Plural Cyclic Carbonate Solvents Patents (Class 429/331)
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Patent number: 7745058Abstract: A non-aqueous solvent is provided that includes ethylene carbonate in a range from 5% or more to less than 60%, propylene carbonate of 40% or less, and diethyl carbonate of 40% or more, as mass ratios. The non-aqueous electrolyte compositions are formed by further adding an electrolytic salt and, if necessary, unsaturated cyclic carbonic ester and a high molecular compound into the non-aqueous solvent. A non-aqueous electrolyte secondary battery is formed by using the non-aqueous electrolyte compositions.Type: GrantFiled: January 29, 2007Date of Patent: June 29, 2010Assignee: Sony CorporationInventor: Yukifumi Takeda
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Patent number: 7745057Abstract: A nonaqueous electrolyte secondary battery 10 according to an embodiment of the invention includes a positive electrode 11, a negative electrode 12, a separator 13 and a nonaqueous electrolyte liquid in which not only the positive electrode 11 contains a positive electrode active material charged at or higher than 4.3 V based on lithium and a halogenated cyclic carbonate is added in the nonaqueous electrolyte liquid, but also an inorganic insulating material particle layer is formed on the surface of at least either of the positive electrode 11, the negative electrode 12 and the separator 13. By employing such a constitution in the present invention, a nonaqueous electrolyte secondary battery using a positive electrode charged at a high electric potential of 4.3 V or more based on lithium in which the amount of a generated gas is small even when the battery is overcharged at higher temperatures, and the impact safety and reliability thereof are high, can be provided.Type: GrantFiled: February 22, 2008Date of Patent: June 29, 2010Assignee: Sanyo Electric Co., Ltd.Inventors: Takeshi Abe, Masato Iwanaga
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Publication number: 20100159336Abstract: A rechargeable lithium battery includes an electrolyte including an additive such as an ethylene carbonate-based compound represented by Chemical Formula 1 and a silicon-included compound, and a negative electrode including a negative active material including an active element selected from the group consisting of Si, Sn, Ga, Cd, Al, Pb, Zn, Bi, In, Mg, and Ge. In Chemical formula 1, X and Y are independently selected from the group consisting of hydrogen, a halogen, and a C1 through C5 fluoroalkyl, provided that at least one of X and Y is selected from the group consisting of a halogen and a C1 through C5 fluoroalkyl. The rechargeable lithium battery has a suppressed volume expansion characteristic due to a high-capacity negative active material, and has excellent reliability and cycle-life characteristics.Type: ApplicationFiled: March 31, 2009Publication date: June 24, 2010Inventors: Jin-Sung Kim, Na-Rae Park, Su-Hee Han, Jin-Hyunk Lim
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Patent number: 7732097Abstract: A battery capable of improving cycle characteristics is provided. A cathode contains an oxide containing lithium and manganese such as Li4Mn5O12 as a cathode material. An anode contains a carbon material as and anode material. The weight ratio of the cathode material to the anode material is in the range from 2.03 to 2.53. The electrical capacity ratio of the cathode to the anode is in the range from 0.8 to 1.0. The open circuit voltage in full charge state per a pair of cathode and anode is from 2.9 V to 3.2 V.Type: GrantFiled: February 7, 2006Date of Patent: June 8, 2010Assignee: Sony CorporationInventor: Kenichi Suzuki
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Patent number: 7727677Abstract: Disclosed is a lithium secondary battery which is excellent in battery characteristics such as long-term cycle characteristics, capacity and shelf life characteristics. Also disclosed is a nonaqueous electrolyte solution which can be used for such a lithium secondary battery. Specifically disclosed is a nonaqueous electrolyte solution for lithium secondary batteries obtained by dissolving an electrolyte salt in a nonaqueous solvent which is characterized by containing 0.01-10% by weight of a carboxylate compound represented by the general formula (I) below and 0.01-10% by weight or 0.01-10% by volume of a vinylene carbonate and/or 1,3-propane sultone. Also disclosed is a lithium secondary battery using such a nonaqueous electrolyte solution. (In the formula, R2 represents a hydrogen atom or COOR3 group, R1 and R3 respectively represent an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group or a phenyl group, and X represents an alkynylene group or an alkenylene group.Type: GrantFiled: May 18, 2005Date of Patent: June 1, 2010Assignee: Ube Industries, Ltd.Inventors: Koji Abe, Takaaki Kuwata, Hirofumi Takemoto
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Publication number: 20100124707Abstract: A secondary battery capable of obtaining superior cycle characteristics and superior swollenness characteristics is provided. The secondary battery includes a cathode and an anode capable of inserting and extracting an electrode reactant; and an electrolyte containing a solvent and an electrolyte salt. The anode has an anode active material layer on an anode current collector. The anode active material layer contains a plurality of crystalline anode active material particles having silicon (Si) as an element. The plurality of anode active material particles contain a spherical particle and a nonspherical particle.Type: ApplicationFiled: November 12, 2009Publication date: May 20, 2010Applicant: SONY CORPORATIONInventors: Takakazu Hirose, Kenichi Kawase, Kazunori Noguchi, Takayuki Fujii
