Silicon Containing Or Process Of Making Patents (Class 502/232)
  • Publication number: 20120189681
    Abstract: A layered heterostructured coating has functional characteristics that enable the controlled release of volatile agents. The coating has photocatalytic properties, since it uses titanium dioxide, its derivatives or materials with similar photocatalytic properties (2), which upon solar irradiation open and/or degrade nano or microcapsules (3) and subsequently releases in a controlled form the volatile agents contained in them.
    Type: Application
    Filed: December 11, 2009
    Publication date: July 26, 2012
    Inventors: Carlos José Macedo Tavares, Femando Da Silva Pina
  • Patent number: 8227034
    Abstract: Catalyst-coated support, method for producing the same, reactor comprising the same and use thereof. Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 ?m in at least two dimensions or having cross-sectional areas of at least 10 ?m2. The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.
    Type: Grant
    Filed: June 9, 2011
    Date of Patent: July 24, 2012
    Assignees: Evonik Degussa GmbH, Uhde GmbH
    Inventors: Steffen Schirmeister, Karsten Bueker, Martin Schmitz-Niederau, Bernd Langanke, Andreas Geisselmann, Georg Markowz, Klaus Thomas Schwarz, Elias Johannes Klemm, Frank Becker, Reinhard Machnik
  • Patent number: 8222470
    Abstract: A process for oligomerizing an olefinic hydrocarbon feed is described which consists of bringing said feed into contact with a catalyst comprising a silica-alumina, the silica content of said catalyst being in the range 5% to 95% by weight, said catalyst being prepared using a process comprising at least: a) mixing at least one alumina compound which is partially soluble in an acid medium with either at least one silica compound which is completely soluble in the reaction mixture or a combination formed by at least one silica compound and at least one alumina compound, said silica and alumina compounds being completely soluble in the reaction mixture, in order to form a solid precursor of said catalyst; b) hydrothermal treatment of the solid derived from step a) by calcining in moist air for a period in the range 4 to 7 hours.
    Type: Grant
    Filed: January 27, 2009
    Date of Patent: July 17, 2012
    Assignee: IFP Energies nouvelles
    Inventors: Vincent Coupard, Alexandra Chaumonnot, Laurent Simon
  • Publication number: 20120178972
    Abstract: A process for depositing nanostructured material onto a particulate substrate material comprising the steps of: a) preparing a precursor material; b) forming an atomised dispersion containing nanophased material when subjecting said precursor material to elevated temperature; and c) contacting the atomised dispersion with the substrate material to deposit the nanophased material on the substrate material. The substrate material is in mobile and particulate form for contacting step (c). An apparatus for carrying out the process is also disclosed.
    Type: Application
    Filed: April 19, 2010
    Publication date: July 12, 2012
    Applicant: Commonwealth Scientific and Industrial Research Organisation
    Inventors: Kok Seng Lim, Jonian Ivanov Nikolav
  • Patent number: 8207082
    Abstract: This invention relates to a method for making shaped bodies having a silica content of at least 85 wt %, to shaped bodies made by such method, to catalyst compositions comprising shaped bodies made by such methods and to catalytic conversion processes using catalyst compositions comprising shaped bodies made by such methods. The method of making the shaped bodies comprises the steps of a) forming shaped bodies from a mixture obtained from at least one amorphous silica powder, at least one silica sol having a pH below 7, and at least one polymeric organic extrusion aid, optionally supplemental liquid medium and optionally crystallites of a zeolite or zeolite-type material; b) drying the shaped bodies obtained in step a); and c) heating the shaped bodies to a temperature ranging from about 500° C. to about 800° C.
    Type: Grant
    Filed: January 12, 2007
    Date of Patent: June 26, 2012
    Assignee: Exxonmobil Research and Engineering Company
    Inventors: Jason Wu, Theodore E. Datz, Ralph Dehaas, Jean W. Beeckman
  • Publication number: 20120148478
    Abstract: The present invention relates to a process for the preparation of chlorine by gas phase oxidation using a supported catalyst based on ruthenium, characterised in that the catalyst support has a plurality of pores having a pore diameter>50 nm and carries nanoparticles containing ruthenium and/or ruthenium compounds as catalytically active components.
    Type: Application
    Filed: July 14, 2010
    Publication date: June 14, 2012
    Applicant: Bayer MaterialScience AG
    Inventors: Timm Schmidt, Christoph Gürtler, Jürgen Kintrup, Thomas Ernst Müller, Tim Loddenkemper, Frank Gerhartz, Walther Müller
  • Publication number: 20120149556
    Abstract: One subject of the invention is a material comprising a substrate coated on at least one portion of at least one of its faces with a stack comprising a photocatalytic layer, the geometrical thickness of which is between 2 and 30 nm, and at least one pair of respectively high and low refractive index layers positioned underneath said photocatalytic layer so that in the or each pair, the or each high refractive index layer is closest to the substrate, said material being such that the optical thickness, for a wavelength of 350 nm, of the or each high refractive index layer, except the photocatalytic layer, is between 170 and 300 nm and the optical thickness, for a wavelength of 350 nm, of the or each low refractive index layer is between 30 and 90 nm.
