wherein the nitrogen content of the refractory metal nitrogen containing compounds and refractory metal alloy nitrogen containing compounds is from about 3 to about 22 atomic percent.

Abstract: An article is coated with a multi-layer decorative and protective coating having the appearance of stainless steel. The coating comprises one or more electroplated layers on the surface of said article and vapor deposited on the electroplated layers a color layer comprised of the reaction products of refractory metal or refractory metal alloy, nitrogen and oxygen wherein the total nitrogen and oxygen content is from about 4 to about 32 atomic percent with the nitrogen content being at least about 3 atomic percent.

Abstract: A coating system and method for forming the coating system on an article designed for use in a hostile environment, such as the superalloy turbine, combustor and augmentor components of a gas turbine engine. The method employs a nitrided zone in the surface of the superalloy substrate to inhibit the formation of deleterious topologically-close packed (TCP) phases in the substrate when protected by an aluminum-rich coating and optionally a thermal insulating ceramic layer. Superalloys of particular interest are those containing significant levels of TCP phase-forming elements, such as tungsten, rhenium, tantalum, molybdenum and chromium.

Abstract: In order to produce a wire electrode having a core consisting of a copper/zinc alloy and to produce a specific sheath layer, the sheath layer is coated onto the core at a temperature at which no diffusion occurs. The wire electrode is subsequently heated at a heating speed higher than 10° C. per second, briefly annealed at temperatures above 500° C. and subsequently cooled again very rapidly at cooling speeds higher than 10° C. per second.

Abstract: A portable electronic device incorporates PEM fuel cells and is designed to operate by the reaction of hydrogen from a hydride-containing fuel container and oxygen from the air, while efficiently removing the product water by a novel water transportation system. Temperature is effectively controlled by placing a plurality of fuel cell subunits as a generally planar array in the lid of the PC adjacent a heat transfer plate. A particularly efficient resupply system is provided where an electrolyzer that supplies H2 at a pressure sufficient to continue to power the PC and simultaneously recharge an operatively-connected container and a second spare container in the electrolyzer.

Abstract: An article is coated with a multi-layer coating comprising a nickel layer, a refractory metal layer, a sandwich layer comprised of a plurality of alternating layers of a refractory metal compound and a refractory metal Layer, and a refractory metal compound layer. The coating provides a decorative appearance to the article and also provides abrasion protection, corrosion protection, and improved chemical resistance.

Abstract: A method of coating of steel products such as plate and sheet using an aluminum-zinc coating alloy includes modifying the coating bath with a particulate compound constituent in effective amounts to decrease the spangle facet size of the coated product, improve tension bend rust stain performance, improve coated surface appearance when brushed, and coated product paintability. Constituents include borides such as titanium boride and aluminum borides, carbides such as titanium carbide, and aluminides such as titanium aluminide. The method produces a coated steel product that does not require temper rolling for painting.

Abstract: An article is coated with a multi-layer coating having the appearance of nickel. The coating comprises one or more electroplated layers on the surface of said article and vapor deposited on the electroplated layers a refractory metal or metal alloy nitride where the nitrogen content of said nitride is from about 6 to about 45 atomic percent.

Abstract: A joint body according to the invention is strong for a heat cycle and generates no local cracks. The joint body has the following features. An end portion of the metal member and the ceramic member are connected via a metal connection portion. The metal connection portion has a metallized layer formed on the ceramic member and a brazing connection portion interposing at least between the metallized layer and an end portion of the metal member. A melt point of a brazing member constructing the brazing connection portion is lower than that of a brazing member constructing the metallized layer.

Abstract: The present invention provides a ceramic circuit board comprising: a ceramic substrate and a metal circuit plate bonded to the ceramic substrate through a brazing material layer; wherein the brazing material layer is composed of Al—Si group brazing material and an amount of Si contained in the brazing material is 7 wt % or less. In addition, it is preferable to form a thinned portion, holes, or grooves to outer peripheral portion of the metal circuit plate. According to the above structure of the present invention, there can be provided a ceramic circuit board having both high bonding strength and high heat-cycle resistance, and capable of increasing an operating reliability as electronic device.

Abstract: A high temperature corrosion-resistant and abrasion-resistant coated member or part which is suitable for use under a severe high temperature corrosive and severe abrasive environment and in flying particles, and a manufacturing method thereof are provided. A manufacturing method of a high temperature corrosion-resistant and abrasion-resistant coated member wherein an Al diffusion and infiltration treatment is performed after a chromium carbide coating has been applied onto the surface of a base material, or wherein a chromium carbide coating layer whose outside surface is an Al diffusion layer is formed on the surface of the base material, and a gas turbine blade comprising the above member are provided.

