Abstract: There is provided a method for production of a conjugated diene from a monoolefin having four or more carbon atoms by a fluidized bed reaction. The method for production of a conjugated diolefin includes bringing a catalyst in which an oxide is supported on a carrier into contact with a monoolefin having four or more carbon atoms in a fluidized bed reactor in which the catalyst and oxygen are present, wherein the method satisfies the following (1) to (3): (1) the catalyst contains Mo, Bi, and Fe; (2) a reaction temperature is in the range of 300 to 420° C.; and (3) an oxygen concentration in a reactor outlet gas is in the range of 0.05 to 3.0% by volume.

Abstract: Systems, catalysts, and methods are provided for transforming carbon based material into synthetic mixed alcohol fuel.

Abstract: Catalysts, systems and methods for abating emissions in an exhaust stream are provided. Systems comprising a transition metal oxide stabilized oxygen storage catalyst are described. The emissions treatment system is advantageously used for the treatment of exhaust streams from lean burn engines including diesel engines and lean burn gasoline engines.

Abstract: Provided is a liquid combustion catalyst composition comprising an ionized metal compound, and more particularly, to a liquid combustion catalyst composition comprising an ionized metal compound, in which the ionic metal compound is added to fuel burning in a combustion engine to quickly achieve a chemical thermal equilibrium condition required for the combustion of fuel such as hydrocarbon fuel, fossil fuel and biomass, and to optimize the amount of air which contains oxygen required for the equilibrium condition in terms of chemical equivalence, thereby improving thermal efficiency and the efficiency of the combustion engine so that fuel consumption for a heat source can be reduced, and optimizing the combustion performed by the combustion device by controlling the generation of sludge, clinker and fouling which may be generated due to an inorganic substance so that a combustion rate per unit area and the productivity of the combustion device can be improved.

Abstract: A process is described for producing a powder batch comprises a plurality of particles, wherein the particles include (a) a first catalytically active component comprising at least one transition metal or a compound thereof; (b) a second component different from said first component and capable of removing oxygen from, or releasing oxygen to, an exhaust gas stream; and (c) a third component different from said first and second components and comprising a refractory support. The process comprises providing a precursor medium comprising a liquid vehicle and a precursor to al least one of said components (a) to (c) and heating droplets of said precursor medium carried in a gas stream to remove at least part of the liquid vehicle and chemically convert said precursor to said at least one component.

Abstract: Disclosed herein are photocatalyst powder and a production method thereof, and by having photocatalyst particles corn binded without reduction of a specific surface area, the reduction of the specific surface area is nearly none while the pores are developed, as well as the absorption rate with respect to light is superior, the method of producing photocatalyst powder includes forming initial photocatalyst powder by molding nanoparticles of photocatalyst substance into a certain shape through extrusion, and splitting the initial photocatalyst powder into a plurality of photocatalyst powder by injecting the initial photocatalyst powder into a predetermined splitting solution, the initial photocatalyst powder being split into the plurality of photocatalyst powder by the predetermined spliting solution.

Abstract: A simple, room-temperature method of producing CuO-doped zinc oxide nanoparticles was established by reacting zinc nitrate hexahydrate, copper nitrate trihydrate and cyclohexylamine (CHA) at room temperature. These nanoparticles may be used for photocatalytic degradation of cyanide in aqueous solutions. The degradation of cyanide is effective because electrons transfer from the p-type copper oxide to the n-type zinc oxide.

Abstract: The present invention is directed to a catalyst suitable for catalyzing a Fischer-Tropsch reaction, said catalyst comprising cobalt metal supported on zinc-oxide and an amount of zirconium(IV)oxide and/or aluminum oxide of between 0.5 and 2.5 wt. % calculated as metal, based on the weight of the calcined catalyst.

Abstract: This invention relates to the synthesis of polycarbonates prepared from carbonate monomers derived from the biomass in the presence of a system comprising an organometallic transfer agent and alcohol. It also relates to the polymers resulting from these cyclic compounds.

Abstract: Systems, catalysts, and methods are provided for transforming carbon based material into synthetic mixed alcohol fuel.

Abstract: A method for preparing a neutral, stable and transparent photocatalytic titanium dioxide sol is provided. The method comprises (1) contacting an alkaline titanium dioxide sol with an alkaline peptizing agent to provide a peptized alkaline titanium dioxide sol; (2) neutralizing the peptized alkaline titanium dioxide sol; and (3) obtaining or collecting the neutral, stable and transparent photocatalytic titanium dioxide sol. The titanium dioxide sol is stable and transparent over a range of pH of about 7.0 to about 9.5. The titanium dioxide sol may include crystallites of titanium dioxide having an average particle size of less than about 10 nm with at least 90% of the crystallites being in the anatase form.

