Molybdenum Patents (Class 502/255)
  • Patent number: 8075859
    Abstract: A nanocomposite particle, its use as a catalyst, and a method of making it are disclosed. The nanocomposite particle comprises titanium dioxide nanoparticles, metal oxide nanoparticles, and a surface stabilizer. The metal oxide nanoparticles are formed hydrothermally in the presence of the titanium dioxide nanoparticles. The nanocomposite particle is an effective catalyst support, particularly for DeNOx catalyst applications.
    Type: Grant
    Filed: July 14, 2009
    Date of Patent: December 13, 2011
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Guoyi Fu, Steven M. Augustine
  • Publication number: 20110257443
    Abstract: A catalyst comprising a first metal, a silicaceous support, and at least one metasilicate support modifier, wherein at least 1 wt. % of the at least one metasilicate support modifier is crystalline in phase, as determined by x-ray diffraction. The invention also relates to processes for forming such catalysts, to supports used therein, and to processes for hydrogenating acetic acid in the presence of such catalysts.
    Type: Application
    Filed: February 1, 2011
    Publication date: October 20, 2011
    Applicant: CELANESE INTERNATIONAL CORPORATION
    Inventors: Heiko Weiner, Victor J. Johnston
  • Publication number: 20110237758
    Abstract: The present invention provides a urethane-forming reaction catalyst which is useful for catalyzing a reaction between an isocyanate compound, in particular, an aliphatic isocyanate and a hydroxyl group-containing compound to form a urethane material, which does not affect the performance of the urethane material, and which can be easily removed from the resulting urethane material, and a method for producing a metal compound-free urethane material using the urethane-forming reaction catalyst. The catalyst of the present invention is a urethane-forming reaction catalyst for producing a urethane material by allowing a hydroxyl group-containing compound to react with an isocyanate compound, the catalyst being at least one solid acid catalyst selected from the group consisting of a (A) composite metal oxide in which a metal oxide (A-2) or a non-metal compound (A-3) is carried on a surface of a metal oxide carrier (A-1), (B) zeolite, and a (C) heteropoly acid.
    Type: Application
    Filed: September 16, 2009
    Publication date: September 29, 2011
    Applicant: DIC Corporation
    Inventors: Hironobu Oki, Yasuyuki Watanabe, Youichi Abe
  • Publication number: 20110195013
    Abstract: The present invention provides a supported catalyst for synthesizing carbon nanotubes. The supported catalyst includes a metal catalyst supported on a supporting body, and the supported catalyst has a surface area of about 15 to about 100 m2/g. The supported catalyst for synthesizing carbon nanotubes according to the present invention can lower production costs by increasing surface area of a catalytic metal to thereby allow production of a large amount of carbon nanotubes using a small amount of the catalyst.
    Type: Application
    Filed: April 15, 2011
    Publication date: August 11, 2011
    Applicant: CHEIL INDUSTRIES INC.
    Inventors: Seung Yong BAE, Byeong Yeol KIM, Yun Tack LEE, Young Kyu CHANG, Young Sil LEE
  • Publication number: 20110172478
    Abstract: [Object] To improve the yield of aromatic hydrocarbon and the stability of active life in a process for producing aromatic compound by using a lower hydrocarbon aromatization catalyst. [Solving Means] A lower hydrocarbon aromatization catalyst for producing aromatic compound under reaction of lower hydrocarbon has an average crystal diameter of not larger than 500 nm. A catalyst in which molybdenum is carried on ZSM-5 zeolite as metallosilicate is used as an example of the above-mentioned catalyst. Additionally, a process for producing aromatic compound upon contact of the above-mentioned catalyst with a reaction gas containing lower hydrocarbon is provided.
    Type: Application
    Filed: June 18, 2009
    Publication date: July 14, 2011
    Inventors: Hongtao Ma, Yuji Ogawa
  • Publication number: 20110172089
    Abstract: [Task] To improve activity of a lower hydrocarbon aromatization catalyst and the catalyst stability. [Solving Means] In a method for producing a lower hydrocarbon aromatization catalyst to produce an aromatic compound by a catalytic reaction using a lower hydrocarbon as a raw material, the catalyst includes a metallosilicate on which molybdenum is supported, a silane in 0.75 weight % or more relative to the metallosilicate component is supported, and the catalyst is prepared by conducting a compressive shaping without adding an inorganic binder that binds particles of the catalyst. As a result, the lower hydrocarbon aromatization catalyst maintains a sufficient shape-retaining property even by a compressive shaping in a binderless manner. Stability of the catalyst and activity of the catalyst improve by subjecting the lower hydrocarbon aromatization catalyst to a compressive shaping in a binderless manner. Its advantageous effect is conspicuous when the amount of addition in terms of silicon oxide is 0.