    Type: Application
    Filed: July 13, 2010
    Publication date: June 14, 2012
    Applicant: SAINT-GOBAIN GLASS FRANCE
    Inventors: Stephane Laurent, Anne Durandeau, Emmanuel Valentin
  • Patent number: 8198207
    Abstract: Borane catalyst complexes with amide functional polymers have a borane portion of the complex that may contain at least one silicon atom. The catalyst complexes can be used as components in curable compositions containing (i) the catalyst complex, (ii) a free radical polymerizable monomer, oligomer or polymer, and optionally (iii) a decomplexer. The curable compositions may contain a component capable of generating a gas, as well as various other optional ingredients. These curable compositions can be used as rubbers, tapes, adhesives, protective coatings, thin films, thermoplastic monolithic molded parts, thermosetting monolithic molded parts, sealants, foams, gaskets, seals, o-rings, pressure sensitive adhesives, die attachment adhesives, lid sealants, encapsulants, potting compounds, conformal coatings, and electronic components.
    Type: Grant
    Filed: February 6, 2007
    Date of Patent: June 12, 2012
    Assignee: Dow Corning Corporation
    Inventor: Mustafa Mohamed
  • Publication number: 20120142521
    Abstract: A photocatalyst-coated body comprises a substrate and a photocatalyst layer provided on the substrate, the photocatalyst layer comprising photocatalyst particles of 1 part or more by mass and less than 20 parts by mass, inorganic oxide particles of 70 parts or more by mass and less than 99 parts by mass, and the dried substance of a hydrolyzable silicone of zero parts or more by mass and less than 10 parts by mass, provided that a total amount of the photocatalyst particles, the dried substance of the inorganic oxide particles and the hydrolyzable silicone is 100 parts by mass in terms of silica. The inorganic oxide particles have a number average particle diameter ranging from 10 nm or more to less than 40 nm calculated by measuring lengths of 100 particles randomly selected from particles located within a visible field magnified 200,000 times by a scanning electron microscope.
    Type: Application
    Filed: February 15, 2012
    Publication date: June 7, 2012
    Applicant: TOTO LTD.
    Inventors: Satoru KITAZAKI, Junji KAMESHIMA, Koji OMOSHIKI, Yoji TAKAKI, Yuki TANAKA, Hironaga IWATA, Makoto HAYAKAWA, Mitsuyoshi KANNO
  • Publication number: 20120131911
    Abstract: An exhaust gas purifying catalyst (1) of the present invention includes anchor/promoter simultaneous enclosure particles (5) including catalyst units (13) which contain: noble metal particles (8); and anchor particles (9) as an anchor material of the noble metal particles (8) supporting the noble metal particles (8); promoter units (14) which are provided not in contact with the noble metal particles (8) and contain first promoter particles (11) having an oxygen storage and release capacity; and an enclosure material (12) which encloses both the catalyst units (13) and the promoter units (14), and separates the noble metal particles (8) and the anchor particles (9) in the catalyst units (13) from the first promoter particles (11) in the promoter units (14). The exhaust gas purifying catalyst (1) further includes second promoter particles (6) which have the oxygen storage and release capacity, and are not enclosed in the anchor/promoter simultaneous enclosure particles (5) by the enclosure material (12).
    Type: Application
    Filed: November 15, 2010
    Publication date: May 31, 2012
    Applicant: Nissan Motor Co., Ltd.
    Inventors: Takamasa Nakagawa, Masanori Nakamura, Misaka Fujimoto, Naoki Kachi
  • Publication number: 20120136180
    Abstract: The present disclosure describes methods and biomimetic catalysts useful for hydrolyzing glucose polymers, such as cellulose, and oligomers, such as cellobiose, to glucose for the subsequent production of ethanol.
    Type: Application
    Filed: March 2, 2010
    Publication date: May 31, 2012
    Applicant: The Trustees of the University of Pennsylvania
    Inventors: Stephen Roth, Daeyeon Lee
  • Publication number: 20120129688
    Abstract: Provided herein are methods of synthesizing large-pore periodic mesoporous quartz. Using the methods herein, large-pore periodic mesoporous quartz has been synthesized at a lower pressure and a temperature than in any previous mesoporous crystalline method, yielding a unique mesoporous article having crystalline pore walls. For example, the methods involve modified nanocasting methods using a mesoporous starting material comprising silica, carbon as a an infiltrating pore filler, followed by application of pressure and heat sufficient to crystallize silica in the infiltrated starting material to form a mesoporous crystalline article having crystalline pore walls therein, and useful in many applications, including as a catalyst.
    Type: Application
    Filed: November 22, 2011
    Publication date: May 24, 2012
    Applicant: LEHIGH UNIVERSITY
    Inventor: Kai Landskron
  • Publication number: 20120063958
    Abstract: The invention relates to a filtering media having a photocatalytic action which has a thickness of at least 2 mm, which is homogeneous and which is devoid of orifice apparent to the naked eye, comprising a felt of inorganic fibers, the fibers of which are coated with a coating comprising a catalyst having a photocatalytic action, said felt exhibiting a weight per unit area of between 30 and 80 g/m2, said coating representing 5 to 80% of the weight of said media, said media exhibiting a gas pressure drop of less than 150 Pa at 1 m/s in unpleated condition. This media is intended to be incorporated in a purifier of gas, such as air, furthermore comprising a system for illuminating said media with UV radiation. The media exhibits an excellent purification efficiency and a very low pressure drop.
