Plural Cyclic Carbonate Solvents Patents (Class 429/331)
  • Patent number: 8372547
    Abstract: There is provided a non-aqueous electrolytic solution assuring good solubility of an electrolyte salt and having enough cell characteristics (charge and discharge cycle characteristic, discharge capacity, and the like), and the non-aqueous electrolytic solution comprises a solvent for dissolving an electrolyte salt comprising (A) at least one fluorine-containing solvent selected from the group consisting of fluorine-containing ethers and fluorine-containing carbonates, (B) a non-fluorine-containing cyclic carbonate and (C) a chain ester represented by the formula (C): R1COOR2, wherein R1 is an alkyl group having 2 to 4 carbon atoms; R2 is an alkyl group having 1 to 4 carbon atoms or a fluorine-containing alkyl group having 1 to 4 carbon atoms, and (II) an electrolyte salt.
    Type: Grant
    Filed: July 6, 2009
    Date of Patent: February 12, 2013
    Assignee: Daikin Industries, Ltd.
    Inventors: Meiten Koh, Hitomi Nakazawa, Hideo Sakata, Michiru Kagawa, Akiyoshi Yamauchi
  • Patent number: 8372546
    Abstract: A non-aqueous electrolyte battery includes a positive electrode, a negative electrode and a gel non-aqueous electrolyte, wherein at least one of the positive electrode and the negative electrode has an active material layer containing an ambient temperature molten salt and polyvinylidene fluoride; the ambient temperature molten salt and the polyvinylidene fluoride are complexed; the non-aqueous electrolyte contains one or more kinds of a non-aqueous solvent having a relative dielectric constant of 20 or more; and the content of the solvent having a relative dielectric constant of 20 or more in the non-aqueous electrolyte is 60% by mass or more relative to the whole of the non-aqueous solvent.
    Type: Grant
    Filed: February 5, 2009
    Date of Patent: February 12, 2013
    Assignee: Sony Corporation
    Inventors: Shinya Wakita, Izaya Okae
  • Publication number: 20130029230
    Abstract: An electrolyte for the lithium secondary battery having flame retardancy, low negative electrode interfacial resistance, and excellent high temperature properties and life characteristics, and a lithium secondary battery including the same. An electrolyte for lithium secondary battery of the present invention may include a non-aqueous organic solvent, a lithium salt, fluorinated ether or phosphazene, and a resistance-improving additive represented as the following chemical formula (1): RSO2—R1—SO2F??[Chemical Formula 1] wherein R1 is a C1-C12 hydrocarbon unsubstituted or substituted with at least one fluorine.
    Type: Application
    Filed: October 3, 2011
    Publication date: January 31, 2013
    Applicant: SAMSUNG SDI, CO., LTD.
    Inventors: Sinyoung Park, Yongbeom Lee, Sunyoung Kim, Bora Lee
  • Publication number: 20130029231
    Abstract: A lithium secondary battery has an anode, a cathode, a separator between the anode and the cathode and a non-aqueous electrolyte. The non-aqueous electrolyte includes a lithium salt; and a non-linear carbonate-based mixed organic solvent in which (a) a cyclic carbonate compound, and (b) a propionate-based compound are mixed at a volume ratio (a:b) in the range from about 10:90 to about 70:30. The cathode has a current density in the range from about 3.5 to about 5.5 mA/cm2 and a porosity in the range from about 18 to about 35%. This battery may be manufactured as a high-loading lithium secondary battery.
    Type: Application
    Filed: October 4, 2012
    Publication date: January 31, 2013
    Applicant: LG CHEM, LTD.
    Inventor: LG CHEM, LTD.
  • Publication number: 20130017433
    Abstract: A battery includes a first portion including a substrate having formed thereon a current collector and an anode electrode material. A second portion is formed on a substrate and includes a current collector and a cathode electrode material. The first portion is joined to the second portion and a separator is disposed between the first portion and the second portion as joined to separate the anode electrode material from the cathode electrode material. An electrolyte is placed in contact with the anode electrode material, the cathode electrode material and the separator.
    Type: Application
    Filed: June 20, 2012
    Publication date: January 17, 2013
    Applicant: The Regents of the University of Michigan
    Inventors: Ann M. SASTRY, Fabio ALBANO
  • Publication number: 20130017455
    Abstract: Disclosed is a non-aqueous electrolyte including a non-aqueous solvent, and a solute dissolved in the non-aqueous solvent. The non-aqueous solvent contains ethylene carbonate (EC), propylene carbonate (PC), diethyl carbonate (DEC), and an additive. The weight percentage WEC of EC the total weight of EC, PC, and DEC is more than 20 wt % and equal to or less than 35 wt %; the weight percentage WPC of PC is 20 to 40 wt %; and the weight percentage WDEC of DEC is 30 to 50 wt %. The additive contains a cyclic carbonate having a C?C unsaturated bond, and a sultone compound. The ratio WC/WSL of a weight percentage WC of the cyclic carbonate having a C?C unsaturated bond contained in the non-aqueous electrolyte, to a weight percentage WSL of the sultone compound contained in the non-aqueous electrolyte is 1 to 6.
