Abstract: A toner, has a number mode diameter of 3 ?m or more and 6 ?m or lower and a particle size distribution of a toner including an externally-applied agent in the range of 0.6 ?m to 400 ?m in which the number frequency of a toner smaller than the number mode diameter is smaller than the number frequency of a toner equal to or larger than the number mode diameter.
Type:
Grant
Filed:
April 12, 2010
Date of Patent:
August 28, 2012
Assignee:
Seiko Epson Corporation
Inventors:
Soichi Yamazaki, Takatomo Fukumoto, Hideki Okada, Toshikazu Ono
Abstract: The present invention provides a toner containing at least two binder resins composed of at least a resin A and a resin B which are incompatible with each other, and a colorant, wherein the toner has an average circularity of 0.93 to 0.98 and is produced by atomizing a toner composition liquid in a vapor phase to form liquid droplets and solidifying the liquid droplets, and the toner composition liquid is prepared by dissolving or dispersing the at least two binder resins and the colorant in an organic solvent.
Abstract: There is provided a method of manufacturing coalesced resin particles for obtaining coalesced resin particles by coalescing aggregated resin particles in a grain boundary-free state in a short period of time while keeping a grain size distribution within a narrow range. In a coalescence process, a slurry of aggregated resin particles is flowed through an inside of a pipe under predetermined heating and pressurizing conditions. In a before-cooling decompression process, a slurry of coalesced resin particles flowing through the inside of the pipe in a heat and pressure-applied state is subjected to pressure reduction before it is cooled down to a predetermined temperature in a cooling process. Then, in a decompression process, a coalesced resin particle slurry that has been cooled in the cooling process while being flowed through the inside of the pipe is decompressed to an atmospheric pressure.
Abstract: A process for making a latex emulsion suitable for use in a toner composition includes contacting at least one crystalline polyester resin with an organic solvent and a stabilizing agent to form a resin mixture, adding a neutralizing agent, and deionized water to the resin mixture, removing the solvent from the formed latex, and continuously recovering latex particles.
Type:
Grant
Filed:
September 9, 2010
Date of Patent:
August 21, 2012
Assignee:
Xerox Corporation
Inventors:
Valerie M. Farrugia, Kimberly D. Nosella, Rosa M. Duque
Abstract: An object of the present invention is to provide a resin microparticle for a toner raw material that has a small particle diameter and a narrow particle diameter distribution and has a low odor. There are provided a resin microparticle for a toner raw material characterized in that all of the following requirements (i) to (iii) are satisfied: Requirement (i): A particle diameter of 50% volume (D50) satisfies the relationship 0.05 ?m?D50?1 ?m; Requirement (ii): A particle diameter of 10% volume (D10) and a particle diameter of 90% volume (D90) satisfy the relationship D90/D10?7; and Requirement (iii): The content of an organic solvent is not more than 70 ppm.
Abstract: The present invention is to provide a method for producing a toner capable of sufficiently decreasing the percentage of moisture content of a wet cake in the process of obtaining colored resin particles in wet state (wet cake), capable of reducing the workload in the following drying process, and thus excellent in productivity.
Type:
Grant
Filed:
October 1, 2009
Date of Patent:
August 21, 2012
Assignee:
Zeon Corporation
Inventors:
Hisashi Kurokawa, Rei Katsuyama, Fuminari Oyama, Hiroto Kidokoro
Abstract: The present disclosure provides processes for increasing the shelf life and stability of resin emulsions suitable for use in forming toner particles. In embodiments, the pH of the resin emulsion is monitored, and a base is added as needed to maintain the pH of the emulsion at from about 6.5 to about 8. Maintaining the pH at from about 6.5 to about 8 prevents the degradation of the resin in the emulsion, including its molecular weight.
Type:
Grant
Filed:
December 9, 2008
Date of Patent:
August 21, 2012
Assignee:
Xerox Corporation
Inventors:
Kimberly D. Nosella, Enno E. Agur, Shigang Qiu, Ke Zhou
Abstract: The present invention provides a process for producing a colored toner comprising the steps of: providing a polymer composition comprising at least one polymer wherein the at least one polymer has a softening temperature from about 30° C. to about 160° C.; and a colorant; forming an aqueous mineral suspension of at least one multivalent metal phosphate by contacting a water-soluble salt of the multivalent metal with an aqueous solution comprising: a water-soluble phosphate salt; and at least one crystal growth inhibitor which controls the growth of the at least one multivalent metal phosphate, wherein the pH of the aqueous mineral suspension is from 5.5 to 14; and forming a dispersion of the polymer composition by adding the polymer composition to the aqueous mineral suspension under agitation to form a solid portion comprising dispersed particles of the polymer composition, wherein the temperature of the aqueous mineral suspension during the dispersing step is at least about 70° C.
