And Group Iii Metal Containing (i.e., Sc, Y, Al, Ga, In Or Tl) Patents (Class 502/332)
  • Patent number: 6780805
    Abstract: Zeolite/alumina composite, and a method for making, the composite for use as a catalyst substrate or catalyst carrier and comprising zeolite having a silica/alumina ratio of greater than 300 and gamma alumina having a specific surface area of greater than 100 m2/g. The zeolite/alumina composite exhibits a modulus of rupture of at least 750 psi. Additionally, the invention is also directed at a three catalyst (TWC) system for use in the removal of hydrocarbons, carbon monoxide and oxides of nitrogen from waste gas, the TWC system comprising the following components: (1) a zeolite/alumina composite catalyst support exhibiting a modulus of rupture of at least 750 psi and having a zeolite with a silica/zeolite ratio of at least 300 and the alumina comprising a gamma alumina having a specific surface area of greater than 100 m2/g; and, (2) a noble metal catalyst impregnated on the catalyst support, the noble metal selected from the group consisting of platinum, rhodium, iridium and palladium.
    Type: Grant
    Filed: May 9, 2002
    Date of Patent: August 24, 2004
    Assignee: Corning Incorporated
    Inventors: Margaret K. Faber, Shy-Hsien Wu, Yuming Xie, Kenneth E. Zaun
  • Patent number: 6780817
    Abstract: A hydrorefining catalyst of a hydrogenation active metal component supported on a refractory porous carrier has a median pore diameter determined by the nitrogen adsorption method of 8 to 20 nm, a pore volume determined by the nitrogen adsorption method of 0.56 cm3/g or greater, and a pore volume of pores with a pore diameter of 50 nm or larger determined by the mercury intrusion porosimetry method of 0.32 cm3/g or greater. Both the demetallizing activity and metal deposition capacity of the catalyst in hydrogenation and demetallizing of heavy oil are high. The hydrorefining catalyst is obtained by kneading a porous starting powder principally composed of &ggr;-alumina and having a pore capacity of 0.75 m3/g or larger and a mean pore diameter of 10 to 200 &mgr;m, molding and calcining, and supporting an active metal component on the product.
    Type: Grant
    Filed: August 8, 2000
    Date of Patent: August 24, 2004
    Assignee: Japan Energy Corporation
    Inventors: Hiroki Koyama, Toru Saito, Hideaki Kumagai
  • Patent number: 6777371
    Abstract: Catalysts and methods for alkane oxydehydrogenation are disclosed. The catalysts of the invention generally comprise (i) nickel or a nickel-containing compound and (ii) at least one or more of titanium (Ti), tantalum (Ta), niobium (Nb), hafnium (Hf), tungsten (W), yttrium (Y), zinc (Zn), zirconium (Zr), or aluminum (Al), or a compound containing one or more of such element(s). In preferred embodiments, the catalyst is a supported catalyst, the alkane is selected from the group consisting of ethane, propane, isobutane, n-butane and ethyl chloride, molecular oxygen is co-fed with the alkane to a reaction zone maintained at a temperature ranging from about 250° C. to about 350° C., and the ethane is oxidatively dehydrogenated to form the corresponding alkene with an alkane conversion of at least about 10% and an alkene selectivity of at least about 70%.
    Type: Grant
    Filed: May 4, 2001
    Date of Patent: August 17, 2004
    Inventor: Yumin Liu
  • Patent number: 6777370
    Abstract: The present invention relates to a layered catalyst composite useful for reducing contaminants in exhaust gas streams, especially gaseous streams containing sulfur oxide contaminants. More specifically, the present invention is concerned with improved catalysts of the type generally referred to as “three-way conversion” catalysts. The layered catalysts trap sulfur oxide contaminants which tend to poison three-way conversion catalysts used to abate other pollutants in the stream. The layered catalyst composites of the present invention have a sulfur oxide absorbing layer before or above a nitrogen oxide absorbing layer. The layered catalyst composite comprises a first layer and a second layer. The first layer comprises a first support and at least one first platinum component. The second layer comprises a second support and a SOx sorbent component, wherein the SOx sorbent component is selected from the group consisting of MgAl2O4, MnO, MnO2, and Li2O.
    Type: Grant
    Filed: April 13, 2001
    Date of Patent: August 17, 2004
    Assignee: Engelhard Corporation
    Inventor: Shau-Lin F. Chen
  • Publication number: 20040157733
    Abstract: An NOx sorption-and-reduction type catalyst is made which includes a hydrogen generating catalyst in which Rh is loaded on a support including an Al2O3—ZrO2 composite oxide. Since the Al2O3—ZrO2 composite oxide exhibits a basicity lower than ZrO2, SOX are less likely to approach so that it is possible to suppress the sulfur poisoning of Rh. Moreover, the Al2O3—ZrO2 composite oxide exhibits higher heat resistance than ZrO2, and it has a function of improving the steam reforming reaction activity of Rh in the same manner as ZrO2. Therefore, the post-durability NOx purifying ability of the NOx sorption-and-reduction type catalyst is improved.