Abstract: A personal ornament having its surface covered with a colored coating, the colored coating formed by dry-plating, which personal ornament comprises a basis material for personal ornament, composed of a copper alloy or zinc; a nickel plating layer on a surface of the basis material, or a nickel plating layer on a surface of a copper plating layer on a surface of the basis material; an amorphous nickel/phosphorus alloy plating layer on a surface of the nickel plating layer; and at least one colored coating layer on a surface of the amorphous nickel/phosphorus alloy plating layer, the colored coating layer formed by dry-plating, and wherein the amorphous nickel/phosphorus alloy plating layer has a phosphorus content of 11 to 16% by weight. As compared with conventional personal ornaments, this personal ornament is furnished with a colored coating having excellent corrosion resistance and can be produced at low cost.

Abstract: An article is coated with a multi-layer color and protective coating. The coating comprises a polymeric basecoat layer on the surface of said article and vapor deposited on the polymeric layer a refractory metal compound or refractory metal alloy compound color and protective layer.

Abstract: An article is coated with a multi-layer coating having the appearance of nickel. The coating comprises a polymeric basecoat layer on the surface of said article, vapor deposited on the polymeric layer, a stack layer comprised of alternating layers of refractory metal compound or refractory metal alloy compound alternating with refractory metal or refractory metal alloy, and vapor deposited on said stack layer a refractory metal or refractory metal alloy nitride color layer where the nitrogen content of said nitride is from about 6 to about 45 atomic percent.

Abstract: An article is coated with a multi-layer protective and decorative coating. The coating comprises a polymeric basecoat layer on the surface of said article, vapor deposited on the polymeric layer a stack layer comprised of alternating layers of refractory metal compound or refractory metal alloy compound alternating with refractory metal or refractory metal alloy, and vapor deposited on said stack layer a refractory metal compound or refractory metal alloy compound color layer.

Abstract: A method for coating stainless steel in which a metallic material layer of Cr and alloys of Cr and at least one of Mo, W, Ni, Si, Ti, Zr is deposited onto a metal substrate. The metallic material layer is then annealed so as to form a diffusion layer between the metallic protective coating and the metal substrate. Thereafter, the metallic material layer may be passivated, forming a stable composition of at least one of carbides, borides, nitrides, silicides, oxides, and mixtures thereof on the metallic protective coating. The protective coatings of this invention significantly reduce the corrosion rate of stainless steel used in bromide-based absorption systems.

Abstract: A substrate for a microelectronic package comprising a substrate that has grooves on a surface for bonding. A method for preparing a substrate for bonding comprising forming a grooved surface in the substrate for accepting a die for bonding, wherein the grooves are of sufficient size to provide a substantially uniform die bond, but no so large as to nullify the thermal path to the underlying substrate.

Abstract: A method for forming an epitaxial layer involves depositing a buffer layer on a substrate by a first deposition process, followed by deposition of an epitaxial layer by a second deposition process. By using such a dual process, the first and second deposition processes can be optimized, with respect to performance, growth rate, and cost, for different materials of each layer. A semiconductor heterostructure prepared by a dual deposition process includes a buffer layer formed on a substrate by MOCVD, and an epitaxial layer formed on the buffer layer, the epitaxial layer deposited by hydride vapor-phase deposition.

Abstract: A Cu plated ceramic substrate is used in a semiconductor. On a ceramic substrate layer, a thin-film Cr layer is put, and a thin-firm Au layer is put on the Cr layer. The Au layer is plated with Cu. By providing the Au and Cr layers between the ceramic plate and Cu layer, adhesibility is increased. A Pertier element which includes the Cu plated ceramic layer is employed in a semiconductor to absorb and generate heat efficiently.

Abstract: An article is coated with a multi-layer coating comprising a nickel layer, a refractory metal layer, and a refractory metal compound layer. The coating is decorative and also provides abrasion protection and corrosion protection.

Abstract: Provided is a composite member comprising a ceramic base and a metallic member which are bonded to each other. An active metal foil is disposed on the surface of the ceramic base and a solder material comprising Au or a solder material comprising an Au-Ag alloy is disposed on the active metal foil, the active metal foil and the solder material are heated to form a bonding layer, the metallic member is disposed on the surface of the bonding layer, and these are pressed and heated to bond the bonding layer and the metallic member through solid phase bonding. Since in this composite member the bonding layer and the metallic member are bonded by solid phase bonding, the composite members can be effectively inhibited from breakage caused by residual stress at the time of bonding and, besides, is excellent in thermal cycle characteristics and thermal shock characteristics.

Abstract: Disclosed are compositions of matter which include a thin metallic and/or metallic oxide, nitride, carbide, silicide, boride, or sulfide coating disposed directly upon a polymeric substrate, in the absence of a carrier layer for the thin coating. Also disclosed are methods to make the composition and an apparatus to practice the method.

Abstract: A method for making a stick resistant cook surface or cooking vessel having the stick resistance in which a hard substrate metal is buffed/polished to a high luster surface finish of less than 20 micro inches and then coated with a layer of zirconium nitride. The method further includes the step of polishing a stamped blank to the desired surface smoothness prior to the drawing/shaping step to provide a stick resistant surface in cooking vessels having side walls, such as pots and pans, which are otherwise difficult to buff in the interior due to the side wall geometry.

