Abstract: Improved anodes and cells are provided, which enable fast charging rates with enhanced safety due to much reduced probability of metallization of lithium on the anode, preventing dendrite growth and related risks of fire or explosion. Anodes and/or electrolytes have buffering zones for partly reducing and gradually introducing lithium ions into the anode for lithiation, to prevent lithium ion accumulation at the anode electrolyte interface and consequent metallization and dendrite growth. Various anode active materials and combinations, modifications through nanoparticles and a range of coatings which implement the improved anodes are provided.

Abstract: A battery includes an anode having an alkali metal as the active material, a cathode having, for example, iron disulfide as the active material, and an increased electrolyte volume.

Abstract: A separator includes a porous substrate having a plurality of pores; and a porous coating layer formed on at least one surface of the porous substrate and made of a mixture of a binder and a plurality of inorganic particles, wherein the binder includes a crosslinked binder. This separator may improve high temperature cycle performance, discharge characteristics and thermal resistance of an electrochemical device since the separator exhibits improved insolubility and impregnation to electrolyte and improved thermal resistance.

Abstract: An anode for a lithium-based energy storage device such as a lithium-ion battery is disclosed. The anode includes an electrically conductive current collector comprising a metal oxide layer and a continuous porous lithium storage layer provided over the metal oxide layer. The continuous porous lithium storage layer includes at least 40 atomic % silicon, germanium or a combination thereof. A method of making the anode includes providing an electrically conductive current collector having an electrically conductive layer and a metal oxide layer provided over the electrically conductive layer. The metal oxide layer may have an average thickness of at least 0.05 ?m. A continuous porous lithium storage layer is deposited over the metal oxide layer by PECVD.

Abstract: A rechargeable lithium-ion battery disclosed herein comprises a positive electrode with a positive electroactive material that in a charged state comprises lithium iron (II) orthosilicate (Li2FeSiO4) and in a discharged state comprises FeSiO4 or LiFeSiO4. A negative electrode comprises phosphorene. A separator is disposed between the positive electrode and the negative electrode. An electrolyte has an organic solvent especially containing ether-based organic solvents and a lithium salt that provides a conductive medium for lithium ions to transfer between the positive electrode and the negative electrode. Such a rechargeable lithium-ion battery provides advantageous power delivery, long driving ranges, and fast charge to enhance widespread use of batteries, especially in vehicles. Furthermore, lithium plating can be minimized or avoided, even at low temperature charging. Methods of recharging a rechargeable lithium-ion battery at low temperatures are also disclosed.

Abstract: In an embodiment, a metal or metal-ion battery cell, includes anode and cathode electrodes, a separator electrically separating the anode and the cathode, and a solid electrolyte ionically coupling the anode and the cathode, wherein the solid electrolyte comprises a material having one or more rearrangeable chalcogen-metal-hydrogen groups that are configured to transport at least one metal-ion or metal-ion mixture through the solid electrolyte, wherein the solid electrolyte exhibits a melting point below about 350° C. In an example, the solid electrolyte may be produced by mixing different dry metal-ion compositions together, arranging the mixture inside of a mold, and heating the mixture while arranged inside of the mold at least to a melting point (e.g., below about 350° C.) of the mixture so as to produce a material comprising one or more rearrangeable chalcogen-metal-hydrogen groups.

Abstract: The present invention relates to a switching device, a method of fabricating the same, and a nonvolatile memory device including the same. A switching device according to an embodiment of the present invention includes a first electrode; a second electrode; and a switching film which is disposed between the first electrode and the second electrode, and includes an electrically insulating matrix and a conductive path formed in the electrically insulating matrix. In this embodiment, the conductive path includes crystalline metal clusters dispersed in the electrically insulating matrix and a metal bridge connecting adjacent crystalline metal clusters.

Abstract: The present invention relates to a negative electrode active material, a method of preparing the same, and a lithium secondary battery including the same. In particular, the present invention relates to a composite negative electrode active material that includes: a core capable of intercalating and deintercalating lithium ions; and a plurality of coating layers comprising two or more Si layers having different densities formed on a surface of the core, and thus has enhanced stability by minimizing the formation of cracks occurring by the repetition of charging and discharging, a method of preparing the same, and a lithium secondary battery including the same and thus exhibiting enhanced lifespan characteristics.

