And Group Iii Metal Containing (i.e., Sc, Y, Al, Ga, In Or Tl) Patents (Class 502/341)
  • Publication number: 20100216634
    Abstract: A method for manufacturing a honeycomb structure includes molding a wet mixture containing an aluminum titanate powdery material to form a honeycomb molded body. The aluminum titanate powdery material contains about 40% to about 60% by mass of Al2O3, about 30% to about 50% by mass of TiO2, and about 1% to about 15% by mass of (MgO+SiO2). The honeycomb molded body has cells provided substantially in parallel with one another in a longitudinal direction of the honeycomb molded body. The honeycomb molded body is fired at a temperature of about 1200° C. to about 1700° C.
    Type: Application
    Filed: March 23, 2010
    Publication date: August 26, 2010
    Applicant: IBIDEN CO., LTD.
    Inventors: Kazushige OHNO, Kazunori Yamayose
  • Publication number: 20100207069
    Abstract: A catalyst for catalytic partial oxidation of hydrocarbon, having high thermal shock resistance, and a process for producing a synthesis gas using the catalyst are provided. A catalyst for catalytic partial oxidation of hydrocarbon is used in producing a synthesis gas containing carbon monoxide and hydrogen by adding oxygen and steam to a raw material hydrocarbon, thereby subjecting the raw material hydrocarbon to catalytic partial oxidation, and comprises a carrier comprising an inorganic oxide and an active metal supported thereon. In the catalyst, the total of volume of pores having a pore diameter in a first range of from 0.1 ?m to less than 1.0 ?m is 32% or more of the whole pore volume, and the total of volume of pores having a pore diameter in a second range of from 1.0 ?m to 10 ?m or less is 14% or more of the whole pore volume.
    Type: Application
    Filed: June 18, 2009
    Publication date: August 19, 2010
    Inventors: Hirokazu Fujie, Yoshiyuki Watanabe
  • Publication number: 20100204039
    Abstract: The exhaust gas-purifying catalyst includes at least one of a first composite oxide represented by a formula A(Al2-xBx)O4 and a second composite oxide represented by a formula (Al2-yCy)O3, wherein element A is a divalent transition metal other than platinum-group elements, each of elements B and C is a transition metal other than platinum-group elements, x satisfies 0<x<2, and y satisfies 0<y<2.
    Type: Application
    Filed: April 22, 2010
    Publication date: August 12, 2010
    Applicants: CATALER CORPORATION, DIAHATSU MOTOR CO., LTD.
    Inventors: Satoshi MATSUEDA, Mareo Kimura, Hiroto Yoshida, Keiichi Narita, Hirohisa Tanaka, Mari Uenishi, Masashi Taniguchi
  • Patent number: 7771586
    Abstract: A strontium-doped, calcium-alumina nickel supported reforming catalyst is useful for reforming reactions when it is desired to generate a low H2/CO ratio synthesis gas and to reduce coking. The catalyst can generate a synthesis gas having a H2/CO ratio of less than about 2.3. The catalyst includes alumina, from about 0.3 wt. % to about 35 wt. % of calcium oxide, from about 0.1 wl % to about 35 wt. % of a strontium promoter, and about 0.5 wt. % to about 30 wt. % nickel. The support is prepared by a method wherein the calcium oxide is combined with the alumina to form aluminum-rich calcium aluminates.
    Type: Grant
    Filed: June 11, 2007
    Date of Patent: August 10, 2010
    Assignee: Sud-Chemie Inc.
    Inventors: Chandra Ratnasamy, Yeping Cai, William M. Faris, Jürgen R. Ladebeck
  • Patent number: 7772147
    Abstract: A solid catalyst carrier substrate coated with a surface area-enhancing washcoat composition including a catalytic component, a metal oxide and a refractory fibrous or whisker-like material having an aspect ratio of length to thickness in excess of 5:1.
    Type: Grant
    Filed: September 12, 2005
    Date of Patent: August 10, 2010
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Paul John Collier, Alison Mary Wagland
  • Publication number: 20100196226
    Abstract: The present invention provides catalysts, reactors, and methods of steam reforming over a catalyst. Surprisingly superior results and properties obtained in methods and catalysts of the present invention are also described. For example, a coated catalyst was demonstrated to be highly stable under steam reforming conditions (high temperature and high pressure of steam). Methods of making steam reforming catalysts are also described.
    Type: Application
    Filed: February 1, 2010
    Publication date: August 5, 2010
    Applicant: VELOCYS INC.
