Copper Containing Patents (Class 502/331)
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Publication number: 20110315931Abstract: A nanoalloy catalyst, dual catalyst and methods for improving the efficiency and output of a biomass gasification process are provided where the catalysts comprise a volatile organometallic compound(s) and/or a nanoalloy catalyst. The subject nanoalloy catalyst cracks and gasifies lignin, which is generally inert in conventional gasification, at relatively low gasification temperatures. The subject disclosure also provides a means to increase gas yields and lower lignin content in the resulting product relative to conventional gasification. Alternatively, oil production may be increased, if desired. Moreover, the resulting gas may achieve a Fischer-Tropsch reactor favorable H2:CO ratio of up to about 9:1. The energy input to the gasification is correspondingly reduced to reduce costs and the environmental impact associated with the gasification process.Type: ApplicationFiled: July 29, 2011Publication date: December 29, 2011Applicant: Afton Chemical CorporationInventors: Allen A. Aradi, Joseph W. Roos, Tze-Chi Jao
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Patent number: 8075859Abstract: A nanocomposite particle, its use as a catalyst, and a method of making it are disclosed. The nanocomposite particle comprises titanium dioxide nanoparticles, metal oxide nanoparticles, and a surface stabilizer. The metal oxide nanoparticles are formed hydrothermally in the presence of the titanium dioxide nanoparticles. The nanocomposite particle is an effective catalyst support, particularly for DeNOx catalyst applications.Type: GrantFiled: July 14, 2009Date of Patent: December 13, 2011Assignee: Millennium Inorganic Chemicals, Inc.Inventors: Guoyi Fu, Steven M. Augustine
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Patent number: 8071655Abstract: A catalyst applicable to the synthesis gas conversions especially E-T slurry processes, said catalyst comprising: a) a support containing at least a first aluminate element of mixed spinel structure of formula MxM?(1?x)Al2O4/Al2O3.SiO2, x ranging between and excluding 0 and 1, or of simple spinel structure of formula MAl2O4/Al2O3.SiO2, said support being calcined in an at least partly oxidizing atmosphere, at a temperature ranging between 850° C. and 900° C., and b) an active phase deposited on said support, which contains one or more group VIII metals, selected from among cobalt, nickel, ruthenium or iron. Said catalyst is used in a fixed bed or suspended in a three-phase reactor for hydrocarbon synthesis from a CO, H2 mixture.Type: GrantFiled: November 17, 2005Date of Patent: December 6, 2011Assignees: IFP Energies Nouvelles, ENI S.p.A.Inventors: Fabrice Diehl, François Hugues, Marie-Claire Marion, Denis Uzio
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Publication number: 20110288353Abstract: A metal loaded catalyst comprises a support and main active metal components and optional auxiliary active metal components, wherein the main active metal components are elementary substances and obtained by ionizing radiation reducing precursors of main active metal components. The catalyst can be widely used in the catalytic reactions of petrochemistry industry with high activity and selectivity. The catalyst can be used directly without being reduced preliminarily by hydrogen.Type: ApplicationFiled: November 26, 2009Publication date: November 24, 2011Inventors: Wei Dai, Jing Peng, Haibo Yu, Hui Peng, Genshuan Wei, Maolin Zhai, Zuwang Mao, Yi Le, Wei Mu, Haijiang Liu, Yunxian Zhu
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Publication number: 20110274615Abstract: A catalyst has a long life span and efficiently separates hydrogen from water. A first metal element (Ni, Pd, Pt) for cutting the combination of hydrogen and oxygen and a second metal element (Cr, Mo, W, Fe) for helping the function of the first metal element are melted in alkaline metal hydroxide or alkaline earth metal hydroxide to make a mixture heated at a temperature above the melting point of the hydroxide to eject fine particles from the liquid surface, bringing steam into contact with the fine particles. Instead of this, a mixture of alkaline metal hydroxide and metal oxide is heated at a temperature above the melting point of the alkaline metal hydroxide to make metal compound in which at least two kinds of metal elements are melted, and fine particles are ejected from the surface of the metal compound to be brought into contact with steam.Type: ApplicationFiled: January 6, 2010Publication date: November 10, 2011Inventor: Yasuo Ishikawa
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Publication number: 20110275009Abstract: A core-shell type platinum-containing catalyst being allowed to reduce the amount of used platinum and having high catalytic activity and stability and a method of producing the same, an electrode and an electrochemical device are provided. The platinum-containing catalyst includes: metal particles each including a core particle including a metal atom except for platinum or an alloy of a metal atom except for platinum and a shell layer, including platinum on a surface of the core particle, the metal particles being supported by a conductive carrier and satisfying 0.25 nm?ts?0.9 nm and 1.4 nm?R1?3.5 nm, where an average thickness of the shell layer is ts and an average particle diameter of the core particle is R1.Type: ApplicationFiled: July 20, 2011Publication date: November 10, 2011Applicant: SONY CORPORATIONInventors: Shuji Goto, Shizuka Hosoi, Yuli Li, Yoshihiro Kudo, Akihiro Maesaka