    Type: Application
    Filed: September 29, 2009
    Publication date: July 14, 2011
    Inventor: Yuji Ogawa
  • Publication number: 20110155641
    Abstract: The present invention concerns a catalyst comprising at least one crystalline material comprising silicon with a hierarchical and organized porosity and at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and/or group VIII of the periodic table of the elements. Said crystalline material comprising silicon with a hierarchical and organized porosity is constituted by at least two spherical elementary particles, each of said particles comprising a matrix based on oxide of silicon, which is mesostructured, with a mesopore diameter in the range 1.5 to 30 nm and having microporous and crystalline walls with a thickness in the range 1.5 to 60 nm, said elementary spherical particles having a maximum diameter of 200 microns. The invention also concerns hydrocracking/hydroconversion and hydrotreatment processes employing said catalyst.
    Type: Application
    Filed: May 13, 2009
    Publication date: June 30, 2011
    Applicant: IFP ENERGIES NOUVELLES
    Inventors: Audrey Bonduelle, Alexandra Chaumonnot
  • Publication number: 20110136658
    Abstract: A catalyst used in the reaction of oxidative bromination of methane is provided. The catalyst is prepared by the following procedures: mixing at least one of the precursors selected from the compounds of Rh, Ru, Cu, Zn, Ag, Ce, V, W, Cd, Mo, Mn, Cr and La which can dissolve in water with the Si precursor, hydrolyzing, drying and sintering. In the catalysis system, methane reacts with HBr, H2O and oxygen source (O2, air or oxygen-rich air), finally CH3Br and CH2Br2 are produced. Another catalyst used in the reaction of condensation of methane bromide to C3-C13 hydrocarbons is also provided. This catalyst is prepared by supporting compounds of Zn or Mg on molecular sieves such as HZSM-5, HY, Hb, 3A, 4A, 5A or 13X et al. With this catalyst, CH3Br and CH2Br2 produced in the former process can react further to give C3 to C13 hydrocarbons and HBr, and HBr can be recycled as a medium.
    Type: Application
    Filed: April 14, 2008
    Publication date: June 9, 2011
    Inventors: Zhen Liu, Hongmin Zhang, Wensheng Li, Yanqun Ren, Xiaoping Zhou
  • Patent number: 7943108
    Abstract: Processes for purifying silicon tetrafluoride source gas by subjecting the source gas to one or more purification processes including: contacting the silicon tetrafluoride source gas with an ion exchange resin to remove acidic contaminants, contacting the silicon tetrafluoride source gas with a catalyst to remove carbon monoxide, by removal of carbon dioxide by use of an absorption liquid, and by removal of inert compounds by cryogenic distillation; catalysts suitable for removal of carbon monoxide from silicon tetrafluoride source gas and processes for producing such catalysts.
    Type: Grant
    Filed: September 11, 2008
    Date of Patent: May 17, 2011
    Assignee: MEMC Electronic Materials, Inc.
    Inventors: Vithal Revankar, Jameel Ibrahim
  • Publication number: 20110101265
    Abstract: A catalyst for producing a carbon nanofiber is obtained by dissolving or dispersing [I] a compound containing Fe element; [II] a compound containing Co element; [III] a compound containing at least one element selected from the group consisting of Ti, V, Cr, and Mn; and [IV] a compound containing at least one element selected from the group consisting of W and Mo in a solvent to obtain a solution or the fluid dispersion, and then impregnating a particulate carrier with the solution or the fluid dispersion. A carbon nanofiber is obtained by bringing a carbon element-containing compound into contact with the catalyst in a vapor phase at a temperature of 300 degrees C. to 500 degrees C.
    Type: Application
    Filed: June 16, 2009
    Publication date: May 5, 2011
    Applicant: SHOWA DENKO K.K.
    Inventors: Eiji Kambara, Akihiro Kitazaki
  • Publication number: 20110100875
    Abstract: The invention relates to a method for synthesizing a hydroprocessing catalyst, wherein the support is prepared by mixing peptized aluminium with amorphous silica or with crystalline aluminium silicate as a catalyst component. The catalyst comprises a metal from group VIB and/or a metal from group VIIIB of the Periodic Table. The catalyst exhibits enhanced activity vis-à-vis hydrodisintegration, hydrodemetallization and hydrodesulphurization, and has a relatively stable life as a function of run time. Thus, the invention relates to a method for developing a catalyst for hydroprocessing heavy hydrocarbon feedstocks, which is characterized in that it comprises two steps: the first step involves optimization of the catalyst formulation with respect to textural properties, the number of acid sites and incorporation of the active metal; the second step involves evaluation with real feedstocks and the stability of the catalyst as is function of run time.
    Type: Application
    Filed: November 27, 2008
    Publication date: May 5, 2011
    Applicant: INSTITUTO MEXICANO DEL PETROLEO
    Inventors: Mohan Singh, Jorge Ancheyta-Juarez, Zenaida Carolina Leyva Inzunza, Samir Kumar Maity
  • Patent number: 7932424
    Abstract: To provide a method for catalytically cracking waste plastics wherein the efficiency in decomposition is high; even polyethylene composed of linear chain molecules difficult in decomposition is decomposable at a low temperature and decomposed residue is hardly produced; the process is simple since dechlorination can be achieved at the same time with catalytically cracking waste plastics in one reaction vessel; and oil fractions can be recovered at 50% or more on a net yield basis. The method for catalytically cracking waste plastics of the present invention has a constitution in which waste plastics are loaded as a raw material into a granular FCC catalyst heated to a temperature range from 350° C. to 500° C. inside a reaction vessel, thereby decomposing and gasifying the waste plastics in contact with the FCC catalyst.