Abstract: Nanoporous composite separators are disclosed for use in batteries and capacitors comprising a nanoporous inorganic material and an organic polymer material. The inorganic material may comprise Al2O3, AlO(OH) or boehmite, AlN, BN, SiN, ZnO, ZrO2, SiO2, or combinations thereof. The nanoporous composite separator may have a porosity of between 35-50%. The average pore size of the nanoporous composite separator may be between 10-90 nm. The separator may be formed by coating a substrate with a dispersion including the inorganic material, organic material, and a solvent. Once dried, the coating may be removed from the substrate, thus forming the nanoporous composite separator. A nanoporous composite separator may provide increased thermal conductivity and dimensional stability at temperatures above 200° C. compared to polyolefin separators.

Abstract: The invention discloses a composite electrode materials with improved structure. The composite electrode materials of this invention includes at least one active material. The active material is coated an artificial passive film on its surface to effectively prevent or reduce the contact of the electrolyte and the active material to avoid unnecessary consumption of Li-ions. Also, there have a middle layer and an outer layer outside of the artificial passive film. Both of the middle layer and the outer layer are composed of the deformable electrolyte and the undeformable electrolyte, but with different concentration ratios. Therefore, the better ion-conduction is achieved with reduced charge-transfer resistance and reduced usage amount of organic solvent.

Abstract: Disclosed is a porous carbon nanotube microsphere material and the preparation method and use thereof, a lithium metal-skeleton carbon composite and the preparation method thereof, a negative electrode of a secondary battery, a secondary battery, and a metal-skeleton carbon composite. The porous carbon nanotube microsphere material is spherical or spheroidal particles composed of carbon nanotubes. The spherical or spheroidal particles have an average diameter of 1 ?m to 100 ?m. A large number of nanoscale pores are composed of interlaced nanotubes inside the particle, and the pore size is 1 nm to 200 nm. The preparation method thereof comprises: mixing and dispersing carbon nanotubes and a solvent, and performing spray drying, to obtain the carbon nanotube microspheres. The lithium metal-skeleton carbon composite is obtained by uniformly mixing lithium metal in a melted state with a porous carbon material carrier and cooling.

Abstract: A composite positive electrode active material includes: a first metal oxide that has a layered structure and is represented by Formula 1; and a second metal oxide that has a spinel structure and is represented by Formula 2, wherein the composite positive electrode active material includes a composite of the first metal oxide and the second metal oxide: LiMO2??Formula 1 LiMe2O4??Formula 2 wherein, in Formulas 1 and 2, M and Me are each independently at least one element selected from Groups 2 to 14 of the periodic table, and a molar ratio of Li/(M+Me) in the composite is less than 1.

Abstract: A nonaqueous battery includes a current collector that supports an electrode active material. The current collector includes a first layer, a second layer and a third layer. The second layer is interposed between the first layer and the third layer. The second layer includes 0.3 mass % or more and 1 mass % or less of magnesium and 0.2 mass % or more and 0.9 mass % or less of silicon, with a remainder being made up of aluminum. The first layer and the third layer constitute outer surfaces of the current collector. The first layer and the third layer each include 99.3 mass % or more of aluminum. In both of the first layer and the third layer, there is less than 0.3 mass % of magnesium and less than 0.2 mass % of silicon.

Abstract: A lithium cobalt composite oxide for a lithium secondary battery and a lithium secondary battery, the lithium cobalt composite oxide including a magnesium (Mg)-doped lithium cobalt composite oxide having an atomic ratio of Mg to cobalt (Co) of about 0.0035:1 to about 0.01:1, wherein the Mg-doped lithium cobalt composite oxide further includes fluorine (F).

Abstract: The present disclosure relates to a method for forming solid-state electrolytes, electrodes, current collectors, and/or conductive additives used in solid-state batteries. In one version, the method includes depositing a stabilization coating on a powdered electrolyte material, or a powdered electrode material, or a powdered conductive additive material and forming a slurry comprising the coated material. The slurry is then cast on a surface to form a layer, and the layer is sintered to form a solid state electrolyte, or an electrode, or an electrode having the conductive additive.

