The Alkali Metal Is Lithium Patents (Class 429/231.95)
  • Patent number: 9819011
    Abstract: An electrode material for an electrochemical energy store, in particular for a lithium cell, includes at least one first lithiatable active material, which is based on a transition metal oxide, and at least one second lithiatable active material, which is based on a doped transition metal oxide, the doped transition metal oxide of the second lithiatable active material being doped with at least one redox-active element. Also described is a method for manufacturing an electrode of this type.
    Type: Grant
    Filed: December 15, 2014
    Date of Patent: November 14, 2017
    Assignee: ROBERT BOSCH GMBH
    Inventors: Thomas Eckl, Anika Marusczyk, Malte Rolff, Ingo Kerkamm
  • Patent number: 9812888
    Abstract: The invention disclosed is a method for decreasing the internal resistance or impedance of a battery or electrochemical cell is described which comprises the step of discharging the battery or cell until it reaches an overdischarge condition and maintaining the battery or cell in the overdischarge condition for a period of time sufficient to effect a diminution of the internal resistance or impedance of a battery or electrochemical cell; and a battery or electrochemical cell having a reduced impedance.
    Type: Grant
    Filed: January 16, 2014
    Date of Patent: November 7, 2017
    Assignee: Bathium Canada Inc.
    Inventors: Patrick Leblanc, Frederic Cotton, Thierry Guena, Cedric Reboul-Salze, Marc Deschamps, Thomas Calvez, Vincent Bodenez, Philippe Bernardo, Mathieu Dru
  • Patent number: 9806333
    Abstract: A secondary battery capable of obtaining superior cycle characteristics and superior swollenness characteristics is provided. The secondary battery includes a cathode and an anode capable of inserting and extracting an electrode reactant; and an electrolyte containing a solvent and an electrolyte salt. The anode has an anode active material layer on an anode current collector. The anode active material layer contains a plurality of crystalline anode active material particles having silicon (Si) as an element. The plurality of anode active material particles contain a spherical particle and a nonspherical particle.
    Type: Grant
    Filed: January 11, 2017
    Date of Patent: October 31, 2017
    Assignee: SONY CORPORATION
    Inventors: Takakazu Hirose, Kenichi Kawase, Kazunori Noguchi, Takayuki Fujii
  • Patent number: 9793573
    Abstract: A lithium ion secondary battery that can be charged without regard to polarity is disclosed. The lithium ion secondary battery includes a lithium ion secondary battery unit, which includes a first electrode layer and a second electrode layer that are laminated on an electrolytic region. The first electrode layer and the second electrode layer contain Li2Mn2O4 as a common active material.
    Type: Grant
    Filed: May 31, 2012
    Date of Patent: October 17, 2017
    Assignee: NAMICS CORPORATION
    Inventors: Mamoru Baba, Takayuki Fujita
  • Patent number: 9786903
    Abstract: The present invention provides a positive electrode active material for a lithium secondary battery including a core including first lithium cobalt oxide, and a surface modifying layer positioned on a surface of the core. The surface modifying layer includes a lithium compound discontinuously distributed on the surface of the core, and second lithium cobalt oxide distributed while making a contact with or adjacent to the lithium compound, with a Li/Co molar ratio of less than 1. The positive electrode active material according to the present invention forms a lithium deficient structure in the positive electrode active material of lithium cobalt oxide and changes two-dimensional lithium transport path into three-dimensional path. The transport rate of lithium ions may increase when applied to a battery, thereby illustrating improved capacity and rate characteristic without decreasing initial capacity.
    Type: Grant
    Filed: October 2, 2015
    Date of Patent: October 10, 2017
    Assignee: LG Chem, Ltd.
    Inventors: Ji Hoon Ryu, Chi Ho Jo, Min Suk Kang, Sun Sik Shin, Wang Mo Jung
  • Patent number: 9780361
    Abstract: In an example of the method disclosed herein, SiOx (0<x<2) particles are combined with a lithium metal. The SiOx (0<x<2) particles and the lithium metal are caused to react to form lithium oxide nanoparticles in a silicon matrix. At least some of the lithium oxide nanoparticles are removed from the silicon matrix to form porous silicon particles.
    Type: Grant
    Filed: November 12, 2014
    Date of Patent: October 3, 2017
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Xingcheng Xiao, Weidong Zhou
  • Patent number: 9773581
    Abstract: The present invention provides a cathode material for a Li—S battery. The cathod material comprises dehydrogenized acrylonitrile based polymer, sulfur and GNS (Graphene NanoSheet), wherein the cathode material particles are spherical, the content of dehydrogenized acrylonitrile based polymer is 20-79 wt %, the content of sulfur is 20-79 wt % and the content of GNS is 1-30 wt %. Also provided a method for preparing a cathode material, a cathode made of the cathod material and a Li—S battery comprising the cathode.