    Type: Grant
    Filed: October 27, 2006
    Date of Patent: April 26, 2011
    Assignee: Kitakyushu Foundation for the Advancement of Industry, Science and Technology
    Inventors: Kaoru Fujimoto, Xiaohong Li
  • Publication number: 20110086755
    Abstract: A catalyst for hydrocracking of heavy oil which comprises a support comprising crystalline aluminosilicate and a porous inorganic oxide excluding the crystalline aluminosilicate and an active metal supported on the support, wherein (a) the support comprises the crystalline aluminosilicate in an amount of 18% by mass or greater and smaller than 45% by mass and the porous inorganic oxide in an amount exceeding 55% by mass and of 82% by mass or smaller based on a sum of the amount of the crystalline aluminosilicate and the amount of the porous inorganic aluminosilicate, (b) the active metal is at least one metal selected from molybdenum, tungsten and nickel, and (c) the distribution of pores in the catalyst for hydrocracking of heavy oil is such that a volume of pores having a diameter of 500 to 10,000 ? is 10% or smaller and a volume of pores having a diameter of 100 to 200 ? is 60% or greater based on a volume of entire pores having a diameter of 50 to 10,000 ?.
    Type: Application
    Filed: March 17, 2009
    Publication date: April 14, 2011
    Inventors: Akira Iino, Kazuhiro Inamura
  • Publication number: 20110073522
    Abstract: The present invention concerns a catalyst comprising at least one amorphous material comprising silicon with a hierarchical and organized porosity and at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and/or group VIII of the periodic table of the elements. Said amorphous material comprising silicon with a hierarchical and organized porosity is constituted by at least two spherical elementary particles, each of said spherical particles comprising a matrix based on oxide of silicon, which is mesostructured, with a mesopore diameter in the range 1.5 to 30 nm and having amorphous and microporous walls with a thickness in the range 1.5 to 50 nm, said elementary spherical particles having a maximum diameter of 200 microns. The invention also concerns hydrocracking/hydroconversion and hydrotreatment processes employing said catalyst.
    Type: Application
    Filed: May 13, 2009
    Publication date: March 31, 2011
    Applicant: IFP ENERGIES NOUVELLES
    Inventors: Audrey Bonduelle, Alexandra Chaumonnot
  • Publication number: 20110065572
    Abstract: The present invention is an improved method for preparing a heterogeneous, supported hydrogenation catalyst that comprises a Group VIII A metal and a catalyst support (for example, SiO2, with either a hydrophilic or a hydrophobic surface) via aqueous deposition precipitation as well as the catalyst prepared by said method.
    Type: Application
    Filed: May 8, 2009
    Publication date: March 17, 2011
    Applicant: DOW GLOBAL TECHNOLOGIES INC.
    Inventors: Michael M. Olken, Edward M. Calverley
  • Publication number: 20110065017
    Abstract: In one embodiment, a composition for use in reforming is provided comprising a catalyst material comprising molybdenum dioxide and/or MO2 (where M=Mo, W, Ru, Re, Os, Ir) nanoparticles having an average particle size from about 2 nm to about 1,000 nm; and a substrate, wherein both the molybdenum dioxide and/or MO2 (where M=Mo, W, Ru, Re, Os, Ir) nanoparticles are substantially immobilized on the substrate. In another embodiment an anode for use in a fuel cell is provided comprising the forgoing composition. And in another embodiment a fuel cell is provided comprising the forgoing anode.
    Type: Application
    Filed: September 10, 2010
    Publication date: March 17, 2011
    Inventors: Su Ha, M. Grant Norton
  • Patent number: 7906689
    Abstract: A catalyst composition for use in manufacturing methacrolein by reacting with one of isobutene and t-butanol, the catalyst composition being represented by the formula of: x (Mo12BiaFebCocAdBeOf)/y Z. Mo12BiaFebCocAdBeOf is an oxide compound. Z is a catalyst carrier is one of graphite, boron, silicon, germanium powder, and a mixture thereof. Mo, Bi, Fe, Co, and O are chemical symbols of molybdenum, bismuth, iron, cobalt, and oxygen respectively. A is one of W, V, Ti, Zr, Nb, Ni, and Re. B is one of K, Rb, Cs, Sr, and Ba. The catalyst is adapted to not only enhance the production of methacrolein with high activeness and high selectivity but also effectively control the heat point of the catalyst during the methacrolein manufacturing process to prolong the catalyst life.
