And Group Viii Metal Containing (i.e., Iron Or Platinum Group) Patents (Class 502/313)
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Patent number: 8592338Abstract: A catalyst structure that allows a carbon nanotube having a desired shape and with larger length to be obtained in a stable manner and in high purity as well as a method of manufacturing a carbon nanotube using the same are provided. The present invention relates to a catalyst structure for use in manufacturing a carbon nanotube by means of vapor deposition of crystalline carbon, having a catalytic material that forms a ring or a whirl on its crystal growth surface, and further relates to a method of manufacturing a carbon nanotube using the same. Preferably, the catalyst structure is a columnar body with its upper surface serving as the crystal growth surface, where at least part of the side of the columnar body has a non-catalytic material that has substantially no catalytic activity with respect to the growth of the crystalline carbon.Type: GrantFiled: December 27, 2004Date of Patent: November 26, 2013Assignee: Sumitomo Electric Industries, Ltd.Inventor: Takeshi Hikata
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Publication number: 20130306517Abstract: A hydroconversion catalyst comprising a Group VIB metal component, a Group VIII metal component and a carrier material is disclosed wherein said catalyst has a total surface area of 240 to 360 m2/g; a total pore volume of 0.5 to 0.9 cc/g; and a pore volume distribution such that greater than 60% of pore volume are in pores present as micropores of diameter between 55 and 115 ?, less than 0.12 cc/g of pore volume are in pores present at pores of diameter greater than 160 ? and less than 10% of pore volume are in pores present as macropores of diameters greater than 250 ?.Type: ApplicationFiled: May 20, 2013Publication date: November 21, 2013Inventors: John George KESTER, David Andrew KOMAR, David Edward SHERWOOD
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Patent number: 8586500Abstract: In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of the metal precursor feeds do not react to form catalyst precursor and end up in the supernatant. In the present disclosure, the metals can be recovered via any of chemical precipitation, ion exchange, electro-coagulation, and combinations thereof to generate an effluent stream containing less than 50 mole % of metal ions in at least one of the metal residuals, and for at least one of the metal residuals is recovered as a metal precursor feed, which can be recycled for use in the co-precipitation reaction. An effluent stream from the process to waste treatment contains less than 50 ppm metal ions.Type: GrantFiled: October 18, 2011Date of Patent: November 19, 2013Assignee: Chevron U.S.A. Inc.Inventors: Alexander E. Kuperman, Theodorus Maesen, Dennis Dykstra
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Patent number: 8586786Abstract: A catalyst for use in the production of an unsaturated aldehyde and/or an unsaturated carboxylic acid, the catalyst comparing (or, preferably, being composed of) a mixed oxide containing molybdenum, bismuth and iron, which has improved methanical strength, is produced by a method including the steps of (1) drying an aqueous solution or an aqueous slurry containing raw materials of the catalyst and then firstly calcining a dried product in a molecular oxygen-containing gas atmosphere to obtain a calcined product; (2) heating the calcined product obtained in Step (1) in the presence of a reducing material to obtain a reduced product having a mass loss of 0.05 to 6%; and (3) secondly calcining the reduced product obtained in Step (2) in a molecular oxygen-containing gas atmosphere.Type: GrantFiled: July 23, 2012Date of Patent: November 19, 2013Assignee: Sumitomo Chemical Company, LimitedInventors: Naoki Miura, Eiichi Shiraishi, Koichi Nagai
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Publication number: 20130296163Abstract: Described is a catalyst and process useful in the hydrodesulfurization of a distillate feedstock to manufacture a low-sulfur distillate product. The catalyst comprises a calcined mixture of inorganic oxide material, a high concentration of a molybdenum component, and a high concentration of a Group VIII metal component. The mixture that is calcined to form the calcined mixture comprises molybdenum trioxide in the form of finely divided particles, a Group VIII metal compound, and an inorganic oxide material. The catalyst is made by mixing the aforementioned starting materials and forming therefrom an agglomerate that is calcined to yield the calcined mixture that may be used as the catalyst or catalyst precursor.Type: ApplicationFiled: July 1, 2013Publication date: November 7, 2013Inventor: Opinder Kishan BHAN
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Patent number: 8575062Abstract: In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor in a co-precipitation reaction, up to 60% of the metal precursor feeds do not react to form catalyst precursor and stay in the supernatant. In one embodiment, at least a precipitant is added to the product mixture at a molar ratio of precipitant to metal residuals in the supernatant ranging from 1.5:1 to 20:1 to precipitate at least 50 mole % of metal ions in the residuals forming additional catalyst precursor. The remaining metal residuals can be recovered via any of chemical precipitation, ion exchange, electro-coagulation, and combinations thereof to generate an effluent stream containing less than 50 mole % of at least one of the metal residuals. In one embodiment, at least one of the metal residuals is recovered and recycled for use as a metal precursor feed in the co-precipitation reaction.Type: GrantFiled: October 18, 2011Date of Patent: November 5, 2013Assignee: Chevron U.S.A. Inc.Inventors: Alexander E. Kuperman, Theodorus Maesen, Dennis Dykstra
