Process Of Making Developer Composition Patents (Class 430/137.1)
  • Patent number: 7713670
    Abstract: A developer for an electrophotographic tandem image forming method is provided that contains a toner; and a carrier, wherein the toner has a shape factor SF-1 of from 120 to 160, an average circularity of form 0.93 to 0.98, a weight-average particle diameter (D4) of from 3.0 to 8.0 ?m, and a ratio (D4/Dn) of the weight-average particle diameter (D4) to a number-average particle diameter (Dn) of from 1.01 to 1.20, and wherein the carrier is almost a spherical ferrite coated with a resin wherein alumina is dispersed, which has an average particle diameter of from 20 to 45 ?m and the following formula: (MgO)x(MnO)y(Fe2O3)z wherein x is from 1 to 5 mol %, y is from 5 to 55 mol % and z is from 45 to 55 mol %.
    Type: Grant
    Filed: May 11, 2005
    Date of Patent: May 11, 2010
    Assignee: Ricoh Company, Ltd.
    Inventors: Masami Tomita, Tomio Kondou, Masahide Yamashita, Kousuke Suzuki
  • Patent number: 7709175
    Abstract: The object of the present invention is to provide a method for producing a toner which includes ejecting a toner composition fluid containing a toner composition which contains a toner and a colorant, from a nozzle vibrated at a constant frequency to make the toner composition fluid into droplets, and solidifying the droplets to be made into particles, in which the toner composition fluid comprises a toner composition, and the toner composition contains a resin, and a colorant.
    Type: Grant
    Filed: March 16, 2006
    Date of Patent: May 4, 2010
    Assignee: Ricoh Company, Ltd.
    Inventor: Shinji Ohtani
  • Patent number: 7709174
    Abstract: A toner is provided including a colorant; a first binder resin; and a second binder resin, wherein an amount of the first binder resin and an amount of the second binder resin are phase separated from each other in the toner, and wherein a phase of the first binder resin is partially or completely covered with a phase of the second binder resin; and a method of preparing the toner, and a developer, an image forming method, an image forming apparatus, and a process cartridge using the toner.
    Type: Grant
    Filed: December 15, 2006
    Date of Patent: May 4, 2010
    Assignee: Ricoh Company Limited
    Inventors: Tsuyoshi Sugimoto, Hiroshi Yamashita, Ryota Inoue, Yoshihiro Moriya, Shinichi Wakamatsu, Akihiro Kotsugai
  • Publication number: 20100104965
    Abstract: The toner includes a binder resin; a release agent; a colorant; and a dispersing resin configured to disperse the release agent. The dispersing resin includes a polyhydroxycarboxylic acid unit obtained from an optically active monomer. The polyhydroxycarboxylic acid unit has an optical purity of not greater than 80%, wherein the optical purity is defined as the absolute value of difference between the mole percentage of a L-monomer in the optically active monomer and the mole percentage of a D-monomer in the optically active monomer.
    Type: Application
    Filed: October 8, 2009
    Publication date: April 29, 2010
    Inventors: Ryota INOUE, Akihiro Kotsugai, Toyoshi Sawada, Akiyoshi Sabu
  • Publication number: 20100098462
    Abstract: A method of preparing a toner using a micro-suspension particle, includes preparing a mixture by mixing a resin having acidic groups, a master batch of coloring pigment, and at least one additive with an organic solvent, and then neutralizing the acid groups of the resin with a base; forming a micro-suspension by adding the prepared mixture to a dispersion medium; and forming a toner composition by removing the organic solvent from the prepared micro-suspension. Therefore, the method of preparing a toner using the disclosed micro-suspension particle and a toner prepared using the same can save manufacturing costs, and can improve charging ability and cleaning properties of the toner.
    Type: Application
    Filed: February 20, 2008
    Publication date: April 22, 2010
    Applicant: Samsung Fine Chemicals Co., Ltd.
    Inventors: Woo Young Yang, Keon Il Kim, Dae Il Hwang, Jae Bum Park, Il Sun Hwang, Jun Hee Lee, Jae Kwang Hwang, Dong Won Kim, Duck Kyun Ahn
  • Patent number: 7691553
    Abstract: A kneaded material obtained by heating and melt-kneading a toner composition and a water-based medium containing water are put into a container of a granulating apparatus, and heated by a heater while agitating, to disperse the kneaded material into the water-based medium in its softened state. A temperature at which a loss tangent value of the kneaded material reaches a predetermined loss tangent value A, specifically, 0.5 or more and less than 5.0, is inputted to a granulating temperature input section as a setting granulating temperature T1. The heater is then controlled by a control section so that a granulating temperature as a temperature of the water-based medium measured by a thermometer reaches the setting granulating temperature T1 inputted to the input section. Accordingly, the granulating temperature as a temperature of the water-based medium, and thus a temperature of the kneaded material in the water-based medium is adjusted to T1.
