Abstract: Disclosed is an electrode comprising a first organic/inorganic composite porous coating layer formed on its surface, wherein the first coating layer includes inorganic particles and a binder polymer for interconnecting and fixing the inorganic particles, and has micropores formed by interstitial volumes among the inorganic particles. An electrochemical device including the same electrode is also disclosed. Further, disclosed is a method for manufacturing an electrode having an organic/inorganic composite porous coating layer on the surface thereof, comprising the steps of: (a) coating a current collector with slurry containing an electrode active material and drying it to provide an electrode; and (b) coating the surface of electrode obtained from step (a) with a mixture of inorganic particles with a binder polymer. A lithium secondary battery including the electrode shows improved safety and minimized degradation in battery performance.

Abstract: A metal-air battery includes a housing having an aperture for the passage of air and a pair of electrodes that extend from the housing. An air cathode may be interconnected with one of the electrodes and an anode may include a metal foil that is interconnected with another of the electrodes. A separator may be interposed between the air cathode and the metal foil and a barrier layer may surround the metal foil. The barrier layer may function to substantially reduce the passage of moisture to the metal foil. A method of making a metal-air battery is also presented.

Abstract: A microporous polyolefin battery separator membrane is extremely high in porosity, high in puncture strength, very low in shrinkage and with shutdown temperature of 130-140 degrees C. and melt integrity greater than 165 degrees C. It consists of 20-30% by weight of a UHMW polyethylene having Mw of 1×106 or higher, 60-70% by weight of a HDPE having average Mw of between 200,000-500,000 and 5-15% by weight of TiO2 with an average particle size of less than 0.2 microns.

Abstract: A lithium rechargeable battery includes a separator that shows excellent safety characteristics such as short circuit resistance and heat resistance. The lithium rechargeable battery includes a cathode, an anode, a separator that separates the cathode and the anode from each other, and a non-aqueous electrolyte, wherein the separator includes a porous membrane formed of a ceramic material and a binder, and wherein the binder includes at least one crystalline resin having a crystal melting temperature of 250° C. or higher or at least one non-crystalline resin having an initial decomposition temperature of 250° C. or higher.

Abstract: An electrical separator for a lithium battery is composed of a porous carrier coated with a porous inorganic nonelectroconductive material and a porous shutdown layer on the porous inorganic nonelectroconductive coating. The shutdown layer melts at a selected temperature defined by layer composition. Upon melting, the pores of the inorganic layer are closed. Such an electrical separator provides a lithium battery of improved safety. A method to produce the electrical separator is provided.

Abstract: A separator for an electrochemical device of the present invention includes a porous film including: a filler; an organic binder; and at least one resin selected from resin A that has a melting point of 80 to 140° C. and resin B that absorbs a non-aqueous electrolyte and swells upon heating and whose swelling degree increases with increasing temperature, and the filler contains boehmite having a secondary particle structure in which primary particles are connected.

Abstract: Disclosed is an organic/inorganic composite separator including: a porous substrate having pores; and a porous active layer containing a mixture of inorganic particles and a binder polymer with which at least one surface of the porous substrate is coated. The organic/inorganic composite separator of the present invention may be useful to enhance peeling and scratch resistances and improve a lamination characteristic by introducing a porous active layer onto a porous substrate having pores, the porous active layer having heterogeneity of morphology toward a thickness direction in which a content ratio of the binder polymer/inorganic particles present in a surface layer is higher than that of the binder polymer/inorganic particles present inside the surface layer. Accordingly, the stability and performances of a battery can be improved together since the detachment of inorganic particles from the porous active layer may be reduced during the assembly process of the electrochemical device.

Abstract: There is provided a porous film, comprising a polymer having a thermal decomposition initiation temperature of 200° C. or more and a raw material monomer thereof, wherein a ratio of the raw material monomer is 0.05% by weight or more and 5% by weight or less based on the total weight of the polymer and the raw material monomer; and a laminated porous film, wherein the porous film and a porous film containing a thermoplastic resin are laminated.

Abstract: An electrode assembly includes a positive electrode including a positive electrode active material; a negative electrode including a negative electrode active material; and a separator separating the positive electrode and the negative electrode from each other, and the separator including a porous layer formed by a combination of a barium titanate (BaTiO3) and a binder.