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Patent number: 8575061Abstract: In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of metal ions in at least one of the metal precursor feeds do not react to form catalyst precursor and end up in the supernatant as metal residuals. In the present disclosure, the metals can be recovered via ion-exchange, wherein an exchange resin is provided for a portion of the metal ions in the supernatant to be exchanged and bound onto the resin. The previously resin-bound metals can be subsequently recovered, or the effluent stream for the exchange resin column can also be recovered, forming at least a metal precursor feed which can be used in the co-precipitation reaction.Type: GrantFiled: October 18, 2011Date of Patent: November 5, 2013Assignee: Chevron U.S.A. Inc.Inventors: Alexander E. Kuperman, Theodorus Maesen, Dennis Dykstra
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Publication number: 20130288892Abstract: Methods of forming monodispersed core-shell nanoparticles are provided. A cobalt(II)-ligand component, a metal(II)-ligand component, an organic reducing agent, and a capping agent can be added to an organic solvent to form a reaction mixture. The reaction mixture is then heated to a dissolving temperature while under a gas (e.g., including methane) such that the reaction mixture becomes a reaction solution while stirring at the dissolving temperature. The reaction solution is then be heated to a reaction temperature (e.g., about 200° C. or more) while under the gas to form the core-shell nanoparticles, and the core-shell nanoparticles can be collected from the reaction solution.Type: ApplicationFiled: April 2, 2013Publication date: October 31, 2013Inventors: Jochen A. Lauterbach, Jason R. Hattrick-Simpers, Cun Wen
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Patent number: 8563460Abstract: A catalyst unit is described comprising a cylinder with a length C and a diameter D, wherein said unit has five holes arranged in a pentagonal pattern extending longitudinally therethrough, with five flutes running along the length of the unit, said flutes positioned equidistant adjacent holes of said pentagonal pattern. The catalyst may be used particularly in steam reforming reactors.Type: GrantFiled: August 24, 2009Date of Patent: October 22, 2013Assignee: Johnson Matthey PLCInventors: David James Birdsall, Mileta Babovic, Mikael Per Uno Carlsson, Samuel Arthur French, Michiel Nijemeisland, William Maurice Sengelow, Edmund Hugh Stitt
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Patent number: 8557729Abstract: A catalyst unit is described in the form of a cylinder having a length C and diameter D, which has two or more flutes running along its length, wherein said cylinder has domed ends of lengths A and B, such that (A+B+C)/D is in the range 0.50 to 2.00, and (A+B)/C is in the range 0.40 to 5.00. The catalyst may be used particularly in reactions where hydrogen is a reactant such as hydroprocessing, hydrogenation, water-gas shift reactions, methanation, hydrocarbon synthesis by the Fischer-Tropsch reaction, methanol synthesis and ammonia synthesis.Type: GrantFiled: August 24, 2009Date of Patent: October 15, 2013Assignee: Johnson Matthey PLCInventors: Daniel Lee Cairns, Mileta Babovic, Terence James Fitzpatrick, Elizabeth Margaret Holt, Colin William Park, William Maurice Sengelow, Edmund Hugh Stitt
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Patent number: 8557728Abstract: A catalyst unit is described in the form of a cylinder having a length C and diameter D, which has one or more holes extending therethrough, wherein said cylinder has domed ends of lengths A and B, such that (A+B+C)/D is in the range 0.50 to 2.00, and (A+B)/C is in the range 0.40 to 5.00. The catalyst or catalyst unit preferably has one or more flutes miming along its length. The catalyst may be used particularly in steam reforming reactors.Type: GrantFiled: August 24, 2009Date of Patent: October 15, 2013Assignee: Johnson Matthey PLCInventors: David James Birdsall, Mileta Babovic, Mikael Per Uno Carlsson, Samuel Arthur French, Michiel Nijemeisland, William Maurice Sengelow, Edmund Hugh Stitt
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Publication number: 20130245332Abstract: The present invention relates to a process for the formation of an alcohol from an alkanoic acid, the steps of the process comprising: contacting a feed stream containing the alkanoic acid and hydrogen at an elevated temperature with a hydrogenating catalyst comprising from 3 to 25 wt. % of active metals comprising tin and cobalt and a metal promoter selected from the group consisting of noble metals or first metal, the first metal selected from the group of barium, cesium and potassium.Type: ApplicationFiled: March 13, 2012Publication date: September 19, 2013Applicant: CELANESE INTERNATIONAL CORPORATIONInventors: Heiko Weiner, Zhenhua Zhou, Radmila Jevtic, Victor J. Johnston
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Patent number: 8535515Abstract: The invention relates to a hydroconversion catalyst, which comprises a refractory oxide support, at least one metal selected from group VIII and at least one metal selected from group VIB and which is characterized in that it has at least one organic compound containing at least one oxime group of formula (I)>C?NOR1, in which R1 is selected among hydrogen and alkyl, allyl, aryl, alkylene or cycloaliphatic groups, and combinations thereof, these groups being able to be substituted by at least one electron donor group.Type: GrantFiled: August 4, 2004Date of Patent: September 17, 2013Assignee: Total FranceInventors: Thierry Cholley, Jean-Pierre Dath