    Type: Application
    Filed: July 17, 2008
    Publication date: March 15, 2012
    Applicant: SAINT-GOBAIN QUARTZ S.A.S
    Inventors: Jean-Paul Riviere, Paul Sargood, Laurent Molins
  • Publication number: 20120058884
    Abstract: Techniques for coating a fiber with metal oxide include forming silica in the fiber to fix the metal oxide to the fiber. The coated fiber can be used to facilitate photocatalysis.
    Type: Application
    Filed: November 9, 2011
    Publication date: March 8, 2012
    Applicant: KOREA UNIVERSITY RESEARCH AND BUSINESS FOUNDATION
    Inventor: Kwangyeol Lee
  • Publication number: 20120046157
    Abstract: A method for strengthening an extruded catalyst honeycomb filter body, including: contacting an extruded catalyst honeycomb filter body and a siliceous formulation including at least one siliceous source comprising a silicone emulsion, a silica sol, or a combination thereof; drying the contacted filter body; and firing the dried contacted filter body to provide the filter body. Also disclosed are zeolite-based honeycomb filter articles, including a matrix of walls of: a primary phase material homogeneously distributed throughout the walls, as defined herein.
    Type: Application
    Filed: August 23, 2010
    Publication date: February 23, 2012
    Inventors: Yanxia Lu, Steven Bolaji Ogunwumi, Jianhua Weng
  • Publication number: 20120039775
    Abstract: Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 ?m in at least two dimensions or having cross-sectional areas of at least 10 ?m2. The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.
    Type: Application
    Filed: June 9, 2011
    Publication date: February 16, 2012
    Applicants: Evonik Degussa GmbH, Uhde GmbH
    Inventors: Steffen Schirmeister, Karsten Büker, Martin Schmitz-Niederau, Bernd Langanke, Andreas Geisselmann, Georg Markowz, Klaus Thomas Schwarz, Elias Johannes Klemm, Frank Becker, Reinhard Machnik
  • Publication number: 20120041160
    Abstract: Systems and methods for the maintenance of active chromium-based catalysts and their use in polymerization processes are described. In one embodiment, a system for the introduction of multiple polymerization components to activate a chromium based catalyst within a mix tank is described. Other described features may include materials and methods to purify the liquid medium of a catalyst slurry so that the catalyst slurry maintains a high level of activity. The active chromium-based catalyst may provide polyolefins with a number of desirable properties in a reliable, consistent, and predictable manner.
    Type: Application
    Filed: August 11, 2010
    Publication date: February 16, 2012
    Applicant: Chevron Phillips Chemical Company LP
    Inventors: Elizabeth A. Benham, Max P. McDaniel, Kathy S. Collins
  • Patent number: 8114797
    Abstract: To Provide a polarizing glass with better weatherability than conventional polarizing glasses, affording high long-term reliability without the above-described surface deterioration. To provide an optical isolator employing polarizing glass of improved weatherability, affording good weatherability and high reliability for extended periods. A polarizing glass comprising geometrically anisotropic particles dispersed in an oriented manner in at least one surface layer of a glass base body. The glass base body does not comprise an oxide of alkali earth metal and PbO, and consists of borosilicate glass comprising at least one additive component selected from the group consisting of Y2O3, ZrO2, La2O3, Ce O2, Ce2O3, Ti O2, V2O5, Ta2O5, WO3, and Nb2O5, and the geometrically anisotropic metal particles are metallic cupper particles. An optical isolator employing the polarizing glass.
    Type: Grant
    Filed: April 12, 2007
    Date of Patent: February 14, 2012
    Assignee: Hoya Candeo Optronics Corporation
    Inventors: Yoshitaka Yoneda, Sei-ichi Yokoyama
  • Publication number: 20120027666
    Abstract: Homogeneous water oxidation catalysts (WOCs) for the oxidation of water to produce hydrogen ions and oxygen, and methods of making and using thereof are described herein. In a preferred embodiment, the WOC is a polyoxometalate WOC which is hydrolytically stable, oxidatively stable, and thermally stable. The WOC oxidized waters in the presence of an oxidant. The oxidant can be generated photochemically, using light, such as sunlight, or electrochemically using a positively biased electrode. The hydrogen ions are subsequently reduced to form hydrogen gas, for example, using a hydrogen evolution catalyst (HEC). The hydrogen gas can be used as a fuel in combustion reactions and/or in hydrogen fuel cells. The catalysts described herein exhibit higher turn over numbers, faster turn over frequencies, and/or higher oxygen yields than prior art catalysts.
