The Single Bonded Oxygen Is Bonded Directly To An Additional Carbon, Which Carbon May Be Single Bonded To Any Element But May Be Multiple Bonded Only To Carbon (i.e., Carboxylic Acid Esters) Patents (Class 44/388)
  • Patent number: 5525126
    Abstract: The present invention includes a process for producing esters from a feedstock that includes a fat or an oil. The process includes mixing the feedstock with an alcohol and a catalyst. The catalyst includes a mixture of calcium acetate and barium acetate The reaction mixture is heated at a temperature effective to make esters.
    Type: Grant
    Filed: October 31, 1994
    Date of Patent: June 11, 1996
    Assignee: Agricultural Utilization Research Institute
    Inventors: Hemendra N. Basu, Max E. Norris
  • Patent number: 5520708
    Abstract: A method is provided to reduce the crystallization temperature of a fatty acid oil ester-petroleum distillate fuel blend. The method comprises combining a petroleum distillate with an amount of an ester of a branched chain (C.sub.3 -C.sub.5) alcohol of a fatty acid, wherein the amount utilized is effective to lower the crystallization onset point of the blend by about 8.degree.-20.degree. C. Blowy that of a blend comprising the same amount of a methyl or ethyl ester.
    Type: Grant
    Filed: April 26, 1994
    Date of Patent: May 28, 1996
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: Lawrence A. Johnson, Earl G. Hammond
  • Patent number: 5507964
    Abstract: The invention relates to the use of isopalmitic acid esters of branched aliphatic polyols containing 2 to 6 primary hydroxyl groups and 4 to 10 carbon atoms as a base oil for two-stroke engine lubricants. The isopalmitic acid esters are low in viscosity, even at low temperatures, and do not crystallize out in gasoline, even over periods of several days.
    Type: Grant
    Filed: March 18, 1994
    Date of Patent: April 16, 1996
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Frank Bongardt, Karl-Heinz Schmid, Reinhold Wuest
  • Patent number: 5460634
    Abstract: An additive comprising an oil-soluble stable free radical, such as a nitroxide, or a precursor therefor, is used in a fuel oil to reduce, on combustion of the fuel oil, one or more of particulate emissions, hydrocarbon emissions, carbon monoxide emissions, and oxides of nitrogen emissions.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: October 24, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Carlo Fava, Wolfgang W. J. Gschwendtner, Anthony K. Smith, Michael D. Sexton, Richard J. Hart
  • Patent number: 5441544
    Abstract: A fuel additive having the formula: ##STR1## where A.sub.1 is a thioether, a sulfoxide, a sulfone, a sulfonic acid, a sulfonamide, a nitrile, a carboxylic acid or ester, or a carboxamide; R.sub.1 and R.sub.2 are independently hydrogen, hydroxy, lower alkyl, or lower alkoxy; R.sub.3 and R.sub.4 are independently hydrogen or lower alkyl and each R.sub.3 and R.sub.4 is independently selected in each --O--CHR.sub.3 --CHR.sub.4 -- unit; R.sub.5 is hydrogen, alkyl having 1 to 100 carbon atoms, phenyl, aralkyl having 7 to 100 carbon atoms or alkaryl having 7 to 100 carbon atoms, or an acyl group of the formula: ##STR2## where R.sub.6 is alkyl having 1 to 30 carbon atoms, phenyl, aralkyl having 7 to 36 carbon atoms or alkaryl having 7 to 36 carbon atoms; n is an integer from 5 to 100; and x is an integer from 0 to 10.
    Type: Grant
    Filed: December 23, 1993
    Date of Patent: August 15, 1995
    Assignee: Chevron Chemical Company
    Inventor: Richard E. Cherpeck
  • Patent number: 5427591
    Abstract: Poly(oxyalkylene) hydroxyaromatic esters having the formula: ##STR1## or a fuel-soluble salt thereof; where R.sub.1 and R.sub.2 are each independently hydrogen, hydroxy, lower alkyl having 1 to 6 carbon atoms, or lower alkoxy having 1 to 6 carbon atoms; R.sub.3 and R.sub.4 are each independently hydrogen or lower alkyl having 1 to 6 carbon atoms; R.sub.5 is hydrogen, alkyl having 1 to 30 carbon atoms, phenyl, aralkyl or alkaryl having 7 to 36 carbon atoms, or an acyl group having the formula: ##STR2## wherein R.sub.6 is alkyl having 1 to 30 carbon atoms, phenyl, or aralkyl or alkaryl having 7 to 36 carbon atoms; R.sub.7 and R.sub.8 are each independently hydrogen, hydroxy, lower alkyl having 1 to 6 carbon atoms, or lower alkoxy having 1 to 6 carbon atoms; n is an integer from 5 to 100; and x and y are each independently an integer from 0 to 10.The poly(oxyalkylene) hydroxyaromatic esters of formula I are useful as fuel additives for the prevention and control of engine deposits.