    Type: Grant
    Filed: November 30, 2012
    Date of Patent: September 26, 2017
    Assignees: Robert Bosch GmbH, Shanghai Jiaotong University
    Inventors: Jiulin Wang, Lichao Yin, Jun Yang, NaHong Zhao, Longjie Zhou
  • Patent number: 9755240
    Abstract: Provided is an electrode for a sodium molten-salt battery in which degradation of the electrode can be suppressed even when charging and discharging are repeated, and which has excellent cycle characteristics. The electrode for a sodium molten-salt battery includes a current collector and an electrode mixture adhering to a surface of the current collector, in which the electrode mixture includes an electrode active material and a binder containing a polymer, and the polymer does not contain a fluorine atom. The polymer can include, for example, at least one selected from the group consisting of polyamide resins and polyimide resins or at least one selected from the group consisting of acrylic resins, rubber-like polymers, and cellulose derivatives.
    Type: Grant
    Filed: December 17, 2013
    Date of Patent: September 5, 2017
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Shoichiro Sakai, Koma Numata, Eiko Imazaki, Atsushi Fukunaga, Koji Nitta, Shinji Inazawa
  • Patent number: 9754728
    Abstract: To improve the reliability of a power storage device. A granular active material including carbon is used, and a net-like structure is formed on part of a surface of the granular active material. In the net-like structure, a carbon atom included in the granular active material is bonded to a silicon atom or a metal atom through an oxygen atom. Formation of the net-like structure suppresses reductive decomposition of an electrolyte solution, leading to a reduction in irreversible capacity. A power storage device using the above active material has high cycle performance and high reliability.
    Type: Grant
    Filed: September 20, 2013
    Date of Patent: September 5, 2017
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventors: Nobuhiro Inoue, Ryota Tajima, Tamae Moriwaka, Junpei Momo, Teppei Oguni, Kai Kimura, Kazutaka Kuriki, Shunpei Yamazaki
  • Patent number: 9748561
    Abstract: A method of forming a carbon coating includes heat treating lithium transition metal composite oxide Li0.9+aMbM?cNdOe, in an atmosphere of a gas mixture including carbon dioxide and compound CnH(2n+2?a)[OH]a, wherein n is 1 to 20 and a is 0 or 1, or compound CnH(2n), wherein n is 2 to 6, wherein 0?a?1.6, 0?b?2, 0?c?2, 0?d?2, b, c, and d are not simultaneously equal to 0, e ranges from 1 to 4, M and M? are different from each other and are selected from Ni, Co, Mn, Mo, Cu, Fe, Cr, Ge, Al, Mg, Zr, W, Ru, Rh, Pd, Os, Ir, Pt, Sc, Ti, V, Ga, Nb, Ag, Hf, Au, Cs, B, and Ba, and N is different from M and M? and is selected from Ni, Co, Mn, Mo, Cu, Fe, Cr, Ge, Al, Mg, Zr, W, Ru, Rh, Pd, Os, Ir, Pt, Sc, Ti, V, Ga, Nb, Ag, Hf, Au, Cs, B, Ba, and a combination thereof, or selected from Ti, V, Si, B, F, S, and P, and at least one of the M, M?, and N comprises Ni, Co, Mn, Mo, Cu, or Fe.
    Type: Grant
    Filed: March 7, 2014
    Date of Patent: August 29, 2017
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: In Hyuk Son, Jun Young Mun, Jin-Hwan Park, Chan Ho Pak, Seung Jae Lee, Hyo Rang Kang
  • Patent number: 9737876
    Abstract: Provided are a carrier for a dry adsorbent for carbon dioxide, including spherical silica whose surface is engraved in the form of nanowires, and a method for preparing the same. Although the carrier for a dry adsorbent for carbon dioxide including spherical silica that has nanowires on the surface thereof has a very non-uniform shape, it serves better as a host structure adsorbing carbon dioxide as compared to the conventional carrier for a carbon dioxide adsorbent, and thus may be used for a host-guest adsorbent applicable to a fluidized bed process. In addition, the method for preparing a carrier for a carbon dioxide adsorbent provides nanowire-coated silicon spheres having an increased surface roughness and an increased surface area, thereby providing increased carbon dioxide capturing efficiency. Further, since the method for forming nanowires is simple, it is easy to carry out mass production without any separate process, thereby providing excellent cost efficiency.
    Type: Grant
    Filed: November 18, 2015
    Date of Patent: August 22, 2017
    Assignee: INDUSTRY-ACADEMIC COOPERATION FOUNDATION, YONSEI UNIVERSITY
    Inventors: Hyung Hee Cho, Hokyu Moon, Geehong Choi, Beom Seok Kim, Donghwi Lee, Hwanseong Lee, Hoanju Yoo, Dong Il Shim
  • Patent number: 9735425
    Abstract: A process for producing a silicon:silicon oxide: lithium composite (SSLC) material useful as a negative electrode active material for non-aqueous battery cells includes: producing a partially lithiated SSLC material by way of mechanical mixing; subsequently producing a further prelithiated SSLC material by way of spontaneous lithiation procedure; and subsequently producing a delithiated SSLC material by way of reacting lithium silicide within the dispersed prelithiated SSLC material with organic solvent(s) to extract lithium from the prelithiated SSLC material, until reactivity of lithium silicide within the prelithiated SSLC material with the organic solvent(s) ceases. The delithiated SSLC material is a porous plastically deformable matrix having nano silicon embedded therein. The delithiated SSLC material can have a lithium silicide content of less than 0.5% by weight.
