Binary, Ternary, Quaternary, Etc., Metal Silicate Crystalline Phase (e.g., Mullite, Diopside, Sphene, Plagioclase, Slagcerams Free Of Alumina, Etc.) Patents (Class 501/5)
  • Patent number: 7176154
    Abstract: To provide a ceramic composition and a ceramic wiring board that can be formed by the firing at a low temperature of 1,000° C. or less, has high strength and is advantageous when electronic component regions utilizing a ceramic layer are formed thereon. A raw ceramic material or calcined powder thereof having a composition consisting of 100 parts by mass of a main component that consists of 52 to 62% by mass of SiO2, 12 to 22% by mass of MgO, and 21 to 32% by mass of CaO and 0.5 to 3 parts by mass of a boron component in terms of the oxide form is molded and fired to obtain a ceramic composition that contains a diopside crystal as a primary crystal. By forming a wiring layer with conductive material on a substrate made of the ceramic composition, a ceramic wiring board is obtained.
    Type: Grant
    Filed: February 25, 2004
    Date of Patent: February 13, 2007
    Assignee: Taiyo Yuden Co., Ltd.
    Inventors: Hakuo Kataoka, Keizo Kawamura, Akitoshi Wagawa
  • Patent number: 7172649
    Abstract: The disclosure relates to a leucite glass ceramic doped with nanoscale metal oxide, to a doped leucite glass ceramic powder suitable for its production, to a method for producing the doped leucite glass ceramic, to its use as dental material, to a dental product containing it and to the use of the nanoscale metal oxide powders for the production of the doped glass ceramic or of the doped leucite glass ceramic powder.
    Type: Grant
    Filed: December 30, 2003
    Date of Patent: February 6, 2007
    Assignees: Chemichl AG
    Inventors: Thomas Conrad, Gerhard Meyer
  • Patent number: 7169725
    Abstract: The invention provides a method to transform large quantities of waste glass into useful ceramic products by a low-cost manufacturing process. The method improves green strength compared to previous methods, and does not require water or any other liquid solvent. Only one firing step is needed with a low peak firing temperature of about 700° C.to about 1000° C. The method conserves energy and natural resources compared to clay-based traditional ceramic manufacturing. High-quality impervious ceramic products can be produced by the invention.
    Type: Grant
    Filed: October 8, 2002
    Date of Patent: January 30, 2007
    Inventor: Michael J. Haun
  • Patent number: 7166548
    Abstract: Apatite glass ceramic which contains at least one glass phase and at least one apatite phase and is characterized in that at least one of the apatite phases is a phosphate- and fluorine-free siliceous oxyapatite phase.
    Type: Grant
    Filed: October 26, 2004
    Date of Patent: January 23, 2007
    Assignee: Ivoclar Vivadent AG
    Inventors: Elke Apel, Wolfram Höland, Christian van't Hoen, Urs Bolle, Volker M. Rheinberger
  • Patent number: 7144833
    Abstract: A dielectric ceramic composition containing crystalline glass, amorphous glass and a ceramic filler, characterized in that a softening point of said crystalline glass is higher than a softening point of said amorphous glass and is 900° C. or lower, and 27% by weight or higher of the crystalline glass and less than 20% by weight of the amorphous glass are contained in the ceramic composition and the total content of the crystalline glass and the amorphous glass is 60% by weight or lower, and 40% by weight or higher of the ceramic filler is contained in the ceramic composition.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: December 5, 2006
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Takashi Umemoto, Hiroshi Nonoue, Toshio Tanuma, Kenichiro Wakisaka
  • Patent number: 7141520
    Abstract: The invention relates to a glass ceramic, wherein the initial glass comprises 30–65 percent (by weight) SiO2; 5–30 percent (by weight) Na2O; 5–30 percent (by weight) CaO, and 0-15 percent (by weight) P2O5, and wherein the main crystalline phases comprise alkali—alkaline earth—silicate and/or alkali silicate and/or alkaline earth silicate. The invention is characterized in that either a glass ceramic with a single crystalline phase 1 Na2O—2CaO—3 SiO2 is excluded, or the crystalline size of the glass ceramic is <10 ?m, or the weight fraction of SiO2 is <47%.