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Patent number: 8536082Abstract: The invention relates to a method of preparing a dehydrogenation catalyst comprising a group VIII metal, a group IVA metal and a refractory oxide support. The method comprises stages of preparing the dry impregnation aqueous solution containing said group VIII metal, ammonia, either in solution or in gas form, and a complexing agent. It then comprises stages of aging the aqueous solution, of dry impregnation of the support, of maturing the impregnated support, of drying the impregnated support and of calcining the dried support.Type: GrantFiled: May 7, 2010Date of Patent: September 17, 2013Assignee: IFP Energies NouvellesInventors: Alexandre Chambard, Yohan Oudart
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Patent number: 8530373Abstract: Described is a catalyst and process useful in the hydrodesulfurization of a distillate feedstock to manufacture a low-sulfur distillate product. The catalyst comprises a calcined mixture of inorganic oxide material, a high concentration of a molybdenum component, and a high concentration of a Group VIII metal component. The mixture that is calcined to form the calcined mixture comprises molybdenum trioxide, a Group VIII metal compound, and an inorganic oxide material. The catalyst is made by mixing the aforementioned starting materials and forming therefrom an agglomerate that is calcined to yield the calcined mixture that may be used as the catalyst or catalyst precursor.Type: GrantFiled: July 7, 2010Date of Patent: September 10, 2013Assignee: Shell Oil CompanyInventor: Opinder Kishan Bhan
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Publication number: 20130225400Abstract: A method for preparing hydrorefining catalyst comprises the following steps: (1) mixing an aqueous ammonia solution with a polyamine complexing agent to form a mixed solvent; (2) adding a cobalt salt to the mixed solvent, dissolving the cobalt salt, and then adding a molybdenum salt and optional salts of other active components, and dissolving them to prepare an impregnating solution; and (3) impregnating a support with the impregnating solution, followed by aging, drying, and activating the impregnated support to form a hydrorefining catalyst. The hydrorefining catalyst prepared by this method has good activity, selectivity and stability in use.Type: ApplicationFiled: August 24, 2012Publication date: August 29, 2013Applicant: PetroChina Company LimitedInventors: Shunqin Liang, Wei Xie, Zongbao Wang, Huifeng Xue, Guangbi Gong, Tinghai Wang, Jie Wu, Limin Sun, Hongmin Kang, Dehua Huang, Shufeng Wang, Yundi Zheng, Cailan Jiang, Longgang Lv
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Publication number: 20130217923Abstract: The present invention relates to novel structured catalysts based on sintered metal fibers (SMF) coated by a basic oxide layer with Pd-nanoparticles, to reactions of organic compounds with hydrogen in the presence of said catalyst and an organic base as well as to vitamins, carotinoids, perfume ingredients, and/or food or feed ingredients prepared by using this reaction.Type: ApplicationFiled: July 1, 2011Publication date: August 22, 2013Applicant: DSM IP ASSETS B.V.Inventors: Werner Bonrath, Lioubov Kiwi-Minsker, Igor Iouranov
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Publication number: 20130205743Abstract: An exhaust gas treatment process, apparatus, and system for reducing the concentration of NOx, CO and hydrocarbons in a gas stream, such as an exhaust stream (29), via selective catalytic reduction with ammonia is provided. The process, apparatus and system include a catalytic bed (32) having a reducing only catalyst portion (34) and a downstream reducing-plus-oxidizing portion (36). Each portion (34, 36) includes an amount of tungsten. The reducing-plus-oxidizing catalyst portion (36) advantageously includes a greater amount of tungsten than the reducing catalyst portion (36) to markedly limit ammonia salt formation.Type: ApplicationFiled: April 23, 2012Publication date: August 15, 2013Inventor: Anatoly Sobolevskiy
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Patent number: 8507403Abstract: A process is described for producing a powder batch comprises a plurality of particles, wherein the particles include (a) a first catalytically active component comprising at least one transition metal or a compound thereof; (b) a second component different from said first component and capable of removing oxygen from, or releasing oxygen to, an exhaust gas stream; and (c) a third component different from said first and second components and comprising a refractory support. The process comprises providing a precursor medium comprising a liquid vehicle and a precursor to al least one of said components (a) to (c) and heating droplets of said precursor medium carried in a gas stream to remove at least part of the liquid vehicle and chemically convert said precursor to said at least one component.Type: GrantFiled: June 27, 2008Date of Patent: August 13, 2013Assignee: Cabot CorporationInventors: Miodrag Oljaca, Toivo T. Kodas, Ranko P. Bontchev, Klaus Kunze, Kenneth C. Koehlert
