Titanium Containing Patents (Class 502/309)
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Patent number: 7771702Abstract: The invention provides active, affordable, durable, and sulfur-tolerant catalysts and related precursors and processes useful in hydrogen production. The catalysts have a wide applicability. For example, in one embodiment, the invention provides sulfur-tolerant catalysts which, when used in a catalytic fuel processor, will facilitate sufficient hydrogen generation within 30 seconds or so of automobile start-up to generate around 50 kW of fuel cell power. Catalysts of the instant invention are made by reducing a catalyst precursor comprising a support phase impregnated with one or more elemental transition metals, wherein: (a) the support phase is formed by dispersion of a monolayer on the surface of a high surface area alumina support; and (b) the monolayer comprises XOnYO2, where (1) XOn is a redox active metal oxide and n is either 1.5, 2, or 2.5 depending on the oxidation number of X, and (2) YO2 is a redox inactive metal oxide. Ni—V2O5—ZrO2/Al2O3 catalysts of the instant invention are preferred.Type: GrantFiled: February 20, 2003Date of Patent: August 10, 2010Assignees: University of Iowa Research Foundation, Honda Motor Co., Ltd.Inventors: Darrell P. Eyman, Christopher Brooks
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Patent number: 7759281Abstract: There is disclosed a photocatalyst which comprises a substrate having a photocatalytic function and metallic nanocolloid particles that are supported on the substrate by the use of a metallic nanocolloid liquid substantially free from a protective colloid formation agent. A highly active photocatalyst containing metallic ultrafine particles is provided by bringing a substrate such as fine particles having a photocatalytic function into contact with a metallic nanocolloid liquid which is substantially free from a protective colloid formation agent, and which has favorable dispersion stability even if containing metallic nanocolloid particles in a relatively high concentration. Accordingly the photocatalyst containing metallic ultrafine particles can be produced at a low cost without being restricted on the place of production.Type: GrantFiled: January 18, 2005Date of Patent: July 20, 2010Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Masamichi Kezuka, Kiyoshi Miyashita, Ryohei Ogawa, Akihiro Hishinuma
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Patent number: 7759530Abstract: The invention relates to a method for hydrogenation of an organic compound comprising at least one carbonyl group, whereby the organic compound is brought into contact with a moulded body in the presence of hydrogen. Said body may be produced by a method in which (i) an oxidic material is prepared, comprising copper oxide, aluminum oxide, and at least one oxide of lanthanum, tungsten, molybdenum, titanium, or zirconium, followed by (ii) addition of powdered metallic copper, copper platelets, powdered cement, graphite, mixtures or a mixture thereof with graphite to the oxidic material and (iii) moulding the mixture from (ii) to give a moulded body, characterised in that the moulded body is in the form of catalyst tablets or catalyst extrudates with a diameter d and/or height h<2.5 mm, catalyst beads with a diameter d<2.5 mm or catalyst honeycomb with a cell diameter rz<2.5 mm.Type: GrantFiled: July 7, 2005Date of Patent: July 20, 2010Assignee: BASF AktiengesellschaftInventors: Christophe Houssin, Henrik Junicke, Andrea Haunert
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Patent number: 7759277Abstract: The present invention provides a catalyst having high activity and excellent stability, a process for preparation of the catalyst, a membrane electrode assembly, and a fuel cell. The catalyst of the present invention comprises an electronically conductive support and catalyst fine particles. The catalyst fine particles are supported on the support and are represented by the formula (1): PtuRuxGeyTz (1). In the formula, u, x, y and z mean 30 to 60 atm %, 20 to 50 atm %, 0.5 to 20 atm % and 0.5 to 40 atm %, respectively. When the element represented by T is Al, Si, Ni, W, Mo, V or C, the content of the T-element's atoms connected with oxygen bonds is not more than four times as large as that of the T-element's atoms connected with metal bonds on the basis of X-ray photoelectron spectrum (XPS) analysis.Type: GrantFiled: March 19, 2009Date of Patent: July 20, 2010Assignee: Kabushiki Kaisha ToshibaInventors: Taishi Fukazawa, Wu Mei, Yoshihiko Nakano, Tsuyoshi Kobayashi, Itsuko Mizutani, Hiroyasu Sumino
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Patent number: 7754647Abstract: The present invention provides a process for preparing a supported catalyst (catalyst C) having a support (support S) selected from among oxides, phosphates, silicates, carbides, borides and nitrides of main group elements and elements of transition groups VI and II and mixtures of the abovementioned compounds and an active component (activator A) comprising one or more compounds containing one or more elements of transition groups V, VI and VII customary for the catalysis of metathesis reactions.Type: GrantFiled: April 4, 2008Date of Patent: July 13, 2010Assignee: Basf AktiengesellschaftInventors: Markus Schubert, Michael Hesse, Juergen Stephan, Volker Boehm, Andreas Brodhagen, Frank Poplow, Martina Sinner-Lang, Uwe Diehlmann, Gerhard Cox, Jochen Pfeifer