    Inventors: Junko M. Watson, Francis P. Daly, Yong Wang, Anna Lee Tonkovich, Sean P. Fitzgerald, Steven T. Perry, Laura J. Silva, Rachid Taha, Enrique Aceves de Alba, Ya-Huei Chin, Robert Rozmiarek, XiaoHong Li
  • Patent number: 7767619
    Abstract: A promoted calcium-alumina supported reforming catalyst that is particularly useful for reforming reactions where low H2/CO ratio synthesis gas, such as less than 2.3 is generated directly is disclosed. The catalyst comprises from about 25 wt % to about 98 wt % alumina, from about 0.5 wt % to about 35 wt % calcium oxide, from about 0.01 wt % to about 35 wt % of a promoter, and from about 0.05 wt % to about 30 wt % of an active metal. The promoter is selected from the group consisting of titanium, zirconium, yttrium, niobium, elements of the lanthanum-series, such as, without limitation, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, ytterbium, and combinations thereof. The active metal is selected from the group consisting of nickel, cobalt, rhodium, ruthenium, palladium, platinum, iridium and combinations thereof as active metal, wherein the calcium oxide is combined with the alumina to form aluminum-rich calcium aluminates.
    Type: Grant
    Filed: July 9, 2004
    Date of Patent: August 3, 2010
    Assignee: Sud-Chemie Inc.
    Inventors: Shizhong Zhao, Yeping Cai, Xiao D. Hu, Jon P. Wagner, Jürgen Ladebeck, R. Steve Spivey
  • Patent number: 7754650
    Abstract: The present invention relates to a trifunctional catalyst used in catalytic cracking device in petroleum refining industry and a method for preparing the same. The trifunctional catalyst of the invention comprises absorbent, cerium dioxide and vanadium pentoxide acting as oxidative catalyst and cerium oxyfluoride acting as structural promoter. The oxidative catalyst and structural promoter are dispersed over the absorbent. The absorbent is spinel-based composite oxides having a general formula of MgAl2-xFexO4.yMgO, where the x is 0.01-0.5 and y is 0.2-1.2. In the trifunctional catalyst, the raw material for forming the chemical compound containing rare-earth cerium is hamartite powder. The method for preparing the trifunctional catalyst of the invention is shown as follows: the components relating to the preparation of the finished product are dissolved or dispersed into liquid materials; then the trifunctional catalyst is obtained after the mixing, drying and calcining of such liquid materials.
    Type: Grant
    Filed: November 10, 2004
    Date of Patent: July 13, 2010
    Assignee: Beijing SJ Environmental Protection and New Material Co., Ltd.
    Inventors: Zhenyi Liu, Xiaowei Li, Hua Chen, Youcheng Liu
  • Patent number: 7754651
    Abstract: Disclosed is an Cu/Zn/Al-catalyst containing copper oxide and zinc oxide as catalytically active components and aluminium oxide as thermostabilising component. The catalyst is characterized in that the Cu/Zn atomic ratio is <2.8 and the aluminium oxide component is obtained from an aluminium hydroxide sol.
    Type: Grant
    Filed: November 6, 2002
    Date of Patent: July 13, 2010
    Assignee: Süd -Chemie AG
    Inventors: Jurgen Ladebeck, Jurgen Koy, Tiberius Regula
  • Publication number: 20100173771
    Abstract: A catalyst for the manufacture of alkylene oxide, for example ethylene oxide, by the vapor-phase epoxidation of alkene containing impregnated silver and at least one efficiency-enhancing promoter on an inert, refractory solid support, said support incorporating a sufficient amount of zirconium component (present and remaining substantially as zirconium silicate) as to enhance at least one of catalyst activity, efficiency and stability as compared to a similar catalyst which does not contain the zirconium component.
    Type: Application
    Filed: February 25, 2010
    Publication date: July 8, 2010
    Inventors: Juliana G. Serafin, Albert C. Liu, Seyed R. Seyedmonir, Hwaili Soo, Thomas Szymanski
  • Publication number: 20100163793
    Abstract: This invention belongs to the field of catalysts for the transesterification of triglycerides, for the production of fatty acid glycerin and esters. This invention describes preparatory methods using solid catalysts and the formulation of these catalysts for the production of fatty acid esters, glycerin, and specifically, biodiesel through the heterogeneous transesterification reaction of triglycerides present in vegetable oils and fats, like soy, cotton seed, canola, castor, peanut oils and animal fat. The solid catalysts of this invention are sufficiently magnetic to use in the production of biodiesel from vegetable oils and fats, not only because they work in a similar fashion as state of the art catalysts, but also because of the low cost of the raw materials used in its production. The invention even describes the composition obtained by using the catalysts, in which the purity of the products, such as biodiesel and glycerin is greater than 96.5%.
    Type: Application
    Filed: October 23, 2009
    Publication date: July 1, 2010
    Applicant: PETROLEO BRASILEIRO S.A. - PETROBRAS
    Inventors: Marcio de Figueiredo Portilho, Alexander Rangel Bastos
  • Patent number: 7737078
    Abstract: The formation of H2S in a stoichiometric or reducing atmosphere is restrained without using Ni or Cu as an environmental load substance. An additional oxide composed of an oxide of at least one kind of metal selected from the group consisting of Bi, Sn and Zn was added to a three-way catalyst for purifying an exhaust gas emitted from an internal combustion engine of which the combustion is controlled in near a stoichiometric atmosphere in the amount of from 0.02 mol to 0.2 mol per liter of the catalyst. The additional oxide forms SO3 or SO4 from SO2 in an oxidizing atmosphere, and stores sulfur components as a sulfide in a reducing atmosphere so that emission of H2S can be restrained. And since no environmental load substance is contained, the catalyst can be used safely.
