Diffusion Transfer Process, Element, Or Identified Image Receiving Layers Therefor Patents (Class 430/202)
  • Patent number: 4362806
    Abstract: Photographic elements, multicolor filters and receivers are disclosed having supports providing microvessels for materials such as radiation-sensitive materials, imaging materials, mordants, silver precipitating agents and materials which are useful in conjunction with these materials. Processes of forming microvessels and introducing materials therein are also disclosed. Processes of forming images are disclosed employing microvessel containing elements. Image transfer processes are disclosed for producing one or a combination of silver and multicolor subtractive primary images alone or in combination with multicolor additive primary images.
    Type: Grant
    Filed: September 8, 1980
    Date of Patent: December 7, 1982
    Assignee: Eastman Kodak Company
    Inventor: Keith E. Whitmore
  • Patent number: 4334005
    Abstract: A radiation-sensitive element is disclosed including a radiation-sensitive layer comprised of a cobalt(III)complex and a photoreductant. A process is disclosed in which the photoreductant is converted to a reducing agent by exposure to electromagnetic radiation longer than 300 nanometers. The reducing agent is then reacted with a cobalt(III)complex. Images can be recorded directly within the radiation-sensitive layer or in a separate image-recording element or layer by use of the residual cobalt(III)complex not exposed or one or more of the reaction products produced by exposure. By using the ammonia liberated from ammine ligand containing cobalt(III)complexes on exposure in combination with imagewise and uniform exposures, positive or negative images can be formed in diazo image-recording layers or elements associated with the radiation-sensitive layer. By the selection of amine-responsive reducing agent precursors, the amines released by the cobalt(III)complexes cause an amplified image.
    Type: Grant
    Filed: March 15, 1979
    Date of Patent: June 8, 1982
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, James C. Fleming
  • Patent number: 4328301
    Abstract: A photographic assembly for the photographic diffusion transfer process is provided wherein a stripping layer is used consisting of a graft copolymer of gelatin which has been substantially fully reacted with a dicarboxylic acid anhydride selected from phthalic anhydrides, succinic anhydrides, glutaric anhydrides and a monomer of a vinyl ester, a vinyl ether, an acrylic ester, an acrylic ether, a methacrylic ester or a methacrylic ether or a mixture thereof. These stripping layers exhibit good dry adhesion to the emulsion layer and to the mordant layer and moderate wet adhesion.
    Type: Grant
    Filed: September 18, 1980
    Date of Patent: May 4, 1982
    Assignee: Ciba-Geigy AG
    Inventor: Peter J. Wright
  • Patent number: 4324852
    Abstract: A radiation-sensitive element is disclosed including a radiation-sensitive layer comprised of a cobalt(III)complex and a photoreductant. A process is disclosed in which the photoreductant is converted to a reducing agent by exposure to electromagnetic radiation longer than 300 nanometers. The reducing agent is then reacted with a cobalt(III)complex. Images can be recorded directly within the radiation-sensitive layer or in a separate image-recording element or layer by use of the residual cobalt(III)complex not exposed or one or more of the reaction products produced by exposure. By using the ammonia liberated from ammine ligand containing cobalt(III)complexes on exposure in combination with imagewise and uniform exposures, positive or negative images can be formed in diazo image-recording layers or elements associated with the radiation-sensitive layer.
    Type: Grant
    Filed: June 7, 1979
    Date of Patent: April 13, 1982
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, James C. Fleming
  • Patent number: 4314019
    Abstract: A radiation-sensitive element is disclosed including a radiation-sensitive layer comprised of a cobalt(III)complex and a photoreductant. A process is disclosed in which the photoreductant is converted to a reducing agent by exposure to electromagnetic radiation longer than 300 nanometers. The reducing agent is then reacted with a cobalt(III)complex. Images can be recorded directly within the radiation-sensitive layer or in a separate image-recording element or layer by use of the residual cobalt(III)complex not exposed or one or more of the reaction products produced by exposure. By using the ammonia liberated from ammine ligand containing cobalt(III)complexes on exposure in combination with imagewise and uniform exposures, positive or negative images can be formed in diazo image-recording layers or elements associated with the radiation-sensitive layer. By the selection of amine-responsive reducing agent precursors, the amines released by the cobalt(III)complexes cause an amplified image.