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Publication number: 20100124706Abstract: A secondary battery capable of obtaining superior cycle characteristics and superior swollenness characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. The electrolytic solution is impregnated in a separator provided between the cathode and the anode. An anode active material layer contains a crystalline anode active material having silicon as an element. The anode active material layer has a coating section where the surface of an anode current collector is coated with the anode active material and a non-coating section where the surface of the anode current collector is not coated with the anode active material but is exposed. Thereby, the physical property of the anode active material is hardly deteriorated with age. Further, at the time of charge and discharge, the anode active material layer is hardly expanded and shrunk, and thus the anode current collector is hardly deformed.Type: ApplicationFiled: November 11, 2009Publication date: May 20, 2010Applicant: SONY CORPORATIONInventors: Takakazu Hirose, Kenichi Kawase, Kazunori Noguchi, Takayuki Fujii
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Patent number: 7709154Abstract: Disclosed is an electrolyte of a lithium secondary battery comprising a lithium salt, an organic solvent, and at least one additive compound selected from the group consisting of compounds represented by the following formula (1) and derivatives thereof: where R1 is selected from the group consisting of hydrogen radicals, alkyls, aryls, cycloalkyls, alkenyls, alkynyls, ester radicals, and aliphatic carbonate radicals. The electrolyte improves both swelling inhibition properties at high temperature and capacity characteristics of a lithium secondary battery.Type: GrantFiled: February 13, 2009Date of Patent: May 4, 2010Assignee: Samsung SDI Co., Ltd.Inventor: Hyung-Gon Noh
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Patent number: 7709157Abstract: The present invention provides a safe non-aqueous electrolyte secondary battery with characteristics analogous to those of a conventional battery by minimizing battery expansion that causes damage to a device during high temperature exposure or storage. The non-aqueous electrolyte secondary battery comprises: (a) a chargeable and dischargeable positive electrode; (b) a negative electrode capable of absorbing and desorbing lithium; (c) a separator for preventing direct electron transfer between the positive electrode and the negative electrode; and (d) an non-aqueous electrolyte; the non-aqueous electrolyte comprising a non-aqueous solvent and a solute, the non-aqueous solvent comprising a lactone, the solute comprising lithium bis(fluorosulfonyl)imide represented by the formula (1): (F—O2S—N—SO2—F)Li.Type: GrantFiled: October 22, 2003Date of Patent: May 4, 2010Assignee: Panasonic CorporationInventors: Kumiko Mie, Hizuru Koshina, Tooru Matsui, Masaki Deguchi
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Patent number: 7709142Abstract: A battery capable of obtaining a high energy density and obtaining superior cycle characteristics is provided. The thickness of a cathode active material layer is from 100 ?m to 130 ?m. The thickness of an anode active material layer is from 85 ?m to 120 ?m, and the volume density of the anode active material layer is from 1.7 g/cm3 to 1.85 g/cm3. An electrolytic solution contains 4-fluoro-1,3-dioxolane-2-one. Thereby, even when the thicknesses of the cathode active material layer and the anode active material layer are increased, the diffusion and acceptance of lithium in an anode are improved, and superior cycle characteristics can be obtained.Type: GrantFiled: December 7, 2006Date of Patent: May 4, 2010Assignee: Sony CorporationInventors: Shinya Wakita, Izaya Okae, Yosuke Ushio, Yoshiaki Takeuchi, Saori Tokuoka
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Patent number: 7704640Abstract: A non-aqueous electrolyte secondary cell excellent in cycle characteristics is provided. This purpose is achieved by the following structure. A non-aqueous electrolyte secondary cell has a positive electrode having a positive electrode active material, a negative electrode having a negative electrode active material, and a non-aqueous electrolyte having a non-aqueous solvent and an electrolytic salt. The positive electrode active material has a lithium-cobalt compound oxide having added therein at least zirconium. The non-aqueous electrolyte has LiBF4 at from 0.05 to 1.0 mass % of a total mass of the non-aqueous electrolyte and unsaturated cyclic carbonate at from 1.0 to 4.0 mass %. The true density ratio of the positive electrode is 0.72 or greater, the true density ratio being represented by formula 1 shown below: (Formula 1) True density ratio=active material apparent density of electrode active material layer÷true density of active material.Type: GrantFiled: February 27, 2006Date of Patent: April 27, 2010Assignee: Sanyo Electric Co., Ltd.Inventors: Keisuke Ooga, Masato Iwanaga, Hideyuki Inomata, Ryuji Ohshita