    Type: Grant
    Filed: December 11, 2002
    Date of Patent: November 28, 2006
    Assignee: Schott AG
    Inventors: José Zimmer, Jörg Hinrich Fechner
  • Patent number: 7015161
    Abstract: Provided is a substrate for information recording medium composed of such a crystallized glass as having high Young's modulus, strength and heat resistance, being excellent in surface smoothness, surface homogeneity and surface processability, as well as having a relatively low temperature of glass liquid phase and being capable of producing cheaply, and an information recording medium using this substrate. The crystallized glass substrate for information recording medium comprising 35–65 mol % of SiO2, 5–25 mol % of Al2O3, 10–40 mol % of MgO and 5–15 mol % of TiO2, in which the total amount of aforementioned composition is at least equal to or higher than 92 mol % and the main crystals are enstatite and/or its solid solution. The information recording medium having this substrate and a recording layer formed on said substrate.
    Type: Grant
    Filed: March 18, 2005
    Date of Patent: March 21, 2006
    Assignee: Hoya Corporation
    Inventor: Xuelu Zou
  • Patent number: 7015160
    Abstract: Glass powder for a dielectric material has a nature that, when fired, diopside (CaMgSi2O6) and at least one of titanite (CaTi(SiO4)O) and titania (TiO2) are precipitated. Preferably, the glass powder has a composition including SiO2, CaO, MgO, and TiO2 and the total content of these components is 80 mass % or more. Preferably, the glass powder comprises, by mass percent, 35–65% SiO2, 10–30% CaO, 10–20% MgO, and 12–30% TiO2.
    Type: Grant
    Filed: February 18, 2005
    Date of Patent: March 21, 2006
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Yoshikatsu Nishikawa, Yoshio Umayahara
  • Patent number: 6984261
    Abstract: The invention relates to uses of glasses and glass-ceramics in dental and orthodontic applications.
    Type: Grant
    Filed: February 5, 2003
    Date of Patent: January 10, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Kevin M. Cummings, Jacqueline C. Rolf, Anatoly Z. Rosenflanz, Richard P. Rusin, Jerome E. Swanson
  • Patent number: 6942713
    Abstract: An aluminum titanate-based ceramic body having a composition a formula comprising a(Al2O3.TiO2)+b(CaO.Al2O3.2SiO2)+c(SrO.Al2O3.2SiO2)+d(BaO.Al2O3.2SiO2)+e(3Al2O3.2SiO2)+f(Al2O3)+g (SiO2)+h(Fe2O3.TiO2)+i(MgO.2TiO2), wherein a, b, c, d, e, f, g, h, and i are weight fractions of each component such that (a+b+c+d+e+f+g+h+i)=1, wherein 0.5<a?0.95; 0?b?0.5; 0?c?0.5; 0?d?0.5; 0<e?0.5; 0?f?0.5; 0?g?0.1; 0?h?0.3; 0?i?0.3; b+d>0.01. A method of forming the ceramic body is provided. The ceramic body is useful in automotive emissions control systems, such as diesel exhaust filtration.
    Type: Grant
    Filed: September 30, 2004
    Date of Patent: September 13, 2005
    Assignee: Corning Incorporated
    Inventors: Steven B. Ogunwumi, Patrick D. Tepesch, Raja R. Wusirika
  • Patent number: 6924245
    Abstract: A glass ceramic composition which can be fired at a low temperature and which has a high dielectric constant, a relatively small thermal expansion coefficient and a small temperature coefficient of dielectric constant is provided. The glass ceramic composition contains about 5% to 75% by weight of TiO2 powder, about 5% to 75% by weight of CaTiSiO5 powder and about 15% to 50% by weight of glass powder.
    Type: Grant
    Filed: May 21, 2003
    Date of Patent: August 2, 2005
    Assignee: Murata Manufacturing Co., Ltd.
    Inventor: Sadaaki Sakamoto
  • Patent number: 6914023
    Abstract: The object of the present invention is to provide a flat-panel-display substrate which is high in heat resistance, of which the coefficient of thermal expansion is approximated to that of a thick film dielectric layer, which is low at high temperatures in reactivity with the lead-doped thick film dielectric layer, and which can be made to have a large area. The substrate of the present invention is obtained by sintering a body comprising glass powder and a filler made of metal and/or semi-metal oxide, and is constituted by the sintered body and whose average coefficient of linear thermal expansion is from 7 to 9.5 ppm/° C. in the temperature range of 25 to 700° C. The glass powder includes alkaline-earth oxide, 15 to 50% by weight of silicon oxide, and no greater than 2% by weight of boron oxide. Furthermore, the filler is at a concentration of 10 to 30% by volume of the total amount of the glass powder and the filler in the mould.