Type:
Grant
Filed:
January 15, 2009
Date of Patent:
August 21, 2012
Assignee:
Penn Color, Inc.
Inventors:
Choung Lai, Ronald W. Schuck, Charles B. Rybny
Abstract: A carrier core material for electrophotographic developer containing a soft ferrite, expressed by (MgXMn1-x)Fe2O4 (wherein X is in a range of 0.1?X<1.), wherein an analysis value of P on the surface of the carrier core material is 0.1 mass % or more, an analysis value of Mg is 2 mass % or more, a content of Mg in the carrier core material is 2 mass % or more by EDS, and when the content of Mg in the carrier core material is expressed by M1, and the analysis value of Mg on the surface of the carrier core material by EDS is expressed by M2, a value of M2/M1 exceeds 1.0.
Abstract: The present invention is a method of manufacturing porous polymer particles comprising: forming a dispersion of porous polymer particles in an external aqueous phase, wherein individual porous particles each comprise a continuous polymer phase and internal pores containing an internal aqueous phase; and filtering the dispersion of porous polymer particles with a filter to remove the external aqueous phase, wherein the filtering is done while agitating the porous particles.
Abstract: A method for manufacturing a resin-layer coated toner is provided. The method for manufacturing the resin-layer coated toner uses a rotary stirring apparatus including a circulating section, a temperature regulation section, a spraying section and an exhausting section, sprays a liquid substance to particles of toner materials and particles of coating materials in a fluidized state to plasticize such particles from a spraying section by carrier gas and gasifies the liquid, circulates the carrier gas in the powder passage and continuously exhausts the carrier gas including the gasified substance through the exhausting section to the outside of the powder passage, and pressure P1 in the powder passage and pressure P0 outside the powder passage satisfy the following formula (1): 0 atm<(Pressure P1 in the powder passage?Pressure P0 outside the powder passage)?0.3 atm??(1).
Abstract: A method for manufacturing a toner is provided. The method for manufacturing a toner uses a rotary stirring apparatus. The rotary stirring apparatus includes at least a circulation section, a temperature regulation section and a spraying section composed of a two-fluid nozzle. The two-fluid nozzle includes a liquid pipe and an air pipe, the liquid pipe is inserted in the air pipe such that an axis of the liquid pipe coincides with an axis of the air pipe, and at least a part of the liquid pipe and the air pipe is fixed such that the centers of those pipes do not move. A substance in liquid form is sprayed in constant rate from the two-fluid nozzle while regulating temperature and circulating the toner base particles and the fine resin particles in a powder passage, thereby forming a film on the surface of the toner base particle.
Abstract: A black toner composition comprising toner particles prepared by a chemical process of manufacture comprising carbon black pigment, a first addition polymer comprising carboxylic acid groups along the polymer backbone, and a thermoplastic second polymer binder distinct from the first polymer, wherein the first polymer has an Acid Value of from 30 to 220 and is present at a weight ratio of greater than 1:2 relative to the amount of carbon, and at a relatively lower weight percent than the second polymer.
Abstract: A toner for electrophotography includes toner particles containing at least a binder resin and a colorant, to which strontium titanate and hydrophobic silica as external additives are admixed, wherein the strontium titanate has a BET specific surface area of 20-50 m2/g and contains particles in a rectangular parallelepiped shape and wherein the hydrophobic silica contains hydrophobic silica A that has at least a BET specific surface area of 150-300 m2/g and the surface of which has been treated with an aminosilane and hexamethyldisilazane and hydrophobic silica B that has at least a BET specific surface area of 90-150 m2/g and the surface of which has been treated with hexamethyldisilazane.
Type:
Grant
Filed:
September 3, 2008
Date of Patent:
July 31, 2012
Assignee:
Tomoegawa Co., Ltd.
