Retort Patents (Class 48/89)
  • Patent number: 7141085
    Abstract: The refractory protected, replaceable insert for a gasifier includes a replaceable floor edge insert that is formed with a predetermined mating profile that is complementary to a finished mating profile of the gasifier floor. The geometry of the mating profiles of the replaceable floor edge insert and the gasifier floor permit removable engagement between the floor edge insert and the mating profile of the gasifier floor. The replaceable floor edge insert is protected by a ring-like arrangement of hanging refractory bricks that each include an appendage. Each brick appendage covers a portion of the inner radial edge of the replaceable floor edge insert and also covers an upper surface portion of an underlying quench ring, thus prolonging the life of the floor and the quench ring. A refractory ceramic fiber paper can be provided between the hanging brick and the floor edge and quench ring.
    Type: Grant
    Filed: January 16, 2003
    Date of Patent: November 28, 2006
    Assignees: Texaco Inc., Texaco Development Corporation
    Inventors: John Corwyn Groen, John D. Winter
  • Patent number: 7128768
    Abstract: A hydrogen-rich reformate gas generator (36), such as a mini-CPO, POX, ATR or other hydrogen generator provides warm, dry, hydrogen-rich reformate gas to a hydrogen desulfurizer (17) which provides desulfurized feedstock gas to a major reformer (14) (such as a CPO) which, after processing in a water-gas shift reactor (26) and preferential CO oxidizer (27) produces hydrogen-containing reformate in a line (31) for use, for instance, as fuel for a fuel cell power plant. The expensive prior art hydrogen blower (30) is thereby eliminated, thus reducing parasitic power losses in the power plant. The drier reformate provided by the small hydrogen generator to the hydrogen desulfurizer favors hydrogen sulfide adsorption on zinc oxide and helps to reduce sulfur to the parts per billion level.
    Type: Grant
    Filed: December 9, 2003
    Date of Patent: October 31, 2006
    Assignee: UTC Fuel Cells, LLC
    Inventors: Ke Liu, Richard J. Bellows, John L. Preston, Jr.
  • Patent number: 7101411
    Abstract: An apparatus for generating hydrogen gas in which hydrogen gas of a high purity is supplied to a hydrogen-utilizing device by using a decahydronaphthalene/naphthalene reaction. The apparatus includes a storage tank in which decahydronaphthalene is stored as a crude fuel, a reaction tank which has a catalyst and a heater for heating the catalyst and which causes dehydrogenation of decahydronaphthalene supplied from the storage tank to the heated catalyst, and a separation tank in which hydrogen-rich gas is separated out from naphthalene and hydrogen gas supplied from the reaction tank by using a hydrogen separation film and from which the separated hydrogen gas is discharged.
    Type: Grant
    Filed: February 26, 2002
    Date of Patent: September 5, 2006
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Takahiro Hayashi, Mamoru Ishikiriyama, Masahiko Sugiyama, Yasukazu Saito
  • Patent number: 7070634
    Abstract: A plasma reformer for the chemical reforming of gaseous mixtures of water and hydrocarbon fuels for producing hydrogen. The reformer contains a reaction chamber with outer lateral walls containing emitter electrodes and inner lateral walls containing collector electrodes. The emitter electrodes and collector electrodes form an electric circuit. There are a multiplicity of thin needle-like extrusions on the emitter electrode from which a profusion of high energy electrons are emitted. These high-energy electrons dissociate the hydrocarbon fuel through absorption and ionization emitting low energy electrons in the process. These low energy electrons cause dissociation of water. Thus, dissociation of hydrocarbon fuel acts to initiate dissociation of water. The molar ratio of water to hydrocarbon fuel in the input mixture for reactions, and therefor the production of hydrogen from water, increases with carbon number of the hydrocarbon fuel.
    Type: Grant
    Filed: November 3, 2003
    Date of Patent: July 4, 2006
    Inventor: Chi S. Wang
  • Patent number: 6932847
    Abstract: A hydrogen generation system includes a fuel container, a spent fuel container, a catalyst system and a control system for generating hydrogen in a manner which provides for a compact and efficient construction while producing hydrogen from a reaction involving a hydride solution such as sodium borohydride.
    Type: Grant
    Filed: July 6, 2001
    Date of Patent: August 23, 2005
    Assignee: Millennium Cell, Inc.
    Inventors: Steven C. Amendola, Phillip J. Petillo, Stephen C. Petillo, Richard M. Mohring
  • Patent number: 6932958
    Abstract: A fuel processor for producing a hydrogen-rich product gas suitable for direct use in fuel cell applications includes a housing, an annular shift/methanator reactor vessel at least one reactor vessel wall disposed within the housing and forming an outer annular space between the at least one reactor vessel wall and the housing. A combustion chamber having at least one combustion chamber wall and forming a first inner annular space between the at least one combustion chamber wall and the at least one reactor vessel wall is disposed in the interior space formed by the annular shift/methanator reactor vessel, and a reformer reactor vessel having at least one reformer vessel wall and forming a second inner annular space between the at least one reformer vessel wall and the at least one combustion chamber wall is disposed within the combustion chamber.
