Titanium Containing Patents (Class 502/309)
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Patent number: 12115518Abstract: The present invention relates to the technical field of catalyst preparation, disclosing a preparation method and application of a coated vanadium-tungsten-titanium oxide monolithic SCR catalyst. The method includes the steps of mixing a vanadium oxide precursor, a tungsten oxide precursor, titanium dioxide, an inorganic adhesive, an organic adhesive and a macromolecular surfactant with deionized water and stirring them to obtain a thick liquid; adding a pH adjuster to the thick liquid to make its pH 1.5-4.5; impregnating a cordierite honeycomb carrier in the thick liquid to obtain a preliminarily-impregnated catalyst and dried and calcined the preliminarily-impregnated catalyst to obtain a finished catalyst. The method has advantages such as simple operation, easy repetition and short time-consuming, so it can be applied to exhaust gas post-treatment of a marine diesel engine, and provide a good choice for catalysts used to denitrify medium and high temperature exhausted gas from marine engines.Type: GrantFiled: December 14, 2023Date of Patent: October 15, 2024Assignee: TIANJIN RESEARCH INSTITUTE FOR WATER TRANSPORT ENGINEERING, M.O.T.Inventors: Mingyu Guo, Yidan Huang, Boqun Liu, Shaoping Cui, Shipei Dong, Siqi Chen, Bin Liu, Yingjie Zhao, Fang Lin, Zhonghua Tian, Junjie Zhao, Wei Ye, Yanjie Wei, Zhipeng Zhang
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Patent number: 11920828Abstract: An air purification system including a filter assembly including a substrate including a fibrous media, and a photocatalytic material disposed on the substrate, wherein the photocatalytic material includes a first quantity of crushed nanostructures; and a photon source arranged to illuminate the photocatalytic material with optical radiation.Type: GrantFiled: March 26, 2020Date of Patent: March 5, 2024Assignee: Molekule, Inc.Inventors: Dilip N. Goswami, Philip Myers
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Patent number: 11761652Abstract: An air purification system including a filter assembly including a substrate including a fibrous media, and a photocatalytic material disposed on the substrate, wherein the photocatalytic material includes a first quantity of crushed nanostructures; and a photon source arranged to illuminate the photocatalytic material with optical radiation.Type: GrantFiled: March 26, 2020Date of Patent: September 19, 2023Assignee: Molekule, Inc.Inventors: Dilip N. Goswami, Philip Myers
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Patent number: 11478783Abstract: A wall-flow honeycomb catalyst for dust removal and low-temperature denitrification of flue gas, and a preparation process thereof are provided. The catalyst is prepared from the following raw materials in parts by weight: calcined titanium dioxide: 30 to 60 parts; crude titanium dioxide: 30 to 50 parts; boehmite: 3 to 5 parts; fused silica powder: 2 to 4 parts; binder: 0.5 to 2 parts; lubricant: 0.5 to 2 parts; vanadium-molybdenum composite oxide: 5 to 10 parts; and water: 150 to 200 parts; and the vanadium-molybdenum composite oxide is obtained by dissolving ammonium metavanadate and ammonium molybdate in an oxalic acid solution and spray-drying a resulting solution. The preparation process of the catalyst of the present disclosure is simple and low in cost.Type: GrantFiled: April 6, 2021Date of Patent: October 25, 2022Assignee: JIANGSU LONGKINGCOTECH CO., LTD.Inventors: Tao Zhang, Lifeng Deng, Anyang Liu, Chunyun Luo, Yingjie Ren, Shengen Zhang
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Patent number: 11434803Abstract: Provided is a combustion system using a catalyst having better denitration efficiency at low temperatures, during a selective catalytic reduction reaction in which ammonia is used as a reducing agent. This combustion system comprises: a combustion device that combusts fuel; an exhaust path through which flows exhaust gas generated from the combustion of fuel in the combustion device; a dust collection device that is arranged on the exhaust path and collects soot/dust in the exhaust gas; and a denitration device that is arranged on the exhaust path and removes nitrogen oxides from the exhaust gas by means of a denitration catalyst, wherein the denitration device is arranged downstream of the dust collection device on the exhaust path, and the denitration catalyst contains vanadium oxide, has a carbon content of 0.05 wt % or more, and has a defect site in which oxygen deficiency occurs in a crystal structure.Type: GrantFiled: March 7, 2019Date of Patent: September 6, 2022Assignees: THE CHUGOKU ELECTRIC POWER CO., INC., TOKYO METROPOLITAN PUBLIC UNIVERSITY CORPORATIONInventors: Eiji Kiyonaga, Kazuhiro Yoshida, Keiichiro Morita, Toru Murayama, Masatake Haruta, Shinichi Hata, Yusuke Inomata
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Patent number: 11278877Abstract: In a photocatalyst and a photocatalyst carrier, tungsten oxide microcrystals that have a crystal grain size of 10 nm or less and oxidizes a gaseous chemical substance and titanium oxide microcrystals that have a crystal grain size of 10 nm or less and oxidizes the gaseous chemical substance are irregularly arranged to form a solid.Type: GrantFiled: May 28, 2018Date of Patent: March 22, 2022Assignee: MITSUBISHI ELECTRIC CORPORATIONInventors: Noriaki Katsumata, Yoko Matsuura, Noboru Wada, Ryu Abe, Osamu Tomita, Masaya Shigemitsu