Inventors:
Tohru Moriya, Hitoshi Onoda, Kazuyoshi Hattori, Yoshihito Suwa
Abstract: The present disclosure provides processes for the production of block copolymer polyester resins suitable for use in manufacturing toners. In embodiments, the copolymers include both a crystalline block and an amorphous block, which can self-assemble to form nanoparticles suitable for use in forming toners.
Abstract: The method for producing a developing agent according to the invention contains subjecting the toner material dispersion liquid to mechanical shearing to make the granular mixture into fine particles, thereby providing a dispersion liquid containing fine particles having a smaller particle diameter than a particle diameter of the granular mixture. The toner material dispersion liquid is subjected to mechanical shearing under a temperature of a glass transition point Tg of the binder resin or more and a pressure of 10 MPa or more, and the resulting dispersion liquid containing the fine particles is depressurized with two or more stages while maintaining the temperature of a glass transition point Tg of the binder resin or more and then cooled to a temperature of a glass transition point Tg of the binder resin or less.
Abstract: The present disclosure provides toner particles having excellent charge characteristics. In embodiments, a toner particle of the present disclosure includes a cation binding material possessing cation binding groups. Processes for producing toners with these cation binding materials are also provided. The resulting toners exhibit excellent stability with respect to relative humidity and excellent charging characteristics.
Type:
Grant
Filed:
February 24, 2011
Date of Patent:
July 24, 2012
Assignee:
Xerox Corporation
Inventors:
Richard P. N. Veregin, Daryl W. Vanbesien, Cuong Vong
Abstract: A method of charging toner particles in a liquid toner includes mixing the toner with an acid, and mixing the toner with a base that reacts with the acid to charge the toner particles. The base is added first and the acid subsequently to charge the toner particles with a positive charge.
Type:
Grant
Filed:
July 8, 2011
Date of Patent:
July 17, 2012
Assignee:
Hewlett-Packard Development Company, L.P.
Inventors:
Yaacov Almog, Avi Koller, Ilya Taraniuk
Abstract: There is provided a method for producing resinous particles, containing: melting a mixture containing a binder resin and at least one additive having a melting point lower than T1/2 of the binder resin so as to prepare a molten material; atomizing resinous particles from the molten material in an atmosphere having a temperature higher than Tg of the binder resin and lower than 3 times of T1/2 of the binder resin; retaining the resinous particles in an atmosphere having a temperature higher than Tg of the binder resin, and lower than 1.5 times of T1/2 of the binder resin for 1 s to 15 s; and cooling and solidifying the resinous particles.
Abstract: Disclosed is a method for producing a polymerized toner. In the method, a mixture of colloidal silica as an aqueous dispersant and a polyvinylpyrrolidone is used during suspension polymerization. The amount of polyvinylpyrrolidone/colloidal silica aggregates having a diameter smaller than 100 nm is also limited to 1% by weight or less, based on the total weight of all aggregates. A polymerized toner produced by the method has a volume average particle diameter (dv) of 5 to 10 ?m and a volume average particle diameter/number average particle diameter ratio (dv/dp) of 1.5 or less. The polymerized toner is consumed in a small amount during printing. According to the method, the formation of emulsion particles having a size smaller than 0.5 ?m is inhibited.
Type:
Grant
Filed:
October 8, 2008
Date of Patent:
July 10, 2012
Assignee:
LG Chem, Ltd.
Inventors:
Wook Jang, Chang Soon Lee, Woo Cheul Jeong, Ji Hoon Lee
Abstract: Toner characterized in that assuming that the glass transition point of the toner measured by a differential scanning calorimeter (DSC) is represented by T1(° C.), in a micro compression test at T1?10 (° C.), when a load from 0.00N (0.00 mgf) to 7.85×10?4 N (80.00 mgf) is applied at the intervals of 7.85×10?7 N (0.08 mgf) to a single particle of the toner, the strain value A80a(%) at 7.85×10?4 N is 35.0 to 75.0%; and in a load (x-axis)-strain (y-axis) curve obtained by the micro compression test, the ratio of an area (S1a) of a specific region, relative to an area (S2a) of a specific region, (S1a/S2a), is 1.5 to 3.5.
