Sensitized Or Doped Patents (Class 430/95)
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Patent number: 4483911Abstract: A photoconductive member comprises a support and an amorphous layer comprising a first layer region and a second layer region, the first layer region having photoconductivity comprising an amorphous material which comprises silicon atoms as a matrix and at least one member selected from hydrogen atoms and halogen atoms as a constituent, the first layer region having a layer region (I) containing an impurity controlling the electroconductivity type at the support side, and the second layer region comprising an amorphous material comprising at least both silicon and carbon as constituents.Type: GrantFiled: December 17, 1982Date of Patent: November 20, 1984Assignee: Canon Kabushiki KaishaInventors: Kyosuke Ogawa, Shigeru Shirai, Junichiro Kanbe, Keishi Saitoh, Yoichi Osato
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Patent number: 4476209Abstract: An electrophotographic photoreceptor comprising a conductive layer and a photosensitive layer of vapor-deposited selenium-antimony alloy film formed thereon is disclosed. The photosensitive layer has an average antimony concentration of 5 to 21 wt % and the center layer thereof except for the skin layer on either side has a change in antimony concentration within 2 wt % in any region that is 1000 deep .ANG. from the surface of the skin layer.Type: GrantFiled: September 16, 1982Date of Patent: October 9, 1984Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Hiroyuki Moriguchi, Takeo Shimura, Tadashi Kaneko, Hiroyuki Nomori, Akira Nishiwaki
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Patent number: 4471042Abstract: An image-forming member for electrophotography has a photoconductive layer comprising a hydrogenated amorphous semiconductor composed of silicon and/or germanium as a matrix and at least one chemical modifier such as carbon, nitrogen and oxygen contained in the matrix.Type: GrantFiled: May 4, 1979Date of Patent: September 11, 1984Assignee: Canon Kabushiki KaishaInventors: Toshiyuki Komatsu, Yutaka Hirai, Katsumi Nakagawa, Tadaji Fukuda
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Patent number: 4468443Abstract: A process for producing a photoconductive member, which comprises forming a photoconductive layer on a substrate for formation of a photoconductive layer by introducing starting substances for formation of a photoconductive layer under gaseous state into a deposition chamber maintained under a desired reduced pressure and exciting discharging under the gas atmosphere of said starting substances is characterized in that said starting substances are constituted of at least one substance selected from the first group consisting of substances(O) containing oxygen atoms as constituent atom, substances(N) containing nitrogen atoms as constituent atom and substances(C) containing carbon atoms as constituent atom, and at least two compounds selected from the second group consisting of the compounds of the formula:Si.sub.n H.sub.2n+2 (A)wherein n is a positive integer and the compounds of the formula:Si.sub.m H.sub.l X.sub.Type: GrantFiled: March 4, 1982Date of Patent: August 28, 1984Assignee: Canon Kabushiki KaishaInventors: Isamu Shimizu, Kyosuke Ogawa, Eiichi Inoue, Junichiro Kanbe
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Patent number: 4465750Abstract: A photoconductive member comprises a support and an amorphous layer compsed of a first layer region composed of a photoconductive amorphous silicon containing p- or n-type impurity distributed nonuniformly and continuously in the layer thickness direction, and a second layer region composed of Si.sub.a C.sub.1-a (0.4<a<1), [Si.sub.b C.sub.1-b ].sub.c H.sub.1-c (0.5<b<1, 0.6.ltoreq.c<1), [Si.sub.d C.sub.1-d ].sub.e X.sub.1-e (0.47<d<1, 0.8.ltoreq.e<1, X: halogen) or [Si.sub.f C.sub.1-f ].sub.g (H+X).sub.1-g (0.47<f<1, 0.8.ltoreq.g<1, X: halogen].Type: GrantFiled: December 13, 1982Date of Patent: August 14, 1984Assignee: Canon Kabushiki KaishaInventors: Kyosuke Ogawa, Shigeru Shirai, Junichiro Kanbe, Keishi Saitoh, Yoichi Osato
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Patent number: 4464451Abstract: An electrophotographic image-forming member comprises a substrate for electrophotography and an amorphous layer which is laid on said substrate and constituted of silicon atoms as matrix containing at least one of hydrogen atom and halogen atom and exhibits photoconductivity, said substrate being constituted of aluminum oxide containing chemi-structurally water at least on the surface thereof, and said amorphous layer having a layer region containing at least one member selected from the group consisting of oxygen atom, nitrogen atom and carbon atom in at least a part thereof, the content of said member in said layer region being distributed unevenly in the direction of the thickness of said layer.Type: GrantFiled: January 29, 1982Date of Patent: August 7, 1984Assignee: Canon Kabushiki KaishaInventors: Shigeru Shirai, Junichiro Kanbe, Tadaji Fukuda
