Abstract: Electrical storage devices having excellent low-temperature properties can be obtained by using a quaternary salt (or ionic liquid) of general formula (1) below as an electrolyte salt for electrical storage devices or a liquid electrolyte for electrical storage devices. In formula (1), R1 to R4 are each independently an alkyl group of 1 to 5 carbons or an alkoxyalkyl group of the formula R?—O—(CH2)n—, with the proviso that at least one group from among R1 to R4 is the above alkoxyalkyl group. X is a nitrogen or phosphorus atom, and Y is a monovalent anion.

Abstract: An all-solid-state lithium-ion secondary battery has an anode, a cathode, a solid electrolyte layer disposed between the anode and the cathode, and at least one of a first intermediate layer disposed between the anode and the solid electrolyte layer, and a second intermediate layer disposed between the cathode and the solid electrolyte layer.

Abstract: A non-aqueous electrolytic solution is provided comprising a non-aqueous solvent, an electrolyte salt, and a siloxane modified with ether bond-bearing organic group. A non-aqueous electrolyte secondary battery using the same has improved characteristics both at low temperatures and at high outputs.

Abstract: A manufacturing method of the present invention includes ejecting a melt 61 of a solid electrolyte onto at least one electrode plate selected from a positive electrode plate 20 and a negative electrode plate 30, thereby depositing the melt 61 onto the at least one electrode plate, and compressing the positive electrode plate 20 and the negative electrode plate 30 while sandwiching the melt 61, thereby forming a layered body including the positive electrode plate 20, an electrolyte layer 62 including the solid electrolyte, and the negative electrode plate 30. In accordance with this manufacturing method, a thin lithium secondary battery having excellent characteristics can be manufactured in a highly productive manner.

Abstract: A more efficient LiPF6 lithium-ion electrochemical system composed of a phosphate free, borate lithium salt electrolyte LiTPTB composed of LiBC32F24H12 in a ternary mixed organic solvent containing a 1:1:1 volume ratio of EC, DMC and EMC is provided. The borate salt of the LiTPTB electrolyte decomposes at temperatures above 110° C. and does not react with water and also has an oxidation potential of about 4.4 V versus lithium, making it suitable for use in high voltage lithium-ion cells and batteries. A 0.3 to 1.0 M molar concentration of LiTPTB composed of LiBC32F24H12 in a ternary mixed organic solvent containing a 1:1:1 volume ratio of EC, DMC and EMC is also provided.

Abstract: A chip battery includes an element body including a solid electrolyte layer, a positive electrode layer, and a negative electrode layer. Current collectors are provided on the positive electrode layer and the negative electrode layer, respectively, of the element body using a conductive material, such as Pt. In addition, protective films are provided on both end surfaces of the element body and on the current collectors so that the current collectors are exposed near the respective ends in the longitudinal direction of the element body. Further, protective films are provided on the side surfaces of the element body to define a base body. Further, terminal electrodes are provided on the base body so as to be brought into surface contact with the exposed surfaces of the current collectors on both end sides in a direction substantially perpendicular to the lamination direction of the element body.

Abstract: A lithium ion secondary battery including: a positive electrode including a lithium composite oxide; a negative electrode capable of charging and discharging lithium ion; a non-aqueous liquid electrolyte; and a solid electrolyte layer interposed between the positive electrode and the negative electrode, wherein the solid electrolyte layer includes solid electrolyte particles and a binder. The solid electrolyte layer may include an inorganic oxide filler. The solid electrolyte particles is, for example, at least one selected from the group consisting of LiCl—Li2O—P2O5, LiTi2(PO4)3—AlPO4, LiI—Li2S—SiS4, LiI—Li2S—B2S3, LiI—Li2S—P2O5 and Li3N.

Abstract: An active material for a non-aqueous electrolyte secondary battery including a lithium-containing transition metal oxide containing nickel and manganese and having a closest-packed structure of oxygen, wherein an atomic ratio MLi/MT between the number of moles of lithium MLi and the number of moles of transition metal Mt contained in the lithium-containing transition metal oxide is greater than 1.0; the lithium-containing transition metal oxide has a crystal structure attributed to a hexagonal system, and the X-ray diffraction image of the crystal structure has a peak P003 attributed to the (003) plane and a peak P104 attributed to the (104) plane; an integrated intensity ratio I003/I104 between the peak P003 and the peak P104 varies reversibly within a range from 0.7 to 1.5 in association with absorption and desorption of lithium by the lithium-containing transition metal oxide; and the integrated intensity ratio varies linearly and continuously.