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Patent number: 7749938Abstract: A catalyst for nitrogen oxide removal, which catalytically reduces nitrogen oxides in an exhaust gas in the presence of ammonia, comprises: a first component comprising an oxide of titanium, an oxide of tungsten, and an oxide of vanadium; and a second component comprising an oxide of manganese, or an oxide of manganese and an oxide of copper.Type: GrantFiled: September 19, 2007Date of Patent: July 6, 2010Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Yoshiaki Obayashi, Akira Hattori, Masanori Demoto
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Patent number: 7749937Abstract: An unsupported catalyst composition which comprises one or more Group VIb metals, one or more Group VIII metals, and a refractory oxide material which comprises 50 wt % or more titania, on oxide basis, which is prepared by precipitation techniques, finds use in the hydroprocessing of hydrocarbonaceous feedstocks.Type: GrantFiled: June 2, 2009Date of Patent: July 6, 2010Assignee: Shell Oil CompanyInventors: Laszlo Domokos, Hermanus Jongkind, Willem Hartman Jurriaan Stork, Johanna Maria Helena Van Den Tol-Kershof
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Publication number: 20100160153Abstract: Titanium oxide (usually titanium dioxide) catalyst support particles are doped for electronic conductivity and formed with surface area-enhancing pores for use, for example, in electro-catalyzed electrodes on proton exchange membrane electrodes in hydrogen/oxygen fuel cells. Suitable compounds of titanium and a dopant are dispersed with pore-forming particles in a liquid medium. The compounds are deposited as a precipitate or sol on the pore-forming particles and heated to transform the deposit into crystals of dopant-containing titanium dioxide.Type: ApplicationFiled: March 3, 2010Publication date: June 24, 2010Applicants: GM GLOBAL TECHNOLOGY OPERATIONS, INC., Administrators Of The Tulane Education FundInventors: Mei Cai, Yunfeng Lu, Zhiwang Wu, Lee Lizhong Feng, Martin S. Ruthkosky, John T. Johnson, Frederick T. Wagner
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Patent number: 7740817Abstract: A catalyst which efficiently removes particulate matter, SOF, sulfate, and SOOT and the like from the exhaust gas from such an internal combustion engine as a diesel engine without inducing a rise in the back pressure of the engine is provided. The catalyst for the purification of the exhaust gas of an internal combustion engine is formed by using an open flow honeycomb containing in the channel walls thereof such pores as possess an average diameter in the range of 10-40 ?m.Type: GrantFiled: February 14, 2003Date of Patent: June 22, 2010Assignees: ICT Co., Ltd., International Catalyst Technology, Inc.Inventors: Takeshi Matsumoto, Takao Kobayashi, Takuji Nakane, Takahiro Uno, Makoto Horiuchi
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Patent number: 7737080Abstract: The invention relates to a structure, comprising a substrate supporting a layer with a photocatalytic and anti-soiling property on at least part of the surface thereof, said layer being based on titanium dioxide (TiO2) which is at least partially crystallized in the anatase form thereof. Said structure is characterised in comprising a sublayer (SC) directly under at least one TiO2 layer, said sublayer having a crystallographic structure which provides assistance to crystallization by heteroepitaxial growth in the anatase form of the TiO2-based upper layer, the photocatalytic property being obtained without any heating step.Type: GrantFiled: October 22, 2004Date of Patent: June 15, 2010Assignee: Saint-Gobain Glass FranceInventors: Laurent Labrousse, Nicolas Nadaud
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Publication number: 20100121007Abstract: The invention provides a catalyst for producing acrylic acid at high yield for a long time, in a method for producing acrylic acid by catalytic gas phase oxidation of propane and/or acrolein in the presence of molecular oxygen or a molecular oxygen-containing gas. This catalyst comprises a complex oxide containing molybdenum, vanadium and X component (here the X component is at least one element selected from antimony, niobium and tin) as the essential components, and is characterized in that its main peak as measured by X-ray diffractiometry using K? ray of Cu, d=4.00±0.1 angstrom, and in that the particle size of the X component in the catalyst does not exceed 20 ?m.Type: ApplicationFiled: May 28, 2008Publication date: May 13, 2010Inventors: Naohiro Fukumoto, Toshiya Nishiguchi
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Publication number: 20100121100Abstract: Disclosed is a catalyst. The catalyst comprises palladium, gold, and a support comprising titanium dioxide and tungsten trioxide. The support preferably comprises from 75 wt % to 99 wt % of titanium dioxide and from 1 wt % to 25 wt % of tungsten trioxide. A method for preparing the catalyst is also disclosed. The method comprises impregnating the support with a palladium compound and a gold compound, calcining the impregnated support, and then reducing the calcined support. Further disclosed is a method for preparing vinyl acetate with the catalyst. The catalyst exhibits improved catalytic activity and selectivity.Type: ApplicationFiled: November 12, 2008Publication date: May 13, 2010Inventor: Daniel Travis Shay