    Type: Grant
    Filed: December 1, 2005
    Date of Patent: June 15, 2010
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Hiromasa Suzuki
  • Patent number: 7713908
    Abstract: A method of producing a porous composite metal oxide comprising the steps of: dispersing first metal oxide powder, which is an aggregate of primary particles each with a diameter of not larger than 50 nm, in a dispersion medium by use of microbeads each with a diameter of not larger than 150 ?m, thus obtaining first metal oxide particles, which are 1 nm to 50 nm in average particle diameter, and not less than 80% by mass of which are not larger than 75 nm in diameter; dispersing and mixing up, in a dispersion medium, the first metal oxide particles and second metal oxide powder, which is an aggregate of primary particles each with a diameter of not larger than 50 nm, and which is not larger than 200 nm in average particle diameter, thus obtaining a homogeneously-dispersed solution in which the first metal oxide particles and second metal oxide particles are homogeneously dispersed; and drying the homogeneously-dispersed solution, thus obtaining a porous composite metal oxide.
    Type: Grant
    Filed: August 29, 2005
    Date of Patent: May 11, 2010
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Toshio Yamamoto, Akihiko Suda, Akira Morikawa, Kae Yamamura, Hirotaka Yonekura
  • Publication number: 20100081569
    Abstract: The invention relates to a coating material having catalytic activity for reducing the combustion temperature of soot and organic substances. It also relates to the use of the coating material. In order to create a catalytically active coating material with which an abrasion-proof coating suitable also for optical applications can be produced for the combustion of soot and organic substances, it is proposed within the scope of the invention that the coating material contains at least 20 and less than 50 wt. % of compounds of subgroup metals or of elements of the third and fourth main groups, and between 10 and 80 wt. % of alkali or alkaline earth compounds, the molar proportion of alkali or alkaline earth compounds being higher than the molar proportion of compounds of subgroup metals or of elements of the third and fourth main groups.
    Type: Application
    Filed: April 1, 2008
    Publication date: April 1, 2010
    Inventors: Stefan Sepeur, Frank Gross, Gerald Frenzer
  • Patent number: 7687429
    Abstract: Catalysts for oxychlorination of ethylene to 1,2-dichlorethane, comprising compounds of copper and magnesium supported on gamma alumina, wherein the copper, expressed as metal, is present in a quantity from 7 to 12% by weight and the Mg/Cu ratio is from 0.05 to 1, wherein the distribution of copper in the catalyst particle is such that the ratio X/Y between the concentration of the copper atoms on the surface given by the Al/Cu ratio (X) on the surface (20-30 nm layer) and the concentration given by the Al/Cu ratio (Y) referred to the entire particle is greater than 1.3 and can reach 3.
    Type: Grant
    Filed: November 23, 2005
    Date of Patent: March 30, 2010
    Assignee: Sud Chemie - Catalysts Italia S.R.L.
    Inventors: Francesco Casagrande, Carlo Orsenigo
  • Publication number: 20100075842
    Abstract: Disclosed herein is a method of producing a catalyst for storing nitrogen oxides, including: supporting a potassium oxide on alumina, which serves as a support, and then calcining the alumina supported with the potassium oxide at a high temperature, thus chemically bonding potassium oxide with the alumina. The method is advantageous in that a catalyst for storing nitrogen oxides, having high nitrogen oxide storage capacity and excellent hydrothermal stability, can be produced at low cost through a simple process.
    Type: Application
    Filed: November 19, 2006
    Publication date: March 25, 2010
    Inventors: Hyun-Sik Han, Gon Seo, Young-San Yoo, Se-Min Park
  • Patent number: 7655596
    Abstract: The present invention if for a catalyst for epoxidation of an alkene, such as ethylene, to an alkene oxide, such as ethylene oxide, on which silver has been deposited on alumina as a support which has been modified with certain weak base compounds, such as oxides of a Group 1A, Group 2A, Group 3A or the first transition series of the Periodic Table of Elements, and with a high temperature heat treatment. Optional promoters selected from the group consisting of compounds of Group 1A, Group 2A, Group 7A and Group 8 may be contacted with the alpha-alumina support in solution with a silver compound, with the catalyst precursor before calcination or with the catalyst after calcination. The catalyst is brought into contact with alkene and oxygen under reaction conditions to selectively convert the alkene to an alkene oxide.
    Type: Grant
    Filed: December 22, 2005
    Date of Patent: February 2, 2010
    Assignee: Saudi Basic Industries Corporation
    Inventors: Xiankuan Zhang, Alla Konstantin Khanmamedova
  • Patent number: 7645440
    Abstract: A catalyst that can be used for the production of hydrogen from hydrocarbon fuels in steam reforming processes contains an active metal of, e.g., at least one of Ir, Pt and Pd, on a catalyst support of, e.g., at least one of monoclinic zirconia and an alkaline-earth metal hexaaluminate. The catalyst exhibits improved activity, stability in both air and reducing atmospheres, and sulfur tolerance.