    Type: Application
    Filed: November 3, 2003
    Publication date: August 12, 2004
    Inventors: Naoyuki Hara, Ichiro Hachisuka
  • Publication number: 20040127352
    Abstract: Methods are disclosed for preparing hydrothermally-stable structurally-promoted refractory-oxide catalyst supports, which includes mixing precursors of the refractory oxide and of at least one structural promoter and calcining the mixture. The methods feature the incorporation of at least one structural promoter into the lattice of a refractory-oxide material such as alumina. The hydrothermally-stable structurally-promoted refractory-oxide catalyst supports are useful in hydrothermal catalytic processes such as Fischer-Tropsch reactions.
    Type: Application
    Filed: October 16, 2003
    Publication date: July 1, 2004
    Applicant: ConocoPhillips Company
    Inventors: Yaming Jin, Rafael L. Espinoza
  • Publication number: 20040127586
    Abstract: This invention relates to methods for making a stabilized transition alumina of enhanced hydrothermal stability, which include the introduction of at least one structural stabilizer; a steaming step before or after the introduction step, wherein steaming is effective in transforming a transition alumina at least partially to boehmite and/or pseudoboehmite; and a calcining step to create a stabilized transition alumina. The combination of the structural stabilizer and the steaming step is believed to impart high hydrothermal stability to the alumina crystal lattice. Particularly preferred structural stabilizers include boron, cobalt, and zirconium. The stabilized transition alumina is useful as a catalyst support for high water partial pressure environments, and is particularly useful for making a catalyst having improved hydrothermal stability. The invention more specifically discloses Fischer-Tropsch catalysts and processes for the production of hydrocarbons from synthesis gas.
    Type: Application
    Filed: October 16, 2003
    Publication date: July 1, 2004
    Applicant: ConocoPhillips Company
    Inventors: Yaming Jin, Rafael L. Espinoza, Nithya Srinivasan, Olga P. Ionkina
  • Patent number: 6746597
    Abstract: A noble metal nanometer-sized catalyst composition is described along with the method for preparation of the composition. The crystal face of the catalyst contains a preponderance of (111) type crystal phase exposure. The crystal phase exposure is controlled by sequestering the noble metal cation before deposition on a catalyst support. Controlled catalyst face exposition combined with the nanometer scale of the catalyst increases the catalyst selectivity and activity, particularly for hydrogenation and dehydrogenation reactions.
    Type: Grant
    Filed: January 31, 2002
    Date of Patent: June 8, 2004
    Assignee: Hydrocarbon Technologies, Inc.
    Inventors: Bing Zhou, Michael Rueter
  • Patent number: 6740615
    Abstract: A method for regenerating used supported noble metal catalysts, which method includes solvent cleaning the used catalyst by contact with a suitable organic liquid cleaning solvent such as alcohols, ketones and such to remove organic deposits from the catalyst, followed by drying and calcining at elevated temperature to remove any remaining organic deposits from the catalyst, then treating the catalyst with an organo-metallic complex forming agent having ionization constant pK1 greater than about 2.5, such as glycolic acid and the like. The organic-metallic complex forming agent acts to break down large clusters of noble metal particles such as palladium (Pd) and redistributes the metal particles on the catalyst support such as alumina (Al2O3) in the same or other larger pores, so as to increase catalyst surface area and catalytic activity to provide a catalytic activity level at least 80% or even exceeding that of the fresh catalyst.
    Type: Grant
    Filed: December 22, 2000
    Date of Patent: May 25, 2004
    Assignee: Hydrocarbon Technologies, Inc.
    Inventor: Bing Zhou
  • Patent number: 6740620
    Abstract: An orthorhombic phase mixed metal oxide is produced selectively in quantitative yield.
    Type: Grant
    Filed: April 8, 2002
    Date of Patent: May 25, 2004
    Assignee: Rohn and Haas Company
    Inventors: Leonard Edward Bogan, Jr., Daniel A. Bors, Fernando Antonio Pessoa Cavalcanti, Michael Bruce Clark, Jr., Anne Mae Gaffney, Scott Han
  • Patent number: 6706659
    Abstract: A catalyst and process is disclosed to selectively upgrade a paraffinic feedstock to obtain an isoparaffin-rich product for blending into gasoline. The catalyst comprises a support of a sulfated oxide or hydroxide of a Group IVB (IUPAC 4) metal, a first component of at least one lanthanide element or yttrium component, which is preferably ytterbium, and at least one platinum-group metal component which is preferably platinum.
    Type: Grant
    Filed: August 29, 2001
    Date of Patent: March 16, 2004
    Assignee: UOP LLC
    Inventors: Ralph D. Gillespie, Michelle J. Cohn
  • Patent number: 6706660
    Abstract: A lean NOx catalyst and method of preparing the same is disclosed. The lean NOx catalyst includes a ceramic substrate, an oxide support material, preferably &ggr;-alumina, deposited on the substrate and a metal promoter or dopant introduced into the oxide support material. The metal promoters or dopants are selected from the group consisting of indium, gallium, tin, silver, germanium, gold, nickel, cobalt, copper, iron, manganese, molybdenum, chromium, cerium, vanadium, oxides thereof, and combinations thereof. The &ggr;-alumina preferably has a pore volume of from about 0.5 to about 2.0 cc/g; a surface area of between about 80 to 350 m2/g; an average pore size diameter of between about 3 to 30 nm; and an impurity level of less than or equal to 0.2 weight percent. In a preferred embodiment the &ggr;-alumina is prepared by a sol-gel method, with the metal doping of the &ggr;-alumina preferably accomplished using an incipient wetness impregnation technique.