Abstract: Prelithiation of a battery anode carried out using controlled lithium metal vapor deposition. Lithium metal can be avoided in the final battery. This prelithiated electrode is used as potential anode for Li-ion or high energy Li—S battery. The prelithiation of lithium metal onto or into the anode reduces hazardous risk, is cost effective, and improves the overall capacity. The battery containing such an anode exhibits remarkably high specific capacity and a long cycle life with excellent reversibility.

Abstract: An energy storage device can include a first electrode, a second electrode and a separator between the first electrode and the second electrode wherein the first electrode includes an electrochemically active material and a porous carbon material, and the second electrode includes elemental lithium metal and carbon particles. A method for fabricating an energy storage device can include forming a first electrode and a second electrode, and inserting a separator between the first electrode and the second electrode, where forming the first electrode includes combining an electrochemically active material and a porous carbon material, and forming the second electrode includes combining elemental lithium metal and a plurality of carbon particles.

Abstract: Low-voltage rechargeable microbatteries having a vanadium-based cathode are provided. In one aspect, a method of forming a battery is provided. The method includes the steps of: forming a first contact on a substrate; forming a cathode on the first contact, wherein the cathode is formed from a vanadium-containing material; forming a solid electrolyte on the cathode; forming an anode on the solid electrolyte; and forming a second contact on the anode. A battery having a vanadium-based cathode is also provided.

Abstract: Provided are an electrolytic copper foil, an electrode comprising the same, and a lithium ion cell comprising the same. The electrolytic copper foil comprises first and second chromium layers each containing 15 ?g/dm2 to 50 ?g/dm2 of chromium, and has a resistivity of 1.72 ??*cm to 2.25 ??*cm. First and second surfaces thereof each have a contact angle of 15 to 50 degrees with oxalic acid, the first surface has a lightness of 17.5 to 40 and the second surface has a lightness of 38 to 60. With these characteristics, the electrolytic copper foil has good weatherability and good adhesion strength with the active materials, thereby improving the cycle life of the lithium ion cell comprising the same.

Abstract: A negative electrode active material having high cycle durability contains an alloy represented by the following chemical formula (1): SixSnyMzAa??(1) wherein M is Zn, A is unavoidable impurities, x, y, z, and a represent % by mass values, and in that case, 0<x<100, 0<y<100, 0<z<100, 0?a<0.5, and x+y+z+a=100, in which the half width of the diffraction peak of the (111) surface of Si in the range of 2?=24 to 33° by X ray diffraction measurement of the alloy using CuK? ray is 0.7° or more, and the x is more than 23 and less than 64, the y is 4 or more and less than 34, and the z is more than 0 and less than 65.

Abstract: A laminated cell (100) of the present invention includes a laminated body (120) formed by sequential stacking a negative electrode (130), a separator (170, 180), a positive electrode (150), and a separator (170, 180). At least one of surfaces of the positive electrode (150) or the negative electrode (130) in a stacking direction (S) has a portion to which a resin member (190) is bonded. The separators each have a portion bonded to the resin member (190) on a side facing the at least one of surfaces. In the present invention, since the separators and at least one of the positive electrode and the negative electrode are integrated together, misalignment in a stacking work can be easily suppressed and the laminated cell has excellent productivity.

Abstract: A lithium secondary battery includes a wound electrode group and a lithium-ion conductive nonaqueous electrolyte. The wound electrode group includes a positive electrode, a negative electrode, and a separator between the positive electrode and the negative electrode. The negative electrode includes a negative electrode current collector. The negative electrode current collector includes: a layer having a first surface facing outward of the winding of the electrode group and a second surface facing inward of the winding of the electrode group; first protrusions protruding from the first surface; and second protrusions protruding from the second surface. Lithium metal is deposited on the first surface and the second surface by charging. A first average height of the first protrusions is higher than a second average height of the second protrusions.

Abstract: Composite anode materials and methods of making same, the anode materials including capsules including graphene, reduced graphene oxide, graphene oxide, or a combination thereof, and particles of an active material disposed inside of the capsules. The particles may each include a core and a buffer layer surrounding the core. The core may include crystalline silicon, and the buffer layer may include a silicon oxide, a lithium silicate, carbon, or a combination thereof.