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Patent number: 7713908Abstract: A method of producing a porous composite metal oxide comprising the steps of: dispersing first metal oxide powder, which is an aggregate of primary particles each with a diameter of not larger than 50 nm, in a dispersion medium by use of microbeads each with a diameter of not larger than 150 ?m, thus obtaining first metal oxide particles, which are 1 nm to 50 nm in average particle diameter, and not less than 80% by mass of which are not larger than 75 nm in diameter; dispersing and mixing up, in a dispersion medium, the first metal oxide particles and second metal oxide powder, which is an aggregate of primary particles each with a diameter of not larger than 50 nm, and which is not larger than 200 nm in average particle diameter, thus obtaining a homogeneously-dispersed solution in which the first metal oxide particles and second metal oxide particles are homogeneously dispersed; and drying the homogeneously-dispersed solution, thus obtaining a porous composite metal oxide.Type: GrantFiled: August 29, 2005Date of Patent: May 11, 2010Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Toshio Yamamoto, Akihiko Suda, Akira Morikawa, Kae Yamamura, Hirotaka Yonekura
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Publication number: 20100099552Abstract: A nanocomposite particle, its use as a catalyst, and a method of making it are disclosed. The nanocomposite particle comprises titanium dioxide nanoparticles, metal oxide nanoparticles, and a surface stabilizer. The metal oxide nanoparticles are formed hydrothermally in the presence of the titanium dioxide nanoparticles. The nanocomposite particle is an effective catalyst support, particularly for DeNox catalyst applications.Type: ApplicationFiled: August 24, 2006Publication date: April 22, 2010Inventors: Guoyi Fu, Steven M. Augustine
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Patent number: 7700516Abstract: A method of preparing a catalyst comprising contacting a support with a trivalent titanium compound and a chromium-containing compound. A catalyst composition comprising a support, chromium, and titanium, wherein the titanium is derived from TiCl3, Ti2(SO4)3, Ti(OAc)3, Ti(+3) oxylate, Ti(NO3)3, Ti(+3) lactate or combinations thereof.Type: GrantFiled: September 26, 2007Date of Patent: April 20, 2010Assignee: Chevron Phillips Chemical Company LPInventors: Max P. McDaniel, Kathy S. Collins
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Patent number: 7696387Abstract: The present invention relates to a novel method for preparing a catalyst for partial oxidation of methylbenzenes, comprising, (a) a step of preparing a solution or slurry of the compounds comprising tungsten; (b) a step of supporting the solution or slurry obtained in the step (a) on inorganic carrier; (c) a step of drying the catalyst obtained in the step (b); and (d) a step of calcining the dried catalyst obtained in the step (c), characterized in that the ratio of the pore volume of inorganic carrier and the volume of the solution or slurry in the step (b) is 1:0.9˜1.1, and the catalyst provides superior aromatic aldehydes selectivity to those prepared by the conventional impregnation or heat evaporation method over a wide range of conversion rate.Type: GrantFiled: May 17, 2006Date of Patent: April 13, 2010Assignee: LG Chem, Ltd.Inventors: Won Ho Lee, Dong Il Lee, Jong Hyun Chae, Hyun Kyung Yoon
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Patent number: 7695611Abstract: Compositions for reduction of NOx emissions generated during catalytic cracking process, preferably, a fluid catalytic cracking process, are disclosed. The compositions comprise (i) an acidic metal oxide containing substantially no zeolite, (ii) an alkali metal, alkaline earth metal, and mixtures thereof, (iii) an oxygen storage component, (iv) palladium and (v) a noble metal component, preferably platinum, rhodium or iridium, and mixtures thereof. Preferably, the compositions are used as separate additives particles circulated along with the circulating FCC catalyst inventory. Reduced content of NOx in an effluent off gas of a full or complete combustion FCC regenerator are accomplished while simultaneously promoting the combustion of CO.Type: GrantFiled: October 31, 2005Date of Patent: April 13, 2010Assignee: W. R. Grace & Co.—Conn.Inventors: George Yaluris, John Rudesill
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Patent number: 7691955Abstract: The present invention relates to the removal of hydrocarbon residues from a catalyst and more specifically the air activation of a catalyst containing hydrocarbon residues. It also relates to extruded pipe and utility conduit resins comprising polyethylene, household/industrial chemicals container resins, and to a polyethylene resin particularly suitable for large parts by blow molding and sheet extrusion procedures, wherein the resin is made by a process using an activated chromium and titanium-based catalyst.Type: GrantFiled: May 1, 2008Date of Patent: April 6, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Scott T. Roger, Thomas W. Towles, Anthony N. Speca, Stanley J. Katzen