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: March 16, 2004
    Assignee: Caterpillar Inc
    Inventor: Paul W. Park
  • Patent number: 6693060
    Abstract: A modified &thgr;-Al2O3-supported nickel reforming catalyst and its use for producing synthesis gas from natural gas, more specifically to a nickel reforming catalyst expressed by the following formula 1, having improved coke resistance, high-temperature catalysis stability and catalytic activity, which is prepared by coating nickel or mixture of nickel and cocatalyst (M1—M2—Ni) on a &thgr;-Al2O3 support modified with metal (M3—M4—ZrO2/&thgr;-Al2O3), and its use for producing synthesis gas from natural gas through steam reforming, oxygen reforming or steam-oxygen reforming, M1—M2—Ni/M3—M4—ZrO2/&thgr;-Al2O3  (1) wherein M1 is an alkali metal, each of M2 and M3 is an alkaline earth metal; and M4 is a IIIB element or a lanthanide.
    Type: Grant
    Filed: May 13, 2002
    Date of Patent: February 17, 2004
    Assignees: Korea Research Institute of Chemical Technology, Korea Gas Corporation, Kyungdong City Gas Co., Ltd.
    Inventors: Sang-Eon Park, Ki-Won Jun, Hyun-Seog Roh, Seung-Chan Baek, Young-Sam Oh, Young-Soon Baek, Ri-Sang Choi, Taek-Yong Song
  • Patent number: 6686311
    Abstract: A catalyst system and method for making carbon fibrils is provided which comprises a catalytic amount of an inorganic catalyst comprising nickel and one of the following substances selected from the group consisting of chromium; chromium and iron; chromium and molybdenum; chromium, molybdenum, and iron; aluminum; yttrium and iron; yttrium, iron and aluminum; zinc; copper; yttrium; yttrium and chromium; and yttrium, chromium and zinc. In a further aspect of the invention, a catalyst system and method is provided for making carbon fibrils which comprises a catalytic amount of an inorganic catalyst comprising cobalt and one of the following substances selected from the group consisting of chromium; aluminum; zinc; copper; copper and zinc; copper, zinc, and chromium; copper and iron; copper, iron, and aluminum; copper and nickel; and yttrium, nickel and copper.
    Type: Grant
    Filed: December 11, 2002
    Date of Patent: February 3, 2004
    Assignee: General Electric Company
    Inventors: Xiao-Dong Sun, Navjot Singh, Lionel Monty Levinson
  • Patent number: 6683024
    Abstract: A sorbent composition is provided which can be used in the desulfurization of a hydrocarbon-containing fluid such as cracked gasoline or diesel fuel. The sorbent composition contains a support component and a promoter component with the promoter component being present as a skin on the support component. Such sorbent composition is prepared by a process of impregnating a support component with a promoter component, wherein the promoter component has been melted under a melting condition, followed by drying, calcining, and reducing to thereby provide the sorbent composition.
    Type: Grant
    Filed: March 15, 2000
    Date of Patent: January 27, 2004
    Assignee: ConocoPhillips Company
    Inventors: Gyanesh P. Khare, Donald R. Engelbert
  • Patent number: 6680279
    Abstract: A method of dispersing nanosized catalyst particles on the surface of larger catalyst carrier particles is disclosed. The coating process is done dry and yields high effective surface area of nanosized catalyst particles coated on the surface of catalyst carrier particles. In this process, nanosized catalyst particles and catalyst carriers are mechanically mixed in a high velocity and impact force environment to which catalyst particles are embedded, or filmed, on the surface of catalyst carrier particles without using water or any other additional chemicals. The catalyst composite structure produced comprises better coating uniformity of the catalyst particle on its catalyst carrier. The catalyst particle/catalyst carrier composite produced can be applied to a support structure, such as a monolith as readily used in automotive or other applications.
    Type: Grant
    Filed: January 24, 2002
    Date of Patent: January 20, 2004
    Assignee: General Motors Corporation
    Inventors: Mei Cai, Lee Lizhong Feng, Martin S. Ruthkosky, Jerry Dale Rogers
  • Patent number: 6673742
    Abstract: This is a hydrogen generation process for use with fuel cells which includes a preferential oxidation step to reduce the concentration of carbon monoxide. The preferential oxidation step includes contacting a fuel stream comprising hydrogen and carbon monoxide in the presence of an oxygen at a preferential oxidation temperature of between about 70° and about 160° C. with preferential oxidation catalyst for reducing the concentration of carbon monoxide to produce a treated fuel gas stream comprising less than about 50 ppm-vol carbon monoxide. The preferential oxidation catalyst comprises ruthenium metal dispersed on a shaped alumina carrier, wherein at least 60 percent of the ruthenium metal is present in a band extending from the surface towards the center and having a width of about 50 percent of the distance from the surface to the center of the shaped alumina carrier. Superior performance at low preferential oxidation temperatures below 130° C.