    Type: Grant
    Filed: March 26, 2007
    Date of Patent: April 6, 2010
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Satoru Ariyoshi, Yoshitaka Kawase, Yoritaka Tsubaki
  • Publication number: 20100080916
    Abstract: A paper sizing or coating composition is provided, which includes: a first binder resin, which is compatible with dry toner binder resin; a second binder resin, which is compatible with liquid toner binder resin, and which is different from the first binder resin; a first pigment, which has a BET surface area of from greater than zero to about 35 m2/g; and a second pigment, which has a BET surface area of about 35 m2/g or greater, and which is different from the first pigment. Recording sheets which include the composition, methods of making the composition and recording sheets, and methods for making an image are provided.
    Type: Application
    Filed: September 11, 2009
    Publication date: April 1, 2010
    Applicant: INTERNATIONAL PAPER COMPANY
    Inventors: Jay C. Song, Sen Yang, Michelle X. Wang, Pat Morabito
  • Publication number: 20100081078
    Abstract: The present invention is to provide a method for producing a toner capable of sufficiently decreasing the percentage of moisture content of a wet cake in the process of obtaining colored resin particles in wet state (wet cake), capable of reducing the workload in the following drying process, and thus excellent in productivity.
    Type: Application
    Filed: October 1, 2009
    Publication date: April 1, 2010
    Applicant: ZEON CORPORATION
    Inventors: Hisashi Kurokawa, Rei Katsuyama, Fuminari Oyama, Hiroto Kidokoro
  • Publication number: 20100081075
    Abstract: A magenta toner, produced by a method including suspending an oily liquid comprising a binder resin and a colorant in an aqueous medium, wherein the colorant comprises a naphthol pigment and a quinacridone pigment, and the quinacridone pigment comprises a pigment having a specific formula.
    Type: Application
    Filed: September 28, 2009
    Publication date: April 1, 2010
    Inventors: Naohiro WATANABE, Shinichi WAKAMATSU, Naohito SHIMOTA, Hiroshi YAMASHITA, Tsuyoshi SUGIMOTO, Masaki WATANABE, Tsuneyasu NAGATOMO
  • Publication number: 20100062358
    Abstract: The present disclosure provides methods for modifying polymeric resin materials after polymerization to make fine adjustments in the chemical or physical properties of the resin, or in modifying the structure of the polymer chains. The resulting resins may be useful in forming toner particles. In embodiments, a polymeric resin may have epoxy groups added to its backbone to increase its melting point. The resulting polymer, sometimes referred to herein as an epoxidized polymer, may, in turn, be reacted with wax-like components, to increase the compatibility of the polyester with waxes utilized in forming toner particles. In other embodiments, the resulting epoxidized polymer may be reacted with components possessing carboxylic acid groups to adjust the acid value and weight average molecular weight of the resin.
    Type: Application
    Filed: September 10, 2008
    Publication date: March 11, 2010
    Applicant: XEROX CORPORATION
    Inventor: Jordan H. Wosnick
  • Publication number: 20100062352
    Abstract: The present invention provides a method for producing a toner, the method including: preparing a wax dispersion liquid by cooling a wax solution, in which a wax is heated and dissolved or dispersed in an organic solvent, in a container so that a standard deviation ? of a temperature distribution between a center portion of the container and an inner wall of the container is 0.5 or less and the cooling rate is 2.0° C./min or more, to precipitate wax particles in the wax solution; forming toner base precursor particles by adding an aqueous phase containing resin fine particles into an oil phase containing at least the wax dispersion liquid, a colorant and a binder resin and mixing the oil phase and the aqueous phase with each other; and preparing toner base particles by removing the solvent from the toner base precursor particles.
    Type: Application
    Filed: September 8, 2009
    Publication date: March 11, 2010
    Inventors: Teruki Kusahara, Junichi Awamura, Tomomi Suzuki, Toshihiko Karato
  • Publication number: 20100055590
    Abstract: A method for producing a toner including periodically forming and discharging liquid droplets of a toner composition liquid containing at least a resin, a releasing agent and a colorant from a plurality of nozzles formed in a thin film which is provided in a reservoir for the toner composition liquid, by vibrating the thin film using a mechanically vibrating unit, and forming toner particles by solidifying the liquid droplets, wherein the forming toner particles comprises primarily drying the liquid droplets under a stream of dry gas containing an organic solvent whose partial pressure is equal to or higher than 1/10 of a saturated vapor pressure thereof but is equal to or lower than the saturated vapor pressure, the saturated vapor pressure being that at a drying temperature; and secondarily drying the primarily dried liquid droplets for solidification while the organic solvent is being evaporated.
    Type: Application
    Filed: August 31, 2009
    Publication date: March 4, 2010
    Inventors: Takahiro HONDA, Yohichiroh Watanabe, Kazumi Suzuki
  • Publication number: 20100047707
    Abstract: A toner which can efficiently induce high-frequency magnetic induction heating by Neel relaxation and/or Brown relaxation is provided. A toner including a core particle containing a thermoplastic polymer material and superparamagnetic ferrite fine particles having a particle diameter of less than 100 nm which adhere to the surfaces of the core particle is manufactured by directly forming the superparamagnetic ferrite fine particles having a particle diameter of less than 100 nm on the surfaces of the core particle so that the superparamagnetic ferrite fine particles having a particle diameter of less than 100 nm are not in contact with each other. As a result, the toner is prevented from being scattered due to the influence of a magnetic field, so that a high quality image is formed.