Abstract: The invention relates to a coloured polymer dispersion containing, as main ingredients: (a) a coloured polymer produced by polymerisation of monomer A with monomer B, monomer A being a pigment B which is coated with a polymerisable wax D wherein the polymerisable function is an ethylenically unsaturated group, monomer B being a ethylenically unsaturated compound; (b) at least one non-ionic surface-active additive E based on polyethers and/or polyglycerines; (c) at least one anionic surface-active additive F based on sulfonates, sulfates, phosphonates, phosphates or carboxylates; and (d) water.
Type:
Application
Filed:
March 16, 2012
Publication date:
July 5, 2012
Applicant:
CLARIANT FINANCE (BVI) LIMITED
Inventors:
Franz-Leo HEINRICHS, Anais BIALY, Klaus SAITMACHER, Josef RITTER
Abstract: A process for making particles is provided. In embodiments, a suitable process includes adding a rheology modifier to an emulsion utilized to form toner particles. The rheology modifier permits the use of a higher solid content in the emulsion, with a resulting higher yield of toner particles, without requiring the use of powerful mixing equipment.
Type:
Grant
Filed:
June 5, 2009
Date of Patent:
July 3, 2012
Assignee:
Xerox Corporation
Inventors:
Zhaoyang Ou, Zhen Lai, Christopher D. Blair, Chieh-Min Cheng
Abstract: A method of preparing a toner using a micro-suspension particle, includes preparing a mixture by mixing a resin having acidic groups, a master batch of coloring pigment, and at least one additive with an organic solvent, and then neutralizing the acid groups of the resin with a base; forming a micro-suspension by adding the prepared mixture to a dispersion medium; and forming a toner composition by removing the organic solvent from the prepared micro-suspension. Therefore, the method of preparing a toner using the disclosed micro-suspension particle and a toner prepared using the same can save manufacturing costs, and can improve charging ability and cleaning properties of the toner.
Type:
Grant
Filed:
February 20, 2008
Date of Patent:
June 26, 2012
Assignee:
Samsung Fine Chemicals Co., Ltd.
Inventors:
Woo Young Yang, Keon Il Kim, Dae Il Hwang, Jae Bum Park, Il Sun Hwang, Jun Hee Lee, Jae Kwang Hwang, Dong Won Kim, Duck Kyun Ahn
Abstract: A method for manufacturing a toner is provided. The method for manufacturing a toner uses a rotary stirring apparatus that includes a circulating section for repeatedly performing circulation in a powder passage having a rotary stirring chamber and a circulation tube to return to the rotary stirring chamber by a rotary stirring section having a rotary disc around which rotary blades are installed and a rotary shaft, and a temperature adjusting section provided at least on a part of the powder passage for adjusting temperatures in the powder passage and of the rotary stirring section to a predetermined temperature, and includes a temperature adjusting step; a fine resin particle adhering step; a spraying step; and a film-forming step. The temperature in the powder passage is adjusted to the predetermined temperature by the temperature adjusting section at the fine resin particle adhering step, the spraying step, and the film-forming step.
Abstract: The present invention provides a porous toner. The porous toner has a porosity of greater that 20 percent. The toner can include vinyl polymers, copolymers of styrene monomers and polyesters. In addition a method of manufacture of the toner particles is provided.
Type:
Grant
Filed:
December 21, 2005
Date of Patent:
June 5, 2012
Assignee:
Eastman Kodak Company
Inventors:
Xin Jin, Jason Morgan, Charles T. Havens
Abstract: A method of manufacturing a toner including dispersing a binder resin, a coloring agent and a releasing agent in an organic solvent to obtain an oil phase; dispersing the oil phase in an aqueous medium with a shearing force to obtain a dispersion emulsion; wherein the shearing force is made by a screen or vessel that is situated around a rotor, the screen spinning in a direction opposite to the direction that the rotor spins. Toner produced. Method of using the toner.
Abstract: A process for making a latex emulsion suitable for use in a toner composition includes contacting at least one polyester resin with a bio-based solvent to form a resin mixture, adding a neutralizing agent and deionized water to the resin mixture, removing the solvent from the formed latex, and recovering the emulsion. The solvent removed from the formed latex may be re-used, making the process very environmentally friendly.