    Type: Application
    Filed: March 17, 2010
    Publication date: February 2, 2012
    Applicant: EMORY UNIVERSITY
    Inventors: Craig L Hill, Yurii V Gueletii, Djamaladdin G. Musaev, Qiushi Yin, Bogdan Botar
  • Publication number: 20120015802
    Abstract: Disclosed is a catalyst which can be used in the process for producing hydrogen by decomposing ammonia, can generate heat efficiently in the interior of a reactor without requiring excessive heating the reactor externally, and can decompose ammonia efficiently and steadily by utilizing the heat to produce hydrogen. Also disclosed is a technique for producing hydrogen by decomposing ammonia efficiently utilizing the catalyst. Specifically disclosed is a catalyst for use in the production of hydrogen, which is characterized by comprising an ammonia-combusting catalytic component and an ammonia-decomposing catalytic component. Also specifically disclosed is a catalyst for use in the production of hydrogen, which is characterized by comprising at least one metal element selected from the group consisting of cobalt, iron, nickel and molybdenum.
    Type: Application
    Filed: March 17, 2010
    Publication date: January 19, 2012
    Inventors: Junji Okamura, Masanori Yoshimune, Masaru Kirishiki, Hideaki Tsuneki, Shinya Kitaguchi
  • Publication number: 20120010379
    Abstract: The present invention relates to spherical beads comprising at least one metal and/or semimetal oxide, having a mean diameter in the range from 10 to 120 ?m, a BET surface area in the range from 400 to 800 m2/g and a pore volume in the range from 0.3 to 3.0 cm3/g, wherein the diameter of a given bead at any one point of said bead deviates by less than 10% from the average diameter of said bead and the surface of said bead is substantially smooth, and also to a process for producing these spherical beads, to a particulate catalyst comprising the spherical beads and to the use of the spherical beads as catalysts or catalyst carriers.
    Type: Application
    Filed: March 9, 2010
    Publication date: January 12, 2012
    Applicant: BASF SE
    Inventors: Angela Siegel, Tobias Eckardt, Andreas Braedikow, Thorsten Puvogel
  • Publication number: 20120003146
    Abstract: This disclosure provides systems, methods, and compositions for facilitating hydrogen storage, typically using naturally-occurring nanostructured biomaterials such as diatoms or diatomaceous material in their natural or modified forms to facilitate the hydrogen storage. For example, when the nanostructured biomaterials are in contact with a metal hydride such as a complex or a simple metal hydride, the resulting composition functions a catalytic composition that can reversibly desorb and resorb hydrogen gas in an efficient manner. Examples of modification include, but are not limited to, modification of the nanostructured silica with any number of metals.
    Type: Application
    Filed: July 2, 2010
    Publication date: January 5, 2012
    Applicant: MICROBES UNLIMITED, LLC
    Inventor: Carl B. Fliermans
  • Publication number: 20120004093
    Abstract: A catalyst is provided, where the catalyst has an active surface that includes at least one nodular-structured (particulate) catalyst layer disposed on a support substrate, where the nodular-structured catalyst layer partially coats a surface of the support substrate. The invention further includes a fabrication method of the catalyst. The method includes depositing a catalyst precursor coating on a support substrate by heating a catalyst precursor solution on the support substrate, and further heating the catalyst precursor-coated substrate until a nodular-structured (particulate) catalyst is formed, where the nodular-structured catalyst layer partially coats a surface of the support substrate.
    Type: Application
    Filed: March 3, 2009
    Publication date: January 5, 2012
    Applicant: THE STATE OF OREGON ACTING BY AND THROUGH THE STAT
    Inventors: Brian P. Reed, Kevin E. Harris, Nicholas Wannenmacher
  • Patent number: 8088883
    Abstract: A transition metal complex obtained by contacting a bipyridine compound represented by the formula (1): wherein R1, R2 and R3 represent a C1-C10 alkyl group which may be substituted, etc., and R4 and R5 represent a hydrogen atom etc., with a compound of a transition metal belonging to Group 9, 10 or 11, and a process for producing a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups are bonded to an aromatic ring with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) being structurally different from the above-mentioned aromatic compound (A) and having one or two leaving groups bonded to an aromatic ring, in the presence of said transition metal complex.
    Type: Grant
    Filed: July 25, 2008
    Date of Patent: January 3, 2012
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Taku Asaumi, Takashi Kamikawa
  • Publication number: 20110312488
    Abstract: A catalyst system for generating at least one polyol from a feedstock comprising saccharide is disclosed. Generating the polyol involves, contacting hydrogen, water, and a feedstock comprising saccharide, with a catalyst system to generate an effluent stream comprising at least one polyol and recovering the polyol from the effluent stream. The catalyst system comprises at least one metal component with an oxidation state greater than or equal to 2+.