    Type: Grant
    Filed: August 2, 1979
    Date of Patent: February 2, 1982
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, James C. Fleming
  • Patent number: 4291113
    Abstract: A method for dispersing an oil-soluble photographic additive into water or a hydrophilic colloid composition wherein an oil-soluble photographic additive is dispersed in water or a hydrophilic colloid composition in the presence of a polymer having a recurring unit represented by the following formula (I):--(A).sub.x -- --(B).sub.y -- (I)wherein A represents an ethylenically unsaturated monomer containing a sulfonic acid group; B represents a copolymerizable ethylenically unsaturated monomer; x is about 10 to 100 mol%; and y is about 0 to 90 mol%.
    Type: Grant
    Filed: February 21, 1980
    Date of Patent: September 22, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Junji Minamizono, Masakazu Yoneyama, Jun Sasaki
  • Patent number: 4287290
    Abstract: A novel process for producing a polymeric image, which comprises the steps of:(1) treating an image-wise light-exposed layer of a photographic silver halide emulsion with a treating solution having a reducing capacity, said treating solution having a capacity for initiating the polymerization of an addition-polymerizable unsaturated compound and a capacity for reducing the silver halide into metallic silver and having a property that it loses said capacity for initiating the polymerization once it is used for the reduction of the silver halide;(2) transferring or diffusing said treating solution from the silver halide emulsion layer into a layer of an addition-polymerizable material, providing polymerized portions and unpolymerized portions; and(3) removing the unpolymerized portions.
    Type: Grant
    Filed: March 31, 1980
    Date of Patent: September 1, 1981
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Masayoshi Mizuno, Hiroyuki Tsuchiya
  • Patent number: 4247615
    Abstract: There is disclosed a composition and element, comprising a diazo resin and a mordant for anionic dyes that is compatible with the resin. The element of the invention is suitable for dye immersion and dye transfer to a mordanted receiver.
    Type: Grant
    Filed: March 6, 1980
    Date of Patent: January 27, 1981
    Assignee: Eastman Kodak Company
    Inventors: Hugh G. McGuckin, Hyman L. Cohen
  • Patent number: 4243738
    Abstract: A process for amplifying an imagewise exposure of a silver halide photographic element comprises the steps of (a) developing the element to release spectral sensitizing dye from a release compound as a function of silver halide development; (b) adsorbing the spectral sensitizing dye to undeveloped silver halide grains; (c) exposing the element overall to radiation absorbable by released spectral sensitizing dye to render developable silver halide grains to which the released spectral sensitizing dye has been adsorbed and (d) developing silver halide grains.
    Type: Grant
    Filed: May 2, 1979
    Date of Patent: January 6, 1981
    Assignee: Eastman Kodak Company
    Inventors: Paul B. Gilman, Jr., Jan R. Haase
  • Patent number: 4239846
    Abstract: Disclosed are tellurium (IV) compounds represented by the formula: ##STR1## wherein: D is a Lewis base function containing a group VA or VIA donor atom;Q represents the atoms necessary to complete a 5- or 6-membered ring, when taken together with C, D and Te, when m is 1 and represents the atoms linking C and D when m is greater than 1;R.sub.1 and R.sub.2 are independently selected from the group consisting of hydrogen, alkyl and aryl;X is an anion;n is 1 or 2; andm is an integer from 1 to 500.These compounds are useful in an image-forming combination comprising the described Te(IV) compound and a reducing agent. The image-forming combination is useful in a variety of materials, including a dry amplification element.
    Type: Grant
    Filed: April 10, 1978
    Date of Patent: December 16, 1980
    Assignee: Eastman Kodak Company
    Inventors: Henry J. Gysling, Sylvia A. Gardner
  • Patent number: 4220700
    Abstract: There is disclosed a composition and element, comprising a diazo resin and a mordant for anionic dyes that is compatible with the resin. The element of the invention is suitable for dye immersion and dye transfer to a mordanted receiver.
    Type: Grant
    Filed: February 3, 1978
    Date of Patent: September 2, 1980
    Assignee: Eastman Kodak Company
    Inventors: Hugh G. McGuckin, Hyman L. Cohen
  • Patent number: 4218368
    Abstract: Aromatic nitro compounds are disclosed where the aromatic ring contains electron-withdrawing groups and said aromatic nitro compound is capable of undergoing intramolecular nucleophilic displacement after reduction of the nitro group. The compounds are especially useful in photographic elements where an image dye-providing material or a photographic reagent are released upon cleavage from the compound.