Type:
Application
Filed:
November 29, 2010
Publication date:
May 31, 2012
Applicant:
XEROX CORPORATION
Inventors:
Guerino G. Sacripante, Shigang Qiu, Rina Carlini, Ke Zhou
Abstract: A method of manufacturing a toner in which uneven distribution of toner ingredients by subjecting them to fine dispersion is prevented and which is excellent in transferability, cleaning properties, anti-filming properties, anti-blocking properties, high-temperature offset resisting properties and transparency is provided. Melt-kneaded substances include binder resins, colorants and release agents, respectively. The colorant and the release agent are dispersed in the binder resin. The melt-kneaded substance is negatively charged by an anionic dispersant, whereas the melt-kneaded substance is positively charged by a cationic dispersant. An aggregate is formed by heteroaggregation of the melt-kneaded substances. The aggregate is fused by heating and formed into a spherical toner.
Abstract: A method of manufacturing the toner comprising dispersing at least one of a binder resin or a precursor thereof, a coloring agent and a releasing agent in an organic solvent to obtain an oil phase, dispersing the oil phase in an aqueous medium with a shearing force to obtain a dispersion emulsion, wherein the dispersion emulsion process has plural stages and the shear speed A of the emulsification process of stage n is faster than the shear speed B of the emulsification process of stage n+1.
Abstract: The present invention relates to a magnetic carrier for an electrophotographic developer comprising spherical magnetic composite particles comprising a phenol resin as a binder and ferromagnetic iron oxide particles bonded to each other through the phenol resin, wherein the spherical magnetic composite particles have a ten-point mean roughness Rz of 0.3 to 2.0 ?m. The magnetic carrier for an electrophotographic developer according to the present invention exhibits an excellent durability against peeling-off and abrasion of coating resins formed thereon and a high stability to mechanical stress exerted onto the carrier, is free from occurrence of spent toner, can be stably held over a long period of time without occurrence of fogging and unevenness in density of toner images, and can keep high-quality images with an excellent gradation for a long period of time.
Abstract: To provide an apparatus for producing a toner, including: a droplet forming unit configured to periodically discharge a toner composition liquid, which includes at least a resin and a colorant, from a plurality of nozzles so as to form droplets; a gas flow forming unit configured to form a gas flow which passes through a narrowed portion that corresponds to a nozzle formation area and that is placed on a downstream side of the nozzles with respect to a droplet discharge direction, and which advances in the droplet discharge direction; and a particle forming unit configured to form toner particles by solidifying the droplets of the toner composition liquid passed through the narrowed portion and then discharged, wherein the opening area of an opening which forms the narrowed portion decreases from an inlet side of the narrowed portion toward an outlet side of the narrowed portion.
Abstract: A magenta toner, produced by a method including suspending an oily liquid comprising a binder resin and a colorant in an aqueous medium, wherein the colorant comprises a naphthol pigment and a quinacridone pigment, and the quinacridone pigment comprises a pigment having a specific formula.
Abstract: A process for preparing a toner for electrophotography containing mother toner particles which contain a resin binder containing a crystalline polyester and a linear amorphous polyester and an external additive, wherein the process includes an external addition step of mixing the mother toner particles and at least a part of the external additive and the step of carrying out a heat-treating step at the external addition step or later. The toner for electrophotography obtained according to the present invention is suitably used for, for example, developing a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method, or the like.
Abstract: A method of manufacturing toner is provided, including discharging a toner constituents liquid from multiple nozzles to form liquid droplets and solidifying the liquid droplets into toner particles. The multiple nozzles satisfy the following formula: 2.5?p/d?7.5 wherein d represents an outlet diameter of each nozzle and p represents an interval between two nozzles.
Type:
Application
Filed:
October 3, 2011
Publication date:
April 19, 2012
Inventors:
Yoshihiro NORIKANE, Masaru Ohgaki, Andrew Mwaniki Mulwa, Yuko Sekiguchi
Abstract: A toner comprising an amorphous polyester, a crystalline polyester that is forming domains in the toner, and a colorant that is being dispersed at least in the domains of the crystalline polyester. The toner may be obtained by dispersing an oil phase including the amorphous polyester or a precursor capable of producing the amorphous polyester, the crystalline polyester, the colorant, and an organic solvent, in an aqueous medium to prepare an O/W dispersion, the oil phase; and removing the organic solvent from the O/W dispersion.