Abstract: An electrode assembly for a secondary battery comprising an adiabatic plate attached to the negative electrode plate is disclosed. The electrode assembly comprises a positive electrode plate having a positive electrode collector, a positive electrode coating, and a non-coated area on the positive electrode collector. The negative electrode plate has a negative electrode collector, a negative electrode coating, and a non-coated area on the negative electrode collector. A separator insulates the positive and negative electrode plates. Positive and negative electrode tabs are attached to the non-coated areas of the positive and negative electrode collectors. The negative electrode plate has an adiabatic plate attached to the surface of a non-coated area of the negative electrode collector that is opposite the surface to which the negative electrode tab is attached.

Abstract: The components of and a proton conducting membrane (PCM) produced from a host polymer and an attached or physically blended in hydrogen cyano fullerene proton-source agent, with the physical blending of the host polymer and hydrogen cyano fullerene further promoted by a poly(ethylene oxide) attached fullerene mixing agent.

Abstract: Separators for lithium batteries based on a sheetlike flexible substrate provided with a plurality of openings and having a porous inorganic electrically insulating coating on and in the substrate, the coating closing the openings in the substrate, the material of the substrate being selected from woven or non-woven electrically nonconductive polymeric fibers and the inorganic electrically conductive coating comprising metal oxide particles, the separators being electrical insulators and having lithium ion conducting properties without the presence of an electrolyte, the separators comprising at least one lithium ion conducting inorganic material which may also contain organic groups chemically bonded to the inorganic coating, which separators, after filling them with an additional lithium ion conducting electrolyte, have much higher ion conduction than conventional combinations of non-lithium ion conducting separators and electrolyte; a process for producing the separators; and batteries, such as high power

Abstract: In a secondary battery including a positive electrode, a negative electrode and a porous film bonded to the surface of at least one of the positive electrode and the negative electrode, the porous film includes ceramic particles and a binder, and the ceramic particles include polycrystalline particles obtained by mechanically crushing a fired material comprising a ceramic that is directly synthesized from a ceramic precursor. The porous film has a porosity of 40 to 80%, for example. The porous film can be formed by a method including the steps of: obtaining a fired material comprising a ceramic from a ceramic precursor; obtaining ceramic particles by mechanically crushing the fired material of the ceramic; obtaining a slurry including the ceramic particles and a binder; and applying the slurry onto the surface of an electrode, followed by drying.

Abstract: A non-aqueous electrolyte secondary battery has an insulating porous membrane, on at least one of a positive electrode, negative electrode, and separator thereof. The membrane contains an inorganic filler, and an active agent for dispersing the inorganic filler uniformly.

Abstract: Disclosed is an organic/inorganic composite porous separator comprising: (a) a polyolefin-based separator substrate; and (b) an active layer formed by coating at least one region selected from the group consisting of a surface of the substrate and a part of pores present in the substrate with a mixture of inorganic particles and a binder polymer, wherein the inorganic particles in the active layer are interconnected among themselves and are fixed by the binder polymer, and interstitial volumes among the inorganic particles form a pore structure. A method for manufacturing the same separator and an electrochemical device including the same separator are also disclosed. An electrochemical device comprising the organic/inorganic composite porous separator shows improved thermal and electrochemical safety and quality, simultaneously.

Abstract: A non-aqueous electrolyte secondary battery is provided that remarkably improves battery reliability by quickly lowering the potential of the positive electrode while preventing separator shrinkage at high temperatures. A separator has on its surface a shrinkage-prevention-layer formed portion (3a), in which a layer for preventing separator shrinkage is formed, and a shrinkage-prevention-layer unformed portion (3b), in which the layer for preventing separator shrinkage is not formed. A positive electrode current collector and a negative electrode current collector respectively have a positive electrode current collector exposed portion (1b) and a negative electrode current collector exposed portion (2b). The shrinkage-prevention-layer unformed portion (3b) of the separator is disposed at a region where the current collector exposed portions (1b, 2b) face each other.