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Patent number: 7700242Abstract: This invention discloses a type of mixed additives for electrolyte of lithium-ion secondary batteries, having the following characteristics: in weight percentage: biphenyl series: 0.5% to 95.4%; cyclohexylbenzene series: 1.1% to 93.8%; vinylene carbonate: 0.4% to 93.2%; phenyl vinyl sulfone: 0.5% to 96.5%; ethenyl sulfonyl benzene: 0.5% to 95.8%. This invention also discloses an electrolyte for lithium-ion secondary batteries comprising organic solvents and lithium saline, wherein the special characteristic is that it comprises 2% to 20% weight percentage of said mixed additives. The distinctive advantage of the mixed additives for lithium-ion secondary batteries of this invention is to effectively enhance the overcharging, low-temperature, and cycle properties of lithium-ion batteries. A lithium-ion battery having the mixed additives of this invention remains explosion-free, ignition-free and reliably safe when the lithium-ion secondary battery is overcharging.Type: GrantFiled: October 18, 2006Date of Patent: April 20, 2010Assignee: BYD Company LimitedInventors: Feng Xiao, Mingxia Wang, Guishu Zhou, Huaying You
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Publication number: 20100092856Abstract: A secondary battery capable of improving the cycle characteristics and the initial charge and discharge characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. The anode has an anode active material layer on an anode current collector. The anode active material layer contains a crystalline anode active material having silicon as an element, and is linked to the anode current collector.Type: ApplicationFiled: April 7, 2009Publication date: April 15, 2010Applicant: SONY CORPORATIONInventors: Takakazu Hirose, Kenichi Kawase, Kazunori Noguchi, Takayuki Fujii, Rikako Imoto
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Patent number: 7687204Abstract: An electrolyte for a lithium secondary battery comprises lithium salts including LiPF6 and LiBF4; a non-aqueous organic solvent including an organic solvent with high boiling point; and vinylene carbonate. The electrolyte may inhibit battery swelling at high temperature storage and may improve battery cycle-life characteristics.Type: GrantFiled: July 23, 2004Date of Patent: March 30, 2010Assignee: Samsung SDI Co., LtdInventors: Jun-won Kang, Jin-Sung Kim
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Publication number: 20100047695Abstract: The invention discloses various embodiments of Li-ion electrolytes containing flame retardant additives that have delivered good performance over a wide temperature range, good cycle life characteristics, and improved safety characteristics, namely, reduced flammability. In one embodiment of the invention there is provided an electrolyte for use in a lithium-ion electrochemical cell, the electrolyte comprising a mixture of an ethylene carbonate (EC), an ethyl methyl carbonate (EMC), a fluorinated co-solvent, a flame retardant additive, and a lithium salt. In another embodiment of the invention there is provided an electrolyte for use in a lithium-ion electrochemical cell, the electrolyte comprising a mixture of an ethylene carbonate (EC), an ethyl methyl carbonate (EMC), a flame retardant additive, a solid electrolyte interface (SEI) film forming agent, and a lithium salt.Type: ApplicationFiled: August 18, 2009Publication date: February 25, 2010Applicants: California Institute of Technology, University of Southern CaliforniaInventors: Marshall C. Smart, Kiah A. Smith, Ratnakumar V. Bugga, Surya G. Prakash, Frederick Charles Krause
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Patent number: 7662515Abstract: A nonaqueous electrolyte battery includes a negative electrode including a current collector and a negative electrode active material having a Li ion insertion potential not lower than 0.4V (vs. Li/Li+). The negative electrode has a porous structure. A pore diameter distribution of the negative electrode as determined by a mercury porosimetry, which includes a first peak having a mode diameter of 0.01 to 0.2 ?m, and a second peak having a mode diameter of 0.003 to 0.02 ?m. A volume of pores having a diameter of 0.01 to 0.2 ?m as determined by the mercury porosimetry is 0.05 to 0.5 mL per gram of the negative electrode excluding the weight of the current collector. A volume of pores having a diameter of 0.003 to 0.02 ?m as determined by the mercury porosimetry is 0.0001 to 0.02 mL per gram of the negative electrode excluding the weight of the current collector.Type: GrantFiled: October 31, 2005Date of Patent: February 16, 2010Assignee: Kabushiki Kaisha ToshibaInventors: Hiroki Inagaki, Norio Takami
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Patent number: 7659037Abstract: Using a positive electrode active material including spinel type manganese oxide as the main constituent, a novel low cost and high output power flat type nonaqueous secondary cell for HEVs that has increased safety at overcharge, and superior storage properties and cycle life is provided. A flat type nonaqueous secondary cell that has increased safety and is superior in storage and cycle properties even though the cell is a laminate type cell which does not have a blocking mechanism can be obtained by blending the spinel type lithium manganese oxide of the positive electrode and 5 wt % to 40 wt % of layered type lithium manganese oxide, to suppress storage deterioration at a high temperature and to simultaneously achieve safety when overcharged, and further, by adding a Li compound having a structure as shown in Formula (1) structure, to suppress deterioration of a mixed positive electrode active material during a high temperature cycle.Type: GrantFiled: December 13, 2006Date of Patent: February 9, 2010Assignees: Hitachi, Ltd., Hitachi Vehicle Energy, Ltd.Inventors: Hiroshi Fukunaga, Youshin Yagi, Shuichi Wada, Kenji Hara, Kazushige Kohno, Hiroshi Haruna