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Publication number: 20110275512Abstract: This invention relates to the field of Fischer-Tropsch catalysis, in particular to activation of a Fischer-Tropsch catalyst. More particularly the invention relates to a method of activating an iron based Fischer-Tropsch catalyst which includes iron in a positive oxidation state by contacting in a reactor said iron based catalyst with a reducing gas selected from the group consisting of CO and a combination of H2 and CO; at a temperature of at least 245° C. and below 280° C.; at a reducing gas pressure of above 0.5 MPa and not more than 2.2 MPa; and at a GHSV of total gas fed to the reactor of at least 6000 ml(N)/g cat/h, thereby reducing the iron that is in a positive oxidation step in the catalyst.Type: ApplicationFiled: August 5, 2008Publication date: November 10, 2011Inventors: Johannes Jacobus Huyser, Matthys Josephus Janse Van Vuuren, Ryno Kotze
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Patent number: 8034156Abstract: A method for producing a decomposer of an organic halogenated compound comprises subjecting an iron powder produced beforehand to plastic deformation that gives the iron powder particles a flat shape. Further, an iron powder and a copper salt powder are mechanically mixed in a ball mill to produce a copper salt-containing iron particle powder in which the particles of the two powders are joined. In this case, the method for producing the decomposer of an organic halogenated compound is characterized in that the iron powder is mechanically deformed to give the particles a flat shape.Type: GrantFiled: March 22, 2006Date of Patent: October 11, 2011Assignee: Dowa Eco-System Co., Ltd.Inventors: Masami Kamada, Taishi Uehara
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Publication number: 20110237430Abstract: A process for preparing a catalyst comprising palladium supported on a carrier via a layered precursor, comprising the following steps: (1) synthesis of hydrotalcite layered precursor which comprises promoting metal element and aluminium on the surface of the carrier of Al2O3 microspheres, the atoms of the promoting metal and aluminium being highly dispersed by each other and bonded firmly to the carrier due to the crystal lattice positioning effect of the hydrotalcite crystal; (2) introduction of palladium into the carrier through impregnation; (3) drying; and (4) calcination and reduction with H2, the hydrotalcite layered precursor being converted into a composite oxide which consists of oxides of the promoting metal and aluminium, and the promoting metal element and aluminium being highly dispersed by each other and being able to separate and disperse the mainly active palladium element loaded later.Type: ApplicationFiled: June 25, 2009Publication date: September 29, 2011Applicant: BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGYInventors: Fazhi Zhang, Peng Chen, Rong Hou, Jiali Chen, Chao Gao, Hui Zhang, Dianqing Li, Feng Li, Xue Duan
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Publication number: 20110236302Abstract: According to one embodiment, there is provided a catalyst including a first structure including a metal oxide substrate having a pore, and a fine particle including Cu as a main component supported on an inner surface of the substrate facing the pore, and a second structure formed on the outer surface of the first structure and including Cu as a main component. The second structure is formed into a needle with a tip thereof oriented outward from the first structure.Type: ApplicationFiled: September 23, 2010Publication date: September 29, 2011Inventors: Yoshio Hanakata, Takayuki Fukasawa, Naoki Shutoh
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Patent number: 8026194Abstract: A catalyst for selective hydrogenation of hydrocarbons is presented. The catalyst selectively hydrogenates acetylenes and diolefins to increase the monoolefins in a product stream. The catalyst includes a layered structure with an inert inner core and an outer layer bonded to the inner core, where the outer layer is a metal oxide and has at least two metals deposited on the outer layer.Type: GrantFiled: November 19, 2008Date of Patent: September 27, 2011Assignee: UOP LLCInventors: Antoine Negiz, Gregory J. Gajda, Dean E. Rende
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Publication number: 20110207069Abstract: The invention relates to a novel type of active mass and to the use thereof in chemical loopping combustion processes. Said active mass contains a spinel which corresponds to the formula AxA?x?ByB?y?O4. The active masses according to the invention have a high oxygen transfer capacity and oxidation and reduction rates which allow their advantageous use in the looping combustion process.Type: ApplicationFiled: October 8, 2009Publication date: August 25, 2011Inventor: Arnold Lambert