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Patent number: 11014075Abstract: A novel catalyst and process for producing a mixed oxide material containing molybdenum, vanadium, tellurium and niobium is disclosed. The material can be used as a catalyst for the oxidative dehydrogenation of ethane to ethene or the oxidation of propane to acrylic acid.Type: GrantFiled: January 26, 2018Date of Patent: May 25, 2021Assignee: Clariant Produkte GmbhInventors: Gerhard Mestl, Klaus Wanninger, Daniel Melzer, Maria Cruz Sanchez-Sanchez, Julia Tseglakova, Johannes Lercher
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Patent number: 11007509Abstract: A simple, scalable, inexpensive, and reproducible method of selectively preparing the M1 phase of a MoVNbTe mixed oxide in a hydrothermal synthesis using tellurium dioxide is disclosed which can utilize inexpensive metal oxides as starting compounds.Type: GrantFiled: January 26, 2018Date of Patent: May 18, 2021Assignee: CLARIANT PRODUCKTE GMBHInventors: Gerhard Mestl, Klaus Wanninger, Silvia Neumann
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Patent number: 10987655Abstract: A molybdenum-vanadium bimetal oxide catalyst having a molecular formula of Mo1Vy, where y represents an atomic molar ratio of vanadium and molybdenum. An oxygen support Mo1Vy is prepared by an impregnation method including impregnation, drying, calcination, and tablet pressing. In the dehydrogenation reaction of a light alkane to an alkene over the supported molybdenum-vanadium bimetal oxide, the reaction temperature is 450° C.-550° C. Propane can be oxidized and dehydrogenated to produce propylene with a high activity and high selectivity. A conversion rate of propane remains at 30%-40%, and a selectivity for propylene is 80%-90%. A fresh oxygen support changes from a high-valence state to a low-valence state after reacting with propane. A low-valence state oxygen support reacts with air or oxygen to be oxidized to a high-valence state, and recovers lattice oxygen and cycles again.Type: GrantFiled: July 25, 2018Date of Patent: April 27, 2021Assignee: TIANJIN UNIVERSITYInventors: Jinlong Gong, Sai Chen, Liang Zeng, Rentao Mu
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Patent number: 10865684Abstract: A combustion system operated at low cost is provided. A combustion system 1 includes a combustion device 10 that burns fuel, an exhaust line L1 through which exhaust gas flows, the exhaust gas being generated through combustion of the fuel in the combustion device 10, an air preheater 30 that is disposed in the exhaust line L1 and that recovers heat from the exhaust gas, and a denitration device 40 that is disposed in the exhaust line L1 and that removes nitrogen oxide from the exhaust gas using a denitration catalyst. The denitration device 40 is disposed downstream from the air preheater 30 in the exhaust line L1, and the denitration catalyst contains 43 wt % or more of vanadium pentoxide and has a BET specific surface area of 30 m2/g or more.Type: GrantFiled: March 7, 2017Date of Patent: December 15, 2020Assignees: THE CHUGOKU ELECTRIC POWER CO., INC., TOKYO METROPOLITAN UNIVERSITYInventors: Eiji Kiyonaga, Kenji Hikino, Keiichiro Morita, Masatake Haruta, Toru Murayama, Makoto Mino
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Patent number: 10763128Abstract: The present invention relates to a process of a surface-mounting three-dimensional package structure electrically connected by a pre-packaged metal, comprising: taking a metal sheet; punching or etching the metal sheet; packaging a conductive metal-pillar frame; performing windowing and slotting; taking a substrate on which a chip is surface-mounted; fitting the conductive metal-pillar frame; performing packaging and grinding; surface-mounting a passive device; performing plastic packaging and ball-mounting; and performing cutting. The process of the present invention can improve the integration level and the reliability.Type: GrantFiled: December 14, 2017Date of Patent: September 1, 2020Assignee: JIANGSU CHANGJIANG ELECTRONICS TECHNOLOGY CO, LTD.Inventors: Haishen Kong, Yubin Lin, Jinxin Shen, Xinfu Liang, Qingyun Zhou
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Patent number: 10682639Abstract: A catalyst-containing ceramic dust filter for off-gas or exhaust gas cleaning is prepared by a method comprising the steps of making a water-based impregnation slurry, which comprises a catalytically effective amount of at least one catalytically active metal and an oxide support, to form a catalytically active metal oxide support, impregnating the filter substrate with the impregnation slurry, spraying from the inside to control the amount of liquor while leaving the outer few millimeters of the filter wall dry, and drying the impregnated filter. The impregnated filter is preferably dried by using microwave energy.Type: GrantFiled: September 28, 2016Date of Patent: June 16, 2020Assignee: Haldor Topsoe A/SInventors: Francesco Castellino, Michael Boe