    Type: Grant
    Filed: March 2, 2016
    Date of Patent: August 15, 2017
    Assignee: EOCELL LTD
    Inventors: Yuriy Matus, Michael Pak
  • Patent number: 9722254
    Abstract: This disclosure relates to a battery and a method for its manufacture. The method of manufacture may include forming a cathode layer proximate to a cathode current collector. The method further includes forming an electrolyte layer proximate to the cathode layer and an anode layer proximate to the electrolyte layer. The method additionally includes forming an anode current collector layer proximate to the anode layer. At least one of the cathode current collector layer or the anode current collector layer includes a plurality of graphene monolayers. The method yet further includes determining a stepped arrangement of the graphene monolayers; and patterning at least a portion of the plurality of graphene monolayers according to the stepped arrangement.
    Type: Grant
    Filed: July 27, 2015
    Date of Patent: August 1, 2017
    Assignee: X Development LLC
    Inventor: Ramesh C. Bhardwaj
  • Patent number: 9716264
    Abstract: An electrode for a lithium secondary battery includes a silicon-based alloy, and has a surface roughness of about 1 to about 10 ?m and a surface roughness deviation of 5 ?m or less. A method of manufacturing the electrode includes mixing an electrode composition, milling the composition, coating the milled composition on a current collector, and drying the milled composition. A lithium secondary battery includes the electrode.
    Type: Grant
    Filed: August 23, 2012
    Date of Patent: July 25, 2017
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Soon-Sung Suh, Sung-Hwan Moon, Yury Matulevich, Seung-Uk Kwon, Yo-Han Park, Chang-Ui Jeong, Jae-Hyuk Kim, Chun-Gyoo Lee, Jong-Seo Choi
  • Patent number: 9711817
    Abstract: A polymer electrolyte membrane which comprises a polymer electrolyte having sulfonic acid groups, and contains any one of the following (a) to (c): (a) cerium ions and an organic compound (X) capable of forming an inclusion compound with cerium ions; (b) an inclusion compound (Y) comprising the organic compound (X) including cerium ions; and (c) at least one of cerium ions and the organic compound (X), and the inclusion compound (Y).
    Type: Grant
    Filed: September 13, 2007
    Date of Patent: July 18, 2017
    Assignee: Asahi Glass Company, Limited
    Inventors: Eiji Endoh, Yoshitaka Doi
  • Patent number: 9705126
    Abstract: An objective is to reduce the sheet resistance and gas evolution in a battery electrode comprising a conductive intermediate layer capable of reducing or shutting off a current when overcharged. A battery electrode (12) comprises a conductive intermediate layer (123) being placed between a current collector (122) and an active layer (124) while comprising conductive particles (50) and a binder (60). The mass proportion of conductive particles (50) is equal to or larger than the mass proportion of the binder (60). Conductive particles (50) has a size distribution that exhibits a first peak with the maximum at a first particle diameter value and a second peak with the maximum at a second particle diameter value larger than the first particle diameter value. The intermediate layer (123) contains 10% to 60% by mass of conductive particles (52) having particle diameters that belong to the second peak.
    Type: Grant
    Filed: October 21, 2010
    Date of Patent: July 11, 2017
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Koji Takahata
  • Patent number: 9698413
    Abstract: Provided are a cathode active material having high capacity and excellent lifetime characteristics as well as being inexpensive by mixing transition metal oxide having high irreversible capacity with composite dimensional manganese oxide (CDMO) of the following Chemical Formula 1, which has high capacity and good lifetime characteristics but is difficult to be charged and discharged by being used alone, and a lithium secondary battery including the cathode active material: xMnO2.(1?x)Li2MnO3 (0<x<1).
    Type: Grant
    Filed: November 22, 2013
    Date of Patent: July 4, 2017
    Assignee: LG CHEM, LTD.
    Inventors: Jung Hwan Park, Hyun Seok Lee, Youn Kyoung Lee, Ji Hee Ahn, Hoe Jin Hah
  • Patent number: 9673435
    Abstract: A nonaqueous electrolyte secondary battery 100 according to the present invention is provided with an electrode assembly 80 having a structure in which a positive electrode 10 and a negative electrode 20 are stacked with a separator 30 interposed therebetween. A porous filler layer 32 is formed between the positive electrode 10 and the separator 30. The filler layer 32 contains a filler made of an inorganic material and contains a binder. The relationship T>D holds where T is the average thickness of the filler layer 32 and D is the average particle diameter of a positive electrode active material 15 present in the positive electrode 10 facing the filler layer 32, and a pressure applied to the electrode assembly 80 in the stacking direction is set to at least 0.1 MPa.