Abstract: A nonaqueous battery includes a current collector that supports an electrode active material. The current collector includes a first layer, a second layer and a third layer. The second layer is interposed between the first layer and the third layer. The second layer includes 0.3 mass % or more and 1 mass % or less of magnesium and 0.2 mass % or more and 0.9 mass % or less of silicon, with a remainder being made up of aluminum. The first layer and the third layer constitute outer surfaces of the current collector. The first layer and the third layer each include 99.3 mass % or more of aluminum. In both of the first layer and the third layer, there is less than 0.3 mass % of magnesium and less than 0.2 mass % of silicon.

Abstract: A composite body includes a positive electrode active material composed of a lithium composite metal oxide containing Li and at least one type of transition metal, and an electrolyte, wherein the positive electrode active material is present on one surface of the composite body, the one type of transition metal is Co, and the molar ratio of Co (cobalt) in the positive electrode active material (lithium cobalt oxide) present on the one surface is equal to or more than the molar ratio of O (oxygen).

Abstract: A lithium ion secondary battery having more improved cycle characteristics is provided. The present invention provides a lithium ion secondary battery which comprises a negative electrode comprising graphite particles, silicon oxide particles having a composition represented by SiOx(0<x?2), and hardly graphitizable carbon particles.

Abstract: An electrochemically active material includes an active phase that includes silicon, and at least one inactive phase having a Scherrer Grain Size of greater than 5 nanometers. Each inactive phase of the material having a Scherrer Grain Size of greater than 5 nanometers has a lattice mismatch to Li15Si4 of greater than 5%.

Abstract: The present invention relates to an electrode manufacturing method, an electrode manufactured thereby, and a battery comprising the same, the electrode manufacturing method comprising the steps of: applying an electrode active material onto a collector; and radiating a laser such that the end of an electrode active material layer, which has been obtained by applying the electrode active material, becomes straight, thereby removing the electrode active material. The present invention is advantageous in that the difference in area between active materials applied to the positive and negative electrodes, respectively, is minimized, thereby increasing the capacity and improving the stability of the battery.

Abstract: The present disclosure is directed to providing improved processability by forming a protective film on the surface of lithium metal used as an electrode layer through a simple process, and to improving the cycle characteristics of a lithium metal secondary battery by forming a stable protective film. The present disclosure provides a method for manufacturing a negative electrode, including the steps of: (S1) preparing lithium metal; and (S2) dipping the lithium metal in an acid solution for 60-120 seconds to form a LiF film on the surface of lithium metal.

Abstract: The object is to provide a lithium ion secondary battery which has an excellent cycle property even in high-temperature environment and which has small volume increase. An exemplary embodiment of the invention is a lithium ion secondary battery, comprising: a positive electrode, a negative electrode comprising a negative electrode active material, and an electrolyte liquid; wherein the electrolyte liquid comprises a chain-type fluorinated ester compound represented by a predetermined formula and a chain-type fluorinated ether compound represented by a predetermined formula; wherein the negative electrode active material comprises metal (a) that can be alloyed with lithium, metal oxide (b) that can absorb and desorb lithium ion, and carbon material (c) that can absorb and desorb lithium ion; and wherein metal (a) is silicon, and metal oxide (b) is silicon oxide.

Abstract: Methods for preparing an electrode for a secondary battery are provided herein. In some embodiments, the method includes coating a current collector with an electrode slurry to form a coating layer on the current collector, the electrode slurry including a binder, an electrode active material, a conductive material, and amorphous selenium nanoparticles, and a solvent; and drying the coating layer, wherein the drying vaporizes the amorphous selenium nanoparticles and forms a passageway in the coating layer.

Abstract: (Problem to be Solved) The present invention was made in view of the above-described problems, with an object of providing a Li—P—S-based sulfide solid electrolyte material with both excellent electrochemical stability and a high lithium ion conductivity, providing a method of producing the Li—P—S-based sulfide solid electrolyte material, and providing a lithium battery including the sulfide solid electrolyte material. (Solution) There is provided a sulfide solid electrolyte material including a Li element, a P element, and a S element and having peaks at positions of 2?=17.90±0.20, 29.0±0.50, and 29.75±0.25? in powder X-ray diffraction measurement using a Cu-K? ray having an X-ray wavelength of 1.5418 ?, in which assuming that the diffraction intensity of the peak at 2?=17.90±0.20 is IA and the diffraction intensity of the peak at 2?=18.50±0.20 is IB, a value of IB/IA is less than 0.50.