Abstract: A lithium ion secondary battery has an electrode group including: a winding core; and a positive electrode and a negative electrode that are wound around the winding core. This electrode group does not have an independent separator between the positive and negative electrodes. A porous film is integrally formed on both sides of at least one of the positive electrode and the negative electrode. The negative electrode and the positive electrode are connected to the winding core by a negative electrode resin film and a positive electrode resin film, respectively. The use of such resin films makes it possible to reduce the breakage of the porous films and prevent a short-circuit between the positive and negative electrodes.

Abstract: A non-aqueous electrolyte secondary battery including: a positive electrode; a negative electrode; a separator interposed between the positive electrode and the negative electrode; a non-aqueous electrolyte; and a porous insulating film adhered to a surface of at least one selected from the group consisting of the positive electrode and the negative electrode, the porous insulating film including an inorganic oxide filler and a film binder, wherein the ratio R of actual volume to apparent volume of the separator is not less than 0.4 and not greater than 0.7, and wherein the ratio R and a porosity P of the porous insulating film satisfy the relational formula: ?0.10?R?P?0.30.

Abstract: The present invention relates to a plastics molding composition based on polyarylene sulfide and/or on liquid-crystalline plastic, where the molding composition comprises carbon black and graphite and/or metal powder, the carbon black has a specific surface area of from 500 to 1500 m2/g, and a dibutyl phthalate value of from 100 to 700 ml/100 g, and the graphite has a specific surface area of from 1 to 35 m2/g. The molding compositions of the invention have good conductivities, and better flowabilities and mechanical properties.

Abstract: Provided are a composite polymer electrolyte for a lithium secondary battery in which a composite polymer matrix multi-layer structure composed of a plurality of polymer matrices with different pore sizes is impregnated with an electrolyte solution, and a method of manufacturing the same. Among the polymer matrices, a microporous polymer matrix with a smaller pore size contains a lithium cationic single-ion conducting inorganic filler, thereby enhancing ionic conductivity, the distribution uniformity of the impregnated electrolyte solution, and maintenance characteristics. The microporous polymer matrix containing the lithium cationic single-ion conducting inorganic filler is coated on a surface of a porous polymer matrix to form the composite polymer matrix multi-layer structure, which is then impregnated with the electrolyte solution, to manufacture the composite polymer electrolyte. The composite polymer electrolyte is used in a unit battery.

Abstract: A microporous polyolefin battery separator membrane is extremely high in porosity, high in puncture strength, very low in shrinkage and with shutdown temperature of 130-140 degrees C. and melt integrity greater than 165 degrees C. It is made of UHMWPE having a weight-average molecular weight of 1×106 or more and an inert filler. A second microporous polyolefin battery separator has a shutdown temperature of between 95 and 110 degrees C. and a melt integrity of more than 165 degrees C. It is made from an UHMWPE having a weight-average molecular weight of 1×106 or more, a shutdown (LMWPE) having a weight-average molecular weight of 4500 or less and an inert filler. Both membranes have a thickness of 5-75 microns, a porosity of 30-95%, an air permeability of 1-200 sec/10 cc, an average pore diameter of 0.001 to 1 micron and puncture strength of more than 300 grams/25 ?m.

Abstract: A microporous polyolefin battery separator membrane is extremely high in porosity, high in puncture strength, very low in shrinkage and with shutdown temperature of 130-140 degrees C. and melt integrity greater than 165 degrees C. It is made of UHMWPE having a weight-average molecular weight of 1×106 or more and an inert filler. A second microporous polyolefin battery separator has a shutdown temperature of between 95 and 110 degrees C. and a melt integrity of more than 165 degrees C. It is made from an UHMWPE having a weight-average molecular weight of 1×106 or more, a shutdown (LMWPE) having a weight-average molecular weight of 4500 or less and an inert filler. Both membranes have a thickness of 5-75 microns, a porosity of 30-95%, an air permeability of 1-200 sec/10 cc, an average pore diameter of 0.001 to 1 micron and puncture strength of more than 300 grams/25 ?m.

Abstract: A binderless glass fiber mat suitable for use as a separator for valve regulated (“recombinant”) lead acid (“VRLA”) batteries is disclosed. The separator is produced by a dry process by collecting the fibers from fiberizing apparatus, without subjecting them to a wet paper making or other post forming process, and selecting portions of the collected fibers which are sufficiently uniform in thickness and grammage for use as battery separators. The fibers can be entwined to produce a superior separator material. Additives can be introduced during the collection process to enhance the properties of the separator. A battery comprises at least one stack of alternating positive and negative plates, with the separator between adjacent plates. Separators according to the invention are significantly more resilient and have longer fibers than otherwise identical separators made from different samples of the same glass fibers, but by a conventional wet paper making process.