    Type: Grant
    Filed: November 7, 2007
    Date of Patent: March 15, 2011
    Inventors: Yan Zhuang, Chunlei Zhang, Xin Wen, Jun Li, Jingming Shao, Peizhang Zhang
  • Publication number: 20110058999
    Abstract: According to one embodiment, described herein is an exhaust gas after-treatment system that is coupleable in exhaust gas stream receiving communication with an internal combustion engine. The exhaust gas after-treatment system includes a low temperature SCR catalyst configured to reduce NOx in exhaust gas having a temperature below a temperature threshold. The system also includes a normal-to-high temperature SCR catalyst configured to reduce NOx in exhaust gas having a temperature above the temperature threshold.
    Type: Application
    Filed: September 10, 2010
    Publication date: March 10, 2011
    Applicant: CUMMINS IP, INC
    Inventors: Padmanabha Reddy Ettireddy, Matthew Henrichsen
  • Patent number: 7902112
    Abstract: A fluidized bed catalyst for producing acrylonitrile capable of maintaining a high yield of acrylonitrile over a long time, and a process for producing acrylonitrile using the catalyst are provided. A fluidized bed catalyst for producing acrylonitrile having a composition represented by a following general formula: MoaBibFecWdNieMgfAgBhCiDjEkFlGmOn(SiO2)p In the formula, A represents Ce and La, B represents Ca, Sr, Ba, Mn, Co, Cu, Zn and Cd, C represents Y, Pr, Nd, Sm, Al, Cr, Ga and In, D represents Ti, Zr, V, Nb, Ta, Ge, Sn, Pb and Sb, E represents Ru, Rh, Pd, Re, Os, Ir, Pt and Ag, F represents P, B and Te, G represents Li, Na, K, Rb, Cs and Tl, SiO2 represents silica, when a=10, b=0.1 to 1.5, c=0.5 to 3, d=0.1 to 1.5, e=0.1 to 8, f=0.1 to 5, g=0.1 to 1.5, h=0 to 8, i=0 to 3, j=0 to 3, k=0 to 3, l=0 to 3, m=0.01 to 2, p=10 to 200 and n is the atomic ratio of oxygen required to satisfy the valence of each of the elements excluding silicon, and (a×2+d×2)/(b×3+c×3+e×2+f×2+g×3+h×2+i×3+m×1)=0.90 to 1.00).
    Type: Grant
    Filed: October 23, 2007
    Date of Patent: March 8, 2011
    Assignee: Dia-Nitrix Co., Ltd.
    Inventors: Motoo Yanagita, Kenichi Miyaki, Hirokazu Watanabe
  • Patent number: 7902104
    Abstract: This invention relates to a solid divided composition comprising grains whose mean size is greater than 25 ?m and less than 2.5 mm, wherein each grain is provided with a solid porous core and a homogeneous continuous metal layer consisting of at least one type of transition non-oxidised metal and extending along a gangue coating the core in such a way that pores are inaccessible. A method for the production of said composition and for the use thereof in the form of a solid catalyst is also disclosed.
    Type: Grant
    Filed: June 21, 2005
    Date of Patent: March 8, 2011
    Assignees: Arkema France, Institut National Polytechnique de Toulouse
    Inventors: Philippe Kalck, Philippe Serp, Massimiliano Corrias
  • Publication number: 20100326890
    Abstract: Described is a catalyst useful in the hydroprocessing of a heavy hydrocarbon feedstock wherein the catalyst comprises a calcined mixture made by calcining a formed particle of a mixture comprising molybdenum trioxide, a nickel compound, and an inorganic oxide material. The catalyst may be made by mixing an inorganic oxide material, molybdenum trioxide, and a nickel compound to form a mixture that is formed into a particle and calcined to provide a calcined mixture. The process involves the hydrodesulfurization and hydroconversion of a heavy hydrocarbon feedstock which process may include the conversion of a portion of the pitch content of the heavy hydrocarbon feedstock and the yielding of a treated product having an enhanced stability as reflected by its P-value.
    Type: Application
    Filed: September 9, 2010
    Publication date: December 30, 2010
    Inventor: Opinder Kishan BHAN
  • Patent number: 7846867
    Abstract: A method for the production of a composition comprising a metal containing compound, a silica containing material, a promoter, and alumina is disclosed. The composition can then be utilized in a process for the removal of sulfur from a hydrocarbon stream.
    Type: Grant
    Filed: August 30, 2007
    Date of Patent: December 7, 2010
    Assignee: China Petroleum & Chemical Corporation
    Inventors: Uday T. Turaga, Tushar V. Choudhary, Glenn W. Dodwell, Marvin M. Johnson, Deborah K. Just
  • Publication number: 20100298592
    Abstract: The present invention relates to a novel catalyst for producing N-substituted carbamates, the preparation of the catalyst and an improved method for producing N-substituted carbamates from these novel catalysts. The active component of the catalyst is a heteropoly acid and the catalyst support comprises a metal oxide or a metalloid oxide. The catalyst can be used to promote the reaction of carbamate and amine, thereby generating N-substituted carbamates with high yield. In the presence of the catalyst, the reaction conditions are relatively mild, the catalytic activity and selectivity of the reaction are high, and the reaction time is relatively short. Furthermore, the catalyst can be conveniently separated from the reaction system and recycled. therefore, the catalyst can be used to facilitate the further scale-up test and commercial application.