    Type: Grant
    Filed: May 2, 2011
    Date of Patent: June 6, 2017
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Tomoyoshi Ueki, Hideaki Fujita, Harunari Shimamura
  • Patent number: 9661276
    Abstract: A peer to peer surveillance architecture comprising a plurality of independent nodes for capturing, analyzing, storing, and viewing surveillance information is disclosed. The surveillance architecture has no central controller or single point of failure because of the peer to peer or independent relationship between its nodes. Generally, surveillance information of various types is captured by one or more capture nodes and transmitted to or one or more viewing, content storage, or server nodes for display, analysis, storage, or a combination thereof. Server nodes may provide authentication services to validate user or device credentials prior to granting access to surveillance information. In one or more embodiments, specialized video compression hardware is provided to allow high quality video surveillance information to be transmitted across low bandwidth connections. Compression may also be performed on other types of surveillance information.
    Type: Grant
    Filed: February 13, 2015
    Date of Patent: May 23, 2017
    Assignee: Leverage Information Systems, Inc.
    Inventor: Raymond G. Leblond
  • Patent number: 9653726
    Abstract: A rechargeable lithium battery including a negative electrode including a silicon-based negative active material; a positive electrode including a positive active material including a sacrificial positive active material selected from lithium nickel oxides, lithium molybdenum oxides, and combinations thereof; and a non-aqueous electrolyte, is disclosed.
    Type: Grant
    Filed: July 23, 2013
    Date of Patent: May 16, 2017
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Soon-Rewl Lee, Ick-Kyu Choi, Young-Ki Kim, Young-Hun Lee, Na-Leum Yoo, Na-Ri Park, Yong-Chul Park
  • Patent number: 9649688
    Abstract: A lithium anode containing spherical lithium metal particles with an average diameter of between 5 and 200 ?m, which are bonded with a fluorine-free rubber-like binding agent from the groups saturated polyolefins and polyolefin copolymers, such as EPM (ethylene-propylene copolymers), EPDM (ethylene-propylene terpolymers) and polybutenes unsaturated polymers (diene polymers and diene copolymers), such as natural rubbers (NR), butadiene rubbers (BR), styrene-butadiene rubbers (SBR), polyisoprene rubbers and butyl rubbers (IIR, such as polyisobutylene isoprene rubber, PIBI) as well as heteroelement-containing copolymers, for example saturated copolymer rubbers, such as ethylene vinyl acetate (EVM), hydrogenated nitrile-butadiene rubber (HNBR), epichlorhydrin rubber (ECO), acrylate rubbers (ACM) and silicon rubbers (SI), as well as unsaturated copolymers, such as nitrile rubbers (NBR), for example, as well as galvanic cells containing the bonded lithium anode according to the invention and method for producin
    Type: Grant
    Filed: December 12, 2013
    Date of Patent: May 16, 2017
    Assignee: Rockwood Lithium GmbH
    Inventors: Ulrich Wietelmann, Ute Emmel, Christoph Hartnig
  • Patent number: 9640832
    Abstract: A non-aqueous electrolyte secondary battery that has a battery element including a positive electrode member, a negative electrode member, and a non-aqueous electrolyte solution. The negative electrode member contains graphitizable carbon. With respect to 100 parts by weight of the non-aqueous electrolyte solution, fluoroethylenecarbonate is added at 0.5 parts by weight or more and 1.0 parts by weight or less, and lithium difluorobis(oxalato)phosphate is added at 0.5 parts by weight or more and 1.0 parts by weight or less, or fluoroethylenecarbonate and lithium difluorobis(oxalato)phosphate are added at 0.5 parts by weight or more and 2.0 parts by weight or less in total.
    Type: Grant
    Filed: July 22, 2013
    Date of Patent: May 2, 2017
    Assignee: MURATA MANUFACTURING CO., LTD.
    Inventor: Seitaro Washizuka
  • Patent number: 9634325
    Abstract: A negative active material, a negative electrode, a lithium battery including the negative active material, and a method of manufacturing the negative active material, the negative electrode, and the lithium battery. The negative active material includes a silicon-based alloy including Si, Ti, Ni, and Fe components. The silicon-based alloy includes a Ti2Ni phase as an inactive phase and active silicon having a lower content than that of typical silicon-based alloys. The negative active material may improve discharge capacity and lifetime characteristics of lithium batteries.
    Type: Grant
    Filed: November 26, 2014
    Date of Patent: April 25, 2017
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Seung-Uk Kwon, Jae-Hyuk Kim, Soon-Sung Suh, Hee-Young Chu, Chang-Ui Jeong, Yo-Han Park, Yury Matulevich, Chun-Gyoo Lee
  • Patent number: 9620758
    Abstract: To realize high capacity of batteries, an object of the invention is to provide nonaqueous electrolyte secondary batteries which are unlikely to become swollen when charged to a high voltage and allowed to stand in a high temperature atmosphere. The nonaqueous electrolyte secondary battery includes a positive electrode including a positive electrode active material, a negative electrode including a negative electrode active material, a nonaqueous electrolyte, and a separator disposed between the positive electrode and the negative electrode. An inorganic particle layer is disposed between the positive electrode and the separator or between the negative electrode and the separator. The inorganic particle layer contains a polymer with a polyethylene glycol group. The polymer with a polyethylene glycol group has an average molecular weight of not less than 200.
    Type: Grant
    Filed: May 10, 2012
    Date of Patent: April 11, 2017
    Assignee: SANYO Electric Co., Ltd.