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Publication number: 20100080737Abstract: Provided are an exhaust gas treatment catalyst capable of reducing ammonia leakage rate while keeping a sufficient NOx removal efficiency, said catalyst comprising a coating layer and a catalyst base material, wherein said coating layer has a decreased thickness relative to that of a catalyst base material; and an exhaust gas treatment system using the same. In the exhaust gas treatment catalyst for catalytically removing nitrogen oxides from an exhaust gas by using ammonia as a reducing agent and simultaneously decomposing and removing unreacted ammonia, a coating layer comprising platinum supported on titania is formed on a surface of a porous catalyst base material comprising titania and at least one compound selected from oxides of vanadium (V), oxides of tungsten (W) and oxides of molybdenum (Mo).Type: ApplicationFiled: August 7, 2008Publication date: April 1, 2010Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventors: Katsumi Nochi, Yoshiaki Obayashi, Akira Hattori
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Patent number: 7687428Abstract: A method of preparing carbon-loaded, gold-based nanoparticle catalysts useful as anode catalysts for the electrocatalytic methanol oxidation reaction (MOR) as well as the oxygen reduction reaction (ORR). AumPtnM100-m-n catalysts may be prepared by either a two-phase protocol or by a thermal decomposition/reduction protocol. The prepared nanoparticles having different bimetallic ratios are assembled on carbon black support materials and activated by thermal treatment. This approach provides good control of nanoparticle size, composition and/or surface properties. Electrocatalytic MOR activities of the prepared and activated AuPt nanoparticle provided in accordance with the methods of the invention are present in both acidic and alkaline electrolytes.Type: GrantFiled: March 29, 2006Date of Patent: March 30, 2010Assignee: The Research Foundation of the State University of New YorkInventors: Chuan-Jian Zhong, Jin Luo, Nancy N. Kariuki, Linyang Wang, Peter Njoki, Derrick Mott
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Publication number: 20100069585Abstract: The present invention provides a process for preparing a supported chromium-based catalyst for the production of polyethylene comprising the steps of a) providing a silica-based support having a specific surface area of at least 250 m2/g and of less than 400 m2/g and comprising a chromium compound deposited thereon, the ratio of the specific surface area of the support to chromium content being at least 50000 m2/g Cr; b) dehydrating the product of step a); and c) titanating the product of step b) in an atmosphere of dry and inert gas containing at least one vaporised titanium compound of the general formula selected from RnTi(OR?)m and (RO)nTi(OR?)m, wherein R and R? are the same or different hydrocarbyl groups containing from 1 to 12 carbon atoms, and wherein n is 0 to 3, m is 1 to 4 and m+n equals 4, to form a titanated chromium-based catalyst having a ratio of specific surface area of the support to titanium content of the titanated catalyst ranging from 5000 to 20000 m2/g Ti.Type: ApplicationFiled: April 13, 2007Publication date: March 18, 2010Applicant: Total Petrochemicals Research FeluyInventors: Philippe Bodart, Guy Debras, Mieke Dams
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Publication number: 20100069231Abstract: The present invention provides a catalyst base material and a catalyst which have high strength, high porosity or high activity and methods of producing the catalyst base material and catalyst. The present invention relates to a method of producing a catalyst base material, the method comprising dispersing or dissolving a hydrophilic polymer coagulant as a first component, a water-soluble thickener as a second component, a colloidal inorganic binder as a third component and an inorganic fiber as a fourth component in water to form a catalytic slurry or paste, supporting the catalytic slurry or paste on a net-like substrate such that the meshes of the net-like substrate are filled up with the slurry or paste, by drying and/or calcinating the substrate.Type: ApplicationFiled: August 28, 2006Publication date: March 18, 2010Inventors: Yasuyoshi Kato, Naomi Imada
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Patent number: 7670985Abstract: The invention provides an activated carbon supported cobalt based catalyst for directly converting of synthesis gas to mixed linear alpha-alcohols and paraffins, comprising cobalt, an activated carbon carrier, a metal promoter which is at least one selected from the group consisting of a zirconium component, a lanthanum component, a cerium component, a chromium component, a vanadium component, a titanium component, a manganese component, a rhenium component, a potassium component, a ruthenium component, a magnesium component and a mixture thereof, wherein the cobalt and the promoter are deposited on the activated carbon carrier or substantially uniformly dispersed therein, and the metal promoter is present in the form of a metal, an oxide or a combination thereof.Type: GrantFiled: August 9, 2007Date of Patent: March 2, 2010Assignees: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, CNOOC New Energy Investment Co., Ltd.Inventors: Yunjie Ding, Hejun Zhu, Tao Wang, Guiping Jiao, Yuan Lv