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Publication number: 20110198210Abstract: A divalent copper salt and/or trivalent iron salt is supported on a surface of a metal ion-doped titanium oxide obtained by doping titanium oxide with metal ions to give a metal ion-doped titanium oxide with a valence band potential of 3 V or more (vs. SHE, pH=0) and a bandgap of 3 V or less between the valence band and an energy level of electrons excited from the valence band (including conduction band minimum potential and isolated potential). The metal ion-doped titanium oxide can be made to exhibit strong oxidative decomposition activity when irradiated with visible light based on the fact the divalent copper salt or trivalent iron salt functions as a catalyst for multi-electron reduction of oxygen.Type: ApplicationFiled: October 29, 2009Publication date: August 18, 2011Inventors: Kazuhito Hashimoto, Hiroshi Irie, Huogen Yu, Kazuhide Kamiya, Koichi Takahama, Shinichiro Miki, Mitsuo Yaguchi
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Publication number: 20110200915Abstract: In one example embodiment, a core-shell type platinum-containing catalyst is allowed to reduce the amount of used platinum and has high catalytic activity and stability. In one example embodiment, the core-shell type platinum-containing catalyst includes a core particle (with an average particle diameter R1) made of a non-platinum element and a platinum shell layer (with an average thickness ts) satisfying 1.4 nm?R1?3.5 nm and 0.25 nm?ts?0.9 nm. The core particle includes an element satisfying Eout?3.0 eV, where average binding energy relative to the Fermi level of 5d orbital electrons of platinum present on an outermost surface of the shell layer is Eout. In a fuel cell including a platinum-containing catalyst which contains a Ru particle as a core particle, the output density at a current density of 300 mA/cm2 is 70 mW/cm2 or over, and an output retention ratio is approximately 90% or over.Type: ApplicationFiled: October 29, 2009Publication date: August 18, 2011Applicant: SONY CORPORATIONInventors: Shuji Goto, Shizuka Hosoi, Yuli Li, Yoshihiro Kudo, Akihiro Maesaka
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Publication number: 20110201702Abstract: A ferrihydrite catalyst composition can comprise a ferrihydrite of a structural promoter metal, a chemical promoter metal and potassium to form an amorphous nanoparticulate. The ferrihydrite catalyst can be formed by dissolving an iron salt, a structural promoter metal salt and a chemical promoter metal salt in water to form an aqueous iron solution. A ferrihydrite solid can be precipitated from the aqueous iron solution by addition of a precipitating agent under conditions such that the ferrihydrite solid is a nanoparticulate. A potassium can be incorporated into the ferrihydrite solid to form a ferrihydrite catalyst precursor. The ferrihydrite catalyst precursor can be calcined to form the ferrihydrite catalyst. A synthesis gas can be readily converted to a fuel product by contacting the ferrihydrite catalyst with the synthesis gas under reaction conditions sufficient to form a fuel product mixture.Type: ApplicationFiled: August 16, 2010Publication date: August 18, 2011Inventors: Sumit Bali, Garima Bali, Edward M. Eyring, Richard D. Ernst, Ronald J. Pugmire
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Publication number: 20110184206Abstract: Disclosed is a catalyst for use in production of carboxylic acid ester by reacting (a) aldehyde and alcohol, or (b) one or more types of alcohols, in the presence of oxygen; wherein oxidized nickel and X (wherein X represents at least one element selected from the group consisting of nickel, palladium, platinum, ruthenium, gold, silver and copper) are loaded onto a support within the range of the atomic ratio of Ni/(Ni+X) of from 0.20 to 0.99.Type: ApplicationFiled: July 31, 2008Publication date: July 28, 2011Inventors: Ken Suzuki, Tatsuo Yamaguchi
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Patent number: 7985395Abstract: Catalyst for oxidation reactions which comprises at least one constituent active in the catalysis of hydrogen chloride oxidation and support therefor, which support is based on uranium oxide. The catalyst is notable for a high stability and activity.Type: GrantFiled: June 26, 2008Date of Patent: July 26, 2011Assignee: Bayer Technology Services GmbHInventors: Aurel Wolf, Leslaw Mleczko, Oliver Felix-Karl Schlüter, Stephan Schubert
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Patent number: 7985706Abstract: Provided are: a uniformly, highly dispersed metal catalyst including a catalyst carrier and a catalyst metal being loaded thereon dispersed throughout the carrier, the uniformly, highly dispersed metal catalyst having excellent performances with respect to catalytic activity, selectivity, life, etc.; and a method of producing the same. The uniformly, highly dispersed metal catalyst includes a catalyst carrier made of a metal oxide and a catalyst metal having catalytic activity, the catalyst metal being loaded on the catalyst carrier, in which the catalyst carrier is a sulfur-containing catalyst carrier having sulfur or a sulfur compound almost evenly distributed throughout the carrier and the catalyst metal is loaded on the sulfur-containing catalyst carrier in a substantially evenly dispersed manner over the entire carrier substantially according to the distribution of the sulfur or the sulfur compound.Type: GrantFiled: June 19, 2006Date of Patent: July 26, 2011Assignee: Chiyoda CorporationInventors: Yoshimi Okada, Toshiji Makabe, Masashi Saito, Takako Nishijima