Abstract: A non-aqueous electrolyte secondary battery has an insulating porous membrane, on at least one of a positive electrode, negative electrode, and separator thereof. The membrane contains an inorganic filler, and an active agent for dispersing the inorganic filler uniformly.

Abstract: Provided are separators for use in an electrochemical cell comprising (a) an inorganic oxide and (b) an organic polymer, wherein the inorganic oxide comprises organic substituents. Preferably, the inorganic oxide comprises an hydrated aluminum oxide of the formula Al2O3.xH2O, wherein x is less than 1.0, and wherein the hydrated aluminum oxide comprises organic substituents, preferably comprising a reaction product of a multifunctional monomer and/or organic carbonate with an aluminum oxide, such as pseudo-boehmite and an aluminum oxide. Also provided are electrochemical cells comprising such separators.

Abstract: A nonaqueous secondary battery comprising a positive electrode and a negative electrode both containing a material capable of reversibly intercalating and deintercalating lithium, a nonaqueous electrolyte containing a lithium salt, and a separator, which has a least one protective layer on the negative electrode and/or the positive electrode. The battery has a high discharge potential, satisfactory charge and discharge cycle characteristics, and high safety.

Abstract: A separator for metal/halogen batteries is provided which is excellent in thermal resistance, resistance to stress-cracking and electric properties. A separator for metal/halogen batteries comprising a polyolefin having a viscosity average molecular weight of not less than 350,000 and not more than 2,000,000, in which polyolefin the proportion by weight of a polyolefin having a molecular weight of not less than 1,000,000 is not less than 15% and not more than 80%, and a hydrophilic fine particulate inorganic material(s), wherein the weight ratio of the polyolefins to the hydrophilic fine particulate inorganic material(s) is not less than 0.55 and less than 1, said separator having a pore volume of not less than 900 mm3/g and a thickness of 0.2 to 1.0 mm.

Abstract: A microporous polyolefin battery separator membrane is extremely high in porosity, high in puncture strength, very low in shrinkage and with shutdown temperature of 130–140 degrees C. and melt integrity greater than 165 degrees C. It is made of UHMWPE having a weight-average molecular weight of 1×106 or more and an inert filler. A second microporous polyolefin battery separator has a shutdown temperature of between 95 and 110 degrees C. and a melt integrity of more than 165 degrees C. It is made from an UHMWPE having a weight-average molecular weight of 1×106 or more, a shutdown (LMWPE) having a weight-average molecular weight of 4500 or less and an inert filler. Both membranes have a thickness of 5–75 microns, a porosity of 30–95%, an air permeability of 1–200 sec/10 cc, an average pore diameter of 0.001 to 1 micron and puncture strength of more than 300 grams/25 {circumflex over (l)}¼ m.

Abstract: A membrane comprising a composition including (a) 1 to 99 wt-% of at least one polyurethane elastomer comprising at least one hard segment and at least one soft segment, and (b) 99 to 1 wt-% of a solid, wherein said solid is incorporated in said at least one polyurethane elastomer.

Abstract: A separator for a valve regulated lead acid battery is composed mainly of fine glass fibers and also contains inorganic powder, beaten natural pulp, and heat-weldable organic fibers. The heat-weldable organic fibers have a fineness of 1.5 d (deniers) or less and a fiber length of 1 mm or more, and the amount of the heat-weldable organic fibers is from 3% to 15% by weight. A valve regulated lead acid battery employs the separator.

Abstract: A film which slowly releases solids is prepared by dissolving cellulose in a solvent such as an alkali metal salt, for example L1Cl in a polar solvent such as DMAC, dispersing the solid in the solution and gelling the solution with water to form a film.

Abstract: A battery separator comprising at least one fibrous layer and at least one support layer, wherein the support layer is formed of an acid-resistant material and comprises a plurality of macroscopic openings.