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Patent number: 4463279Abstract: A photoconductive film comprising a photo-conductive layer which is mainly made of selenium and a region added with tellurium in a direction of the thickness of the layer, wherein at least either one of a portion in a direction of hole flow of said region added with tellurium and a portion in the hole flow of another region which is located adjacent to said region added with tellurium is doped with at least one member selected from the group consisting of an oxide, a fluoride and elements which belong to the group II, III and VII, which are capable of forming a negative space charge in selenium, at a concentration in a range of 10 ppm to 1% by weight on an average. Typical examples of such oxide, fluoride and element include CuO, In.sub.2 O.sub.3, SeO.sub.2, V.sub.2 O.sub.5, MoO.sub.3, WO.sub.3, GaF.sub.2 InF.sub.3, Zn, Ga, In, Cl, I, Br and the like. The after image characteristic ascribable to incident light of high intensity can be significantly improved.Type: GrantFiled: May 21, 1982Date of Patent: July 31, 1984Assignees: Hitachi, Ltd., Nippon Hoso KyokaiInventors: Keiichi Shidara, Kenkichi Tanioka, Teruo Uchida, Chushirou Kusano, Yukio Takasaki, Yasuhiko Nonaka, Eisuke Inoue
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Patent number: 4461819Abstract: Image-forming member for electrophotography comprising a charge generation layer composed of hydrogenated amorphous silicon.Type: GrantFiled: June 3, 1981Date of Patent: July 24, 1984Assignee: Canon Kabushiki KaishaInventors: Katsumi Nakagawa, Toshiyuki Komatsu, Yutaka Hirai, Teruo Misumi, Tadaji Fukuda
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Amorphous silicon electrophotographic image-forming member having an aluminum oxide coated substrate
Patent number: 4461820Abstract: An electrophotographic image-forming member comprises (1) a substrate for electrophotography which has a surface coating of an aluminum oxide containing water chemi-structurally and (2) a photoconductive layer which is laid on said surface coating of the substrate and constituted of an amorphous material containing at least one of hydrogen atom and halogen atom in a matrix of silicon atom, said photoconductive layer containing at least one of oyxgen atom, nitrogen atom, and carbon atom.Type: GrantFiled: February 1, 1982Date of Patent: July 24, 1984Assignee: Canon Kabushiki KaishaInventors: Shigeru Shirai, Junichiro Kanbe, Tadaji Fukuda -
Patent number: 4460670Abstract: A photoconductive member comprises a support for a photoconductive member and an amorphous layer having photoconductivity constituted of an amorphous material comprising silicon atoms as a matrix, said amorphous layer having a first layer region containing at least one kind of atoms selected from the group consisting of oxygen atoms, carbon atoms and nitrogen atoms as constituent atoms in a distribution which is ununiform and continuous in the direction of layer thickness and a second layer region containing atoms of an element belonging to the group III of the periodic table as constituent atoms in a distribution which is ununiform and continuous in the direction of layer thickness.Type: GrantFiled: November 19, 1982Date of Patent: July 17, 1984Assignee: Canon Kabushiki KaishaInventors: Kyosuke Ogawa, Shigeru Shirai, Junichiro Kanbe, Keishi Saitoh, Yoichi Osato
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Patent number: 4460669Abstract: A photoconductive member comprises a support for a photoconductive member and an amorphous layer having photoconductivity constituted of an amorphous material comprising silicon atoms as a matrix, said amorphous layer having a first layer region containing as the constituent atom at least one kind of atoms selected from the group consisting of oxygen atoms, carbon atoms and nitrogen atoms in a distribution state which is ununiform and continuous in the direction of layer thickness and a second layer region containing atoms belonging to the group III of the periodic table as constituent atoms in a distribution state which is ununiform and continuous in the direction of layer thickness, said first layer region existing internally below the surface of said amorphous layer.Type: GrantFiled: November 22, 1982Date of Patent: July 17, 1984Assignee: Canon Kabushiki KaishaInventors: Kyosuke Ogawa, Shigeru Shirai, Junichiro Kanbe, Keishi Saitoh, Yoichi Osato