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Publication number: 20100028771Abstract: Electrolyte and lithium secondary batteries containing the same are disclosed. In one instance, the electrolyte includes a lithium salt, a solvent and an additive. In some examples, the additive includes substances A, B and C, wherein substance A is vinylene carbonate, substance B includes at least one of fluorinated or chlorinated ethylene carbonate or diethylene carbonate, and substance C includes at least one of ethylene sulfite, 1,3-propanesultone and propenyl sulfite.Type: ApplicationFiled: June 11, 2009Publication date: February 4, 2010Inventors: GuiShu ZHOU, Lei SI, Yong WANG, YiWei FAN
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Patent number: 7642015Abstract: A nonaqueous electrolyte secondary battery includes an electrode group having a positive electrode and a negative electrode wound flatly by way of an interposed separator, a positive electrode tab electrically connected to the positive electrode, and projecting from a spiral winding surface of the electrode group, a negative electrode tab electrically connected to the negative electrode, and projecting from the spiral winding surface, and a nonaqueous electrolyte, wherein the nonaqueous solvent contains sultone compound including a ring having at least one double bond, and a distance between the positive electrode tab and the negative electrode tab is 6 mm to 18 mm.Type: GrantFiled: August 6, 2007Date of Patent: January 5, 2010Assignee: Kabushiki Kaisha ToshibaInventors: Shusuke Inada, Masahiro Sekino, Akira Yajima, Nao Shimura, Asako Satoh, Masayuki Oguchi, Hiroshi Kitayama
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Publication number: 20090325041Abstract: A lithium secondary battery is disclosed which includes: a cathode that is capable of storing/releasing a lithium ion, an anode that is capable of storing/releasing a lithium ion, a separator that separates the electrodes from each other, and an electrolyte solution. The cathode includes a cathode-active material and an electroconductive material comprised of at least one gas-generating resin that is decomposed with generation of a gas at a temperature at which oxygen is eliminated from the cathode-active material, and an electroconductive filler.Type: ApplicationFiled: June 25, 2009Publication date: December 31, 2009Applicant: Hitachi, Ltd.Inventors: Takefumi OKUMURA, Shigetaka Tsubouchi
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Patent number: 7635542Abstract: A non-aqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and a non-aqueous electrolyte comprising an electrolyte dissolved in a non-aqueous solvent. The negative electrode uses a low crystalline carbon coated graphite in which at least part of the surface of graphite is coated with a low crystalline carbon material having lower crystallinity than that of graphite as a negative electrode active material, and the non-aqueous electrolyte comprises a lithium salt which has oxalate complex as an anion, in addition to a mixed solvent of propylene carbonate and chain carbonate as a non-aqueous solvent.Type: GrantFiled: October 3, 2007Date of Patent: December 22, 2009Assignee: Sanyo Electric Co., Ltd.Inventors: Hideki Kitao, Takanobu Chiga
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Publication number: 20090311608Abstract: A secondary battery capable of improving the cycle characteristics and the voltage retention characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolyte. The anode includes an anode current collector, an anode active material layer formed on the anode current collector and including an anode active material containing silicon as an element, and a coat formed on the anode active material layer and having an integral structure of three-dimensional network.Type: ApplicationFiled: June 10, 2009Publication date: December 17, 2009Applicant: SONY CORPORATIONInventors: Takakazu Hirose, Kenichi Kawase, Kazunori Noguchi, Takayuki Fujii, Masaki Kawata
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Patent number: 7615317Abstract: A rechargeable lithium-ion cell contains a positive electrode, negative electrode, charge-carrying electrolyte containing charge carrying medium and lithium salt, and cycloaliphatic N-oxide compound dissolved in or dissolvable in the electrolyte. The N-oxide compound has an oxidation potential above the positive electrode recharged potential and serves as a cyclable redox chemical shuttle providing cell overcharge protection.Type: GrantFiled: May 17, 2005Date of Patent: November 10, 2009Assignee: 3M Innovative Properties CompanyInventors: Jeffrey R. Dahn, Claudia Buhrmester