    Type: Grant
    Filed: March 14, 2002
    Date of Patent: January 6, 2004
    Assignee: UOP LLC
    Inventors: Suheil F. Abdo, Cynthia A. DeBoy, Geralyn F. Schroeder
  • Patent number: 6670515
    Abstract: A material composed of ultrafine particles, comprising at least a metal element M having catalytic properties and at least a metal element M′ having a standard oxidation potential less than that of M, part at least of M′ atoms being in oxidized form, the average size of the particles being less than 50 nm, at least 80% in number of the particles having an average size less than 10 nm. One particle of the material is constituted by at least a metal element M with oxidation level 0, or by at least a metal element M′ in oxidized form, or by at least a metal element M′ with oxidation level 0, or by the combination of at least two species selected from the three previous species. The material is useful as a catalyst for hydrogenation or coupling reactions.
    Type: Grant
    Filed: August 16, 2001
    Date of Patent: December 30, 2003
    Assignee: Centre National de la Recherche Scientifique
    Inventors: Jean-Marie Dubois, Yves Fort, Olivier Tillement
  • Patent number: 6670303
    Abstract: Catalysts having a bimodal pore radius distribution comprise a) from 10 to 99.9% by weight of zirconium dioxide and b) from 0 to 60% by weight of aluminum oxide, silicon dioxide and/or titanium dioxide and c) from 0.1 to 10% by weight of at least one element of main group I or II, an element of transition group III, an element of transition group VIII, of the Periodic Table of the Elements, lanthanum and/or tin, with the proviso that the sum of the percentages by weight is 100.
    Type: Grant
    Filed: July 25, 2000
    Date of Patent: December 30, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Daniel Heineke, Klaus Harth, Uwe Stabel
  • Patent number: 6660897
    Abstract: A catalyst comprising at least one noble metal deposited on an acidic support, wherein the dispersion of the noble metal is less than 20%.
    Type: Grant
    Filed: May 1, 2000
    Date of Patent: December 9, 2003
    Assignee: Institut Francais du Petrole
    Inventors: Nathalie Marchal-George, Eric Benazzi, Tivadar Cseri, Slavik Kasztelan
  • Publication number: 20030203813
    Abstract: A catalyst for selective oxidation of carbon monoxide present in a hydrogen-containing gas is provided in which the catalyst comprises ruthenium supported on an alumina hydrate. This catalyst has a high selective oxidation activity to carbon monoxide. A carbon monoxide elimination method using this catalyst is also provided. In this method, to a gas containing at least hydrogen and carbon monoxide and being richer in the hydrogen than the carbon monoxide on the basis of volume, oxygen is added in an amount necessary for oxidizing at least part of carbon monoxide present in that gas, and thereafter the gas to which the oxygen has been added is brought into contact with the catalyst described above. Also provided is a solid polymer electrolyte fuel cell system that utilizes this method.
    Type: Application
    Filed: May 2, 2003
    Publication date: October 30, 2003
    Applicants: N. E. Chemcat Corporation, Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Takashi Itoh, Katsumi Kurabayashi, Takahiro Naka, Masako Takayama, Osamu Usaka, Shoji Isobe
  • Publication number: 20030203981
    Abstract: A supported cobalt-based catalyst is described, characterized in that the carrier has an average particle diameter, measured by means of Coulter LS230, ranging from 70 to 250 &mgr;m, a surface area higher than 175 m2/g and a pore volume higher than 0.35 cm3/g, measured with the B.E.T. method. The above catalyst is particularly useful in the Fischer-Tropsch reaction.
    Type: Application
    Filed: April 2, 2003
    Publication date: October 30, 2003
    Applicants: ENI S.p.A., AGIP PETROLI S.p.A., INSTITUT FRANCAIS DU PETROLE, ENITECNOLGIE S.p.A.
    Inventors: Giuseppe Bellussi, Roberto Zennaro, Vincenzo Piccolo, Enrico Radaelli, Magalie Roy-Auberger
  • Publication number: 20030185750
    Abstract: The present invention provides a method of steam reforming a hydrocarbon over a spinel-containing catalyst at short residence times or short contact times. The present invention also provides spinel-containing catalysts. Surprisingly superior results and properties obtained in methods and catalysts of the present invention are also described.
    Type: Application
    Filed: March 24, 2003
    Publication date: October 2, 2003
    Inventors: Yong Wang, Anna Lee Y. Tonkovich, David P. Vanderwiel
  • Patent number: 6627777
    Abstract: Catalysts for the fluid-bed hydrodechlorination of carbon tetrachloride to chloroform having high catalytic stability and comprising platinum supported on microspheroidal gamma alumina, characterized in that the platinum is in the form of particles dispersed throughout the mass of the support.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: September 30, 2003
    Assignee: Sud Chemie MT S.R.L.