    Type: Grant
    Filed: July 16, 2003
    Date of Patent: July 5, 2005
    Assignee: TDK Corporation
    Inventors: Takaji Shimosaka, Yukihiko Shirakawa, Shirou Ootsuki
  • Patent number: 6905988
    Abstract: Provided is a substrate for information recording medium composed of such a crystallized glass as having high Young's modulus, strength and heat resistance, being excellent in surface smoothness, surface homogeneity and surface processability, as well as having a relatively low temperature of glass liquid phase and being capable of producing cheaply, and an information recording medium using this substrate. The crystallized glass substrate for information recording medium comprising 35-65 mol % of SiO2, 5-25 mol % of Al2O3, 10-40 mol % of MgO and 5-15 mol % of TiO2, in which the total amount of aforementioned composition is at least equal to or higher than 92 mol % and the main crystals are enstatite and/or its solid solution. The information recording medium having this substrate and a recording layer formed on said substrate.
    Type: Grant
    Filed: July 3, 2003
    Date of Patent: June 14, 2005
    Assignee: Hoya Corporation
    Inventor: Xuelu Zou
  • Patent number: 6897172
    Abstract: The present invention provides a dielectric ceramic composition comprising: 30 to 90% by weight of a crystallized glass powder capable of depositing a diopside crystal, 1 to 40% by weight of a calcium titanate powder, a strontium titanate powder or a mixed powder thereof, and 0 to 60% by weight of at least one kind of a powder selected from the group consisting of Al2O3, TiO2, ZrO2, MgTiO3, BaTi4O9, La2Ti2O7, Nd2Ti2O7, Ca2Nb2O7, SrZrO3 and CaZrO3, and a dielectric ceramics obtained by firing the same.
    Type: Grant
    Filed: January 23, 2003
    Date of Patent: May 24, 2005
    Assignee: Kyocera Corporation
    Inventors: Tatsuji Furuse, Seiichiro Hirahara, Shuji Nakazawa, Yasushi Ode, Tomoyuki Kojima, Fumiaki Sekine, Hiroshi Makino, Manabu Yonekura
  • Patent number: 6897171
    Abstract: The present invention refers to glass-ceramics consisting of the mixtures (I): ZrO2—SiO2—MeIIO, or (II) SiO2—MeIIIO2—MeIIO, wherein: MeII is chosen in the group consisting of: Ca, Ba, Mg, Zn or mixture thereof; MeIII is chosen in the group consisting of Al, B or mixtures thereof; each of the above said constituents being present in determined quantities; the invention refers also to a process for preparing the glass-ceramics above defined; porcelain stonewares and glazes containing them and their use for preparing ceramic items.
    Type: Grant
    Filed: June 12, 2003
    Date of Patent: May 24, 2005
    Assignee: Colorobbia Italia S.p.A.
    Inventors: Marco Bitossi, Giovanni Baldi, Davide Settembre Blundo, Enrico Generali
  • Patent number: 6878464
    Abstract: A glass-ceramic composite material for use in forming a multilayered circuit substrate is provided which has a low dielectric constant, but exhibits a relatively high thermal expansion coefficient. Specifically, the glass-ceramic composite material comprises a glass power and a ceramic powder. The glass powder contains: about 30 to 60 mol % of SiO2, about 20 to 40 mol % of BaO, 0 to about 40 mol % of MgO, 0 to about 40 mol % of ZnO, 0 to about 20 mol % of B2O3, with the total content of MgO and ZnO being about 10 to 40 mol %. The ceramic powder contains an alumina powder. The content of the glass powder is set to be at least about 50 wt %. A sintered compact formed by sintering the above glass powder and the above ceramic powder contains a BaO.Al2O3.2SiO2 (BaAl2Si2O8) crystal, and its Q value becomes about 400 or more when a measured frequency is 10 GHz.
    Type: Grant
    Filed: October 22, 2002
    Date of Patent: April 12, 2005
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Yoichi Moriya, Osamu Chikagawa, Yasutaka Sugimoto
  • Patent number: 6878651
    Abstract: A glass composition consisting essentially by mol percent of about 55<SiO2<75; 5<BaO<30; and 2 <MgO<22 for use as a matrix of composite materials. A method of making a glass matrix-ceramic particulate composition useful for sealing electrochemical structures, such as solid oxide fuel cells is also disclosed. Method steps include the admixture of finely divided Mg2SiO4 particulates with the matrix glass, to reach an overall composition by mol percent of about 55<SiO2<65; 5<BaO<15; and 25<MgO<35.