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Publication number: 20100038285Abstract: The present invention relates to the novel catalytic composition having a high specific activity in reactions involving hydroprocessing of light and intermediate petroleum fractions, and preferably in hydrodesulphurization and hydrodenitrogenation reactions. The inventive catalyst contains at least one element of a non-noble metal from group VIII, at least one element from group VIB and, optionally, a group one element of the VA group, which are deposited on a novel catalytic support comprising of an inorganic metal oxide from group IVB, consisting of an (ID) one-dimensional nanostructured material having nanofibers and/or nanotube morphology with high specific surface area of between 10 and 500 m2/g.Type: ApplicationFiled: October 10, 2003Publication date: February 18, 2010Inventors: José Antonio Toledo Antonio, José Escobar Aguilar, Maria Antonia Cortés Jacome, Maria de Lourdes Mosqueira Mondragon, Vitor Pérez Moreno, Calos Angeles Chávez, Esteban López Salinas, Marcelo Lozada y Cassou
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Patent number: 7655593Abstract: A method of manufacturing a cobalt catalyst is described, which comprises the steps of forming an aqueous solution of a cobalt amine complex, oxidising said solution such that the concentration of Co(III) in the oxidised solution is greater than the concentration of Co(III) in the un-oxidized solution, and then decomposing the cobalt amine complex by heating the solution to a temperature between 80 and 110° C. for sufficient time to allow an insoluble cobalt compound to precipitate out of the solution. A catalyst intermediate is also described which comprises a cobalt compound, comprising a Co(II)/Co(III) hydrotalcite phase and a CO3O4 cobalt spine) phase, wherein the ratio of cobalt hydrotalcite phase: cobalt spine) phase is less than 0.6:1, said cobalt hydrotalcite phase and said cobalt spine) phase being measured by X-ray diffractometry.Type: GrantFiled: May 10, 2005Date of Patent: February 2, 2010Assignee: Johnson Matthey PLCInventors: Cornelis Martinus Lok, Jill Turner
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Patent number: 7655749Abstract: Methods for synthesizing dimeric or higher polymeric reaction products of nitrogen aromatics comprise contacting a composition comprising the nitrogen aromatic with a catalyst composition. The catalyst is in particulate form and comprises a first metal substrate having a second reduced metal coated on the substrate.Type: GrantFiled: September 19, 2005Date of Patent: February 2, 2010Assignee: GM Global Technology Operations, Inc.Inventors: Andrew M. Mance, Tao Xie, Belabbes Merzougui, Charlene A. Hayden
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Patent number: 7648940Abstract: This invention relates to a catalyst composition of the formula: where Z—O is a support material, where O is oxygen, preferably Z is Si, Ti, Al, Sn, Fe, Ga, Zr, B, Mg, or Cr; each X is, independently, N, O, P or S; each n is, independently, 1 or 2; each R is, independently, an alkyl group, a substituted alkyl group, an aryl group, or a substituted aryl group, provided at least one R group is an aryl or substituted aryl group. This invention also relates to the use of the above catalyst compound with an aluminum alkyl to polymerize olefins and other monomers.Type: GrantFiled: October 30, 2006Date of Patent: January 19, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Matthew W. Holtcamp, Renuka N. Ganesh
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Patent number: 7645897Abstract: A process for producing a high-performance catalyst for use in a reaction for acrylic acid production from propane or propylene through air oxidation, is provided. A process for producing a metal oxide catalyst having the following composition formula, the process comprising the following steps (1) and (2): MoViAjBkCxOy??Composition formula (wherein A is Te or Sb; B is at least one element selected from the group consisting of Nb, Ta, and Ti; C is Si or Ge; i and j each are 0.01-1.5 and j/i is from 0.3 to 1.0; k is 0.001-3.0; x is 0.002-0.Type: GrantFiled: July 13, 2005Date of Patent: January 12, 2010Inventors: Xinlin Tu, Naomasa Furuta, Yuuichi Sumida
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Patent number: 7642214Abstract: An object of the present invention is to provide a highly active catalyst for producing an unsaturated oxygen-containing compound from an alkane and the catalyst comprising Mo, V, Ti and Sb or Te as the indispensable active components. The preferable catalyst is represented by formula (1) or (2) as shown below, Mo1.0VaTibXcYdOe??(1) Mo1.0VaTibXcYdZfOe??(2) wherein X represents Sb or Te; Y represents Nb, W or Zr; Z represents Li, Na, K, Rb, Cs, Mg, Ca or Sr; a, b, c, d, e and f represent atomic ratios of their respective elements, with 0<a<0.7, 0<b<0.3, 0<c<0.7, 0?d<0.3, 0<f<0.1; e is a number determined by oxidation states of the other elements than oxygen.Type: GrantFiled: July 28, 2006Date of Patent: January 5, 2010Assignee: Nippon Kayaku Kabushiki KaishaInventors: Tomoaki Kobayashi, Yoshimasa Seo