    Type: Application
    Filed: March 10, 2011
    Publication date: January 17, 2013
    Applicant: PANASONIC CORPORATION
    Inventors: Masaki Deguchi, Shinji Kasamatsu
  • Patent number: 8349500
    Abstract: There are provided a solvent for dissolving an electrolyte salt of lithium secondary battery comprising at least one fluorine-containing solvent (I) selected from the group consisting of a fluorine-containing ether, a fluorine-containing ester and fluorine-containing chain carbonate, 1,2-dialkyl-1,2-difluoroethylene carbonate (II) and other carbonate (III), a non-aqueous electrolytic solution comprising the solvent and an electrolyte salt, and a lithium secondary battery using the non-aqueous electrolytic solution. The solvent for dissolving an electrolyte salt provides a lithium secondary battery being excellent particularly in discharge capacity, rate characteristic and cycle characteristic and has enhanced incombustibility (safety) and the non-aqueous electrolytic solution comprises the solvent and an electrolyte salt.
    Type: Grant
    Filed: January 22, 2009
    Date of Patent: January 8, 2013
    Assignee: Daikin Industries, Ltd.
    Inventors: Meiten Koh, Hideo Sakata, Hitomi Nakazawa, Akiyoshi Yamauchi, Akinori Tani
  • Publication number: 20130004860
    Abstract: A quaternary ammonium salt of the formula (1), a composition containing the quaternary ammonium salt and an organic solvent, and an electrochemical device using the salt wherein R1 and R2 are both methyl and X? is BF4? or N(CF3SO2)2?.
    Type: Application
    Filed: September 13, 2012
    Publication date: January 3, 2013
    Inventors: Tetsuo NISHIDA, Yasutaka Tashiro, Megumi Tornisaki, Masashi Yamamoto, Kazutaka Hirano, Akihiro Nabeshima, Hiroaki Tokuda, Kenji Sato, Takashi Higono
  • Publication number: 20130004859
    Abstract: Disclosed are a nonaqueous electrolyte for a lithium secondary battery containing a hetero polycyclic compound and a lithium secondary battery using the same.
    Type: Application
    Filed: June 29, 2012
    Publication date: January 3, 2013
    Inventors: Sung-Hoon YU, Doo Kyung YANG, Jong-Ho JEON, Min-Jung JOU
  • Publication number: 20120315549
    Abstract: A battery electrolyte solution contains from 0.001 to 20% by weight of certain phosphorus-sulfur compounds. The phosphorus-sulfur compound performs effectively as a solid-electrolyte interphase (SEI) forming material. The phosphorus-sulfur compound has little adverse impact on the electrical properties of the battery, and in some cases actually improves battery performance. Batteries containing the electrolyte solution form robust and stable SEIs even when charged at high rates during initial formation cycles.
    Type: Application
    Filed: November 16, 2009
    Publication date: December 13, 2012
    Inventors: Houxiang Tang, William J. Kruper, JR., Ravi B. Shankar, Deidre A. Strand, Peter M. Margl, Andrew J. Pasztor, JR., David R. Wilson, Jerey R. Stajdi
  • Publication number: 20120282529
    Abstract: A nonaqueous electrolytic solution capable of improving the low-temperature cycle properties, which is a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, wherein the nonaqueous solvent contains at least two cyclic carbonates selected from ethylene carbonate, 1,2-butylene carbonate, a cyclic carbonate having a methyl group at least at 4-position of ethylene carbonate, and a cyclic carbonate having a fluorine atom at least at 4-position of ethylene carbonate, and the content of the cyclic carbonate having a methyl group at least at 4-position of ethylene carbonate and/or the cyclic carbonate having a fluorine atom at least at 4-position of ethylene carbonate is from 1 to 40% by volume of the total volume of the nonaqueous solvent, and which contains trimethylene glycol sulfite in an amount of from 0.1 to 5% by mass, and an electrochemical element using the same.
    Type: Application
    Filed: January 18, 2011
    Publication date: November 8, 2012
    Applicant: UBE INDUSTRIES, LTD.
    Inventors: Koji Abe, Masahide Kondo
  • Publication number: 20120276456
    Abstract: Electrolyte, comprising an aprotic solvent, a lithium salt as conducting salt, and an additive, characterized in that the additive is a compound which contains a protonable nitrogen atom and is hydrolysable by water.
    Type: Application
    Filed: August 27, 2010
    Publication date: November 1, 2012
    Applicant: LI-TEC BATTERY GMBH
    Inventors: Peter Pilgram, Rolf-Walter Terwonne, Denny Thiemig, Joerg Kaiser, Andreas Gutsch
  • Patent number: 8273478
    Abstract: A rechargeable lithium battery includes an electrolyte including an additive such as an ethylene carbonate-based compound represented by Chemical Formula 1 and a silicon-included compound, and a negative electrode including a negative active material including an active element selected from the group consisting of Si, Sn, Ga, Cd, Al, Pb, Zn, Bi, In, Mg, and Ge. In Chemical formula 1, X and Y are independently selected from the group consisting of hydrogen, a halogen, and a C1 through C5 fluoroalkyl, provided that at least one of X and Y is selected from the group consisting of a halogen and a C1 through C5 fluoroalkyl. The rechargeable lithium battery has a suppressed volume expansion characteristic due to a high-capacity negative active material, and has excellent reliability and cycle-life characteristics.
