Of Zinc Patents (Class 502/343)
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Patent number: 12145140Abstract: The present disclosure provides a honeycomb catalyst for catalytic oxidative degradation of VOCs prepared by an ultrasonic double-atomization process.Type: GrantFiled: March 22, 2024Date of Patent: November 19, 2024Assignee: CHANGZHOU UNIVERSITYInventors: Xiazhang Li, Chao Yao, Shixiang Zuo, Xuhua Ye, Fengqin Wu, Haoguan Gui, Guanghui Lu, Liang Wang, Zeyue Xu
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Patent number: 12109555Abstract: An efficient photocatalyst nanocomposite comprising reduced graphene oxide, noble metal, and a metal oxide prepared by a one-step method that utilizes date seed extract as a reducing and nanoparticle determining size agent. The photocatalyst of the invention is a more effective sunlight photocatalyst than that prepared by traditional method in the photo decomposition of organic compounds in contaminated water.Type: GrantFiled: June 11, 2024Date of Patent: October 8, 2024Assignee: Imam Abdulrahman Bin Faisal UniversityInventors: Nuhad Abdullah Alomair, Hanan Hussein Amin Mohamed
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Patent number: 12048918Abstract: An efficient photocatalyst nanocomposite comprising reduced graphene oxide, noble metal, and a metal oxide prepared by a one-step method that utilizes date seed extract as a reducing and nanoparticle determining size agent. The photocatalyst of the invention is a more effective sunlight photocatalyst than that prepared by traditional method in the photo decomposition of organic compounds in contaminated water.Type: GrantFiled: October 27, 2023Date of Patent: July 30, 2024Assignee: Imam Abdulrahman Bin Faisal UniversityInventors: Nuhad Abdullah Alomair, Hanan Hussein Amin Mohamed
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Patent number: 12036543Abstract: The present disclosure provides a preparation method of a doped ZnO catalyst. The preparation method includes the following steps: mixing a precipitant and a first solvent to form a first solution having 1 mol/L to 5 mol/L of the precipitant by concentration; mixing one of a Cu salt or a Ga salt, a Zn salt, and a second solvent to form a second solution having Cu and Zn at a molar ratio of less than 0.05:1 and Ga and Zn at a molar ratio of less than 0.1:1; subjecting the first solution and the second solution to precipitation or hydrolysis at 50° C. to 90° C. to obtain a precipitate, and washing and drying the precipitate to obtain a precursor sample; and conducting calcination on the precursor sample at 300° C. to 500° C. for 3 h to 5 h to obtain a Cu-doped ZnO catalyst or a Ga-doped ZnO catalyst.Type: GrantFiled: October 31, 2022Date of Patent: July 16, 2024Assignee: Taiyuan University of TechnologyInventors: Wei Huang, Fang Li, Qian Zhang, Penglong Jia, Yongjun Liu
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Patent number: 11878287Abstract: This invention relates to development of novel Cu-based nanocatalysts synthesized via one-pot solution combustion synthesis for CO2 hydrogenation to methanol. The novel Cu-based catalyst has exceptional activity for CO2 hydrogenation with high methanol selectivity in the reaction temperature range between 250° C.-350° C. The novel catalyst also exhibits excellent resilience to deactivation due to sintering.Type: GrantFiled: January 7, 2022Date of Patent: January 23, 2024Assignee: QATAR UNIVERSITYInventors: Sardar Ali, Dharmesh Kumar, Muftah El-Naas
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Patent number: 11866387Abstract: A process for producing methacrylic acid or a methacrylic acid ester including, producing acrolein, reacting the produced acrolein with hydrogen to produce propanal, reacting the propanal with formaldehyde to produce methacrolein, and oxidizing the methacrolein in the presence of an oxygen containing gas and optionally an alcohol, to methacrylic acid or a methacrylic acid ester.Type: GrantFiled: July 11, 2019Date of Patent: January 9, 2024Assignee: Röhm GmbHInventors: Alexander May, Steffen Krill, Marcel Treskow, Diego Carambia, Gabriel Avella
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Patent number: 11833490Abstract: An efficient photocatalyst nanocomposite comprising reduced graphene oxide, noble metal, and a metal oxide prepared by a one-step method that utilizes date seed extract as a reducing and nanoparticle determining size agent. The photocatalyst of the invention is a more effective sunlight photocatalyst than that prepared by traditional method in the photo decomposition of organic compounds in contaminated water.Type: GrantFiled: August 16, 2023Date of Patent: December 5, 2023Assignee: Imam Abdulrahman Bin Faisal UniversityInventors: Nuhad Abdullah Alomair, Hanan Hussein Amin Mohamed