Abstract: A secondary cell comprising a positive cathode electrode of capacity P (mAh) in communication with a liquid or gel electrolyte; an negative anode electrode of capacity N (mAh) in communication with the electrolyte; and a separator permeable to at least one mobile species which is redox-active at least one of the anode and the cathode; designed and constructed such that the anode capacity N is smaller than that of the cathode capacity P, hence N/P<0.9.

Abstract: Provided is a method of producing a mass of graphene-embraced particulates, comprising (A) peeling off graphene sheets from graphite particles and directly or indirectly transferring these graphene sheets to encapsulate primary particles of an anode active material using an energy-impact device, wherein multiple graphene sheets are overlapped together to embrace or encapsulate a primary particle; and (B) combining the resulting graphene-encapsulated primary particles with additional graphene sheets, along with an optional conductive additive, to form graphene-embraced particulates. Also provided are an anode electrode comprising multiple graphene-embraced particulates and a battery comprising such an anode electrode.

Abstract: The purpose of the present invention is to provide a graphene which has high dispersibility, high electrical conductivity and oxidation resistance namely a graphene which has high electrochemical stability. In order to achieve the above-described purpose, a surface-treated graphene according to the present invention is obtained by having a compound represented by general formula (1) or a neutralized salt thereof adhere to a graphene.

Abstract: The disclosure includes a composition of matter including a film formed on substantially all nSi-cPAN particles included in an electrode, the film including fluorine, oxygen, sulfur, carbon and lithium.

Abstract: According to one embodiment, a nonaqueous electrolyte battery includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The positive electrode includes at least one oxide selected from the group consisting of a first oxide having a spinel structure and represented by LixNi0.5Mn1.5O4, a second metal phosphate having an olivine structure and represented by LixMn1?wFewPO4, and a third oxide having a layered structure and represented by LixNiyMnzCo1?y?zO2. The nonaqueous electrolyte includes a first solvent. The first solvent includes at least one compound selected from the group consisting of trimethyl phosphate, triethyl phosphate, tripropyl phosphate, tributyl phosphate, and fluorinated phosphate ester.

Abstract: According to one embodiment, a nonaqueous electrolyte battery includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The positive electrode includes at least one oxide selected from the group consisting of a first oxide having a spinel structure and represented by LixNi0.5Mn1.5O4, a second metal phosphate having an olivine structure and represented by LixMn1-wFewPO4, and a third oxide having a layered structure and represented by LixNiyMnzCo1-y-zO2. The nonaqueous electrolyte includes a first solvent. The first solvent includes at least one compound selected from the group consisting of trimethyl phosphate, triethyl phosphate, tripropyl phosphate, tributyl phosphate, and fluorinated phosphate ester.

Abstract: The present invention provides a negative electrode material for a non-aqueous electrolyte secondary battery, comprising negative electrode active material particles containing a silicon compound expressed by SiOx at least partially coated with a carbon coating where 0.5?x?1.6. The negative electrode active material particles have a negative zeta potential and exhibiting fragments of CyHz compound in an outermost surface layer of the silicon compound when subjected to TOF-SIMS. This negative electrode material can increase the battery capacity and improve the cycle performance and battery initial efficiency. The invention also provides a negative electrode active material layer, a negative electrode, and a non-aqueous electrolyte secondary battery using this material, and a method of producing this material.

Abstract: An electrode mixture of the present invention comprises: an electrode active material; a binder; and a conductive material. When a cross-section of the electrode mixture is imaged such that a pixel filled 100% with a conductive material among a plurality of divided pixels is considered to be a condensed pixel and a value obtained by counting condensed pixels is considered to be the degree of agglomeration, the degree of agglomeration of a conductive material in the electrode mixture in the depth direction of the electrode mixture has a standard deviation less than 3.0. The electrode mixture as described above includes a conductive material uniformly distributed therein and thus has low electrode resistance. Therefore, the electrode mixture can improve output and lifespan properties of a lithium secondary battery to which the electrode mixture has been applied.