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Patent number: 4430405Abstract: A xeroradiographic material comprising a substrate at least one surface of which is electrically conductive, and an X-ray sensitive layer provided on the conductive surface of the substrate and essentially consisting of an organic binder, .gamma.-form crystal grains of a bismuth oxide-based compound oxide and n-type semiconductor grains dispersed in the organic binder. The material is made by dispersing these grains in an organic binder solution, applying the dispersion onto the conductive surface of the substrate, drying the coat of the dispersion at a temperature in a range not lower than the boiling point of the solvent but below the softening point of the organic binder to form an X-ray sensitive layer, and heat-treating the X-ray sensitive layer at a temperature in a range not lower than the softening point of the organic binder but below the temperature at which the organic binder begins decomposing.Type: GrantFiled: September 29, 1982Date of Patent: February 7, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshihiro Ono, Hiroshi Sunagawa
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Patent number: 4424269Abstract: Disclosed is a photosensitive plate for electrophotography, which comprises a conductive substrate and a layer of a composition formed by dispersing a photoconductor in a binder resin, which is formed on the substrate, wherein the resin binder comprises an epoxy resin component and an amine type curing agent component and the resin binder further comprises an acid anhydride as the ozone deterioration preventing agent.This photosensitive plate is excellent in the ozone resistance and the moisture resistance.Type: GrantFiled: March 8, 1982Date of Patent: January 3, 1984Assignee: Mita Industrial Co., Ltd.Inventors: Hideyuki Sasaki, Toru Nakazawa, Yoshiaki Kato, Hideo Fukuda, Yasushi Kamezaki, Akira Fushida
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Patent number: 4423133Abstract: A photoconductive layer comprises a support and an amorphous layer. The amorphous layer is photoconductive, comprises silicon as matrix and hydrogen and/or halogen, and has a layer region containing group III atoms which is distributed such that the distribution is continuous in the direction of layer thickness and said atoms are more enriched on the aforesaid support side than on the opposite side to the aforesaid support side in said layer.Type: GrantFiled: November 10, 1982Date of Patent: December 27, 1983Assignee: Canon Kabushiki KaishaInventors: Junichiro Kanbe, Shigeru Shirai, Kyosuke Ogawa, Keishi Saitoh, Yoichi Osato
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Patent number: 4418134Abstract: An aqueous composition-sensitive photoconductive composition useful in the preparation of aqueous composition decoatable electrophotographic elements, such elements and low cost lithographic printing plates prepared from said elements the aqueous composition-sensitive photoconductive composition comprising the admixture of an inorganic photoconductor, an organic photoconductor and an aqueous composition-sensitive resin, and, if desired, to increase exposure speed, a dyestuff photosensitizer.Type: GrantFiled: March 28, 1983Date of Patent: November 29, 1983Assignee: Polychrome CorporationInventors: Jayanti Patel, Ken-ichi Shimazu
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Patent number: 4418136Abstract: An electrophotographic element comprising a photoconductive layer consisting essentially of a Bi-containing As.sub.2 Se.sub.3 layer on an electrically conductive substrate.Type: GrantFiled: May 17, 1982Date of Patent: November 29, 1983Assignee: Ricoh Co., Ltd.Inventor: Masahiro Kameda
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Patent number: 4416962Abstract: An electrophotographic image-forming member comprises a substrate for electrophotography and a photoconductive layer which is laid on said substrate and constituted of an amorphous material containing at least one of hydrogen atom or halogen atom in a matrix of silicon atom, said substrate being constituted of aluminum oxide containing chemi-structually water at least on the surface thereof.Type: GrantFiled: December 7, 1981Date of Patent: November 22, 1983Assignee: Canon Kabushiki KaishaInventors: Shigeru Shirai, Junichiro Kanbe, Tadaji Fukuda
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Patent number: 4415642Abstract: The metal substrate of an electrophotographic member is provided with a selenium-tellurium alloy layer containing 5-30% tellurium, 10-5,000 ppm of a metallic element of the fifth main group, and 10-100 ppm of a halogen. A preferred embodiment contains 15% tellurium, 40 ppm arsenic, and 40 ppm chlorine. The addition of the metallic element of the fifth main group to the selenium-tellurium alloy results in a stabilization of charging potentials in multicycle operation.If the metal substrate is an aluminum drum, the electrophotographic member can be used as a copying drum in high-speed copiers.Type: GrantFiled: May 28, 1982Date of Patent: November 15, 1983Assignee: International Standard Electric CorporationInventors: Kurt Elsasser, Helmut Ebner, Armin Baumgartner