    Type: Application
    Filed: May 17, 2010
    Publication date: November 25, 2010
    Applicant: Bayer MaterialScience AG
    Inventors: Stefan Wershofen, Stephan Klein, Hongchao Li, Xinkui Wang, Qifeng Li, Maoqing Kang
  • Patent number: 7833929
    Abstract: The present invention refers to a continuous process for the manufacture of methyl mercaptan using Mo—O—K-based catalysts. It is further described that the total selectivity of methylmercaptan can be increased by at least 1% by lowering the total gas hourly space velocity. The invention further refers to a process for the preparation of a solid, preformed catalyst system.
    Type: Grant
    Filed: July 24, 2009
    Date of Patent: November 16, 2010
    Assignee: Evonik Degussa GmbH
    Inventors: Yiquan Yang, Qi Wang, Renchun Lin, Hongbin Zhang, Youzhu Yuan, Weiping Fang, Quanxing Zheng, Shenjun Dai, Xingguo Yan, Aiping Chen, Jan-Olaf Barth, Christoph Weckbecker, Klaus Huthmacher, Hubert Redlingshöfer, Sabine Ackermann
  • Publication number: 20100266478
    Abstract: The present invention provides a metal nano catalyst, a method for preparing the same and a method for controlling the growth types of carbon nanotubes using the same. The metal nano catalyst can be prepared by burning an aqueous metal catalyst derivative comprising Co, Fe, Ni or a combination thereof in the presence of a supporting body precursor.
    Type: Application
    Filed: November 30, 2009
    Publication date: October 21, 2010
    Applicant: CHEIL INDUSTRIES INC.
    Inventors: Byeong Yeol KIM, Seung Yong BAE, Young Sil LEE
  • Patent number: 7815792
    Abstract: A process and catalyst for the selective hydrodesulfurization of a naphtha containing olefins. The process produces a naphtha stream having a reduced concentration of sulfur while maintaining the maximum concentration of olefins.
    Type: Grant
    Filed: October 26, 2009
    Date of Patent: October 19, 2010
    Assignee: UOP LLC
    Inventors: Lorenz J. Bauer, Suheil F. Abdo, Laura E. Leonard, Peter Kokayeff
  • Patent number: 7816299
    Abstract: A stacked bed catalyst system comprising at least one first catalyst selected from conventional hydrotreating catalyst having an average pore diameter of greater than about 10 nm and at least one second catalyst comprising a bulk metal hydrotreating catalyst comprised of at least one Group VIII non-noble metal and at least one Group VIB metal and optionally a binder material.
    Type: Grant
    Filed: March 31, 2009
    Date of Patent: October 19, 2010
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Gary P. Schleicher, Kenneth L. Riley
  • Patent number: 7807600
    Abstract: A catalyst for acrylonitrile synthesis is disclosed which is composed of particles containing silica and a composite oxide including at least molybdenum. When the Mo/Si atomic ratio in bulk composition of the catalyst is represented by A and the Mo/Si atomic ratio in surface composition of the particles is represented by B, B/A is not more than 0.6.
    Type: Grant
    Filed: April 14, 2004
    Date of Patent: October 5, 2010
    Assignee: Dia-Nitrix Co., Ltd.
    Inventors: Seigo Watanabe, Koichi Mizutani, Motoo Yanagita, Jinko Izumi
  • Patent number: 7790019
    Abstract: The invention relates to a catalyst including at least one hydro-dehydrogenating element chosen from the group formed by the group VIB and group VIII elements of the periodic table and a substrate based on a silica-alumina matrix with a reduced content of macropores containing a quantity greater than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and based on at least one zeolite. The invention also relates to a substrate based on a silica-alumina matrix with a reduced content of macropores containing a quantity greater than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and based on at least one zeolite. The invention also relates to hydrocracking and/or hydroconversion processes and hydrotreating processes utilizing a catalyst according to the invention.
    Type: Grant
    Filed: December 16, 2004
    Date of Patent: September 7, 2010
    Assignee: IFP Energies Nouvelles
    Inventors: Patrick Euzen, Patrick Bourges, Hugues Dulot, Christophe Gueret
  • Publication number: 20100206775
    Abstract: This invention relates to a method for making shaped bodies having a silica content of at least 85 wt %, to shaped bodies made by such method, to catalyst compositions comprising shaped bodies made by such methods and to catalytic conversion processes using catalyst compositions comprising shaped bodies made by such methods. The method of making the shaped bodies comprises the steps of a) forming shaped bodies from a mixture obtained from at least one amorphous silica powder, at least one silica sol having a pH below 7, and at least one polymeric organic extrusion aid, optionally supplemental liquid medium and optionally crystallites of a zeolite or zeolite-type material; b) drying the shaped bodies obtained in step a); and c) heating the shaped bodies to a temperature ranging from about 500° C. to about 800° C.