Abstract: A method of making toner particles, including mixing at least one emulsion of at least one resin, a colorant, an optional wax, and optional additives to form a slurry; heating the slurry to form aggregated particles in the slurry; freezing aggregation of the particles by adjusting the pH; and heating the aggregated particles in the slurry to coalesce the particles into toner particles.
Type:
Grant
Filed:
June 29, 2010
Date of Patent:
March 27, 2012
Assignee:
Xerox Corporation
Inventors:
Daryl W. Vanbesien, Paul Gerroir, Karen A. Moffat, Melanie L. Davis, Abdisamed Sheik-Qasim, David Kurceba, Faisal Shamshad, Michael D'Amato, Juan A. Morales-Tirado
Abstract: A method of manufacturing toner including mixing mother toner particles containing a binder resin and a coloring agent and first particles having an average primary particle diameter of from 100 nm to 1 ?m to using a mixer including a rotary shaft member, multiple stirring members provided to the surface of the shaft member, and a casing to cover the multiple stirring members, wherein the cross section of the inner periphery of the casing relative to a direction perpendicular to the rotation axis of the shaft member is circular around the rotation axis with a substantially constant distance between the inner periphery and the rotation axis. The casing covers the multiple stirring members and a cooling jacket is provided to at least part of the outer periphery of the casing. The weight ratio of the particles to the mother toner particles is from 1.5% to 10%.
Abstract: A hybrid toner includes micro cylinders, cores inserted into the micro cylinders, and an external addition layer covering the micro cylinders to which the cores are inserted. The hybrid toner prevents a toner blocking phenomenon, image contamination, and low storage stability which occur due to dispersion of wax and colorants to an outer surface of the toner.
Abstract: A toner for developing electrostatic images which is obtained by melt mixing at least a binder resin and a coloring agent, forming a powder material by pulverizing the obtained mixture after cooling and removing rough particles and fine particles from the formed powder material by classification, wherein inorganic fine particles having a roundness of 1.00 to 1.30, an average of the diameter of primary particles of 0.05 to 0.45 ?m and a ratio of a standard deviation to the average of the diameter of primary particles of 0.25 or smaller are added as an external additive, and a process for producing a toner for developing electrostatic images which comprises melt mixing at least a binder resin and a coloring agent, forming a powder material by pulverizing the obtained mixture after cooling, rounding the powder material by a heat treatment and adding the above inorganic fine particles to the rounded powder material.
Abstract: A method of preparing a toner, including periodically dripping and discharging a droplet of a toner constituent liquid including a resin and a colorant; and solidifying and granulating the droplet, wherein the dripper includes a thin film including plural nozzles; and an oscillator including an oscillation generator generating an oscillation; and an oscillation amplifier, including an oscillation surface facing the thin film in parallel therewith, amplifying the oscillation, and wherein the toner constituent liquid is fed between the thin film and the oscillation surface.
Abstract: A method for the preparation of shaped polymeric particles, and in a particular embodiment shaped electrostatographic toner particles, of controlled morphology including the following steps. A selected solvent or solvent mixture is used to dissolve a polyester polymer material to form an organic phase, wherein the polyester material is formed from at least one diol and at least one multicarboxylic aromatic acid and has a solubility parameter of greater than 9.0 (cal/cm3)1/2, the selected solvent or solvent mixture includes at least a first solvent having a solubility parameter of less than 9.0 (cal/cm3)1/2, and the difference in solubility parameters for the polyester material and the at least first solvent is between 1.0 and 3.0 (cal/cm3)1/2. The organic phase is dispersed in an aqueous phase containing a particulate stabilizer to form a dispersion, which is then homogenized.
Abstract: A toner containing toner particles, each toner particle containing: a releasing agent; a colorant; and a binder resin containing at least a crystalline polyester resin and a non-crystalline polyester resin, wherein in the case where a volume average particle diameter of the toner is defined as Dv, the toner contains a group of the toner particles having 4/5Dv, and a group of the toner particles having 6/5Dv, and wherein an endothermic value A of the crystalline polyester resin at a first temperature increase in DSC of the toner, an endothermic value B of the crystalline polyester resin at a first temperature increase in DSC of the group of the toner particle having 4/5Dv, and an endothermic value C of the crystalline polyester resin at a first temperature increase in DSC of the group of the toner particles having 6/5Dv satisfy the relation represented by the following formulas: 50<(B/A)×100<90, and 110<(C/A)×100<150.