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Patent number: 4414319Abstract: A photoconductive member, comprises a support for a photoconductive member and an amorphous layer which is constituted of silicon atoms as matrix containing at least one of hydrogen atom and halogen atom and exhibits photoconductivity, said amorphous layer having a layer region containing oxygen atoms in at least a part thereof, the content of the oxygen atoms in said layer region being distributed unevenly in the direction of the thickness of said layer.Type: GrantFiled: October 29, 1981Date of Patent: November 8, 1983Assignee: Canon Kabushiki KaishaInventors: Shigeru Shirai, Junichiro Kanbe, Tadaji Fukuda
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Patent number: 4413047Abstract: Disclosed is a photosensitive material for electrophotography comprising a conductive substrate and a layer of a composition comprising a dispersion of a photoconductive pigment in a binder resin, which is formed on the conductive substrate, wherein a (dialkypyrophosphato) organic titanate is incorporated into said composition.This photosensitive material is excellent in the ozone resistance and the moisture resistance.Type: GrantFiled: April 12, 1982Date of Patent: November 1, 1983Assignee: Mita Industrial Co., Ltd.Inventors: Yoshiaki Kato, Akira Fushida, Hideo Fukuda, Toru Nakazawa, Yasushi Kamezaki, Hideyuki Sasaki
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Patent number: 4409310Abstract: The electrophotographic photosensitive member has a photoconductive layer containing photoconductive particles each of which has a water insoluble compound of a metal element of Group VIII of the Periodic Table deposited on the surface.Type: GrantFiled: February 17, 1982Date of Patent: October 11, 1983Assignee: Canon Kabushiki KaishaInventors: Kazumi Okano, Yuji Nishigaki, Masanao Kasai
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Patent number: 4409311Abstract: A hydrogen containing amorphous silicon photoconductive layer exhibits infrared absorption peaks between wavenumber of 2000 cm.sup.-1 where Si-H bonds are predominant and wavenumber of 2090 cm.sup.-1 where Si-H.sub.2 bonds are predominant and has an absorption coefficient ratio of the peaks of 2090 cm.sup.-1 to 2000 cm.sup.-1 of about 0.2 to 1.7. Preferably, the photoconductive layer is formed by a glow discharge decomposition and may contain small amount of oxygen and 10 to 20,000 ppm of Group IIIA impurity of the Periodic Table.Type: GrantFiled: March 8, 1982Date of Patent: October 11, 1983Assignees: Minolta Camera Kabushiki Kaisha, Takao Kawamura, Kyoto Ceramic Co., Ltd.Inventors: Takao Kawamura, Yoshida Masazumi
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Patent number: 4397933Abstract: The hydrogenated amorphous silicon photoconductive layer has an infrared spectrum containing a peak at 880.+-.10 cm.sup.-1 (intensity of this peak being referred to as I.sub.A) and a peak at 970.+-.10 cm.sup.-1 (intensity of this peak being referred to as I.sub.B) in the infrared spectrum, the ratio I.sub.A /I.sub.B, being not more than 1.0.Type: GrantFiled: September 15, 1981Date of Patent: August 9, 1983Assignee: Canon Kabushiki KaishaInventors: Masao Sugata, Masaki Fukaya, Takashi Nakagiri, Takaaki Yamagata, Yutaka Hirai
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Patent number: 4391901Abstract: The photosensitivity of lead lanthanum zirconate titanate (PLZT) ceramic material used in high resolution, high contrast, and non-volatile photoferroelectric image storage and display devices is enhanced significantly by positive ion implantation of the PLZT near its surface. Implanted ions include H.sup.+, He.sup.+, Ne.sup.+, Ar.sup.+, as well as chemically reactive ions from Fe, Cr, and Al. The positive ion implantation advantageously serves to shift the absorption characteristics of the PLZT material from near-UV light to visible light. As a result, photosensitivity enhancement is such that the positive ion implanted PLZT plate is sensitive even to sunlight and conventional room lighting, such as fluorescent and incandescent light sources. The method disclosed includes exposing the PLZT plate to the positive ions at sufficient density, from 1.times.10.sup.12 to 1.times.10.sup.17, and with sufficient energy, from 100 to 500 KeV, to provide photosensitivity enhancement.Type: GrantFiled: January 28, 1982Date of Patent: July 5, 1983Assignee: The United States of America as represented by the United States Department of EnergyInventors: Cecil E. Land, Paul S. Peercy