    Type: Grant
    Filed: March 31, 2009
    Date of Patent: September 25, 2012
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Jin-Sung Kim, Na-Rae Park, Su-Hee Han, Jin-Hyunk Lim
  • Patent number: 8263269
    Abstract: The present invention provides a lithium secondary battery which has improved safety, mainly coming from use of an electrolyte solution which is not inflammable at room temperature (20° C.), while not deteriorating output characteristics at low temperatures and room temperature or output maintenance characteristics after storage at high temperature (50° C.). The lithium secondary battery of the present invention, encased in a container, is provided with a cathode and an anode, both capable of storing/releasing lithium ions, a separator which separates these electrodes from each other, and an electrolyte solution containing a cyclic carbonate and a linear carbonate as solvents and a compound such as VC at composition ratios of 18.0 to 30.0%, 74.0 to 81.9% and 0.1 to 1.0%, respectively, based on the whole solvents, all percentages by volume.
    Type: Grant
    Filed: August 3, 2010
    Date of Patent: September 11, 2012
    Assignee: Hitachi Vehicle Energy, Ltd.
    Inventors: Takefumi Okumura, Takahiro Yamaki, Masanori Yoshikawa, Yoshimi Yanai, Toyotaka Yuasa
  • Patent number: 8263268
    Abstract: The present invention includes (1) an ester compound having a specific structure, (2) a nonaqueous electrolytic solution for lithium secondary battery comprising an electrolyte dissolved in a nonaqueous solvent and containing an ester compound having a specific structure in an amount of from 0.01 to 10% by weight of the nonaqueous electrolytic solution, which is excellent in initial battery capacity and cycle property, and (3) a lithium secondary battery comprising a positive electrode, a negative electrode and a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, wherein the nonaqueous electrolytic solution contains an ester compound having a specific structure in an amount of from 0.01 to 10% by weight of the nonaqueous electrolytic solution.
    Type: Grant
    Filed: February 1, 2008
    Date of Patent: September 11, 2012
    Assignee: UBE Industries, Ltd.
    Inventors: Koji Abe, Chisen Hashimoto
  • Patent number: 8263267
    Abstract: A rechargeable battery and associated methods, the rechargeable battery including an anode, a cathode, wherein the cathode includes a ternary cathode-active material, a separator interposed between the cathode and the anode, an electrolyte, and a housing enclosing the electrolyte, the anode, and the cathode, wherein the electrolyte includes a lithium salt, a non-aqueous organic solvent, about 0.5 weight % to about 5 weight % of succinonitrile, and at least one of about 1 weight % to about 10 weight % of halogenated ethylene carbonate and about 1 weight % to about 5 weight % of vinyl ethylene carbonate.
    Type: Grant
    Filed: July 6, 2009
    Date of Patent: September 11, 2012
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Jinhee Kim
  • Publication number: 20120202121
    Abstract: The present invention provides a electrolyte solution, particularly useful for lithium batteries that includes succinonitrile and a co-solvent that has improved conductivity and, in turn, better battery performance.
    Type: Application
    Filed: February 4, 2011
    Publication date: August 9, 2012
    Applicant: Toyota Motor Engin. & Manufact. N.A.(TEMA)
    Inventor: Monique Nathalie RICHARD
  • Publication number: 20120202123
    Abstract: A lithium secondary battery comprises an anode capable of intercalating or disintercalating lithium ions, a cathode configured with a lithium-containing oxide, and a nonaqueous electrolyte solution. The lithium-containing oxide comprises a lithium nickel based oxide. The nonaqueous electrolyte solution comprises vinyl ethylene carbonate (VEC) and a mono-nitrile compound. This lithium secondary battery solves the deterioration of charge/discharge cycle characteristics caused by a lithium nickel based oxide used for a cathode, and also controls the decomposition reaction of electrolyte to solve the swelling phenomenon even though the battery is stored at a high temperature or charged/discharged in a fully-charged state, thereby improving high-temperature life characteristics.
    Type: Application
    Filed: April 29, 2010
    Publication date: August 9, 2012
    Applicant: LG Chem, Ltd.
    Inventors: Jong-Ho Jeon, Soo-Jin Kim, Ho-Chun Lee
  • Publication number: 20120196190
    Abstract: A lithium secondary battery has an anode, a cathode, a separator between the anode and the cathode and a non-aqueous electrolyte. The non-aqueous electrolyte includes a lithium salt; and a non-linear carbonate-based mixed organic solvent in which (a) a cyclic carbonate compound, and (b) a propionate-based compound are mixed at a volume ratio (a:b) in the range from about 10:90 to about 70:30. The cathode has a current density in the range from about 3.5 to about 5.5 mAh/cm2 and a porosity in the range from about 18 to about 35%. This battery may be manufactured as a high-loading lithium secondary battery.