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Patent number: 11834385Abstract: The invention relates to novel methods for preparing N-methyl-p-toluidine for the use thereof as additive for aviation fuel, and to specific catalysts for these methods.Type: GrantFiled: May 28, 2020Date of Patent: December 5, 2023Assignee: LANXESS CorporationInventors: Martina Gerdinand, Rainer Dost, Ralf Krahwinkel, Hans-Jurgen Quella, Daniel Ullrich, Patrick Kurr
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Patent number: 11827595Abstract: A process for direct esterification of an alkyl aldehyde with an alkyl alcohol to produce an alkyl ester is disclosed. The process comprises reacting an alkyl aldehyde with an alkyl alcohol in the presence of an Au/TiOa catalyst, a base and an enal or oxygen to form an ester and an aldehyde. The process avoids liberation of water and avoids the step of oxidation of the alkyl aldehyde to an alkyl acid.Type: GrantFiled: November 12, 2019Date of Patent: November 28, 2023Assignee: Eastman Chemical CompanyInventors: William Christopher Ketchie, Sumit Chakraborty, Leslie Sharon Depew
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Patent number: 11779907Abstract: An efficient photocatalyst nanocomposite comprising reduced graphene oxide, noble metal, and a metal oxide prepared by a one-step method that utilizes date seed extract as a reducing and nanoparticle determining size agent. The photocatalyst of the invention is a more effective sunlight photocatalyst than that prepared by traditional method in the photo decomposition of organic compounds in contaminated water.Type: GrantFiled: May 17, 2023Date of Patent: October 10, 2023Assignee: Imam Abdulrahman Bin Faisal UniversityInventors: Nuhad Abdullah Alomair, Hanan Hussein Amin Mohamed
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Patent number: 11745157Abstract: A process provides for minimizing an amount of fuel gas utilized in an absorber off-gas incinerator and better control of emissions. The process provides for less temperature deviations in the absorber off-gas incinerator firebox and for less deviation in an amount of oxygen in the absorber off-gas incinerator stack gas.Type: GrantFiled: May 4, 2017Date of Patent: September 5, 2023Assignee: INEOS EUROPE AGInventors: Manoj Shrikant Shouche, Timothy Robert McDonel, Jay Robert Couch
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Patent number: 11650203Abstract: Disclosed are a one-pot biosensor and an immunoassay method using the same. The one-pot biosensor includes a photocatalyst substrate deposited with metal nanoparticles; and a reaction pad which is disposed on an upper surface of the photocatalyst substrate and includes a first binding material-fluorescent material complex specifically binding to a molecule to be detected, and the immunoassay method using the same. The one-pot biosensor may detect a target by once solution injection and has a size enough to be portable. Accordingly, since the one-pot biosensor can detect the target by only once solution injection without a washing step, because of a sensor platform capable of being easily used by an individual other than a diagnostic expert, it is predicted to be positioned as a means capable of confirming the health condition of the individual without seeing the doctor, such as a pregnancy diagnostic kit which has been currently commercialized.Type: GrantFiled: June 29, 2021Date of Patent: May 16, 2023Assignee: GIST (Gwangju Institute of Science and Technology)Inventors: Min Gon Kim, Ki Hyeun Kim, Eun Jung Jo, Dong Gu Hong
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Patent number: 11612673Abstract: In various embodiments, an air purifier capable of destroying and deactivating airborne contaminants such as SARS-CoV-2 is described. The air purifier comprises a photocatalytic system comprising at least one photoactivated semiconductor photocatalyst and a lamp configured to irradiate and excite the at least one photoactivated semiconductor photocatalyst to generate reductive and/or oxidative reactive species from oxygen and/or water on the photocatalyst surface. In various embodiments, the photocatalytic system comprises a stack of PCB cards, each card having a photocatalytic layer disposed thereon, or a 3-dimensionally ordered macroporous (3-DOM) structure comprising an open cell lattice.Type: GrantFiled: August 31, 2020Date of Patent: March 28, 2023Assignee: PROMETHIUM LIMITEDInventors: Xavier Isaiah Morgan-Lange, Devon Paul Scheg, Harry Larson