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Patent number: 4389474Abstract: A thiopyrylium compound having t-butyl groups at the 2- and 6-positions of the thiopyrylium nucleus, having a main absorption near the red region, i.e., 600 to 700 nm but substantially no side absorption near 400 nm, and useful as a sensitizer for a photoconductive composition.Type: GrantFiled: August 20, 1981Date of Patent: June 21, 1983Assignee: Fuji Photo Film Co., Ltd.Inventors: Kouichi Kawamura, Hideo Sato, Harumi Katsuyama
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Patent number: 4388394Abstract: A photoreceptor device comprises a conductive substrate and an electrophotographic layer thereon. The electrophotographic layer comprises copper-chlorine activated cadmium sulfide blended with a light-absorbing material.Type: GrantFiled: July 13, 1981Date of Patent: June 14, 1983Assignee: Gte Products CorporationInventors: Sixdeniel Faria, Ronald E. Karam
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Patent number: 4387149Abstract: An electrophotographic photosensitive material in which organic photoconductor is sensitized by a compound represented by the formula, ##STR1## wherein A, B, D and E represent independently a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, a phenyl group or a 5- or 6-membered heterocyclic ring residue, and at least two of them represent a phenyl group; F is an alkyl, phenyl or styryl group; m is a number of 0 or 1, and n is a number of zero, 1 or 2, provided that when m is 1, n is 0; and X.sup..crclbar. represents an anion residue, has a high sensitivity to the whole range of visible light as well as to the infrared rays of up to around 1,100 nm, and is stable in the potential characteristics such as surface potential and dark damping factor and capable of separation photographing by use of a color separation filter.Type: GrantFiled: March 4, 1982Date of Patent: June 7, 1983Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Kazuhiro Emoto, Kiyoshi Futaki
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Patent number: 4386146Abstract: In an electrophotographic photosensitive material comprising an electroconductive substrate having positioned thereon a photosensitive layer comprising as main components titanium dioxide and a binding material, the photosensitivity and whiteness can be improved by allowing a specific cyanine dye compound to exist in said photosensitive layer.Type: GrantFiled: October 20, 1981Date of Patent: May 31, 1983Assignee: Ishihara Sangyo Kaisha, Ltd.Inventors: Shigeru Kishino, Shigeo Yasui, Kei Takahata, Masakuni Ohkawa
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Patent number: 4384034Abstract: A photoconductive layer sensitized by a compound of the general formula: ##STR1## in which: R.sup.1 and R.sup.2 independently represent a hydrogen atom, an alkyl or substituted alkyl group, an aryl or substituted aryl group, an aralkyl or substituted aralkyl group, a cycloaliphatic or substituted cycloaliphatic group or a heterocyclic or substituted heterocyclic group providing R.sup.1 and R.sup.2 do not both represent cyclic groups of aromatic nature, or R.sup.1 and R.sup.2 together may represent the necessary atoms to complete a non-aromatic heterocyclic ring,R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently represent a hydrogen atom or any substituent providing the sum of their .sigma..sub.p constants has a value of less than +0.5, or R.sup.3 and R.sup.4 and/or R.sup.5 and R.sup.6 may represent the necessary atoms to complete an alicyclic or aromatic ring, R.sup.3 and R.sup.2 and/or R.sup.1 and R.sup.6 may represent the necessary atoms to complete a non-aromatic heterocyclic ring,R.sup.7 and R.sup.Type: GrantFiled: February 27, 1981Date of Patent: May 17, 1983Assignee: Minnesota Mining and Manufacturing CompanyInventors: Alan N. Ferguson, Kenneth Reynolds
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Patent number: 4381338Abstract: Photoconductive particles are prepared by the reaction of a water-soluble metal salt with an ion exchange resin having an anion which reacts with the metal ion of the water-soluble metal salt to produce a water insoluble metal compound and the deposition of the water insoluble metal compound resulting from the reaction on the surface of the photoconductive particles.Type: GrantFiled: September 17, 1980Date of Patent: April 26, 1983Assignee: Canon Kabushiki KaishaInventor: Kiyoshi Suzuki