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Patent number: 7641875Abstract: A multi-phase catalyst for the simultaneous conversion of oxides of nitrogen, carbon monoxide, and hydrocarbons is provided. A catalyst composition comprising the multi-phase catalyst and methods of making the catalyst composition are also provided. The multi-phase catalyst may be represented by the general formula of CeyLn1-xAx+sMOZ, wherein Ln is a mixture of elements originally in the form of single-phase mixed lanthanides collected from natural ores, a single lanthanide, or a mixture of lanthanides; A is an element selected from a group consisting of Mg, Ca, Sr, Ba, Li, Na, K, Cs, Rb, or any combination thereof; and M is an element selected from the group consisting of Fe, Mn, Cr, Ni, Co, Cu, V, Zr, Pt, Pd, Rh, Ru, Ag, Au, Al, Ga, Mo, W, Ti, or any combination thereof; x is a number defined by 0?x<1.0; y is a number defined by 0?y<10; s is a number defined by 0?s<10; where s=0 only when y>0 and y=0 only when s>0.Type: GrantFiled: November 3, 2008Date of Patent: January 5, 2010Assignee: Catalytic Solutions, Inc.Inventor: Stephen J. Golden
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Publication number: 20090325787Abstract: A nanocomposite particle, its use as a catalyst, and a method of making it are disclosed. The nanocomposite particle comprises titanium dioxide nanoparticles, metal oxide nanoparticles, and a surface stabilizer. The metal oxide nanoparticles are formed hydrothermally in the presence of the titanium dioxide nanoparticles. The nanocomposite particle is an effective catalyst support, particularly for DeNOx catalyst applications.Type: ApplicationFiled: July 14, 2009Publication date: December 31, 2009Inventors: Guoyi Fu, Steven M. Augustine
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Publication number: 20090325788Abstract: The present invention is related to single and/or multiple-wall carbon nanotubes which may contain interstitial metals obtainable by a preparation process, comprising a catalytic step using a catalytic system, said catalytic system comprising a catalyst and a support, said support comprising hydroxides and/or carbonates or mixtures thereof with or without metal oxides. The present invention is also related to carbon fibers obtainable by said preparation process. The present invention also pertains in particular to said catalytic system and to said preparation process. Another aspect concerns the use of the nanotubes and of the catalytic system according to the invention.Type: ApplicationFiled: July 20, 2009Publication date: December 31, 2009Applicant: FACULTES UNIVERSITAIRES NOTRE-DAME DE LA PAIXInventors: Janos B. Nagy, Narasimaiah Nagaraju, Isabelle Willems, Antonio Fonseca
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Patent number: 7638459Abstract: A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.Type: GrantFiled: May 25, 2005Date of Patent: December 29, 2009Assignee: UOP LLCInventors: Dean E. Rende, James E. Rekoske, Jeffery C. Bricker, Jeffrey L. Boike, Masao Takayama, Kouji Hara, Nobuyuki Aoi
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Publication number: 20090311155Abstract: A catalyst is provided having higher mercury oxidation performance than a conventional catalyst without increasing catalyst quantity or enhancing SO2 oxidation performance and constitutes an oxidation catalyst for metal mercury, which contains a molybdenum and vanadium complex oxide, for example, MoV2O8, as a main component having a catalytic activity and is formed by placing the molybdenum and vanadium complex oxide in layers only on the surface of a plate-like or honeycomb-like porous carrier. The porous carrier contains Ti and W and has a function of an NOx removal catalyst as a whole.Type: ApplicationFiled: September 21, 2007Publication date: December 17, 2009Applicant: BABCOCK-HITACHI KABUSHIKI KAISHAInventors: Keiichiro Kai, Yasuyoshi Kato
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Publication number: 20090305874Abstract: The invention relates to a process for coating ceramic honeycomb bodies with a coating suspension containing, in a carrier liquid, catalyst components as solids and/or in dissolved form. The honeycomb bodies have parallel flow channels running through them. The walls of the flow channels generally have an open pore structure. To coat the channel walls and in particular also the interior surfaces of the pores with the coating suspension, it is proposed that the flow channels be temporarily alternately closed and the coating suspension be forced through the open pore structure of the channel walls. The coating is subsequently dried and calcined. To close the flow channels, it is possible to use thermally or chemically decomposable or soluble compositions which are decomposed or dissolved either during calcination or by means of a subsequent chemical treatment. The coated honeycomb bodies are preferably used for the purification of exhaust gases from automobiles.Type: ApplicationFiled: November 22, 2006Publication date: December 10, 2009Applicant: UMICORE AG & CO. KGInventors: Marcus Pfeifer, Paul Spurk, Markus Koegel, Egbert S.J. Lox, Thomas Kreuzer