Abstract: An object of the invention is to provide a lithium secondary battery using a fused salt at ambient temperature where a high capacity is able to be maintained even when it is stored at a high temperature environment or even when it is subjected to charge and discharge repeatedly and also to provide an electrode for a nonaqueous electrolytic lithium secondary battery. There is disclosed a lithium secondary battery using at least a fused salt at ambient temperature having ionic conductivity in which at least one of the positive and negative electrode contains a powder which solely comprises an inorganic solid electrolyte having lithium ionic conductivity. There is also disclosed an electrode for a lithium secondary battery using, at least, a ionic liquid having ionic conductivity which contains a powder solely comprising inorganic solid electrolyte having lithium ionic conductivity.

Abstract: A primary cell having an anode comprising lithium and a cathode comprising iron disulfide (FeS2) and carbon particles. The cell can be in the configuration of a coin cell or the anode and cathode can be spirally wound with separator therebetween and inserted into the cell casing with electrolyte then added. The electrolyte comprises a lithium salt dissolved in a nonaqueous solvent mixture which may include an organic cyclic carbonate such as ethylene carbonate and propylene carbon. The cell after assembly is subjected to a two step preconditioning (prediscahrge) protocol involving at least two distinct discharge steps having at lease one cycle of pulsed current drain in each step and at least one rest period (step rest) between said two steps, wherein said step rest period is carried out for a period of time at above ambient temperature. The preconditioning improves cell performance.

Abstract: A lithium ion conductive solid electrolyte includes an ion conductive inorganic solid and, in a part or all of the pores of the inorganic solid, a material of a composition which is different from the composition of the inorganic solid exists. A method for manufacturing this lithium ion conductive solid electrolyte includes a step of forming an ion conductive inorganic solid to a predetermined form and a step of thereafter filling a material of a composition which is different from the composition of the inorganic solid in pores of the inorganic solid.

Abstract: A non-aqueous electrolyte secondary battery including: a positive electrode; a negative electrode; a separator interposed between the positive electrode and the negative electrode; a non-aqueous electrolyte; and a porous insulating film adhered to a surface of at least one selected from the group consisting of the positive electrode and the negative electrode, the porous insulating film including an inorganic oxide filler and a film binder, wherein the ratio R of actual volume to apparent volume of the separator is not less than 0.4 and not greater than 0.7, and wherein the ratio R and a porosity P of the porous insulating film satisfy the relational formula: ?0.10?R?P?0.30.

Abstract: A solid electrolyte of the present invention is represented by a general formula: LixMOyNz, where M is at least one element selected from the group consisting of Si, B, Ge, Al, C, Ga and S, and x, y and z respectively satisfy x=0.6 to 5.0, y=1.050 to 3.985, and z=0.01 to 0.50. The solid electrolyte hardly deteriorates in a wet atmosphere.

Abstract: The present invention relates to Lithium Metal batteries. In particular, it is related to lithium metal batteries containing a polyimide-based electrolyte. The present invention concerns a new concept of polyimide-based electrolytic component having an electrolyte comprising of at least one solvent and at least one alkali metal salt, with specific amounts of solvents, to optimize the properties of conductivity of the polyimide-based electrolyte and the mechanical properties of the polyimide-based electrolyte separator towards metallic lithium anode to prevent dendrites growths.

Abstract: Affords high-stability, high-safety lithium secondary batteries of high energy density and superlative charge/discharge cyclability, in which shorting due to the growth of dendrites from the metallic-lithium negative electrode is kept under control. A lithium secondary battery negative-electrode component material, formed by laminating onto a substrate a metallic lithium film and an inorganic solid-electrolyte film, the lithium secondary battery negative-electrode component material characterized in that the inorganic solid-electrolyte film incorporates lithium, phosphorous, sulfur, and oxygen, and is represented by the compositional formula noted below. aLi·bP·cS·dO (Li: lithium; P: phosphorous; S: sulfur; O: oxygen), wherein the ranges of the atomic fractions in the composition are: 0.20?a?0.45; 0.10?b?0.20; 0.35?c?0.60; 0.03?d?0.13; (a+b+c+d=1).