    Type: Application
    Filed: August 20, 2009
    Publication date: February 25, 2010
    Inventors: Tomoaki UEDA, Masanori Abe
  • Patent number: 7662534
    Abstract: To provide a method including processing electrophotographic toner constituent material to a fibrous fine precursor and pulverizing and cutting it to obtain a uniform fibrous toner with energy efficiency in an apparatus for producing electrophotographic toner including a nozzle unit containing a nozzle having a flow path tapering toward the nozzle hole at 2° to 20° and a gas nozzle unit containing a gas nozzle and gas flow path tapering toward the nozzle hole at 15° to 33° relative to a direction of a nozzle axis, wherein the toner constituent material containing a raw material A containing a resin and pigment, and a raw material B containing one of a low melting point resin, wax and organic solvent, is extruded from the nozzle at 150° C. to 320° C., and drawn by gas flow from the gas nozzles so as to be a fibrous fluid while controlling the flow rate.
    Type: Grant
    Filed: September 10, 2007
    Date of Patent: February 16, 2010
    Assignee: Ricoh Company Ltd.
    Inventors: Naotoshi Kinoshita, Tetsuya Tanaka, Masahiro Kawamoto
  • Patent number: 7662535
    Abstract: The present invention is a method for the preparation of electrostatographic toner that includes the following steps. A polymer material is dissolved in an organic solvent to form an organic phase that includes a metal complex of zinc dimethyldithiocarbamate; zinc diethyldithiocarbamate; dibenzyldithiocarbamate, zinc di-n-butyldithiocarbamate. The organic phase is dispersed in an aqueous phase that includes a particulate stabilizer to form a dispersion and the resultant dispersion is homogenized. The organic solvent is evaporated and the resultant product is recovered, washed and dried.
    Type: Grant
    Filed: December 15, 2006
    Date of Patent: February 16, 2010
    Assignee: Eastman Kodak Company
    Inventors: Xiqiang Yang, Sandra G. Taft, Mridula Nair
  • Publication number: 20100035175
    Abstract: A method for producing a toner, comprising the step of feeding raw materials containing a resin binder and a colorant to an open-roller type kneader, and melt-kneading the raw materials, wherein the resin binder contains a crystalline polyester and an amorphous polyester, and wherein the crystalline polyester and the amorphous polyester fed to the open-roller type kneader are in a weight ratio, i.e. crystalline polyester/amorphous polyester, of from 5/95 to 30/70, and have a ratio of average particle sizes of crystalline polyester/amorphous polyester of from 1.5 to 4.0. The toner obtained according to the present invention is used in, for example, the development of a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.
    Type: Application
    Filed: July 28, 2009
    Publication date: February 11, 2010
    Applicant: KAO CORPORATION
    Inventor: Akihiro EIDA
  • Publication number: 20100028794
    Abstract: The present invention provides an aqueous dispersion of nonspherical fine resin particles having excellent storage stability and processability such as aggregation and adherence to other substances, a method for producing the aqueous dispersion of fine resin particles, and a method for producing toner particles using the aqueous dispersion of fine resin particles. The present invention relates to an aqueous dispersion of fine resin particles characterized in that the fine resin particles are nonspherical particles with an average minor axis being 0.02 ?m or more and 1.00 ?m or less and an average ratio of a major axis to a minor axis being 2.0 or more and 5.0 or less, a method for producing the aqueous dispersion of fine resin particles, and a method for producing toner particles using the aqueous dispersion of fine resin particles.
    Type: Application
    Filed: October 6, 2009
    Publication date: February 4, 2010
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Masayoshi Kato, Takayuki Toyoda, Ryuji Higashi, Ryo Natori, Takaho Shibata, Yuya Chimoto, Takeshi Miyazaki
  • Patent number: 7655375
    Abstract: The present invention is a method for the preparation of electrostatographic toner including the following steps. A polymer material is dissolved in an organic solvent to form an organic phase. The organic phase is dispersed in an aqueous phase that includes a particulate stabilizer and a salt including an anion selected from chloride, oxychloride, sulfate, perchlorate, nitrate, dihydrogen phosphate, lactate, trifluoromethylsulfonate, and trifluromethylhydrate and a cation selected from aluminum, iron (III), tin (II) and zirconium (IV), to form a dispersion. The dispersion is homogenized. The organic solvent is evaporated from the dispersion and the resultant product is recovered, washed and dried. In an alternate method the salt is added directly to the dispersion.
    Type: Grant
    Filed: December 15, 2006
    Date of Patent: February 2, 2010
    Assignee: Eastman Kodak Company
    Inventors: Xiqiang Yang, Dinesh Tyagi, Lloyd A. Lobo, Patrick M. Lambert, Sandra G. Taft
  • Publication number: 20100021838
    Abstract: Porous particles comprising a polymer binder and at least one additive distinct from any pore stabilizing compound present in the particle, wherein: the polymer binder comprises a solid compositionally continuous phase having an external particle surface; discrete pores are dispersed within the solid compositionally continuous phase, forming internal pore surfaces; and the at least one additive is present primarily in the discrete pores. The additive may further preferably not be present in the solid compositionally continuous phase, and be substantially absent from the external particle surface. A toner set for forming a color electrophotographic image comprising a plurality of different colored toners, where at least one of the different colored toners comprise such porous particles comprising additives, and in a particular embodiment wherein at least two different colored toners each comprise different pigments present primarily in the internal pores. A process of making such porous particles.