Abstract: A toner which contains: toner base particles having Dv of 4.0-6.0 ?m; and two or more additives on surfaces of the toner base particles, where the additives contains Additives A and B, wherein the toner base particles are obtained by the method containing: dispersing, in an aqueous medium, an oil phase in which at least one of a crystalline polyester resin and a non-crystalline polyester resin is contained in an organic solvent, to prepare a dispersion liquid; and removing the organic solvent from the dispersion liquid, and wherein the Additive A has the largest average primary particle diameter in the additives and has CA of 5-10% where the CA is determined by the formula A, and the Additive B has the smallest average primary particle diameter in the additives and has CB of 45-100% where the CB is determined by the formula B.
Abstract: A toner including a release promoter and a binder resin containing crystalline polyester resin and non-crystalline polyester resin, wherein W/R is 0.045 to 0.850 where W denotes height of third bottom peak in infrared absorption spectrum of crystalline polyester resin and R denotes height of maximum top peak in infrared absorption spectrum of non-crystalline polyester resin, each of the infrared absorption spectra being measured by infrared spectroscopic method (KBr method) using Fourier transform infrared spectrometer, wherein the toner is used as toner contained with carrier in premix agent which is developer containing them previously mixed together before shipment, and wherein the premix agent is used in an image forming apparatus containing latent image bearing member, developing device for developing latent image on the latent image bearing member with developer containing toner and carrier, and agent supplying unit configured to supply the premix agent to the developing device.
Abstract: A negatively chargeable developer includes: negatively chargeable toner mother particles including at least binding resin and colorant; and an external additive that is externally added to a surface of the toner mother particles, wherein the external additive includes polymethyl methacrylate that is within a range from approximately 0.4 parts by weight to approximately 0.8 parts by weight inclusive per 100 parts by weight of the toner mother particles and that has positive chargeability.
Abstract: A process for making a resin emulsion suitable for use in forming toner particles is provided. In embodiments, a suitable process includes melt mixing a resin in the absence of an organic solvent, optionally adding a surfactant to the resin, adding to the resin a basic agent and water, and subjecting the resin, basic agent and water to acoustic mixing at a suitable frequency to form an emulsion of resin particles. In embodiments, the resin emulsion thus produced may be utilized to form a toner.
Type:
Grant
Filed:
April 20, 2009
Date of Patent:
February 28, 2012
Assignee:
Xerox Corporation
Inventors:
Zhen Lai, Chieh-Min Cheng, Shigang Qiu, Emily L. Moore, Tie Hwee Ng
Abstract: Provided are an electrophotographic toner and a method for producing the electrophotographic toner that satisfy high image quality, cleaning stability, and high productivity. The electrophotographic toner is produced by spray-drying a toner ingredient-containing liquid, wherein the toner ingredient-containing liquid dissolves or disperses at least a resin, a low molecular mass organic material, and a colorant in an organic solvent, the resin is soluble in the organic solvent, the low molecular mass organic material is a crystalline compound or a composition of crystalline compounds that is soluble in the organic solvent, the toner ingredient-containing liquid contains substantially no particles having a particle diameter of 500 nm or more, the crystalline compound or the composition of crystalline compounds crystallizes upon spray-drying to deform toner particles into a circularity of 0.93 or higher to 0.98 or less, and volume average particle diameter of the toner particles is 3.
Abstract: To provide a toner A containing: base particles, each containing polyester, microcrystalline wax, and a colorant; and spherical silica particles having an average primary particle diameter of 100 nm to 150 nm, wherein the microcrystalline wax has an onset temperature of 45° C. to 60° C. as determined by DSC, and a carbon number distribution of 25 to 55.
Abstract: A method of manufacturing toner particles capable of decreasing the manufacturing costs by simplifying the manufacturing apparatus and by decreasing the number of the steps, as well as to provide toner particles, a two-component developer, a developing apparatus and an image forming apparatus are provided. A high-pressure homogenizer is constituted by a tank, a feed pump, a high-pressure pump, a heat exchanger, a nozzle, a first depressurizing module, a cooling unit, a second depressurizing module and a take-out port arranged in this order. A flow path constituted in the first depressurizing module has a straight portion tilted with respect to a direction in which the aqueous slurry passes and a portion for relaxing the flow of the aqueous slurry.