    Type: Grant
    Filed: December 18, 1992
    Date of Patent: June 27, 1995
    Assignee: Chevron Chemical Company
    Inventor: Richard E. Cherpeck
  • Patent number: 5417725
    Abstract: The present invention relates to a composition that is useful as a penetration and fixture freeing agent. Specifically, the composition aids in the freeing of metal fixtures, such as hardware. In a preferred embodiment, the composition is a combination of a lower alkyl aromatic carboxylic acid ester, a lower alkyl alcohol, and a light petroleum distillate vehicle or carrier. In a highly preferred embodiment, the composition is methyl salicylate, isopropanol, and kerosene.
    Type: Grant
    Filed: February 1, 1994
    Date of Patent: May 23, 1995
    Inventor: Gordon C. Graves
  • Patent number: 5389113
    Abstract: Mixtures containinga) 58 to 95% by weight of at least one ester with an iodine value of 50 to 150 derived from fatty acids containing 12 to 22 carbon atoms and lower aliphatic alcohols containing 1 to 4 carbon atoms,b) 4 to 40% by weight of at least one ester of fatty acids containing 6 to 14 carbon atoms and lower aliphatic alcohols containing 1 to 4 carbon atoms andc) 0.1 to 2% by weight of at least one polymeric ester, are distinguished by particular low-temperature stability and can be used as a fuel for diesel engines.
    Type: Grant
    Filed: August 17, 1993
    Date of Patent: February 14, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Guenther Demmering, Karl Schmid, Frank Bongardt, Leonhard Wittich
  • Patent number: 5378249
    Abstract: A biodegradable two-cycle engine oil composition comprises about (a) 20 to 85 wt. % of a heavy ester or a mixture of heavy ester oils characterized by a kinematic viscosity of at least about 7.0 cSt at 100.degree. C., (b) 10 to 85 wt. % of a light ester oil or a mixture of light ester oils characterized by a kinematic viscosity of less than about 6.0 cSt at 100.degree. C., and optionally an additive, wherein the composition has a biodegradability of at least about 66% as measured by the CEC L-33-T-82 method.
    Type: Grant
    Filed: June 28, 1993
    Date of Patent: January 3, 1995
    Assignee: Pennzoil Products Company
    Inventor: David S. Morrison
  • Patent number: 5264005
    Abstract: This invention relates to a two-cycle engine lubricant composition, comprising (A) at least one dispersant, (B) at least one reaction product of a fatty acid and a polyamine, and (C) at least about 25% by weight of the composition of at least one varnish dissolver selected from (a) keto-alcohols, (b) carboxylic esters having up to a total of 24 carbon atoms and (c) alkoxy alcohols, and (D) at least about 15% by weight of the composition of at least one fluidizing oil, and a method, comprising the steps of introducing into a two-cycle internal combustion engine a fuel-lubricant mixture comprising a major amount of a fuel and a minor amount sufficient to increase compression or release stuck piston rings, of the two-cycle engine lubricant composition.
    Type: Grant
    Filed: August 9, 1991
    Date of Patent: November 23, 1993
    Assignee: The Lubrizol Corporation
    Inventor: Glen H. Blythe
  • Patent number: 5232464
    Abstract: The fuel for internal combustion engines employing electrical fuel ignition and a carburetor and/or fuel injection, comprises a boiling fraction of 30.degree. C. to 200.degree. C., especially 30.degree. C. to 180.degree. C., containing hydrocarbons selected from the group consisting essentially of paraffinic, olefinic, naphthenic and aromatic hydrocarbons and mixtures thereof, and which is free of manganese, lead and iron. According to the invention, the fuel contains methyl formate in an amount in the range of 1.0 percent by volume to 50.0 percent by volume, if desired 1.0 percent by volume to 30.0 percent by volume, and preferably 3.5 percent by volume to 10.0 percent by volume of the fuel.
    Type: Grant
    Filed: February 21, 1992
    Date of Patent: August 3, 1993
    Assignee: OMV Aktiengesellschaft
    Inventor: Peter Klezl
  • Patent number: 5194068
    Abstract: The invention relates to a fuel for gasoline engines and diesel engines, containing small amounts of an ester of a mono- and/or poly-carboxylic acid with an alkyl alkanolamine or alkyl aminopolyalkylene glycol of the general formula I ##STR1## in which R.sub.1 is a C.sub.6 -C.sub.30 -alkyl radical,R.sub.2 is a C.sub.6 -C.sub.30 -alkyl radical or a hydroxyalkyl radical of the general formula II ##STR2## and R.sub.3 is a hydroxylalkyl radical of formula II, in which R.sub.4 is hydrogen or a C.sub.1 -C.sub.6 -alkyl radical and m is an integer from 0 to 100.