    Type: Application
    Filed: July 20, 2009
    Publication date: January 28, 2010
    Inventors: David D. Putnam, Mridula Nair, Mary C. Brick, Tamara K. Jones
  • Publication number: 20100015547
    Abstract: Provided is a method for producing an electrostatic image developing toner comprising: agglutinating wax and resin particles in aqueous medium; manufacturing a toner composed of wax and resin for developing an electrostatic image, wherein the wax is inside colorants. The method solves the problems of existing toner for developing an electrostatic image, such as low dispersion and easy detachment of colorants, low image density, the contamination of carriers and developing sleeves and low durability. The toner of the invention has high roll viscosity resistance and durability, and the colorants will not detach.
    Type: Application
    Filed: September 3, 2008
    Publication date: January 21, 2010
    Applicant: HUBEI DINGLONG CHEMICAL CO., LTD.
    Inventors: Shuangquan ZHU, Zeguan LAN, Liping LU
  • Publication number: 20100009277
    Abstract: Hydrophobic inorganic fine particles are provided which: does not cause melt adhesion of toner to a photosensitive member and contamination of a contact charging member; imparts excellent flowability, charging performance and durability to toner even after the toner is stored in a high-temperature, high-humidity environment over a long time period; and does not cause dripping of toner and contamination with the toner. The hydrophobic inorganic fine particles are obtained by subjecting inorganic fine particles to surface treatment with silicone oil and then with a silane compound and/or a silazane compound, or by subjecting inorganic fine particles to surface treatment with a silane compound and/or a silazane compound in the presence of silicone oil, and further subjecting the inorganic fine particles thus surface-treated to surface treatment with silicone oil.
    Type: Application
    Filed: September 18, 2009
    Publication date: January 14, 2010
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Yoshihiro Ogawa, Yusuke Hasegawa, Kouji Nishikawa, Miho Okazaki, Yoshitaka Suzumura, Takashige Kasuya
  • Publication number: 20100009280
    Abstract: Treated metal oxide particles include metal oxide particles treated with at least a charge modifying agent. The charge modifying agent is represented by the following formula: An-Zc-Yb—Ar(EW)a wherein Ar represents an aromatic group, EW represents an electron withdrawing group, Y represents a spacer group, Z represents an alkylene group, An represents an anchor group, a is an integer from 1 to 5, b is 0 or 1, and c is 0 or 1. The treated metal oxide particles may also be treated with a second charge modifying agent or with a hydrophobicity-imparting agent. A toner composition including toner particles and treated metal oxide particles is also disclosed.
    Type: Application
    Filed: July 9, 2008
    Publication date: January 14, 2010
    Inventors: Jinsong Liu, Hairuo Tu, Dmitry Fomitchev
  • Patent number: 7645549
    Abstract: Broadly the invention provides for a deinkable toner composition, an image made with the deinkable toner, and a method for making the toner including a coloring agent; a thermoplastic polymer; and a protein. In another embodiment the toner includes a coloring agent and a thermoplastic polymer where the protein has been incorporated into the polymer itself. In typical embodiments the protein is derived from soybeans but may be from other plant or animal sources. Typically the toner has a positive triboelectric charge of between about 10 to about 40 microCoulomb/g, or a negative triboelectric charge of between about 10 to about 40 microCoulomb/g.
    Type: Grant
    Filed: February 27, 2004
    Date of Patent: January 12, 2010
    Assignee: Battelle Memorial Institute
    Inventors: Bhima R. Vijayendran, Herman P. Benecke, Elizabeth Drotleff, Joel D. Elhard, J. David Robbins, Jeffrey Cafmeyer, Joan Muellerleile
  • Patent number: 7642033
    Abstract: In a toner production method, a volatile solvent gas is jetted into a dispersion of aggregated resin particles where at least resin particles dispersed in a continuous phase are aggregated. A form of the aggregated resin particles is controlled by jetting the volatile solvent gas into the dispersion of aggregated resin particles. The volatile solvent is removed from the form-controlled aggregated resin particles.
    Type: Grant
    Filed: February 16, 2006
    Date of Patent: January 5, 2010
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventors: Jun Ikami, Masateru Kawamura
  • Publication number: 20090325100
    Abstract: The present invention provides a toner containing at least two binder resins composed of at least a resin A and a resin B which are incompatible with each other, and a colorant, wherein the toner has an average circularity of 0.93 to 0.98 and is produced by atomizing a toner composition liquid in a vapor phase to form liquid droplets and solidifying the liquid droplets, and the toner composition liquid is prepared by dissolving or dispersing the at least two binder resins and the colorant in an organic solvent.