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Patent number: 11603341Abstract: A catalytic composition is disclosed, which exhibits an X-ray amorphous oxide with a spinel formula, and crystals of ZnO, CuO, and at least one Group VIB metal oxide, and preferably, at least one acidic oxide of B, P. or Si, as well. The composition is useful in oxidative processes for removing sulfur from gaseous hydrocarbons.Type: GrantFiled: January 4, 2021Date of Patent: March 14, 2023Assignees: SAUDI ARABIAN OIL COMPANY, BORESKOV INSTITUTE OF CATALYSISInventors: Omer Refa Koseoglu, Yaming Luisa Jin, Zinfer Ismagilov, Svetlana Letizia Yashnik, Anton Salnikov, Mikhail Kerzhentsev, Valentin Parmon
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Patent number: 11446641Abstract: An efficient catalyst for the synthesis of methanol by catalytic hydrogenation of carbon dioxide is provided. A process for the preparation of the catalyst by self-combustion of a gel and a process for the synthesis of methanol by catalytic hydrogenation of carbon dioxide are also presented. The catalyst has the following formula (Cu)x(ZnO)y(ZrO2)z supported on mesoporous silica.Type: GrantFiled: February 7, 2019Date of Patent: September 20, 2022Assignee: SOTACARBO—SOCIETA TECHNOLOGIE AVANZATE LOW CARBON S.P.A.Inventors: Mauro Mureddu, Francesca Ferrara, Alberto Pettinau
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Patent number: 10639615Abstract: The present invention discloses a water oxidation catalyst having composition ZnxCo(3-x)O4 for splitting water into oxygen and hydrogen gas and a process for the preparation thereof.Type: GrantFiled: October 5, 2017Date of Patent: May 5, 2020Assignee: COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESEARCHInventors: Rani Mohan Ramsundar, Pattayil Alias Joy
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Patent number: 10030201Abstract: The present development is a catalyst composition, comprising zinc oxide nanowires having one or more catalytically-active metal particles attached to a surface of the zinc oxide nanowires. The catalytically-active metal particles are comprised of a metal selected from the group consisting of nickel, cobalt, molybdenum, tungsten, copper, and platinum. The present development further discloses a method to prepare the catalyst composition, and use of the catalyst composition for desulfurization.Type: GrantFiled: July 15, 2013Date of Patent: July 24, 2018Assignee: University of Louisville Research FoundationInventors: Mahendra Sunkara, Franz Petzold, Mayank Gupta, Dania Alvarez Fonseca
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Patent number: 9029286Abstract: A method of making a metal oxide nanoparticle comprising contacting an aqueous solution of a metal salt with an oxidant. The method is safe, environmentally benign, and uses readily available precursors. The size of the nanoparticles, which can be as small as 1 nm or smaller, can be controlled by selecting appropriate conditions. The method is compatible with biologically derived scaffolds, such as virus particles chosen to bind a desired material. The resulting nanoparticles can be porous and provide advantageous properties as a catalyst.Type: GrantFiled: April 29, 2013Date of Patent: May 12, 2015Assignee: Massachusettes Institute of TechnologyInventors: Brian Neltner, Angela M. Belcher
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Patent number: 9024090Abstract: A catalyst composition for converting ethanol to higher alcohols, such as butanol, is disclosed. The catalyst composition comprises at least one alkali metal, at least a second metal and a support. The second metal is selected from the group consisting of palladium, platinum, copper, nickel, and cobalt. The support is selected from the group consisting of Al2O3, ZrO2, MgO, TiO2, zeolite, ZnO, and a mixture thereof.Type: GrantFiled: December 19, 2012Date of Patent: May 5, 2015Assignee: Celanese International CorporationInventors: Cheng Zhang, Kenneth Balliet, Victor J. Johnston
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Publication number: 20150111723Abstract: A process for biomass catalytic cracking is disclosed herein. More specifically, the process is in presence of is a mixed metal oxide catalyst represented by the formula (X1O).(X2O)a.(X3YbO4) wherein X1, X2 and X3 are alkaline earth elements selected from the group of Mg, Ca, Be, Ba, and mixture thereof, and Y is a metal selected from the group of Al, Mn, Fe, Co, Ni, Cr, Ga, B, La, P and mixture thereof, wherein the catalyst is formed by calcining at least one compound comprising at least one alkaline earth element and a metal element.Type: ApplicationFiled: December 4, 2014Publication date: April 23, 2015Inventors: Robert Bartek, Michael Brady, Dennis Stamires