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Publication number: 20130186806Abstract: Preparation of a catalyst having at least one metal from group VIII, at least one metal from group VIB and at least one support; in succession: i) one of i1) contacting a pre-catalyst with metal from group VIII, metal from group VIB and support with a cyclic oligosaccharide naming at least 6 ?-(1,4)-bonded glucopyranose subunits; i2) contacting support with a solution containing a precursor of metal from group VIII, a precursor of said metal from group VIB and a cyclic oligosaccharide composed of at least 6 ?-(1,4)-bonded glucopyranose subunits; or i3) contacting support with a cyclic oligosaccharide composed of at least 6 ?-(1,4)-bonded glucopyranose subunits followed by contacting solid derived therefrom with a precursor of metal from group VIII and a precursor of metal from group VIB.Type: ApplicationFiled: June 24, 2011Publication date: July 25, 2013Applicant: IFP ENERGIES NOUVELLESInventors: Fabrice Diehl, Elodie Devers, Karin Marchand, Bertrand Guichard
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Patent number: 8492303Abstract: The invention describes an electrode and an electrode coating which are based on a catalyst containing finely divided carbon modifications and noble metal (oxide)s.Type: GrantFiled: July 30, 2010Date of Patent: July 23, 2013Assignee: Bayer MaterialScience AGInventors: Andreas Bulan, Norbert Schmitz
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Patent number: 8492305Abstract: The present invention relates to a catalyst for hydrocarbon steam cracking for the production of light olefin, a preparation method of the catalyst and a preparation method of olefin by using the same. More precisely, the present invention relates to a composite catalyst prepared by mixing the oxide catalyst powder represented by CrZrjAkOx (0.5?j?120, 0?k?50, A is a transition metal, x is the number satisfying the condition according to valences of Cr, Zr and A, and values of j and k) and carrier powder and sintering thereof, a composite catalyst wherein the oxide catalyst is impregnated on a carrier, and a method of preparing light olefin such as ethylene and propylene by hydrocarbon steam cracking in the presence of the composite catalyst. The composite catalyst of the present invention has excellent thermal/mechanical stability in the cracking process, and has less inactivation rate by coke and significantly increases light olefin yield.Type: GrantFiled: December 1, 2011Date of Patent: July 23, 2013Assignee: LG Chem, Ltd.Inventors: Jun-han Kang, Jong-hun Song, Jun-seon Choi, Byoung-gi Park, Chang-hoon Kang, Si-hyun Noh
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Publication number: 20130184148Abstract: A process for the selective production of ethanol by vapor phase reaction of acetic acid over a hydrogenating catalyst composition to form ethanol is disclosed and claimed. In an embodiment of this invention reaction of acetic acid and hydrogen over either cobalt and palladium supported on graphite or cobalt and platinum supported on silica selectively produces ethanol in a vapor phase at a temperature of about 250° C.Type: ApplicationFiled: March 6, 2013Publication date: July 18, 2013Applicant: CELANESE INTERNATIONAL CORPORATIONInventor: CELANESE INTERNATIONAL CORPORATION
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Patent number: 8486259Abstract: The invention relates to a bulk catalyst comprising at least 60 wt % metal oxidic particles comprising one or more Group VIII metals and Group VIB metal molybdenum, comprising less than 10 mole % of a second Group VIB metal (relative to the total amount of Group VIB metals) and comprising a Group V metal in an amount less than 10 mole % (relative to the total of the Group VIB metals), which bulk catalyst has been calcined at a temperature below a temperature where the hexagonal metastable crystal structure changes to an inactive crystalline structure, preferably below 450° C. and which bulk catalyst has a metastable hexagonal phase characterized by an X-ray diffraction pattern having reflections at 33-35 and 58-61° 2?. Preferably, the main reflections have a full width at half maximum (FWHM) of less than 2.5.Type: GrantFiled: October 25, 2006Date of Patent: July 16, 2013Assignee: Albemarle CorporationInventors: Sona Eijsbouts-Spickova, Jacobus Nicolaas Louwen, Frans L. Plantenga, Robertus Gerardus Leliveld, Sabato Miseo, Stuart Leon Soled
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Publication number: 20130178668Abstract: The present invention relates to catalysts, to processes for making catalysts and to chemical processes employing such catalysts. The multifunctional catalysts are preferably used for converting acetic acid and ethyl acetate to ethanol. The catalyst is effective for providing an acetic acid conversion greater than 20% and an ethyl acetate conversion greater than 0%. The catalyst comprises a precious metal and one or more active metals on a modified support. The modified support includes a metal selected from the group consisting of tungsten, vanadium, and tantalum, provided that the modified support does not contain phosphorous.Type: ApplicationFiled: August 27, 2012Publication date: July 11, 2013Applicant: CELANESE INTERNATIONAL CORPORATIONInventors: Zhenhua Zhou, Heiko Weiner, Radmila Wollrab
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Publication number: 20130178667Abstract: The present invention relates to catalysts, to processes for making catalysts and to chemical processes employing such catalysts. The catalysts are preferably used for converting acetic acid to ethanol. The catalyst comprises a precious metal and one or more active metals on a support, optionally a modified support.Type: ApplicationFiled: August 27, 2012Publication date: July 11, 2013Applicant: CELANESE INTERNATIONAL CORPORATIONInventors: Zhenhua Zhou, Heiko Weiner, Radmila Wollrab