    Type: Grant
    Filed: December 18, 2006
    Date of Patent: January 12, 2010
    Assignees: Sud-Chemie Inc., Air Liquide
    Inventors: Franklin D. Lomax, Jr., John S. Lettow, Aaron L. Wagner, Jon P. Wagner, Duane Myers
  • Patent number: 7641875
    Abstract: A multi-phase catalyst for the simultaneous conversion of oxides of nitrogen, carbon monoxide, and hydrocarbons is provided. A catalyst composition comprising the multi-phase catalyst and methods of making the catalyst composition are also provided. The multi-phase catalyst may be represented by the general formula of CeyLn1-xAx+sMOZ, wherein Ln is a mixture of elements originally in the form of single-phase mixed lanthanides collected from natural ores, a single lanthanide, or a mixture of lanthanides; A is an element selected from a group consisting of Mg, Ca, Sr, Ba, Li, Na, K, Cs, Rb, or any combination thereof; and M is an element selected from the group consisting of Fe, Mn, Cr, Ni, Co, Cu, V, Zr, Pt, Pd, Rh, Ru, Ag, Au, Al, Ga, Mo, W, Ti, or any combination thereof; x is a number defined by 0?x<1.0; y is a number defined by 0?y<10; s is a number defined by 0?s<10; where s=0 only when y>0 and y=0 only when s>0.
    Type: Grant
    Filed: November 3, 2008
    Date of Patent: January 5, 2010
    Assignee: Catalytic Solutions, Inc.
    Inventor: Stephen J. Golden
  • Publication number: 20090324468
    Abstract: The present invention pertains to catalyst systems for nitrogen oxide, carbon monoxide, hydrocarbon, and sulfur reactions that are free or substantially free of platinum group metals. The catalyst system of the present invention comprise a substrate and a washcoat, wherein the washcoat comprises at least one oxide solid, wherein the oxide solid comprises one or more selected from the group consisting of a carrier material oxide, a catalyst, and mixtures thereof. The catalyst system may optionally have an overcoat, wherein the overcoat comprises at least one oxide solid, wherein the oxide solid comprises one or more selected from the group consisting of a carrier material oxide, a catalyst, and mixtures thereof. The catalyst comprises one or more selected from the group consisting of a ZPGM transition metal catalyst, a mixed metal oxide catalyst, a zeolite catalysts, or mixtures thereof.
    Type: Application
    Filed: June 27, 2008
    Publication date: December 31, 2009
    Inventors: Stephen J. Golden, Randal Hatfield, Jason Pless, Johnny Ngo, Mann Sakbodin
  • Patent number: 7638459
    Abstract: A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.
    Type: Grant
    Filed: May 25, 2005
    Date of Patent: December 29, 2009
    Assignee: UOP LLC
    Inventors: Dean E. Rende, James E. Rekoske, Jeffery C. Bricker, Jeffrey L. Boike, Masao Takayama, Kouji Hara, Nobuyuki Aoi
  • Publication number: 20090314993
    Abstract: The present invention relates to a novel composite metal oxide catalyst, a method of making the catalyst, and a process for producing synthesis gas using the catalyst. The catalyst may be a nickel and cobalt based dual-active component composite metal oxide catalyst. The catalyst may be used to produce synthesis gas by the carbon dioxide reforming reaction of methane. The catalyst on an anhydrous basis after calcinations has the empirical formula: M a m + ? N b n + ? Al c 3 + ? Mg d 2 + ? O ( am 2 + bn 2 + 3 2 ? c + d ) Mm+ and Nn+ are two transition metals serving as dual-active components and selected from the group consisting of Ni, Co, Fe, Mn, Mo, Cu, Zn or mixtures thereof, a+b+c+d=1, and 0.001?a?0.8, 0.001?b?0.8, 0.1?c?0.99, 0.01?d?0.99.
    Type: Application
    Filed: June 19, 2008
    Publication date: December 24, 2009
    Applicant: UNIVERSITY OF SASKATCHEWAN
    Inventors: Jianguo ZHANG, Hui WANG, Ajay Kumar DALAI
  • Patent number: 7635461
    Abstract: Composite combustion catalyst particles are described and disclosed. A metal core of a combustible metal can be coated with a metal oxide coating. Additionally, a catalyst coating can at least partially surround the metal oxide coating to form a composite catalyst particle. The composite catalyst particles can be dispersed in a variety of fuels such as propulsion fuels and the like to form an enhanced fuel. During initial stages of combustion, the catalyst coating acts to increase combustion of the fuel. As combustion proceeds, the metal core heats sufficiently to disturb the metal oxide coating. The metal core then combusts in highly exothermic reactions with an oxidizer and the catalyst coating to provide improved energy densities to the enhanced fuel.