    Type: Application
    Filed: July 28, 2011
    Publication date: December 22, 2011
    Applicant: UOP LLC
    Inventors: John Q. Chen, Tom N. Kalnes, Joseph A. Kocal
  • Publication number: 20110312055
    Abstract: The invention provides a process for producing alcohol from a cellulosic material, said process comprising: hydrolyzing said cellulosic material with an aqueous acid to produce a hydrolysate; extracting acid and water from said hydrolysate with a water-miscible organic extraction solvent to yield (a) a first aqueous acidic solution containing said extraction solvent and (b) a residue containing sugars; subjecting said residue to an oligosaccharide cleavage reaction to yield an aqueous solution of fermentable sugars; fermenting said fermentable sugars and distilling alcohol from the resulting fermented mixture; contacting said first aqueous acidic solution with a pressurized fluid lipophilic solvent in non-gaseous form, which fluid solvent is substantially water-immiscible and is gaseous at ambient conditions, to yield a second aqueous acid solution and a solvent mixture of said extraction solvent and said fluid solvent; depressurizing said solvent mixture to release said extraction solvent for recycling; and,
    Type: Application
    Filed: October 1, 2009
    Publication date: December 22, 2011
    Applicant: Weyland AS
    Inventor: Karl Ragnar Weydahl
  • Patent number: 8080347
    Abstract: There is provided a catalyst for a fuel cell, which simultaneously realizes excellent catalytic activity and catalytic stability. The catalyst for a fuel cell comprises a fine particle of a metal represented by formula: PtxRuySizT1u wherein T1 represents at least one element selected from the group consisting of nickel (Ni), tungsten (W), vanadium (V), and molybdenum (Mo); x=30 to 90 atomic %; y=0 to 50 atomic %; z=0.5 to 20 atomic %; and u=0.5 to 40 atomic %, or comprises a fine particle of a metal represented by formula: PtxRuySizT2u wherein T2 represents at least one element selected from the group consisting of hafnium (Hf), tin (Sn), zirconium (Zr), niobium (Nb), titanium (Ti), tantalum (Ta), chromium (Cr), and aluminum (Al); x=30 to 90 atomic %; y=0 to 50 atomic %; z=0.5 to 20 atomic %; and u=0.5 to 40 atomic %.
    Type: Grant
    Filed: March 17, 2008
    Date of Patent: December 20, 2011
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Wu Mei, Taishi Fukazawa, Takahiro Sato, Itsuko Mizutani, Yoshihiko Nakano
  • Publication number: 20110301392
    Abstract: A catalyst for the dehydrogenation of alkanes or alkyl substituents of hydrocarbons, is a shaped body having at least one oxide from the elements of the main or secondary group II to IV of the periodic table or of a mixed oxide thereof serving as base material of the shaped body. The catalyst further contains an additional constituent which is an oxide of an element of the main group IV of the periodic table, added during the shaping process. A platinum compound and a compound of an element of the main group IV of the periodic table is used as a surface constituent of the catalyst. The invention further relates to the production of the catalyst and to a method for the dehydrogenation of alkanes using the catalyst.
    Type: Application
    Filed: December 15, 2009
    Publication date: December 8, 2011
    Applicant: UHDE GMBH
    Inventors: Muhammad Iqbal Mian, Max Heinritz-Adrian, Sascha Wenzel, Oliver Noll, Meinhard Schwefer, Helmut Gehrke
  • Publication number: 20110294969
    Abstract: Process for supportation of a catalyst system comprising at least two different active catalyst components on a support wherein in an earlier supportation step a first active catalyst component is applied to the support at a first predetermined temperature and in a later supportation step a second active catalyst component is applied to the support at a temperature which is at least 20° C. lower than the first predetermined temperature.
    Type: Application
    Filed: December 12, 2009
    Publication date: December 1, 2011
    Applicant: Basell Polyolefine GmbH
    Inventors: Harald Schmitz, Fabiana Fantinel, Jürgen Hilz, Shahram Mihan
  • Patent number: 8052937
    Abstract: A catalyst composition for facilitating the oxidation of soot from diesel engine exhaust is provided. The catalyst composition includes a catalytic metal selected from Pt, Pd, Pt—Pd, Ag, or combinations thereof, an active metal oxide component containing Cu and La, and a support selected from alumina, silica, zirconia, or combinations thereof. The platinum group metal loading of the composition is less than about 20 g/ft3. The catalyst composition may be provided on a diesel particulate filter by impregnating the filter with an alumina, silica or zirconia sol solution modified with glycerol and/or saccharose, impregnating the filter with a stabilizing solution, and impregnating the filter with a solution containing the active metal oxide precursor(s) and the catalytic metal precursor(s). The resulting catalyst coated diesel particulate filter provides effective soot oxidation, exhibits good thermal stability, has a high BET surface area, and exhibits minimal backpressure.
    Type: Grant
    Filed: May 20, 2010
    Date of Patent: November 8, 2011
    Assignee: Ford Global Technologies, LLC
    Inventors: Albert Chigapov, Alexei Dubkov, Brendan Carberry
  • Patent number: 8052788
    Abstract: Colloidal silica having a controllable broad particle size distribution and a controllable minimum particle size is disclosed and claimed. Particles below a predetermined size are excluded from the product colloidal silica of the invention. A method for continuously producing the desired colloidal composition is disclosed comprising the steps of providing preformed silica particles having a surface area which controls the particle size of the colloidal silica product, adding a feed silica comprising an alkaline solution and silicate at a feed rate which is less than a nucleation rate.