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Patent number: 10618000Abstract: Articles comprising a catalyst film comprising VOx, MoO3 or WO3, and TiO2 deposited on a substrate are disclosed. The articles are useful for selective catalytic reduction (SCR) of NOx in exhaust gases. Methods for producing such articles deposit a catalyst film on the substrate to form a coated substrate, which is then calcined. When used in an SCR process, the coated articles have enhanced activity for NOx conversion, reduced activity for SOx conversion, or both. Light-weight, coated articles having high catalyst loads can be fabricated at the same or reduced dimensions when compared with laminated articles, and increased kNOx/kSOx ratios are available even from coated articles having relatively thin catalyst films. The articles should have particular value for power plant operations, where coal and high-sulfur fuels are commonly used and controlling sulfur trioxide generation is critical.Type: GrantFiled: September 1, 2017Date of Patent: April 14, 2020Assignee: Johnson Matthey Public Limited CompanyInventors: Paul Joseph Andersen, Maria Brandmair, Silvia Alcove Clave, Rodney Foo, Bruce Gomersall, Michael Nash, Alison Mary Wagland
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Patent number: 10286384Abstract: A novel mixed metal molybdate useful as a hydroprocessing catalyst or catalyst precursor has been created. The hydroprocessing using the novel mixed metal molybdate material or the decomposition product thereof may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.Type: GrantFiled: July 17, 2018Date of Patent: May 14, 2019Assignee: UOP LLCInventors: Stuart Miller, Susan C. Koster
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Patent number: 10052614Abstract: A novel mixed metal molybdate useful as a hydroprocessing catalyst has been created. The hydroprocessing using the novel mixed metal molybdate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.Type: GrantFiled: December 13, 2016Date of Patent: August 21, 2018Assignee: UOP LLCInventors: Stuart Miller, Susan C. Koster
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Patent number: 10022704Abstract: The invention relates to a catalyst comprising at least two catalytically active layers, A and B, wherein A contains a carrier oxide and components A1 and A2, and B contains a carrier oxide and components B1, B2, and B3, wherein A1, A2, and B1 to B3 are defined as disclosed in claim 1. The proportion of component A1 in layer A is thereby greater than the proportion of component B1 in layer B, wherein the proportion of layer A with respect to the total weight of layers A and B, is greater than the proportion of layer B. The invention further relates to a method for reducing nitrogen oxides in exhaust gases of lean-burn internal combustion engines and to an exhaust gas cleaning system.Type: GrantFiled: November 19, 2014Date of Patent: July 17, 2018Assignee: UMICORE AG & CO. KGInventors: Stephan Malmberg, Nicola Soeger, Yvonne Demel, Gerald Jeske
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Patent number: 9856149Abstract: It discloses a vanadium-titanium compound material with high thermal stability and high activity and a preparation method thereof. The vanadium-titanium compound material is mainly composed of vanadium oxide and titanium oxide, where the content of vanadium oxide is 0.5% to 30% by mass of the vanadium-titanium compound material, and the crystal form of titanium oxide in the vanadium-titanium compound material is one of anatase and TiO2(B) or a mixture thereof.Type: GrantFiled: September 29, 2012Date of Patent: January 2, 2018Assignees: NANJING TECH UNIVERSITY, CHANGSHU YUTYRONE ADVANCED WEAR MATERIALS TECHNOLOGY CO., LTD.Inventors: Zhuhong Yang, Licheng Li, Xiaohua Lu, Wenjun Yao, Tuo Ji, Zheng Li, Chang Liu
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Patent number: 9833776Abstract: The present invention relates to a dispersion liquid of titanium oxide-tungsten oxide composite photocatalytic fine particles that is characterized by having two types of photocatalytic fine particles dispersed in an aqueous dispersion medium, the fine particles including i) fine particles of titanium oxide that contain a peroxotitanium component and a copper component and ii) fine particles of tungsten oxide. The present invention can provide a dispersion liquid and the like that can be used to conveniently manufacture a photocatalytic thin film that demonstrates photocatalytic activity even within visible light (400-800 nm) only, exhibits high antibacterial performance, is highly durable, and wherein the state of copper coordination is stable against exposure to heat and ultraviolet rays and is not easily modified. The dispersion liquid is a dispersion liquid of titanium oxide-tungsten oxide composite photocatalytic fine particles that contains copper-containing titanium oxide fine particles.Type: GrantFiled: September 29, 2014Date of Patent: December 5, 2017Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Manabu Furudate, Tomohiro Inoue, Yoshitsugu Eguchi, Takashi Kobayashi
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Patent number: 9321651Abstract: The present invention relates to a catalyst composition for the synthesis of multi-walled carbon nanotube having high apparent density in a manner of high yield. More particularly, this invention relates to a multi-component metal catalyst composition comprising i) main catalyst of Fe and Mo, ii) inactive support of Al and iii) optional co-catalyst at least one selected from Co, Ni, Ti, Mn, W, Sn or Cu. Further, the present invention affords multi-walled carbon nanotube having 5˜15 nm of fibrous diameter and 0.5˜4 ?m bundle diameter.Type: GrantFiled: August 21, 2015Date of Patent: April 26, 2016Assignee: KOREA KUMHO PETROCHEMICAL CO., LTD.Inventors: Sang Kyu Choi, Sang Hyo Ryu, Ho Soo Hwang, Chung Heon Jeong, Dong Hoon Oh, Yeon Ja Lee, Youngchan Jang