Abstract: A solid-state lithium battery including a lithium-containing anode and a phosphorus-containing cathode is disclosed. The cathode may include any of a number of electronically conductive allotropes of phosphorus, referred to as a group as black phosphorus. A solid discharge product of the cell acts as an electrolyte for the cell. The cathode may include an auxiliary electronic conductor phase to improve the conductivity of the cathode, improve the cathode utilization during discharge and reduce the overall cell impedance.

Abstract: A solid amorphous electrolyte composition for a thin-film battery. The electrolyte composition includes a lithium phosphorus oxynitride material containing an aluminum ion dopant wherein the atomic ratio of aluminum ion to phosphorus ion (Al/P) in the electrolyte ranges greater than zero up to about 0.5. The composition is represented by the formula: LitPxAlyOuNvSw, where 5x+3y=5, 2u+3v+2w=5+t, t ranges from about 2.9 to about 3.3, x ranges from about 0.94 to about 0.85, y ranges from about 0.094 to about 0.26, u ranges from about 3.2 to about 3.8, v ranges from about 0.13 to about 0.46, and w ranges from zero to about 0.2. Thin film batteries containing such electrolyte films have less tendency to fail prematurely.

Abstract: A solid oxide electrolyte material comprising an electrolyte material 50 using oxygen ions as carriers as a base material and a lithium-containing compound 60 added to the base material as a sintering additive is sintered at a sintering temperature of 1300° C. or lower to produce a solid oxide electrolyte 100. This solid oxide electrolyte material can reduce the sintering temperature to extend the range of choices of components of a solid oxide fuel cell and suppress reactions between other components to reduce the manufacturing cost. This solid oxide electrolyte material further can produce a solid oxide electrolyte with sufficient denseness and high gas tightness capable of suppressing fuel leak to improve the electromotive force and output.

Abstract: A non-aqueous mixture solvent for a non-aqueous electrolytic solution to be used for electrochemical energy devices, which contains an aprotic solvent, and a fluorinated ketone of the formula: (wherein Rf1 and Rf2 each independently represents a fluorinated aliphatic group, or Rf1 and Rf2 together form a cyclic group, Q represents a fluorinated or non-fluorinated alkylene group or a bond, and n represents 0 or 1), and an electrolytic solution containing the mixture solvent.

Abstract: A method and system for fabricating solid-state energy-storage devices including fabrication films for devices without an anneal step. A film of an energy-storage device is fabricated by depositing a first material layer to a location on a substrate. Energy is supplied directly to the material forming the film. The energy can be in the form of energized ions of a second material. Supplying energy directly to the material and/or the film being deposited assists in controlling the growth and stoichiometry of the film. The method allows for the fabrication of ultrathin films such as electrolyte films and dielectric films.

Abstract: Disclosed are an inexpensive all-solid-state lithium battery and a group of batteries having a small internal resistance. The electrode active material of the battery is formed on the surface of a solid electrolyte (it may be a crystal or a glass material) containing lithium ion such as Li3.4V0.6Si0.4O4 and a Li—Ti—Al—P—O based glass material by exerting ion impact, high voltage application (e.g., about 400 V) and the like on the surface to react it. The resultant battery comprises the solid electrolyte and an electrode active material composed of a decomposition product of the solid electrolyte and provided on at least one side of the solid electrolyte. One obtainable by accumulating a plurality of the batteries serves as a group of batteries.

Abstract: To present a nonaqueous electrolyte secondary battery using iron compound which is inexpensive and abundant in resource, as the active material for the positive electrode. An iron compound with particle size of 1 to 300 nm or less, being composed of substantially spherical primary particles of pore-free matter, is used as the active material for a positive electrode, which is used together with a negative electrode and a nonaqueous electrolyte for composing the battery. By forming the primary particles for composing particles of the iron compound as a pore-free matter, being controlled in a range of 1 to 300 nm, nano effects are brought about, and it is also effective to suppress excessive increase of surface area which may lead to promotion of decomposition of electrolyte, and an excellent discharge capacity is realized stably for a long period.