    Inventors: Michele Rossi, Carlo Rubini, Antonio Pasquale, Luigi Cavalli
  • Patent number: 6625976
    Abstract: A platinum group metal three-way conversion catalyst composition containing a high temperature catalytic component and a low temperature catalytic component has each catalytic component present as separate distinct particles in the same washcoat layer. The catalyst composition is prepared from a washcoat slurry containing a high temperature catalyst support material, and a low temperature catalyst support material, each support material being of sufficiently large particle size so as to prevent each support material forming a solution or a sol with the liquid medium of the slurry. The platinum group metal or metals can be impregnated into each support material either after formation of the washcoat on a non-porous refractory, metallic or palletized substrate or before forming the washcoat slurry.
    Type: Grant
    Filed: February 8, 1999
    Date of Patent: September 30, 2003
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Paul Joseph Andersen, Christopher John Bennett, Barry John Cooper, Phillip Shady
  • Patent number: 6624116
    Abstract: An on-line method of synthesizing or regenerating catalysts for autothermal oxidation processes, specifically, the oxidation of paraffinic hydrocarbons, for example, ethane, propane, and naphtha, to olefins, for example, ethylene and propylene. The catalyst comprises a Group 8B metal, for example, a platinum group metal and, optionally, a promoter, such as tin, antimony, or copper, on a support, preferably a monolith support. On-line synthesis or regeneration involves co-feeding a volatile Group 8B metal compound and/or a volatile promoter compound with the paraffinic hydrocarbon and oxygen into the oxidation reactor under ignition or autothermal conditions.
    Type: Grant
    Filed: November 3, 2000
    Date of Patent: September 23, 2003
    Assignee: Dow Global Technologies Inc.
    Inventors: Sameer S. Bharadwaj, Joseph J. Maj, Jonathan H. Siddall
  • Patent number: 6624109
    Abstract: The present invention relates to a process for the synthesis of highly active modified carbon supported palladium catalyst by simultaneously impregnating activated carbon with a palladium precursor and an aluminium precursor. The carbon supported palladium catalyst is useful for the hydrodechlorination of dichlorodifluoromethane to produce difluoromethane.
    Type: Grant
    Filed: October 23, 2001
    Date of Patent: September 23, 2003
    Assignee: Council of Scientific and Industrial Research
    Inventors: Janmanchi K. Murthy, Sridara C. Shekar, Kamaraju S. Ramarao, Burri D. Raju, Kondapuram V. Raghavan
  • Publication number: 20030166465
    Abstract: Novel sorbent systems for the desulfurization of cracked-gasoline and diesel fuels are provided which are comprised of a bimetallic promotor on a particulate support such as that formed of zinc oxide and an inorganic or organic carrier. Such bimetallic promotors are formed of at least two metals of the group consisting of nickel, cobalt, iron, manganese, copper, zinc, molybdenum, tungsten, silver, tin, antimony and vanadium with the valence of same being reduced, preferably to zero. Processes for the production of such sorbents are provided wherein the sorbent is prepared from impregnated particulate supports or admixed to the support composite prior to particulation, drying, and calcination. Further disclosed is the use of such novel sorbents in the desulfurization of cracked-gasoline and diesel fuels whereby there is achieved not only removal of sulfur but also an increase in the olefin retention in the desulfurized product.
    Type: Application
    Filed: January 21, 2003
    Publication date: September 4, 2003
    Inventor: Gyanesh P. Khare
  • Publication number: 20030153456
    Abstract: The present invention is provided a method of a high stability selectable hydrogenate catalyst producing and using for MCHD manufacturing. The present invention comprised a preparing procedure for Ru/Al2O3 catalyst including an activity raising procedure for said catalyst including and a DMCHD manufacturing process which said high stability catalyst is used for a selectable hydrogenating reaction.
    Type: Application
    Filed: January 18, 2002
    Publication date: August 14, 2003
    Inventors: Man-Yin Lo, Mei-Yuan Chang
  • Patent number: 6605566
    Abstract: A novel supported bimetallic catalyst comprises a group VIII metal such as platinum, and tin, at least a portion of which interacts strongly with the group VIII metal in the catalyst in the reduced state. In the partially oxidized state, the catalyst of the invention contains at least 10% of tin in the form of a reduced tin species with oxidation state 0, said species having an isomer shift in the range 0.80 to 2.60 mm/s and a quadrupolar splitting in the range 0.65 to 2.00 mm/s. The invention also concerns the preparation of said catalyst, and processes using said catalyst for transforming hydrocarbons into aromatic compounds, such as gasoline reforming processes and aromatic production processes.