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Patent number: 8999881Abstract: The present disclosure relates to a Cu/Zn/Al catalyst and a method for preparing same. More particularly, the present disclosure relates to a Cu/Zn/Al catalyst including copper particles having high surface area and thus having excellent activity, which is prepared by: preparing a metal precursor solution by dissolving a copper precursor, a zinc precursor and an aluminum precursor in an organic solvent; mixing an aqueous basic solution with the metal precursor solution and precipitating metal particles; and preparing a Cu/Zn/Al catalyst by collecting and sintering the precipitated metal particles, and a method for preparing same.Type: GrantFiled: October 31, 2013Date of Patent: April 7, 2015Assignee: Korea Institute of Science and TechnologyInventors: Adeline Budiman, Jeong-Myeong Ha, Jae Wook Choi, Young Hyun Yoon, Sung Min Kim, Gi Seok Yang, Dong Jin Suh
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Patent number: 8961681Abstract: A process for the preparation of nano zinc oxide particles is disclosed. The process comprises of dissolving a zinc metal precursor in a solvent to obtain a first solution and dissolving a base in an alcohol to obtain an alkali solution. The alkali solution is then added to the first solution over a predetermined period of time to obtain nano zinc oxide particles in solution.Type: GrantFiled: January 7, 2009Date of Patent: February 24, 2015Assignee: TATA Chemicals LimitedInventor: Sachin Parashar
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Publication number: 20150050494Abstract: A multi-walled titanium-based nanotube array containing metal or non-metal dopants is formed, in which the dopants are in the form of ions, compounds, clusters and particles located on at least one of a surface, inter-wall space and core of the nanotube. The structure can include multiple dopants, in the form of metal or non-metal ions, compounds, clusters or particles. The dopants can be located on one or more of on the surface of the nanotube, the inter-wall space (interlayer) of the nanotube and the core of the nanotube. The nanotubes may be formed by providing a titanium precursor, converting the titanium precursor into titanium-based layered materials to form titanium-based nanosheets, and transforming the titanium-based nanosheets to multi-walled titanium-based nanotubes.Type: ApplicationFiled: March 19, 2013Publication date: February 19, 2015Applicant: The Hong Kong University of Science and TechnologyInventors: King Lun Yeung, Shammi Akter Ferdousi, Wei Han
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Patent number: 8895764Abstract: A method of forming a biodiesel product and a heterogeneous catalyst system used to form said product that has a high tolerance for the presence of water and free fatty acids (FFA) in the oil feedstock is disclosed. This catalyst system may simultaneously catalyze both the esterification of FAA and the transesterification of triglycerides present in the oil feedstock. The catalyst system is comprised of a mixture of zinc oxide and a second metal oxide. The zinc oxide includes a mixture of amorphous zinc oxide and zinc oxide nanocrystals, the zinc nanocrystals having a mean grain size between about 20 and 80 nanometers with at least one of the nanocrystals including a mesopore having a diameter of about 5 to 15 nanometers. Preferably, the second metal oxide is a lanthanum oxide, the lanthanum oxide being selected as one from the group of La2CO5, LaOOH, and combinations or mixtures thereof.Type: GrantFiled: June 16, 2009Date of Patent: November 25, 2014Assignee: Wayne State UniversityInventors: Shuli Yan, Steven O. Salley, K. Y. Simon Ng
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Patent number: 8889078Abstract: A porous oxide catalyst includes porous oxide, and an oxygen vacancy-inducing metal which induces an oxygen vacancy in a lattice structure of a porous metal oxide.Type: GrantFiled: March 15, 2011Date of Patent: November 18, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Sang-min Ji, Hyun-chul Lee, Doo-hwan Lee, Seon-ah Jin
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Patent number: 8877069Abstract: A system is provided that substantially increases the efficiency of CO2 capture and removal by positioning a catalyst within an optimal distance from the air-liquid interface. The catalyst is positioned within the layer determined to be the highest concentration of carbon dioxide. A hydrophobic tether is attached to the catalyst and the hydrophobic tether modulates the position of the catalyst within the liquid layer containing the highest concentration of carbon dioxide.Type: GrantFiled: February 8, 2012Date of Patent: November 4, 2014Assignee: Lawrence Livermore National Security, LLC.Inventors: Carlos A. Valdez, Joe H. Satcher, Jr., Roger D. Aines, Sergio E. Wong, Sarah E. Baker, Felice C. Lightstone, Joshuah K. Stolaroff