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Patent number: 7968611Abstract: A method of producing an iron catalyst for catalyzing the hydrogenation of carbon monoxide is disclosed. The method comprises using a reduced amount of acid for iron dissolution compared to certain previous methods. The resulting acidic iron mixture is heated without boiling to obtain a nitrate solution having a Fe2+:Fe3+ ratio in the range of about 0.01%: 99.99% to about 100%:0% (wt:wt). Iron phases are precipitated at a lower temperature compared to certain previous methods. The recovered catalyst precursor is dried and sized to form particles having a size distribution between 10 microns and 100 microns. In embodiments, the Fe2+:Fe3+ ratio in the nitric acid solution may be in the range of from about 3%:97% to about 30%:70% (wt:wt) and the calcined catalyst may comprise a maghemite:hematite ratio of about 1%:99% to about 70%:30%.Type: GrantFiled: February 26, 2010Date of Patent: June 28, 2011Assignee: Rentech, Inc.Inventors: Belma Demirel, Charles B. Benham, Jesse W. Taylor, Pandurang V. Nikrad, Sara L. Rolfe, Olga P. Ionkina, Dawid J. Duvenhage, Harold A. Wright
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Publication number: 20110152547Abstract: A process for producing an olefin oxide which comprises reacting an olefin with oxygen in the presence of a catalyst comprising (a) copper oxide, (b) ruthenium metal or ruthenium oxide and (c) alkaline metal component or alkaline earth metal component.Type: ApplicationFiled: June 29, 2010Publication date: June 23, 2011Inventors: Selim SENKAN, Anusorn SEUBSAI
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Publication number: 20110152546Abstract: A process for producing an olefin oxide which comprises reacting an olefin with oxygen in the presence of a catalyst comprising a copper oxide and a ruthenium oxide on a porous support.Type: ApplicationFiled: June 29, 2010Publication date: June 23, 2011Inventors: Selim Senkan, Anusorn Seubsai
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Patent number: 7964114Abstract: The present development is a catalyst for use in water gas shift processes, a method for making the catalyst and a method of using the catalyst. The catalyst is composed of iron oxide, copper oxide, zinc oxide, alumina, and optionally, potassium oxide, and is produced using a hydrothermal synthesis process. The catalyst demonstrates surprising activity for conversion of carbon monoxide under high to moderate temperature shift reaction conditions.Type: GrantFiled: December 17, 2007Date of Patent: June 21, 2011Assignee: Sud-Chemie Inc.Inventors: Chao Chen, Eshan Li, Yanxia Wang, Yeping Cai, Chandra Ratnasamy, Jeffery E. Riley, Xueqin J. Wang, Shizhong Zhao, Jürgen R. Ladebeck
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Publication number: 20110143915Abstract: A nanoparticle comprises a nano-active material and a nano-support. In some embodiments, the nano-active material is platinum and the nano-support is alumina. Pinning and affixing the nano-active material to the nano-support is achieved by using a high temperature condensation technology. In some embodiments, the high temperature condensation technology is plasma. Typically, a quantity of platinum and a quantity of alumina are loaded into a plasma gun. When the nano-active material bonds with the nano-support, an interface between the nano-active material and the nano-support forms. The interface is a platinum alumina metallic compound, which dramatically changes an ability for the nano-active material to move around on the surface of the nano-support, providing a better bond than that of a wet catalyst. Alternatively, a quantity of carbon is also loaded into the plasma gun.Type: ApplicationFiled: December 7, 2010Publication date: June 16, 2011Applicant: SDCMATERIALS, INC.Inventors: Qinghua Yin, Xiwang Qi, Eliseo Ruiz
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Publication number: 20110137029Abstract: A process for preparing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group of ammonia and primary and secondary amines, in the presence of a supported copper-, nickel- and cobalt-containing catalyst, wherein the catalytically active material of the catalyst, before the reduction thereof with hydrogen, comprises oxygen compounds of aluminum, of copper, of nickel, of cobalt and of tin, and in the range from 0.2 to 5.0% by weight of oxygen compounds of yttrium, of lanthanum, of cerium and/or of hafnium, each calculated as Y2O3, La2O3, Ce2O3 and Hf2O3 respectively, and catalysts as defined above.Type: ApplicationFiled: December 2, 2010Publication date: June 9, 2011Applicant: BASF SEInventors: PETR KUBANEK, Wolfgang Mägerlein, Johann-Peter Melder, Thomas Heidemann
