Silver Compound Sensitizer Containing Patents (Class 430/564)
  • Patent number: 4357419
    Abstract: A silver-halide/gelatin light-sensitive emulsion containing a saturated cyclic oxime compound, and optionally containing a di- or trimethylol lower alkane compound is disclosed. The light-sensitive emulsion coated on a substrate is particularly useful as a radiographic film.
    Type: Grant
    Filed: April 2, 1981
    Date of Patent: November 2, 1982
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Peter D. Sills
  • Patent number: 4357392
    Abstract: Photographic assemblages, elements, receiving elements and cover sheets comprise a combination of two timing layers and a neutralizing layer. The outermost timing layer contains photographic addenda, such as development inhibitors, for substantially terminating development of the silver halide emulsion. The timing layer next to the neutralizing layer has a much longer breakdown time so that it is permeated by the alkaline processing composition only after silver halide development has been substantially terminated.
    Type: Grant
    Filed: October 2, 1981
    Date of Patent: November 2, 1982
    Assignee: Eastman Kodak Company
    Inventors: Kenneth J. Reed, Patrick H. Saturno, Gerald L. Ducharme
  • Patent number: 4355092
    Abstract: There are disclosed novel compounds which are represented by the formula ##STR1## wherein X represents the nonmetallic atoms necessary to form a nucleus which completes a 5- or 6-membered heterocyclic moiety, R is H, an alkali metal or a group which is cleavable in aqueous alkaline medium and Z is H, alkyl having from 1 to 10 carbon atoms, aralkyl such as benzyl or phenethyl, phenyl or substituted phenyl. The compounds are useful in photographic applications.
    Type: Grant
    Filed: January 5, 1981
    Date of Patent: October 19, 1982
    Assignee: Polaroid Corporation
    Inventors: Avinash C. Mehta, George H. Nawn, Lloyd D. Taylor
  • Patent number: 4355101
    Abstract: Novel compounds which are represented by the formula ##STR1## wherein X represents the nonmetallic atoms necessary to form a nucleus which completes a 5- or 6-membered heterocyclic moiety, R is a group which is cleavable in aqueous alkaline medium and R.sub.1 is either a group which has a pKa of from about 7 to about 14 which is ionizable to an anion and wherein the silver salt of the mercaptan resulting from cleavage of -SR is rendered more soluble in the pH range within which R.sub.1 is ionized to an anion than it is below that pH range or a precursor of such a group. The compounds are useful in photographic applications.
    Type: Grant
    Filed: January 5, 1981
    Date of Patent: October 19, 1982
    Assignee: Polaroid Corporation
    Inventors: Avinash C. Mehta, George H. Nawn, Lloyd D. Taylor
  • Patent number: 4353977
    Abstract: A photosensitive silver halide element comprising a support carrying photosensitive silver halide grains in a predetermined spaced array is prepared by a method which comprises at least partially coalescing fine-grain silver halide in a plurality of spaced depressions in a hydrophobic layer, superposing said layer with a hydrophilic layer during or subsequent to said coalescence, and then separating said hydrophilic layer and said hydrophobic layer whereby said coalesced silver halide grains are retained on said hydrophilic layer in a pattern corresponding substantially to the pattern of said spaced depressions.
    Type: Grant
    Filed: September 2, 1981
    Date of Patent: October 12, 1982
    Assignee: Polaroid Corporation
    Inventors: Arthur M. Gerber, Warren D. Slafer, Vivian K. Walworth
  • Patent number: 4352874
    Abstract: A fine-grain emulsion in a plurality of predetermined spaced depressions is coalesced to form, in situ, a plurality of single effective silver halide grains in a predetermined spaced array by the action of a solution of a silver halide solvent containing a dissolved silver salt.
    Type: Grant
    Filed: September 2, 1981
    Date of Patent: October 5, 1982
    Assignee: Polaroid Corporation
    Inventors: Edwin H. Land, Vivian K. Walworth
  • Patent number: 4350758
    Abstract: A photographic emulsion containing composite crystals of (a) silver halide and (b) copper halide or a solid solution crystal of copper halide and silver halide is found to be sufficiently photosensitive and developable. In such a photographic emulsion, the amount of silver used can significantly be decreased.