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Patent number: 4379820Abstract: A layered electrophotographic photoconductor comprising an electrically conductive base; a charge transporting layer, formed on the electrically conductive base, which charge transporting layer comprises a selenium-tellurium alloy, doped with halogen; and a charge generating layer, formed on the charge transporting layer, which charge generating layer comprises a selenium-tellurium-arsenic alloy, doped with halogen.Type: GrantFiled: April 17, 1981Date of Patent: April 12, 1983Assignee: Ricoh Company, Ltd.Inventors: Hitoshi Nakamura, Hideyo Nishizima, Hideaki Ema, Makoto Harigaya, Satoshi Otomura
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Patent number: 4374917Abstract: A copper-activated mercury-containing cadmium selenide telluride infrared-responsive photoconductor.Type: GrantFiled: December 11, 1981Date of Patent: February 22, 1983Assignee: GTE Products CorporationInventor: Sixdeniel Faria
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Patent number: 4370399Abstract: An ambipolar electrophotographic plate and materials used in the manufacture thereof including a photoconductive layer formulated of selenium, selenium-arsenic alloy or selenium-arsenic-tellurium alloy containing indium as a dopant which extends the range for electrons without noticeable deterioration of the long range for holes.Type: GrantFiled: March 23, 1981Date of Patent: January 25, 1983Assignee: A. B. Dick CompanyInventors: Syamal K. Ghosh, Frank D. Kelly
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Patent number: 4362800Abstract: A photoconductive composition for electrophotography containing a photoconductive material, a sensitizing dye comprising a specific very stable sensitizing dye for red light to infrared rays, and a film-forming polymer binder.Type: GrantFiled: September 4, 1981Date of Patent: December 7, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Masaaki Takimoto, Kenichi Sawada, Kouichi Kawamura
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Patent number: 4361638Abstract: An electrophotographic light-sensitive element and process for the production thereof are described, wherein the element comprises an electrically conductive support coated with a photoconductive layer composed of a silicon- and carbon-based amorphous material doped with hydrogen and fluorine.Type: GrantFiled: October 30, 1980Date of Patent: November 30, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Akio Higashi, Kazuhiro Kawashiri, Yuzo Mizobuchi
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Method of making .alpha.-silicon powder, and electrophotographic materials incorporating said powder
Patent number: 4356246Abstract: A noncrystalline silicon powder having excellent photoconductivity is described, comprising silicon and hydrogen, exhibiting an infrared absorption spectrum characterized by absorption peaks centered at about 2000 cm.sup.-1 and 630 cm.sup.-1, wherein the height of the absorbance peak at 2000 cm.sup.-1 is at least one-tenth the height of the peak centered at 630 cm.sup.-1, and exhibiting a spin density of not more than 10.sup.18 cm.sup.-3 determined by electron spin resonance spectroscopy; the noncrystalline silicon powder is used as highly efficient photoconductor in photoconductive compositions utilized for the production of electrophotographic photoreceptors.Type: GrantFiled: June 16, 1980Date of Patent: October 26, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Masatoshi Tabei, Keiji Takeda, Kazuhiro Kawaziri, Akio Higashi -
Patent number: 4349617Abstract: A function separated type electrophotographic light-sensitive member and a process for production thereof are described, said member comprising an electrically conductive support, a light-sensitive layer made of a hydrogen-doped amorphous silicon semiconductor, and an organic electric charge transport layer containing at least one positive charge transport carrier selected from the group consisting of pyrazolines, aryl-alkanes, arylketones, arylamines and chalcones.Type: GrantFiled: October 23, 1980Date of Patent: September 14, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazuhiro Kawashiri, Yuzo Mizobuchi, Akio Higashi, Hiroshi Tamura, Keiji Takeda, Masayoshi Nagata
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Patent number: 4341851Abstract: An electrophotographic photoconductor, formed on a conductive substrate by spray pyrolysis, comprising essentially a major amount of cadmium sulphide and a minor amount of zinc sulphide. The cadmium layer is at least three microns in thickness and is formed in three zones. The zone adjacent the metal substrate, adapted to form a contact layer, bears an amount of lead sulphide; the outermost zone, adapted to absorb light, is doped with a minor amount of copper to eliminate fatigue; and the intermediate zone, which is necessary to increase the surface potential, is adapted to transport light-generated charge and is doped with a minor amount of chlorine. The process is carried on in the atmosphere with three different aqueous solutions of reagents to form the three different zones. The photoconductive layer is microcrystalline in structure and bears adsorbed oxygen.Type: GrantFiled: February 23, 1981Date of Patent: July 27, 1982Assignee: Savin CorporationInventors: John B. Mooney, Ivor Brodie