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Patent number: 7615316Abstract: In order to manufacture a lithium secondary battery having excellent performances in safety under overcharge condition, cycle property, electric capacity, and storage endurance, 0.1 wt. % to 10 wt. % of a tert-alkylbenzene compound is favorably incorporated into a non-aqueous electrolytic solution comprising a non-aqueous solvent and an electrolyte, preferably in combination with 0.1 wt. % to 1.5 wt. % of a biphenyl compound.Type: GrantFiled: October 24, 2007Date of Patent: November 10, 2009Assignee: UBE Industries, Ltd.Inventors: Koji Abe, Yasuo Matsumori, Akira Ueki
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Patent number: 7601463Abstract: A nonaqueous electrolyte secondary battery includes: an outer housing; a nonaqueous electrolyte filled in the outer housing, a positive electrode housed in the outer housing, a negative electrode housed in the outer housing and a separator disposed between the negative electrode and the positive electrode. The nonaqueous electrolyte comprises a nonaqueous solvent including diethyl carbonate and at least one of ethylene carbonate and propylene carbonate, and the nonaqueous electrolyte has a content of the diethyl carbonate of from 80 to 95% by volume. The positive electrode comprises a positive electrode active substance having a positive electrode potential in a full charged state of 4.4 V or higher with respect to a potential of metallic lithium. The negative electrode comprises a negative electrode active substance having a negative electrode potential in a full charged state of 1.0 V or higher with respect to a potential of metallic lithium.Type: GrantFiled: June 9, 2005Date of Patent: October 13, 2009Assignee: Kabushiki Kaisha ToshibaInventors: Hiroki Inagaki, Hideaki Morishima, Yoshinao Tatebayashi, Yuji Sato, Norio Takami
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Patent number: 7595130Abstract: A separator is disclosed which enables to inject a non-aqueous electrolytic solution easily during production of batteries such as lithium ion secondary batteries and also enables to produce a battery which is excellent in various battery performances. The battery separator comprises a long porous film in which plural non-porous linear regions are arranged in a width direction of the film, at least one surface of the linear regions being a concave or convex surface is advantageously used as a battery separator for lithium secondary batteries or the like.Type: GrantFiled: August 30, 2004Date of Patent: September 29, 2009Assignee: UBE Industries, Ltd.Inventors: Kenji Kawabata, Koji Abe
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Publication number: 20090226819Abstract: A secondary battery is provided and includes a cathode, an anode and an electrolytic solution, in which the anode includes an anode active material layer including a plurality of anode active material particles, the plurality of anode active material particles including silicon as a constituent element. The anode active material layer includes at least one of an oxide-containing film and a metal material as a constituent element. The oxide-containing film with which surfaces of the anode active material particles are covered. The metal material includes a metal element which is not alloyed with an electrode reactant, and being arranged in a gap in the anode active material layer. The electrolytic solution includes a solvent including at least one kind selected from the group consisting of specific isocyanate compounds.Type: ApplicationFiled: March 10, 2009Publication date: September 10, 2009Applicant: SONY CORPORATIONInventors: Masayuki Ihara, Hiroyuki Yamaguchi, Tadahiko Kubota
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Publication number: 20090226818Abstract: An organic electrolytic solution including a lithium salt; an organic solvent including a high dielectric solvent and a low boiling point solvent; and an additive compound containing an electron withdrawing group and hydrocarbon-based substituents. A lithium battery using the organic electrolytic solution can have improved cycle characteristics and cycle life through preventing decomposition of the electrolyte.Type: ApplicationFiled: August 22, 2008Publication date: September 10, 2009Applicant: Samsung SDI Co., Ltd.Inventors: Seok-soo LEE, Dong-joon LEE, Young-gyoon RYU
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Patent number: 7585590Abstract: Provided is a rechargeable lithium-ion cell that contains a positive electrode, a negative electrode, a charge-carrying electrolyte containing a charge carrying medium and a lithium salt, and a triphenylamine compound dissolved in or dissolvable in the electrolyte. The triphenylamine compound has an oxidation potential above the positive electrode recharged potential and serves as a cyclable redox chemical shuttle providing cell overcharge protection. Also provided are methods for manufacturing a rechargeable lithium-ion cell.Type: GrantFiled: February 5, 2007Date of Patent: September 8, 2009Assignee: 3M Innovative Properties CompanyInventors: Richard L. Wang, Claudia Buhrmester, William M. Lamanna, Jeffrey R. Dahn, Lee Moshurchak
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Patent number: 7582389Abstract: A non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode and a non-aqueous electrolyte, wherein the non-aqueous electrolyte includes an onium compound, a lithium salt and a chain carbonate having a C?C unsaturated bond. The onium compound is preferably at least one selected from the group consisting of a chain quaternary ammonium compound, a pyrrolidinium compound and a piperidinium compound. The chain carbonate having a C?C unsaturated bond is preferably at least one selected from the group consisting of diallyl carbonate and allyl phenyl carbonate.Type: GrantFiled: August 29, 2005Date of Patent: September 1, 2009Assignee: Panasonic CorporationInventors: Tooru Matsui, Masaki Deguchi, Hiroshi Yoshizawa