Abstract: A binderless glass fiber mat suitable for use as a separator for valve regulated (“recombinant”) lead acid (“VRLA”) batteries is disclosed. The separator is produced by a dry process by collecting the fibers from fiberizing apparatus, without subjecting them to a wet paper making or other post forming process, and selecting portions of the collected fibers which are sufficiently uniform in thickness and grammage for use as battery separators. The fibers can be entwined to produce a superior separator material. Additives can be introduced during the collection process to enhance the properties of the separator. A battery comprises at least one stack of alternating positive and negative plates, with the separator between adjacent plates. Separators according to the invention are significantly more resilient and have longer fibers than otherwise identical separators made from different samples of the same glass fibers, but by a conventional wet paper making process.

Abstract: A separator for a valve regulated lead acid battery is composed mainly of fine glass fibers 1 and also contains inorganic powder 3, beaten natural pulp 2, and heat-weldable organic fibers 4. The heat-weldable organic fibers 4 have a fineness of 1.5 d (deniers) or less and a fiber length of 1 mm or more, and the amount of the heat-weldable organic fibers is from 3% to 15% by weight. The separator is excellent in resistance against a short circuit between a positive electrode plate and a negative electrode plate of the battery such as an electrochemical short circuit, for example a short circuit due to lead penetration, and a mechanical short circuit. The separator is also excellent in folding endurance, in durability against repetition of folding, and in tearing strength, and allows easy formation of envelope-like separator, thus preventing active materials from being coming off at the sides thereof.

Abstract: A battery, in which measures are taken to suppress a reduction in charge/discharge capacity and degradation of load characteristics due to peeling of an active material off the current collector during repeated charging and discharging, is disclosed. Boehmite treatment or chromate treatment of the current collector surface of the electrode plate for the battery suppresses the degradation of charge/discharge capacity and load characteristics.

Abstract: The non-aqueous electrolyte secondary battery of the present invention comprises, e.g., a positive electrode 6, a negative electrode 5, a polymer membrane 1 containing carbon powder or the like, and a separating membrane layer 7 for preventing shortcircuiting. A carbon powder, silicon powder, tin powder or aluminum powder 2 contained in the polymer membrane 1 containing carbon powder or the like absorbs as a lithium-absorbing material metallic lithium powders 3 or metallic lithium dendrite 4 which has been produced from the negative electrode 5 due to charge or discharge and takes no part in charge or discharge. This lithium-absorbing material is less reactive than the metallic lithium powders 3 or metallic lithium dendrite 4 and thus enhances the safety of the battery and controls shortcircuiting between the positive electrode and the negative electrode due to metallic lithium dendrite, making it possible to drastically improve charge and discharge cycle life performance.

Abstract: A battery comprising a positive electrode (10), a negative electrode (20) and a separator (31) provided interposed between the positive electrode (10) and the negative electrode (20), characterized in that at least one surface of said separator (31) is bonded to said positive electrode (10) or negative electrode (20) via a porous resin layer (41, 33) containing a solid filler. This battery can provide a battery which exhibits a high energy density and an excellent cycle life performance even if the electricity-storing element is received in a flexible material case.

Abstract: This invention relates to electrolyte solution compositions useful in lithium-ion batteries. These electrolytes feature lower volatility than solutions known in the art while retaining excellent battery performance using graphite based negative electrode active materials.

Abstract: The present invention relates to a nonaqueous electrolyte secondary battery, and more particularly to its separator, and it is an object thereof to prevent electrolyte leakage accident due to elevation of cell internal pressure even if the cell is exposed to high temperature without sacrificing the cell capacity. To achieve the object, by using the polyolefin group separator large in endothermic calorie per unit area by the heat of fusion in a temperature range of 70 to 150° C., and selecting appropriate graphite powder for negative electrode and organic solvent in nonaqueous electrolyte, the electrolyte leakage accident can be successfully eliminated by suppressing the reaction between the cell active substance and organic solvent, thereby suppressing elevation of cell internal pressure.

Abstract: A Li-ion polymer battery and methods for its fabrication. A first and second layer, of a polymer/particulate material composition, separate and bind each anode and cathode. The polymer of the first layer and its associated solvent differ from the polymer of the second layer and its associated solvent. Solubility requirements are such that the polymer of the first layer is non-soluble in the solvent of the second layer, and the polymer of the second layer is non-soluble in the solvent of the first layer. The polymers and particulate materials of the layers form a porous structure for containing the electrolyte of the battery so as to eliminate the need for a substantial case for enclosing the battery.