    Type: Application
    Filed: January 12, 2007
    Publication date: August 19, 2010
    Inventors: Jean W. Beeckman, Jason Wu, Theodore E. Datz, Ralph Dehaas
  • Patent number: 7772148
    Abstract: An annular unsupported catalyst for the heterogeneously catalyzed partial gas phase oxidation of propene to acrolein at a propene hourly space velocity on the fixed catalyst bed of ?120 1 (STP)/1·h and a total CO2 and saturated hydrocarbon content of the starting reaction gas mixture of below 15 mol %, the catalysts of the fixed catalyst bed are the annular unsupported catalysts whose active composition is a multimetal oxide in which the molar Co/Fe ratio=from 2 to 4 and the molar Co/Mo ratio=from 0.3 to 0.7.
    Type: Grant
    Filed: January 26, 2007
    Date of Patent: August 10, 2010
    Assignee: BASF Aktiengesellschaft
    Inventors: Jochen Petzoldt, Klaus Joachim Mueller-Engel
  • Patent number: 7772147
    Abstract: A solid catalyst carrier substrate coated with a surface area-enhancing washcoat composition including a catalytic component, a metal oxide and a refractory fibrous or whisker-like material having an aspect ratio of length to thickness in excess of 5:1.
    Type: Grant
    Filed: September 12, 2005
    Date of Patent: August 10, 2010
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Paul John Collier, Alison Mary Wagland
  • Patent number: 7759277
    Abstract: The present invention provides a catalyst having high activity and excellent stability, a process for preparation of the catalyst, a membrane electrode assembly, and a fuel cell. The catalyst of the present invention comprises an electronically conductive support and catalyst fine particles. The catalyst fine particles are supported on the support and are represented by the formula (1): PtuRuxGeyTz (1). In the formula, u, x, y and z mean 30 to 60 atm %, 20 to 50 atm %, 0.5 to 20 atm % and 0.5 to 40 atm %, respectively. When the element represented by T is Al, Si, Ni, W, Mo, V or C, the content of the T-element's atoms connected with oxygen bonds is not more than four times as large as that of the T-element's atoms connected with metal bonds on the basis of X-ray photoelectron spectrum (XPS) analysis.
    Type: Grant
    Filed: March 19, 2009
    Date of Patent: July 20, 2010
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Taishi Fukazawa, Wu Mei, Yoshihiko Nakano, Tsuyoshi Kobayashi, Itsuko Mizutani, Hiroyasu Sumino
  • Patent number: 7754647
    Abstract: The present invention provides a process for preparing a supported catalyst (catalyst C) having a support (support S) selected from among oxides, phosphates, silicates, carbides, borides and nitrides of main group elements and elements of transition groups VI and II and mixtures of the abovementioned compounds and an active component (activator A) comprising one or more compounds containing one or more elements of transition groups V, VI and VII customary for the catalysis of metathesis reactions.
    Type: Grant
    Filed: April 4, 2008
    Date of Patent: July 13, 2010
    Assignee: Basf Aktiengesellschaft
    Inventors: Markus Schubert, Michael Hesse, Juergen Stephan, Volker Boehm, Andreas Brodhagen, Frank Poplow, Martina Sinner-Lang, Uwe Diehlmann, Gerhard Cox, Jochen Pfeifer
  • Patent number: 7666296
    Abstract: The invention relates to a process for converting heavy hydrocarbonaceous feedstocks carried out in a slurry reactor in the presence of hydrogen and in the presence of a catalytic composition obtained by: injecting a catalytic precursor of at least one metal of Group VIB and/or Group VIII in at least part of the feedstock to be treated in the absence of an oxide substrate, thermal treatment at a temperature of 400° C.
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: February 23, 2010
    Assignee: Institut Francais du Petrole
    Inventor: Magalie Roy-Auberger
  • Publication number: 20100029474
    Abstract: A stacked bed catalyst system comprising at least one first catalyst selected from conventional hydrotreating catalyst having an average pore diameter of greater than about 10 nm and at least one second catalyst comprising a bulk metal hydrotreating catalyst comprised of at least one Group VIII non-noble metal and at least one Group VIB metal and optionally a binder material.
    Type: Application
    Filed: March 31, 2009
    Publication date: February 4, 2010
    Inventors: Gary P. Schleicher, Kenneth L. Riley
  • Publication number: 20100009844
    Abstract: Processes for purifying silicon tetrafluoride source gas by subjecting the source gas to one or more purification processes including: contacting the silicon tetrafluoride source gas with an ion exchange resin to remove acidic contaminants, contacting the silicon tetrafluoride source gas with a catalyst to remove carbon monoxide, by removal of carbon dioxide by use of an absorption liquid, and by removal of inert compounds by cryogenic distillation; catalysts suitable for removal of carbon monoxide from silicon tetrafluoride source gas and processes for producing such catalysts.
    Type: Application
    Filed: September 21, 2009
    Publication date: January 14, 2010
    Applicant: MEMC ELECTRONIC MATERIALS, INC.