    Type: Application
    Filed: April 13, 2012
    Publication date: August 2, 2012
    Inventors: Jong-Ho JEON, Jeong-Ju Cho, Ho-Chun Lee
  • Publication number: 20120189920
    Abstract: A lithium secondary battery having reduced swelling tendency includes an electrolytic solution. The electrolytic solution includes a lithium salt, a cyclic carbonate, a linear asymmetric carbonate, a third carbonate, a sultone and a phosphazene compound.
    Type: Application
    Filed: January 25, 2011
    Publication date: July 26, 2012
    Applicant: NOVOLYTE TECHNOLOGIES INC.
    Inventors: Wentao Li, Martin W. Payne
  • Publication number: 20120183865
    Abstract: The non-aqueous electrolyte for secondary batteries includes a non-aqueous solvent and a lithium salt dissolved in the non-aqueous solvent. The non-aqueous solvent includes a fluorine-containing cyclic carbonate, propylene carbonate, and diethyl carbonate. The content WFCC of the fluorine-containing cyclic carbonate is 2 to 12 mass %, the content WPC of the propylene carbonate is 40 to 70 mass %, and the content WDEC of the diethyl carbonate is 20 to 50 mass % relative to the total of the non-aqueous solvent. The content of ethylene carbonate in the non-aqueous solvent may be 5 mass % or less.
    Type: Application
    Filed: June 30, 2011
    Publication date: July 19, 2012
    Inventor: Masaki Deguchi
  • Publication number: 20120183864
    Abstract: A non-aqueous electrolytic solution is advantageously used in preparation of a lithium secondary battery excellent in cycle characteristics. In the non-aqueous electrolytic solution for a lithium secondary battery, an electrolyte salt is dissolved in a non-aqueous solvent. The non-aqueous electrolytic solution further contains a vinylene carbonate compound in an amount of 0.01 to 10 wt. %, and an alkyne compound in an amount of 0.01 to 10 wt. %.
    Type: Application
    Filed: March 27, 2012
    Publication date: July 19, 2012
    Applicant: UBE INDUSTRIES, LTD.
    Inventors: Koji ABE, Kazuhiro Miyoshi, Takaaki Kuwata
  • Patent number: 8216726
    Abstract: A battery is provided. The battery includes an electrolytic solution, a positive electrode and a negative electrode. The negative electrode has a negative electrode active material layer containing a carbon material and having a thickness per one face of 70 ?m or more and not more than 120 ?m. The electrolytic solution contains a solvent containing 15% by mass or more and not more than 30% by mass of a cyclic carbonate represented by the following formula (1): wherein R1 to R4 each independently represents hydrogen, a halogen, an alkyl group or a halogenated alkyl group. A mass content ratio (B/A) of a halogenated cyclic carbonate (B % by mass) contained in the cyclic carbonate (A % by mass) which is represented by the formula (1) being from 0.5 to 1.0.
    Type: Grant
    Filed: December 9, 2008
    Date of Patent: July 10, 2012
    Assignee: Sony Corporation
    Inventors: Shinya Wakita, Izaya Okae
  • Publication number: 20120171579
    Abstract: A non-aqueous electrolyte including a lithium salt, an organic solvent, and an electrolyte additive is provided. The electrolyte additive is a meta-stable state nitrogen-containing polymer formed by reacting Compound (A) and Compound (B). Compound (A) is a monomer having a reactive terminal functional group. Compound (B) is a heterocyclic amino aromatic derivative as an initiator. A molar ratio of Compound (A) to Compound (B) is from 10:1 to 1:10. A lithium secondary battery containing the non-aqueous electrolyte is further provided. The non-aqueous electrolyte of this disclosure has a higher decomposition voltage than a conventional non-aqueous electrolyte, such that the safety of the battery during overcharge or at high temperature caused by short-circuit current is improved.
    Type: Application
    Filed: December 29, 2011
    Publication date: July 5, 2012
    Applicant: Industrial Technology Research Institute
    Inventors: Li-Duan Tsai, Yueh-Wei Lin, Chia-Chen Fang, Cheng-Liang Cheng, Jing-Pin Pan, Tsung-Hsiung Wang
  • Publication number: 20120171577
    Abstract: An electrolytic solution including: a magnesium salt; a non-aqueous organic solvent; and an anion receptor, wherein the anion receptor comprises at least one compound selected from the group consisting of compounds represented by Formulae 1 and 2 below: where A, m, p1, P2, P3, q1, RA, Ra, R1 through R6, and Ry are the same as described in the detailed description section.
    Type: Application
    Filed: June 10, 2011
    Publication date: July 5, 2012
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Young-gyoon Ryu, Sang-ho Park, Myung-dong Cho, Young-min Choi, Seok-soo Lee
  • Publication number: 20120171576
    Abstract: A non-aqueous electrolyte including a lithium salt, an organic solvent, and an electrolyte additive is provided. The electrolyte additive is a meta-stable state nitrogen-containing polymer formed by reacting Compound (A) and Compound (B). Compound (A) is a monomer having a reactive terminal functional group. Compound (B) is a heterocyclic amino aromatic derivative as an initiator. A molar ratio of Compound (A) to Compound (B) is from 10:1 to 1:10. A lithium secondary battery containing the non-aqueous electrolyte is further provided. The non-aqueous electrolyte of this disclosure has a higher decomposition voltage than a conventional non-aqueous electrolyte, such that the safety of the battery during overcharge or at high temperature caused by short-circuit current is improved.