Abstract: Novel catalytic materials and methods for producing the same are shown and described. The present disclosure provides catalytic materials formed from producing an alloy of an oxophilic metal and a metal having electro-oxidative activity using spray pyrolysis. The present disclosure further provides methods and mechanisms for both detecting and removing hydrazine from a system.

Abstract: The present invention is directed to a granulate having photocatalytic activity, comprising particles of an inorganic particulate material coated with a photocatalytically active compound for introducing photocatalytic activity into or on building materials. The invention is further related to the manufacture of such a granulate and its use into or on building materials such as cement, concrete, gypsum and/or limestone and water-based coatings or paints for reducing an accumulation and growth of microorganisms and environmental polluting substances on these materials and thus reducing the tendency of fouling, while the brilliance of the color is maintained and the quality of the air is improved.

Abstract: A catalyst for hydrogenating aldehydes to alcohols includes a combination of copper oxide and zinc oxide and promoters including one or more alkaline earth metal promoters and/or one or more transition metal promoters. The promoters may be combined with copper oxide and zinc oxide after formation of a copper/zinc precursor material.

Abstract: It is provided that the catalyst shows a high activity in an ammonia decomposition reaction and can efficiently decompose ammonia into hydrogen and nitrogen. The catalyst for decomposing ammonia of the present invention comprises at least one element (component (A)) selected from the elements of groups 6 to 10 of the long-form periodic table, and an oxide and/or complex oxide of at least one element (component (B)) selected from the elements of groups 2 to 5 and groups 12 to 15 of the long-form periodic table, wherein the calculated specific surface area (S2) of the component (A) is 20 m2/g or larger, and the ratio (S2/S1) of the calculated specific surface area (S2) of the component (A) to the specific surface area (S1) of the catalyst per se is 0.15 to 0.85.

Abstract: A supported oxidation catalyst includes a support having a metal oxide or metal salt, and mixed metal particles thereon. The mixed metal particles include first particles including a palladium compound, and second particles including a precious metal group (PMG) metal or PMG metal compound, wherein the PMG metal is not palladium. The oxidation catalyst may also be used as a gas sensor.

Abstract: Isopropyl alcohol is a very useful chemical that is widely used in the industry as a solvent. Economical and easy process to make ispopropyl alcohol using novel composite catalyst is described in the instant application. Production of isopropyl alcohol (IPA) from dimehtyl ketone (DMK) and hydrogen (H2) in gas-phase using a ruthenium nano-particle-supported on activated charcoal/nano-zinc oxide composite catalyst is described. Gas phase production of isopropyl alcohol using DMK and hydrogen is also described using optimal time on stream, temperature, catalyst ratio and DMK/H2 ratio. Ruthenium nano-zinc oxide composite catalyst is formulated using different ratios of ruthenium activated charcoal and n-ZnO is described. CAT-IV is shown to be the best performer for the efficient production of isopropyl alcohol.

Abstract: A process for producing dry alcohol (including ethanol) that comprises at least one stage wherein a gaseous feedstock, which includes alcohol and water, is contacted with carbon monoxide in the presence of a water-gas shift catalyst, at a temperature sufficiently high so that carbon monoxide and water are consumed and carbon dioxide and hydrogen are produced, thereby removing a portion of the water. The process may include multiple stages; the dry alcohol produced contains 99.5 wt. % or greater of alcohol and 0.5 wt. % or less of water.

Abstract: A catalyst composition, a method of preparation of catalyst composition, a catalytic reduction system including the catalyst composition and a system using the catalytic reduction system are provided. The catalyst composition includes a templated amorphous metal oxide substrate, a catalyst material, and a sulfur scavenger material. The catalyst material includes a catalyst metal disposed on the templated metal oxide substrate and the sulfur scavenger includes an alkali metal.

Abstract: Provided is a photocatalytic composition comprising zinc (Zn) doped titanium dioxide (TiO2) nanoparticles, wherein the ratio of titanium dioxide nanoparticles to zinc is from about 5 to about 150. The photocatalytic composition absorbs electromagnetic radiation in a wavelength range from about 200 nm to about 500 nm, and the absorbance of light of wavelengths longer than about 450 nm is less than 50% the absorbance of light of wavelengths shorter than about 350 nm. Further provided is a method for treating or preventing microbial diseases and infestations in a plant and a method for increasing crop yield of a plant by applying the photocatalytic compositions taught herein to the surface of a plant. Also provided is a method for treating microbial diseases on a surface by applying the photocatalytic compositions taught herein to a surface illuminated by artificial light.