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Patent number: 9248433Abstract: A composition that comprises a titanium compound, an iron compound, and a tungsten compound, wherein the titanium compound has a microcrystalline anatase structure and/or is obtained in the production of TiO2 according to the sulphate process, during hydrolysis of a solution which contains titanyl sulphate, and also in that the composition has a vanadium content, calculated as V, of less than 0.15 wt. % in relation to the solids content of the composition.Type: GrantFiled: March 30, 2012Date of Patent: February 2, 2016Assignee: Sachtleben Pigment GmbHInventors: Ralf Becker, Gerhard Auer, Frank Hipler, Nicole Galbarczyk, Kai-Sven Lange, Horst Günnel, Uwe Dörschug
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Publication number: 20150148221Abstract: The disclosure provides molybdenum and/or tungsten containing catalyst materials useful for the sour gas shift reactions and methods for using such catalyst materials, for example, for converting carbon monoxide and steam to carbon dioxide and hydrogen.Type: ApplicationFiled: November 25, 2013Publication date: May 28, 2015Applicant: Clariant CorporationInventors: Justin X. Wang, William M. Faris, Yeping Cai
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Publication number: 20150125369Abstract: The invention relates to a coated particle filter (3), in particular wall-flow filter, having a length (L). According to the invention, at least two zones (4, 5) which have different coatings are provided along the length (L). The invention also relates to a catalytic converter (2), wherein the catalytic converter (2) is formed with a coating which has a washcoat coating layer as a lower coating layer, onto which palladium is deposited. The invention finally relates to a device (1) for the purification of exhaust gases, in particular exhaust gases of diesel-engined motor vehicles, comprising a catalytic converter (2) and a coated particle filter (3) of length (L) positioned downstream of the catalytic converter (2), wherein the particle filter (3) and the catalytic converter (2) are designed in accordance with the invention.Type: ApplicationFiled: April 26, 2013Publication date: May 7, 2015Inventor: Bernhard Kahlert
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Patent number: 9011809Abstract: An ammonia oxidation catalyst being superior in heat resistance and capable of suppressing by-production of N2O or NOx. The ammonia oxidation catalyst is made by coating at least two catalyst layers having a catalyst layer (lower layer) including a catalyst supported a noble metal on an inorganic base material including any of a composite oxide (A) having at least titania and silica as main components, alumina, and a composite oxide (B) consisting of alumina and silica; and a catalyst layer (upper layer) including a composite oxide (C) consisting of at least silica, tungsten oxide, ceria and zirconia, at the surface of an integral structure-type substrate, wherein a composition of the composite oxide (C) is silica: 20% by weight or less, tungsten oxide: 1 to 50% by weight, ceria: 1 to 60% by weight, and zirconia: 30 to 90% by weight.Type: GrantFiled: February 24, 2012Date of Patent: April 21, 2015Assignee: N.E. Chemcat CorporationInventors: Tomoaki Ito, Toshinori Okajima, Takashi Hihara, Makoto Nagata
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Publication number: 20150105244Abstract: An electrode material for a direct fuel cell or an electrochemical hydrogenation electrolytic tank, includes component A, or component B, or the mixture of component A and component B. The component A is any one of or a mixture of two or more than two of HnNb2O5, HnV2O5, HnMoO3, HnTa2O5 or HnWO3 at any ratio, where 0<n?4. The component B is any one of or a mixture of two or more than two of Nb2O5, V2O5, MoO3, Ta2O5, WO3 at any ratio.Type: ApplicationFiled: December 19, 2014Publication date: April 16, 2015Inventors: Hansong Cheng, Chaoqun Han, Ming Yang, Gang Ni, Liang Huang, Libin Pei
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Publication number: 20150105580Abstract: The present invention relates to a device for treatment of material transported through the device comprising at least one porous element consisting of specific solid metallic structure which allows cross-flow of the material through the porous element and wherein the porous element is coated by a non-acidic metal oxide which is impregnated by palladium (Pd).Type: ApplicationFiled: April 17, 2013Publication date: April 16, 2015Inventor: Werner Bonrath
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Patent number: 9000207Abstract: A method for producing a silica-supported catalyst comprising Mo, V. Nb, and a component X (Sb and/or Te) to be used in a vapor phase catalytic oxidation or ammoxidation of proprane, comprising the steps of: (I) preparing a raw material mixture solution by mixing Mo, V, Nb, component X, a silica sol, and water; (II) obtaining a dry powder by drying the raw material mixture solution; and (III) obtaining a silica-supported catalyst by calcining the dry powder, wherein the silica sol contains 10 to 270 wt ppm of nitrate ions based on SiO2.Type: GrantFiled: May 22, 2014Date of Patent: April 7, 2015Assignee: Asahi Kasei Chemicals CorporationInventors: Yusuke Ishii, Takaaki Kato