    Inventors: Nobuhiro Sakitani, Takanobu Chiga, Hiroyuki Fujimoto
  • Patent number: 9614225
    Abstract: A positive active material including a compound represented by Li1+xM1?kMekO2. A surface part of a particle of the positive active material has a mole ratio [Me/M] (A) of element represented by Me to element represented by M in Li1+xM1?kMekO2 of 0.05?A?0.60; the entire particle has a mole ratio [Me/M] (B) of element represented by Me to element represented by M in Li1+xM1?kMekO2 of 0.003?B?0.012; and element represented by Me has a concentration difference of between two positions of less than or equal to about 0.02 wt % in an inner part of the particle. In Li1+xM1?kMekO2, ?0.2?x?0.2, 0<k?0.05 M is one selected from Ni, Mn, Co, and a combination thereof, Me is one selected from Al, Mg, Ti, Zr, B, Ni, Mn, and a combination thereof, and M is not the same element as Me or does not include the same element as Me.
    Type: Grant
    Filed: December 10, 2012
    Date of Patent: April 4, 2017
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Jung-Joon Park
  • Patent number: 9608269
    Abstract: The invention relates to electrodes that contain active materials of the formula: NaaXbMcM?d(condensed polyanion)e(anion)f; where X is one or more of Na+, Li+ and K+; M is one or more transition metals; M? is one or more non-transition metals; and where a>b; c>0; d?0; e?1 and f?0. Such electrodes are useful in, for example, sodium ion battery applications.
    Type: Grant
    Filed: September 25, 2012
    Date of Patent: March 28, 2017
    Assignee: FARADION LTD.
    Inventor: Jeremy Barker
  • Patent number: 9595709
    Abstract: Disclosed are an anode active material comprising a lithium metal oxide, and a metal powder reacting with lithium ions present in an electrolyte to form a lithium alloy, or a metal oxide, the metal powder or the metal oxide having a content of not lower than 1% by weight and not higher than 30% by weight, based on the total weight of an anode mix, and a lithium secondary battery comprising the same.
    Type: Grant
    Filed: April 16, 2013
    Date of Patent: March 14, 2017
    Assignee: LG CHEM, LTD.
    Inventors: Jihyun Kim, Jae Hyun Lee, SooHyun Lim
  • Patent number: 9590250
    Abstract: A layer system includes at least three layers, the three layers including a top electrode layer, a bottom electrode layer, and an electrolyte layer situated between the top electrode layer and the bottom electrode layer. The electrolyte layer has a solid-state electrolyte, and at least one of the top and bottom electrode layers includes a paste-like composite layer. A layer system of this type may be used to manufacture in particular energy stores, such as rechargeable lithium-ion accumulators, having an enhanced capacity. Moreover, a method for producing a layer system or an energy store is described.
    Type: Grant
    Filed: March 20, 2012
    Date of Patent: March 7, 2017
    Assignee: ROBERT BOSCH GMBH
    Inventors: Tjalf Pirk, Gilbert Moersch, Oliver Schecker
  • Patent number: 9577247
    Abstract: A positive electrode active material capable of improving an output performance of a nonaqueous electrolyte secondary battery is provided. A positive electrode active material of a nonaqueous electrolyte secondary battery 1 contains a first positive electrode active material and a second positive electrode active material. In the first positive electrode active material, the content of cobalt is 15% or more on an atomic percent basis in transition metals. In the second positive electrode active material, the content of cobalt is 5% or less on an atomic percent basis in transition metals. An average secondary particle diameter r1 of the first positive electrode active material is smaller than an average secondary particle diameter r2 of the second positive electrode active material.
    Type: Grant
    Filed: August 30, 2012
    Date of Patent: February 21, 2017
    Assignee: SANYO Electric Co., Ltd.
    Inventors: Daisuke Nishide, Fumiharu Niina, Hiroshi Kawada, Toshikazu Yoshida, Yoshinori Kida
  • Patent number: 9573820
    Abstract: A rechargeable lithium battery includes a non-aqueous electrolyte, a negative electrode including a silicon-based negative active material, and a positive active material including a compound represented by a Chemical Formula 1, Li1+xCo1?yMyO2, wherein, ?0.2?x?0.2, 0<y?0.2, and M includes Ni and one selected from Mn, B, Mg, Ca, Sr, Ba, Ti, V, Cr, Fe, Cu, Al, and a combination thereof.
    Type: Grant
    Filed: February 18, 2014
    Date of Patent: February 21, 2017
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Young-Ki Kim, Young-Hun Lee, Na-Leum Yoo, Na-Ri Park, Soon-Rewl Lee, Ick-Kyu Choi, Yong-Chul Park
  • Patent number: 9570748
    Abstract: A lithium ion battery includes an anode and a cathode. The cathode includes a lithium, manganese, nickel, and oxygen containing compound. An electrolyte is disposed between the anode and the cathode. A protective layer is deposited between the cathode and the electrolyte. The protective layer includes pure lithium phosphorus oxynitride and variations that include metal dopants such as Fe, Ti, Ni, V, Cr, Cu, and Co. A method for making a cathode and a method for operating a battery are also disclosed.