    Inventors: Vithal Revankar, Jameel Ibrahim
  • Publication number: 20100009843
    Abstract: Processes for purifying silicon tetrafluoride source gas by subjecting the source gas to one or more purification processes including: contacting the silicon tetrafluoride source gas with an ion exchange resin to remove acidic contaminants, contacting the silicon tetrafluoride source gas with a catalyst to remove carbon monoxide, by removal of carbon dioxide by use of an absorption liquid, and by removal of inert compounds by cryogenic distillation; catalysts suitable for removal of carbon monoxide from silicon tetrafluoride source gas and processes for producing such catalysts.
    Type: Application
    Filed: September 21, 2009
    Publication date: January 14, 2010
    Applicant: MEMC ELECTRONIC MATERIALS, INC.
    Inventors: Vithal Revankar, Jameel Ibrahim
  • Publication number: 20090325788
    Abstract: The present invention is related to single and/or multiple-wall carbon nanotubes which may contain interstitial metals obtainable by a preparation process, comprising a catalytic step using a catalytic system, said catalytic system comprising a catalyst and a support, said support comprising hydroxides and/or carbonates or mixtures thereof with or without metal oxides. The present invention is also related to carbon fibers obtainable by said preparation process. The present invention also pertains in particular to said catalytic system and to said preparation process. Another aspect concerns the use of the nanotubes and of the catalytic system according to the invention.
    Type: Application
    Filed: July 20, 2009
    Publication date: December 31, 2009
    Applicant: FACULTES UNIVERSITAIRES NOTRE-DAME DE LA PAIX
    Inventors: Janos B. Nagy, Narasimaiah Nagaraju, Isabelle Willems, Antonio Fonseca
  • Patent number: 7629289
    Abstract: A process and catalyst for the selective hydrodesulfurization of a naphtha containing olefins. The process produces a naphtha stream having a reduced concentration of sulfur while maintaining the maximum concentration of olefins.
    Type: Grant
    Filed: June 23, 2004
    Date of Patent: December 8, 2009
    Assignee: UOP LLC
    Inventors: Lorenz J. Bauer, Suheil F. Abdo, Laura E. Jones, Peter Kokayeff
  • Publication number: 20090270648
    Abstract: A fluidized bed catalyst for producing acrylonitrile capable of maintaining a high yield of acrylonitrile over a long time, and a process for producing acrylonitrile using the catalyst are provided. A fluidized bed catalyst for producing acrylonitrile having a composition represented by a following general formula: MoaBibFecWdNieMgfAgBhCiDjEkFlGmOn(SiO2)p In the formula, A represents Ce and La, B represents Ca, Sr, Ba, Mn, Co, Cu, Zn and Cd, C represents Y, Pr, Nd, Sm, Al, Cr, Ga and In, D represents Ti, Zr, V, Nb, Ta, Ge, Sn, Pb and Sb, E represents Ru, Rh, Pd, Re, Os, Ir, Pt and Ag, F represents P, B and Te, G represents Li, Na, K, Rb, Cs and Tl, SiO2 represents silica, when a=10, b=0.1 to 1.5, c=0.5 to 3, d=0.1 to 1.5, e=0.1 to 8, f=0.1 to 5, g=0.1 to 1.5, h=0 to 8, i=0 to 3, j=0 to 3, k=0 to 3, l=0 to 3, m=0.01 to 2, p=10 to 200 and n is the atomic ratio of oxygen required to satisfy the valence of each of the elements excluding silicon, and (a×2+d×2)/(b×3+c×3+e×2+f×2+g×3+h×2+i×3+m×1)=0.90 to 1.00).
    Type: Application
    Filed: October 23, 2007
    Publication date: October 29, 2009
    Applicant: DIA-NITRIX CO., LTD.
    Inventors: Motoo Yanagita, Kenichi Miyaki, Hirokazu Watanabe
  • Patent number: 7605107
    Abstract: This invention relates to supported multi-metallic catalysts for use in the hydroprocessing of hydrocarbon feeds, as well as a method for preparing such catalysts. The catalysts are prepared from a catalyst precursor comprised of at least one Group VIII metal and a Group VI metal and an organic agent selected from the group consisting of amino alcohols and amino acids. The catalyst precursor is thermally treated to partially decompose the organic agent, then sulfided.
    Type: Grant
    Filed: September 29, 2005
    Date of Patent: October 20, 2009
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Stuart L. Soled, Sabato Miseo, Joseph E. Baumgartner, Christine E. Kliewer, Andrzej Malek, Andrew C. Moreland
  • Publication number: 20090255851
    Abstract: A catalyst that includes one or more metals from Column 6 of the Periodic Table and/or one or more compounds of one or more metals from Column 6 of the Periodic Table and a support. The support comprises from 0.01 grams to 0.2 gram of silica and from 0.80 grams to 0.99 grams of alumina per gram of support. The catalyst has a surface area of at least 315 m2/g, a pore size distribution with a median pore diameter of at most 100 ?, and at least 80% of its pore volume in pores having a pore diameter of at most 300 ?. The catalyst exhibits one or more peaks between 35 degrees and 70 degrees, and at least one of the peaks has a base width of at least 10 degrees, as determined by x-ray diffraction at 2-theta. Methods of preparation of such catalyst are described herein. Methods of contacting a hydrocarbon feed with hydrogen in the presence of such catalyst to produce a crude product. Uses of crude products obtained. The crude product composition is also described herein.