    Type: Grant
    Filed: June 7, 2004
    Date of Patent: December 22, 2009
    Assignee: University of Utah Research Foundation
    Inventor: Scott L. Anderson
  • Publication number: 20090305872
    Abstract: Fluid catalytic cracking process comprising the steps of (a) preparing a physical 5 mixture comprising (i) aluminium trihydrate and/or flash-calcined aluminium trihydrate and (ii) a divalent metal oxide, hydroxide, carbonate, or hydroxycarbonate, (b) shaping the physical mixture of step a) to form fluidisable particles, and (c) adding the fluidisable particles obtained from step b) or step c) to a fluid catalytic cracking unit. In this FCC process, active sites of the catalyst composition are formed in-situ, i.e. in the FCC unit, without requiring peptisation, aging, or calcination steps prior to the addition of the composition to the hydrocarbon conversion unit.
    Type: Application
    Filed: November 19, 2005
    Publication date: December 10, 2009
    Applicant: ALBEMARLE NETHERLANDS BV
    Inventors: Dennis Stamires, Paul O'Connor
  • Publication number: 20090298680
    Abstract: An aluminum product includes an aluminum substrate, a porous alumina film formed on the aluminum substrate, and a photo-catalyst film. The alumina film has an array of pores defined on a surface thereof. The photo-catalyst film is formed on the surface of the alumina film and inner walls of the alumina film located in the pores. An exemplary method for producing the aluminum product is also provided.
    Type: Application
    Filed: April 10, 2009
    Publication date: December 3, 2009
    Applicant: HON HAI PRECISION INDUSTRY CO., LTD.
    Inventor: CHIEN-HAO HUANG
  • Patent number: 7625836
    Abstract: To provide a heat-resistant oxide which is excellent in heat resistance and durability at high temperature and has high activity, a heat-resistant oxide which has an oxide crystal structure and in which a rate of a solid solution of a noble metal in the oxide crystal structure is 50% or more is obtained by heat-treating (secondarily baking) a precursor composition comprising zirconia, at least one coordinative element selected from the group consisting of rare earth elements, alkaline earth elements, aluminum and silicon, and at least one noble metal selected from the group consisting of platinum, rhodium and palladium at 650° C. or higher.
    Type: Grant
    Filed: December 13, 2005
    Date of Patent: December 1, 2009
    Assignees: Cataler Corporation, Daihatsu Motor Co., Ltd.
    Inventors: Satoshi Matsueda, Mareo Kimura, Naoto Miyoshi, Yoshinori Ishii, Hirohisa Tanaka, Isao Tan, Mari Uenishi, Masashi Taniguchi
  • Patent number: 7618919
    Abstract: A method of producing a catalyst support comprising a substrate, and coating formed on the surface of the substrate and including powder of a first metal oxide of at least one member selected from the group consisting of alumina, zirconia, titania, iron oxides, oxides of rare earth elements, alkali metal oxides and alkali earth metal oxides, wherein the coating is obtained by heat treating the substrate after applied with a coating composition obtained by mixing the first metal oxide powder together with a fluid raw material composition containing raw material of a second metal oxide of at least one member selected from the group consisting of alumina, zirconia, titania, iron oxides, oxides of rare earth elements, alkali metal oxides and alkali earth metal oxides, at a shear rate of 1000 sec?1 or higher.
    Type: Grant
    Filed: January 30, 2006
    Date of Patent: November 17, 2009
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Takashi Shimazu, Ryusuke Tsuji, Hideo Sobukawa
  • Publication number: 20090275763
    Abstract: A catalyst for the manufacture of alkylene oxide, for example ethylene oxide, by the vapor-phase epoxidation of alkene containing impregnated silver and at least one efficiency-enhancing promoter on an inert, refractory solid support, said support incorporating a sufficient amount of zirconium component (present and remaining substantially as zirconium silicate) as to enhance at least one of catalyst activity, efficiency and stability as compared to a similar catalyst which does not contain the zirconium component.
    Type: Application
    Filed: June 2, 2009
    Publication date: November 5, 2009
    Inventors: Juliana G. Serafin, Albert C. Liu, Seyed R. Seyedmonir, Hwaili Soo, Thomas Szymanski
  • Patent number: 7612013
    Abstract: An object of the present invention is to provide a catalyst which, in the FT process, exhibits a high chain growth probability, and a high catalytic activity, can stably and smoothly promote the reaction, exhibits a high productivity of C5+, and can efficiently produce liquid hydrocarbons, and a process therefore. The invention relates to a hydrocarbon-producing catalyst obtainable by supporting a ruthenium compound on a support composed of a manganese oxide and an aluminum oxide, and which satisfies at least one of characteristics (1) and (2): (1) the catalyst being treated with an aqueous alkaline solution and subsequently subjected to calcination treatment in the air at 150 to 500° C., (2) the aluminum oxide being an aluminum oxide wherein pore volume formed by pores having a pore diameter of 8 nm or more accounts for 50% or more of total pore volume.
    Type: Grant
    Filed: February 23, 2005
    Date of Patent: November 3, 2009
    Assignees: Japan Oil, Gas and Metals National Corporation, Cosmo Oil Co., Ltd.