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Publication number: 20140316167Abstract: Provided by the present invention is a method for producing an alkanediol, such as 1,5-pentanediol, with a high reaction selectivity thereto by reacting a cyclic ether group-containing methanol such as tetrahydrofurfuryl alcohol by using a non-chromium catalyst not containing chromium atom. More specifically, the method is to produce an alkanediol having hydroxy groups at both molecular terminals shown by the formula (2), includes reacting a cyclic ether group-containing methanol shown by the formula (1) with hydrogen in the presence of a metal catalyst which contains copper atom, at least one co-existing atom selected from the group consisting of elements of the third to the sixth periods of the II to XIV groups (excluding chromium) in the periodical table and lanthanide elements.Type: ApplicationFiled: November 19, 2012Publication date: October 23, 2014Applicant: UBE INDUSTRIES, LTDInventors: Yasutaka Yoshida, Kenji Hirotsu, Takashi Doi, Kouichi Kashiwagi
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Publication number: 20140296056Abstract: A fibrous photo-catalyst includes titanium oxide, zinc oxide, and a transition metal. A molar ratio of the transition metal and the titanium oxide ranges from 0.1:100 to 8:100, and a molar ratio of the zinc oxide and the titanium oxide ranges from 5:100 to 50:100.Type: ApplicationFiled: March 26, 2014Publication date: October 2, 2014Inventor: Yu-Hsun Nien
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Patent number: 8845998Abstract: A catalyst has a long life span and efficiently separates hydrogen from water. A first metal element (Ni, Pd, Pt) for cutting the combination of hydrogen and oxygen and a second metal element (Cr, Mo, W, Fe) for helping the function of the first metal element are melted in alkaline metal hydroxide or alkaline earth metal hydroxide to make a mixture heated at a temperature above the melting point of the hydroxide to eject fine particles from the liquid surface, bringing steam into contact with the fine particles. Instead of this, a mixture of alkaline metal hydroxide and metal oxide is heated at a temperature above the melting point of the alkaline metal hydroxide to make metal compound in which at least two kinds of metal elements are melted, and fine particles are ejected from the surface of the metal compound to be brought into contact with steam.Type: GrantFiled: January 6, 2010Date of Patent: September 30, 2014Inventor: Yasuo Ishikawa
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Publication number: 20140284521Abstract: This invention provides a CO2 desorption catalyst that has an excellent CO2 desorption activity and that can be used to replace metal filler.Type: ApplicationFiled: November 22, 2012Publication date: September 25, 2014Applicant: THE KANSAI ELECTRIC POWER CO., INC.Inventors: Hiroshi Deguchi, Tsunenori Watanabe, Yasuyuki Yagi
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Publication number: 20140274679Abstract: There is presented a catalyst support that has a substantially spherical body, penetrated with a plurality of tunnels extending from a first end on a surface location of the catalyst body to another end on another surface location of the body. The support is made of alumina or like composition. The catalyst body has a total surface that includes the outer surface and surfaces within the tunnels. This total surface is adapted to receive catalyst composition. The catalyst support is adapted to being packed in a reactor and provides lower packed bed pressure drop.Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Applicant: UNICAT CATALYST TECHNOLOGIES, INC.Inventor: Mani Erfan
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Publication number: 20140256966Abstract: A method for stabilizing a metal or metal-containing particle supported on a surface is described, along with the resulting composition of matter. The method includes the steps of depositing upon the surface a protective thin film of a material of sufficient thickness to overcoat the metal or metal-containing particle and the surface, thereby yielding an armored surface; and then calcining the armored surface for a time and at a temperature sufficient to form channels in the protective thin film, wherein the channels so formed expose a portion of the metal- or metal-containing particle to the surrounding environment. Also described is a method of performing a heterogeneous catalytic reaction using the stabilized, supported catalyst.Type: ApplicationFiled: March 8, 2013Publication date: September 11, 2014Applicant: Wisconsin Alumni Research FoundationInventors: James A. Dumesic, Brandon J. O'Neill