    Type: Application
    Filed: June 12, 2008
    Publication date: December 31, 2009
    Inventors: Yohichiroh Watanabe, Kazumi Suzuki, Shinji Ohtani, Takahiro Honda, Yoshihiro Norikane
  • Publication number: 20090325099
    Abstract: A toner produced by a method including dissolving or dispersing toner components comprising a colorant and at least one of a binder resin and a precursor thereof in an organic solvent to prepare a toner components liquid, dispersing the toner components liquid in an aqueous medium including a surfactant, a particulate resin A having the same polarity as the surfactant and a volume average particle diameter of from 5 to 50 nm, and a particulate resin B having a volume average particle diameter of from 10 to 500 nm to form liquid droplets, and removing the organic solvent from the liquid droplets. The particulate resin B is incompatible with the binder resin and swells in the organic solvent.
    Type: Application
    Filed: June 26, 2009
    Publication date: December 31, 2009
    Inventors: Masaki WATANABE, Hiroshi YAMASHITA, Tsuyoshi SUGIMOTO, Naohiro WATANABE, Shinichi WAKAMATSU
  • Publication number: 20090311614
    Abstract: A charge director material for charging a liquid toner, the charge director material comprising (a) nanoparticles of a simple salt and (b) a sulfosuccinate salt of the general formula MAn, wherein M is a metal, n is the valence of M, and A is an ion of the general formula (I) [R1—O—C(O)CH2CH(SO3?)C(O)—O—R2],??(I) wherein each of R1 and R2 is an alkyl group; said charge director material being substantially free of acids of the general formula (I), wherein one or both of R1 and R2 is hydrogen, and if only one of them is hydrogen, the other is an alkyl group,
    Type: Application
    Filed: May 10, 2006
    Publication date: December 17, 2009
    Applicant: Hewlett-Packard Development Company, L.P.
    Inventors: Yaacov Almog, Avi Koller, Elliad Silcoff, Albert Teishev, Yaffa Israeli, Gary Larson, Lufei Lin
  • Patent number: 7629099
    Abstract: A toner is provided manufactured by a method having the steps: dispersing toner constituents including a resin, in an aqueous medium containing a particulate resin, wherein the resin has a polyester skeleton formed by a ring-opening addition reaction of a cyclic ester with a first compound having an active hydrogen group; and a developer and an image forming method using the toner, and a toner container containing the toner.
    Type: Grant
    Filed: July 17, 2006
    Date of Patent: December 8, 2009
    Assignee: Ricoh Company Limited
    Inventors: Hiroshi Yamashita, Tsuyoshi Sugimoto, Hiroto Higuchi, Yohichiroh Watanabe, Yasuhiro Shindo
  • Publication number: 20090291384
    Abstract: A method of manufacturing a toner including a first dispersing wherein (i) at least two binder resins having different weight average molecular weight, (ii) a coloring agent and (iii) a releasing agent are dispersed in an organic solvent to obtain an oil phase, a second dispersing comprising continuously mixing the oil phase with an aqueous medium comprising a solid particulate dispersion agent to form a dispersion emulsion comprising emulsification particles (where at least one of the first and the second dispersing is carried out under at least one condition based on a property of the binder resin which has the lowest weight-average molecular weight), measuring automatically the volume average particle diameter of the dispersion emulsion during the second dispersing, calculating automatically a difference between the volume average particle diameter of the dispersion emulsion measured during the measuring and a target volume average particle diameter, maintaining automatically an allowable difference betwee
    Type: Application
    Filed: May 20, 2009
    Publication date: November 26, 2009
    Inventor: Hiroshi TAKAHASHI
  • Patent number: 7611812
    Abstract: Layered double hydroxide salts as charge control agents in electrophotographic toners and developers, in powder coating materials, electret materials and in electrostatic separation processes of chargeable materials, such as polymers, wherein the double hydroxide salt contains monovalent and/or divalent, and also trivalent, metal cations, and also contains one or more organic anions A of the formula (I) X—R—Y??(1) wherein X is hydroxyl, carboxyl, sulfato or sulfo; Y is carboxyl, sulfato or sulfo, and R is an aliphatic, cycloaliphatic, heterocycloaliphatic, olefinic, cycloolefinic. heterocycloolefinic, aromatic, heteroaromatic, araliphatic or heteroaraliphatic radical having a total of at least 8 carbon atoms which can be substituted by one or several substituents from the group hydroxyl, amino, halogen, C1-C22-alkyl, C1-C22-alkoxy, —C1-C22-alkylene-(CO)—O—(CH2CH2O)0-50-alkyl,—C1-C22-alkylene-(CO)—O—(CH2H2O)0-50-haloalkyl, carboxy, sulfo, nitro or cyano.
    Type: Grant
    Filed: July 9, 2003
    Date of Patent: November 3, 2009
    Assignee: Clariant Produkte ( Deutschland) GmbH
    Inventors: Eduard Michel, Ruediger Baur, Hans-Tobias Macholdt
  • Patent number: 7611816
    Abstract: In a process for producing toner particles through granulation by a wet process, a process for producing toner particles is provided that enables reduction of water content in wet toner particle cakes obtained by separating toner particles from a toner particle dispersion in a good efficiency, followed by washing, and enables efficient wash-away of impurities remaining on the toner particle surfaces so as to promise superior image characteristics. The toner particles are produced through a filtering step in which a slurry which contains toner particles is subjected to solid-liquid separation by means of a belt filter having a pressing aeration means which carries out aeration with pressing, to form wet toner particle cakes.