    Inventors: Kazuhito Sato, Shigenori Nakashizu, Osamu Iwamoto, Hiroaki Otsuka
  • Publication number: 20090269266
    Abstract: Oxidic composition consisting essentially of oxidic forms of a first metal, a second metal, and optionally a third metal, the first metal being either Ca or Ba and being present in the composition in an amount of from about 5 to about 80 wt %, the second metal being Al and being present in the composition in an amount of from about 5 to about 80 wt %, the third metal being selected from the group consisting of La, Ti, and Zr, and being present in an amount of from 0 to about 17 wt %—all weight percentages calculated as oxides and based on the weight of the oxidic composition, the oxidic composition being obtainable by (a) preparing a physical mixture comprising solid compounds of the first, the second, and the optional third metal, (b) optionally aging the physical mixture, without anionic clay being formed, and (c) calcining the mixture. This composition is suitable for use in FCC processes for the passivation of metals with only minimal influence on the zeolite's hydrothermal stability.
    Type: Application
    Filed: June 2, 2006
    Publication date: October 29, 2009
    Applicant: ALBEMARLE NETHERLANDS B.V.
    Inventors: Dennis Stamires, Paul O'connor, William Jones, Erik Jeroen Laheij
  • Patent number: 7605110
    Abstract: A ceramic body, a ceramic catalyst body, a ceramic catalyst body and related manufacturing methods are disclosed wherein a cordierite porous base material has a surface, formed with acicular particles made of a component different from that of cordierite porous base material, which has an increased specific surface area with high resistance to a sintering effect. The ceramic body is manufactured by preparing a slurry containing an acicular particle source material, preparing a porous base material, applying the slurry onto a surface of the porous base material and firing the porous base material, whose surface is coated with the slurry, to cause acicular particles to develop on the surface of the porous base material. A part of or a whole of surfaces of the acicular particles is coated with a constituent element different from that of the acicular particles.
    Type: Grant
    Filed: April 5, 2007
    Date of Patent: October 20, 2009
    Assignees: Denso Corporation, Nippon Soken, Inc.
    Inventors: Keiichi Yamada, Kazuhiko Koike, Katsumi Yoshida, Hideki Kita, Naoki Kondo, Hideki Hyuga
  • Patent number: 7605108
    Abstract: A catalyst which suppresses aggregation of metal particles and which has superior heat resistance. In the catalyst, metal particles are supported by a surface of a carrier while being partially embedded therein.
    Type: Grant
    Filed: July 5, 2005
    Date of Patent: October 20, 2009
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Hironori Wakamatsu, Hirofumi Yasuda, Kazuyuki Shiratori, Masanori Nakamura, Katsuo Suga, Toru Sekiba
  • Patent number: 7598204
    Abstract: A reagent suitable for use as a catalyst comprises a first metal species substrate having a second reduced metal species coated thereon, the second reduced metal species being less electropositive than the first metal. Methods of manufacture are also provided.
    Type: Grant
    Filed: September 19, 2005
    Date of Patent: October 6, 2009
    Assignee: General Motors Corporation
    Inventors: Andrew M. Mance, Tao Xie, Belabbes Merzougui
  • Publication number: 20090239739
    Abstract: A catalyst 1 has a heat-resistant support 2 selected from among Al2O3, SiO2, ZrO2, and TiO2, and a first metal 4 supported on an outer surface of the support 2, and included by an inclusion material 3 containing a component of the support 2.
    Type: Application
    Filed: December 5, 2005
    Publication date: September 24, 2009
    Inventors: Hirofumi Yasuda, Katsuo Suga, Makoto Aoyama, Toshiharu Miyamura
  • Publication number: 20090232728
    Abstract: A water gas shift catalyst for use at temperatures above about 450° C. up to about 900° C. or so comprising rhenium deposited on a support, preferably without a precious metal, wherein the support is prepared from a high surface area material, such as a mixed metal oxide, particularly a mixture of zirconia and ceria, to which may be added one or more of a high surface area transitional alumina, an alkali or alkaline earth metal dopant and/or an additional dopant selected from Ga, Nd, Pr, W, Ge, Fe, oxides thereof and mixtures thereof.
    Type: Application
    Filed: March 14, 2008
    Publication date: September 17, 2009
    Applicant: Sud-Chemie Inc.
    Inventors: Jon P. Wagner, Michael W. Balakos, Chandra Ratnasamy
  • Patent number: 7585812
    Abstract: A catalyst for use in the Fischer-Tropsch process, and a method to prepare the catalyst is disclosed. The catalyst of the present invention has a higher surface area, more uniform metal distribution, and smaller metal crystallite size than Fischer-Tropsch catalysts of the prior art.
    Type: Grant
    Filed: June 20, 2008
    Date of Patent: September 8, 2009
    Assignee: Sud-Chemie Inc.