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: April 12, 2005
    Assignee: Ford Global Technologies, LLC
    Inventor: Gary Mark Crosbie
  • Patent number: 6875715
    Abstract: Glass powder for a dielectric material has a nature that, when fired, diopside (CaMgSi2O6) and at least one of titanite (CaTi(SiO4)O) and titania (TiO2) are precipitated. Preferably, the glass powder has a composition including SiO2, CaO, MgO, and TiO2 and the total content of these components is 80 mass % or more. Preferably, the glass powder comprises, by mass percent, 35-65% SiO2, 10-30% CaO, 10-20% MgO, and 12-30% TiO2.
    Type: Grant
    Filed: March 4, 2003
    Date of Patent: April 5, 2005
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Yoshikatsu Nishikawa, Yoshio Umayahara
  • Patent number: 6849334
    Abstract: Nanoscale particles, particle coatings/particle arrays and corresponding consolidated materials are described based on an ability to vary the composition involving a wide range of metal and/or metalloid elements and corresponding compositions. In particular, metalloid oxides and metal-metalloid compositions are described in the form of improved nanoscale particles and coatings formed from the nanoscale particles. Compositions comprising rare earth metals and dopants/additives with rare earth metals are described. Complex compositions with a range of host compositions and dopants/additives can be formed using the approaches described herein. The particle coating can take the form of particle arrays that range from collections of disbursable primary particles to fused networks of primary particles forming channels that reflect the nanoscale of the primary particles. Suitable materials for optical applications are described along with some optical devices of interest.
    Type: Grant
    Filed: March 15, 2002
    Date of Patent: February 1, 2005
    Assignee: NeoPhotonics Corporation
    Inventors: Craig R. Horne, Pierre J. DeMascarel, Christian C. Honeker, Benjamin Chaloner-Gill, Herman A. Lopez, Xiangxin Bi, Ronald J. Mosso, William E. McGovern, James T. Gardner, Sujeet Kumar, James A. Gilliam, Vince Pham, Eric Euvrard, Shivkumar Chiruvolu, Jesse Jur
  • Patent number: 6824877
    Abstract: A clay composition comprises, in parts by weight on oxide basis, 10-15% Al2O3, 50-85% SiO2, 0-12.5% B2O3 and 10-20% metal oxides of the form RO or R2O.
    Type: Grant
    Filed: August 29, 2002
    Date of Patent: November 30, 2004
    Inventor: John Howard Groth
  • Patent number: 6821628
    Abstract: The cooking panel is made from an opaque glass-ceramic material uniformly colored throughout and having keatite mixed crystals as the predominant crystalline phase. The cooking panel is made by ceramicizing a ceramicizable glass or a transparent glass-ceramic with high quartz mixed crystals as the predominant crystalline phase in a definite color location range with a brightness parameter value (L*) less than 85 and a color shade and chromaticity according to its later service and wear pattern. The cooking panel makes deposited material, such as dirt and the like, less conspicuous.
    Type: Grant
    Filed: December 9, 1999
    Date of Patent: November 23, 2004
    Assignee: Schott Glas
    Inventors: Bernd Schultheis, Waldemar Weinberg, Monica Cotlear De Witzmann, Roland Dudek, Friedrich Siebers, Klaus Schoenberger
  • Patent number: 6818573
    Abstract: The present invention is concerned with a process for the formation of dental restorations from glass-ceramic materials and the resulting dental restorations. A dental restoration is formed by pressing a lithium discilicate glass ceramic where the concentration of lithium discilicate crystals in the glass ceramic composition is at least 30% by weight. Crystal formation is effected with P2O5. The glass ceramic material may further contain coloring oxides, fluoresing agents, pigments, opacifiers and glass modifiers. The resulting dental restorations have superior optical, esthetic and strength properties.
    Type: Grant
    Filed: October 19, 2002
    Date of Patent: November 16, 2004
    Assignee: TEC Ventures, Inc.
    Inventor: Richard W. Petticrew
  • Patent number: 6802894
    Abstract: This invention is directed to lithium disilicate (Li2Si2O5) based glass-ceramics comprising silica, lithium oxide, alumina, potassium oxide and phosphorus pentoxide. The glass-ceramics are useful in the fabrication of single and multi-unit dental restorations (e.g. anterior bridges) made by heat pressing into refractory investment molds produced using lost wax techniques. The glass-ceramics have good pressability, i.e., the ability to be formed into dental articles by heat-pressing using commercially available equipment. In accordance with one embodiment directed to the process of making the glass-ceramics, the compositions herein are melted at about 1200 ° to about 1600 ° C., thereafter cast into steel molds in the shape of cylindrical blanks (pellets), or alternately, cooled to the crystallization temperature. The resulting glass blank are heat-treated to form glass-ceramic blanks via a one or two step heat-treatment cycle preferably in the temperature range of about 400 ° to about 1100 ° C.