    Type: Grant
    Filed: November 3, 1980
    Date of Patent: September 21, 1982
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Takeo Koitabashi, Syozi Matsuzaka, Toshifumi Iijima, Tetsuya Harada
  • Patent number: 4350754
    Abstract: There are described novel compounds which are represented by the formula ##STR1## wherein R is ##STR2## A is sulfur or selenium; X represents the nonmetallic atoms necessary to form a nucleus which completes a five or six membered heterocyclic moiety; R.sub.1 is H or lower alkyl; R.sub.2 is H or a hydrolyzable group; and R.sub.3 is H, alkyl or a hydrolyzable group. The compounds are useful in photographic applications and provide controlled release of a photographically useful material during processing of photographic elements with an aqueous alkaline processing composition.
    Type: Grant
    Filed: June 12, 1981
    Date of Patent: September 21, 1982
    Assignee: Polaroid Corporation
    Inventors: James R. Bartels-Keith, Anthony J. Puttick
  • Patent number: 4347309
    Abstract: A photosensitive material in the form of a silver and chlorine-containing polyphosphate which exhibits permanent visible darkening on exposure to ultraviolet or short wavelength visible light, is described.
    Type: Grant
    Filed: February 25, 1981
    Date of Patent: August 31, 1982
    Assignee: Corning Glass Works
    Inventor: Che-Kuang Wu
  • Patent number: 4343887
    Abstract: Fabrication of a resist, useful for high resolution pattern delineation and having a silver containing layer on a glassy material, produces better results when the sensitizing bath contains both potassium silver cyanide and a metal cyanide complex capable of providing CN.sup.- ions to shift the equilibrium of Ag(CN).sub.2.sup.- .revreaction.AgCN+CN.sup.- to the left.
    Type: Grant
    Filed: May 14, 1981
    Date of Patent: August 10, 1982
    Assignee: Bell Telephone Laboratories, Incorporated
    Inventors: Adam Heller, Richard G. Vadimsky
  • Patent number: 4340665
    Abstract: Spots due to iron contamination in developed silver halide films are reduced in number by incorporating therein a phosphate and trisodium hydroxyethylethylenediaminetriacetate.
    Type: Grant
    Filed: March 4, 1981
    Date of Patent: July 20, 1982
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Lloyd G. Sidwell
  • Patent number: 4335199
    Abstract: High contrast photographic images suitable for lithographic use are obtained with stable (nonlithographic) developers when iodide is released from a surface-sensitized iodobromide emulsion to induce development of the exposed areas in an internally sensitized core-shell emulsion. A bromoiodide or trihalide core is produced by balanced double jet precipitation, then the core is chemically sensitized and covered with a chlorobromide or chloride shell by balanced double jet precipitation or preferably by a cyclic pAg addition technique. The core-shell emulsion must have a sensitivity equal to or greater than the surface sensitized emulsion.
    Type: Grant
    Filed: February 19, 1980
    Date of Patent: June 15, 1982
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: daniel J. Mickewich, John R. Shock, Daniel F. Juers
  • Patent number: 4330604
    Abstract: An improved process is provided for attaching layers of hydrophilic, photosensitive materials onto hydrophobic plastic substrates, which comprises forming a layer of a polycrystalline, optically transparent, moisture barrier material on the substrate, followed by depositing thereon a layer of a hydrophilic, polar material, prior to depositing the photosensitive layer thereon. The process is especially suitable for the fabrication of pre-holographic elements and holograms. Holograms are fabricated by exposing and developing latent images in the photosensitive layer of pre-holographic elements and attaching to the photosensitive layer by an optical adhesive a protective cover layer comprising a plastic substrate coated with the moisture barrier material and the hydrophilic material. Additional moisture barrier protection may optionally be provided by forming a combination of moisture barrier layers and hydrophilic layers on the outer surfaces of the plastic substrates.
    Type: Grant
    Filed: August 4, 1980
    Date of Patent: May 18, 1982
    Assignee: Hughes Aircraft Company
    Inventors: John E. Wreede, Andrejs Graube, Mark A. Mulvihill
  • Patent number: 4323645
    Abstract: Small amounts of specific organic halogen compounds added to medical X-ray emulsions (ex. 2-chloro-4-nitrobenzyl chloride, 2,2,2-trichloroethanol and m-nitrobenzyl chloride) give significantly reduced fog levels accompanied by little or no speed loss.