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Publication number: 20090197184Abstract: A non-aqueous electrolytic solution battery includes a positive electrode, a negative electrode and an electrolytic solution, wherein the non-aqueous electrolytic solution contains two kinds of halogenated cyclic carbonates containing a different halogen element from each other.Type: ApplicationFiled: January 30, 2009Publication date: August 6, 2009Applicant: SONY CORPORATIONInventor: Atsumichi Kawashima
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Publication number: 20090191465Abstract: An additive for an electrolyte of a lithium secondary battery, the additive including a polysiloxane-based compound represented by Formula 1 below: In formula 1 R1, R2, R3, A1, A2, l, m, n, o and p are as described in the detailed description of the present invention.Type: ApplicationFiled: August 4, 2008Publication date: July 30, 2009Applicant: SAMSUNG SDI CO., LtdInventors: Seung-sik HWANG, Young-gyoon Ryu, Seok-soo Lee, Dong-joon Lee
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Publication number: 20090181311Abstract: The preservation performance of a nonaqueous electrolyte secondary cell charged to high potential is improved while the initial capacity and the cycle property of the cell are also improved. The nonaqueous electrolyte secondary cell includes: a positive electrode having lithium phosphate and a positive electrode active material containing lithium cobalt compound oxide and lithium manganese nickel compound oxide having a layer structure, the lithium cobalt compound oxide having at least zirconium and magnesium added in LiCoO2; a negative electrode having a negative electrode active material; and a nonaqueous electrolyte having a nonaqueous solvent and an electrolytic salt. The potential of the positive electrode is more than 4.3 V and 5.1 V or less based on lithium. The nonaqueous electrolyte contains vinylene carbonate as the nonaqueous solvent and, as the electrolytic salt, at least one of lithium bis(pentafluoroethane sulfonyl)imide and lithium bis(trifluoromethane sulfonyl)imide at 0.1 M or more and 0.Type: ApplicationFiled: May 30, 2007Publication date: July 16, 2009Applicant: SANYO ELECTRIC CO., LTD.Inventors: Masato Iwanaga, Kentaro Takahashi, Yukihiro Oki, Yoshihiko Ikeda, Akira Kinoshita, Nobumichi Nishida
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Patent number: 7556889Abstract: A life of a secondary battery is extended, increase in a resistance when storing a secondary battery at an elevated temperature is prevented, and increase in a resistance during a charge-discharge cycle is prevented. A positive electrode active material comprising a lithium manganate and a lithium nickelate are used. The lithium manganate is a compound represented by the following formula (1) or the compound in which some of Mn or O sites are replaced with another element: Li1+xMn2?xO4??(1) (in the above-shown formula (1), 0.15?x?0.24).Type: GrantFiled: May 26, 2004Date of Patent: July 7, 2009Assignee: NEC CorporationInventors: Tomokazu Kumeuchi, Tatsuji Numata, Daisuke Kawasaki
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Patent number: 7537861Abstract: A lithium secondary battery comprising a positive electrode, a negative electrode of artificial graphite or natural graphite and a nonaqueous electrolytic solution having an electrolyte dissolved in a nonaqueous solvent, wherein 0.1 to 20 wt. % of a cyclohexylbenzene having a halogen atom bonded to a benzene ring thereof is contained in the nonaqueous electrolytic solution exhibits large electric capacity and excellent cycle performance.Type: GrantFiled: July 31, 2003Date of Patent: May 26, 2009Assignee: UBE Industries, Ltd.Inventors: Koji Abe, Takashi Hattori, Takaaki Kuwata, Yasuo Matsumori
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Publication number: 20090123849Abstract: The present application provides a nonaqueous electrolyte secondary battery that includes, a cathode capable of being electrochemically doped/dedoped with lithium, an anode capable of being electrochemically doped/dedoped with lithium, and an electrolyte placed between the cathode and the anode, wherein the electrolyte contains at least one of fluoro ethylene carbonate represented by Chemical Formula (1) and difluoro ethylene carbonate represented by Chemical Formula (2) as a solvent and the ratio of a discharge capacity B during discharging at a 5C rate to a discharge capacity A during discharging at a 0.2C rate ((B/A)×100) is 80% or more.Type: ApplicationFiled: October 24, 2008Publication date: May 14, 2009Applicant: Sony CorporationInventors: Akira Yamaguchi, Kunihiko Hayashi, Tadahiko Kubota, Hiroyuki Suzuki, Akira Ichihashi, Yuzuru Fukushima, Hironori Sato, Masaki Kuratsuka, Hideto Watanabe, Kimio Tajima, Masahiro Miyamoto
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Patent number: 7524581Abstract: Electrochemical cells are disclosed. In some embodiments, an electrochemical cell includes a cathode having less than about 2,000 ppm of water, an anode, and an electrolyte having a first lithium salt and LiPF6.Type: GrantFiled: October 19, 2007Date of Patent: April 28, 2009Assignee: The Gillette CompanyInventors: Nikolai N. Issaev, Michael Pozin