    Type: Grant
    Filed: October 12, 2012
    Date of Patent: February 14, 2017
    Assignee: UT-BATTELLE, LLC
    Inventors: Nancy J. Dudney, Chengdu Liang, Jagjit Nanda, Gabriel M. Veith, Yoongu Kim, Surendra Kumar Martha
  • Patent number: 9564656
    Abstract: Provided is a process for producing an alkali metal battery, comprising: (A) Preparing an anode material suspension and a cathode active material suspension; (B) Assembling a porous cell framework composed of a first conductive foam structure, a second conductive foam structure, and a porous separator disposed between said first and said second conductive foam structure; and (C) Injecting the anode suspension into pores of the first conductive foam structure to form an anode and injecting cathode suspension into pores of the second conductive foam structure to form a cathode, wherein the anode active material has a material mass loading no less than 20 mg/cm2 or the cathode active material has a material mass loading no less than 15 mg/cm2 for an organic or polymer material or no less than 40 mg/cm2 for an inorganic material. The resulting batteries exhibit exceptional gravimetric and volumetric energy densities and long cycle life.
    Type: Grant
    Filed: September 14, 2015
    Date of Patent: February 7, 2017
    Assignee: Nanotek Instruments, Inc.
    Inventors: Aruna Zhamu, Bor Z Jang
  • Patent number: 9553292
    Abstract: In an aspect, a rechargeable lithium battery that includes a positive electrode; negative electrode; a separator interposed between the positive electrode and the negative electrode and including a porous substrate and a coating layer formed on at least one side of the porous substrate; and an electrolyte including a lithium salt, a non-aqueous organic solvent, and an additive is provided.
    Type: Grant
    Filed: December 19, 2013
    Date of Patent: January 24, 2017
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Moon-Sung Kim, Woo-Cheol Shin, Sang-Il Han, Sang-Hoon Kim, Byung-Joo Chung, Duck-Hyun Kim, Myung-Hwan Jeong, Jung-Yi Yu, Seung-Tae Lee, Tae-Hyun Bae, Mi-Hyun Lee, Eon-Mi Lee, Ha-Rim Lee, In-Haeng Cho, E-Rang Cho, Dong-Myung Choi, Vladimir Egorov, Pavel Alexandrovich Shatunov, Alexey Tereshchenko, Denis Chernyshov, Makhmut Khasanov, Jung-Hyun Nam
  • Patent number: 9553311
    Abstract: Provided is a cathode active material for a non-aqueous electrolyte secondary battery capable of obtaining high initial discharge capacity and good output characteristics at low temperature. In order to achieve this, a cathode active material that is a lithium nickel composite oxide composed of secondary particles that are an aggregate of primary particles is expressed by the general expression: Liw(Ni1-x-yCoxAly)1-zMzO2 (where 0.98?w?1.10, 0.05?x?0.3, 0.01?y?0.1, 0?z?0.05, and M is at least one metal element selected from a group consisting of Mg, Fe, Cu, Zn and Ga), and where the crystallite diameter at (003) plane of that lithium nickel composite oxide that is found by X-ray diffraction and the Scherrer equation is within the range of 1200 ? to 1600 ? is used as the cathode material.
    Type: Grant
    Filed: December 9, 2014
    Date of Patent: January 24, 2017
    Assignees: SUMITOMO METAL MINING CO., LTD, TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Katsuya Kase, Syuhei Oda, Ryuichi Kuzuo, Yutaka Oyama
  • Patent number: 9543578
    Abstract: A method for manufacturing a negative electrode active material for a secondary battery that uses a non-aqueous electrolyte, including the steps of: depositing silicon according to an electron beam vapor-deposition method with metallic silicon as a raw material on a substrate of which temperature is controlled from 800 to 1100° C. at a vapor deposition rate exceeding 1 kg/hr in the range of film thickness of 2 to 30 mm; and pulverizing and classifying the deposited silicon to obtain the negative electrode active material. As a result, there is provided a method for manufacturing a negative electrode active material of silicon particles as an active material useful for a negative electrode of a non-aqueous electrolyte secondary battery that is, while maintaining high initial efficiency and battery capacity of silicon, excellent in the cycle characteristics and has a reduced volume change during charge/discharge.
    Type: Grant
    Filed: October 26, 2012
    Date of Patent: January 10, 2017
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Tetsuo Nakanishi, Yoshiyasu Yamada, Kazuyuki Taniguchi
  • Patent number: 9537144
    Abstract: A sulfur-containing electrode has a binder comprising a single-lithium ion conductor. The electrode may be used a cathode in a lithium-sulfur or silicon-sulfur battery.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: January 3, 2017
    Assignee: GM Global Technology Operations LLC
    Inventors: Xiaosong Huang, Mei Cai, Mark W. Verbrugge, Li Yang
  • Patent number: 9531002
    Abstract: A method is provided for cycling power in a transition metal cyanometallate (TMCM) cathode battery. The method provides a battery with a TMCM cathode, an anode, and an electrolyte, where TMCM corresponds to the chemical formula of AXM1NM2M(CN)Y-d(H2O), where “A” is an alkali or alkaline earth metal, and where M1 and M2 are transition metals. The method charges the battery using a first charging current, or greater. In response to the charging current, a plating of “A” metal is formed overlying a plating surface of the anode. In response to discharging the battery, the “A” metal plating is removed from the anode plating surface. In one aspect, in an initial charging of the battery, a permanent solid electrolyte interphase (SEI) layer is formed overlying the anode plating surface. In subsequent charging and discharging cycles, the permanent SEI layer is maintained overlying the anode plating surface.