Abstract: Solid electrolytes of the composition: 60L2O·15Li2SO4·25B2O3; 65L2O·10Li2SO4·25B2O3; 65L2O·15Li2SO4·20B2O3; 60L2O·20Li2SO4·20B2O3; 59,55L2O·19,85Li2SO4·19,85B2O3·0,75MoO3, characterized by the high level of productivity, high ionic conductivity, negligible low level of electronic conductivity and resistance to metal lithium suitable for use in primary and rechargeable lithium power sources.

Abstract: A monolithically integrated lithium thin film battery (10) provides increased areal capacity on a single level (without stacking of multiple cells). The Lithium thin film battery (10) comprises a substrate (12) having a surface (13) textured to comprise a plurality of openings (16) having sides (15) angled between 10 and 80 degrees to the surface (13). A current collector (18) and a cathode (22) are formed on the substrate (12) and within the openings (16). An electrolyte (24) comprising lithium phorphous oxynitride is formed by physical vapor deposition on the cathode (22), thereby providing a layer on the surface of the cathode (22) and within the openings (16) of the cathode having substantially the same thickness. An anode (26) and a capping layer (28) are then formed on the electrolyte (24).

Abstract: A solid amorphous electrolyte composition for a thin-film battery. The electrolyte composition includes a lithium phosphorus oxynitride material containing a sulfide ion dopant wherein the atomic ratio of sulfide ion to phosphorus ion (S/P) in the electrolyte ranges greater than 0 up to about 0.2. The composition is represented by the formula: LitPxAlyOuNvSw, where 5x+3y=5, 2u+3v+2w=5+t, t ranges from about 2.9 to about 3.3, x ranges from about 0.94 to about 0.85, y ranges from about 0.094 to about 0.26, u ranges from about 3.2 to about 3.8, v ranges from about 0.13 to about 0.46, and w ranges from zero to about 0.2. Thin film batteries containing such electrolyte films have less tendency to fail prematurely.

Abstract: A method of manufacturing an intrinsically conductive polymer crosslinking at least a portion of an intrinsically conductive polymer precursor in the solid state, the swollen state, or combinations comprising at least one of the foregoing states, wherein the swollen state is characterized as being one wherein the intrinsically conductive polymer precursor increases in volume upon exposure to a solvent without completely dissolving in the solvent. In another embodiment, a method of manufacturing a pattern comprises casting a film of an intrinsically conductive polymer precursor on a substrate; and crosslinking at least a portion of the film by oxidation, wherein the crosslinking occurs in the solid state, the swollen state or combinations comprising at least one of the foregoing states.

Abstract: A solid electrolyte and a method of manufacturing the same are provided. The solid electrolyte contains x atomic % of lithium, y atomic % of phosphorus, z atomic % of sulfur, and w atomic % of oxygen, in which the x, the y, the z, and the w satisfy the following expressions (1)-(5): 20?x?45 ??(1) 10?y?20 ??(2) 35?z?60 ??(3) 1?w?10 ??(4) x+y+z+w=100 , and ??(5) apexes of X-ray diffraction peaks in an X-ray diffraction pattern obtained by an X-ray diffraction method using a K?-ray of Cu exist at diffraction angles 2? of 16.7°±0.25°, 20.4°±0.25°, 23.8°±0.25°, 25.9°, 0.25°, 29.4°±0.25°, 30.4°±0.25°, 31.7°±0.25°, 33.5°±0.25°, 41.5°±0.25°, 43.7°±0.25°, and 51.2°±0.25°, respectively, in the X-ray diffraction pattern, and a half-width of each of the X-ray diffraction peaks is not larger than 0.5°.

Abstract: A lithium ion conductive solid electrolyte formed by sintering a molding product containing an inorganic powder and having a porosity of 10 vol % or less, which is obtained by preparing a molding product comprising an inorganic powder as a main ingredient and sintering the molding product after pressing and/or sintering the same while pressing, the lithium ion conductive solid electrolyte providing a solid electrolyte having high battery capacity without using a liquid electrolyte, usable stably for a long time and simple and convenient in manufacture and handling also in industrial manufacture in the application use of secondary lithium ion battery or primary lithium battery, a solid electrolyte having good charge/discharge cyclic characteristic in the application use of the secondary lithium ion battery a solid electrolyte with less water permeation and being safe when used for lithium metal-air battery in the application use of primary lithium battery, a manufacturing method of the solid electrolyte, and a