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Patent number: 4338387Abstract: This invention is generally directed to an inorganic overcoated photoresponsive device comprised of a substrate, a layer of electron trapping material, this layer being comprised of halogen doped selenium, halogen doped arsenic selenium alloys, and mixtures thereof; a hole transport layer in operative contact with the electron trapping layer, this layer being comprised of a halogen doped selenium arsenic alloy wherein the percentage of selenium present by weight is from about 99.5 percent to about 99.9 percent, the percentage of arsenic present by weight is from about 0.5 percent to about 0.Type: GrantFiled: March 2, 1981Date of Patent: July 6, 1982Assignee: Xerox CorporationInventor: Harvey J. Hewitt
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Patent number: 4338389Abstract: In a photosensitive member for electrophotography comprising a photoconductive layer containing photoconductive cadmium sulfide particles dispersed in a binder material, the member comprises a particular additive to the photoconductive layer, said additive being selected from the group consisting of iron, nickel, cobalt and compounds thereof.Type: GrantFiled: September 24, 1980Date of Patent: July 6, 1982Assignee: Canon Kabushiki KaishaInventors: Kiyoshi Suzuki, Kazumi Okano
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Patent number: 4316947Abstract: Cadium sulfide for electrophotography is produced by reacting hydrogen sulfide with a solution containing cadmium sulfate, sulfuric acid and hydrochloric acid of a low concentration, and then firing the resulting cadmium sulfide without adding a donor impurity other than that derived from the hydrochloric acid.Type: GrantFiled: September 8, 1980Date of Patent: February 23, 1982Assignee: Canon Kabushiki KaishaInventors: Kiyoshi Suzuki, Hirokuni Kawashima
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Patent number: 4315983Abstract: 2,6-Di-tert-Butyl-4-substituted thiopyrylium salt represented by formula (I), a process for production of said salt and a photoconductive composition containing said salt. ##STR1## wherein Z.sup..crclbar. is an anion, X is a hydrogen atom, an aryl group, a substituted aryl group or an alkyl group, and R.sup.1 and R.sup.2 are the same or different and include alkyl groups.Type: GrantFiled: July 14, 1980Date of Patent: February 16, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Koichi Kawamura, Harumi Katsuyama, Hideo Sato
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Patent number: 4314014Abstract: Disclosed is an electrophotographic plate having a laminated structure comprising a first Se layer containing 3 to 10% by weight of As, a second Se layer containing 40 to 47% by weight of Te and 3 to 10% by weight of As and a fourth Se layer consisting solely of Se or comprising Se and up to 10% by weight of As or an organic semiconductor layer, wherein a substrate is arranged so that at least the face of the substrate which is contiguous to the face of one of said first Se layer and said fourth Se layer or organic semiconductor layer, that is located on the outer side of the laminated structure, is electrically conductive.It is preferred that the fourth Se layer be formed by vacuum evaporation deposition while maintaining the substrate temperature at 50.degree. to 80.degree. C. The residual potential of the electrophotographic plate can be reduced.Type: GrantFiled: June 11, 1980Date of Patent: February 2, 1982Assignee: Hitachi, Ltd.Inventors: Hideaki Yamamoto, Akio Taniguchi, Shinkichi Horigome, Susumu Saito, Yoshiaki Mori, Eiichi Maruyama
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Patent number: 4286035Abstract: An electrophotographic photoconductor comprising an electroconductive base and a photosensitive layer formed thereon, the photosensitive layer comprising a selenium-tellurium alloy with a concentration of tellurium in the range of 5 to 20 wt. % and halogen, with a concentration in the range of 5 to 500 ppm, selected from the group consisting of fluorine, chlorine, bromine and iodine, in the photosensitive layer, with the concentration of tellurium substantially uniform or increasing in the direction toward the surface of the photosensitive layer and the ratio of the concentration of tellurium near the electroconductive base to the concentration of tellurium near the surface of said photosensitive layer being 65 or more:100.Type: GrantFiled: May 28, 1980Date of Patent: August 25, 1981Assignee: Ricoh Company, Ltd.Inventors: Hideyo Nishizima, Hideaki Ema, Hiroshi Tamura, Hideki Akiyoshi