    Type: Application
    Filed: May 19, 2011
    Publication date: July 5, 2012
    Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Li-Duan Tsai, Yueh-Wei Lin, Jason Fang, Cheng-Liang Cheng, Jing-Pin Pan, Tsung-Hsiung Wang
  • Publication number: 20120171578
    Abstract: The battery includes an electrolyte activating one or more cathodes and one or more anodes. The electrolyte includes one or more salts in a solvent. The solvent includes one or more organic solvents and one or more silanes and/or one or more siloxanes.
    Type: Application
    Filed: March 22, 2007
    Publication date: July 5, 2012
    Inventors: Zhengcheng Zhang, Phuong-Nghi Karen Lam, Mikito Nagata, Hisashi Tsukamoto
  • Publication number: 20120140378
    Abstract: A rechargeable energy storage device is disclosed. In at least one embodiment the energy storage device includes an air electrode providing an electrochemical process comprising reduction and evolution of oxygen and a capacitive electrode enables an electrode process consisting of non-faradic reactions based on ion absorption/desorption and/or faradic reactions. This rechargeable energy storage device is a hybrid system of fuel cells and ultracapacitors, pseudocapacitors, and/or secondary batteries.
    Type: Application
    Filed: December 3, 2010
    Publication date: June 7, 2012
    Applicant: IMRA AMERICA, INC.
    Inventors: Bing TAN, Zhendong Hu, Yong Che
  • Publication number: 20120141883
    Abstract: The invention discloses various embodiments of electrolytes for use in lithium-ion batteries, the electrolytes having improved safety and the ability to operate with high capacity anodes and high voltage cathodes. In one embodiment there is provided an electrolyte for use in a lithium-ion battery comprising an anode and a high voltage cathode. The electrolyte has a mixture of a cyclic carbonate of ethylene carbonate (EC) or mono-fluoroethylene carbonate (FEC) co-solvent, ethyl methyl carbonate (EMC), a flame retardant additive, a lithium salt, and an electrolyte additive that improves compatibility and performance of the lithium-ion battery with a high voltage cathode. The lithium-ion battery is charged to a voltage in a range of from about 2.0 V (Volts) to about 5.0 V (Volts).
    Type: Application
    Filed: February 14, 2012
    Publication date: June 7, 2012
    Applicants: University of Southern California, California Institute of Technology
    Inventors: Marshall C. Smart, Ratnakuma V. Bugga, Surya G. Prakash, Frederick C. Krause
  • Publication number: 20120135314
    Abstract: Provided are an electrolyte additive represented by the following formula (1), an electrolyte solution containing the electrolyte additive, and a lithium secondary battery including the electrolyte solution: The electrolyte solution containing the electrolyte additive can enhance the normal-temperature and high-temperature lifetime characteristics of the battery to be equivalent or superior to the characteristics of conventional batteries, and can extend the service life of the battery.
    Type: Application
    Filed: November 28, 2011
    Publication date: May 31, 2012
    Applicant: SOULBRAIN CO., LTD
    Inventors: Eun Gi SHIM, Ji Seong Han, Ji Young Choi, Soo Young Kim, Hyeong Kyu Lim
  • Patent number: 8187744
    Abstract: A non-aqueous electrolyte secondary battery is produced using a non-aqueous electrolyte including: a non-aqueous solvent that primarily contains a solvent mixture of ethylene carbonate and propylene carbonate and includes a fluorine-substituted ether having a divalent group represented by a formula: —CFX—CH(CH3)—O—, where X is a hydrogen atom or fluorine atom, in a molecule thereof; and a lithium salt that is dissolved in the non-aqueous solvent. The non-aqueous electrolyte has favorable wettability towards a polyolefin separator, and improves the cycle characteristics and the load characteristics of the non-aqueous electrolyte secondary battery.
    Type: Grant
    Filed: June 23, 2009
    Date of Patent: May 29, 2012
    Assignee: Panasonic Corporation
    Inventors: Tooru Matsui, Tetsuo Nanno, Hiroshi Yoshizawa
  • Patent number: 8178246
    Abstract: The present invention provides a nonaqueous electrolytic solution which can give excellent cycle characteristics. The nonaqueous electrolytic solution contains a linear carbonate represented by the formula (1): wherein, in the formula (1), Xa represents each independently hydrogen or any group; Ra represents optionally substituted alkyl; and n represents an integer of zero or more.
    Type: Grant
    Filed: June 9, 2006
    Date of Patent: May 15, 2012
    Assignee: Mitsubishi Chemical Corporation
    Inventor: Noriko Shima
  • Publication number: 20120115042
    Abstract: Nonaqueous electrolytes which can produce a battery of high capacity and excellent storability and cycle characteristics are provided, as are batteries produced with the electrolytes. The electrolytes include ones with (i) an aromatic compound having 7-18 carbon atoms in total and a fluorinated cyclic carbonate having two or more fluorine atoms, (ii) diethyl carbonate and a fluorinated cyclic carbonate having two or more fluorine atoms, (iii) at least one of a cyclic sulfonic acid ester compound, disulfonic acid ester compound, nitrile compound, and a compound of formula (1) and a fluorinated cyclic carbonate having two or more fluorine atoms, or (iv) a nonaqueous electrolyte solution for use in a high-voltage battery having a final charge voltage of 4.3 V or higher and having a fluorinated cyclic carbonate with two or more fluorine atoms.