Abstract: A protective coat formed by thermal spraying, and having an outstanding durability against corrosion by a molten light alloy. A thermal spraying composite material used to form such a coat contains from about 30 to about 70% by weight of molybdenum boride, from about 20 to about 40% by weight of nickel or cobalt, from about 5 to about 20% by weight of chromium, and from about 5 to about 10% by weight of at least one metal boride selected from the borides of Cr, W, Zr, Ni and Nb.

Abstract: The present invention employs lightweight, flexible, plastic substrates for constructing flat panel displays, packaging materials and electro luminescence lamps. The display medium must be protected from oxygen and moisture in order to avoid degradation. In the present invention, at least one layer with barrier and electrode characteristics is deposited over the substrate that has both a low enough resistivity to function as an electrode for the display and low oxygen and moisture permeability. If lower permeability and/or higher conductivity is required, multiple alternating layers of barrier materials and conductive materials can be applied. The barrier material includes a thin metallic film, an organic polymer, a thin transparent dielectric, and a thin transparent conductive oxide. The conductive material includes a thin transparent conductive oxide, a thin transparent metallic film, and/or a metal nitride. Preferably there is a Polymer Multi Layer (PML) processed base coat deposited over the substrate.

Abstract: A thin film magnetic head includes an upper core layer and a lower core layer which are made of an Fe—M—O alloy, an Fe—M—T—O alloy or an NI—Fe—X alloy so that the upper core layer has a high saturation magnetic flux density, low coercive force and high resistivity, and the lower core layer has a lower saturation magnetic flux density than the upper core layer, low coercive force, high resistivity, and a low magnetostriction constant. Also the lower core layer is formed so that the thickness gradually decreases toward both side ends, and a gap layer can be formed on the lower core layer to have a uniform thickness. Since the lower core layer is formed by sputtering, a material having excellent soft magnetic material can be used, thereby enabling recording at high frequency.

Abstract: IC fabrication employs the deposition of aluminum as a metallization layer. Frequently, the aluminum is doped with copper in small amounts to improve electric properties. Low temperature deposition of these layers is preferred to ensure the proper microstructure and surface roughness. Low temperature deposition (below about 300° C.) results in the formation of copper precipitates which can be difficult to remove. Annealing the layer formed, either prior to, or after formation of capping layers and additional layers thereon, drives the copper precipitate back into solution, permitting small dimension fabrication.

Abstract: A method and resultant product are disclosed wherein a metal film is deposited by sputtering a metal cathode target in an essentially nonreactive atmosphere comprising inert gas and a reactive gas, wherein the concentration of reactive gas is sufficiently low that the sputtering is accomplished in the metallic mode, i.e. the film is deposited as metal. The metal film of the present invention is harder than a metal film sputtered in an atmosphere consisting of only inert gas. The method and resultant product may further comprise thermal oxidation of the metal film, which proceeds more efficiently than oxidation of a metal film sputtered in an atmosphere consisting of only inert gas.

Abstract: A synthetic-type spin-valve MR sensor having a pinned magnetic layer with a multi-layer film structure. In one embodiment, on a substrate are formed by layering a free magnetic layer, a pinned magnetic layer including first and second ferromagnetic films, which are mutually coupled antiferromagnetically and which enclose a nonmagnetic coupling film. A nonmagnetic conductive layer is enclosed between these two magnetic layers. An antiferromagnetic layer neighbors the pinned magnetic layer. The first ferromagnetic film neighboring the antiferromagnetic layer is formed from a high-resistivity Co-base material. By making the products of the saturation magnetization and the film thickness of the first ferromagnetic layer and the second ferromagnetic layer substantially equal, the apparent magnetic moment of the pinned magnetic layer as a whole is zero, and the magnetostatic action on the free magnetic layer is eliminated or reduced.

Abstract: A ceramic metal matrix composite and copper material having a layer of ceramic metal matrix composite such as aluminum silicon carbide (Al—SiC) bonded to a layer of metal such as copper useful for forming heat-dissipating components for microelectronics concerned with lightweight, high stiffness, high thermal conductivity and compatible thermo expansion characteristics. The clad material may be formed from plurality of sucessive layers of composite and metal. The material is formed by rolling an extruded strip of Al—SiC with the metal layer. Alternately, an interim layer of aluminum, aluminum silicon or other bond-enhancing material is clad to the metal layer prior to rolling it with the composite. The interim layer is thought to form a stronger bond with the exposed aluminum matrix portion of the composites layer.

Abstract: The invention relates to a method of applying a coating by physical vapor deposition onto an article of organic material, in particular of non- conductive organic material such as plastic and/or epoxy material, especially ABS (Acrylonitrile-Butadiene-Styrene Copolymers) and polymers with high temperature resistance, or onto an article of another composition coated with such organic material, wherein a Cr layer is deposited on the article prior to deposition of said coating to form a diffusion barrier for water coming from said article, said Cr layer itself being deposited by a physical vapor deposition process comprising at least the following steps: