Devitrified Glass-ceramics Patents (Class 501/2)
  • Patent number: 5281563
    Abstract: A dental ceramic material is disclosed for the preparation and repair of metal ceramic and fully ceramic dentures, which has a processing temperature of 660.+-.30.degree. C., and has the following composition: 60 to 65% by weight of SiO.sub.2, 8.5 to 11% by weight of Al.sub.2 O.sub.3, 8 to 12% by weight of K.sub.2 O, 10.5 to 12% by weight of Na.sub.2 O, 0.7 to 2% by weight of CaO, 0.6 to 2% by weight of BaO, 0.5 to 2.5% by weight of B.sub.2 O.sub.3, 0.1 to 0.6% by weight of Sb.sub.2 O.sub.3, 0 to 0.5% by weight of CeO.sub.2, 1.2 to 3.8% by weight of TiO.sub.2, 0.8 to 1.4% by weight of Li.sub.2 O, and 1.2 to 3.8% by weight of F.sub.2.
    Type: Grant
    Filed: November 20, 1992
    Date of Patent: January 25, 1994
    Assignee: Degussa Aktiengesellschaft
    Inventors: Ottmar Komma, Juergen Steidl
  • Patent number: 5173331
    Abstract: A ceramic material suitable for packaging of large scale integrated circuits is produced by the process of forming a mixture of a powdered glass ceramic material which is a glassy precursor to cordierite ceramic material, formed by the steps which are as follows:a. Mix tetragonal phase material selected from the group consisting of zirconia of hafnia powder containing a stabilizing oxide compound selected from the group consisting of MgO, CaO and Y.sub.2 O.sub.3 and a glass frit powder or frit of a glassy precursor of cordierite glass ceramic to yield a suspension of solids. Preferably, a binder is included.b. Disperse the suspended solids to yield a dispersion of the zirconia or hafnia with the stabilizing oxide compound and the glassy precursor.c. Densify the dispersion of zirconia or hafnia with the stabilizing oxide compound and the glassy precursor by a sintering heat treatment at a temperature of about 840.degree. C.
    Type: Grant
    Filed: August 12, 1991
    Date of Patent: December 22, 1992
    Assignee: International Business Machines Corporation
    Inventors: Richard W. Adams, Jr., David R. Clarke, Sarah H. Knickerbocker, Linda L. Rapp, Bernard Schwartz
  • Patent number: 5110357
    Abstract: In a mold material for use in molding a titanium cast to be mounted into the mouth as a dental prosthesis, magnesia and phosphate are added as a binder to its main ingredient composed of alumina and zirconia.
    Type: Grant
    Filed: August 3, 1990
    Date of Patent: May 5, 1992
    Assignee: Iwatani Sangyo Kabushiki Kaisha (Iwatani International Corp.)
    Inventors: Akira Kuwano, Yoshimasa Kidowaki
  • Patent number: 5074916
    Abstract: Sol-gel processing techniques are used to produce alkali-free bioactive glass compositions based on SiO.sub.2, CaO and P.sub.2 O.sub.5. By varying the SiO.sub.2 content, a range of hydroxyapatite production rates can be obtained; conversely, varying the time of exposure to actual or simulated in vivo solutions permits use of a range of allowable proportions of SiO.sub.2. The sol-gel derived compositions can be chosen to achieve target values for thermal expansion coefficient, elastic modulus and volume electrical resistivity.
    Type: Grant
    Filed: May 18, 1990
    Date of Patent: December 24, 1991
    Assignee: Geltech, Inc.
    Inventors: Larry L. Hench, Arthur E. Clark, Rounan Li
  • Patent number: 4931413
    Abstract: Glass ceramic precursor compositions comprise from about 15 to about 75 percent by weight of titanium diboride and from about 10 to about 85 percent by weight of a silica compound, such as colloidal silica. The glass ceramic precursor compositions may also contain an amount up to about 60 percent by weight of an intemetallic compound, such as silicon carbide. Upon firing of the precursor compositions, glass ceramic materials are formed which are useful at high temperatures and in harsh environments as sealants, as protective coatings or as articles of manufacture.
    Type: Grant
    Filed: July 5, 1988
    Date of Patent: June 5, 1990
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Richard L. Weir, Jeannine A. Pearsall
  • Patent number: 4877484
    Abstract: Disclosed are flocced mineral materials which may be utilized to prepare high temperature resistant, water resistant articles. These materials are prepared by utilizing, as a starting material, a gellable layered swelled silicate that has an average charge per structural unit that ranges from about -0.4 to -1 and which contains interstitial cations which promote swelling with a source of at least one species of multi-amine derived cations.
    Type: Grant
    Filed: February 17, 1987
    Date of Patent: October 31, 1989
    Assignee: Armstrong World Industries, Inc.
    Inventors: Walter J. Bohrn, Richard A. Brubaker, Shelly N. Garman, Lewis K. Hosfeld, Kenneth K. Ko, Thomas M. Tymon
  • Patent number: 4861646
    Abstract: Glass-ceramic packages for integrated circuits containing multi-layer, interconnected thick film wiring patterns are obtained by co-sintering a glass-ceramic composite and copper, silver, palladium, gold, based conductors at temperatures not exceeding about 1000.degree. C. The dielectric systems include composites of borosilicate glasses and crystalline fillers which are fabricated by either mixing glass frit and the filler or by a sol-gel coating process. The package is fabricated using a tape specifically designed for clean binder burnout in a reducing atmosphere at low temperatures and also for superior mechanical and thermal properties. Metallization, applied by the thick film screening technique, utilized herein has glass-ceramic bonding agents designed to promote adhesion yet maintain the desired electrical properties and post-processing characteristics.
    Type: Grant
    Filed: August 13, 1987
    Date of Patent: August 29, 1989
    Assignee: Ceramics Process Systems Corp.
    Inventors: Eric A. Barringer, Sheldon I. Lieberman, Mark S. Schmidt, James D. Hodge, Richard Waack, Donald J. Kelley, Brian W. Saxton, William C. Gruber
  • Patent number: 4775646
    Abstract: A fluoride-containing bioactive glass composition suitable for bulk implant prosthetic devices and coatings for prosthetic devices, the bioactive glass compositions selected from glass formulations containing, by mole 46.1% SiO.sub.2, 2.6% P.sub.2 O.sub.5, 26.9% CaO and 24.4% Na.sub.2 O and glass formulations containing, by mole, 52.1% SiO.sub.2, 23.8% CaO, 21.5% Na.sub.2 O, 2.6% P.sub.2 O.sub.5 wherein, respectively, 30 to 50 molar percent and 40 to 60 molar percent of the CaO is substituted with CaF.sub.2. These fluoride-containing bioactive glass materials demonstrate high resistance to demineralization in physiological fluids as well as extensive apatite formation which shows a predominance of crystalline apatite of mixed phase character.
    Type: Grant
    Filed: September 10, 1986
    Date of Patent: October 4, 1988
    Assignee: University of Florida
    Inventors: Larry L. Hench, Derek B. Spilman, June W. Hench
  • Patent number: 4772346
    Abstract: In a process for forming elements from a slurry that includes particulate ceramic and/or glass, an organic binder resin, and a solvent for the resin, where the element is shaped from the slurry, and the element heated to remove the organic materials of the slurry and subsequently fuse the ceramic and/or glass particles, the improvement comprised of coating the ceramic and/or glass particles prior to forming the slurry with a surface modification compound selected from the group consisting of organo silanes, organo silazanes, titanium chelates, titanium esters, and mixtures thereof.
    Type: Grant
    Filed: October 29, 1987
    Date of Patent: September 20, 1988
    Assignee: International Business Machines Corporation
    Inventors: Herbert R. Anderson, Jr., Constance J. Araps, Renuka S. Divakaruni, Daniel P. Kirby, Robert W. Nufer, Harbans S. Sachdev, Krishna G. Sachdev, Darbha Suryanarayana, Stoyan M. Zalar
  • Patent number: 4758538
    Abstract: A foamed ceramic body comprising at least 90% by weight of a ceramic composed of 60 to 80% by weight of SiO.sub.2, 5 to 15% by weight of Al.sub.2 O.sub.3, 8 to 14% by weight of an alkali metal oxide, and 1 to 10% by weight of CaO; and a process for producing the said foamed ceramic body, which comprises mixing 100 parts by weight of a powdery mixture composed of 75 to 90% by weight of a volcanic material, 5 to 15% by weight of an alkali metal oxide or compound which forms an alkali metal oxide on heating and 2 to 10% by weight of CaO or a compound which forms CaO on heating, uniformly with 0.1 to 1 part by weight of a blowing agent, and heating the mixture to a temperature of 800.degree. to 1100.degree. C.
    Type: Grant
    Filed: March 21, 1986
    Date of Patent: July 19, 1988
    Assignee: Sekisui Kagaku Kogyo Kabushiki Kaisha
    Inventors: Shyuji Satoh, Tadaoki Ogasawara
  • Patent number: 4642148
    Abstract: A method for producing a multilayer ceramic circuit board including the steps of forming a multilayer structure consisting of patterns of copper-based paste and glass-ceramic layers, the glass-ceramic layers consisting of a mixture of 10 percent to 75 percent by weight of .alpha.-alumina, 20 percent to 60 percent by weight of crystallizable or noncrystallizable glass which can be sintered at a temperature lower than the melting point of copper, and 5 percent to 70 percent by weight of quartz glass, based on the total weight of the glass-ceramic, blended with a binder containing a thermally depolymerizable resin; prefiring the multilayer structure in an inert atmosphere containing water vapor, the partial pressure of which is 0.005 to 0.3 atmosphere, at a temperature where the thermally depolymerizable resin is eliminated; and firing the multilayer structure in an inert atmosphere containing no water vapor at a temperature below the melting point of copper so as to sinter the glass-ceramic.
    Type: Grant
    Filed: May 28, 1985
    Date of Patent: February 10, 1987
    Assignee: Fujitsu Limited
    Inventors: Kazuaki Kurihara, Nobuo Kamehara, Hiromitsu Yokoyama, Hiromi Ogawa, Kishio Yokouchi, Yoshihiko Imanaka, Koichi Niwa
  • Patent number: 4621066
    Abstract: Low temperature fired ceramics produced by firing at a low temperature a mixture consisting of, in weight percentages:(a) 50 to 65% of powder glass consisting of 10 to 55% of CaO, 45 to 70% of SiO.sub.2, 0 to 30% of Al.sub.2 O.sub.3 and up to 10% of impurities; and(b) 50 to 35% of powder Al.sub.2 O.sub.3 containing up to 10% of impurities. The glass component (a) may further contains B.sub.2 O.sub.3 up to 20% based on the total weight of the former glass-forming components. The ceramics exhibit excellent thermal conductivity, high mechanical strength, low thermal expansion and small dielectric constant and such advantageous combination of properties make them useful in many applications, more especially highly suited to the use as substrate of various electronic parts, components or multilayer integrated circuits. Also, since the ceramics can be prepared at lower firing temperatures and a higher heating rate, the production cost and time can be advantageously saved.
    Type: Grant
    Filed: March 27, 1985
    Date of Patent: November 4, 1986
    Assignee: Narumi China Corporation
    Inventors: Susumu Nishigaki, Shinsuke Yano, Shirohito Matsuyama
  • Patent number: 4522924
    Abstract: The present invention relates to an immobilized enzyme composite having a mica carrier. More particularly, the composite comprises a mixture of an enzyme and a water-swelling mica selected from fluorohectorite, boron fluorophlogopite, hydroxyl boron phlogopite and solid solutions of at least one mica and a structurally compatible species selected from talc, fluorotalc, polylithonite, fluoropolylithonite, phlogopite, and fluorophlogopite.
    Type: Grant
    Filed: March 29, 1984
    Date of Patent: June 11, 1985
    Assignee: Corning Glass Works
    Inventors: David L. Tennent, Bhavender P. Sharma
  • Patent number: 4490645
    Abstract: A color television display tube having attached to the cone surface abutments in the form of studs or wedges against which the system of deflection coils is placed. The abutments consist of a glass-ceramic material which enables them to be manufactured in a simple manner and allows attachment by means of a rigid lasting glued joint between the abutments and the cone.
    Type: Grant
    Filed: November 15, 1982
    Date of Patent: December 25, 1984
    Assignee: U.S. Philips Corporation
    Inventor: Robert Hamersma
  • Patent number: 4455382
    Abstract: This invention is directed to the preparation of neutralized polyelectrolyte complexes exhibiting hydrophobic behavior containing crystals of an organic polycation exchanged lithium and/or sodium water-swelling mica. The process for making such products comprises:(1) forming a glass-ceramic body containing crystals selected from the group of fluorhectorite, hydroxyl hectorite, boron fluorphlogopite, hydroxyl boron phlogopite, and solid solutions among those and between those and other structurally-compatible species selected from the group of talc, fluortalc, polylithionite, fluorpolylithionite, phlogopite, and fluorphlogopite;(2) contacting that body with a polar liquid to cause swelling and disintegration of the body accompanied with the formation of a gel; and(3) contacting said gel with a source of organic polycations to cause a reaction between the Li.sup.+ and/or Na.sup.
    Type: Grant
    Filed: January 27, 1983
    Date of Patent: June 19, 1984
    Assignee: Corning Glass Works
    Inventor: Shy-Hsien Wu
  • Patent number: 4453981
    Abstract: There is disclosed a method of producing a slurry composed of ion-exchanged, synthetic mica crystals dispersed in a polar liquid. The method comprises providing a synthetic, lithium and/or sodium, water-swelling body of selected crystal type, and dispersing the mica body in the polar liquid while simultaneously effecting an exchange of larger cations from a contacting source with lithium and/or sodium ions from the mica crystals. The synthetic mica body may be vigorously mixed in a dilute solution of the exchangeable ion source. Alternatively, the mica body may be disintegrated in a mixer, the exchangeable ion source added to form a paste and more liquid added to dilute the paste.
    Type: Grant
    Filed: March 2, 1983
    Date of Patent: June 12, 1984
    Assignee: Corning Glass Works
    Inventor: Mark P. Taylor
  • Patent number: 4454237
    Abstract: This invention is directed to the preparation of an organic-inorganic composite body demonstrating hydrophobic behavior containing crystals of an organic polycation-exchanged lithium and/or sodium water-swelling mica, the organic polycation being selected from the group of aminosilanes and organic chrome complexes.
    Type: Grant
    Filed: January 27, 1983
    Date of Patent: June 12, 1984
    Assignee: Corning Glass Works
    Inventors: Syed N. Hoda, Anthony R. Olszewski
  • Patent number: 4340839
    Abstract: Highly densed zinc sulfide ceramic materials, which essentially comprise zinc sulfide and alkali metals and/or alkaline earth metals and impurities acting as luminescent center, and which show a high brightness of cathode luminescence under irradiation of electron beam having a low energy, are easily made in the form of the sintered material, by heating the mixture of the said materials in inert or sulfuring atmosphere.
    Type: Grant
    Filed: December 20, 1979
    Date of Patent: July 20, 1982
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yosuke Fujita, Fumio Fukushima, Yoji Fukuda, Tsuneharu Nitta
  • Patent number: 4315778
    Abstract: A flux composition for ceramic color, containing no harmful heavy metal such as lead, cadmium, chromium, etc. is provided.The flux composition consists mainly of 30 to 45% of SiO.sub.2, 0 to 5% of TiO.sub.2, 4 to 10% of ZrO.sub.2, 13 to 18% of B.sub.2 O.sub.3, 18 to 23% of ZnO, 0 to 3% of CaO, 12 to 15% of the total of two or three kinds of R.sub.2 O selected from Na.sub.2 O, K.sub.2 O and Li.sub.2 O, 4 to 10% of fluorine and 0 to 5% of tin oxide (% being all by weight).The composition uses no lead which has been indispensable for lower melting glasses, and exhibits superior performances difficult to afford according to conventional lower melting lead-free fluxes.
    Type: Grant
    Filed: April 7, 1980
    Date of Patent: February 16, 1982
    Inventors: Kimitoshi Ueno, Toshio Yoshida
  • Patent number: 4304602
    Abstract: Thermally crystallizable silicon oxynitride glasses containing substantial quantities of MgO, thermally crystallizable to fine-grained glass-ceramic products comprising forsterite, clinohumite and/or a beta-silicon nitride solid solution as the predominant crystal phase, are described.
    Type: Grant
    Filed: September 8, 1980
    Date of Patent: December 8, 1981
    Assignee: Corning Glass Works
    Inventor: Raja R. Wusirika
  • Patent number: 4297139
    Abstract: The present invention is related to the production of crystal-containing gels and papers, films, fibers, boards, and coatings made therefrom. The process for making the gels comprises three general steps: first, a fully or predominantly crystalline body is formed containing crystals consisting essentially of a lithium and/or sodium water-swelling mica selected from the group of fluorhectorite, hydroxyl hectorite, boron fluorphlogopite, hydroxyl boron phlogopite, and solid solutions among those and between those and other structurally-compatible species selected from the group of talc, fluortalc, polylithionite, fluorpolylithionite, phlogopite, and fluorphlogopite; second, that body is contacted with a polar liquid, desirably water, to cause swelling and disintegration of the body accompanied with the formation of a gel; and, third, the solid:liquid ratio of the gel is adjusted to a desired value depending upon the application therefor.
    Type: Grant
    Filed: June 25, 1980
    Date of Patent: October 27, 1981
    Assignee: Corning Glass Works
    Inventors: George H. Beall, David G. Grossman, Syed N. Hoda, Karen R. Kubinski