    Type: Grant
    Filed: June 25, 2002
    Date of Patent: October 12, 2004
    Assignee: Jeneric/Pentron Incorporated
    Inventors: Dmitri Brodkin, Carlino Panzera, Paul Panzera
  • Patent number: 6774072
    Abstract: Enclosed are crystallized glasses suitable for a substrate for an information recording medium such as a magnetic disc, optical disc, or optomagnetic disc, a substrate for information recording medium using such a crystallized glass substrate, and an information recording medium using such a substrate for information recording medium. The crystallized glasses are capable of providing a glass substrate having a high Young's modulus, as well as excellent mechanical strength, surface flatness, and heat resistance and having an excellent surface smoothness upon polishing. Glass substrate having an excellent surface smoothness using such a crystallized glass are also disclosed.
    Type: Grant
    Filed: February 25, 2003
    Date of Patent: August 10, 2004
    Assignee: Hoya Corporation
    Inventors: Xuelu Zou, Kouji Azegami
  • Patent number: 6753070
    Abstract: An insulating ceramic compact is provided which can be obtained by low-temperature firing, has a low relative dielectric constant and superior high frequency characteristics, and can be co-sintered with a material having a high coefficient of thermal expansion. The insulating ceramic compact is a fired mixture of an MgAl2O4-based ceramic and a borosilicate glass, in which an MgAl2O4 crystal phase and at least one of an Mg3B2O6 crystal phase and an Mg2B2O5 crystal phase are precipitated as primary crystal phases.
    Type: Grant
    Filed: July 11, 2001
    Date of Patent: June 22, 2004
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Naoya Mori, Yasutaka Sugimoto, Osamu Chikagawa
  • Publication number: 20040072669
    Abstract: A composition for a glass-ceramic material that contains a crystallinity of at least about 30% by weight of forsterite components at a liquidus temperature of about 1525 ° C. or below. The glass-ceramic has a composition, in weight percent on an oxide basis, consisting essentially of about: 40-60% SiO2; 10-25% Al2O3; 18-30% MgO; 3-10% Na2O; 0-10% K2O; >5-15% TiO2. The invention further comprises a method for achieving high crystalline yield at such a low liquidus with increased solubility of high levels of chromium ions. The glass-ceramics can be used in drawing optical fibers and as gain media in amplifier and laser devices for near infrared wavelengths.
    Type: Application
    Filed: September 30, 2003
    Publication date: April 15, 2004
    Inventors: George H. Beall, Joseph E. Pierson, Linda R. Pinckney
  • Patent number: 6703332
    Abstract: A glass-ceramic for substrate of magnetic disks having high strength can be obtained by subjecting to heat treatment a base glass comprising, in terms of weight percent of their oxides, from 65% to 80.0% of SiO2, from 0.5% to 5.0 % of Al2O3, from 13.0% to 19.0% of Li2O, from 1.0% to 7.0% of P2O5, from 0.5% to 10.0% of Y2O3 and from 0.2% to 2.0% of at least one of Sb2O3 and As2O3, and the glass-ceramic comprises Li2O·2SiO2 as the main crystal phase. The glass-ceramic has a bending strength of 230-36O Mpa and a surface roughness of less than 10 Angstroms after final polishing, and is thus suitable for use as substrate of magnetic disk. A process for producing the glass-ceramic is also provided.
    Type: Grant
    Filed: May 16, 2001
    Date of Patent: March 9, 2004
    Assignee: Hubei New Huanguang New Information Materials Co., Ltd.
    Inventors: Bo Peng, Shaolin Huang, Zusheng Zhan, Youming Cao
  • Patent number: 6699807
    Abstract: A glass ceramic, for use as a resistor or a gas-tight glass ceramic solder for use in a spark plug, includes a fused seal of a starting glass fused from a starting mixture containing SiO2, Al2O3, TiO2 and CaO, the fused seal including crystalline phases in at least some areas. A method for producing such a glass ceramic provides for the starting glass to be processed in a first method step to form a starting material, which is heated for a first period of time in a second method step from a starting temperature, which is below the softening temperature of the starting glass, to a fusion temperature, which is above the softening temperature of the starting glass, and is kept at that temperature for a second period of time and finally is cooled again. A spark plug may include a terminal stud and a center electrode, which are electrically connected across a resistor that is formed in at least some areas by the glass ceramic.