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Patent number: 8802044Abstract: The invention relates to a filtration structure, for filtering a gas coming from a diesel engine, which is laden with gaseous pollutants of the nitrogen oxide NOx type and with solid particles, of the particulate filter type, said filtration structure being characterized in that it includes a catalytic system comprising at least one noble metal or transition metal suitable for reducing the NOx and a support material, in which said support material comprises or is made of a zirconium oxide partially substituted with a trivalent cation M3+ or with a divalent cation M?2+, said zirconium oxide being in a reduced, oxygen-sub-stoichiometric, state.Type: GrantFiled: December 16, 2009Date of Patent: August 12, 2014Assignees: Saint-Gobain Centre de Recherches et d'Etudes Europeen, Centre National de la Recherche ScientifiqueInventors: Philippe Vernoux, Abdelkader Hadjar, Agnes Princivalle, Christian Guizard
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Patent number: 8785343Abstract: This invention relates to a mesoporous carbon supported copper based catalyst comprising mesoporous carbon, a copper component and an auxiliary element supported on said mesoporous carbon, production and use thereof. The catalyst is cheap in cost, friendly to the environment, and satisfactory in high temperature resistance to sintering, with a highly improved and a relatively stable catalytic activity.Type: GrantFiled: August 27, 2012Date of Patent: July 22, 2014Assignees: China Petroleum & Chemical Corp., Sinopec Yangzi Petrochemical Co., Ltd.Inventors: Jingwei Liu, Zezhuang Li, Shaohui Chen, Aiwu Yang, Jiye Bai, Lijuan Liu, Yingwu Wang
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Patent number: 8785699Abstract: Systems, catalysts, and methods are provided for transforming carbon based material into synthetic mixed alcohol fuel.Type: GrantFiled: April 19, 2013Date of Patent: July 22, 2014Assignee: Pioneer Energy, Inc.Inventors: Emily Bostwick White, Cherie Wilson, Mark Berggren, Robert M. Zubrin
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Publication number: 20140174905Abstract: A system and method for splitting water to produce hydrogen and oxygen employing sunlight energy are disclosed. Hydrogen and oxygen may then be stored for later use as fuels. The system and method use inorganic capping agents that cap the surface of semiconductor nanocrystals to form photocatalytic capped colloidal nanocrystals, which may be deposited on a substrate and treated to form a photoactive material. The photoactive material may be employed in the system to harvest sunlight and produce energy necessary for water splitting. The system may also include elements necessary to collect, transfer and store hydrogen and oxygen, for subsequent transformation into electrical energy.Type: ApplicationFiled: December 20, 2012Publication date: June 26, 2014Applicant: SUNPOWER TECHNOLOGIES LLCInventor: DANIEL LANDRY
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Patent number: 8734743Abstract: Described is a nitrogen oxide storage catalyst comprising: a substrate; a first washcoat layer provided on the substrate, the first washcoat layer comprising a nitrogen oxide storage material, a second washcoat layer provided on the first washcoat layer, the second washcoat layer comprising a hydrocarbon trap material, wherein the hydrocarbon trap material comprises substantially no element or compound in a state in which it is capable of catalyzing selective catalytic reduction, preferably wherein the hydrocarbon trap material comprises substantially no element or compound in a state in which it is capable of catalyzing a reaction wherein nitrogen oxide is reduced to N2, said catalyst further comprising a nitrogen oxide conversion material which is either comprised in the second washcoat layer and/or in a washcoat layer provided between the first washcoat layer and the second washcoat layer.Type: GrantFiled: June 9, 2011Date of Patent: May 27, 2014Assignee: BASF SEInventors: Torsten W. Müller-Stach, Susanne Stiebels, Edith Schneider, Torsten Neubauer
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Publication number: 20140141968Abstract: The disclosure provides a photocatalyst material and a method for fabricating the same. The photocatalyst material includes a zinc oxide material doped with metal, wherein the zinc oxide material has a lattice structure including a plurality of defects.Type: ApplicationFiled: November 1, 2013Publication date: May 22, 2014Applicant: Industrial Technology Research InstituteInventors: Jyh Ming WU, Lu-Chih WANG, Hong-Ching LIN, Wei-Tsung KAO, Hsin-Hsien YEH
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Publication number: 20140135210Abstract: The present disclosure relates to a Cu/Zn/Al catalyst and a method for preparing same. More particularly, the present disclosure relates to a Cu/Zn/Al catalyst including copper particles having high surface area and thus having excellent activity, which is prepared by: preparing a metal precursor solution by dissolving a copper precursor, a zinc precursor and an aluminum precursor in an organic solvent; mixing an aqueous basic solution with the metal precursor solution and precipitating metal particles; and preparing a Cu/Zn/Al catalyst by collecting and sintering the precipitated metal particles, and a method for preparing same.Type: ApplicationFiled: October 31, 2013Publication date: May 15, 2014Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Adeline BUDIMAN, Jeong-Myeong HA, Jae Wook CHOI, Young Hyun YOON, Sung Min KIM, Gi Seok YANG, Dong Jin SUH