    Type: Grant
    Filed: September 24, 2008
    Date of Patent: November 8, 2011
    Assignee: Nalco Company
    Inventor: Dennis L. MacDonald
  • Publication number: 20110268970
    Abstract: The present invention provides a process for making mesoporous nanoparticles. The process comprises providing an acidic mixture comprising a fluorocarbon surfactant, a second surfactant and a silica precursor. The silica precursor is then reacted to form the mesoporous nanoparticles.
    Type: Application
    Filed: July 7, 2011
    Publication date: November 3, 2011
    Applicant: AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH
    Inventors: Jackie Y. YING, Yu HAN
  • Publication number: 20110270007
    Abstract: An alkylation catalyst having a zeolite catalyst component and a binder component providing mechanical support for the zeolite catalyst component is disclosed. The binder component is an ion-modified binder that can include metal ions selected from the group consisting of Co, Mn, Ti, Zr, V, Nb, K, Cs, Ga, B, P, Rb, Ag, Na, Cu, Mg, Fe, Mo, Ce, and combinations thereof. The metal ions reduce the number of acid sites on the zeolite catalyst component. The metal ions can range from 0.1 to 50 wt % based on the total weight of the ion-modified binder. Optionally, the ion-modified binder is present in amounts ranging from 1 to 80 wt % based on the total weight of the catalyst.
    Type: Application
    Filed: May 22, 2011
    Publication date: November 3, 2011
    Applicant: FINA TECHNOLOGY, INC.
    Inventors: Sivadinarayana Chinta, Joseph E. Pelati
  • Patent number: 8043990
    Abstract: The invention relates to a catalyst system for polymerization of olefins, the catalyst system comprising a titanium-containing procatalyst carrying internal electron donor(s), an organoaluminium cocatalyst and a mixture of external electron donors, the mixture comprising a carboxylic acid ester or derivatives thereof, an alkoxy silane and a nitrogen based compound. The invention also relates to a process for polymerization of olefin(s) and to the polyolefin synthesized by the process.
    Type: Grant
    Filed: August 25, 2008
    Date of Patent: October 25, 2011
    Assignee: Reliance Industries Limited
    Inventors: Virendrakumar Gupta, Harshad Ramdas Patil, Dhananjay Ghelabhai Naik, Sukhdeep Kaur, Gurmeet Singh, Priyanshu Bharatkumar Vyas
  • Publication number: 20110244003
    Abstract: The present invention discloses a self standing network or scaffold of nanoparticles with controllably variable mesh size between 500 nm and 1 mm having particle volume fraction between 0.5 to 50%. The network comprises nanoparticles, a surfactant capable of forming ordered structured phases and a cross linking agent, wherein the surfactant is washed off leaving the self standing scaffold. The invention further discloses the process for preparing the self standing scaffolds and uses thereof.
    Type: Application
    Filed: December 15, 2009
    Publication date: October 6, 2011
    Applicant: COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH
    Inventors: Guruswamy Kumaraswamy, Kamendra Prakash Sharma
  • Patent number: 8029882
    Abstract: A silicon carbide porous object includes silicon carbide as an aggregate and metal silicon as a binder, the particles of silicon carbide being bonded to one another so as to have pores thereamong. A method for producing a silicon carbide porous object includes: firing raw materials formed by mixing silicon carbide and metal silicon with metal aluminum or an alloy including metal silicon and metal aluminum in an inert gas atmosphere or a reduced-pressure atmosphere to produce a metal aluminum-metal silicon-silicon carbide porous object; and oxidizing and firing the metal aluminum-metal silicon-silicon carbide porous object in an oxygen atmosphere.
    Type: Grant
    Filed: September 8, 2008
    Date of Patent: October 4, 2011
    Assignee: NGK Insulators, Ltd.
    Inventors: Yoshio Kikuchi, Shinji Kawasaki
  • Publication number: 20110237758
    Abstract: The present invention provides a urethane-forming reaction catalyst which is useful for catalyzing a reaction between an isocyanate compound, in particular, an aliphatic isocyanate and a hydroxyl group-containing compound to form a urethane material, which does not affect the performance of the urethane material, and which can be easily removed from the resulting urethane material, and a method for producing a metal compound-free urethane material using the urethane-forming reaction catalyst. The catalyst of the present invention is a urethane-forming reaction catalyst for producing a urethane material by allowing a hydroxyl group-containing compound to react with an isocyanate compound, the catalyst being at least one solid acid catalyst selected from the group consisting of a (A) composite metal oxide in which a metal oxide (A-2) or a non-metal compound (A-3) is carried on a surface of a metal oxide carrier (A-1), (B) zeolite, and a (C) heteropoly acid.
    Type: Application
    Filed: September 16, 2009
    Publication date: September 29, 2011
    Applicant: DIC Corporation
    Inventors: Hironobu Oki, Yasuyuki Watanabe, Youichi Abe
  • Patent number: 8012903
    Abstract: Methods are provided to prepare a catalyst system that includes at least one titanium compound, at least one magnesium compound, at least one electron donor compound, at least one activator compound, and at least one silica support material, the at least one silica support material having a median particle size in the range of from 20 to 50 microns with no more than 10% of the particles having a size less than 10 microns and no more than 10% of the particles having a size greater than 50 microns and average pore diameter of at least ?220 angstroms.