    Type: Grant
    Filed: March 23, 2002
    Date of Patent: March 2, 2004
    Assignee: Robert Bosch GmbH
    Inventors: Heinz Geier, Rudolf Pollner, Imke Koengeter, Ulrich Eisele
  • Patent number: 6699605
    Abstract: In a sintered glass ceramic product including at least three layers each of which is formed by a glass ceramic material, the layers are stacked to be substantially symmetrical in a stacking direction and integrally sintered. Among the sintered layers, each of outermost layers and an inner layer adjacent thereto have crystal phases different from each other. Each of the outermost layers and the inner layer have thermal expansion coefficients &agr;1 and &agr;2 selected so that the relationship given by 0<&agr;2−&agr;1<5 ppm is satisfied.
    Type: Grant
    Filed: August 20, 2002
    Date of Patent: March 2, 2004
    Assignee: Nippon Electric Glass Co., LTD
    Inventors: Yoshio Umayahara, Yoshikatsu Nishikawa, Kazuyoshi Shindo
  • Patent number: 6693053
    Abstract: A glass or glass powder is fused from a starting mixture containing approximately 38 wt % to 48 wt % SO2, 15 wt % to 19 wt % Al2O3, 4.5 wt % to 11 wt % TiO2, 0 wt % to 1.5 wt % Na2O, 0 wt % to 1.5 wt % K2O and 23 wt % to 30 wt % CaO. In addition, a glass powder mixture includes two glass powders, a carbon black powder and an organic binder, the first glass powder having a mean particle size of approximately 150 &mgr;m to 250 &mgr;m, the second glass powder having a mean particle size of less than approximately 100 &mgr;m, which may be 10 &mgr;m to 70 &mgr;m. The glass or glass powder mixture is suitable for producing a glass ceramic, such as that used as a resistor seal and/or a gas-tight glass ceramic solder in a spark plug.
    Type: Grant
    Filed: March 22, 2002
    Date of Patent: February 17, 2004
    Assignee: Robert Bosch GmbH
    Inventors: Heinz Geier, Rudolf Pollner, Ulrich Eisele, Peter Wange
  • Publication number: 20040018929
    Abstract: Provided is a substrate for information recording medium composed of such a crystallized glass as having high Young's modulus, strength and heat resistance, being excellent in surface smoothness, surface homogeneity and surface processability, as well as having a relatively low temperature of glass liquid phase and being capable of producing cheaply, and an information recording medium using this substrate.
    Type: Application
    Filed: July 3, 2003
    Publication date: January 29, 2004
    Applicant: HOYA CORPORATION
    Inventor: Xuelu Zou
  • Publication number: 20040014582
    Abstract: This invention relates to glass-ceramic materials in the BaO—La2O3—SiO2 system, which are suitable for processing via a powder route, and which, after heat-treatment have a combination of high thermal expansion and excellent refractoriness. The precursor glass powders of the present invention have compositions on a weight percent basis of 10-55% BaO, 3-50% La2O3, 25-48% SiO2 and optionally up to 30% in total of other compatible metal oxides. The powders are substantially free from alkali metal oxides and from boron oxide such that the refractoriness of the glass-ceramic materials is not compromised. The materials may be advantageously employed at high temperatures in direct combination with other materials of high expansion or may be used to join or hermetically seal components made of other materials having similarly high expansion.
    Type: Application
    Filed: May 30, 2003
    Publication date: January 22, 2004
    Inventor: Michael Budd
  • Publication number: 20040009863
    Abstract: The present invention provides a dielectric ceramic composition comprising: 30 to 90% by weight of a crystallized glass powder capable of depositing a diopside crystal, 1 to 40% by weight of a calcium titanate powder, a strontium titanate powder or a mixed powder thereof, and 0 to 60% by weight of at least one kind of a powder selected from the group consisting of Al2O3, TiO2, ZrO2, MgTiO3, BaTi4O9, La2Ti2O7, Nd2Ti2O7, Ca2Nb2O7, SrZrO3 and CaZrO3, and a dielectric ceramics obtained by firing the same.