    Type: Application
    Filed: January 19, 2012
    Publication date: May 10, 2012
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Minoru KOTATO, Shinichi Kinoshita
  • Publication number: 20120115041
    Abstract: One example of the disiloxanes include a backbone with a first silicon and a second silicon. The first silicon is linked to a first substituent selected from a group consisting of: a first side chain that includes a cyclic carbonate moiety; a first side chain that includes a poly(alkylene oxide) moiety; and a first cross link links the disiloxane to a second siloxane and that includes a poly(alkylene oxide) moiety. In some instance, the second silicon is linked to a second substituent selected from a group consisting of: a second side chain that includes a cyclic carbonate moiety, and a second side chain that includes a poly(alkylene oxide) moiety.
    Type: Application
    Filed: December 12, 2011
    Publication date: May 10, 2012
    Inventors: Robert C. West, Khalil Amine, Zhengcheng Zhang, Qingzheng Wang, Nicholas Agostino Antonio Rossi, Donald R. Vissers
  • Patent number: 8173298
    Abstract: An electrolyte for a lithium battery includes a non-aqueous organic solvent, a lithium salt, and an additive comprising a) a compound represented by the following Formula (1), and b) a compound selected from the group consisting of a sulfone-based compound, a poly(ester)(metha)acrylate, a polymer of poly(ester)(metha)acrylate, and a mixture thereof: wherein R1 is a C1 to C10 alkyl, a C1 to C10 alkoxy, or a C6 to C10 aryl, and preferably a methyl, ethyl, or methoxy, X is a halogen, and m and n are integers ranging from 1 to 5, where m+n is less than or equal to 6.
    Type: Grant
    Filed: February 23, 2011
    Date of Patent: May 8, 2012
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Jun-Ho Kim, Ha-Young Lee, Sang-Hoon Choy, Ho-Sung Kim, Hyeong-Gon Noh
  • Patent number: 8173299
    Abstract: An anode capable of relaxing the stress concentration and improving the characteristics and a battery using it are provided. The anode includes an anode current collector and an anode active material layer containing silicon (Si) as an element, wherein the anode active material layer has a metal element increasing and decreasing region in which a metal element is contained as an element, and a concentration of the metal element is increased and then decreased in a thickness direction.
    Type: Grant
    Filed: March 1, 2011
    Date of Patent: May 8, 2012
    Assignee: Sony Corporation
    Inventors: Takakazu Hirose, Masayuki Iwama, Koichi Matsumoto, Isamu Konishiike, Kenichi Kawase
  • Publication number: 20120100434
    Abstract: The invention related to a liquid electrolyte for a lithium battery comprising a lithium salt dissolved in a mixture of three non-aqueous organic solvents. This mixture consists of: 33% to 49 volume % of propylene carbonate, 33% to 49 volume % of diethyl carbonate, and 2% to 34 volume % of ethyl acetate. The liquid electrolyte is in particular suitable for a lithium battery based on the LiFePO4/Li4Ti5O-12 pair or derivatives thereof, these materials being the respective active materials of the positive and negative electrodes. Such a lithium battery in fact has the advantage of operating in power, over a wide temperature range, while at the same time preserving a low self-discharge capacity.
    Type: Application
    Filed: July 1, 2010
    Publication date: April 26, 2012
    Applicant: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Severine Jouanneau-Si Larbi, Lise Daniel, Florence Masse
  • Patent number: 8163427
    Abstract: A non-aqueous electrolytic solution is advantageously used in preparation of a lithium secondary battery excellent in cycle characteristics. In the non-aqueous electrolytic solution for a lithium secondary battery, an electrolyte salt is dissolved in a non-aqueous solvent. The non-aqueous electrolytic solution further contains a vinylene carbonate compound in an amount of 0.01 to 10 wt. %, and an alkyne compound in an amount of 0.01 to 10 wt. %.
    Type: Grant
    Filed: July 16, 2004
    Date of Patent: April 24, 2012
    Assignee: Ube Industries, Ltd.
    Inventors: Koji Abe, Kazuhiro Miyoshi, Takaaki Kuwata
  • Patent number: 8163422
    Abstract: There is provided an electrochemical device provided with an electrolytic solution comprising (I) a solvent for dissolving an electrolyte salt comprising (A) a fluorine-containing ether represented by the formula (1): Rf1—O—Rf2 wherein Rf1 and Rf2 are the same or different and each is a fluorine-containing alkyl group having 3 to 6 carbon atoms, (B) a cyclic carbonate, and (C) a chain carbonate being compatible with both of the fluorine-containing ether (A) and the cyclic carbonate (B), and (II) an electrolyte salt, in which the solvent (I) for dissolving an electrolyte salt comprises 30 to 60% by volume of the fluorine-containing ether (A), 3 to 40% by volume of the cyclic carbonate (B) and 10 to 67% by volume of the chain carbonate (C) based on the whole solvent (I), and when the electrochemical device is provided with such an electrolytic solution, no phase separation occurs even at low temperature, flame retardancy and heat resistance are excellent, solubility of an electrolyte salt is high, discharge
    Type: Grant
    Filed: July 12, 2007
    Date of Patent: April 24, 2012
    Assignee: Daikin Industries, Ltd.