    Type: Grant
    Filed: August 23, 2001
    Date of Patent: August 12, 2003
    Assignee: Institut Francais du Petrole
    Inventors: Fabienne Le Peltier, Blaise Didillon, Jean-Claude Jumas, Josette Olivier-Fourcade
  • Publication number: 20030144553
    Abstract: The catalyst can be prepared by reduction of a precursor of a hydrogenation-active metal, which may be present on an oxidic support, by reaction with at least one compound of the formula (I)
    Type: Application
    Filed: January 2, 2003
    Publication date: July 31, 2003
    Inventors: Dominic Vanoppen, Michael Veith, Kroum Valtchev
  • Publication number: 20030144144
    Abstract: A catalyst for purifying NOx is provided which efficiently decomposes and purify the NOx in an exhaust gas in an oxygen-excess atmosphere, excels in resistance to heat and in durability in a high temperature range under a high-temperature oxidizing atmosphere and in the presence of moisture and SOx, and manifests the catalytic activity over a wide range of temperature. It is a catalyst for purifying nitrogen oxides formed by coating (A) a catalytically active component comprising (A-a) iridium and (A-b) at least one element selected from the group consisting of the elements of Group IIIB and Group IVB in the Periodic Table of the Elements with (B) a refractory inorganic compound.
    Type: Application
    Filed: December 9, 2002
    Publication date: July 31, 2003
    Inventors: Hideki Goto, Shigeyoshi Taniguchi, Makoto Horiuchi
  • Patent number: 6596667
    Abstract: A supported cobalt-based catalyst characterized in that the carrier has an average particle diameter, measured by means of Coulter LS230, ranging from 70 to 250 &mgr;m, a surface area higher than 175 m2/g and a pore volume higher than 0.35 cm3/g, measured with the B.E.T. method. The catalyst is useful in the Fischer-Tropsch reaction.
    Type: Grant
    Filed: March 1, 2001
    Date of Patent: July 22, 2003
    Assignees: Eni S.p.A., AGIP Petroli S.p.A., Institut Francais du Petrole, Enitecnologie S.p.A.
    Inventors: Giuseppe Bellussi, Roberto Zennaro, Vincenzo Piccolo, Enrico Radaelli, Magalie Roy-Auberger
  • Patent number: 6589909
    Abstract: A method by which a highly active catalyst for the steam reforming of methanol is efficiently produced by a simple process. The catalyst is produced from alloy fine particles obtained by first grinding an Al alloy containing quasi-crystals consisting of aluminum, copper and at least one metal atom selected from Fe, Ru and Os, and then leaching the ground Al alloy.
    Type: Grant
    Filed: March 30, 2001
    Date of Patent: July 8, 2003
    Assignee: Japan as represented by Director General of Ministry of Education, Culture, Sports, Science and Technology National Research Institute for Metals
    Inventors: Masatoshi Yoshimura, Yuzuru Takahashi, An-pang Tsai
  • Patent number: 6589908
    Abstract: A method for making alumina having a pore structure characterized by the absence of macropores, no more than 5% of the total pore volume in pores greater than 350 Å, a high pore volume (greater than 0.8 cc/g measured by mercury intrusion) and a bi-modal pore volume distribution character, where the two modes are separated by 10 to 200 Å, and the primary pore mode is larger than the median pore diameter (MPD), calculated either by volume or by surface area, the MPD by volume being itself larger than the MPD by surface area. Alumina made by such process and catalyst made therefrom.
    Type: Grant
    Filed: November 28, 2000
    Date of Patent: July 8, 2003
    Assignee: Shell Oil Company
    Inventors: Josiane M. Ginestra, Russell C. Ackerman, Christian G. Michel
  • Publication number: 20030125203
    Abstract: A process for the decomposition of perfluoroalkanes comprises contacting a gaseous stream comprising the perfluoroalkanes with a catalyst comprising alumina. The alumina is prepared from one or more alumina sources, one of which is aluminum nitrate. The catalyst preferably comprises stabilizing agent, in particular zirconium oxide or cobalt, preferably both. The catalyst is prepared by forming a slurry of aluminum nitrate, optionally with one or more additional sources of alumina, in a suitable solvent, such as water. The resulting mixture is dried and calcined to yield the finished catalyst. The stabilizing agent or a precursor thereof may be included in the mixture or impregnated into the finished catalyst.
    Type: Application
    Filed: December 13, 2002
    Publication date: July 3, 2003
    Applicant: Guild Associates, Inc.
    Inventor: Joseph Anthony Rossin
  • Patent number: 6586650
    Abstract: A process for opening naphthenic rings of naphthenic ring-containing compounds, along with catalysts which can be used in that process. The naphthene ring opening catalyst is a catalyst comprising at least one Group VIII metal selected from Ir, Pt, Rh, and Ru, wherein these metals are supported on an alkali metal or alkaline-earth metal modified support in an amount effective for opening a naphthene ring-containing compound at a tertiary carbon site.
    Type: Grant
    Filed: July 2, 2001
    Date of Patent: July 1, 2003
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: William C. Baird, Jr., Darryl P. Klein, Michele S. Touvelle, Jingguang G. Chen, Gary B. McVicker
  • Patent number: 6586481
    Abstract: A catalyst, which can be used in the Fischer-Tropsch process, and contains cobalt oxide having crystals with an average size ranging from 20 to 80 Å supported on an inert carrier of alumina. A preparation process for the catalyst and a Fischer-Tropsch process utilizing the catalyst are also provided.