    Type: Application
    Filed: January 23, 2003
    Publication date: January 15, 2004
    Applicant: KYOCERA CORPORATION
    Inventors: Tatsuji Furuse, Seiichiro Hirahara, Shuji Nakazawa, Yasushi Ode, Tomoyuki Kojima, Fumiaki Sekine, Hiroshi Makino, Manabu Yonekura
  • Patent number: 6677259
    Abstract: Glass-ceramics for a light filter capable of preventing variation of refractive index in a band-pass filter have a coefficient of thermal expansion within a range from 95×10−7/°C. to 140×10−7/°C. within a temperature range from −20° C. to +70° C. and, preferably, Young's modulus of 85 GPa and bending strength of 10 kg/mm2, and light transmittance for plate thickness of 10 mm of 60% or over within a wavelength range from 950 nm to 1600 nm. Predominant crystal phases of these glass-ceramics should preferably be (a) lithium disilicate and (b) one selected from the group consisting of &agr;-quartz, &agr;-quartz solid solution, &agr;-cristobalite and &agr;-cristobalite solid solution.
    Type: Grant
    Filed: February 4, 2002
    Date of Patent: January 13, 2004
    Assignee: Kabushiki Kaisha Ohara
    Inventors: Naoyuki Goto, Mariko Kataoka, Donald G. Polensky
  • Patent number: 6667256
    Abstract: When ceramic electronic parts such as multilayer ceramic substrates that have a substrate body and metal wiring conductors comprising silver are manufactured, a composition comprising not only a borosilicate glass powder and a ceramic powder, but also an additive powder comprising at least one of cerium oxide, bismuth, bismuth oxide, antimony and antimony oxide is used as a composition for preparing the substrate body. Gray discoloration of the substrate body and yellow discoloration in the vicinities of the metal wiring conductors can be prevented.
    Type: Grant
    Filed: May 2, 2003
    Date of Patent: December 23, 2003
    Assignee: Murata Manufacturing Co., Ltd.
    Inventor: Kenji Masuko
  • Patent number: 6660670
    Abstract: Ceramics containing a diopside crystal phase and a cordierite phase, the remainder being a glass phase and/or other ceramic crystal phases, and having an open porosity of not larger than 1%. The ceramics is obtained by firing at from 800 to 1050° C., and exhibits a dielectric constant of not larger than 7 and a small dielectric loss in a high-frequency region, a ceramic strength of not smaller than 250 MPa, and a coefficient of thermal expansion close to those of the chips such as of Si and Ga—As and of the printed board.
    Type: Grant
    Filed: November 29, 2001
    Date of Patent: December 9, 2003
    Assignee: Kyocera Corporation
    Inventors: Yoshitake Terashi, Hiromi Iwachi, Tsutae Iryo
  • Patent number: 6660669
    Abstract: A composition for a glass-ceramic material that contains a crystallinity of at least about 30% by weight of forsterite components at a liquidus temperature of about 1525° C. or below. The glass-ceramic has a composition, in weight percent on an oxide basis, consisting essentially of about: 40-60% SiO2; 10-25% Al2O3; 18-30% MgO; 3-10% Na2O; 0-10% K2O; >5-15% TiO2. The invention further comprises a method for achieving high crystalline yield at such a low liquidus with increased solubility of high levels of chromium ions. The glass-ceramics can be used in drawing optical fibers and as gain media in amplifier and laser devices for near infrared wavelengths.
    Type: Grant
    Filed: August 14, 2001
    Date of Patent: December 9, 2003
    Assignee: Corning Incorporated
    Inventors: George H. Beall, Joseph E. Pierson, Linda R. Pinckney
  • Patent number: 6652973
    Abstract: The present invention provides a glass-ceramic suitable as a material for forming a reflecting mirror substrate. The glass-ceramic has celsian as a primary crystal phase and contains SiO2, Al2O3, BaO, and TiO2 as primary components and at least Li2O as a modification component, wherein the amount of Li2O is within a range of 0.05 to 1.0 wt. %. The glass-ceramic is substantially formed of a crystal phase of celsian alone, that is, the glass-ceramic is substantially free from hexacelsian crystal phase.
    Type: Grant
    Filed: July 15, 2002
    Date of Patent: November 25, 2003
    Assignee: NGK Insulators, Ltd.