    Type: Grant
    Filed: March 25, 2015
    Date of Patent: December 27, 2016
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Yuhao Lu, Long Wang, Jong-Jan Lee
  • Patent number: 9515318
    Abstract: Compositions and methods of making are provided for mesoporous metal oxide microspheres electrodes. The mesoporous metal oxide microsphere compositions comprise (a) microspheres with an average diameter between 200 nanometers (nm) and 10 micrometers (?m); (b) mesopores on the surface and interior of the microspheres, wherein the mesopores have an average diameter between 1 nm and 50 nm and the microspheres have a surface area between 50 m2/g and 500 m2/g. The methods of making comprise forming composite powders. The methods may also comprise refluxing the composite powders in a basic solution to form an etched powder, washing the etched powder with an acid to form a hydrated metal oxide, and heat-treating the hydrated metal oxide to form mesoporous metal oxide microspheres.
    Type: Grant
    Filed: February 11, 2013
    Date of Patent: December 6, 2016
    Assignee: UT-Battelle, LLC
    Inventors: Mariappan Parans Paranthaman, Hansan Liu, Gilbert M. Brown, Xiao-Guang Sun, Zhonghe Bi
  • Patent number: 9496547
    Abstract: A composite electrode material of a lithium secondary battery and a lithium secondary battery are provided. The composite electrode material of the lithium secondary battery at least includes an electrode active powder and a nanoscale coating layer coated on the surface of the electrode active powder, wherein the nanoscale coating layer is composed of a metastable state polymer, a compound A, a compound B, or a combination thereof. The compound A is a monomer having a reactive terminal functional group, and the compound B is a heterocyclic amino aromatic derivative used as an initiator. The weight ratio of the nanoscale coating layer to the composite electrode material of the lithium secondary battery is 0.005% to 10%.
    Type: Grant
    Filed: June 5, 2013
    Date of Patent: November 15, 2016
    Assignee: Industrial Technology Research Institute
    Inventors: Li-Duan Tsai, Yueh-Wei Lin, Chia-Chen Fang, Wei-Hsin Wu, Deng-Tswen Shieh
  • Patent number: 9496549
    Abstract: A negative electrode for a rechargeable lithium battery includes: a current collector; and a negative active material layer on the current collector. The negative active material layer includes a negative active material including a graphite-silicon composite including a graphite particle, a silicon (Si) particle on a surface of the graphite particle, and a carbon coating layer surrounding the graphite particle on the surface of the silicon (Si) particle. A rechargeable lithium battery includes the negative electrode.
    Type: Grant
    Filed: November 11, 2014
    Date of Patent: November 15, 2016
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Chul Youm
  • Patent number: 9490482
    Abstract: A galvanic element containing a substantially transition metal-free oxygen-containing conversion electrode, a transition metal-containing cathode, and an aprotic lithium electrolyte. The substantially transition metal-free oxygen-containing conversion electrode materials contain lithium hydroxide and/or lithium peroxide and/or lithium oxide, and in the charged state additionally contain lithium hydride, and are contained in a galvanic element, for example a lithium battery, as the anode. Methods for producing substantially transition metal-free oxygen-containing conversion electrode materials and galvanic elements made of substantially transition metal-free oxygen-containing conversion electrode materials are also provided.
    Type: Grant
    Filed: November 18, 2010
    Date of Patent: November 8, 2016
    Inventor: Ulrich Wietelmann
  • Patent number: 9478802
    Abstract: The present invention aims to provide a nonaqueous electrolyte secondary battery having excellent charge discharge cycle characteristics in a high-temperature environment. The present invention relates to a nonaqueous electrolyte secondary battery which includes a positive electrode in which a positive electrode active material mixture layer is formed, a negative electrode in which a negative electrode active material mixture layer is formed, a nonaqueous electrolyte, and a separator, and in the above nonaqueous electrolyte secondary battery, on at least one surface of the positive electrode active material mixture layer and the negative electrode active material mixture layer, an inorganic particle layer containing a rare earth element compound is formed.
    Type: Grant
    Filed: October 30, 2013
    Date of Patent: October 25, 2016
    Assignee: SANYO Electric Co., Ltd.
    Inventors: Akihiro Kawakita, Takeshi Ogasawara
  • Patent number: 9478834
    Abstract: A fire suppressant battery system has a battery pack, a non-conductive fire suppressant liquid in a fire suppressant bladder, and a fire suppressant protective layer. The bladder melts at a temperature above the battery pack's desired operating condition, has a cavity for receiving the liquid and contacts at least a section of the battery pack. The protective layer is positioned onto a portion of the fire suppression bladder's exterior surface that is on the opposite side to that which contacts the battery pack.