Abstract: The present invention provides a cationic conductor comprising a block copolymer comprising: a polymer moiety having a structural unit represented by formula (1): wherein R represents an organic group obtained via polymerization of monomer compounds having polymerizable unsaturated linkages; Q represents an n+1-valence organic group bonded to R through a single bond; Z represents a functional group capable of forming an ionic bond to or having coordination ability to a cation; Mk+ represents a k-valence cation; and n and m are each independently an integer of 1 or larger, provided that Z forms an ionic or coordination bond to a cation; and a polymer moiety having addition polymerizable monomers.

Abstract: A solid electrolyte including a composition represented by Formula 1 below is provided: aLi2O-bB2O3-cM-dX (1) wherein M is at least one selected from the group consisting of TiO2, V2O5, WO3, and Ta2O5; X is at least one selected from LiCl and Li2SO4; 0.4<a<0.55; 0.4<b<0.55; 0.02<c<0.05; a+b+c=1, and 0?d<0.2. A method for preparing the solid electrolyte and a battery using the solid electrolyte are also provided. The solid electrolyte exhibits high ionic conductivity. Lithium and thin film batteries using the solid electrolyte are improved in charge/discharge rate, power output, and cycle life.

Abstract: An all-solid battery having a high output power, exhibiting high safety, and capable of being produced at a low cost is provided. The all-solid battery (8) includes an internal electrode body (6) having a cathode (1) comprising a cathode material, an anode (2) comprising an anode material, and a solid electrolyte layer (3) comprising a solid electrolyte, the cathode material, the anode material, and the solid electrolyte being phosphoric acid compounds, the internal electrode body (6) being integrated by firing the cathode (1), anode (2), and solid electrolyte layer (3), and the internal electrode body (6) containing water.

Abstract: An all-solid-state battery having a high output power and a long life, exhibiting high safety, and being produced at a low cost is provided. The all-solid-state battery has a cathode comprising a cathode material, an anode comprising an anode material, and a solid electrolyte layer comprising a solid electrolyte, wherein the cathode material, the anode material, and the solid electrolyte are a compound shown by the following formulas (1), (2), and (3), respectively: MaN1bX1c ??(1) MdN2eX2f ??(2) MgN3hX3i ??(3) wherein M represents H, Li, Na, Mg, Al, K, or Ca and X1, X2, and X3 are polyanions, each of N1 and N2 is at least one atom selected from the group consisting of transition metals, Al, and Cu, and N3 is at least one atom selected from the group consisting of Ti, Ge, Hf, Zr, Al, Cr, Ga, Fe, Sc, and In.

Abstract: The invention concerns an electrochemical generator element (102) comprising successively a first electrode layer having a polarity (114), a first electrolyte layer (110), a second electrode layer with reverse polarity (108), a second electrolyte layer (112), a second electrode layer with said polarity (116). The electrode layers of said polarity (114, 116) are connected by a parallel connection. It further comprises current collectors (118, 120) connected to the electrode layers with said polarity (114, 116). The thickness of the first electrode layer with said polarity (114) is different from the thickness of said second electrode layer with said polarity (116). The invention is applicable to lithium-polymer storage batteries.

Abstract: An object of the present invention is to provide a boron-containing compound capable of forming an ion-conductive polyelectrolyte having high ion-conductive properties, and a polymer of said compound.

Abstract: A solid state ion conducting electrolyte and a battery incorporating same. The electrolyte includes a polymer matrix with an alkali metal salt dissolved therein, the salt having an anion with a long or branched chain having not less than 5 carbon or silicon atoms therein. The polymer is preferably a polyether and the salt anion is preferably an alkyl or silyl moiety of from 5 to about 150 carbon/silicon atoms.

Abstract: A solid electrolyte, a method of manufacturing the same, and a lithium battery and a thin-film battery that employ the solid electrolyte are provided. The solid electrolyte contains nitrogen to enhance the ionic conductivity and electrochemical stability of batteries.

Abstract: To inhibit decrease in charge-discharge, storage and charge-discharge cycle characteristics due to reduction of phosphorus atoms in a battery including lithium phosphorus oxynitride as a solid electrolyte, a transition metal element is incorporated into lithium phosphorus oxynitride to prepare a solid electrolyte.