    Type: Grant
    Filed: August 1, 1980
    Date of Patent: April 6, 1982
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Laurence W. Hall, Joseph D. Overman
  • Patent number: 4323643
    Abstract: A silver halide photographic light-sensitive material is described, comprising at least one silver halide photographic emulsion layer, wherein at least one layer contains a compound represented by formula (I) ##STR1## wherein R.sup.1 and R.sup.2 each represents hydrogen, an aliphatic group, an aromatic group, or a heterocyclic group;R.sup.3 represents hydrogen or an aliphatic group, andX represents a divalent aromatic group.The light-sensitive material provides high-contrast negative images and good dot image quality.
    Type: Grant
    Filed: November 6, 1980
    Date of Patent: April 6, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shigeo Hirano, Yoshitaka Akimura
  • Patent number: 4318979
    Abstract: A light-sensitive silver halide photographic material comprising a combination of a salt of tetrazolium containing only a non-metallic anion and a salt of tetrazolium containing a metallic anion.
    Type: Grant
    Filed: December 10, 1980
    Date of Patent: March 9, 1982
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Takeshi Habu, Chika Honda
  • Patent number: 4315072
    Abstract: Artificial gelatins containing higher proportions of methionine than are found in natural gelatin are made by thermal polymerization of methionine with various proportions of other .alpha.-amino acids, including some proportion of aspartic acid, glutamic acid or lysine. Artificial gelatins containing as much as 40 mole percent methionine can be obtained. Proportions in the polymer can be adjusted by control of proportions in the reaction mixture. Photographic silver halide emulsions containing these artificial gelatins and photographic films employing the emulsions are also disclosed.
    Type: Grant
    Filed: March 11, 1980
    Date of Patent: February 9, 1982
    Assignee: Polymicro
    Inventors: Sidney W. Fox, Arthur I. Holden
  • Patent number: 4314020
    Abstract: Photographic assemblages, elements, receiving elements and cover sheets comprise a combination of two timing layers and a neutralizing layer. The outermost timing layer contains photographic addenda, such as development inhibitors, for substantially terminating development of the silver halide emulsion. The timing layer next to the neutralizing layer has a much longer breakdown time so that it is permeated by the alkaline processing composition only after silver halide development has been substantially terminated.
    Type: Grant
    Filed: August 4, 1980
    Date of Patent: February 2, 1982
    Assignee: Eastman Kodak Company
    Inventors: Kenneth J. Reed, Patrick H. Saturno, Gerald L. Ducharme
  • Patent number: 4314024
    Abstract: Photographic silver halide emulsions are stabilized by aminocarboxylic acids.
    Type: Grant
    Filed: July 30, 1980
    Date of Patent: February 2, 1982
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventor: Herbert Gernert
  • Patent number: 4301243
    Abstract: Traces of free inhibitors for the development of silver halide which might be present as impurities of inhibitor releasing compounds or which might be prematurely released therefrom because of insufficient stability thereof during storage of the photographic material are scavenged by compounds which are capable of binding free inhibitors at pH values below 7 but to a much less extent at pH values higher than 9.
    Type: Grant
    Filed: December 12, 1979
    Date of Patent: November 17, 1981
    Assignee: AGFA-Gevaert Aktiengesellschaft
    Inventors: Walter Puschel, Heinrich Odenwalder, Erwin Ranz
  • Patent number: 4301238
    Abstract: An improved method of producing a silver halide photographic material having a layer containing gelatin coated on a support is disclosed. The coated layer is dried so that its surface temperature during the falling rate drying period is more than 5.degree. C. over the melting point of the layer during drying and the jelly strength of the gelatin is at least 200 g according to the PAGI method.