    Type: Grant
    Filed: March 26, 2003
    Date of Patent: August 23, 2005
    Assignee: Gas Technology Institute
    Inventors: James R. Wangerow, Alvie R. Meadows, Andy H. Hill, Michael Onischak
  • Patent number: 6830597
    Abstract: The subject invention pertains to unique and advantageous systems for gasifying and/or liquefying biomass. The systems of the subject invention utilize a unique design whereby heat from a combustion chamber is used to directly gasify or liquefy biomass. In a preferred embodiment, the biomass is moved through a reactor tube in which all the gasification and/or liquefaction takes place. Preferably, char exits the biomass reactor tube and enters the combustion chamber where the char serves as fuel for combustion. The combustion chamber partially surrounds the reactor tube and is in direct thermal contact with the reactor tube such that heat from the combustion chamber passes through the reactor wall and directly heats the biomass within the reactor tube.
    Type: Grant
    Filed: February 18, 2000
    Date of Patent: December 14, 2004
    Assignee: Green Liquids and Gas Technologies
    Inventor: Alex E. S. Green
  • Patent number: 6827751
    Abstract: An apparatus which is capable of supporting a process for gasifying a variety of hydrocarbon-containing materials. The resulting hydrogen-containing gas is suitable for use in various combustion processes and for petrochemical processes. A hydrocarbon-containing material is mixed with natural gas (or other suitable hydrocarbon gas) under pressure. The suspended material and gas are then injected under pressure into an acceleration/gasification tube. Intense heat (provided by an external energy source) is applied to the mixture as it travels through this tube, resulting in the cracking of the hydrocarbon chains and the release of additional energy. The released bond energy, along with the addition of the external energy, rapidly expands the gas and causes the velocity of the moving mixture to rise sharply as it proceeds down the tube. The acceleration/gasification tube is connected to a diffuser, which is essentially an expansion nozzle with a series of heat exchangers to cool the rapidly expanding gas.
    Type: Grant
    Filed: October 28, 2003
    Date of Patent: December 7, 2004
    Inventors: Thomas W. Kaufman, Verner Christensen
  • Patent number: 6814940
    Abstract: The present invention concerns a process and an apparatus for thermal conversion of biomass and organic wastes. According to the invention, the feedstock is fed into a fluidized-bed reactor, wherein the feed is converted at an elevated temperature under the influence of particulate matter kept in a fluidized state by a fluidizing gas, the particulate matter is transferred from the reactor to a regenerator for regeneration and then recirculated to the reactor after the regeneration, and the converted hydrocarbon products are recovered from the reactor. Both the reactor and the regenerator comprise risers having an axially annular cross section and being equipped with multi-inlet cyclones for the separation of particulate matter. By means of the invention, it is possible to producer pyrolysis oil, the quality of which is higher than that of oil produced with the processes of the prior art.
    Type: Grant
    Filed: October 30, 2000
    Date of Patent: November 9, 2004
    Assignee: Fortum Oyj
    Inventors: Jyrki Hiltunen, Steven Gust, Jukka-Pekka Nieminen
  • Publication number: 20040205997
    Abstract: A dual-chamber, aqueous-chemistry-based portable reactor for reducing water via any of numerous possible exothermic reactions to produce both heat and hydrogen gas. In one embodiment, aluminum metal is contained within a lower reaction chamber, an aqueous, sodium-hydroxide solution is contained in an upper chamber, and the aqueous, sodium-hydroxide solution is fed by gravity into the lower reaction chamber to vigorously react with the aluminum metal to produce both heat and hydrogen gas. A static feedback-control tube returns the aqueous, sodium-hydroxide solution back from the second chamber to the first chamber in the event that excessive hydrogen-gas pressure builds up in the second chamber, providing feedback-control of the rate of the reduction of water in the second chamber by a combination of gas pressure and hydrostatic pressure.
    Type: Application
    Filed: April 15, 2003
    Publication date: October 21, 2004
    Inventor: David Youngblood
  • Patent number: 6805773
    Abstract: The method of protecting a surface in a gasifier which is normally an exposed surface in the gasifier. The method includes forming a refractory attachment with a securement surface that confronts the protectable surface in the gasifier and mechanically securing the refractory attachment onto the protectable surface in the gasifier without the refractory attachment penetrating the protectable surface. Such mechanical securing is achieved by providing a latch which if formed of complementary shapes of the securement surface and the protectable surface.
    Type: Grant
    Filed: February 1, 2001
    Date of Patent: October 19, 2004
    Assignee: Texaco Inc. and Texaco Development Corporation
    Inventor: Donald Duane Brooker
  • Patent number: 6793700
    Abstract: An apparatus for a hydrocarbon reforming process includes a combustion chamber, a convection chamber in fluid communication with the combustion chamber, at least one burner disposed in the combustion chamber, a reaction chamber, a means for flowing a first mixed-feed through a first part of the reaction chamber, and a means for flowing a second mixed-feed through an annular portion of a second part of the reaction chamber, the second part being a tube-in-tube in fluid communication with the first part. The burner(s) generates a flow of a flue gas having a sensible heat from the combustion chamber to the convection chamber. The flow of the flue gas in the convection chamber is counter-currently with the flow of the second mixed-feed.
    Type: Grant
    Filed: January 14, 2002
    Date of Patent: September 21, 2004
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Hoanh Nang Pham, Shoou-I Wang, David Hon Sing Ying, Kevin Boyle Fogash
  • Publication number: 20040134127
    Abstract: The present invention is an apparatus arranged to maximize heat utilization for a hydrocarbon steam reforming process to produce synthesis gas. The apparatus comprises a refractory lined vessel with partition walls that divide the inside of the vessel into (1) a combustion chamber(s) containing one or more burners, and (2) convection chambers used as a means to remove combustion products from the combustion chamber through one or more openings at the opposite end of the burner end. The combustion chamber contains one or more reformer tubes in which a mixed-feed of hydrocarbon and steam flow co-current with combustion products and receive direct radiant heat from the combustion flame through the tube wall. The convection chambers contain a tube-in-tube device filled with catalyst in the annuli.
    Type: Application
    Filed: December 24, 2003
    Publication date: July 15, 2004
    Inventors: Hoanh Nang Pham, David Hon Sing Ying, Shoou-l Wang, Scott David Madara, Joel Charles MacMurray
  • Patent number: 6746497
    Abstract: A waste is dry-distilled in a gasification furnace and generated combustible gas is combusted in a combustion furnace. A temperature in the combustion furnace is set to be substantially constant at a first preset temperature or more. When the temperature in the combustion furnace is greater than the first preset temperature by combustion of other fuels, the combustible gas is introduced. When the temperature in the combustion furnace reaches a second preset temperature or more by the combustion of only the combustible gas, the combustion of the other fuels is finished. When the temperature in the combustion furnace falls below a third preset temperature the combustion of the other fuels is resumed. When the temperature in the gasification furnace falls below a fourth preset temperature, the combustion of the other fuels is finished.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: June 8, 2004
    Assignee: Kinsei Sangyo Co., Ltd.
    Inventor: Masamoto Kaneko
  • Patent number: 6733552
    Abstract: A hydrogen generating apparatus having a fuel feeding part, a water feeding part for fuel reforming, an oxidant gas feeding part, a reforming catalyst body, a heating part for the reforming catalyst, a CO shifting catalyst body and a CO purification catalyst body is provided wherein the reforming catalyst body, the CO shifting catalyst body and the CO purification catalyst body are sequentially ordered from the fuel feeding part toward the downstream side, and wherein a shifting catalyst of the shifting catalyst body contains as one component at least a platinum group-type catalyst.
    Type: Grant
    Filed: March 13, 2000
    Date of Patent: May 11, 2004
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Kiyoshi Taguchi, Takeshi Tomizawa, Kunihiro Ukai, Toshiyuki Shono, Kouichiro Kitagawa
  • Publication number: 20040049982
    Abstract: A hydrogen supply system is configured so that a hydrogen supply station and a mobile hydrogen production system 1 are included, and hydrogen produced by the mobile hydrogen production system is supplied to the hydrogen supply station.
    Type: Application
    Filed: August 5, 2003
    Publication date: March 18, 2004
    Inventors: Taku Shimizu, Masaki Iijima, Masahiro Hirano, Kazuto Kobayashi, Akira Oguchi, Kennosuke Kuroda
  • Publication number: 20040052724
    Abstract: A process for the producton of pure syngas (hydrogen and carbon dioxide) by fast gasification of liquid, muddy, or solid raw materials, either produced for the purpose or from industrial processes in which they can not be recycled, or fuels from wastes or biomass, which process is carried out in a modular reactor including a raw materials feeding area, a gasification area, a discharging area of the residues in powdery or vitrified form.
    Type: Application
    Filed: September 24, 2003
    Publication date: March 18, 2004
    Inventor: Vincenzo Sorace
  • Patent number: 6692707
    Abstract: Monolith catalyst 42 is disposed in the reaction layer 40 of reformer 20, the monolith catalyst 42 carrying a copper-zinc catalyst which accelerates a water vapor reforming reaction and an oxidation reaction of methanol on a monolith carrier with a ratio of the length to the diameter between 5 and 18, more preferably 8 and 15, 600 to 3400 cells per square inch, more preferably 900 to 3000 cells per square inch, and formed from ceramics of low thermal conductivity at the region within 15 mm from the flow-in end of the mixture gas and from a metal of high thermal conductivity at the other portions. As a result, the degree of freedom of design and the efficiency of the water vapor reforming reaction can both be improved.
    Type: Grant
    Filed: February 7, 2000
    Date of Patent: February 17, 2004
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Takeshi Hirabayashi
  • Publication number: 20040006917
    Abstract: A fuel preparation apparatus in which coal or coal and other carbon containing material is converted to an environmentally acceptable fuel gas by the reaction with air and steam at a pressure of from 20 to 90 pounds per square inch absolute suitable for providing fuel to a gas turbine, or a stoker type or other boiler having a coal delivery system, a coal crusher, coal storage bins, lock hoppers, a gasifier vessel of two stages, liquid and solid separator vessels, heat and steam recovery vessels, equipment to control the flow of steam and air to the gasifier so as to maintain fuel quality, and a gas clean up plant that will remove environmentally unacceptable components of the gas such as hydrogen sulphide and other sulphur containing compounds and tars and light oils.
    Type: Application
    Filed: July 9, 2002
    Publication date: January 15, 2004
    Inventors: David W. Wakefield, Robert Glover Jackson
  • Patent number: 6648932
    Abstract: A gasification reactor apparatus (10) comprising a gasification vessel (12), a gas-fired combustion chamber (70) and a combination fan and cyclone unit (20) in an upper part (12′) of the vessel (12) with two functions: first, the fan (62, 64) impels incoming feedstock (14, 14′) centrifugally into contact with the hot inside surface of the vessel to produce rapid onset of gasification. Second, the unit (20) exerts a cyclonic motion on the product gas causing outward separation of particulate matter from the gas, which passes to the outlet via a path through the middle of the vessel (12).
    Type: Grant
    Filed: March 15, 2000
    Date of Patent: November 18, 2003
    Assignee: Graveson Energy Management Ltd.
    Inventor: Maurice Edward George Maton
  • Patent number: 6648931
    Abstract: A turbine produces in an improved gasification process a stream of pressurized air, which is cooled and further compressed by a cooler and booster/compressor. The cooled and compressed air is humidified in a humidifier, heated by a low temperature heat source and subsequently fed into a gasification vessel in which a feedstock is gasified or partially oxidized. The humidifier may advantageously utilize wastewater to humidify the cooled and compressed air, wherein the wastewater may or may not be produced by a component in a gasification plant.
    Type: Grant
    Filed: August 8, 2000
    Date of Patent: November 18, 2003
    Assignee: Fluor Corporation
    Inventor: Ashok Rao
  • Publication number: 20030188486
    Abstract: A reformer (5) which generates hydrogen-rich reformate gas by causing a catalytic reaction of fuel and air comprises a premixing chamber (12) for premixing the fuel with the air. High temperature air is supplied to the premixing chamber (12) from an air intake tube (13) via an orifice (14). A fuel injector (16) injects the fuel into the flow of the high temperature air in the premixing chamber (12) to generate fuel-air mixture. A homogenizing filter (17) homogenizes the composition of the fuel-air mixture in the premixing chamber (12) and supplies a uniform fuel-air mixture to a reforming catalyst (11).
    Type: Application
    Filed: February 25, 2003
    Publication date: October 9, 2003
    Applicant: NISSAN MOTOR CO., LTD.
    Inventors: Shiro Tanaka, Mikiya Shinohara, Akihiro Sakakida, Tadashi Shoji
  • Publication number: 20030182861
    Abstract: The present invention provides a method for carrying out high temperature thermal dissociation reactions requiring rapid-heating and short residence times using solar energy. In particular, the present invention provides a method for carrying out high temperature thermal reactions such as dissociation of hydrocarbon containing gases and hydrogen sulfide to produce hydrogen and dry reforming of hydrocarbon containing gases with carbon dioxide. In the methods of the invention where hydrocarbon containing gases are dissociated, fine carbon black particles are also produced. The present invention also provides solar-thermal reactors and solar-thermal reactor systems.
    Type: Application
    Filed: March 7, 2003
    Publication date: October 2, 2003
    Inventors: Alan W. Weimer, Jaimee K. Dahl, Allan A. Lewandowski, Carl Bingham, Karen J. Raska Buechler, Willy Grothe
  • Patent number: 6613111
    Abstract: A process and method is provided for operating a small-scale high-throughput gasifier. As is known in the art, the exothermic combustion reactions can be separated from the endothermic gasification reactions. The exothermic combustion reactions can take place in or near the combustor while the endothermic gasification reactions take place in the gasifier. Heat from the exothermic zone is transferred to the endothermic reaction zone by circulation of an inert particulate solid such as sand. In order to increase efficiency by reducing heat loss from the gasifier, the gasifier is concentrically-disposed within the endothermic reaction zone of the combustor.
    Type: Grant
    Filed: November 16, 2001
    Date of Patent: September 2, 2003
    Assignee: Future Energy Resources Corporation
    Inventor: Mark A. Paisley
  • Publication number: 20030154655
    Abstract: A process for converting carbon monoxide and water in a reformate stream into carbon dioxide and hydrogen comprising: generating a reformate by reacting a hydrocarbon via partial oxidation, steam reforming, or both, including autothermal reforming; and promoting a water gas shift in the reformate in the presence of a platinum group metal selected from the group consisting of platinum, palladium, iridium, osmium, rhodium and mixtures thereof, supported on zirconium oxide. The platinum group metal advantageously may be supported directly on a monolithic substrate composed of zirconium oxide.
    Type: Application
    Filed: February 24, 2003
    Publication date: August 21, 2003
    Inventors: Prashant S. Chintawar, Craig Thompson, Mark R. Hagan
  • Publication number: 20030150161
    Abstract: An apparatus and a method fractionate solid fuels, especially whole tires, into metal as well as volatiles and coal to be used as alternative fuels. The apparatus includes a feeding zone wherein the solid fuels are fed to the apparatus, a gasifying zone into which the solid fuels are processed, obtaining a gaseous fraction, coal, and metal; cooled grills controlling the bed permeability and permanence time of the solid fuels at the gasifying zone; and a discharging zone into which the resultant coal and metal are discharged, in which the solid fuel coal and solid and gaseous fractions follow a path inside the apparatus through the feeding zone, the gasifying zone and discharging zone, and in which the gases inside the apparatus follow a path that is co-current with the solid fuel fractions path inside the apparatus.