    Type: Grant
    Filed: April 17, 2008
    Date of Patent: September 6, 2011
    Assignee: Univation Technologies, LLC
    Inventors: Maria A. Apecetche, Phuong A. Cao, Michael D. Awe, Ann M. Schoeb-Wolters, Ryan W. Impelman
  • Publication number: 20110212829
    Abstract: A process for making a ceramic catalyst material includes mixing a catalyst precursor material with a mineral particulate to form a mixture; adding a binder, silicon carbide, and a parting agent to the mixture to form unfired spheroids; and heating the unfired spheroids at a temperature effective to oxidize the silicon carbide and the catalyst precursor material to form the ceramic catalyst material. In another embodiment, the process includes the addition of a catalyst metal oxide salt to an aluminosilicate hydrogel aggregate mixture. Once the mixture sets, the set mixture is heated to a temperature to effective to produce a high surface area ceramic catalyst material.
    Type: Application
    Filed: March 16, 2011
    Publication date: September 1, 2011
    Inventor: Felice DiMascio
  • Patent number: 8003743
    Abstract: A process for preparing 1-butene polymers comprising polymerizing 1-butene and optionally ethylene, propylene or higher alpha-olefin, in the presence of a catalyst system obtainable by contacting: a) metallocene compound of formula (I): wherein: M is a transition metal; p is an integer from 0 to 3; X, same or different, is a hydrogen atom, a halogen atom, or a hydrocarbon group; L is a divalent C1-C40 hydrocarbon radical; R1 is a C1-C40 hydrocarbon radical; T1, is a moiety of formula (IIa) or (IIb): wherein R2 and R3, are C1-C40 hydrocarbon radicals or they can form together a C3-C7-membered ring; R4 is C1-C40 hydrocarbon radicals; T2 and T3, are a moiety of formula (IIIa) or (IIIb): wherein R6 and R7, equal to or different from each other, are hydrogen atoms or C1-C40 hydrocarbon radicals; R5 is a hydrogen atom or a C1-C40 hydrocarbon radicals; with the proviso that if T1 is a moiety of formula (IIa) at least one between T2 and T3 is a moiety of formula (IIIb), and if T1 is a moiety of formula
    Type: Grant
    Filed: May 31, 2005
    Date of Patent: August 23, 2011
    Assignee: Basell Poliolefine Italia, S.R.L.
    Inventors: Luigi Resconi, Friederike Morhard
  • Patent number: 8003567
    Abstract: The present teachings are directed toward hexagonally patterned porous titania synthesized from a titanium isopropoxide precursor using a viscous template of surface-active agents separating nanoscopic bicontinuous channels of water and isooctane. Subsequent catalyst metal salt reduction in the aqueous nanochannels deposits well-separated catalyst metal nanoparticles on the pore surfaces. These nanocomposites exhibit significantly higher carbon monoxide oxidation efficiency than that obtained with known supports with higher specific surface area; efficiency is believed to be due to decreased mass transfer resistance provided the presently disclosed support material.
    Type: Grant
    Filed: August 17, 2009
    Date of Patent: August 23, 2011
    Assignees: Honda Motor Co., Ltd., The Administrators of the Tulane Educational Fund, Rhode Island Board of Governors for Higher Education, Rensselaer Polytechnic Institute
    Inventors: Christopher Brooks, Arijit Bose, Jayashri Sarkar, Ganapathiraman Ramanath, Vijay T. John
  • Publication number: 20110172086
    Abstract: A catalyst unit is described comprising a cylinder with a length C and a diameter D, wherein said unit has five holes arranged in a pentagonal pattern extending longitudinally therethrough, with five flutes running along the length of the unit, said flutes positioned equidistant adjacent holes of said pentagonal pattern. The catalyst may be used particularly in steam reforming reactors.
    Type: Application
    Filed: August 24, 2009
    Publication date: July 14, 2011
    Applicant: JOHNSON MATTHEY PLC
    Inventors: David James Birdsall, Mileta Babovic, Mikael Per Uno Carlsson, Samuel Arthur French, Michiel Nijemeisland, William Maurice Sengelow, Edmund Hugh Stitt
  • Publication number: 20110172482
    Abstract: A catalyst that comprises at least one binder and at least one crystallized material with hierarchized and organized porosity in the fields of microporosity and mesoporosity is described, whereby said crystallized material consists of at least two elementary spherical particles, each of said particles comprising a mesostructured silicon-oxide-based matrix that has a mesopore diameter of between 1.5 and 30 nm and that has microporous and crystallized walls with a thickness of between 1 and 60 nm, whereby said elementary spherical particles have a maximum diameter of 200 microns. Said catalyst is used in a process for oligomerization of an olefinic feedstock that contains hydrocarbon molecules that have 2 to 12 carbon atoms per molecule.