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Publication number: 20130178664Abstract: The present invention relates to catalysts, to processes for making catalysts and to chemical processes employing such catalysts. The catalysts are preferably used for converting acetic acid to ethanol. The catalyst comprises a precious metal and one or more active metals on a modified support. The modified support may comprise cobalt tungstate.Type: ApplicationFiled: August 27, 2012Publication date: July 11, 2013Applicant: CELANESE INTERNATIONAL CORPORATIONInventors: Zhenhua Zhou, Victor Johnston, Dheeraj Kumar, Xiaoyan Tu, Heiko Weiner, Radmila Wollrab
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Publication number: 20130178670Abstract: The present invention relates to catalysts, to processes for making catalysts and to chemical processes employing such catalysts. The catalysts are preferably used for converting acetic acid and ethyl acetate to ethanol. The catalyst comprises an extruded modified support, and a precious metal. The processes for making the catalysts comprises modifying the catalyst, extruding the catalyst, and impregnating the precious metal onto the catalyst.Type: ApplicationFiled: January 4, 2013Publication date: July 11, 2013Applicant: Celanese International CorporationInventor: Celanese International Corporation
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Publication number: 20130178663Abstract: The present invention relates to catalysts, to processes for making catalysts and to chemical processes employing such catalysts. The catalysts are preferably used for converting acetic acid to ethanol. The catalyst comprises cobalt, precious metal and one or more active metals on a modified support.Type: ApplicationFiled: August 27, 2012Publication date: July 11, 2013Applicant: CELANESE INTERNATIONAL CORPORATIONInventors: Zhenhua Zhou, Dheeraj Kumar, Xiaoyan Tu, Heiko Weiner, Radmila Wollrab
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Patent number: 8481450Abstract: Methods and systems for contacting of a crude feed with one or more catalysts to produce a total product that includes a crude product are described. The crude product is a liquid mixture at 25° C. and 0.101 MPa. The crude product has an MCR content of at most 90% of the MCR content of the crude feed. One or more other properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed.Type: GrantFiled: March 9, 2011Date of Patent: July 9, 2013Assignee: Shell Oil CompanyInventor: Opinder Kishan Bhan
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Patent number: 8481451Abstract: The present invention relates to a catalyst for hydrocarbon steam cracking, a method of preparing the same, and a method of preparing olefin by the hydrocarbon steam cracking by using the catalyst, and more specifically, to a catalyst for hydrocarbon steam cracking for preparing light olefin including an oxide catalyst (0.5?j?120, 1?k?50, A is transition metal, and x is a number corresponding to the atomic values of Cr, Zr, and A and values of j and k) represented by CrZrjAkOx, wherein the composite catalyst is a type that has an outer radius r2 of 0.5R to 0.96R (where R is a radius of a cracking reaction tube), a thickness (t; r2?r1) of 2 to 6 mm, and a length h of 0.5r2 to 10r2, a method of preparing the same, and a method of preparing light olefins by using the same.Type: GrantFiled: June 4, 2010Date of Patent: July 9, 2013Assignee: LG Chem, Ltd.Inventors: Jun-Han Kang, Jonghun Song, Junseon Choi
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Patent number: 8476184Abstract: The invention relates to a bulk catalyst composition comprising metal oxidic particles comprising one or more Group VIII metals and two or more Group VIB metals, which bulk catalyst composition comprises first metal oxidic particles comprising one or more first Group VIII metals and one or more first Group VIB metals and separately prepared second metal oxidic particles comprising one or more second Group VIII metals and one or more second Group VIB metals, wherein the composition of Group VIB and Group VIII metals in the first and second metal oxidic particles are different, wherein the first and second oxidic bulk particles-are separately shaped to separate first and second shaped bulk catalyst particles, which are combined, preferably into a homogeneous blend, to form the bulk catalyst composition. The invention further relates to a process for the preparation of the bulk catalyst composition and to hydroprocessing a hydrocarbon feed using the bulk catalyst composition.Type: GrantFiled: October 25, 2006Date of Patent: July 2, 2013Assignee: Albemarle CorporationInventors: Sona Eijsbouts-Spickova, Robertus Gerardus Leliveld, Bob Gerardus Oogjen, Marinus Bruce Cerfontain, Johannes Cornelis Sitters
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Patent number: 8475921Abstract: A composite material includes an aggregate which contains a first metal particle constituting a core and second metal oxide particulates surrounding the first metal particle and having an average primary particle diameter ranging from 1 to 100 nm.Type: GrantFiled: July 20, 2006Date of Patent: July 2, 2013Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Tomoyuki Kayama, Kouzi Banno, Kiyoshi Yamazaki, Koji Yokota
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Publication number: 20130137009Abstract: An electrode catalyst for a fuel cell which including alloy particles including a Group 8 metal and a Group 9 metal.Type: ApplicationFiled: November 29, 2012Publication date: May 30, 2013Applicants: SAMSUNG SDI CO., LTD., SAMSUNG ELECTRONICS CO., LTD.Inventors: Samsung Electronics Co., Ltd., Samsung SDI Co., Ltd.