    Type: Application
    Filed: August 26, 2002
    Publication date: August 14, 2003
    Inventors: Armando Garcia-Segovia, Luis Ramon Farias-Martinez, Jose Javier Garza-Ondarza, Jorge Berrun-Castanon, Hector Agustin Cantun-Martinez, Angel Cuevas-Martinez
  • Publication number: 20030150163
    Abstract: A fuel reforming method includes the step of supplying carbon-containing fuel and steam to a reactor filled with a fuel reforming catalyst and a CO2 absorbent and discharging CO2, and setting the absorbent at an absorption temperature, thereby converting the carbon-containing fuel into reformed fuel, and separating CO2 from the reformed fuel, the step of obtaining a product gas by oxidizing a portion of the reformed fuel and/or the carbon-containing fuel with an oxidizer, and heating the absorbent with this product gas to a regeneration temperature, thereby regenerating the absorbent and storing heat in this absorbent, and the step of supplying the carbon-containing fuel and steam to the reactor, thereby cooling, to the absorption temperature, the absorbent heated to the regeneration temperature, and converting the carbon-containing fuel into reformed fuel by heat energy stored in the CO2 absorbent. An apparatus for the method is also disclosed.
    Type: Application
    Filed: January 24, 2003
    Publication date: August 14, 2003
    Inventors: Keiji Murata, Kazuaki Nakagawa, Yoshikazu Hagiwara, Kazuya Yamada, Mitsutoshi Hamamura, Yasuhito Sakakibara, Hidetsugu Fujii
  • Publication number: 20030140558
    Abstract: The refractory protected, replaceable insert for a gasifier includes a replaceable floor edge insert that is formed with a predetermined mating profile that is complementary to a finished mating profile of the gasifier floor. The geometry of the mating profiles of the replaceable floor edge insert and the gasifier floor permit removable engagement between the floor edge insert and the mating profile of the gasifier floor. The replaceable floor edge insert is protected by a ring-like arrangement of hanging refractory bricks that each include an appendage. Each brick appendage covers a portion of the inner radial edge of the replaceable floor edge insert and also covers an upper surface portion of an underlying quench ring, thus prolonging the life of the floor and the quench ring. A refractory ceramic fiber paper can be provided between the hanging brick and the floor edge and quench ring.
    Type: Application
    Filed: January 16, 2003
    Publication date: July 31, 2003
    Applicant: Texaco Development Corporation and Texaco, Inc.
    Inventors: John Corwyn Groen, John D. Winter
  • Publication number: 20030131533
    Abstract: An apparatus for a hydrocarbon reforming process includes a combustion chamber, a convection chamber in fluid communication with the combustion chamber, at least one burner disposed in the combustion chamber, a reaction chamber, a means for flowing a first mixed-feed through a first part of the reaction chamber, and a means for flowing a second mixed-feed through an annular portion of a second part of the reaction chamber, the second part being a tube-in-tube in fluid communication with the first part. The burner(s) generates a flow of a flue has having a sensible heat from the combustion chamber to the convection chamber. The flow of the flue has in the convection chamber is counter-currently with the flow of the second mixed-feed.
    Type: Application
    Filed: January 14, 2002
    Publication date: July 17, 2003
    Inventors: Hoanh Nang Pham, Shoou-I Wang, David Hon Sing Ying, Kevin Boyle Fogash
  • Publication number: 20030115799
    Abstract: A reactor for autothermal reforming of hydrocarbons that allows a reduction of excess-air factor &phgr; during the reforming without resulting in a reduced conversion of the hydrocarbons in an end region of the reaction zone. The reactor includes at least one reaction zone in which is arranged at least one catalyst structure for the reformation so that the educts involved in the reformation are converted while flowing through the reaction zone. A heating device is included for heating the end region of the reaction zone to accelerate the conversion of the hydrocarbons.
    Type: Application
    Filed: December 4, 2002
    Publication date: June 26, 2003
    Applicant: DaimlerChrysler AG
    Inventors: Andreas Docter, Bernhard Vogel, Steffen Oliver Wieland
  • Publication number: 20030110694
    Abstract: Abstract of the Invention This invention is directed to a process for producing syngas by increasing the flow of a mixture of steam and methane into a steam methane reformer reaction. This process comprises adding an oxygen-enriched gas to the steam to produce an enriched-oxygen/steam mixture prior to mixing the steam with the methane in the reformer reaction. Oxygen-enriched gas may be added directly to the steam-methane mixture, or to the combustion air. Oxygen-enriched gas may also be added to the air-methane mixture of a gas turbine for operation with the steam methane reforming process.
    Type: Application
    Filed: December 17, 2001
    Publication date: June 19, 2003
    Inventors: Raymond Francis Drnevich, Gary Wayne Fenner, Hisashi Kobayashi, Lawrence E. Bool
  • Publication number: 20030110693
    Abstract: This invention is directed to a process for increasing production of product that is formed in a reactor having a combustion section in which fuel is burned to produce heat to drive an endothermic reaction occurring within a reaction section. Production is increased by adding supplemental oxygen to air or other oxygen containing gas used to support combustion in the combustion section, thereby to generate more heat to support an increase in the endothermic reaction. Additionally, supplemental oxygen can be introduced into the reaction section to partially oxidize a reactant to generate heat and to allow an increase in the production of the product. Supplemental oxygen may be added directly to the steam-methane mixture, or to the combustion air.
    Type: Application
    Filed: August 21, 2002
    Publication date: June 19, 2003
    Inventors: Raymond Francis Drnevich, Gary Wayne Fenner, Hisashi Kobayashi, Lawrence E. Bool
  • Publication number: 20030101650
    Abstract: A reformer that includes a housing including a tubular member and an end plate member hermetically joined to the tubular member. The housing defines within it a first fluid flow path and a second fluid flow path in a heat exchanging relationship with each other. A reforming catalyst is disposed within the first fluid flow path. The tubular member has a tubular end, and the end plate member has an abutting rim that contacts with and extends along the tubular end of the tubular member and that is folded together over an entire circumference thereof to define a folded hermetic seam between the tubular member and the end plate member. The reformer can be low-priced and it manufacture is easy and efficient.
    Type: Application
    Filed: November 8, 2002
    Publication date: June 5, 2003
    Applicant: Mitsubishi Denki Kabushiki Kaisha
    Inventors: Tatsunori Okada, Kenji Kawaguchi, Hideo Ichimura
  • Publication number: 20030037487
    Abstract: A hydrogen generation system includes a fuel container, a spent fuel container, a catalyst system and a control system for generating hydrogen in a manner which provides for a compact and efficient construction while producing hydrogen from a reaction involving a hydride solution such as sodium borohydride.
    Type: Application
    Filed: July 6, 2001
    Publication date: February 27, 2003
    Inventors: Steven C. Amendola, Philip J. Petillo, Stephen C. Petillo, Richrd M. Mohring
  • Patent number: 6228224
    Abstract: The protective refractory shield for a gasifier includes a refractory attachment that is mechanically secured to a protectable surface of the gasifier. The refractory attachment includes a plurality of attachment members of predetermined angular sector. The refractory attachment is provided to cover a downwardly facing horizontal surface of the gasifier or to be positioned upon a vertical surface thereof. Latching means for the attachment include a projecting formation that projects from the protectable surface that engages a complementary shaped recess in the attachment to mechanically secure the attachment to the protectable surface. The latching means do not form recesses in the protectable surface nor does the refractory attachments form recesses in the protectable surface. Thus the integrity of the protectable surface is maintained while it is protected.
    Type: Grant
    Filed: August 4, 1998
    Date of Patent: May 8, 2001
    Assignee: Texaco Inc.
    Inventor: Donald Duane Brooker
  • Patent number: 6048374
    Abstract: The subject invention pertains to unique and advantageous systems for gasifying and/or liquefying biomass. The systems of the subject invention utilize a unique design whereby heat from a combustion chamber is used to directly gasify or liquefy biomass. In a preferred embodiment, the biomass is moved through a reactor tube in which all the gasification and/or liquefaction takes place. Preferably, char exits the biomass reactor tube and enters the combustion chamber where the char serves as fuel for combustion. The combustion chamber partially surrounds the reactor tube and is in direct thermal contact with the reactor tube such that heat from the combustion chamber passes through the reactor wall and directly heats the biomass within the reactor tube.
    Type: Grant
    Filed: August 18, 1997
    Date of Patent: April 11, 2000
    Inventor: Alex E. S. Green
  • Patent number: 5993751
    Abstract: Embodiments of a pyrolizer are disclosed in which carbonaceous materials are pyrolyzed in a two stage process. In the first stage the materials are moved through a pretreater using augers and are heated to between 180 and 220 degrees C. In the second stage the materials are moved through a pyrolysis reactor using augers and are heated to between 500 and 1,100 degrees C.
    Type: Grant
    Filed: June 2, 1998
    Date of Patent: November 30, 1999
    Inventors: Jack Moriarty, Bill Moriarty, Nathan Moriarty
  • Patent number: 5730763
    Abstract: The invention relates to a process and an apparatus for gasifying liquid and/or fine-grain solid gasification substances and/or for reforming a gas, using a gasification agent, in a reaction (1). In the process the process heat is supplied by heat carrier particles which are heated within a substantially closed circuit in a heater (5) by combustion gases which are produced in a combustion chamber (3), and passed through the reactor (1) in counter-flow relationship with the gasification substance or the gas to be reformed and the gasification agent, and then returned to the heater (5) for renewed heating. In accordance with the invention the particles and the combustion gas form a fluidized bed above at least one grid (34, 34a, 34b, 34c, 34d, 34e) arranged in the heater (5).
    Type: Grant
    Filed: December 2, 1996
    Date of Patent: March 24, 1998
    Assignee: Kortec AG
    Inventors: Mircea Tudor Manulescu, Jean-Paul Vandenhoeck
  • Patent number: 4980029
    Abstract: Gaseous, liguid and solid fuels are recovered from carbonaceous organic waste material by treating charges of waste material in several successive stages including preheating, drying and conversion into solid and gaseous phases, all as a result of heating in a common vessel or in two or three successive vessels. The solid phases are thereupon cooled prior to admission into a bin, either in a separate vessel or in the vessel for conversion into solid and gaseous phases. The gaseous phases are treated to separate oil from reaction water, combustible gases and inert gases. The charges are heated from without and are sealed from the atmosphere during all four stages of treatment. Each charge is mixed during heating and the intensity of mixing action, the heating action and/or the pressure in the vessel can be varied during one or more stages.
    Type: Grant
    Filed: January 23, 1989
    Date of Patent: December 25, 1990
    Assignee: Alfred Bolz GmbH & Co. KG
    Inventors: Alfred Bolz, Gunther Boos
  • Patent number: 4921680
    Abstract: A stepped support and seal plate (44) is sealed to firing tube (18) with an axially compressed seal (62). It carries sleeves (24) and is sealed thereto by gasket seals (55). A diagonal movement seal (69) seals plate (44) to the wall of pressure vessel (10). Bellows (76) has a straight portion (77) at the hot end. Insulation (14) is tapered to provide variations in heat transfer from the bellows to provide a uniform strain pattern in the bellows.
    Type: Grant
    Filed: September 12, 1989
    Date of Patent: May 1, 1990
    Assignee: International Fuel Cells Corporation
    Inventors: Stanley P. Bonk, George F. Morganthaler, Yoshiharu Miura
  • Patent number: 4881947
    Abstract: A high efficiency gasifier employs a rotary kiln having an indirect fired gasifier and a recycle system. The rotary kiln provides an essentially oxygen-free gasifying chamber into which raw feed material is introduced. Radiant tubes within the chamber transfer heat to the incoming raw feed material to pyrolyze it and convert it to char and product gas as the material advances toward the outlet end. The recycle system within the chamber returns both product gas and hot char to a receiving end of the kiln to aid in heat transfer to the raw feed material. The feed is thus heated more rapidly, and less heat input is required. Efficiency is further aided by providing additional residence time and gasification of the char.
    Type: Grant
    Filed: June 28, 1988
    Date of Patent: November 21, 1989
    Inventors: Thomas H. Parker, Virgil J. Flanigan
  • Patent number: 4865624
    Abstract: The present invention relates to a steam reforming method of methanol for obtaining hydrogen gas and a system therefor. The present method and present system utilizes a heat transfer medium for regulating the temperature at each step of the process. By optimizing the flow so that the heat transfer medium circulate through the system as heat-exchanging with reactant at each step, temperature of the reactant is regulated at a desirable temperature for proceeding the reaction. Temperature of the decomposition process and the conversion process of methanol is independently regulated.
    Type: Grant
    Filed: June 28, 1988
    Date of Patent: September 12, 1989
    Assignee: Nippon Sanso Kabushiki Kaisha
    Inventor: Hidetake Okada
  • Patent number: 4756722
    Abstract: Part of the synthesis gas produced by coal gasification in an allothermically heated fluidized bed reactor is burned after removal of dust and sulfur and serves as a source of energy to heat the reactor by indirect heat exchange and to produce the steam required for the gasification process. The flue gas exiting from the heat exchanger of the reactor can be used to perform work in expansion turbines. The rest of the synthesis gas is available for use in downstream processes, such as iron ore reduction, or can be burned and used to perform work in turbines to produce electric current. The result is a process that is environmentally safer and operates with a better yield than direct coal burning or autothermal coal gasification, but requires no outside source of energy, such as nuclear power, as prior art allothermal coal gasification processes do.
    Type: Grant
    Filed: March 10, 1987
    Date of Patent: July 12, 1988
    Assignee: M.A.N. GHH
    Inventors: Klaus Knop, Gunter Wolters, Helmut Kubiak
  • Patent number: 4740216
    Abstract: A device for the gasification of waste, particularly light waste, is comprised of a reactor having a single fluidized bed including two concentric chambers communicating at the top and bottom wherein the outer chamber is intended to implement the pyrolysis of supplied waste and the inner chamber is intended to implement the combustion of pyrolyzed materials. A circulation of pyrolysis gas and combustion gas is established between the outer chamber and the inner chamber.
    Type: Grant
    Filed: March 13, 1986
    Date of Patent: April 26, 1988
    Assignee: Cokerill Mechanical Industries, Inc.
    Inventor: Georges A. L. Allard
  • Patent number: 4507127
    Abstract: This invention is a system for recovering resources from sludge in which sludge including water of 90 to 70 percent is first supplied to a sludge concentrator invented by the inventor through a forced supply equipment where the sludge is concentrated to have water content up to about 60 percent; then is sent to a drying furnace having a fluidized sand bed.A product yielded in the said drying furnace is separated to gas and solid. After the separated gas is pressurized by a fan and is heated by a heat exchanger through a circulation passage, a required part thereof is supplied to the drying furnace as gas for drying and the remainder is sent to the said sludge concentrator. After the water content is removed from the gas concentrated and the gas yielded by the said sludge concentrator is used in the system as gaseous fuel.
    Type: Grant
    Filed: September 8, 1982
    Date of Patent: March 26, 1985
    Assignee: Nippon Furnace Kogyo Co., Ltd.
    Inventor: Yasuo Hirose
  • Patent number: 4482359
    Abstract: A combustible gas producer plant is described in which a finely divided inert particulate material fluidized bed is divided into a first, combustible-gas producing section and a second, heating section, to both of which sections fuel is fed. Heat transfer, by bed material migration, from the second to the first section sustains the reaction in the first section leading to the production of combustible gas. A diaphragm water wall divides and surrounds the volumes above bed sections and is part of a boiler generating steam used (optionally with added oxygen) to fluidize the first bed section. The steam is also used to fluidize the bed material at the boundary of the bed sections and prevent in-bed gas migration across that boundary. The second section of the bed is fluidized with air or an air/inert gas mixture. Fluidization is effected with sparge tubes and the plant may include evaporator, superheater and economizer sections for the boiler.
    Type: Grant
    Filed: July 20, 1982
    Date of Patent: November 13, 1984
    Assignee: The Energy Equipment Company Limited
    Inventor: Peter B. Caplin
  • Patent number: 4367075
    Abstract: A thrust containment apparatus is disclosed for use with a pressurized rotary kiln gasifier. The thrust containment apparatus maintains stationary hoods mounted on both ends of the kiln shell in fixed positions by relieving the hoods of forces generated by high pressures within the kiln. The thrust containment device comprises braces mounted on the hoods on the sides remote from the kiln shell. Tie members, or tie rods, extending along the exterior of the kiln shell connect the braces. An expandable bellows is provided between one brace and its adjacent hood. As tie members deform through thermal and tensile expansion, the bellows accomodates the expansion while maintaining a gas-tight seal between the hood and the brace.
    Type: Grant
    Filed: November 16, 1981
    Date of Patent: January 4, 1983
    Assignee: Allis-Chalmers Corporation
    Inventor: Walter J. Hartwig
  • Patent number: 4344773
    Abstract: In a device for the gasification of carbon and/or carbon-containing media, in particular for the continuous production of a gas essentially containing CO and H.sub.2 with a molten bath of iron or an iron alloy, a reactor receives the carbon-containing media and oxidizing gasification media under the surface of the molten bath, and outlets are provided for gas and for removing at least one liquid phase, in particular slag. The reactor is stationary and is tightly sealed to a gas outlet and to a liquid outlet. In a wall region of the reactor and close to the floor thereof a plurality of nozzles are provided for feeding the gasification media. The nozzles are distributed almost symmetrically with respect to a vertical plane which extends axially with respect to the liquid outlet and to the reactor floor about the circumference of the wall region.
    Type: Grant
    Filed: December 18, 1980
    Date of Patent: August 17, 1982
    Assignee: Klockner-Humboldt-Deutz AG
    Inventors: Peter Paschen, Roland Pfeiffer, Heinz-Dieter Waldhecker, Alfred Kryczun, Rolf Pufal
  • Patent number: 4290779
    Abstract: A solar-powered fluidized bed gasification system for gasifying carbonaceous material. The system includes a solar gasifier (10) which is heated by fluidizing gas and steam. Energy to heat the gas and steam is supplied by a high heat capacity refractory honeycomb (16) which surrounds the fluid bed reactor zone (14). The high heat capacity refractory honeycomb (16) is heated by solar energy focused on the honeycomb (16) by solar concentrator (32) through solar window (20). The fluid bed reaction zone (14) is also heated directly and uniformly by thermal contact of the high heat capacity ceramic honeycomb (16) with the walls of the fluidized bed reactor (12).Provisions are also made for recovering and recycling catalysts used in the gasification process. Back-up furnace (50) is provided for start-up procedures and for supplying heat to the fluid bed reaction zone (14) when adequate supplies of solar energy are not available.
    Type: Grant
    Filed: May 15, 1980
    Date of Patent: September 22, 1981
    Inventors: Robert A. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Frosch, Shaik A. Qader
  • Patent number: 4236899
    Abstract: A gas generator which comprises a heat resistant housing and a reaction chamber which is centrally arranged therein and contains a catalytic charge, with an inlet opening for the reactants and an outlet opening for the fuel gas is used for catalytically reacting liquid, hydrocarbon containing fuel to be evaporated with an oxygen containing gas at elevated temperature to form a fuel gas. The housing consists of a lower part and a removable cover and the reaction chamber including the catalytic charge is replaceable. The fuel and/or the oxygen containing gas is fed to the reaction chamber for preheating and evaporating, respectively, via a system of tubes which is arranged between the reaction chamber and the lower part of the housing and is run around the reaction chamber in helical fashion.
    Type: Grant
    Filed: September 20, 1978
    Date of Patent: December 2, 1980
    Assignee: Siemens Aktiengesellschaft
    Inventors: Peter Gulden, Friedrich Kozdon, Eugen S. de Bucs, Walter Kusebauch, Helmut Forster, Mathias Schnicke, Heinz Christoph, Berthold Pfadenhauer, Gerald Edinger