    Type: Grant
    Filed: June 24, 1991
    Date of Patent: March 16, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Mohr, Knut Oppenlaender, Roland Schwen, Hans P. Rath, Juergen Thomas, Hans-Henning Vogel
  • Patent number: 5160506
    Abstract: The invention relates to a liquid fuel mixture, comprising a C.sub.3 and/or at least a C.sub.4 -alkane, at least one oil component and optionally at least one additive, a process for its preparation and its use for two-stroke engines.
    Type: Grant
    Filed: July 13, 1990
    Date of Patent: November 3, 1992
    Inventors: Hans Schur, Werner Angerer, Friedrich Sprugel
  • Patent number: 5160507
    Abstract: Ester-type ashless dispersants containing additional integral sulfur-ester moieties which have been found to possess enhanced thermal and oxidative stability are claimed.
    Type: Grant
    Filed: June 4, 1990
    Date of Patent: November 3, 1992
    Assignee: Mobil Oil Corp.
    Inventor: Andrew G. Horodysky
  • Patent number: 5094666
    Abstract: A wax-containing middle distillate, such as diesel fuel, having improved low temperature flow properties comprises three or more components including (A) an oil-soluble ethylene backbone flow improving polymer such as ethylene vinyl acetate copolymer, (B) a hydrocarbyl substituted amine salt and/or amide of a carboxylic acid or anhydride such as phthalic anhydride salts, and (C) a hydrocarbyl substituted amine salt and/or amide of a derivative of benzoic acid such as the dihydrogenerated tallow amine salt of an alkyl substituted dithiobenzoic acid.
    Type: Grant
    Filed: June 28, 1990
    Date of Patent: March 10, 1992
    Assignee: Exxon Research and Engineering Company
    Inventors: Nicholas Feldman, Jacob J. Habeeb
  • Patent number: 5092908
    Abstract: A wax-containing middle distillate, such as diesel fuel, having improved low temperature flow properties comprises three or more components including (A) an oil-soluble ethylene backbone flow improving polymer such as ethylene vinyl acetate copolymer, (B) a hydrocarbyl substituted amine salt and/or amide of a carboxylic acid or anhydride such as phthalic anhydride salts, and (C) a hydrocarbyl substituted amine salt of a derivative of phosphoric acid such as the dihydrogenated tallow amine salt of dialkyldithiophosphoric acid.
    Type: Grant
    Filed: June 28, 1990
    Date of Patent: March 3, 1992
    Assignee: Exxon Research and Engineering Company
    Inventors: Nicholas Feldman, Jacob J. Habeeb
  • Patent number: 5042990
    Abstract: Storage-stable, pumpable, concentrated dispersions of coal in water contain a non-ionic additive constituted by a polymer containing polyethoxy chains grafted onto suitably functionalized polystyrenes having a molecular weight comprised within the range of from 500 to 15000.
    Type: Grant
    Filed: November 27, 1989
    Date of Patent: August 27, 1991
    Assignee: Eniricerche S.p.A.-and- Snamprogetti S.p.A.
    Inventors: Fabrizio Bonaccorsi, Aldo Prevedello, Armando Marcotullio, Edoardo Platone, Arnaldo Roggero, Elio Donati
  • Patent number: 5028239
    Abstract: A method of dehazing a contained body of petroleum distillate by removing suspended water droplets from the distillate phase, or releasing free water trapped in an emulsion settled from the distillate phase, a detergent having been added to the petroleum distillate, comprising the step of adding to the distillate an effective amount of a vinyl copolymer which includes both a hydrophilic and hydrophobic monomer.
    Type: Grant
    Filed: May 12, 1989
    Date of Patent: July 2, 1991
    Assignee: Nalco Chemical Company
    Inventor: William K. Stephenson
  • Patent number: H1071
    Abstract: Liquid hydrocarbon fuels such as diesel fuel and aviation jet fuel are stabilized by insertion of solid porous stabilizing foam into storage tanks. Fuel-insoluble particles resulting from degradation of the fuel which form during prolonged storage are absorbed by the foam. The absorbed particles are removed from the foam by contacting it with a polar solvent. The foam thus regenerated is re-used for continued stabilization of stored liquid hydrocarbon fuels. The polar solvent having fuel-insoluble particles dissolved therein is recovered by distillation for re-use.
    Type: Grant
    Filed: December 13, 1990
    Date of Patent: July 7, 1992
    Assignee: United States of America
    Inventors: Margaret A. Wechter, Dennis R. Hardy