    Type: Grant
    Filed: July 24, 2006
    Date of Patent: November 3, 2009
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yoshinori Tuji, Hidekazu Fumita, Minoru Omura
  • Publication number: 20090269692
    Abstract: A method of manufacturing the toner comprising dispersing at least one of a binder resin or a precursor thereof, a coloring agent and a releasing agent in an organic solvent to obtain an oil phase,dispersing the oil phase in an aqueous medium with a shearing force to obtain a dispersion emulsion, wherein the dispersion emulsion process has plural stages and the shear speed A of the emulsification process of stage n is faster than the shear speed B of the emulsification process of stage n+1.
    Type: Application
    Filed: April 23, 2009
    Publication date: October 29, 2009
    Inventors: Junichi AWAMURA, Akinori SAITOH, Osamu UCHINOKURA, Tomomi SUZUKI
  • Patent number: 7601477
    Abstract: A method of manufacturing a toner by using a liquid dispersion in which a dispersoid containing a material for manufacturing a toner is dispersed in a dispersion medium, and containing a dispersant having a function of improving the dispersibility of the dispersoid, the method including the steps of: preparing the liquid dispersion, applying ozone to the liquid dispersion and/or a liquid dispersion from which at least a portion of the dispersion medium has been removed, and irradiating UV-rays to the liquid dispersion and/or the liquid dispersion from which at least a portion of the dispersion medium has been removed.
    Type: Grant
    Filed: July 21, 2008
    Date of Patent: October 13, 2009
    Assignee: Seiko Epson Corporation
    Inventors: Harunobu Komatsu, Keiichi Inoue, Takashi Teshima, Ken Ikuma
  • Publication number: 20090239170
    Abstract: A method for producing a toner, the method including discharging a toner composition liquid from a plurality of nozzles to form liquid droplets thereof, the toner composition liquid being prepared by dissolving or dispersing in a solvent a toner composition containing at least a binder resin, a colorant, an acid-modified hydrocarbon wax and an unmodified hydrocarbon wax, the waxes serving as a releasing agent, and solidifying the liquid droplets so as to form solid particles.
    Type: Application
    Filed: March 17, 2009
    Publication date: September 24, 2009
    Inventors: Takahiro Honda, Yohichiroh Watanabe, Kazumi Suzuki, Shinji Ohtani, Yoshihiro Norikane
  • Publication number: 20090232557
    Abstract: The toner includes a plurality of toner particles containing a binder resin and a colorant. In toner particles, according to measurement by a flow particle image analyzer, the content of small size particles having a circle-equivalent diameter of 0.5 to 2.0 ?m is 5% by number or less based on the entire toner particles, the content of medium size particles having a circle-equivalent diameter of more than 2.0 ?m and 4.0 ?m or less is 20% by number or more and 30% by number or less based on the entire toner particles, and the content of large size particles having a circle-equivalent diameter of more than 4.0 ?m and 6.0 ?m or less is 50% by number or more and 70% by number or less based on the entire toner particles, and the shape factor of the toner particles SF1 is 130 or more and 140 or less.
    Type: Application
    Filed: March 13, 2009
    Publication date: September 17, 2009
    Inventors: Keiichi KIKAWA, Ayae NAGAOKA, Katsuru MATSUMOTO
  • Publication number: 20090233219
    Abstract: Charge control resin particles comprising a mixture of at least a charge control agent and a resin, wherein a crystalline zinc 3,5-di-tert-butylsalicylate represented by General Formula below, and having major peaks of X-ray diffraction using the CuK?-characteristic X-ray at Bragg angles 2? of at least 6.4±0.2° and 15.4±0.2°, is contained as said charge control agent. Toner for developing electrostatic images which comprises a coloring agent, a binder resin for toner, and the charge control resin particles.
    Type: Application
    Filed: April 1, 2009
    Publication date: September 17, 2009
    Inventors: Akihide Isoda, Tetsuji Kihara, Tohru Tsuruhara
  • Publication number: 20090226840
    Abstract: A production apparatus and a production method of toner particles are provided which efficiently and stably reduce the water content of the wet toner particle cake obtained by separating and washing toner particles from toner particle dispersion in a production apparatus of toner particles granulated in a wet process. A wet toner particle cake 1 formed on a belt filter is aerated and dehydrated with air, and at the same time, sealing units provided on the upstream and downstream sides of the aeration unit 3 can be operated to efficiently seal aeration air.