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Publication number: 20140127414Abstract: Surface treatment agent with high photocatalytic and sanitary effects based on TiO2 nanoparticles comprising 10 to 500 g of TiO2nanoparticles per 1 liter of water, and binding ingredient A, which is an inorganic binder selected from the group comprising ZnO, MgO, CaO, Ca(OH)2, Mg(OH)2, CaCO3, MgCO3, Na2CO3, K2CO3 in the amount of 0.1 to 10% by weight related to the N weight of TiO2. Agent for treatment of surfaces for application on surfaces, which comprise a minimum of 50% of substances selected from the group formed by CaCO3, MgCO3 ZnO, MgO, CaO, Ca(OH)2, Mg(OH)2 or their mixtures, where the agent contains 10 to 500 g of TiO2 nanoparticles per 1 liter of water, and optionally contains a minimum of 0.1 wt % H2CO3 related to the weight of TiO2.Type: ApplicationFiled: June 21, 2012Publication date: May 8, 2014Inventors: Jan Prochazka, SR., Jan Prochazka, JR.
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Patent number: 8716165Abstract: A method for providing a catalyst on a substrate is disclosed comprising providing a first washcoat comprising a soluble washcoat salt species, a polar organic solvent, and an insoluble particulate material, contacting the first washcoat with a substrate to form a coated substrate, and then contacting the coated substrate with a second washcoat comprising an oxide or an oxide-supported catalyst to physisorb, chemisorb, bond, or otherwise adhere the oxide or the oxide-supported catalyst to the coated substrate. Also disclosed is a catalyst on a substrate comprising: a substrate; an anchor layer comprising a soluble washcoat salt species, a polar organic solvent, and an insoluble particulate material; and a second layer comprises an oxide or an oxide-supported catalyst. The catalyst on a substrate can be in either green or fired form.Type: GrantFiled: April 30, 2008Date of Patent: May 6, 2014Assignee: Corning IncorporatedInventor: William Peter Addiego
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Patent number: 8697597Abstract: A method and system for the reduction of pollutant NOx gases from automobile exhaust, as well as a method of reforming hydrocarbons, using a self-sustaining catalyst comprising an ion conductive support, a dispersed cathodic phase, a dispersed anodic phase, and a dispersed sacrificial phase, and a method of forming the self-sustaining catalyst.Type: GrantFiled: April 6, 2010Date of Patent: April 15, 2014Assignee: University of MiamiInventor: Xiangyang Zhou
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Patent number: 8685877Abstract: A catalyst particle for use in growth of elongated nanostructures, such as e.g. nanowires, is provided. The catalyst particle comprises a catalyst compound for catalyzing growth of an elongated nanostructure comprising a nanostructure material without substantially dissolving in the nanostructure material and at least one dopant element for doping the elongated nanostructure during growth by substantially completely dissolving in the nanostructure material. A method for forming an elongated nanostructure, e.g. nanowire, on a substrate using the catalyst particle is also provided. The method allows controlling dopant concentration in the elongated nanostructures, e.g. nanowires, and allows elongated nanostructures with a low dopant concentration of lower than 1017 atoms/cm3 to be obtained.Type: GrantFiled: December 19, 2007Date of Patent: April 1, 2014Assignee: IMECInventors: Francesca Iacopi, Philippe M. Vereecken
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Publication number: 20140080698Abstract: A method of making a metal oxide nanoparticle comprising contacting an aqueous solution of a metal salt with an oxidant. The method is safe, environmentally benign, and uses readily available precursors. The size of the nanoparticles, which can be as small as 1 nm or smaller, can be controlled by selecting appropriate conditions. The method is compatible with biologically derived scaffolds, such as virus particles chosen to bind a desired material. The resulting nanoparticles can be porous and provide advantageous properties as a catalyst.Type: ApplicationFiled: April 29, 2013Publication date: March 20, 2014Applicant: Massachusetts Institute of TechnologyInventor: Massachusetts Institute of Technology