    Inventors: Meiten Koh, Hideo Sakata, Hitomi Nakazawa, Michiru Tanaka, Akiyoshi Yamauchi
  • Publication number: 20120094191
    Abstract: Provided is a lithium secondary battery comprising an anode, a cathode and a non-aqueous electrolyte, wherein the anode includes an aqueous binder, and the non-aqueous electrolyte contains (a) a cyclic anhydride or a derivative thereof; and (b) any one anion receptor selected from the group consisting of a borane compound, a borate compound and mixtures thereof. According to the present invention, a stable SEI film is formed on the anode, and the life characteristics of the battery are improved by controlling the LiF content in the SEI film.
    Type: Application
    Filed: February 26, 2010
    Publication date: April 19, 2012
    Applicant: LG CHEM, LTD.
    Inventors: Su-Jin Yoon, Sung-Hoon Yu, Jong-Ho Jeon
  • Patent number: 8148017
    Abstract: An electrochemical energy storage device includes a negative electrode which contains a carbon material and has a negative electrode potential of 1.4 V or less relative to a lithium reference when being charged, and a non-aqueous electrolyte solution prepared by dissolving a lithium salt, an ammonium salt, and at least one kind of fluorinated benzene selected among hexafluorobenzene, pentafluorobenzene, 1,2,3,4-tetrafluorobenzene, 1,2,3,5-tetrafluorobenzene, 1,2,4,5-tetrafluorobenzene and 1,2,3-trifluorobenzene, in a non-aqueous solvent.
    Type: Grant
    Filed: March 1, 2007
    Date of Patent: April 3, 2012
    Assignee: Panasonic Corporation
    Inventors: Tooru Matsui, Masaki Deguchi, Hiroshi Yoshizawa
  • Patent number: 8148007
    Abstract: An organic electrolyte solution includes a lithium salt; an organic solvent including a high permittivity solvent and a low boiling solvent; and a vinyl-based compound represented by Formula 1 below, wherein m and n are each independently integers of 1 to 10; X1, X2, and X3 each independently represent O, S, or NR9; and R1, R2, R3, R4, R5, R6, R7, R8, and R9 are represented in the detailed description. The organic electrolyte solution of the present invention and a lithium battery using the same suppress degradation of an electrolyte, providing improved cycle properties and life span thereof.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: April 3, 2012
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Seok-soo Lee, Young-gyonn Ryu, Seung-sik Hwang, Dong-joon Lee, Boris A. Trofimov
  • Publication number: 20120064414
    Abstract: A process for producing a solvent mixture comprising (A) at least one compound of formula (I) (B) at least one compound of formula (II a) or (II b) (C) optionally at least one additive selected from aromatic compounds, sultones and exo-methylene ethylene carbonates, melamine, urea, organic phosphates and halogenated organic carbonates, (D) optionally at least one lithium salt, and from 3 to 30 weight ppm of water, which process comprises (a) components (A), (B) and, if used, (C) being mixed with one another, (b) dried over at least one ion exchanger or molecular sieve, (c) separated from ion exchanger or, respectively, molecular sieve, and (d) at least one lithium salt, if used, being added, where the variables are defined as follows: R1, R2 are each the same or different and selected from C1-C4-alkyl, R3 is selected from hydrogen and C1-C4-alkyl.
    Type: Application
    Filed: September 7, 2011
    Publication date: March 15, 2012
    Applicant: BASF SE
    Inventors: Klaus Leitner, Itamar Michael Malkowsky, Florian Stecker, Wunibald Kippenberger, Markus Hummelsberger, Christian Seitz, Mariella Schütz, Carsten Süling
  • Publication number: 20120064390
    Abstract: Electrolytes of lithium ion batteries of the present disclosure comprise: a lithium salt, a non-aqueous solvent, and an additive. The additive further comprises a first and second compound. The first compound is a 4 X1, 5 R1 [1,3]dioxolan-2-one, wherein X1 is selected from the group consisting of: F, Cl, and Br and R1 is selected from the group consisting of hydrogen and linear alkyl compounds having between 1 and 3 carbon atoms. The second compound has a molecular formula of: F(CF2CF2)x—CH2CH2—(CH2CH2O)yH, wherein x is any integer ranging from 1 to 7, and y is any integer ranging from 1 to 15.