    Type: Grant
    Filed: July 21, 1980
    Date of Patent: November 17, 1981
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Sadayuki Miyazawa, Takashi Kadowaki, Isao Yamamoto
  • Patent number: 4292400
    Abstract: Photographic elements containing image-wise developable silver halide are developed in the presence of an oxathioether development activator according to the formula:R.sup.1 --A--(OCH.sub.2 CH.sub.2).sub.n --S--A'--(X--A").sub.m --Y--R.sup.2wherein:R.sup.1 is H, alkyl, hydroxyalkyl, or R.sup.2 --Y--(A"--X).sub.m --A'--S--,A, A', and A" is alkylene, with the proviso that A is a monovalent bond when R.sup.1 is hydrogen or alkyl or hydroxyalkyl,X is --OCO--, --SO.sub.2 --, --CONH--, or Y,Y is ligand or complexing function of the type of --S-- and --N(Q)-- (Q=H or alkyl),R.sup.2 is alkyl, which may be substituted by OH, or when Y is --N(Q)--, R.sup.2 together with Q may represent the atoms needed to complete a nitrogen-containing saturated ring,n is at least 2, and m is 0 or 1.The development activators can be used in black-and-white development or in color development. They can be incorporated in the photographic material or in the developing solution.
    Type: Grant
    Filed: September 10, 1980
    Date of Patent: September 29, 1981
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Robert J. Pollet, Francis J. Sels, Karel A. Brems, Maurice A. de Ramaix
  • Patent number: 4279987
    Abstract: This invention relates to a light-sensitive, direct positive silver halide photographic material, more particularly to a light-sensitive silver halide photographic material of internal latent image type containing a novel, development-accelerating compound, as used for the formation of a direct positive image by imagewise exposure followed by overall light-exposure before and/or during development or development treatment in the presence of a fogging agent.
    Type: Grant
    Filed: November 13, 1979
    Date of Patent: July 21, 1981
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Keiji Ogi, Takashi Sasaki, Yasuo Tosaka
  • Patent number: 4279990
    Abstract: Discoloring and fading of silver halide color photographic materials are effectively prevented by incorporating a compound of the formula (I) or (II) in a silver halide photographic layer thereof ##STR1## wherein A represents an aryl group; R.sub.1, R.sub.2 and R.sub.3 each represents hydrogen, a halogen atom, an alkyl group, or an aryl group, except that R.sub.1, R.sub.2 and R.sub.3 cannot all be hydrogen atoms; R.sub.4 and R.sub.5 each represents hydrogen, a halogen atom, an alkyl group, an aryl group, an alkoxy group, an alkylthio group, an acyl group, an aryloxy group, a carboxy group, a sulfo group or a hydroxy group; and R.sub.6 and R.sub.7 each represents hydrogen, a halogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an acyl group, or a hydroxy group; or R.sub.6 and R.sub.7 together form an ##STR2## group or a 5-membered or 6-membered carbocyclic or heterocyclic ring.
    Type: Grant
    Filed: September 10, 1980
    Date of Patent: July 21, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Aoki, Nobuo Furutachi, Satoru Sawada
  • Patent number: 4278757
    Abstract: A silver halide photographic light-sensitive material having a hydrophilic organic colloid layer containing a dispersion of a substantially water-insoluble photographic additive dissolved in a phosphoric acid ester represented by the following general formula (I): ##STR1## wherein R.sub.1 represents a saturated alicyclic group; and R.sub.2 and R.sub.3, which may be the same or different, each represents a saturated alicyclic group, an alkyl group or an aryl group.
    Type: Grant
    Filed: August 10, 1979
    Date of Patent: July 14, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuo Mukunoki, Masakazu Yoneyama, Jiro Yamaguchi, Hideki Naito, Jun Sasaki
  • Patent number: 4275141
    Abstract: An ultraviolet-sensitive optical information recording material comprising doped silver chloride and tin oxide which exhibits high ultraviolet darkening sensitivity and good resistance to darkening or bleaching by visible light, and a method for optically recording information in permanent, optically-readable form in such a material by direct writing without chemical development, are described.
    Type: Grant
    Filed: October 22, 1979
    Date of Patent: June 23, 1981
    Assignee: Corning Glass Works
    Inventors: Nicholas F. Borrelli, Peter L. Young
  • Patent number: 4272614
    Abstract: A silver halide photographic light-sensitive material having at least one silver halide photographic emulsion layer comprising substantially surface latent image type silver halide grains, and containing in said photographic emulsion layer or at least one of other hydrophilic colloid layers a compound represented by the following general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom, an aliphatic group which may be substituted or an aromatic group which may be substituted; Ar represents a divalent aromatic group which may be substituted; Y represents a divalent linking group; n represents 0 or 1; R.sup.2 represents a hydrogen atom, an aliphatic group which may be substituted or an aromatic group which may be substituted; and Z represents a nonmetallic atomic group necessary to form a 5-membered or 6-membered heterocyclic ring together with the ##STR2## linkage.