    Inventors: X. D. Hu, Patrick J. Loi, Robert J. O'Brien
  • Patent number: 7582276
    Abstract: The invention relates to nanoscale rutile or oxide powder that is obtained by producing amorphous TiO2 by mixing an alcoholic solution with a titanium alcoholate and with an aluminum alcohalate and adding water and acid. The amorphous, aluminum-containing TiO2 is isolated by removing the solvent, and is redispersed in water in the presence of a tin salt. Thermal or hydrothermal post-processing yields rutile or oxide that can be redispersed to primary particle size. The n-rutile or the obtained oxide having a primary particle size ranging between 5 and 20 nm can be incorporated into all organic matrices so that they remain transparent. Photocatalytic activity is suppressed by lattice doping with trivalent ions. If the amorphous precursor is redispersed in alcohol, or not isolated, but immediately crystallized, an anatase is obtained that can be redispersed to primary particle size.
    Type: Grant
    Filed: August 30, 2002
    Date of Patent: September 1, 2009
    Assignee: ITN Nanovation AG
    Inventor: Ralph Nonninger
  • Patent number: 7582202
    Abstract: A Composition comprising one or more metal hydroxy salts and a matrix, binder or carrier material, wherein the metal hydroxy salt is a compound comprising (a) as metal either (i) one or more divalent metals, at least one of them being selected from the group consisting of Ni, Co, Ca, Zn, Mg, Fe, and Mn, or (ii) one or more trivalent metal(s), (b) framework hydroxide, and (c) a replaceable anion. This composition has various catalytic applications.
    Type: Grant
    Filed: February 10, 2004
    Date of Patent: September 1, 2009
    Assignees: Akzo Nobel N.V., Albemarle Netherlands B.V.
    Inventors: William Jones, Paul O'Connor, Dennis Stamires
  • Publication number: 20090215613
    Abstract: The present invention is directed to yttrium compositions and methods for making such metal oxide compositions, specifically, metal oxide compositions having high surface area, high metal/metal oxide content, and/or thermal stability with inexpensive and easy to handle materials.
    Type: Application
    Filed: November 1, 2007
    Publication date: August 27, 2009
    Applicant: Symyx Technologies, Inc.
    Inventor: Alfred Hagemeyer
  • Publication number: 20090209412
    Abstract: A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.
    Type: Application
    Filed: October 7, 2005
    Publication date: August 20, 2009
    Applicant: ALLIANCE FOR SUSTAINABLE ENERGY, LLC
    Inventors: Yves O. Parent, Kim Magrini, Steven M. Landin, Marcus A. Ritland
  • Patent number: 7576035
    Abstract: A pillar-shaped honeycomb structure has a plurality of cells longitudinally placed in parallel with one another with a wall portion therebetween, wherein the honeycomb structure mainly includes inorganic fibers which form the honeycomb structure without lamination interfaces.
    Type: Grant
    Filed: April 7, 2008
    Date of Patent: August 18, 2009
    Assignee: Ibiden Co., Ltd.
    Inventors: Kazushige Ohno, Tomokazu Oya
  • Patent number: 7566393
    Abstract: Compounds and methods for sorbing organosulfur compounds from fluids are provided. Generally, compounds according to the present invention comprise mesoporous, nanocrystalline metal oxides. Preferred metal oxide compounds either exhibit soft Lewis acid properties or are impregnated with a material exhibiting soft Lewis acid properties. Methods according to the invention comprise contacting a fluid containing organosulfur contaminants with a mesoporous, nanocrystalline metal oxide. In a preferred embodiment, nanocrystalline metal oxide particles are formed into pellets (14) and placed inside a fuel filter housing (12) for removing organosulfur contaminants from a hydrocarbon fuel stream.
    Type: Grant
    Filed: April 26, 2005
    Date of Patent: July 28, 2009
    Assignee: NanoScale Corporation
    Inventors: Kenneth Klabunde, Bill R. Sanford, P. Jeevanandam
  • Patent number: 7563744
    Abstract: The present invention relates to a catalyst for the purification of exhaust gases from an internal combustion engine, which comprises a catalytically active coating on an inert ceramic or metal honeycomb body, said coating comprising at least one platinum group metal selected from the group consisting of platinum, palladium, rhodium and iridium on a fine, oxidic support material. As an oxidic support material, the catalyst comprises a low-porosity material on the basis of silicon dioxide that comprises aggregates of essentially spherical primary particles having an average particle diameter of between 7 and 60 nm.
    Type: Grant
    Filed: August 8, 2002
    Date of Patent: July 21, 2009
    Assignee: Umicore AG & Co. KG
    Inventors: Harald Klein, Ulrich Neuhausen, Egbert Lox, Jürgen Gieshoff, Thomas Kreuzer
  • Patent number: 7560411
    Abstract: A process is provided for preparing a carrier which process comprises incorporating into the carrier at any stage of the carrier preparation a strength-enhancing additive. Also provided is the resultant carrier having incorporated therein a strength-enhancing additive and a catalyst comprising the carrier. Also provided is a process for the epoxidation of an olefin employing the catalyst. Also provided is a method of using the olefin oxide so produced for making a 1,2-diol, a 1,2-diol ether or an alkanolamine.