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Publication number: 20130130151Abstract: A metal alloy catalyst for the oxygen reduction reaction in fuel cells is disclosed. The catalyst contains the metals Pd, M1 and M2. M1 and M2 are different metals selected from Co, Fe, Au, Cr and W, excluding the combination PdCoAu.Type: ApplicationFiled: November 8, 2012Publication date: May 23, 2013Applicant: Ilika Technologies Ltd.Inventors: Karen Marie Brace, Brian Elliot Hayden, Christopher Edward Lee, Thierry Le Gall
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Publication number: 20130116488Abstract: The present invention relates to a catalyst composition for conversion of vegetable oils to hydrocarbon products in the diesel boiling range, comprising a porous support; Group III A or VA element in the range of 1-10 wt %; Group VI B elements in the range of 1 to 20 wt %; Group VIII B elements in range of 0.01 to 10 wt %. The present invention further provides the process for preparing the catalyst composition for conversion of vegetable oils to hydrocarbon products in the diesel boiling range. The present invention also provides the process for conversion of vegetable oils to hydrocarbon products in the diesel boiling range using the catalyst composition or discarded refinery spent hydro-treating catalyst.Type: ApplicationFiled: October 31, 2012Publication date: May 9, 2013Applicant: BHARAT PETROLEUM CORPORATION LIMITEDInventor: BHARAT PETROLEUM CORPORATION LIMITED
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Patent number: 8420878Abstract: The present invention relates to a complex oxide catalyst of Bi/Mo/Fe and an oxidative dehydrogenation of 1-butene in the presence of a catalyst herein. A catalyst of the present invention is superior to the conventional Bi/Mo catalyst in thermal and mechanical stabilities, conversion and selectivity toward 1,3-butadiene, while showing a long-term catalytic activity.Type: GrantFiled: October 13, 2009Date of Patent: April 16, 2013Assignee: Korea Kumho Petrochemical Co., Ltd.Inventors: Chae-Ho Shin, Jung-Hyun Park, Eunae Noh, Kyoungho Row, Ji Won Park
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Patent number: 8410015Abstract: A process and catalyst for the liquid phase selective hydrogenation of alkynes to alkenes with high selectivity to alkenes relative to alkanes, high alkyne conversion, and sustained catalytic activity comprising a reactant comprising an alkyne and a non-hydrocarbon solvent/absorbent, contacting the reactant stream with a hydrogen-containing stream in the presence of a supported, promoted, Group VIII catalyst, removing the solvent/absorbent, and recovering the alkene product.Type: GrantFiled: February 25, 2010Date of Patent: April 2, 2013Assignee: Synfuels International, Inc.Inventors: Marvin M. Johnson, Edward R. Peterson, Sean C. Gattis
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Patent number: 8404204Abstract: The present invention is directed to a granulate having photocatalytic activity, comprising particles of an inorganic particulate material coated with a photocatalytically active compound for introducing photocatalytic activity into or on building materials. The invention is further related to the manufacture of such a granulate and its use into or on building materials such as cement, concrete, gypsum and/or limestone and water-based coatings or paints for reducing an accumulation and growth of microorganisms and environmental polluting substances on these materials and thus reducing the tendency of fouling, while the brilliance of the color is maintained and the quality of the air is improved.Type: GrantFiled: March 31, 2008Date of Patent: March 26, 2013Assignee: Rockwood Italia SpAInventors: Marino Sergi, Christian Egger
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Patent number: 8394263Abstract: The invention relates to a bulk catalyst having improved activity in hydrodesulphurization, in particular in relatively low Group VIII over Group VIB metal molar ratios. The bulk catalyst comprises metal oxidic particles comprising one or more Group VIB metals and one or more-Group VIII metals which metal oxidic particles are obtainable by a process comprising the steps of reacting the compounds comprising one or more Group VIB metals and compounds comprising one or more Group VIII metals in hydrothermal conditions at a reaction temperature above the boiling temperature of the protic liquid, preferably in an autoclave at a reaction pressure above atmospheric pressure and. The invention also relates to the corresponding sulphided catalyst, to a process for the manufacture of said bulk catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurization and hydrodenitrogenation of hydrocarbon feedstock.Type: GrantFiled: October 25, 2006Date of Patent: March 12, 2013Assignee: Albemarle Netherlands B.V.Inventors: Sona Eijsbouts-Spickova, Robertus Gerardus Leliveld, Stuart Leon Soled, Sabato Miseo