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Publication number: 20140073828Abstract: A catalyst for converting methane to aromatic hydrocarbons is described herein. The catalyst comprises an active metal or a compound thereof, zinc or a compound thereof and an inorganic oxide support wherein the active metal is added to the support as a metal oxalate. A method of making the catalyst and a method of using the catalyst are also described.Type: ApplicationFiled: January 24, 2012Publication date: March 13, 2014Inventors: Armin Lange De Oliveira, Larry Lanier Marshall, Peter Tanev Tanev
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Patent number: 8664146Abstract: A bulk metal oxide catalyst composition of the general formula (X)b(M)c(Z)d(O)e??(I) wherein X represents at least one non-noble Group VIII metal; M represents at least one non-noble Group VIb metal; Z represents one or more elements selected from aluminum, silicon, magnesium, titanium, zirconium, boron, and zinc; one of b and c is the integer 1; and d and e and the other of b and c each are a number greater than 0 such that the molar ratio of b:c is in the range of from 0.5:1 to 5:1, the molar ratio of d:c is in the range of from 0.2:1 to 50:1, and the molar ratio of e:c is in the range of from 3.7:1 to 108:1; is prepared by controlled (co)precipitation of component metal compounds, refractory oxide material, and alkali compound in protic liquid. Resulting compositions find use in hydrotreatment processes involving particularly hydrodesulphurization and hydrodenitrification.Type: GrantFiled: November 17, 2011Date of Patent: March 4, 2014Assignee: Shell Oil CompanyInventors: Laszlo Domokos, Hermanus Jongkind, Johannes Anthonius Robert Van Veen
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Patent number: 8648005Abstract: The present invention provides a method of preparing the copper-containing hydrogenation catalyst having high activity by liquid phase reduction without decreasing purity of the solvent and a method for efficiently producing an alcohol. The present invention provides the method of preparing the copper-containing hydrogenation catalyst, including reducing a molded precursor of the copper-containing hydrogenation catalyst by supplying hydrogen gas or a mixture of hydrogen gas with an inert gas at a temperature of 50 to 150° C. in the presence of a solvent to obtain the copper-containing hydrogenation catalyst, wherein the reduction is conducted at an average reduction velocity of the copper-containing hydrogenation catalyst of not more than 3.0% by weight/hour.Type: GrantFiled: September 10, 2009Date of Patent: February 11, 2014Assignee: Kao CorporationInventors: Toru Sakamoto, Shoji Hasegawa
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Patent number: 8623220Abstract: A simple, room-temperature method of producing CuO-doped zinc oxide nanoparticles was established by reacting zinc nitrate hexahydrate, copper nitrate trihydrate and cyclohexylamine (CHA) at room temperature. These nanoparticles may be used for photocatalytic degradation of cyanide in aqueous solutions. The degradation of cyanide is effective because electrons transfer from the p-type copper oxide to the n-type zinc oxide.Type: GrantFiled: July 13, 2012Date of Patent: January 7, 2014Assignee: King Abdulaziz City for Science and Technology (KACST)Inventors: Abdulaziz A Bagabas, Ahmed S. Alshammari, Mohamed F. Aboud, Mohamed Mokhtar Mohamed Mostafa, Emad Addurihem, Zeid A. Al-Othman, Musaed A Alangari
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Patent number: 8614161Abstract: A CO2 reforming catalyst composition includes a hydroxyl group-containing porous oxide, and a composite porous catalyst supported by a porous supporter. The composite porous catalyst includes a catalyst metal.Type: GrantFiled: May 16, 2011Date of Patent: December 24, 2013Assignee: Samsung Electronics Co., Ltd.Inventors: Seung Jae Lee, InHyuk Son, Chan Ho Pak, Hyun Chul Lee, Jeong Kuk Shon, Young Gil Jo
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Patent number: 8609575Abstract: A catalyst of one or more complex oxides having a nominal composition as set out in formula (1): AxB1-y-zMyPzOn (1) wherein A is selected from one or more group III elements including the lanthanide elements or one or more divalent or monovalent cations; B is selected from one or more elements with atomic number 22 to 24, 40 to 42 and 72 to 75; M is selected from one or more elements with atomic number 25 to 30; P is selected from one or more elements with atomic number 44 to 50 and 76 to 83; x is defined as a number where 0<x?1; y is defined as a number where 0?y<0.5; and z is defined as a number where 0<z<0.2.Type: GrantFiled: April 12, 2007Date of Patent: December 17, 2013Assignee: Very Small Particle Company LimitedInventors: Peter Cade Talbot, Jose Antonio Alarco, Geoffrey Alan Edwards