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Patent number: 8992871Abstract: A CO shift catalyst according to the present invention reforms carbon monoxide (CO) contained in gas. The CO shift catalyst is prepared from one or both of molybdenum (Mo) and cobalt (Co) as an active ingredient and an oxide of one of, or a mixture or a compound of, titanium (Ti), silicon (Si), zirconium (Zr), and cerium (Ce) as a carrier for supporting the active ingredient. The CO shift catalyst can be used in a halogen-resistant CO shift reactor (15) that converts CO contained in gasified gas (12) generated in a gasifier (11) into CO2.Type: GrantFiled: April 10, 2009Date of Patent: March 31, 2015Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Toshinobu Yasutake, Tetsuya Imai, Masanao Yonemura, Susumu Okino, Keiji Fujikawa, Shinya Tachibana
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Patent number: 8975205Abstract: Embodiments of the present disclosure include structures, photocatalytic structures, and photoelectrochemical structures, methods of making these structures, methods of making photocatalysis, methods of splitting H2O, methods of splitting CO2, and the like.Type: GrantFiled: November 10, 2009Date of Patent: March 10, 2015Assignee: University of Georgia Research Foundation, Inc.Inventors: Wilson Smith, Yiping Zhao
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Patent number: 8969238Abstract: The present invention concerns a method of preparation of nanoparticular metal oxide catalysts having a narrow particle size distribution. In particular, the invention concerns preparation of nanoparticular metal oxide catalyst precursors comprising combustible crystallization seeds upon which the catalyst metal oxide is co-precipitated with the carrier metal oxide, which crystallization seeds are removed by combustion in a final calcining step. The present invention also concerns processes wherein the nanoparticular metal oxide catalysts of the invention are used, such as SCR (deNOx) reactions of nitrogen oxides with ammonia or urea as reductant, oxidations of alcohols or aldehydes with dioxygen or air to provide aldehydes, ketones or carboxylic acids, and photocatalytic oxidation of volatile organic compounds (VOCs).Type: GrantFiled: November 17, 2009Date of Patent: March 3, 2015Assignee: Danmarks Tekniske UniversitetInventors: Rasmus Fehrmann, Anders Riisager, Søren Birk Rasmussen, Steffen Buss Kristensen, Andreas Jonas Kunov-Kruse
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Patent number: 8956995Abstract: The invention provides a catalyst for thermal decomposition of an organic substance having the form of spherical granule having a particle diameter of 0.1 to 1.2 mm, a pore volume of 0.1 to 0.3 mL/g, a tap density of 1.05 to 1.4 g/mL, and a wear rate of 2% by weight or less, the catalyst being obtained by mixing and granulating a pulverized product of an inorganic oxide exemplified by titanium oxide with at least one sol selected from a titania sol, a silica sol, an alumina sol, and a zirconia sol to make spherical granules, calcining the spherical granules at a temperature from 400 to 850° C., and sieving the calcined granules.Type: GrantFiled: August 18, 2009Date of Patent: February 17, 2015Assignee: Sakai Chemical Industry Co., Ltd.Inventors: Mitsuru Masatsugu, Toshikatsu Umaba, Itsushi Kashimoto
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Publication number: 20150031526Abstract: A catalyst article for treating an emission gas is provided comprising (a) an oxidation catalyst comprising at least one noble metal on a WO3—TiO2 support, wherein the support contains about 1 to about 20 weight percent WO3 based on the combined weight of the WO3 and TiO2; and (b) a substrate, wherein the first and second catalyst layers are on and/or within the substrate.Type: ApplicationFiled: July 28, 2014Publication date: January 29, 2015Inventors: David Micallef, Alex Parsons
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Publication number: 20150024927Abstract: A hydrogenation catalyst and process using the catalyst for converting a mixture comprising acetic acid and ethyl acetate to ethanol at a first temperature, and the catalyst desorbs ethyl acetate, in the absence of hydrogen, at a second temperature that is greater than the first temperature. The catalyst has a suitable chemisorption of ethyl acetate at the first temperature in the absence of hydrogen. In one embodiment, the first temperature ranges from 125° C. to 350° C. and the second temperature ranges from 300° C. to 600° C. The catalyst comprises one or more active metals or oxide thereof on a support that comprises tungsten or an oxide thereof. The one or more active metals are selected from the group consisting of cobalt, copper, gold, iron, nickel, palladium, platinum, iridium, osmium, rhenium, rhodium, ruthenium, tin, zinc, lanthanum, cerium, manganese, chromium, vanadium, and molybdenum.Type: ApplicationFiled: September 23, 2014Publication date: January 22, 2015Inventors: Zhenhua Zhou, Heiko Weiner, Dheeraj Kumar, Xiaoyan Tu, Victor J. Johnston, Radmila Wollrab