Abstract: There are provided glass-ceramics having a high lithium ion conductivity which include in mol %: P2O5 38–40% TiO2 25–45% M2O3 (where M is Al or Ga) ?5–15% Li2O 10–20% and contain Li1+X(Al, Ga)XTi2?X(PO4)3 (where 0<X<0.8) as a main crystal phases. There are also provided glass-ceramics having a high lithium ion conductivity which include in mol %: P2O5 ?26–40% SiO2 0.5–12% TiO2 ?30–45% M2O3 (where M is Al or Ga) ??5–10% Li2O ?10–18% and contain Li1+X+YMXTi2?XSiYP3?YO12 (where 0<X?0.4 and 0<Y?0.6) as a main crystal phase. There are also provided solid electrolytes for an electric cell and a gas sensor using alkali ion conductive glass-ceramics, and a solid electric cell and a gas sensor using alkali ion conductive glass-ceramics as a solid electrolyte.

Abstract: Provided are a composite polymer electrolyte for a lithium secondary battery that includes a composite polymer matrix structure having a single ion conductor-containing polymer matrix to enhance ionic conductivity and a method of manufacturing the same. The composite polymer electrolyte includes a first polymer matrix made of a first porous polymer with a first pore size; a second polymer matrix made of a single ion conductor, an inorganic material, and a second porous polymer with a second pore size smaller than the first pore size. The second polymer matrix is coated on a surface of the first polymer matrix. The composite polymer matrix structure can increase mechanical properties. The single ion conductor-containing porous polymer matrix of a submicro-scale can enhance ionic conductivity and the charge/discharge cycle stability.

Abstract: A sulfide-based inorganic solid electrolyte that suppresses the reaction between silicon sulfide and metallic lithium even when the electrolyte is in contact with metallic lithium, a method of forming the electrolyte, and a lithium battery's member and lithium secondary battery both incorporating the electrolyte. The electrolyte comprises Li, P, and S without containing Si. It is desirable that the oxygen content vary gradually from the electrolyte to the lithium-containing material at the boundary zone between the two members when analyzed by using an XPS having an analyzing chamber capable of maintaining a super-high vacuum less than 1.33×10?9 h Pa and that the oxygen-containing layer on the surface of the lithium-containing material be removed nearly completely. The electrolyte can be formed such that at least part of the forming step is performed concurrently with the step for etching the surface of the substrate by irradiating the surface with inert-gas ions.

Abstract: A method and system for fabricating solid-state energy-storage devices including fabrication films for devices without an anneal step. A film of an energy-storage device is fabricated by depositing a first material layer to a location on a substrate. Energy is supplied directly to the material forming the film. The energy can be in the form of energized ions of a second material. Supplying energy directly to the material and/or the film being deposited assists in controlling the growth and stoichiometry of the film. The method allows for the fabrication of ultrathin films such as electrolyte films and dielectric films.

Abstract: A non-aqueous electrolyte containing propylene carbonate and 1,3-propanesultone as additives can reduce the amount of a gas evolved during storage at a high temperature of a non-aqueous electrolyte secondary cell comprising the electrolyte, a non-aqueous electrolyte containing at least one compound selected from the group consisting of vinylene carbonate, diphenyl disulfide, di-p-tolydisulfide and bis(4-methoxyphenyl)disulfide as comprising the electrolyte, and a non-aqueous electrolyte containing a combination of the above-two types of additives can provide a non-aqueous electrolyte secondary cell exhibiting excellent retention of capacity and storage stability.

Abstract: The present invention provides a cationic conductor comprising a block copolymer comprising: a polymer moiety having a structural unit represented by formula (1): wherein R represents an organic group obtained via polymerization of monomer compounds having polymerizable unsaturated linkages; Q represents an n+1-valence organic group bonded to R through a single bond; Z represents a functional group capable of forming an ionic bond to or having coordination ability to a cation; Mk+ represents a k-valence cation; and n and m are each independently an integer of 1 or larger, provided that Z forms an ionic or coordination bond to a cation; and a polymer moiety having addition polymerizable monomers.