    Type: Grant
    Filed: December 20, 1979
    Date of Patent: June 9, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shigeo Hirano
  • Patent number: 4269935
    Abstract: A layer of a chalcogenide glass resist material, on a substrate on which a microlithographic pattern is to be formed, has a deposit of silver halide on its outer surface. By actinic irradiation a latent silver image replicating the desired pattern is formed in the silver halide deposit. This image is developed to a metallic silver, which is used to photodope the resist material for subsequent etching to produce the microlithographic pattern on the substrate. Positive and negative patterns are possible from the same starting laminate. One form of a microlithographic pattern is a mask for producing electronic circuits.
    Type: Grant
    Filed: October 17, 1979
    Date of Patent: May 26, 1981
    Assignee: Ionomet Company, Inc.
    Inventors: Joseph I. Masters, Gershon M. Goldberg
  • Patent number: 4268627
    Abstract: A photographic light-sensitive material is described comprising at least one hydrophilic colloidal layer containing a hardener and further containing as an acid-captor at least one compound represented by formula (I) or (II): ##STR1## wherein R.sub.1 represents hydrogen, a lower alkyl group containing 5 or less carbon atoms, an alkoxy group containing 5 or less carbon atoms, or a halogen atom, and R.sub.2 and R.sub.3 each independently represents hydrogen, an alkyl group containing 10 or less carbon atoms, an aryl group containing from 6 to 12 carbon atoms, or an alkoxycarbonyl group containing 5 or less carbon atoms.
    Type: Grant
    Filed: June 13, 1980
    Date of Patent: May 19, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hidefumi Sera, Katuzi Kitatani, Masasi Ogawa, Kunio Ishigaki, Hisashi Shiraishi
  • Patent number: 4268621
    Abstract: A light-sensitive silver halide photographic material of internal latent image type for use in the formation of a direct positive image containing a compound of the following general formula (I) or (II):General formula (I) ##STR1## General formula (II) ##STR2## The photographic material can be developed after a shortened induction period, can yield good positive images that are free from stain when undergoing fogging development, and can yield good direct positive images with a high maximum density and a low minimum density. The photographic material forms a direct positive image when subjected, after imagewise exposure, to an overall light exposure or development in the presence of a fogging agent and can be developed by surface development.
    Type: Grant
    Filed: July 27, 1979
    Date of Patent: May 19, 1981
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Keiji Ogi, Takashi Sasaki, Kenichiro Okaniwa, Yasuo Tosaka
  • Patent number: 4268617
    Abstract: A silver halide color photographic light-sensitive material comprising a support and at least one silver halide emulsion layer, at least one of the layers of said photographic sensitive material containing at least one compound selected from the group consisting of those compounds represented by the formulae (I), (II), (III) and (IV):[Co(NH.sub.3).sub.6 ][R.sup.1 COO].sub.3 (I)[Co(NH.sub.3).sub.6 ][R.sup.2 OOCR.sup.3 COO].sub.3 (II)[Co(NH.sub.3).sub.5 (R.sup.4 COO)]X.sub.2 (III)[Co(NH.sub.3).sub.5 (R.sup.5 NH.sub.2)]X.sub.3 (IV)wherein R.sup.1, R.sup.2 and R.sup.4 each represent an alkyl group having at least 3 carbon atoms or a fluorine-substituted alkyl group having at least 1 carbon atom; R.sup.3 is an alkylene group; R.sup.5 is an alkyl group having at least 1 carbon atom; X is a halogen atom, a nitrate ion, a sulfate ion, or a carboxylate ion is disclosed.
    Type: Grant
    Filed: September 27, 1979
    Date of Patent: May 19, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akio Mitsui, Yoshiaki Suzuki
  • Patent number: 4264717
    Abstract: Compounds of the formula ##STR1## are useful in photographic materials and processes for the color development.