Abstract: A positive active material for a rechargeable lithium battery includes a lithium nickel-based metal oxide represented by LixNi1-yMyO2 and a lithium-containing oxide on a surface of the lithium nickel-based metal oxide. In the formula LixNi1-yMyO2, M is one or more of Co, Mn, Al, Mg, Ti, Zr, or a combination thereof, 0<x<1.1, and 0?y<0.5.

Abstract: A method of manufacturing an electrode laminate, which includes an active material layer and a solid electrolyte layer formed on the active material layer, includes: an active material layer forming step of forming an active material layer; and a solid electrolyte layer forming step of forming a solid electrolyte layer on the active material layer by applying a solid electrolyte layer-forming slurry to the active material layer and drying the solid electrolyte layer-forming slurry. In this method, a surface roughness Ra value of the active material layer is 0.29 ?m to 0.98 ?m when calculated using a laser microscope.

Abstract: A battery and related methods are described. The battery can include a plurality of battery cell segments. Each of the battery cell segments can include: a positive temperature coefficient (PTC) material whose resistance increases with temperature, an anode segment, a cathode segment, and one or more current limiters. The one or more current limiters of a battery cell segment are configured to conditionally electrically isolate the battery cell segment based on an occurrence of a short circuit within the battery cell segment. The battery can be used to store electrical power and/or provide electrical power to a load.

Abstract: A negative electrode active material constituting a lithium ion secondary battery having high energy density and excellent cycle characteristics, and a negative electrode and a lithium ion secondary battery comprising the same are provided. The present invention relates to a negative electrode active material comprising graphite particles and crystalline silicon particles, wherein a median diameter of the crystalline silicon particles is 0.7 ?m or less, and a weight ratio of the crystalline silicon particles to the total weight of the graphite particles and the crystalline silicon particles is 1 wt % or more and 25 wt % or less.

Abstract: The invention discloses a composite electrode materials. The composite electrode materials of this invention includes at least one active material. The active material is coated an artificial passive film on its surface to effectively block the contact of the electrolyte and the active material to prevent unnecessary consumption of Li-ions. Also, there have a middle layer and an outer layer outside of the artificial passive film. Both of the middle layer and the outer layer are composed of the gel/liquid electrolyte and the solid electrolyte, but with different concentration ratios. Therefore, the better ion-conduction is achieved with reduced charge-transfer resistance and reduced amount of organic solvent.

Abstract: The present invention relates to a negative electrode for lithium secondary battery and a lithium secondary battery including the same. The negative electrode includes a negative electrode active layer comprising lithium, and a protective layer disposed on the negative electrode active layer, wherein the protective layer comprises a polymer matrix having a three dimensional crosslinked network structure of polymer or includes a non-crosslinked linear polymer, and an electrolyte in the polymer matrix in the amount of 100 to 1000 parts by weight based on 100 parts by weight of the polymer matrix. The negative electrode according to the present invention has no concern about loss of electrolyte and the resulting deterioration of battery life characteristics even during the repetitive charging/discharging of the battery and has improved battery stability due to the inhibition of growth of lithium dendrite.

Abstract: The present invention relates to a positive electrode and a secondary battery including the same, and particularly, to a positive electrode which includes a current collector; a first active material layer including first active material particles and disposed on the current collector; and a first pattern and a second pattern alternately disposed separately from each other on the first active material layer, wherein the first pattern includes first pattern active material particles, the second pattern includes second pattern active material particles, the first pattern has a thickness greater than that of the second pattern, and the second pattern has a volume expansion rate greater than that of the first pattern, and a secondary battery including the same.

Abstract: The present invention provides an electrolyte solution for a lithium secondary battery including an additive, which may prevent a chemical reaction between the electrolyte solution and an electrode by forming a stable solid electrolyte interface (SEI) and a protection layer on the surface of the electrode, and a lithium secondary battery in which life characteristics and high-temperature stability are improved by including the same.

Abstract: A system and method of forming a silicon-hybrid anode material. The silicon-hybrid anode material including a microparticle mixture of a quantity of silicon microparticles and a quantity of metal microparticles intermixed with the quantity of silicon microparticles in a selected ratio. The microparticle mixture is formed in a silicon-hybrid anode material layer having a thickness of between about 2 and about 15 ?m.

Abstract: A positive active material includes an over-lithiated lithium transition metal oxide having a core-shell structure, wherein a shell layer of the core-shell structure includes a metal cation.