Abstract: A polymeric sol electrolyte including a sol-forming polymer and an electrolytic solution consisting of a lithium salt and an organic solvent. Use of the polymeric sol electrolyte allows problems such as swelling or leakage to be overcome, compared to the case of using a liquid-type electrolytic solution. Also, the polymeric sol electrolyte has better ionic conductivity than a polymeric gel electrolyte. In addition, when the lithium battery according to the present invention is overcharged at 4.2 V or higher, an electrochemically polymerizable material existing in the polymeric sol electrolyte is subjected to polymerization to prevent heat runaway, which simplifies a separate protection circuit, leading to a reduction in manufacturing cost.

Abstract: This invention pertains to the composition and method for fabricating nano-tube composite polymer electrolyte. The composite polymer electrolyte is made by blending suitable amount of highly dispersed, nano-tube, such as titanium dioxide (TiO2), with highly amorphous polymer electrolyte, such as polyethylene oxide. The hollow nano-tube structure facilitates salt dissociation, serves temporarily storage for lithium ions, creates new conducting mechanism and improves the conductivity thereof. The subsequent thermal treatment and high electric field arrange the nano-tubes in order for increase of the dielectric constant thereof, which increased ion mobility at room temperature. The mechanical properties are also improved due to the physical cross-linking of the nano-tubes, suitable for industrial processing.

Abstract: A nonaqueous electrolyte lithium secondary cell comprising a positive electrode (1), a negative electrode (2) and a nonaqueous electrolyte containing a lithium salt is characterized by that the nonaqueous electrolyte contains a room temperature molten salt as a main component, a material wherein a working potential of the negative electrode (2) is nobler by above 1V than a potential of a metallic lithium is used for a negative active material of the negative electrode. This nonaqueous electrolyte lithium secondary cell has excellent safety and cell performance.

Abstract: The invention provides novel lithium-mixed metal materials which, upon electrochemical interaction, release lithium ions, and are capable of reversibly cycling lithium ions. The invention provides a rechargeable lithium battery which comprises an electrode formed from the novel lithium-mixed metal materials. Methods for making the novel lithium-mixed metal materials and methods for using such lithium-mixed metal materials in electrochemical cells are also provided. The lithium-mixed metal materials comprise lithium and at least one other metal besides lithium. Preferred materials are lithium-mixed metal phosphates which contain lithium and two other metals besides lithium.

Abstract: Solid battery components are provided. A block copolymeric electrolyte is non-crosslinked and non-glassy through the entire range of typical battery service temperatures, that is, through the entire range of at least from about 0° C. to about 70° C. The chains of which the copolymer is made each include at least one ionically-conductive block and at least one second block immiscible with the ionically-conductive block. The chains form an amorphous association and are arranged in an ordered nanostructure including a continuous matrix of amorphous ionically-conductive domains and amorphous second domains that are immiscible with the ionically-conductive domains. A compound is provided that has a formula of LixMyNzO2. M and N are each metal atoms or a main group elements, and x, y and z are each numbers from about 0 to about 1. y and z are chosen such that a formal charge on the MyNz portion of the compound is (4-x). In certain embodiments, these compounds are used in the cathodes of rechargeable batteries.

Abstract: Disclosed is a lithium secondary battery comprising a positive electrode including a material that is capable of reversible intercalation/deintercalation of lithium ions as a positive active material; a negative electrode including a material that is capable of reversible intercalation/deintercalation of lithium ions as a negative active material; and an electrolyte including a lithium salt, a carbonate-based organic solvent, and an isoxazole compound of the following formula (1):

Abstract: Provided are a polymeric electrolyte or a nonaqueous electrolyte that can improve a transport rate of charge carrier ions by adding a compound having boron atoms in the structure, preferably one or more selected from the group consisting of compounds represented by the following general formulas (1) to (4), and an electric device such as a cell or the like using the same. wherein R11, R12, R13, R14, R15, R16, R21, R22, R23, R24, R25, R26, R27, R28, R31, R32, R33, R34, R35, R36, R37, R38, R39, R310, R41, R42, R43, R44, R45, R46, R47, R48, R49, R410, R411 and R412 each represent a hydrogen atom, a halogen atom or a monovalent group, or represent groups bound to each other to form a ring, and Ra, Rb, Rc and Rd each represent a group having a site capable of being bound to boron atoms which are the same or different.