    Type: Application
    Filed: April 28, 2009
    Publication date: July 14, 2011
    Applicant: IFP ENERGIES NOUVELLES
    Inventors: Amandine Cabiac, Alexandra Chaumonnot, Laurent Simon
  • Publication number: 20110166012
    Abstract: In one embodiment, the catalyst assembly includes a two-dimension (2-D) extensive catalyst having a catalyst crystal plane; and a substrate supporting the 2-D extensive catalyst and having a substrate crystal plane in substantial alignment with the catalyst crystal plane. In certain instances, the catalyst crystal plane includes first and second adjacent catalyst atoms defining a catalyst atomic distance, the substrate crystal plane includes first and second adjacent substrate atoms defining a substrate atomic distance, a percent difference between the catalyst and substrate atomic distances is less than 10 percent.
    Type: Application
    Filed: October 26, 2010
    Publication date: July 7, 2011
    Applicant: FORD GLOBAL TECHNOLOGIES, LLC
    Inventors: Jun Yang, Shinichi Hirano, Richard E. Soltis, Andrew Robert Drews, Andrea Pulskamp, James Waldecker
  • Publication number: 20110163044
    Abstract: A ceramic structure for water treatment, a water treatment apparatus and method are provided. Immersion efficiency of a photo catalyst and a specific surface area of the immersed photo catalyst can be improved using a ceramic medium including a ceramic paper prepared of a ceramic fiber. Accordingly, it is possible to provide the water treatment apparatus and method capable of increasing decomposition efficiency of contaminated materials due to irradiation of ultraviolet light, and so on, enabling continuous purification treatment, and remarkably reducing preparation, management and water treatment expenses.
    Type: Application
    Filed: December 23, 2010
    Publication date: July 7, 2011
    Applicant: LG HAUSYS, LTD.
    Inventors: Moonsuk HAN, Ju-Hyung Lee, Seongmoon Jung
  • Publication number: 20110140004
    Abstract: A glass article comprising identification means and a method for detecting the presence of the said identification means are disclosed. The glass article comprises at least one glass sheet which is covered by a layer comprising dispersed and invisible identification means. The identification means according to the invention allows identification of the presence of an intrinsic characteristic of said glass article which is invisible to the naked eye or difficult to detect.
    Type: Application
    Filed: July 22, 2008
    Publication date: June 16, 2011
    Applicant: AGC Glass Europe
    Inventors: Daniel Decroupet, Fabrice Sinapi, Pavel Cumpelik
  • Publication number: 20110143930
    Abstract: A method of tuning the size of an nano-active material on a nano-carrier material comprising: providing a starting portion of a carrier material and a starting portion of an active material in a first ratio; adjusting the first ratio, forming a second ratio, thereby tuning the ratio of active material and carrier material; combining the portion of the active material in a vapor phase and the portion of the carrier material in a vapor phase, forming a conglomerate in a vapor phase; and changing the phase of the conglomerate, thereby forming nano-spheres comprising a nano-carrier material decorated with a nano-active material, wherein the size of the nano-active material is dependent upon the second ratio.
    Type: Application
    Filed: December 7, 2010
    Publication date: June 16, 2011
    Applicant: SDCMATERIALS, INC.
    Inventors: Qinghua Yin, Xiwang Qi, Maximilian A. Biberger, David Leamon
  • Publication number: 20110143257
    Abstract: One embodiment includes a method of forming a hydrophilic particle containing electrode including providing a catalyst; providing hydrophilic particles suspended in a liquid to form a liquid suspension; contacting said catalyst with said liquid suspension; and, drying said liquid suspension contacting said catalyst to leave said hydrophilic particles attached to said catalyst.
    Type: Application
    Filed: March 8, 2010
    Publication date: June 16, 2011
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
    Inventors: Eric L. Thompson, Anusorn Kongkanand, Frederick T. Wagner
  • Publication number: 20110143922
    Abstract: A composition with catalyst particles for making a circuit pattern is provided. The composition includes an insulation material and a plurality of catalyst particles. The catalyst particles are distributed in the insulation material and not made of metal. When the composition is bathed in a chemical plating solution, a redox reaction takes place between some of the catalyst particles and the chemical plating solution so as to deposit a conductive pattern on the composition.
    Type: Application
    Filed: August 11, 2010
    Publication date: June 16, 2011
    Inventors: Cheng-Hsien Lee, Yi-Chun Liu
  • Patent number: 7959728
    Abstract: A process for wet pulverizing mesoporous silica particles while a surfactant exists in mesopores, and mesoporous silica particles having an average particle diameter of 1 ?m or less, wherein the volume of mesopores having a diameter of 2 to 50 nm is 0.7 mL/g or more and the geometric standard deviation of a mesopore distribution is 2.0 or less. Mesoporous silica particles having a particle diameter in a submicron order can be obtained at a high yield without causing the marked collapse of mesopores and can be produced efficiently by using an ordinary pulverizer and safely by using an aqueous medium. The mesoporous silica particles having an average particle diameter of 1 ?m or less are useful as an ink absorbent for ink jet recording paper, low-dielectric film, catalyst support, separating agent, adsorbent and medical carrier for medicines.
    Type: Grant
    Filed: August 14, 2008
    Date of Patent: June 14, 2011
    Assignee: Tokuyama Corporation
    Inventors: Kentaro Fukuda, Kenji Fukunaga, Hiroya Yamashita