    Type: Grant
    Filed: April 25, 2013
    Date of Patent: October 25, 2016
    Assignee: Electrochem Solutions, Inc.
    Inventors: Todd E. Sweetland, Brian Robert Peterson
  • Patent number: 9478827
    Abstract: A non-aqueous electrolyte solution for a lithium secondary battery and a lithium secondary battery including the same are provided. The non-aqueous electrolyte solution includes an organic solvent, an ionizable lithium salt, a dinitrile compound including an ether bond represented by Chemical Formula 1, and an aliphatic dinitrile compound represented by Chemical Formula 2. The lithium secondary battery including the non-aqueous electrolyte solution having the possibility of generating a swelling phenomenon while storing or charging/discharging at a high temperature may be restrained. In addition, a cycle life of the charging/discharging may be improved.
    Type: Grant
    Filed: August 14, 2013
    Date of Patent: October 25, 2016
    Assignee: LG Chem, Ltd.
    Inventors: You Jin Shim, Jae Seung Oh, Yeon Suk Hong, Byoung Bae Lee, Hyo Jin Lee
  • Patent number: 9466826
    Abstract: A method for making a lithium ion battery electrode is provided. An electrode material layer including a plurality of electrode active material particles is provided. The electrode material layer includes a surface. A carbon nanotube layer is formed on the surface of the electrode material layer. The carbon nanotube layer consists of carbon nanotubes.
    Type: Grant
    Filed: April 27, 2012
    Date of Patent: October 11, 2016
    Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.
    Inventors: Jia-Ping Wang, Ke Wang, Kai-Li Jiang, Shou-Shan Fan
  • Patent number: 9455429
    Abstract: Non-aqueous electrolyte secondary batteries are provided. In one embodiment, the non-aqueous electrolyte secondary battery includes a positive electrode, a negative electrode, a separator disposed between the positive and negative electrodes, a polymeric layer disposed between the separator and at least one of the positive electrode and the negative electrode, and an exterior member housing the positive electrode, the negative electrode, the separator, and the polymeric layer. The separator has a thickness of 5 ?m to 20 ?m and includes at least 90% by mass of polyethylene. The polymeric layer holds therein a non-aqueous electrolytic solution including 13% by mass to 25% by mass of an electrolyte salt. The battery has a maximum attained temperature not higher than 100° C. using a nail piercing safety test at the time of conducting the safety test.
    Type: Grant
    Filed: November 21, 2014
    Date of Patent: September 27, 2016
    Assignee: Sony Corporation
    Inventor: Tomoyuki Nakamura
  • Patent number: 9444098
    Abstract: A positive active material including: a lithium-containing oxide, and a lithium-intercalatable phosphate compound disposed on the lithium-containing oxide.
    Type: Grant
    Filed: March 25, 2013
    Date of Patent: September 13, 2016
    Assignee: SAMSUNG SDI CO., LTD.
    Inventors: Jun-ho Park, Jun-young Mun, Jin-hwan Park, Jae-gu Yoon
  • Patent number: 9444090
    Abstract: An embodiment of the invention combines the superior performance of a polyvinylidene difluoride (PVDF) or polyethyleneoxide (POE) binder, the strong binding force of a styrene-butadiene (SBR) binder, and a source of lithium ions in the form of solid lithium metal powder (SLMP) to form an electrode system that has improved performance as compared to PVDF/SBR binder based electrodes. This invention will provide a new way to achieve improved results at a much reduced cost.
    Type: Grant
    Filed: October 5, 2012
    Date of Patent: September 13, 2016
    Assignee: The Regents of the University of California
    Inventors: Gao Liu, Vince Battaglia, Lei Wang
  • Patent number: 9437898
    Abstract: Disclosed is a secondary battery including a plurality of electrode assemblies. The secondary battery includes a first electrode assembly including a first cathode, a first separator and a first anode, and a second electrode assembly including a second cathode, a second separator and a second anode, wherein, when an electrode plate area of the second electrode assembly is smaller than that of the first electrode assembly, a cross-sectional thickness of the second electrode assembly is larger than that of the first electrode assembly.
    Type: Grant
    Filed: May 21, 2014
    Date of Patent: September 6, 2016
    Assignee: LG CHEM, LTD.
    Inventors: Sun Woo Lee, Hyun Jong Yang, Jae Dong Chang
  • Patent number: RE46187
    Abstract: The invention provides a positive electrode material and a battery using the same which can achieve a higher discharge voltage and which can obtain excellent charge-and-discharge properties, without reducing the capacity. A positive electrode (12) and a negative electrode (14) are configured through a separator (15) in between. The positive electrode (12) contains a compound expressed by a general formula Li1+xMnyFezPO4 (wherein x, y and z are values within ranges of 0<x<0.1, 0.5<y<0.95, and 0.9<y+z?1, respectively). According to the compound, the higher discharge voltage can be obtained due to Mn, the Jahn Teller effect of Mn3+ can be attenuated and furthermore distortion of the crystal structure and the reduction of the capacity can be inhibited due to Fe and the excess Li.
    Type: Grant
    Filed: April 11, 2008
    Date of Patent: October 25, 2016
    Assignee: SONY CORPORATION
    Inventor: Guohua Li