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Patent number: 7524588Abstract: A nonaqueous secondary battery includes a negative electrode using a negative electrode active material containing a carbonaceous material; a positive electrode using a positive electrode active material capable of reversibly intercalating and deintercalating lithium; and a nonaqueous electrolyte. The nonaqueous electrolyte contains: (1) a vinyl ethylene carbonate derivative represented by Formula (I): wherein R1 to R6 independently represent a hydrogen atom or an alkyl group having a carbon number of 1 to 4; (2) a cyclic acid anhydride; and (3) at least one cyclic ether derivative selected from the group consisting of 1,3-dioxanes, 1,3-dioxolanes and derivatives thereof.Type: GrantFiled: April 17, 2007Date of Patent: April 28, 2009Assignee: Sanyo Electric C.o., Ltd.Inventor: Kentaro Takahashi
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Patent number: 7510807Abstract: Disclosed is an electrolyte of a lithium secondary battery comprising a lithium salt, an organic solvent, and at least one additive compound selected from the group consisting of compounds represented by the following formula (1) and derivatives thereof: where R1 is selected from the group consisting of hydrogen radicals, alkyls aryls, cycloalkyls, alkenyls, alkynyls, ester radicals, and aliphatic carbonate radicals. The electrolyte improves both swelling inhibition properties at high temperature and capacity characteristics of a lithium secondary battery.Type: GrantFiled: April 28, 2004Date of Patent: March 31, 2009Assignee: Samsung SDI Co., Ltd.Inventor: Hyung-Gon Noh
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Patent number: 7510803Abstract: A battery with a high battery voltage at charging and improved energy density is provided. A cathode (12) and an anode (14) are laminated with a separator (15) sandwiched therebetween which is impregnated with an electrolyte. The cathode (12) has a cathode active material including a lithium composite oxide which contains lithium, at least either cobalt or nickel, and oxygen. The battery voltage at charging is 4.25 V or more. The total amount of lithium carbonate and lithium sulphate in the cathode (12) to the cathode active material is 1.0 wt % or less, a concentration of protic impurities in the electrolyte, which is converted to a mass ratio of protons to the electrolyte, is 20 ppm or less, or moisture content in the electrolyte is 20 ppm mass ratio or less to the electrolyte. This inhibits metal eluting from the lithium composite oxide even at high voltages.Type: GrantFiled: August 23, 2002Date of Patent: March 31, 2009Assignee: Sony CorporationInventors: Momoe Adachi, Shigeru Fujita, Takuya Endo, Yasunobu Iwakoshi, Goro Shibamoto
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Publication number: 20090068565Abstract: The rechargeable lithium battery includes: a negative electrode including a non-carbon-based negative active material; a positive electrode including a positive active material that reversibly intercalates and deintercalates lithium ions; and an electrolyte that includes a non-aqueous organic solvent that includes ethylene carbonate in an amount of 20 volume % or less, a lithium salt including LiPF6, a first additive represented by the following Formula 1 and a second additive that is LiB(C2O4)2. The electrolyte has a viscosity of 3.02 cP or less: wherein, R1 and R2 are independently selected from the group consisting of hydrogen, a halogen, a cyano (CN), a nitro (NO2), and a C1 to C5 fluoroalkyl, provided that at least one of R1 and R2 is selected from the group consisting of a halogen, a cyano (CN), a nitro (NO2), and a C1 to C5 fluoroalkyl.Type: ApplicationFiled: September 11, 2008Publication date: March 12, 2009Applicant: SAMSUNG SDI CO., LTD.Inventor: Doo-Kyoung LEE
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Publication number: 20090068566Abstract: A rechargeable lithium battery including: a negative electrode including lithium-vanadium-based oxide, negative active material; a positive electrode including a positive active material to intercalate and deintercalate lithium ions; and an electrolyte including a non-aqueous organic solvent, and a lithium salt. The lithium salt includes 0.7 to 1.2M of a first lithium salt including LiPF6; and 0.3 to 0.8M of a second lithium salt selected from the group consisting of LiBC2O4F2, LiB(C2O4)2, LiN(SO2C2F5)2, LiN(SO2CF3)2, LiBF4, LiClO4, and combinations thereof.Type: ApplicationFiled: September 11, 2008Publication date: March 12, 2009Applicant: Samsung SDI Co., Ltd.Inventors: Su-Yeong Park, Nam-Soon Choi, Kyoung-Han Yew, Doo-Kyoung Lee, Sung-Soo Kim
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Publication number: 20090068564Abstract: Provided is a method of designing an electrolyte composition including a nonaqueous organic solvent mixture and a lithium salt to obtain an optimal composition ratio of components of the electrolyte composition for a high charging/high-output discharging secondary battery. The method includes: selecting components of the nonaqueous organic solvent mixture; determining composition ratio ranges of the selected components satisfying such conditions that an average dielectric constant, an average viscosity, and an average boiling point satisfy predetermined boundary values; dividing the ranges of the composition ratios into a plurality of groups; selecting a representative composition ratio of each of the groups; adding a lithium salt to a nonaqueous organic solvent mixture having the representative composition ratio to prepare an electrolyte composition; and measuring properties of the electrolyte composition to determine a composition ratio of an electrolyte composition having predetermined properties.Type: ApplicationFiled: February 28, 2008Publication date: March 12, 2009Applicant: Electronics and Telecommunications Research InstituteInventors: Young-Gi Lee, Kwang Man Kim, Mangu Kang, Jongdae Kim