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Publication number: 20110137030Abstract: A process for preparing an amine by reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group of ammonia and primary and secondary amines, in the presence of a supported copper-, nickel- and cobalt-containing catalyst, wherein the catalytically active material of the catalyst, before the reduction thereof with hydrogen, comprises oxygen compounds of aluminum, of copper, of nickel and of cobalt, and in the range from 0.2 to 5.0% by weight of oxygen compounds of tin, calculated as SnO, and catalysts as defined above.Type: ApplicationFiled: December 2, 2010Publication date: June 9, 2011Applicant: BASF SEInventors: Petr Kubanek, Wolfgang Mägerlein, Johann-Peter Melder, Thomas Heidemann
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Publication number: 20110124500Abstract: High-quality bimetallic PtxCu100-x (x=54-80 at. %) nanocubes can be prepared from a hot organic solution. Synthetic conditions, such as the ratio of oleylamine/tetraoctylammonium bromide as well as the doses of 1-dodecanethiol and 1,2-tetradecanediol have been optimized to ensure a formation of Pt—Cu nanocubes. Electrochemical evaluation shows that the catalytic activity of Pt60Cu40 nanocubes for methanol oxidation is superior, in comparison with those of spherical Pt60Cu40 nanocubes and Pt nanocubes with similar sizes, implying that the {100}-terminated Pt60Cu40 nanocubes offer a higher activity for methanol oxidation reaction than those with mixed crystallographic facets do.Type: ApplicationFiled: November 23, 2010Publication date: May 26, 2011Applicant: THE RESEARCH FOUNDATION OF STATE UNIVERSITY OF NEW YORKInventors: Jiye Fang, Dan Xu
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Publication number: 20110124499Abstract: Platinum (Pt)-based alloys are effective catalysts for oxygen reduction reaction (ORR) or fuel oxidation in proton exchange membrane fuel cells (PEMFCs). A wet-chemical approach for preparing monodisperse Pt3Ni, Pt3Co and Pt3Fe nanocubes and Pt3Ni nanoctahedra which are terminated with {100} and {111} facets, respectively, were developed. Such nanoscaled electrocatalysts supported on carbon black with controlled shape, e.g., octahedral configuration, is provided. ORR activity on the Pt3Ni nanoctahedra is ˜5.1 fold higher than that of nanocubes with a similar size, and their C-supported samples are highly active with respect to commercial Pt/C.Type: ApplicationFiled: November 23, 2010Publication date: May 26, 2011Applicant: THE RESEARCH FOUNDATION OF STATE UNIVERSITY OF NEW YORKInventors: Jiye Fang, Jun Zhang
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Patent number: 7947251Abstract: Fe—Al—Cu catalysts have numerous industrial applications, for example, as catalysts in a water gas shift reactor. A method of producing a Fe—Al—Cu catalyst comprises the steps of providing an organic iron precursor, dissolving the organic iron precursor in a solvent solution, adding an aqueous solution comprising aluminum nitrate and copper nitrate to the organic iron pre-cursor-solvent solution, precipitating a gel comprising Fe—Al—Cu by adding a base, and drying the gel to form the Fe—Al—Cu catalyst.Type: GrantFiled: June 15, 2006Date of Patent: May 24, 2011Assignee: The Ohio State University Research FoundationInventors: Umit S. Ozkan, Xueqin Wang, Lingzhi Zhang, Sittichai Natesakhawat
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Publication number: 20110118110Abstract: The invention relates to a catalyst comprising an alloy of at least two different metals of which at least one metal is a metal of transition group VIII. The alloy is present in at least two phases having different degrees of alloying. The invention further relates to a process for producing the catalyst and a use of the catalyst.Type: ApplicationFiled: August 1, 2008Publication date: May 19, 2011Applicant: BASF SEInventors: Stefan Kotrel, Gerhard Cox, Ekkehard Schwab, Alexander Panchenko
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Publication number: 20110112203Abstract: Iron- and copper-comprising heterogeneous catalyst and process for producing it, which comprises the following steps: I. thermal decomposition of gaseous iron pentacarbonyl to give carbonyl iron powder having spherical primary particles, II. treatment of carbonyl iron powder obtained in step I with hydrogen, resulting in the metallic spherical primary particles at least partly agglomerating, III. surface oxidation of the iron particles from step II (agglomerates=secondary particles, and also any primary particles still present) to form iron oxide, IV. contacting of the particles from step III with an aqueous solution of a copper compound, V. drying in the presence of oxygen and subsequent calcination in the absence of oxygen, resulting firstly in oxygen-comprising copper compounds on the particles and finally reaction of these with the iron oxide to form a mixed oxide of the formula CuxFe3-xO4, where 0<x?1.Type: ApplicationFiled: November 4, 2010Publication date: May 12, 2011Applicant: BASF SEInventors: JOCHEN STEINER, Kerem Bay, Vera Werner, Jürgen Amann, Stefan Bunzel, Claudia Moßbacher, Joachim Müller, Ekkehard Schwab, Markus Weber