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Patent number: 4283475Abstract: 2,6-Di-tert-butyl-4-[5-(2,6-di-tert-butyl-4H-thiopyran-4-ylidene)penta-1,3- dienyl]thiopyrylium salts, which are novel, colorless, transparent, having an adsorption in the far infrared to near infrared region and capable of imparting high sensitivity to photoconductive substance; process for producing the salts; and a photoconductive composition containing the salt.Type: GrantFiled: August 20, 1980Date of Patent: August 11, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Koichi Kawamura, Harumi Katsuyama, Hideo Sato
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Patent number: 4277551Abstract: An electrophotographic plate comprising a conductive substrate, a photoconductive-insulative layer overlaying the substrate and a transparent, electrically active, organic, electron transport layer overlaying the photoconductive-insulative layer in which the photoconductive layer comprises a Se--Te or Se--As mixture in the range of 90-97.5 atomic percent Se or 60-97.5 atomic percent, respectively, and wherein the thicknesses of the photoconductive layer and transport overlayer range between 40 to 100 micrometers and 1 to 5 micrometers, respectively.Type: GrantFiled: August 20, 1979Date of Patent: July 7, 1981Assignee: Minnesota Mining and Manufacturing CompanyInventors: Terry J. Sonnonstine, Kenneth G. Kneipp
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Patent number: 4275135Abstract: A photoconductive insulating layer for an electrophotographic sensitive member formed of a fine powder of CdS.nCdCO.sub.3, wherein 0<n.ltoreq.4, bonded by an insulating resin and having manganese stearate dispersed therein. Advantageously the CdS.nCdCO.sub.3 contains copper as an acceptor impurity in an amount of between about 0.025 and 0.1 grain atomic weight of copper per 100 gram atomic weight of cadmium, the manganese stearate is present in an amount of about 2 to 4 parts by weight per 100 parts by weight of CdS.nCdCO.sub.3 and is preferably adherent thereto, the layer is between 10 and 100 microns thick and the CdS.nCdCO.sub.3 particle size is about 1 to 2 microns or less. In producing the layer the CdS.nCdCO.sub.3 (Cu) is produced by reacting Cd, Cu and CO.sub.Type: GrantFiled: July 11, 1979Date of Patent: June 23, 1981Assignee: Minolta Camera Kabushiki KaishaInventor: Tetsuo Tomonaga
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Patent number: 4269919Abstract: A photoconductive coating which comprises a crystalline deposit of a wholly inorganic material, in the preferred form comprising cadmium sulfide, of almost perfect stoichiometry, either with or without small amounts of dopant.The coating is deposited on a suitable substrate such as a thin, clear, flexible polyester sheet with an intervening layer of ohmic material such as indium-tin oxide in a sputtering method that results in unusual properties. The deposit can be made on metal substrates if desired, but the greater utility is in its application to a transparent substrate so that a transparent electrophotographic member is formed suitable for many uses.Two important properties worthy of mention are that the coating is such that a charge density may be maintained on its surface (surface charge) which is ten to one hundred times greater than known photoconductive coatings and that there is no photoconductive fatigue.Type: GrantFiled: May 20, 1977Date of Patent: May 26, 1981Assignee: Coulter Systems CorporationInventor: Manfred R. Kuehnle
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Patent number: 4265991Abstract: A layer of amorphous silicon containing H, preferably 10-40 atomic %H, is used as a photoconductive layer for electrophotographic photosensitive member.Type: GrantFiled: December 19, 1978Date of Patent: May 5, 1981Assignee: Canon Kabushiki KaishaInventors: Yutaka Hirai, Toshiyuki Komatsu, Katsumi Nakagawa, Teruo Misumi, Tadaji Fukuda
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Patent number: 4264695Abstract: A photosensitive material for use in electrophotography which comprises a conductive support, a first layer consisting essentially of a substance capable of generating a conductive carrier through light absorption and an electron donor or an electron acceptor, and a second layer consisting essentially of an electron acceptor or an electron donor, to wit, a substance constituting the opposite party of the electron donor or the electron acceptor contained in the first layer, said first and second layers being formed in that order on said conductive support.Type: GrantFiled: January 28, 1980Date of Patent: April 28, 1981Assignee: Ricoh Co., Ltd.Inventors: Akio Kozima, Mitsuru Hashimoto, Masafumi Ohta, Masaomi Sasaki, Zenjiro Okuno