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Patent number: 8937203Abstract: The present invention relates to catalysts, to processes for making catalysts and to chemical processes employing such catalysts. The multifunctional catalysts are preferably used for converting acetic acid and ethyl acetate to ethanol. The catalyst is effective for providing an acetic acid conversion greater than 20% and an ethyl acetate conversion greater than 0%. The catalyst comprises a precious metal and one or more active metals on a modified support. The modified support includes a metal selected from the group consisting of tungsten, vanadium, and tantalum, provided that the modified support does not contain phosphorous.Type: GrantFiled: August 27, 2012Date of Patent: January 20, 2015Assignee: Celanese International CorporationInventors: Zhenhua Zhou, Heiko Weiner, Radmila Wollrab
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Publication number: 20150018581Abstract: The present invention provides a method for simultaneous production of components suitable for production of base oil and fuel components. In the method a feedstock comprising fatty acids and/or fatty acid esters is entered into a reaction zone and subjected to a ketonisation reaction in the presence of a dual catalyst system. This system is configured to perform a ketonisation reaction and a hydrotreatment reaction, under hydrogen pressure. Subsequently ketones are obtained.Type: ApplicationFiled: November 1, 2012Publication date: January 15, 2015Applicant: Neste Oil OyjInventors: Mika Kettunen, Jukka Myllyoja, Rami Piilola, Goran Sandstrom, Pekka Aalto
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Patent number: 8932977Abstract: A catalyst for the electrolysis of water molecules and hydrocarbons, the catalyst including catalytic groups comprising A1-xB2-yB?yO4 spinels having a cubical M4O4 core, wherein A is Li or Na, B and B? are independently any transition metal or main group metal, M is B, B?, or both, x is a number from 0 to 1, and y is a number from 0 to 2. In photo-electrolytic applications, a plurality of catalytic groups are supported on a conductive support substrate capable of incorporating water molecules. At least some of the catalytic groups, supported by the support substrate, are able to catalytically interact with water molecules incorporated into the support substrate. The catalyst can also be used as part of a photo-electrochemical cell for the generation of electrical energy.Type: GrantFiled: June 24, 2011Date of Patent: January 13, 2015Assignee: Rutgers, The State University of New JerseyInventors: G. Charles Dismukes, Martha Greenblatt
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Publication number: 20140343307Abstract: A carrier for an ethylene epoxidation catalyst is provided that includes an alumina first component and a mixed metal oxide of alumina second component. The mixed metal oxide of alumina second component comprises a corundum lattice structure having a plurality of O—Al—O bonds, wherein an Al atom of at least one O—Al—O bond of the plurality of O—Al—O bonds, but not all of the plurality of O—Al—O bonds, is replaced with a divalent or trivalent transition metal selected from the group consisting of scandium (Sc), titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni) copper (Cu), and zinc (Zn). A catalyst containing the carrier, as well as a process for the epoxidation of ethylene using the catalyst are also disclosed.Type: ApplicationFiled: May 16, 2014Publication date: November 20, 2014Applicant: Scientific Design Company, Inc.Inventors: Nabil Rizkalla, Andrzej Rokicki
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Patent number: 8889078Abstract: A porous oxide catalyst includes porous oxide, and an oxygen vacancy-inducing metal which induces an oxygen vacancy in a lattice structure of a porous metal oxide.Type: GrantFiled: March 15, 2011Date of Patent: November 18, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Sang-min Ji, Hyun-chul Lee, Doo-hwan Lee, Seon-ah Jin
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Patent number: 8883100Abstract: The present invention relates to a particle filter comprising a porous carrier body, an SCR active component and an oxidation catalyst, wherein the SCR active component is present as coating on the exhaust-gas entry surface and the inner surface of the porous carrier body and the oxidation catalyst as coating on the exhaust-gas exit surface of the porous carrier body. According to the invention the oxidation catalyst changes its function depending on operating conditions. In normal operation it serves as NH3 slip catalyst for oxidizing excess NH3 and during filter regeneration it operates according to the 3-way principle for converting NOx and CO. The invention also relates to a method for producing the particle filter, the use of the particle filter for treating exhaust gases from the combustion of fossil, synthetic or biofuels as well as an exhaust-gas cleaning system which contains the particle filter according to the invention.Type: GrantFiled: November 4, 2009Date of Patent: November 11, 2014Assignee: Sued-Chemie IP GmbH & Co. KGInventors: Martin Paulus, Klaus Wanninger
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Publication number: 20140329668Abstract: A NOx removal catalyst for high-temperature flue gas according to the present invention is a NOx removal catalyst for high-temperature flue gas that contains nitrogen oxide in which tungsten oxide with the number of molecular layers of tungsten oxide (WO3) being five or less is supported on a complex oxide carrier containing titanium oxide. Even when high-temperature denitration is continued, a bonding force with a carrier of WO3 can be properly maintained and volatilization can be suppressed while maintaining a high NOx removal performance. For example, the NOx removal catalyst is particularly suitable for reducing and removing nitrogen oxide contained in high-temperature gas discharged from a thermal power plant and a high-temperature boiler.Type: ApplicationFiled: July 16, 2014Publication date: November 6, 2014Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventors: Katsumi Nochi, Toshinobu Yasutake, Masanao Yonemura