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Publication number: 20110112204Abstract: Iron—comprising heterogeneous catalyst and a process for producing it, which comprises the following steps: I. thermal decomposition of gaseous iron pentacarbonyl to give carbonyl iron powder having spherical primary particles, II. treatment of carbonyl iron powder obtained in step I with hydrogen, resulting in the metallic spherical primary particles at least partially agglomerating, III. contacting of the agglomerates (=secondary particles) with iron pentacarbonyl, IV. thermal decomposition of the iron pentacarbonyl applied in step III to give at least predominantly pore- and void-free secondary particles. Process for preparing olefins by reaction of carbon monoxide with hydrogen in the presence of a catalyst, with the abovementioned iron-comprising heterogeneous catalyst being used as catalyst.Type: ApplicationFiled: November 4, 2010Publication date: May 12, 2011Applicant: BASF SEInventors: JOCHEN STEINER, Kerem Bay, Ralf Böhling, Ekkehard Schwab
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Patent number: 7932205Abstract: The invention relates to a process for the preparation of a catalyst comprising: a) The preparation of a colloidal oxide suspension of a first metal M1 that consists in the neutralization of a basic solution by an acidic mineral solution that contains the precursor of the metal M1, b) Bringing into contact the precursor of the promoter M2, either directly in its crystallized form or after dissolution in aqueous phase, with the colloidal suspension that is obtained in stage a), c) Bringing into contact the colloidal suspension that is obtained in stage b) with the substrate, d) Drying at a temperature of between 30° C. and 200° C., under a flow of air. The invention also relates to a process for the treatment of an olefinic fraction that uses the catalyst prepared [by] said preparation process.Type: GrantFiled: December 14, 2006Date of Patent: April 26, 2011Assignee: IFPInventors: Vincent Coupard, Denis Uzio, Carine Petit-Clair, Lars Fischer, Frederic Portejoie
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Patent number: 7919655Abstract: Processes comprising: (i) providing a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones and mixtures thereof; and (ii) reacting the reactant with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a catalyst comprising a zirconium dioxide- and nickel-containing catalytically active composition, to form an amine; wherein the catalytically active composition, prior to reduction with hydrogen, comprises oxygen compounds of zirconium, copper, and nickel, and one or more oxygen compounds of one or more metals selected from the group consisting of Sb, Pb, Bi, and In.Type: GrantFiled: July 4, 2007Date of Patent: April 5, 2011Assignee: BASF SEInventors: Petr Kubanek, Bram Willem Hoffer, Ekkehard Schwab, Johann-Peter Melder, Holger Evers, Till Gerlach
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Patent number: 7915196Abstract: A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.Type: GrantFiled: October 7, 2005Date of Patent: March 29, 2011Assignee: Alliance for Sustainable Energy, LLCInventors: Yves O. Parent, Kim Magrini, Steven M. Landin, Marcus A. Ritland
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Publication number: 20110071018Abstract: This invention is directed a catalyst for dehydrogenating primary alcohols. In one embodiment, for example, the catalyst comprises a metal support (preferably a metal sponge support) having a copper-containing coating at the surface thereof. In another embodiment, the catalyst comprises a metal selected from the group consisting of zinc, cobalt, iron, tin and combinations thereof having a copper-containing coating at the surface thereof.Type: ApplicationFiled: August 19, 2010Publication date: March 24, 2011Applicant: MONSANTO TECHNOLOGY LLCInventors: David A. Morgenstern, Juan P. Arhancet, Howard C. Berk, William L. Moench, JR., James C. Peterson
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Patent number: 7910516Abstract: A decomposer of organic halogenated compounds comprises iron powder constituted of flat iron particles of a planar ratio of 2 or greater. Further, a decomposer of organic halogenated compounds comprises a copper salt-containing iron particle powder constituted of copper salt-carrying iron particles having a flat shape with a planar ratio of 2 or greater whose surfaces have adhered thereto copper salt particles that are finer than the iron particles.Type: GrantFiled: March 22, 2006Date of Patent: March 22, 2011Assignee: Dowa Eco-Systems Co., Ltd.Inventors: Masami Kamada, Taishi Uehara
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Patent number: 7910517Abstract: A catalyst for gas-phase reactions which has high mechanical stability and comprises one or more active metals on a support comprising aluminum oxide as support material, wherein the aluminum oxide in the support consists essentially of alpha-aluminum oxide. Ruthenium, copper and/or gold are preferred as active metal. Particularly preferred catalysts according to invention comprise a) from 0.001 to 10% by weight of ruthenium, copper and/or gold, b) from 0 to 5% by weight of one or more alkaline earth metals, c) from 0 to 5% by weight of one or more alkali metals, d) from 0 to 10% by weight of one or more rare earth metals, e) from 0 to 10% by weight of one or more further metals selected from the group consisting of palladium, platinum, osmium, iridium, silver and rhenium, in each case based on the total weight of the catalyst, on the support comprising alpha-Al2O3. The catalysts are preferably used in the oxidation of hydrogen chloride (Deacon reaction).Type: GrantFiled: August 22, 2006Date of Patent: March 22, 2011Assignee: BASF AktiengesellschaftInventors: Olga Schubert, Martin Sesing, Lothar Seidemann, Martin Karches, Thomas Grassler, Martin Sohn