Abstract: A separator for a valve-regulated lead acid battery consists mainly of fine glass fibers. The separator includes inorganic powder in an amount of 5 to 30% by weight and natural pulp in an amount of 3 to 20% by weight, and has a density of not less than 0.165 g/cm3. The separator sufficiently suppresses the occurrence of electrical short circuits between the positive and negative electrode plates.

Abstract: A positive electrode of a lithium-sulfur battery, a method of producing the same, and a lithium-sulfur battery include, as the positive electrode, a current collector, a positive active material layer on the current collector, and a polymer layer on the positive active material on the current collector.

Abstract: Separator for silver-zinc batteries made of cellulose and containing insoluble fluoride ions which when placed next to the cathode slowly release and retard silver deposition thereon.

Abstract: An inorganic compound with a specific inductive capacity not less than 12, is contained in a separator, a gelated electrolyte, a non-aqueous electrolyte, and an electrode. This improves the degree of ion dissociation of a lithium compound as an electrolytic salt contained in the non-aqueous solvent, the gelated electrolyte, and the electrolytic salt, while diminishing resistance against ion conduction to improve ion conductivity and while preventing crystallization in a low-temperature environment.

Abstract: An inexpensive composite electrolyte for use in electrochemical fuel cells includes (i) an inorganic cation exchange material, (i) a silica-based binder; and (ii) a polymer-based binder. The cation exchange material includes aluminosilicate clays. The composite electrolyte can be fabricated with a tape casting apparatus.

Abstract: A battery separator favorably employable for lithium secondary battery comprises at least one porous film in which 100 to 40,000 ppm of particles of silicon dioxide, aluminum oxide, magnesium oxide, zinc oxide or metal oxides containing at least two metal elements selected from the group consisting of Si, Al, Mg and Zn having a mean diameter of 0.1 to 10 &mgr;m are dispersed in a porous resin matrix.

Abstract: The invention provides a separator in lead acid battery, composed of fiber material and polymers; the polymers provide functions of increasing the mechanical strength for separators, avoiding shortage between positive and negative electrodes, and decreasing the thickness of separators. The invention also provides a manufacturing method of battery separators, whereby polymers are used to coat or absorb to porous separators through means of spraying, immersing, brushing, adhering or other similar means, thus acquiring thinner battery separators with increased mechanical strength.

Abstract: The non-aqueous electrolyte secondary battery of the present invention comprises, e.g., a positive electrode 6, a negative electrode 5, a polymer membrane 1 containing carbon powder or the like, and a separating membrane layer 7 for preventing shortcircuiting. A carbon powder, silicon powder, tin powder or aluminum powder 2 contained in the polymer membrane 1 containing carbon powder or the like absorbs as a lithium-intercalating material lithium powders 3 or dendrite 4 which has been produced from the negative electrode 5 due to charge or discharge and takes no part in charge or discharge. This lithium-intercalating material is less reactive than the lithium powders 3 or dendrite 4 and thus enhances the safety of the battery and controls shortcircuiting between the positive electrode and the negative electrode due to dendrite, making it possible to drastically improve charge and discharge cycle life performance.

Abstract: A separator for metal/halogen batteries is provided which is excellent in thermal resistance, resistance to stress-cracking and electric properties. A separator for metal/halogen batteries comprising a polyolefin having a viscosity average molecular weight of not less than 350,000 and not more than 2,000,000, in which polyolefin the proportion by weight of a polyolefin having a molecular weight of not less than 1,000,000 is not less than 15% and not more than 80%, and a hydrophilic fine particulate inorganic material(s), wherein the weight ratio of the polyolefins to the hydrophilic fine particulate inorganic material(s) is not less than 0.55 and less than 1, said separator having a pore volume of not less than 900 mm3/g and a thickness of 0.2 to 1.0 mm.

Abstract: A battery separator containing cellulose and an insoluble inorganic salt of copper ions when placed in a zinc-based battery, minimizes zinc dendrite formation to extend battery cycle life.