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Patent number: 7491471Abstract: An electrolyte for a lithium secondary battery which has a non-aqueous organic solvent including a ?-butyrolactone and optionally a cyclic carbonate, an ester compound having an electron withdrawing group, and at least two salts. The lithium secondary battery including the electrolyte has good safety and good storage characteristics at high temperature.Type: GrantFiled: July 15, 2004Date of Patent: February 17, 2009Assignee: Samsung SDI Co., Ltd.Inventors: Takitaro Yamaguchi, Ryuichi Shimizu, Hyun-Jei Chung, Cheol-Soo Jung, Hyeong-Gon Noh, Eui-Hwan Song, Joong-Hun Kim
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Publication number: 20090042095Abstract: An active material for a battery includes a mixed phase includes a lithium titanium composite oxide phase and a nonstoichiometric titanium oxide phase. This active material is excellent in lithium absorption/desorption performance, exhibiting high electric potentials in lithium absorption/desorption and high conductivity.Type: ApplicationFiled: March 14, 2008Publication date: February 12, 2009Inventors: Hiroki Inagaki, Norio Takami
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Patent number: 7482098Abstract: A secondary cell employs a nonaqueous electrolyte solution including a nonaqueous solvent and a salt, and a flame retardant material that is liquid at room temperature and pressure and substantially immiscible in the nonaqueous electrolyte solution. The nonaqueous electrolyte solution is formed by dissolving a salt, preferably an alkali metal salt, in a nonaqueous solvent. The nonaqueous solvent preferably includes a cyclic carbonate and/or a linear carbonate. The cyclic carbonate preferably contains an alkylene group with 2 to 5 carbon atoms, and the linear carbonate preferably contains a hydrocarbon group with 1 to 5 carbon atoms. Preferred salts include LiPF6 and LiBF4 at a concentration between about 0.1 and 3.0 moles/liter. The flame retardant material is preferably a halogen-containing compound in an amount by weight of nonaqueous solvent in a range of about 1 to about 99 wt %, and preferred halogen-containing compounds contain perfluoralkyl or perfluorether groups.Type: GrantFiled: December 10, 2002Date of Patent: January 27, 2009Assignee: Quallion LLCInventors: Hisashi Tsukamoto, Tsuneaki Koike
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Patent number: 7482101Abstract: A battery is provided. The battery provides improved battery characteristics such as cycle characteristics. A battery includes a cathode; an anode; and an electrolytic solution, wherein the anode contains a carbon material, the electrolytic solution contains propylene carbonate and 4-fluoroethylene carbonate, and the content of 4-fluoroethylene carbonate is from about 0.0027 g to about 0.056 g per about 1 g of the carbon material.Type: GrantFiled: June 7, 2005Date of Patent: January 27, 2009Assignee: Sony CorporationInventors: Karin Tsuda, Gentaro Kano
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Patent number: 7479348Abstract: Electrochemical cells are disclosed. In some embodiments, an electrochemical cell includes a cathode, an anode, and an electrolyte having a first lithium salt and LiBF4.Type: GrantFiled: April 8, 2005Date of Patent: January 20, 2009Assignee: The Gillette CompanyInventors: Nikolai N. Issaev, Michael Pozin
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Publication number: 20090017386Abstract: Non-aqueous electrolyte solutions capable of protecting negative electrode materials such as lithium metal and carbonaceous materials in energy storage electrochemical cells (e.g., lithium metal batteries, lithium ion batteries and supercapacitors) include an electrolyte salt, a non-aqueous electrolyte solvent mixture, an unsaturated organic compound 4-methylene-1,3-dioxolan-2-one or 4,5-dimethylene-1,3-dioxolan-2-one, and other optional additives. The 1,3-dioxolan-2-ones help to form a good solid electrolyte interface on the negative electrode surface.Type: ApplicationFiled: July 11, 2007Publication date: January 15, 2009Applicant: FERRO CORPORATIONInventors: Wu Xu, Pascal Bolomey, Martin W. Payne
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Publication number: 20090011340Abstract: An organic electrolytic solution comprising a nonaqueous solvent and a lithium salt, wherein the organic electrolytic solution comprises a compound of Formula 1 and at least one selected from compounds of Formulas 2 through 5: wherein R1, a C1˜C10 alkoxy group, wherein R2 and R3 are independently unsubstituted C1˜C5 alkyl group or C1˜C5 alkyl group substituted with halogen atom, wherein n is an integer between 1 and 6.Type: ApplicationFiled: August 8, 2008Publication date: January 8, 2009Applicant: SAMSUNG SDI CO., LTD.Inventors: Doo-yeon Lee, Hyo-sug Lee