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Publication number: 20140316018Abstract: An object of the present invention is to provide titanium oxide granules that have a novel structure and have a characteristic of highly efficient decomposing capability, and a method of decomposing plastic and organic waste by using the granules. The present invention has been completed based on the finding that a method of decomposing plastic waste by using titanium oxide granules having a transition metal and/or a transition metal oxide, in particular copper, supported thereon enables decomposition of plastic waste at extremely high efficiency in a low-temperature region for a long period of time as compared to methods of decomposing plastic waste by using the related-art titanium oxide granules.Type: ApplicationFiled: December 14, 2012Publication date: October 23, 2014Inventors: Hiromitsu Shimizu, Itsushi Kashimoto
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Patent number: 8865615Abstract: Ammonia oxidation catalyst being superior in heat resistance and capable of suppressing by-production of N2O and leakage of ammonia. The ammonia oxidation catalyst (AMOX) removes surplus ammonia, in selectively reducing nitrogen oxides by adding urea or ammonia and using a selective catalytic reduction (SCR) catalyst, into exhaust gas, wherein the ammonia oxidation catalyst is made by coating at least two catalyst layers having a catalyst layer (lower layer) including a catalyst supported a noble metal element on a composite oxide (A) having titania and silica as main components, and a catalyst layer (upper layer) including a composite oxide (C) consisting of tungsten oxide, ceria, and zirconia, at the surface of an integral structure-type substrate, wherein a composition of the composite oxide (C) is tungsten oxide: 1 to 50% by weight, ceria: 1 to 60% by weight, and zirconia: 30 to 90% by weight.Type: GrantFiled: November 17, 2011Date of Patent: October 21, 2014Assignee: N.E. Chemcat CorporationInventors: Tomoaki Ito, Toshinori Okajima, Makoto Nagata
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Patent number: 8852518Abstract: The present invention is to provide a catalyst for removing nitrogen oxides which is capable of keeping sufficient denitrification performance, i.e., a high removal rate of nitrogen oxides in exhaust gas having a high NO2 content especially under conditions where the ratio of NO2/NO in exhaust gas is 1 or higher, a catalyst molded product therefor, and an exhaust gas treating method. The catalyst is designed for removing nitrogen oxides, which is used to denitrify exhaust gas containing nitrogen oxides having a high NO2 content, which comprises: at least one kind of oxide selected from the group consisting of copper oxides, chromium oxides, and iron oxides as a component for reducing NO2 to NO; and which further comprises: at least one kind of titanium oxide; at least one kind of tungsten oxide; and at least one kind of vanadium oxide as components for reducing NO to N2.Type: GrantFiled: May 8, 2008Date of Patent: October 7, 2014Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Shigeru Nojima, Kozo Iida, Yoshiaki Obayashi, Masashi Kiyosawa, Masanori Demoto
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Publication number: 20140275685Abstract: A layered multimetallic mixed oxide (LMMO) is characterized by one or more diffraction peaks at 5<2?<15, preferably between 10<2?<15. The catalysts can be represented by the general formula: M1M2M3O? wherein M1 is selected from the group of Ag, Au, Zn, Sn, Rh, Pd, Pt, Cu, Ni, Fe, Co, an alkaline metal, an alkaline earth metal, a rare earth metal, or mixtures thereof. M2 is selected from the group of Ti, Hf, Zr, Sn, Bi, Sb, V, Nb, Ta and P, or mixtures thereof. M3 is selected from the group of Mo, W and Cr, or mixtures thereof. ? depends on the amount and oxidation state or valence of the other components, also it depends on the starting materials, preparation method and the activation process, and where the catalyst exhibits at least one X-ray diffraction peak between 5<2?<15.Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Inventors: Jaime SANCHEZ VALENTE, Enelio TORRES GARCIA, Hector ARMENDARIZ HERRERA, Maria de Lourdes Alejandra GUZMAN CASTILLO, Andrea RODRIGUEZ HERNANDEZ, Roberto QUINTANA SOLORZANO, Maiby VALLE ORTA, Jose Manuel LOPEZ NIETO
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Patent number: 8815194Abstract: A NOx removal catalyst for high-temperature flue gas according to the present invention is a NOx removal catalyst for high-temperature flue gas that contains nitrogen oxide in which tungsten oxide with the number of molecular layers of tungsten oxide (WO3) being five or less is supported on a complex oxide carrier containing titanium oxide. Even when high-temperature denitration is continued, a bonding force with a carrier of WO3 can be properly maintained and volatilization can be suppressed while maintaining a high NOx removal performance. For example, the NOx removal catalyst is particularly suitable for reducing and removing nitrogen oxide contained in high-temperature gas discharged from a thermal power plant and a high-temperature boiler.Type: GrantFiled: October 6, 2009Date of Patent: August 26, 2014Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Katsumi Nochi, Toshinobu Yasutake, Masanao Yonemura