    Type: Grant
    Filed: August 30, 2005
    Date of Patent: July 14, 2009
    Assignee: Shell Oil Company
    Inventors: Randall Clayton Yeates, John Robert Lockemeyer, Marek Matusz
  • Publication number: 20090149321
    Abstract: A particulate inorganic oxide contains an aluminum oxide, a metal oxide forming no composite oxide with an aluminum oxide, and at least one additional element selected from the group consisting of rare earth elements and alkaline earth elements. In the inorganic oxide, a percentage content of the aluminum oxide to a total amount of aluminum in the aluminum oxide, a metal element in the metal oxide, and the additional element is in a range from 48 at % to 92 at % in terms of element content. At least 80% of primary particles in the inorganic oxide have a particle diameter of 100 nm or smaller. At least a part of the primary particles have a surface concentrated region where a percentage content of the additional element is locally increased in a surface layer part thereof. The content of the additional element in the surface concentrated region to a whole amount of the inorganic oxide is in a range from 0.06% by mass to 0.98% by mass in terms of oxide amount.
    Type: Application
    Filed: June 8, 2007
    Publication date: June 11, 2009
    Inventors: Akira Morikawa, Toshitaka Tanabe, Naoki Takahashi, Kae Yamamura, Takeru Yoshida, Akemi Sato
  • Patent number: 7541311
    Abstract: A vermiculite supported catalyst for carbon monoxide (CO) preferential oxidation (PROX) is disclosed. The CO PROX catalyst comprises at least one catalytic agent, one optional modifier agent, one carrier material, and a vermiculite support. The process for preparing the vermiculite supported catalyst in this invention includes depositing first the carrier material on a vermiculite support followed by calcination to form the carrier-containing support, and wet impregnating the catalytic agent and the optional modifier agent on the carrier-containing support followed by drying and calcination to form the CO preferential oxidation catalyst.
    Type: Grant
    Filed: August 31, 2007
    Date of Patent: June 2, 2009
    Assignee: Institute of Nuclear Energy Research
    Inventors: Chao-Yuh Chen, Ching-Tsuen Huang, Chi-Hung Liao, Ching-Tu Chang
  • Publication number: 20090131695
    Abstract: A catalyst which comprises a carrier and silver deposited on the carrier, which carrier has a surface area of at least 1.3 m2/g, a median pore diameter of more than 0.8 ?m, and a pore size distribution wherein at least 80% of the total pore volume is contained in pores with diameters in the range of from 0.1 to 10 ?m and at least 80% of the pore volume contained in the pores with diameters in the range of from 0.1 to 10 ?m is contained in pores with diameters in the range of from 0.
    Type: Application
    Filed: June 6, 2006
    Publication date: May 21, 2009
    Inventors: William Herman Gerdes, John Robert Lockemeyer, Donald James Remus, Thomas Szymanski, Randall Clayton Yeates
  • Patent number: 7528092
    Abstract: The present invention relates to a catalyst nickel, silica, alumina and magnesium, wherein the nickel to magnesium atomic ratio is 5-75. In particular the present invention relates to a catalyst comprising nickel, silica, alumina and magnesium, wherein the nickel to silicium atomic ratio (Ni/Si) is 2 to 30 the nickel to aluminum atomic ratio (Ni/Al) is 9 to 40 and the nickel to magnesium atomic ratio (Ni/Mg) is 5-75. The invention further relates to a method for preparing such a catalyst. The invention further relates to a process for hydrogenating unsaturated organic compounds.
    Type: Grant
    Filed: October 17, 2003
    Date of Patent: May 5, 2009
    Assignee: BASF Catalysts LLC
    Inventors: Pieter Hildegardus Berben, Tjalling Rekker
  • Publication number: 20090092534
    Abstract: Processes for purifying silicon tetrafluoride source gas by subjecting the source gas to one or more purification processes including: contacting the silicon tetrafluoride source gas with an ion exchange resin to remove acidic contaminants, contacting the silicon tetrafluoride source gas with a catalyst to remove carbon monoxide, by removal of carbon dioxide by use of an absorption liquid, and by removal of inert compounds by cryogenic distillation; catalysts suitable for removal of carbon monoxide from silicon tetrafluoride source gas and processes for producing such catalysts.
    Type: Application
    Filed: September 11, 2008
    Publication date: April 9, 2009
    Applicant: MEMC Electronic Materials, Inc.
    Inventors: Vithal Revankar, Jameel Ibrahim
  • Patent number: 7507844
    Abstract: A carrier and a catalyst useful for the oxidation of ethylene to ethylene oxide which uses the carrier. The carrier is composed of an inert, refractory solid support such as alpha alumina and has a surface exhibiting a plurality of nanometer scale protrusions projecting outwardly from the surface, and has a catalytically effective amount of silver thereon.
    Type: Grant
    Filed: May 9, 2005
    Date of Patent: March 24, 2009
    Assignee: SD Lizenzverwertungsgesellschaft mbH & Co. KG
    Inventor: Serguei Pak