Abstract: A mix-type catalyst filter which has a variety of pore sizes and thus improves efficiency of catalysts and a method for manufacturing the same. The method includes spinning nanofibers, heating the nanofibers, crushing the nanofibers to form chip-type nanofibers, mixing the chip-type nanofibers with particulate catalysts to obtain a mix-type catalyst and heating the mix-type catalyst.

Abstract: Mixed metal oxide catalysts (ZnO, CeO, La2O3, NiO, Al203, Si02, TiO2, Nd2O3, Yb2O3, or any combination of these) supported on zirconia (ZrO2) or hydrous zirconia are provided. These mixed metal oxide catalysts can be prepared via coprecipitation, impregnation, or sol-gel methods from metal salt precursors with/without a Zirconium salt precursor. Metal oxides/ZrO2 catalyzes both esterification and transesterification of oil containing free fatty acids in one batch or in single stage. In particular, these mixed metal oxides supported or added on zirconium oxide exhibit good activity and selectivity for esterification and transesterification. The low acid strength of this catalyst can avoid undesirable side reaction such as alcohol dehydration or cracking of fatty acids. Metal oxides/ZrO2 catalysts are not sensitive to any water generated from esterification. Thus, esterification does not require a water free condition or the presence of excess methanol to occur when using the mixed metal oxide catalyst.

Abstract: This invention is directed to catalysts for dehydrogenating primary alcohols. Catalysts comprising a metal support comprising (a) from about 2% to about 30% by weight copper, and (b) at least about 50% by weight non-copper metal selected from the group consisting of nickel, zinc, tin, cobalt, iron and combinations thereof; and a copper-containing coating are described.

Abstract: Process for preparing a catalyst for preparing ethylene oxide, which comprises silver and zinc applied to a support, where the process comprises at least (i) providing a support, (ii) applying zinc to the support according to (i) in an amount of from 10 ppm to 1500 ppm, in each case calculated as element and based on the total weight of the support according to (i), by bringing the support into contact with at least one mixture G1 comprising at least one zinc compound, (iii) drying and/or calcining the support obtained according to (ii), (iv) applying silver to the dried and/or calcined support by bringing the support into contact with at least one mixture G2 comprising at least one silver compound.

Abstract: A method of forming a product from an oil feedstock, such as a biodiesel product, and a heterogeneous catalyst system used to form said product is disclosed. This catalyst system, which has a high tolerance for the presence of water and free fatty acids (FFA) in the oil feedstock, may simultaneously catalyze both the esterification of FAA and the transesterification of triglycerides present in the oil feedstock. The catalyst system is comprised of a mixture of zinc oxide and a second metal oxide. The zinc oxide includes a mixture of amorphous zinc oxide and zinc oxide nanocrystals, the zinc nanocrystals having a mean grain size between about 20 and 80 nanometers with at least one of the nanocrystals including a mesopore having a diameter of about 5 to 15 nanometers. Preferably, the second metal oxide is a lanthanum oxide, the lanthanum oxide being selected as one from the group of La2CO5, LaOOH, and combinations or mixtures thereof.

Abstract: A catalyst is provided comprising nickel in a reduced valence state on a carrier comprising zinc oxide and alumina, wherein the Zn:Ni atomic ratio is at least 12, and the catalyst particles are prepared by: mixing zinc oxide in the form of a powder and alumina or an alumina precursor in the form of a powder; peptizing the powder mixture and forming an extrudable dough by adding acid and water to the powder mixture in such amounts that the dough contains 0.8-1.2 moles acid equivalents per kg powder; extruding the extrudable dough to form extrudates; drying and calcining the extrudates; impregnating the extrudates with an aqueous solution of a nickel compound; drying, calcining and reducing the impregnated extrudates. Further provided is a process for desulphurization of a hydrocarbonaceous feedstock using such catalyst.

Abstract: A regenerable sorbent for the removal of acid gas from a fluid stream. The regenerable sorbent is made from raw materials such as iron mineral, expansive clay and starch. Acid gas is removed from the fluid stream by a process where the raw materials are obtained, crushed, sifted, possibly pelletized, calcined and contacted with the fluid stream containing the acid gas.

Abstract: Applicant discloses multifunctional, highly active oxidation catalysts and methods of making such catalysts. Such methods include providing nanoparticles comprising titanium-oxo and zinc-oxo compositions, such as crystalline anatase titania nanoparticles with zinc-oxo domains on their surfaces, and etching the nanoparticles. The method also includes depositing catalytically active gold onto the nanoparticles, by, for example, physical vapor deposition.