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Patent number: 7628968Abstract: The present invention is directed to high activity titanium oxide DeNOx catalysts. In preferred embodinents, by depositing vanadium oxide on a titania supported metal oxide such as tungsten oxide, an improved catalyst may be generated. This catalyst may be used in the treatment of exhaust from sources such as automobiles and industrial plants.Type: GrantFiled: May 23, 2008Date of Patent: December 8, 2009Assignee: Millenium Inorganic Chemicals, Inc.Inventors: Steven M Augustine, Guoyi Fu
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Publication number: 20090270518Abstract: The present invention provides a catalyst carrier, catalyst and catalyst precursor comprising a refractory metal oxide and support structure comprising a wire gauze having between 1002 to 6002 openings per inch2, and having a wire thickness in the range of 20 micrometer to 110 micrometer. The volume of the support structure is less than 50% of the volume of the catalyst carrier and at least 70% of said openings are filled with the refractory metal oxide.Type: ApplicationFiled: November 25, 2008Publication date: October 29, 2009Inventors: Gerrit Leendert Bezemer, Hans Peter Alexander Calis, Ronald Jan Dogterom
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Patent number: 7608560Abstract: A fuel cell catalyst comprising platinum, titanium and tungsten. In one or more embodiments, the concentration of platinum is less than 60 atomic percent, and/or the concentration of titanium is at least 20 atomic percent, and/or the concentration of tungsten is at least 25 atomic percent.Type: GrantFiled: June 7, 2004Date of Patent: October 27, 2009Assignees: Symyx Technologies, Inc., Honda Giken Kogyo Kabushiki KaishaInventors: Qun Fan, Peter Strasser, Alexander Gorer, Martin Devenney, Ting He, Hiroyuki Oyanagi, Daniel M. Giaquinta, Kenta Urata, Hiroichi Fukuda, Konstantinos Chondroudis, Keith James Cendak
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Patent number: 7598204Abstract: A reagent suitable for use as a catalyst comprises a first metal species substrate having a second reduced metal species coated thereon, the second reduced metal species being less electropositive than the first metal. Methods of manufacture are also provided.Type: GrantFiled: September 19, 2005Date of Patent: October 6, 2009Assignee: General Motors CorporationInventors: Andrew M. Mance, Tao Xie, Belabbes Merzougui
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Patent number: 7598203Abstract: Provided are a hydrogenation catalyst for hydrocarbon oil, having markedly improved desulfurization activity, denitrogenation activity, and dearomatization activity; a carrier for the catalyst and its production; and a method of hydrogenation of hydrocarbon oil with the catalyst.Type: GrantFiled: January 17, 2007Date of Patent: October 6, 2009Assignee: Idemitsu Kosan Co., Ltd.Inventors: Narinobu Kagami, Ryuichiro Iwamoto
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Publication number: 20090246111Abstract: The invention realizes a catalyst which is hardly deteriorated even when volatile catalyst-poisoning compounds such as P and As are accumulated and which can reduce the rate of oxidation of SO2 to a level as low as a fraction of that of the catalyst in the prior art, and provides an exhaust gas purification catalyst which can maintain a high activity and a low rate of oxidation of SO2 for a long time even with any diversified coal, a method of producing the same, and an exhaust gas purification method using the same. Disclosed is an exhaust gas purification catalyst having a composition comprising oxides of titanium (Ti), molybdenum (Mo) and/or tungsten (W), vanadium (V) and bismuth (Bi), wherein the atomic ratio of Ti:(Mo and/or W):V is 75 to 98.9:1 to 0.1 to 10 and the atomic ratio of Bi/(Mo and/or W) is 0.1 to 0.8.Type: ApplicationFiled: January 30, 2008Publication date: October 1, 2009Applicant: BABACOCK-HITACHI KABUSHIKI KAISHAInventors: Yasuyoshi Kato, Keiichiro Kai, Naomi Imada
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Publication number: 20090247401Abstract: A methanol oxidation catalyst comprises a material of composition: PtxMzTau in which Pt is platinum, Ta is tantalum, M is an element includes at least one selected from the group consisting of V (vanadium), W (tungsten), Ni (nickel) and Mo (molybdenum), x is 40 to 98 at. %, z is 1.5 to 55 at. %, and u is 0.5 to 40 at. %. To maximize catalytic activity the mater al is preferably in the form of nanoparticles. The values of x, z and u are selected such that the element exhibits X-ray photoelectron spectroscopy peaks derived from an oxygen bond and a metal bond in which a peak area derived from the oxygen bond is twice or less of a peak area derived from the metal bond.Type: ApplicationFiled: March 10, 2009Publication date: October 1, 2009Inventors: Wu Mei, Taishi Fukazawa, Itsuko Mizutani, Tsuyoshi Kobayashi, Yoshihiko Nakano, Mina Farag, Shinji Aoki, Yi-Qun Li
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Publication number: 20090239743Abstract: An unsupported catalyst composition which comprises one or more Group VIb metals, one or more Group VIII metals, and a refractory oxide material which comprises 50 wt % or more titania, on oxide basis, which is prepared by precipitation techniques, finds use in the hydroprocessing of hydrocarbonaceous feedstocks.Type: ApplicationFiled: June 2, 2009Publication date: September 24, 2009Inventors: Laszlo DOMOKOS, Hermanus JONGKIND, Willem Hartman Jurriaan STORK, Johanna Maria Helena VANDENTOL-KERSHOF