    Type: Grant
    Filed: October 17, 1979
    Date of Patent: April 28, 1981
    Assignee: AGFA-Gevaert, A.G.
    Inventors: Helmut Haseler, Fritz Nittel
  • Patent number: 4263393
    Abstract: Novel electron donor precursors have the structure: ##STR1## wherein: Z represents the atoms to complete a mono-, bi- or tricyclic ring system, each ring of which contains 5 to 6 nuclear atoms;n is 1 or 2;R.sup.1 is a monovalent aromatic group when n is 1 and a bivalent aromatic group when n is 2; andR.sup.2 represents hydrogen, an alkyl group, an aryl group, an acyl group, an ester group or an amido group.The compounds are useful in photographic elements, film units and processes to provide electrons to immobile compounds which must accept at least one electron before releasing a diffusible dye or photographic reagent.
    Type: Grant
    Filed: September 6, 1979
    Date of Patent: April 21, 1981
    Assignee: Eastman Kodak Company
    Inventor: Chin H. Chen
  • Patent number: 4259437
    Abstract: Development inhibitor releasing compounds of the formula ##STR1## are provided wherein R.sub.1 is hydrogen or a substituent which may contain a long chain ballasting group and n is 1 or 2, or R.sub.1 may form an annelated ring, R.sub.2 is hydrogen or alkyl having 1 to 4 carbon atoms, R.sub.3 is alkyl, aryl or aralkyl, Y is hydrogen, halogen, optionally substituted phenyl, --COOR.sub.4, --COR.sub.4, ##STR2## or --OR.sub.4 where R.sub.4 is alkyl or aryl or a group ##STR3## where Z represents the atoms necessary to complete an optionally substituted 5- or 6-membered heterocyclic ring which optionally may be benzannelated.The new DIR-compounds form colorless compounds when reacted with the oxidation products of the color developing agent. They have an extremely high reactivity with the oxidation products of the color developing agent so that only small quantities of the DIR-compounds are required to produce excellent intra-image and inter-image effects of excellent speed.
    Type: Grant
    Filed: September 5, 1979
    Date of Patent: March 31, 1981
    Assignee: Ciba-Geigy AG
    Inventor: Terence C. Webb
  • Patent number: 4252895
    Abstract: A photodevelopable silver halide photosensitive material wherein a visible image is formed by a latent image-forming step in which high illumination exposure is effected for a short time and a subsequent light development step in which low illumination exposure is effected, which comprises at least one compound of the formula: ##STR1## wherein R.sub.1 is hydrogen, lower alkyl or a substituted or unsubstituted aryl group and salts thereof.
    Type: Grant
    Filed: July 31, 1979
    Date of Patent: February 24, 1981
    Assignee: Oriental Photo Industrial Co., Ltd.
    Inventors: Masahiro Kato, Shoichiro Sumi, Shoji Iwata
  • Patent number: 4247620
    Abstract: A light-sensitive silver halide photographic material which comprises a compound represented by general formula [I] shown below:General formula [I] ##STR1## wherein A represents a phosphorus atom, a nitrogen atom or an arsenic atom; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represent a substituted or unsubstituted aryl group; X represents a persulfate ion, a chlorate ion, a bromate ion, an iodate ion or a metal complex anion; and n is an integer of 1 to 4,and a method for processing the same.
    Type: Grant
    Filed: June 18, 1979
    Date of Patent: January 27, 1981
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Toshio Nagatani, Kazuo Takahashi, Takeshi Habu
  • Patent number: 4246333
    Abstract: A photographic element having on a support at least one silver halide emulsion layer having associated therewith a development inhibitor precursor represented by the formula (I) ##STR1## wherein A is a phenyl group, a substituted phenyl group or a 5- or 6-membered nitrogen-containing heterocyclic ring; said A splitting together with the sulfur atom in the above molecule from the residue of the molecule to provide a silver halide development inhibitor; R.sup.1 is an alkyl group having 1 to 4 carbon atoms; and R.sup.2 is a cyano group, a carbamoyl group or the group represented by the formula ##STR2## wherein R.sup.3 is an aryl group.