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Patent number: 8389175Abstract: A fuel cell (70) having an anode (72), a cathode (78) and an electrolyte (76) between the anode (72) and the cathode (78) includes a cathode catalyst (80) formed of a plurality of nanoparticles. Each nanoparticle (20) has a plurality of terraces (26) formed of platinum surface atoms (14), and a plurality of edge (28) and corner regions (29) formed of atoms from a second metal (30)—The cathode catalyst may be formed by combining a platinum nanoparticle with a metal salt in a solution. Ions from the second metal react with platinum and replace platinum atoms on the nanoparticle. The second metal atoms at the corner and edge regions of the nanoparticle, as well as at any surface defects, result in a more stable catalyst structure. In some embodiments, the fuel cell (70) is a proton exchange membrane fuel cell and the nanoparticles are tetrahedron-shaped. In some embodiments, the fuel cell (70) is a phosphoric acid fuel cell and the nanoparticles are cubic-shaped.Type: GrantFiled: May 16, 2008Date of Patent: March 5, 2013Assignee: UTC Power CorporationInventors: Minhua Shao, Belabbes Merzougui, Patrick L. Hagans, Susanne M. Opalka
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Patent number: 8388923Abstract: Methods and systems of preparing a catalyst to be used in the synthesis of carbon nanotubes through Chemical Vapor Depositions are disclosed. The method may include a mixture comprising at least one of an iron catalyst source and a catalyst support. In another aspect, a method of synthesizing multi-walled carbon nanotubes using the catalyst is disclosed. The method may include driving a reaction in a CVD furnace and generating at least one multi-walled carbon nanotube through the reaction. The method also includes depositing the catalyst on the CVD furnace and driving a carbon source with a carrier gas to the CVD furnace. The method further includes decomposing the carbon source in the presence of the catalyst under a sufficient gas pressure for a sufficient time to grow at least one multi-walled carbon nanotube.Type: GrantFiled: March 9, 2012Date of Patent: March 5, 2013Assignee: King Abdulaziz City for Science and TechnologyInventors: Mohammed Abdullah Bahattab, Abdulaziz A Bagabas, Ibrahim M Al-Najjar
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Patent number: 8377289Abstract: A complex metal oxide catalyst comprising a Group VIII metal MI and at least two Group VIB metals MII and MIII, wherein the molar ratio of Group VIII metal MI to Group VIB metals MII+MIII is 1:9-9:1 and the molar ratio of the Group VIB metals MII and MIII is 1:5 to 5:1. When applied to the hydrodesulfurization of diesel, the catalyst exhibits a super high HDS activity. The sulfur level in the diesel can be reduced from 1200 ppm to 27 ppm under a gentle operating condition.Type: GrantFiled: November 26, 2008Date of Patent: February 19, 2013Assignee: Dalian Institute of Chemical Physics, Chinese Academy of SciencesInventors: Can Li, Zongxuan Jiang, Lu Wang
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Patent number: 8372268Abstract: A catalyst composition that is especially useful in the hydroconversion of pitch, micro carbon residue and sulfur contents of a heavy hydrocarbon feedstock without the excessive formation of sediment. The catalyst composition is a reasonably high surface area composition containing alumina and a low molybdenum content with a high ratio of nickel-to-molybdenum. The catalyst composition further has a unique pore distribution that in combination with the special metals loading provide for good conversion of pitch and micro carbon residue without an excessive yield of sediment.Type: GrantFiled: October 1, 2009Date of Patent: February 12, 2013Assignee: Shell Oil CompanyInventors: Josiane Marie-Rose Ginestra, John G. Kester, David Andrew Komar, David Edward Sherwood, Jr.