    Type: Grant
    Filed: July 26, 1978
    Date of Patent: August 19, 1980
    Assignee: Eastman Kodak Company
    Inventors: Jerald C. Hinshaw, Richard P. Henzel
  • Patent number: 4217242
    Abstract: Provided is a process for preparing an improved gum formulation useful for preventing oxidation in exposed and developed lithographic printing plates. The gum so produced exhibits reduced foaming and air entrapment properties.
    Type: Grant
    Filed: July 3, 1978
    Date of Patent: August 12, 1980
    Assignee: Polychrome Corporation
    Inventor: Cromwell D. Mukai
  • Patent number: 4210450
    Abstract: Photosensitive silver halide emulsions are prepared by alternating precipitation of silver halide and the addition of a water-soluble iodide salt which replaces a portion of the less soluble halide.
    Type: Grant
    Filed: November 20, 1978
    Date of Patent: July 1, 1980
    Assignee: Polaroid Corporation
    Inventor: Leo D. Corben
  • Patent number: 4204993
    Abstract: Photographic elements, diffusion transfer assemblages and processes are described which employ a novel nondiffusible compound having a releasable 6-arylazo-2-amino-3-pyridinol dye moiety or precursor thereof. The compound contains in the ortho position of the arylazo moiety a ballasted carrier moiety attached thereto either through a sulfonamido linking group or through the oxygen of a ##STR1## which said ballasted carrier moiety contains, the ballasted carrier moiety being capable of releasing the diffusible 6-arylazo-2-amino-3-pyridinol dye or precursor thereof under alkaline conditions. The dye is transferred imagewise to an image-receiving layer, where it is contacted with metal ions to form a metal-complexed 6-arylazo-2-amino-3-pyridinol dye transfer image of excellent stability.
    Type: Grant
    Filed: January 16, 1979
    Date of Patent: May 27, 1980
    Assignee: Eastman Kodak Company
    Inventor: Derek D. Chapman
  • Patent number: 4199354
    Abstract: Photographic elements, processes for forming images in photographic elements and new compounds are disclosed. Generally, the invention relates to immobile compounds which can be used to provide positive images from negative recording-developing photographic materials such as negative silver halide emulsions. The compounds contain a photographically useful group such as a dye or dye precursor and are capable of releasing said photographically useful group under alkaline conditions, and are also capable of reaction with an oxidized silver halide developing agent before substantial release of said photographically useful group occurs, to provide a reaction product having a substantially lower rate of release of said photograhically useful group.
    Type: Grant
    Filed: December 20, 1974
    Date of Patent: April 22, 1980
    Assignee: Eastman Kodak Company
    Inventors: Jerald C. Hinshaw, Paul B. Condit
  • Patent number: 4199355
    Abstract: Photographic elements, processes for forming images in photographic elements and new compounds are disclosed. Generally, the invention relates to improved immobile compounds which can be used to provide positive images from negative recording-developing photographic materials such as negative silver halide emulsions. The compounds contain a photographically useful group such as a dye or dye precursor and are capable of releasing said photographically useful group under alkaline conditions, and are also capable of reaction with an oxidized silver halide developing agent before substantial release of said photographically useful group occurs, to provide a reaction product having a substantially lower rate of release of said photographically useful group.
    Type: Grant
    Filed: June 24, 1975
    Date of Patent: April 22, 1980
    Assignee: Eastman Kodak Company
    Inventors: Jerald C. Hinshaw, Paul B. Condit
  • Patent number: 4187108
    Abstract: In a heat developable photographic material and process for providing a dye enhanced silver image, an element comprising a support having thereon in reactive association: (A) at least one heat developable photographic layer comprising (i) photosensitive silver halide, (ii) at least one active silver halide developing agent, (iii) an activating concentration of a development activator precursor, and (iv) a polymeric binder and (B) at least one layer comprising an azoaniline dye that is bleached in the non-image areas of the described element upon development of a latent image in the layer (A) by uniformly heating, can provide an improved image. After imagewise exposure of the described heat developable material, a dye enhanced silver image can be provided by heating the element containing the described combination of layers and materials.
    Type: Grant
    Filed: June 5, 1978
    Date of Patent: February 5, 1980
    Assignee: Eastman Kodak Company
    Inventor: Roland G. Willis