    Type: Application
    Filed: September 9, 2011
    Publication date: March 15, 2012
    Inventors: Huiying Wang, Guishu Zhou
  • Patent number: 8133619
    Abstract: A nonaqueous electrolyte battery includes a negative electrode including a current collector and a negative electrode active material having a Li ion insertion potential not lower than 0.4V (vs. Li/Li+). The negative electrode has a porous structure. A pore diameter distribution of the negative electrode as determined by a mercury porosimetry, which includes a first peak having a mode diameter of 0.01 to 0.2 ?m, and a second peak having a mode diameter of 0.003 to 0.02 ?m. A volume of pores having a diameter of 0.01 to 0.2 ?m as determined by the mercury porosimetry is 0.05 to 0.5 mL per gram of the negative electrode excluding the weight of the current collector. A volume of pores having a diameter of 0.003 to 0.02 ?m as determined by the mercury porosimetry is 0.0001 to 0.02 mL per gram of the negative electrode excluding the weight of the current collector.
    Type: Grant
    Filed: June 2, 2011
    Date of Patent: March 13, 2012
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hiroki Inagaki, Norio Takami
  • Publication number: 20120045698
    Abstract: A non-aqueous liquid electrolyte to be used for a non-aqueous liquid electrolyte secondary battery containing a anode electrode and a cathode electrode, capable of intercalating and deintercalating lithium ions, and the non-aqueous liquid electrolyte. In the non-aqueous liquid electrode, the anode electrode contains an anode electrode active material having at least one kind of atom selected from the group consisting of Si atom, Sn atom and Pb atom. The non-aqueous liquid electrolyte also contains a carbonate having at least either an unsaturated bond or a halogen atom, and also contains a compound represented by formula (III-1) as defined herein.
    Type: Application
    Filed: October 31, 2011
    Publication date: February 23, 2012
    Applicant: Mitsubishi Chemical Corporation
    Inventor: Noriko SHIMA
  • Publication number: 20120040252
    Abstract: A non-aqueous liquid electrolyte to be used for a non-aqueous liquid electrolyte secondary battery containing a anode electrode and a cathode electrode, capable of intercalating and deintercalating lithium ions, and the non-aqueous liquid electrolyte. In the non-aqueous liquid electrode, the anode electrode contains an anode electrode active material having at least one kind of atom selected from the group consisting of Si atom, Sn atom and Pb atom. The non-aqueous liquid electrolyte also contains a carbonate having at least either an unsaturated bond or a halogen atom, and also contains a compound represented by formula (I) as defined herein and a saturated cyclic carbonate compound as defined herein.
    Type: Application
    Filed: October 24, 2011
    Publication date: February 16, 2012
    Applicant: Mitsubishi Chemical Corporation
    Inventor: Noriko SHIMA
  • Publication number: 20120034532
    Abstract: A non-aqueous electrolyte solution for a lithium secondary battery comprises a lithium salt and an organic solvent. The non-aqueous electrolyte solution further comprises a specific siloxane compound and a sulfonate compound. This non-aqueous electrolyte solution solves the capacity degradation phenomenon, which appears in a lithium secondary battery using a non-aqueous electrolyte solution containing only a specific siloxane compound when the lithium secondary battery is used for a long time, so this non-aqueous electrolyte solution is especially useful for high-capacity batteries.
    Type: Application
    Filed: April 29, 2010
    Publication date: February 9, 2012
    Applicant: LG Chem, Ltd.
    Inventors: Soo-Jin Kim, Jeong-Ju Cho, Su-Jin Yoon, Yong-Joon Ha, Chul-Haeng Lee, Jeong-Hwan Koh
  • Publication number: 20120034533
    Abstract: Disclosed is a non-aqueous electrolyte solution for a lithium secondary battery. The non-aqueous electrolyte solution includes a lithium salt, an organic solvent and additives. The additives include: 1 to 10% by weight of a mixture of a particular halogenated cyclic carbonate and a compound containing a vinylene or vinyl group; and 0.1 to 9% by weight of a nitrile compound having a C2-C12 alkoxyalkyl group. A lithium secondary battery including the non-aqueous electrolyte solution is also disclosed. The lithium secondary battery is protected from catching fire when overcharged and is prevented from swelling during storage at high temperature.
    Type: Application
    Filed: July 9, 2010
    Publication date: February 9, 2012
    Applicant: LG CHEM, LTD.
    Inventors: Yeon-Suk Hong, Jae-Seung Oh, Ji-Won Park, Byoung-Bae Lee, Dong-Su Kim, Hyo-Jin Lee
  • Publication number: 20120015256
    Abstract: Disclosed is a sodium-ion secondary battery having excellent charge and discharge efficiencies as well as excellent charge and discharge characteristics, wherein charging and discharging can be repeated without causing problems such as deterioration in battery performance. Specifically disclosed is a sodium ion secondary battery which is provided with a positive electrode, a negative electrode having a negative electrode active material, and a nonaqueous electrolyte solution containing a nonaqueous solvent. The nonaqueous solvent is substantially composed of a saturated cyclic carbonate (excluding the use of ethylene carbonate by itself), or a mixed solvent of a saturated cyclic carbonate and a chain carbonate, and a hard carbon is used as the negative electrode active material.
    Type: Application
    Filed: March 25, 2010
    Publication date: January 19, 2012
    Applicant: Tokyo University of Science Educational Foundation Administrative Organization
    Inventors: Shinichi Komaba, Tomoaki Ozeki, Wataru Murata, Toru Ishikawa