    Type: Grant
    Filed: April 3, 1979
    Date of Patent: January 20, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshiharu Fuseya, Yukio Karino, Yoshio Sakakibara, Katsusuke Endo
  • Patent number: 4243739
    Abstract: A silver halide photographic light-sensitive material having at least one silver halide photographic emulsion layer comprising substantially surface latent image type silver halide grains, and containing in said photographic emulsion layer or at least one of other hydrophilic colloid layers a compound represented by the following general formula (I): ##STR1## wherein X.sup.1 represents a group containing a ##STR2## moiety, Ar.sup.1 and Ar.sup.2 each represents a substituted or unsubstituted aromatic group, B represents a divalent linking group, n is 0 or 1, and R.sup.1 represents a hydrogen atom, an unsubstituted alkyl group, or a substituted or unsubstituted aryl group.
    Type: Grant
    Filed: October 11, 1979
    Date of Patent: January 6, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shunji Takada, Yoshitaka Akimura, Shigeo Hirano
  • Patent number: 4234678
    Abstract: A photographic material having a light-sensitive silver halide emulsion layer coated on a support and containing a compound, useful as a development inhibitor of the formula: ##STR1## wherein X, Y and Z are as herein defined, is described.
    Type: Grant
    Filed: November 20, 1978
    Date of Patent: November 18, 1980
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shinji Yoshimoto, Mitsuto Fujiwhara, Shoji Kikuchi, Ryosuke Satoh, Takaya Endo, Satoshi Nakagawa
  • Patent number: 4233400
    Abstract: Light-sensitive silver halide photographic materials to be treated with a hydroquinones-containing developing solution which material comprises a support and at least one hydrophilic colloidal layer coated thereon containing silver halide grains having an average grain size of 0.05 to 1.5.mu. and a tetrazolium compound and a method of processing thereof.
    Type: Grant
    Filed: March 2, 1979
    Date of Patent: November 11, 1980
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Mitsuto Fujiwhara, Syunji Matsuo, Toyoaki Masukawa, Yutaka Kaneko, Mikio Kawasaki
  • Patent number: 4232107
    Abstract: Said material contains a quinone-type compound which corresponds to one of the formulae (A) or (B) and which is capable in reduced state and under alkaline conditions of releasing a photographically useful group e.g. a dye: ##STR1## wherein: each of (Nuox).sup.1 and (Nuox).sup.2 represents an oxidized nucleophilic group,Z represents a bivalent atomic group which is electronegative,Q together with the Z group represents a releasable photographically useful group,each of R.sup.1, R.sup.2 and R.sup.3 is hydrogen, halogen, alkyl, alkoxy, or an acylamino group or R.sup.1 and R.sup.2 in adjacent positions on the ring form a ring fused with the remainder of the molecule, or R.sup.2 and R.sup.3 together are fused with the remainder of the molecule.each of R.sup.4 and R.sup.5 represents hydrogen or a hydrocarbon group.At least one of the substituents R.sup.1, R.sup.2, R.sup.3, R.sup.4 or R.sup.5 is a ballasting group X.
    Type: Grant
    Filed: March 15, 1979
    Date of Patent: November 4, 1980
    Assignee: AGFA-GEVAERT N.V.
    Inventor: Wilhelmus Janssens
  • Patent number: 4230796
    Abstract: High speed litho film in which short-life development accelerators such as cysteine methyl ester and its analogues are incorporated into the silver halide emulsion layer.
    Type: Grant
    Filed: September 22, 1978
    Date of Patent: October 28, 1980
    Assignee: E. I. Du Pont De Nemours and Company
    Inventors: Herbert Gunther, Herbert Blank
  • Patent number: 4209328
    Abstract: In a dye image forming process in color photography comprising imagewise exposing a photographic element comprising a support and a light sensitive silver halide emulsion layer, and processing the exposed photographic element with an alkaline processing solution in the presence of a dye developer whereby a dye image corresponding to the imagewise exposure is formed by oxidation of said developer as a function of development of silver halide, the improvement which comprises the dye developer being a mono azo dye developer represented by the following formula:X--N.dbd.