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Publication number: 20110065017Abstract: In one embodiment, a composition for use in reforming is provided comprising a catalyst material comprising molybdenum dioxide and/or MO2 (where M=Mo, W, Ru, Re, Os, Ir) nanoparticles having an average particle size from about 2 nm to about 1,000 nm; and a substrate, wherein both the molybdenum dioxide and/or MO2 (where M=Mo, W, Ru, Re, Os, Ir) nanoparticles are substantially immobilized on the substrate. In another embodiment an anode for use in a fuel cell is provided comprising the forgoing composition. And in another embodiment a fuel cell is provided comprising the forgoing anode.Type: ApplicationFiled: September 10, 2010Publication date: March 17, 2011Inventors: Su Ha, M. Grant Norton
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Publication number: 20110065025Abstract: Disclosed is a method for preparing a platinum/support catalyst or a platinum alloy/support catalyst, including: a) preparing a dispersion solution including urea, a support and a water-soluble salt of at least one metal(s) having catalytic activity; (b) reacting the dispersion solution at high temperature so as to deposit the metal hydroxide particles derived from the at least one metal(s) on the support; and (c) reducing the metal hydroxide particles. The size and distribution of the platinum particles or platinum alloy particles are greatly improved by the use of urea. The disclosed method allows loading of platinum particles or platinum alloy particles having small particle size and uniform size distribution on the support since hydroxide ions homogenously generated in situ by the hydrolysis of urea react with metal salts to form the catalyst complex species deposited on the support.Type: ApplicationFiled: September 30, 2010Publication date: March 17, 2011Inventor: Jong-Sung Yu
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Patent number: 7901835Abstract: A platinum alloy catalyst can be used as a fuel cell catalyst. The platinum alloy is a PtAuX alloy wherein X is one or more metals chosen from the group consisting of transition metals, and wherein the alloy contains 40-97% Pt, 1-40% Au and 2-20% X. Electrodes, catalysed membranes and membrane electrode assemblies comprising the catalyst are also disclosed.Type: GrantFiled: July 27, 2005Date of Patent: March 8, 2011Assignee: Johnson Matthey Public Limited CompanyInventors: Brian Elliott Hayden, Christopher Edward Lee, Claire Mormiche, David Thompsett
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Publication number: 20110054167Abstract: Processes for preparing an amine, which processes comprise: reacting a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones, and mixtures thereof, with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a zirconium dioxide-, copper- and nickel-containing catalyst; wherein the catalyst comprises a catalytically active composition which comprises, before reduction with hydrogen, oxygen compounds of zirconium, copper, nickel and tin, and 0.5 to 8.0% by weight of an oxygen compound of cobalt, calculated as CoO, and wherein the catalytically active composition does not comprise any ruthenium.Type: ApplicationFiled: December 10, 2008Publication date: March 3, 2011Inventors: Petr Kubanek, Wolfgang Mägerlein, Ekkehard Schwab, Johann-Peter Melder, Manfred Julius
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Patent number: 7884139Abstract: The present invention relates to a catalyst comprising particles of a cobalt and zinc co-precipitate, having a volume average particle size of less than 150 ?m. Another aspect of the invention is the use of such a catalyst in a Fischer-Tropsch process. The present invention further relates to a method for preparing a catalyst comprising cobalt and zinc oxide, wherein an acidic solution comprising zinc ions and cobalt ions and a alkaline solution are contacted and the precipitate is isolated.Type: GrantFiled: January 16, 2009Date of Patent: February 8, 2011Assignee: BASF CorporationInventors: Cornelis Roeland Baijense, Tjalling Rekker
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Patent number: 7879756Abstract: A method of producing an iron catalyst for catalyzing the hydrogenation of carbon monoxide is disclosed. The method comprises using a reduced amount of acid for iron dissolution compared to certain previous methods. The resulting acidic iron mixture is heated without boiling to obtain a nitrate solution having a Fe2+:Fe3+ ratio in the range of about 0.01%:99.99% to about 100%:0% (wt:wt). Iron phases are precipitated at a lower temperature compared to certain previous methods. The recovered catalyst precursor is dried and sized to form particles having a size distribution between 10 microns and 100 microns. In embodiments, the Fe2+:Fe3+ ratio in the nitric acid solution may be in the range of from about 3%:97% to about 30%:70% (wt:wt) and the calcined catalyst may comprise a maghemite:hematite ratio of about 1%:99% to about 70%:30%.Type: GrantFiled: August 11, 2008Date of Patent: February 1, 2011Assignee: Rentech, Inc.Inventors: Belma Demirel, Charles B. Benham, Jesse W. Taylor, Pandurang V. Nikrad, Sara L. Rolfe, Olga P. Ionkina, Dawid J. Duvenhage, Harold A. Wright