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Publication number: 20090239742Abstract: The present disclosure relates to nanocrystalline titanium dioxide (TiO2) photocatalysts having nanocrystallites of less than 14 nanometers in diameter, which are substantially defect-free. The TiO2 photocatalysts form porous particles having a very large mass transfer surface area, large cylindrical pores, and low mass transfer resistance. The nanocrystalline TiO2 photocatalysts provide at least 75% of the photocatalytic activity of commercially-available TiO2 crystals having diameters greater than 20 nm. The nanocrystalline TiO2 photocatalysts may be doped with a metal, metal oxide, or non-metal dopant. A process for preparing the nanocrystalline TiO2 photocatalysts is disclosed. The present disclosure also provides methods for using nanocrystalline TiO2 photocatalysts to remove contaminants.Type: ApplicationFiled: May 31, 2007Publication date: September 24, 2009Applicant: CARRIER CORPORATIONInventors: Thomas Henry Vanderspurt, Treese Hugener-Campbell, Stephen O. Hay, Timothy N. Obee
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Patent number: 7592290Abstract: The invention relates to supported catalysts and a process for the production of these catalysts. These supported catalysts may be used in various reactions such as reforming reactions (e.g. steam methane reforming (SMR) reactions and autothermal reforming (ATR) reactions). In one aspect of the invention, the supported catalyst comprises a transition metal oxide; optionally a rare-earth metal oxide; and a transition metal aluminate.Type: GrantFiled: April 7, 2005Date of Patent: September 22, 2009Assignee: Sulzer Metco(Canada) Inc.Inventors: Syed Tajammul Hussain, Eugene Stelmack
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Publication number: 20090232728Abstract: A water gas shift catalyst for use at temperatures above about 450° C. up to about 900° C. or so comprising rhenium deposited on a support, preferably without a precious metal, wherein the support is prepared from a high surface area material, such as a mixed metal oxide, particularly a mixture of zirconia and ceria, to which may be added one or more of a high surface area transitional alumina, an alkali or alkaline earth metal dopant and/or an additional dopant selected from Ga, Nd, Pr, W, Ge, Fe, oxides thereof and mixtures thereof.Type: ApplicationFiled: March 14, 2008Publication date: September 17, 2009Applicant: Sud-Chemie Inc.Inventors: Jon P. Wagner, Michael W. Balakos, Chandra Ratnasamy
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Patent number: 7589044Abstract: A method comprising contacting a donor support with a recipient support to generate a mixture, and heating the mixture to produce a polymerization catalyst, wherein a metal or a metal-containing compound migrates from the donor support to the recipient support. A method comprising contacting a donor support comprising inactive metal species with a recipient support, and mobilizing the inactive metal species from the donor support to form an active metal species on the recipient support.Type: GrantFiled: October 2, 2007Date of Patent: September 15, 2009Assignee: Chevron Phillips Chemical Company LPInventors: Max P. McDaniel, Kathy S. Collins, Elizabeth A. Benham, William B. Beaulieu
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Patent number: 7585812Abstract: A catalyst for use in the Fischer-Tropsch process, and a method to prepare the catalyst is disclosed. The catalyst of the present invention has a higher surface area, more uniform metal distribution, and smaller metal crystallite size than Fischer-Tropsch catalysts of the prior art.Type: GrantFiled: June 20, 2008Date of Patent: September 8, 2009Assignee: Sud-Chemie Inc.Inventors: X. D. Hu, Patrick J. Loi, Robert J. O'Brien
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Patent number: 7576028Abstract: A catalyst body comprising a carrier and a catalyst layer containing an alkali metal and/or an alkaline earth metal, loaded on the carrier, which catalyst further contains a substance capable of reacting with the alkali metal and/or the alkaline earth metal, dominating over the reaction between the main components of the carrier and the alkali metal and/or the alkaline earth metal. With this catalyst body, the deterioration of the carrier by the alkali metal and/or the alkaline earth metal is prevented; therefore, the catalyst body can be used over a long period of time.Type: GrantFiled: December 14, 2000Date of Patent: August 18, 2009Assignee: NGK Insulators, Ltd.Inventors: Naomi Noda, Junichi Suzuki, Takashi Harada
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Publication number: 20090185968Abstract: The present invention is directed to a catalytic member, and a method of use for the treatment of pollutants in a gaseous stream. More specifically, the present invention is directed to a catalyst member comprising a substrate coated with a metallic anchor layer to enhance the adherence of a catalytic washcoat layer.Type: ApplicationFiled: January 18, 2008Publication date: July 23, 2009Inventors: Michael Galligan, Young Kim