    Type: Grant
    Filed: March 4, 2002
    Date of Patent: July 1, 2003
    Assignees: ENI S.p.A., AGIP Petroli S.p.A., Institut Francais du Petrole, Enitecnologie S.p.A.
    Inventors: Giovanni Pederzani, Roberto Zennaro, Sonia Morselli, Gastone Del Piero
  • Publication number: 20030120116
    Abstract: Fixed-bed Raney-type catalysts are made from metal alloy fibers and/or flakes previously fabricated according to the crucible metal extraction method and then tablated, pressed in mats and/or located into a cartridge. The catalysts are used for the hydrogenation, dehydrogenation, isomerization, reductive alkylation, reductive amination, and/or hydration of organic compounds.
    Type: Application
    Filed: December 4, 2002
    Publication date: June 26, 2003
    Inventors: Daniel Ostgard, Andreas Freund, Claus Rehren, Monika Berweiler, Gunter Stephani
  • Publication number: 20030119668
    Abstract: A catalyst or precursor thereto comprising cobalt and/or a cobalt compound on a transition alumina support having a total cobalt content of at least 41% by weight and a cobalt surface area, after reduction, greater than 25 m2 per gram of total cobalt. The catalyst or precursor may be made by slurrying a transition alumina powder having a pore volume of at least 0.7 ml/g with an aqueous cobalt ammine carbonate complex and heating the slurry to decompose the complex.
    Type: Application
    Filed: November 19, 2002
    Publication date: June 26, 2003
    Applicant: Johnson Matthey PLC
    Inventors: Martinus C. Lok, Gordon J. Kelly, Gavin Gray
  • Patent number: 6583085
    Abstract: A method for manufacturing an indium-tin-iron catalyst that is used to obtain carbon nanocoils that have an external diameter of 1000 nm or less, the method comprising a first process that forms an organic solution by mixing an indium-containing organic compound and a tin-containing organic compound with an organic solvent, a second process that forms an organic film by coating a substrate with the thus obtained organic solution, a third process that forms an indium-tin film by baking this organic film, and a fourth process that forms an iron film on the surface of this indium-tin film.
    Type: Grant
    Filed: October 26, 2001
    Date of Patent: June 24, 2003
    Assignees: Daiken Chemical Co., Ltd.
    Inventors: Yoshikazu Nakayama, Akio Harada
  • Patent number: 6576586
    Abstract: A selective hydrogenation catalyst for pyrolysis gasoline. The catalyst mainly consists of a support of &dgr;, &agr; mixed alumina covered by palladium and alkali metal and/or alkaline-earth metal which are distributed on the support surface, and the support has 0.5 to 09. ml/g of specific pore volume. 40 to 200 Å pores account for more than 85% of the total pore volume. The specific surface area is 70 to 140 m2/g, and &agr; crystal structure in the alumina support is 0.5 to 5% based on the weight percentage of &dgr;, &agr; mixed alumina support. The catalyst includes palladium in amount of 0.05 to 0.4 wt %, alkali metal and/or alkaline-earth metal in amount of 0.05 to 2.0 wt %.
    Type: Grant
    Filed: January 22, 2001
    Date of Patent: June 10, 2003
    Assignee: Petrochina
    Inventors: Li Siqin, Men Xiaotang, Gensheng Liu, Shunqin Liang, Xiaogong Zhang
  • Patent number: 6576584
    Abstract: A method for producing a hydrotreating catalyst which relates to the production of a solid catalyst composed of a carrier impregnated with an active component, to give a catalyst for hydrotreating hydrocarbon oils, which contains a large quantity of a hydrogenation-active component and uniform, crystalline composite metal compound, and shows high catalytic activity.
    Type: Grant
    Filed: August 31, 2000
    Date of Patent: June 10, 2003
    Assignee: Tonen Corporation
    Inventors: Masahiko Iijima, Takao Hashimoto, Yoshinobu Okayasu, Takeshi Isoda
  • Patent number: 6576208
    Abstract: A catalyst for selective oxidation of carbon monoxide present in a hydrogen-containing gas is provided in which the catalyst comprises ruthenium supported on an alumina hydrate. This catalyst has a high selective oxidation activity to carbon monoxide. A carbon monoxide elimination method using this catalyst is also provided. In this method, to a gas containing at least hydrogen and carbon monoxide and being richer in the hydrogen than the carbon monoxide on the basis of volume, oxygen is added in an amount necessary for oxidizing at least part of carbon monoxide present in that gas, and thereafter the gas to which the oxygen has been added is brought into contact with the catalyst described above. Also provided is a solid polymer electrolyte fuel cell system that utilizes this method.