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Patent number: 7875251Abstract: An ozone-decomposing agent including a first iron compound and a second iron compound is provided. The second iron compound may have a spinel type structure. The first iron compound of the ozone-decomposing agent may include an oxide selected from Fe2O3, FeO(OH) or Fe(OH)3. The second iron compound of the ozone-decomposing agent may include an oxide selected from MnFe2O4, ZnFe2O4, NiFe2O4, CuFe2O4 or CoFe2O4.Type: GrantFiled: April 25, 2006Date of Patent: January 25, 2011Assignee: Toyo Boseki Kabushiki KaishaInventor: Kazuhiro Ueda
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Publication number: 20110011772Abstract: Novel nickel and/or cobalt plated sponge based catalysts are disclosed. The catalyst have an activity and/or selectivity comparable to conventional nickel and/or cobalt sponge catalysts, e.g., Raney® nickel or Raney® cobalt catalysts, but require a reduced content of nickel and/or cobalt. Catalysts in accordance with the invention comprise nickel and/or cobalt coated on at least a portion of the surface of a sponge support. Preferably, the sponge support comprises at least one metal other than or different from the metal(s) contained in the coating. The method of preparing the plated catalysts, and the method of using the catalysts in the preparation of organic compounds are also disclosed.Type: ApplicationFiled: July 15, 2009Publication date: January 20, 2011Inventor: Stephen Raymond Schmidt
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Publication number: 20110014099Abstract: The invention relates to a catalytically active particulate filter which, in addition to the properties typical of particulate filters, has hydrogen sulphide block function, and to a process for removing nitrogen oxides and particulates from the exhaust gas of internal combustion engines operated predominantly under lean conditions (so-called “lean-burn engines”) using the inventive catalytically active particulate filter. This particulate filter comprises a filter body, a copper compound and an oxidation-catalytic active coating which comprises at least one catalytically active platinum group metal. The copper compound is in a second coating applied to the filter body. The two functional coatings may be applied to the filter body consecutive in the direction of flow, i.e. zoned, or layered one on top of the other.Type: ApplicationFiled: July 8, 2010Publication date: January 20, 2011Applicant: UMICORE AG & CO.KGInventors: Franz DORNHAUS, Stephanie Frantz, Ina Grisstede
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Publication number: 20110002826Abstract: The invention relates to the use of a novel type of active mass in looping redox processes. Said mass contains a spinel of formula Cu1?xFe1+xAlO4 with 0?x?0.1. The active mass according to the invention has a high oxygen transfer capacity and improved oxidation and reduction rates.Type: ApplicationFiled: May 16, 2008Publication date: January 6, 2011Inventor: Arnold Lambert
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Patent number: 7857981Abstract: A catalyst which, by means of a reduction reaction at ambient temperature, permits the elimination of nitrates and nitrites in waters. The catalyst comprises a combination of a noble metal and a non-noble metal supported on or incorporated into the structure of a support which, in elemental and anhydrous form, has the formula XYMgAl, in which X is at least one noble metal, Y is at least one non-noble metal, Mg is magnesium and Al is aluminum, the Mg and Al preferably forming the structure of a hydrotalcite or a mixed oxide deriving from a hydrotalcite.Type: GrantFiled: August 20, 2008Date of Patent: December 28, 2010Assignees: Consejo Superior de Investigaciones Cientificas, Universidad Politecnica de ValenciaInventors: Avelino Corma Canós, Antonio Eduardo Palomares Gimeno, Jose Gregorio Prato Moreno
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Publication number: 20100310950Abstract: A catalyst for a fuel cell, a fuel cell system including the same, and associated methods, the catalyst including a platinum-metal alloy having a face-centered tetragonal structure, and a carrier, wherein the platinum-metal alloy shows a broad peak or a peak having two split tips at a 2? of about 65 to about 75 degrees in an XRD pattern using a Cu—K ? line, and the platinum-metal alloy is supported in the carrier and has an average particle size of about 1.5 to about 5 nm.Type: ApplicationFiled: January 22, 2010Publication date: December 9, 2010Inventors: Myoung-Ki Min, Geun-Seok Chai, Hee-Tak Kim, Tae-Yoon Kim, Sang-Il Han, Sung-Yong Cho, Kah-Young Song
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Publication number: 20100304268Abstract: Alloy catalysts have the formula of PtiIrjXk, wherein X represents an element from the group consisting of Ti, Mn, Co, V, Cr, Ni, Cu, Zr, Zn, and Fe. These catalysts can be used as electrocatalysts in fuel cells.Type: ApplicationFiled: May 28, 2009Publication date: December 2, 2010Inventors: Tetsuo Kawamura, Lesia Protsailo