    Type: Application
    Filed: April 10, 2009
    Publication date: October 15, 2009
    Inventors: Opinder Kishan BHAN, Scott Lee WELLINGTON
  • Patent number: 7598203
    Abstract: Provided are a hydrogenation catalyst for hydrocarbon oil, having markedly improved desulfurization activity, denitrogenation activity, and dearomatization activity; a carrier for the catalyst and its production; and a method of hydrogenation of hydrocarbon oil with the catalyst.
    Type: Grant
    Filed: January 17, 2007
    Date of Patent: October 6, 2009
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Narinobu Kagami, Ryuichiro Iwamoto
  • Publication number: 20090240010
    Abstract: The present invention provides activator-supports containing alumina-silica compounds with high levels of alumina, and polymerization catalyst compositions employing these activator-supports. Methods for making these activator-supports based on alumina-silica and for using such compounds in catalyst compositions for the polymerization and copolymerization of olefins are also provided.
    Type: Application
    Filed: March 20, 2008
    Publication date: September 24, 2009
    Inventors: Max P. McDaniel, Qing Yang, Randy S. Muninger, Elizabeth A. Benham, Kathy S. Collins
  • Publication number: 20090230026
    Abstract: This invention relates to a hydrodesulfurization catalyst, a method for preparing the catalyst, and a method for the preparation of low sulfur gasoline fuel with minimal loss of RON. The catalyst particles include a group VIB metal and a support material having relatively high surface area, and optionally includes one or more group VIIIB metal. The method for preparing the catalyst allows for greater loading of the active metal species on the surface of the support material under aqueous reaction conditions.
    Type: Application
    Filed: February 23, 2009
    Publication date: September 17, 2009
    Inventors: Ki-Hyouk Choi, Sameer Ali Al-Ghamdi, Ali H. Al-Shareef, Ali H. Al-Hamadah
  • Publication number: 20090223865
    Abstract: A catalyst composition comprising a special support of alumina and an amount of silica in the range of from 0.3 wt % to 10 wt % of the total weight of the support, a cobalt component, and a high concentration of a molybdenum component that exceeds 12 wt % of the total weight of the catalyst composition. The catalyst composition is highly active toward the desulfurization of an olefin-containing feedstock having a sulfur concentration while being selective toward the hydrogenation of the olefins contained in the feedstock and is used in a novel process for the selective desulfurization of an olefin-containing feedstock.
    Type: Application
    Filed: March 6, 2008
    Publication date: September 10, 2009
    Inventor: Opinder Kishan BHAN
  • Patent number: 7585812
    Abstract: A catalyst for use in the Fischer-Tropsch process, and a method to prepare the catalyst is disclosed. The catalyst of the present invention has a higher surface area, more uniform metal distribution, and smaller metal crystallite size than Fischer-Tropsch catalysts of the prior art.
    Type: Grant
    Filed: June 20, 2008
    Date of Patent: September 8, 2009
    Assignee: Sud-Chemie Inc.
    Inventors: X. D. Hu, Patrick J. Loi, Robert J. O'Brien
  • Patent number: 7579297
    Abstract: A method for producing a catalyst containing at least molybdenum, bismuth and iron including the steps of kneading particles containing catalyst components, an organic binder and a liquid, where the organic binder contains at least a high-viscosity organic binder having a viscosity of from 5,000 mPa·s to 25,000 mPa·s and a low-viscosity organic binder having a viscosity of from 10 mPa·s to less than 5,000 mPa·s, and extrusion molding the resultant kneaded mixture is provided.
    Type: Grant
    Filed: December 9, 2004
    Date of Patent: August 25, 2009
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Masahide Kondo, Hiroyuki Naitou, Toru Kuroda
  • Publication number: 20090209796
    Abstract: The present invention provides a heteropolyacid salt catalyst for use in an alkylation reaction of an aromatic compound or a transalkylation, disproportionation or isomerization reaction of an alkyl aromatic compound, which comprises a heteropolyacid salt catalyst represented by the following formula (1): H4-mZmSiXl2O40??(1) wherein X represents W or Mo, Z represents (NH4) or an alkali metal atom, and m represents a numerical value of 0?m?4, and comprising a heteropolyacid salt crystal having an average particle diameter in the short axis of the crystal of less than 300 nm as a main component, wherein said heteropolyacid salt catalyst has an acid amount on the external surface of not less than 190 ?mol per weight of a heteropolyacid salt.
    Type: Application
    Filed: May 28, 2007
    Publication date: August 20, 2009
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventor: Takuo Hibi