    Type: Grant
    Filed: November 3, 2000
    Date of Patent: June 10, 2003
    Assignees: N.E. Chemcat Corporation, Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Takashi Itoh, Katsumi Kurabayashi, Takahiro Naka, Masako Takayama, Osamu Usaka, Shoji Isobe
  • Patent number: 6576200
    Abstract: A catalytic converter for cleaning exhaust gas includes a heat-resistant support, and a coating formed on the support. The coating contains at least one kind of catalytically active substance and at least one kind of oxygen-storing oxide. The oxygen-storing oxide is selected from oxides of Pr and Tb. The oxygen-storing oxide may be Pr6O11 or Tb4O7. Alternatively, the oxygen-storing oxide may be a complex oxide which may be represented by the formula, Ce1−(x+y)RxEyOxide or Ce1−(x+y)RxZryOxide where “R” represents Pr or Tb, “E” represents an element selected from a group consisting of Nd, Y and Gd.
    Type: Grant
    Filed: August 26, 1999
    Date of Patent: June 10, 2003
    Assignee: Daihatsu Motor Co., Ltd.
    Inventors: Mari Yamamoto, Hirohisa Tanaka
  • Publication number: 20030104935
    Abstract: A catalyst system and method for making carbon fibrils is provided which comprises a catalytic amount of an inorganic catalyst comprising nickel and one of the following substances selected from the group consisting of chromium; chromium and iron; chromium and molybdenum; chromium, molybdenum, and iron; aluminum; yttrium and iron; yttrium, iron and aluminum; zinc; copper; yttrium; yttrium and chromium; and yttrium, chromium and zinc. In a further aspect of the invention, a catalyst system and method is provided for making carbon fibrils which comprises a catalytic amount of an inorganic catalyst comprising cobalt and one of the following substances selected from the group consisting of chromium; aluminum; zinc; copper; copper and zinc; copper, zinc, and chromium; copper and iron; copper, iron, and aluminum; copper and nickel; and yttrium, nickel and copper.
    Type: Application
    Filed: December 11, 2002
    Publication date: June 5, 2003
    Inventors: Xiao-Dong Sun, Navjot Singh, Lionel Monty Levinson
  • Patent number: 6573214
    Abstract: Disclosed is a hydrogen generation process for use with fuel cells which includes a preferential oxidation step to reduce the concentration of carbon monoxide. The preferential oxidation step includes contacting a fuel stream comprising hydrogen and carbon monoxide in the presence of an oxygen at a preferential oxidation temperature of between about 70° and about 160° C. with preferential oxidation catalyst for reducing the concentration of carbon monoxide to produce a treated fuel gas stream comprising less than about 50 ppm-vol carbon monoxide. The preferential oxidation catalyst comprises ruthenium metal disposed on an alumina carrier having a low density and a high porosity. Superior performance at low preferential oxidation temperatures below 130° C. was observed when the alumina carrier contained a bimodal pore distribution with an average pore distribution of from about 20 to about 3000 angstroms.
    Type: Grant
    Filed: June 8, 2001
    Date of Patent: June 3, 2003
    Assignee: UOP LLC
    Inventors: Suheil F. Abdo, Cynthia A. DeBoy, Geralyn F. Schroeder
  • Patent number: 6569804
    Abstract: A chromium-free Fe-based catalyst for CO HTS reaction, comprising about 65 to about 90% by weight of Ferriate oxides; about 1 to about 10% by weight of Al, Fe, Si-mixed oxides (Al:Fe:Si=6:2:1) or aluminum-silicon-sol (Al:Si=8:2); about 0.5 to about 2.0% by weight of vanadium oxides; about 0.5 to about 3.0% by weight of magnesium oxides; about 0.5 to about 3.0% by weight of nickel oxides and about 0.1 to about 0.6% by weight of potassium oxide, based on the total weight of the catalyst. There is also provided a method for producing the catalyst.
    Type: Grant
    Filed: September 28, 2000
    Date of Patent: May 27, 2003
    Assignee: National Engineering, Research Center of Chemical Fertilizer Catalyst at FuZhou University
    Inventors: Kemei Wei, Qi Zheng, Jianben Xu, Xingyi Ling
  • Patent number: 6569803
    Abstract: A catalyst, for purifying an exhaust gas, contains at least one catalyst component from among Pt, Pd, Rh, Au, Ag and Ir, and a complex oxide of the perovskite type comprising at least two different metal elements. In the catalyst, the catalyst component is carried on the complex oxide.
    Type: Grant
    Filed: January 16, 2001
    Date of Patent: May 27, 2003
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Masahiko Takeuchi
  • Patent number: 6555496
    Abstract: A microcrystalline boehmite containing additive in a homogeneously dispersed state. Suitable additives are compounds containing elements selected from the group consisting of alkaline earth metals, alkaline metals, rare earth metals, transition metals, actinides, silicon, gallium, boron, titanium, and phosphorus. The microcrystalline boehmite according to the invention may be prepared in several ways. In general, a microcrystalline boehmite precursor and an additive are converted to a microcrystalline boehmite containing the additive in a homogeneously dispersed state. The additive does not contain zirconia or magnesia.
    Type: Grant
    Filed: August 11, 2000
    Date of Patent: April 29, 2003
    Assignee: Akzo Nobel N.V.
    Inventors: Dennis Stamires, Paul O'Connor, Gregory Pearson, William Jones