    Type: Grant
    Filed: June 22, 1977
    Date of Patent: June 24, 1980
    Assignees: Konishiroku Photo Industry Co., Ltd., Mitsubishi Chemical Industries Limited
    Inventors: Yuzuru Sato, Ryuichiro Kobayashi, Naoshi Kunieda, Kazumasa Watanabe, Noboru Mizukura, Kenji Yoshida, Tadanori Oya
  • Patent number: 4204869
    Abstract: Silver-precipitating nuclei are prepared by partially oxidizing a stannous salt reducing agent and then reducing a noble metal salt or complex with said reducing agent.
    Type: Grant
    Filed: April 4, 1978
    Date of Patent: May 27, 1980
    Assignee: Polaroid Corporation
    Inventors: Charles H. Byers, Robert W. Hausslein, Mara O. Nestle
  • Patent number: 4203764
    Abstract: An image holding member for holding electrostatic latent images and/or toner images is characterized in that the surface of the image holding member has a surface layer formed by a coating, said surface layer essentially consisting of at least one of substances A and B wherein the substance A is a linear polyester resin soluble in organic solvents and the substance B is a copolymerization product of a linear isocyanate of the formula: ##STR1## and a polyol of the formula: HO--(CH.sub.2).sub.n --OH wherein n is a positive integer.
    Type: Grant
    Filed: December 15, 1978
    Date of Patent: May 20, 1980
    Assignee: Canon Kabushiki Kaisha
    Inventors: Umi Tosaka, Hideyo Kondo, Keiichi Murai, Hitoshi Toma
  • Patent number: 4201587
    Abstract: A .beta.-eliminating graft copolymer useful as a diffusion control layer in film units adapted for diffusion transfer processes is disclosed.
    Type: Grant
    Filed: September 15, 1978
    Date of Patent: May 6, 1980
    Assignee: Polaroid Corporation
    Inventors: Stanley F. Bedell, Charles I. Sullivan, Lloyd D. Taylor
  • Patent number: 4197124
    Abstract: A planographic printing plate material comprising a support and a light sensitive layer provided on the support, the light-sensitive layer being composed of (A) an inorganic material; (B) at least one metal and/or metal compound [(A)/(B) are capable of reacting with each other upon application of electromagnetic radiation] and (C) an organic compound capable of affecting the reaction between the inorganic material (A) and the metal and/or metal compound (B), wherein the inorganic material (A), the metal or metal compound (B), and the organic compound (C) are in contact with each other. When the light-sensitive layer is exposed to electromagnetic radiation, a difference in the hydrophilic or oleophilic nature of the exposed areas and the unexposed areas results, whereby a planographic printing plate is obtained which can be mounted on a printing machine and printed without any other treatments.
    Type: Grant
    Filed: February 6, 1978
    Date of Patent: April 8, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tomoaki Ikeda, Yuzo Mizobuchi, Fumiaki Shinozaki, Akira Nahara, Yoshihiro Ono, Yasuo Washizawa, Satoshi Yoshida, Takeshi Tomotsu
  • Patent number: 4193795
    Abstract: A photographic element comprising a support, a layer containing certain photographically useful and/or active fragments and a layer containing a dye mordant composition comprising a polymer having recurring units of the formula selected from the group consisting of: ##STR1## wherein: R.sup.2 is hydrogen or alkyl;R.sup.1 is hydrogen, alkyl or aryl;L is a linking group;W is an electron-withdrawing group;X is a leaving group; andn is 0 or 1.The polymeric mordants covalently bond with dyes or dye precursors and are especially useful in diffusion transfer processes.
    Type: Grant
    Filed: May 15, 1978
    Date of Patent: March 18, 1980
    Assignee: Eastman Kodak Company
    Inventors: Gerald A. Campbell, Hyman Cohen, Lewis R. Hamilton, George Villard
  • Patent number: 4175966
    Abstract: A light-sensitive silver halide photographic material containing a substantially non-diffusible compound having oxidation power on a hydroquinone developing agent in a hydrophilic colloidal layer is processed, after light exposure, with a developer containing the said hydroquinone developing agent to form a high-contrast silver image.
    Type: Grant
    Filed: October 4, 1978
    Date of Patent: November 27, 1979
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Mitsuto Fujiwhara, Syunji Matsuo, Toyoaki Masukawa, Yutaka Kaneko, Mikio Kawasaki