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Patent number: 8361924Abstract: Disclosed herein is fine particles of core-shell structure, each particle being composed of a core particle which is formed from a first material and has the face-centered cubic crystal structure and a shell layer which is formed from a second material differing from the first material on the surface of the core particle and has the face-centered cubic crystal structure, the fine particles containing particles which are multiply twinned fine particles and are surrounded by the {111} crystal plane.Type: GrantFiled: August 2, 2011Date of Patent: January 29, 2013Assignee: Sony CorporationInventors: Shinji Tanaka, Shuji Goto, Shigetaka Tomiya
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Patent number: 8361923Abstract: A process is provided for producing a complex oxide catalyst which exhibits superior catalytic activity in a vapor phase catalytic oxidation reaction, particularly in production of unsaturated aldehyde and unsaturated carboxylic acid. The process is characterized by the steps of preparing an aqueous slurry by mixing a complex oxide containing molybdenum and cobalt with an acid and water; drying the aqueous slurry; and calcining the resulting dried solid. Preferably, the complex oxide is obtained as follows: a molybdenum- and cobalt-containing complex oxide catalyst which has been used in a vapor phase catalytic oxidation reaction is mixed with an aqueous extracting solution obtained by dissolving at least one of ammonia and an organic base in water, to thereby extract molybdenum and cobalt into the aqueous phase; and the aqueous phase is dried and is then calcined under an atmosphere of an oxidizing gas.Type: GrantFiled: September 29, 2010Date of Patent: January 29, 2013Assignee: Sumitomo Chemical Company, LimitedInventors: Hirotsugu Kano, Eiichi Shiraishi
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Publication number: 20120323056Abstract: Disclosed herein is a catalyst for producing biodiesel, including a carrier having water resistance and an active component supported on the carrier and used in a hydrotreating reaction or a decarboxylation reaction. Since the catalyst for producing biodiesel includes a carrier having strong water resistance, the deactivation of the catalyst due to the water produced through a process of producing HBD can be prevented, thus remarkably improving the long term stability of a catalyst.Type: ApplicationFiled: October 20, 2010Publication date: December 20, 2012Applicants: SK ENERGY CO., LTD., SK INNOVATION CO., LTD.Inventors: Sang Il Lee, Do Woan Kim, Hee Jung Jeon, Sang Jun Ju, Jae Wook Ryu, Gyung Rok Kim
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Publication number: 20120316056Abstract: In one embodiment, an aqueous dispersion liquid contains at least one particles selected from tungsten oxide particles and tungsten oxide composite particles. A mean primary particle diameter (D50) of the particles is in the range of 1 nm to 400 nm. In the aqueous dispersion liquid, concentration of the particles is in the range of 0.1 mass % to 40 mass %, and pH is in the range of 1.5 to 6.5. The aqueous dispersion liquid excels in dispersibility of particles and capable of maintaining good liquidity for a long period.Type: ApplicationFiled: August 23, 2012Publication date: December 13, 2012Inventors: Kayo NAKANO, Akira SATO, Yasuhiro SHIRAKAWA, Keiichi FUSE, Shinya KASAMATSU, Akito SASAKI
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Patent number: 8329961Abstract: The present invention provides a catalyst for producing alcohols from carboxylic acids by hydrogenation, containing Co metal as an essential component and one or more elements selected from Zr, Y, La, Ce, Si, Al, Sc, V and Mo as a first co-catalyst component, and having 20% or more of cubic phase in the crystal phase of the Co metal, the method for producing the catalyst, and the method for producing an alcohol from a carboxylic acid as a raw material by hydrogenation using the catalyst.Type: GrantFiled: February 14, 2008Date of Patent: December 11, 2012Assignee: Kao CorporationInventors: Hiroshi Danjo, Noriaki Fukuoka, Taku Mimura
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Publication number: 20120308907Abstract: A catalyst composition comprising at least one precious metal, wherein the catalyst composition is capable of catalyzing, in the presence of a halogen ion or a mixture of halogen ions, a charging reaction and a discharging reaction in a regenerative fuel cell. This disclosure relates to electrodes comprising those catalysts that are useful in fuel cells. The catalysts are active towards hydrogen evolution reaction (HER) and hydrogen oxidation reaction (HOR) and porous electrodes are made in a process designed to control their porosity. The catalysts and electrodes are employed in regenerative fuel cells comprising hydrogen and halogen acid or mixture of halogen acids. The catalysts are particularly useful in hydrogen/bromine reduction/oxidation reactions. The catalysts exhibit highly acceptable life and performance.Type: ApplicationFiled: January 24, 2011Publication date: December 6, 2012Applicant: RAMOT AT TEL AVIV UNIVERSITY LTD.Inventors: Emanuel Peled, Arnon Blum, Adi Aharon, Nina Travitsky, Yaron Konra, Kobby Saadi, Vladimir Zel, Meital Goor, Meital Alon, Roy Gorenshtein