    Type: Application
    Filed: March 2, 2009
    Publication date: September 10, 2009
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Hidekazu Fumita, Yoshinori Tsuji, Takeshi Tsujino, Minoru Omura, Satoshi Iki, Naoto Aiko
  • Publication number: 20090226837
    Abstract: A method of manufacturing a toner includes preparing a droplet forming device, comprising a storage portion to store a toner composition solution, a thin film formed from a rigid material, bonded to the storage portion by a bonding material, and provided with a nozzle and an oscillation device including an oscillation generation device configured to generate an oscillation upon the thin film and an oscillation amplification device which has an oscillation surface including a position that is parallel and opposite to the thin film and is configured to amplify the oscillation, periodically forming a droplet of the toner composition solution including at least a resin and a coloring agent to be supplied between the thin film and the oscillation surface and discharging the droplet via the nozzle, and solidifying the droplet of the toner composition solution discharged via the nozzle, and forming a toner particle.
    Type: Application
    Filed: March 10, 2009
    Publication date: September 10, 2009
    Inventors: Yoshihiro NORIKANE, Shinji AOKI, Tetsuya SONODA, Keisuke UCHIDA
  • Patent number: 7572375
    Abstract: The present invention provides a method for treating fine particles contained in a first fluid comprising: feeding the first fluid containing the fine particles and a second fluid to generate two laminar flows; migrating a diffusible substance contained in the first fluid into the second fluid at an interface between the first fluid and the second fluid in the laminar flows; and separating the laminar flows into the first fluid containing the fine particles and the second fluid in a diverging region.
    Type: Grant
    Filed: August 31, 2004
    Date of Patent: August 11, 2009
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Seiichi Takagi, Kazuya Hongo, Hiroshi Miyamoto, Tetsuo Ohta, Kazuki Inami
  • Patent number: 7572566
    Abstract: According to the method of producing toner, toner is produced by (i) forming particles of a pigmented resin by applying shear stress to a mixture of a pigmented resin composition, an organic solvent, a polymer dispersing agent, and a hydrophobic medium, the organic solvent being capable of reducing viscosity of the pigmented resin composition, and said polymer dispersing agent having a glass transition point in a range of 50° C. to 80° C. and an SP value in a range of 8.5 to 10, (ii) distilling off the organic solvent, and (iii) separating the toner from the hydrophobic medium and drying the toner. With the above arrangement, the method makes it possible to (i) easily downsize toner particle without causing thermal decomposition of a resin or separation of a release agent, and (ii) produce toner that is small in particle size, excellent in humidity-resistance, and less likely to aggregate.
    Type: Grant
    Filed: July 20, 2006
    Date of Patent: August 11, 2009
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Yasuhiro Shibai, Katsuru Matsumoto
  • Publication number: 20090170018
    Abstract: There is provided a toner for developing a latent electrostatic image, obtained by a method containing: ejecting a toner composition fluid from an ejection hole so as to make the toner composition fluid into droplets; and solidifying the droplets in an atomizing space so as to form solid particles, wherein the toner composition fluid contains at least a colorant formed by reacting a polymer containing 10 mol % or more of a monomer unit having a sulfonic acid group or a salt thereof, or a monomer unit having a sulfuric acid group or a salt thereof as a constitutional unit, and a basic dye.
    Type: Application
    Filed: December 23, 2008
    Publication date: July 2, 2009
    Inventors: Shinichi KURAMOTO, Shinji OHTANI, Yoshihiro NORIKANE
  • Patent number: 7553599
    Abstract: A toner, a method of and an apparatus for preparing a permanently-charged electret toner, including discharging a solution or dispersion including a resin and a colorant through a nozzle vibrating at a constant frequency to form a droplet; applying a direct potential to an electrode facing the nozzle to positively or negatively charge the droplet by an induction phenomenon to form a charged droplet; and drying and solidifying the charged droplet to be permanently charged.
    Type: Grant
    Filed: April 24, 2006
    Date of Patent: June 30, 2009
    Assignee: Ricoh Company, Ltd.
    Inventor: Shinji Ohtani
  • Patent number: 7550244
    Abstract: The present invention provides a method for the preparation of a UV curable electrostatographic toner. The process includes the steps of dispersing a polymeric material and a UV curable material and a UV photoinitiator in an organic solvent to form an organic phase. The organic phase is dispersed in an aqueous phase containing a particulate stabilizer to form a dispersion. The dispersion is homogenized and the organic solvent is removed from the dispersed particles in the dispersion which are then recovered.
    Type: Grant
    Filed: June 14, 2006
    Date of Patent: June 23, 2009
    Assignee: Eastman Kodak Company
    Inventors: Xin Jin, Lloyd A. Lobo, Dinesh Tyagi
  • Publication number: 20090155711
    Abstract: A toner composition including toner particles, wherein the toner particles are prepared by a method in which toner constituents including at least a binder resin and a colorant are kneaded upon application of heat to prepare a toner constituent mixture; the toner constituent mixture is dissolved or swelled in an organic solvent capable of dissolving or swelling at least the binder resin to prepare an oil phase liquid; the oil phase liquid is emulsified in an aqueous liquid to prepare an emulsion; the emulsion is coagulated; and then the coagulated emulsion is dried to prepare the toner particles.