    Inventors: Takashi Ota, Atushi Watanabe, Kazuki Ohtoh
  • Patent number: 6649550
    Abstract: The present invention provides a glass ceramics dielectric material, comprising: a crystallizable glass powder in an amount of from 40% to 100% by mass; and a ceramics powder in an amount of from 0% to 60% by mass, wherein the crystallizable glass powder comprises: SiO2 in an amount of from 35% to 65% by mass; CaO in an amount of from 10% to 30% by mass; MgO in an amount of from 10% to 20% by mass; and ZnO in an amount of from 0.5% to 35% by mass, and wherein the material is capable of forming: diopside, CaMgSi2O6, as crystals; and at least one of hardestnite, Ca2ZnSiO7, and willemite, Zn2SiO4, as crystals; and a sintered glass ceramics, comprising: diopside, CaMgSi2O6, as crystals; and at least one of hardestnite, Ca2ZnSiO7, and willemite, Zn2SiO4, as crystals.
    Type: Grant
    Filed: November 16, 2001
    Date of Patent: November 18, 2003
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Yoshio Umayahara, Yoshikatsu Nishikawa
  • Patent number: 6649549
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Grant
    Filed: April 2, 2001
    Date of Patent: November 18, 2003
    Assignee: Minolta Co., Ltd.
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Patent number: 6645285
    Abstract: Micaceous glass-ceramics are useful in the fabrication of single and multi-unit dental restorations including but not limited to orthodontic appliances, bridges, space maintainers, tooth replacement appliances, splints, crowns, partial crowns, dentures, posts, teeth, jackets, inlays, onlays, facing, veneers, facets, implants, abutments, cylinders, and connectors by machining the glass-ceramic using CAM/CAM devices. The micaceous glass-ceramics are provided in a plurality of shades and colors to adequately match the colors and shades of teeth found in 95% or more of the human population.
    Type: Grant
    Filed: February 4, 2002
    Date of Patent: November 11, 2003
    Assignee: Pentron Corporation
    Inventors: Dmitri Brodkin, Carlino Panzera, Paul Panzera
  • Patent number: 6645890
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Grant
    Filed: April 2, 2001
    Date of Patent: November 11, 2003
    Assignee: Minolta Co., Ltd.
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Patent number: 6645888
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Grant
    Filed: April 2, 2001
    Date of Patent: November 11, 2003
    Assignee: Minolta Co., Ltd.
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Patent number: 6645891
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Grant
    Filed: April 2, 2001
    Date of Patent: November 11, 2003
    Assignee: Minolta Co., Ltd.
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Patent number: 6645892
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Grant
    Filed: April 2, 2001
    Date of Patent: November 11, 2003
    Assignee: Minolta Co., Ltd.
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Patent number: 6645889
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Grant
    Filed: April 2, 2001
    Date of Patent: November 11, 2003
    Assignee: Minolta Co., Ltd.
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Patent number: 6642161
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Grant
    Filed: April 2, 2001
    Date of Patent: November 4, 2003
    Assignee: Minolta Co., Ltd.
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Patent number: 6642162
    Abstract: A polished glass disk medium substrate suitable for use as a substrate for a hard disk, a hard disk containing the substrate and methods for making the substrate. The substrate containing glass forming raw materials may be formed so as to have a Young's modulus of 110 or higher.
    Type: Grant
    Filed: April 2, 2001
    Date of Patent: November 4, 2003
    Assignee: Minolta Co., Ltd.
    Inventors: Hideki Nagata, Hiroshi Yuki, Toshiharu Mori, Hideki Kawai, Kazuhiko Ishimaru
  • Publication number: 20030198838
    Abstract: The present invention is concerned with a process for the formation of dental restorations from glass-ceramic materials and the resulting dental restorations. A dental restoration is formed by pressing a lithium discilicate glass ceramic where the concentration of lithium discilicate crystals in the glass ceramic composition is at least 30% by weight. Crystal formation is effected with P2O5. The glass ceramic material may further contain coloring oxides, fluoresing agents, pigments, opacifiers and glass modifiers. The resulting dental restorations have superior optical, esthetic and strength properties.
    Type: Application
    Filed: October 19, 2002
    Publication date: October 23, 2003
    Applicant: TEC VENTURES, INC.
    Inventor: Richard W. Petticrew
  • Patent number: 6632757
    Abstract: A glass-ceramic which is substantially and desirably totally transparent, and which contains a predominant crystal phase of forsterite. The glass-ceramic is formed from precursor glasses having the following compositions, in weight percent on an oxide basis: SiO2 30-60; Al2O3 10-25; MgO 13-30; K2O 8-20; TiO2 0-10; and GeO2 0-25. The glass-ceramic may be doped with up to 1 wt. % chromium oxide to impart optical activity thereto.
    Type: Grant
    Filed: August 14, 2001
    Date of Patent: October 14, 2003
    Assignee: Corning Incorporated
    Inventor: George H. Beall