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Publication number: 20140235893Abstract: The invention relates to the development of a catalyst for selectively producing acetic acid from a gaseous feedstock of ethane, ethylene or mixtures thereof and oxygen at a low temperature. Said gaseous feedstock is brought together with a catalyst containing the oxides of Mo, V and Nb and nano metallic Pd optionally together with a hetero-poly acid and/or Sb and Ca. The present catalytic system provides both higher selectivity and yield of acetic with minimal production of side products of ethylene and CO.Type: ApplicationFiled: February 21, 2013Publication date: August 21, 2014Applicants: KING ABDULAZIZ CITY FOR SCIENCE AND TECHNOLOGY, KING SAUD UNIVERSITYInventors: Yousef S. Al-Zeghayer, Moustafa A. Soliman, Sulaiman Al-Mayman, Abdulrhman S. Al-Awadi
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Publication number: 20140212350Abstract: A catalyst article for treating an emission gas is provided comprising (a) a first catalyst layer having a plurality of consecutive sub-layers, wherein each sub-layer includes vanadium on a first refractory metal oxide support selected from alumina, titania, zirconia, ceria, silica, and mixtures of these; (b) a second catalyst layer comprising one or more noble metals disposed on a second refractory metal oxide support; and (c) a substrate, wherein the first and second catalyst layers are on and/or within the substrate.Type: ApplicationFiled: January 28, 2014Publication date: July 31, 2014Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANYInventors: PAUL JOSEPH ANDERSEN, KEVIN DOURA
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Publication number: 20140206527Abstract: An object of the present invention is to provide a catalyst for glycerin dehydration reaction for producing unsaturated aldehyde and unsaturated carboxylic acid at higher yield by a dehydration reaction of glycerin, and that can reduce a decrease in time of the conversion ratio of glycerin and the yields of unsaturated aldehyde and of unsaturated carboxylic acid. Another object of the present invention is to provide a catalyst for glycerin dehydration reaction that can produce acrolein and acrylic acid at higher yield by the dehydration reaction of glycerin, and the catalyst has a longer life. Still another object of the present invention is to provide a method for preparing the catalysts above.Type: ApplicationFiled: July 30, 2012Publication date: July 24, 2014Applicant: NIPPON KAYAKU KABUSHIKI KAISHAInventors: Kimito Okumura, Yasushi Kobayashi, Ryota Hiraoka, Jean-Luc Dubois
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Patent number: 8772195Abstract: To produce a silica-supported catalyst having an excellent yield of a target product and excellent catalyst attrition resistance. A method for producing a silica-supported catalyst comprising Mo, V, Nb, and a component X (Sb and/or Te) to be used in a vapor phase catalytic oxidation or ammoxidation of propane, comprising the steps of: (I) preparing a raw material mixture solution by mixing Mo, V, Nb, component X, a silica sol, and water; (II) obtaining a dry powder by drying the raw material mixture solution; and (III) obtaining a silica-supported catalyst by calcining the dry powder, wherein the silica sol contains 10 to 270 wt ppm of nitrate ions based on SiO2.Type: GrantFiled: January 21, 2010Date of Patent: July 8, 2014Assignee: Asahi Kasei Chemicals CorporationInventors: Yusuke Ishii, Takaaki Kato
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Publication number: 20140187412Abstract: In one embodiment, an aqueous dispersion liquid contains at least one particles selected from tungsten oxide particles and tungsten oxide composite particles. A mean primary particle diameter (D50) of the particles is in the range of 1 nm to 400 nm. In the aqueous dispersion liquid, concentration of the particles is in the range of 0.1 mass % to 40 mass %, and pH is in the range of 1.5 to 6.5. The aqueous dispersion liquid excels in dispersibility of particles and capable of maintaining good liquidity for a long period.Type: ApplicationFiled: March 6, 2014Publication date: July 3, 2014Applicants: TOSHIBA MATERIALS CO., LTD., KABUSHIKI KAISHA TOSHIBAInventors: Kayo NAKANO, Akira SATO, Yasuhiro SHIRAKAWA, Keiichi FUSE, Shinya KASAMATSU, Akito SASAKI
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Publication number: 20140171298Abstract: A hydroprocessing co-catalyst composition may comprise in an embodiment a first component comprising co-catalyst particles and a liquid carrier, and a second component comprising a dispersant and a dispersant diluent. The co-catalyst particles may be in the micron size range, and the dispersant may promote dispersion of the co-catalyst particles in materials such as the liquid carrier, the dispersant diluent, and combinations thereof. Methods of introducing a hydroprocessing co-catalyst composition into a hydroprocessing system are also disclosed.Type: ApplicationFiled: December 14, 2012Publication date: June 19, 2014Inventors: Julie Chabot, Bo Kou, Alexander Kuperman