    Type: Application
    Filed: January 12, 2009
    Publication date: June 18, 2009
    Inventors: Hiroshi Yamashita, Masami Tomita, Shigeru Emoto, Tsunemi Sugiyama
  • Patent number: 7544459
    Abstract: The present invention relates to a process for producing a toner which includes the steps of emulsifying a resin binder containing a polyester in an aqueous medium to prepare an emulsion of the resin binder and adding a water-soluble nitrogen-containing compound having a molecular weight of 350 or less to the emulsion obtained in the previous step to aggregate emulsified particles contained in the emulsion. According to the present invention, the shape of toner particles can be controlled simply for a short production time by using a resin binder containing a polyester and using substantially no organic solvent, and further a toner having a narrow and sharp particle size distribution can be produced.
    Type: Grant
    Filed: October 11, 2006
    Date of Patent: June 9, 2009
    Assignee: KAO Corporation
    Inventors: Shinichi Sata, Yoshinobu Ishikawa, Nobumichi Kamiyoshi
  • Publication number: 20090142685
    Abstract: An image forming method including charging an image bearing member by applying combination of DC voltage and AC voltage with frequency of 6.5 to 8.5 cycle/mm; irradiating the image bearing member with light to form an electrostatic image; developing the electrostatic image with a developer including toner to form a toner image; transferring the toner image onto a receiving material; fixing the toner image; cleaning the image bearing member with a blade; then applying a lubricant to the image bearing member; and then spreading the lubricant with a spreading member countering the image bearing member. The toner includes toner particles granulated in an aqueous medium; and at least three kinds of external additives including a first particulate hydrophobic silica, a particulate hydrophobic titanium oxide and a second particulate hydrophobic silica respectively having BET specific surface areas of 20 to 40 m2/g, 40 to 80 m2/g, and 130 to 300 m2/g.
    Type: Application
    Filed: November 24, 2008
    Publication date: June 4, 2009
    Inventors: Tsuneyasu NAGATOMO, Toyoshi Sawada, Satoshi Kojima
  • Publication number: 20090142690
    Abstract: A method of manufacturing a toner including forming a wax liquid dispersion in which a wax is dispersed in an organic solvent (A1), mixing an organic layer including the wax liquid dispersion, a binder resin and an organic solvent (A) to form an oil phase and dispersing and emulsifying the oil phase in an aqueous medium to obtain an emulsified liquid dispersion, wherein the aspect ratio average of the wax in the wax liquid dispersion is from 0.3 to 0.7 and the toner includes toner particles satisfying the following relationship (1) in an amount of 20% by number or smaller based on all toner particles: 0.5<D2/D1, relationship (1), where D1 represents the major diameter (D1) of the toner and D2 represents the major diameter of the wax.
    Type: Application
    Filed: November 28, 2008
    Publication date: June 4, 2009
    Inventors: Junichi AWAMURA, Akinori Saitoh, Masahide Yamada, Osamu Uchinokura, Tomomi Suzuki
  • Publication number: 20090142682
    Abstract: A toner including a binder resin, a coloring agent, a releasing agent and a modified laminar inorganic mineral, wherein the toner is granulated by dispersing the coloring agent, the releasing agent, the modified laminar inorganic mineral and at least one of the binder resin and a precursor thereof in an organic solvent to form an oil phase, dispersing the oil phase in an aqueous medium to obtain a dispersion emulsion and removing solvents therefrom, and the toner satisfies the following relationship (1): 0.2?{1/Dv (?m)}×Sb (m2/g)?1.4, where Dv represents a volume average particle diameter of the toner, and Sb represents a BET specific surface area of the toner.
    Type: Application
    Filed: December 1, 2008
    Publication date: June 4, 2009
    Inventors: Akinori Saitoh, Osamu Uchinokura, Masahide Yamada, Tomomi Suzuki, Junichi Awamura
  • Publication number: 20090136864
    Abstract: It is intended to provide a method includes the step of forming agglomerated particles by agglomerating fine particulate mixture containing a binder resin and a colorant. In the step of forming agglomerated particles, a cationic organic coagulating agent having an average molecular weight of from 1000 to 100000 is added to a liquid dispersion containing fine particles.
    Type: Application
    Filed: October 2, 2008
    Publication date: May 28, 2009
    Applicants: KABUSHIKI KAISHA TOSHIBA, TOSHIBA TEC KABUSHIKI KAISHA
    Inventors: Tsuyoshi Itou, Takayasu Aoki, Takashi Urabe, Motonari Udo, Yasuhito Noda, Satoshi Araki, Masahiro Ikuta, Takafumi Hara
  • Publication number: 20090130585
    Abstract: A coarse particle containing a polyester based resin and a coloring agent is added in an aqueous medium containing a surfactant, a basic substance and an inorganic water-soluble electrolyte, and dispersion and coagulation are carried out to form a toner particle.
    Type: Application
    Filed: November 6, 2008
    Publication date: May 21, 2009
    Applicants: KABUSHIKI KAISHA TOSHIBA, TOSHIBA TEC KABUSHIKI KAISHA
    Inventors: Takayasu Aoki, Takashi Urabe, Takafumi Hara, Tsuyoshi Itou, Masahiro Ikuta, Motonari Udo, Yasuhito Noda, Satoshi Araki, Asumi Matsumoto