Abstract: A particulate desulfurization material includes one or more nickel compounds, a zinc oxide support material, and one or more alkali metal compounds wherein the nickel content of the material is in the range 0.3 to 10% by weight and the alkali metal content of the material is in the range 0.2 to 10% by weight. A method of making the desulfurization material includes the steps: (i) contacting a nickel compound with a particulate zinc support material and an alkali metal compound to form an alkali-doped composition, (ii) shaping the alkali-doped composition, and (iii) drying, calcining, and optionally reducing the resulting material. The desulfurization material may be used to desulfurize hydrocarbon gas streams with reduced levels of hydrocarbon hydrogenolysis.

Abstract: A layered heterostructured coating has functional characteristics that enable the controlled release of volatile agents. The coating has photocatalytic properties, since it uses titanium dioxide, its derivatives or materials with similar photocatalytic properties (2), which upon solar irradiation open and/or degrade nano or microcapsules (3) and subsequently releases in a controlled form the volatile agents contained in them.

Abstract: A method of screening catalysts for liquid-phase selective hydrogenation by preparing a test catalyst by adding a promoter to a reference catalyst; preparing a liquid reactant stream comprising C2H2 dissolved in n-methyl-2-pyrrolidone; testing the test and reference catalysts by contacting the reactant stream and gas mixture comprising hydrogen and carbon monoxide in continuous flow with the test catalyst and reference catalyst, respectively, at selective hydrogenation reaction conditions to produce a product stream, condensing substantially all of the n-methyl-2-pyrrolidone from the product stream; measuring the concentrations of products comprising C2H2, C2H4, and C2H6 in the product stream at steady state; determining performance parameters for the test catalyst and the reference catalyst comprising the respective C2H2 conversion Sc and C2H4 selectivity relative to C2H6 Ss; and comparing the test catalyst performance parameters to those for the reference catalyst.

Abstract: A catalyst and its use for the abatement of carbon monoxide and unburned hydrocarbons in the exit stream of a combustion device, such as an automobile and spray paint booths are disclosed.

Abstract: A CO2 reforming catalyst composition includes a hydroxyl group-containing porous oxide, and a composite porous catalyst supported by a porous supporter. The composite porous catalyst includes a catalyst metal.

Abstract: The present invention provides methods for controlling defects in materials, including point defects, such as interstitials and vacancies, and extended defects, including dislocations and clusters. Defect control provided by the present invention allows for fabrication and processing of materials and/or structures having a selected abundance, spatial distribution and/or concentration depth profile of one or more types of defects in a material, such as vacancies and/or interstitials in a crystalline material. Methods of the invention are useful for processing materials by controlling defects to access beneficial physical, optical, chemical and/or electronic properties.

Abstract: Embodiments include metal (102) containing composites (100) and methods of forming metal containing composites. A metal containing composite can be formed by contacting an oxide support surface (104) with coordination compounds having metal atoms for a first predetermined time, where the metal atoms of the coordination compounds deposit on the oxide support surface; contacting the oxide support surface with a first reagent for a second predetermined time; and contacting the first reagent with a second reagent for a third predetermined time, where the first reagent and the second reagent react to form another layer of the oxide support surface.

Abstract: Presented are one or more aspects and/or one or more embodiments of catalysts, methods of preparation of catalyst, methods of deoxygenation, and methods of fuel production.

Abstract: Provided is a method of manufacturing porous metal oxide, the method including: preparing a metal-organic framework (MOF) wherein an ion of a metal to be used as a catalyst is linked to an organic ligand; impregnating the MOF with a precursor solution of metal oxide to be manufactured; and thermally treating the metal oxide precursor solution-impregnated MOF to remove the organic ligand. The inventive method of manufacturing porous metal oxide involves the impregnation of a metal oxide precursor solution in a MOF wherein metal ions are uniformly linked to organic ligands and the thermal treatment (calcination) of the metal oxide precursor solution-impregnated MOF to remove the organic ligands.

Abstract: An eggshell catalyst useful for a Fischer-Tropsch (FT) synthesis or other reactions comprises a homogeneously dispersed transition metal and a promoter situated in an active phase in a precisely selected outer region of a catalyst pellet. The active phase region is controlled to a specific depth, which permits the control of the catalysts selectivity, for example, the size of the hydrocarbon chains formed in the FT process. A method of preparing these eggshell catalysts involves a non-aqueous synthesis where polar and non-polar solvents of relatively low vapor pressure are employed to define the depth of penetration of metal species in a refractory oxide substrate, which is followed by fixing and activating metallic catalytic species in the structure by calcination of the catalyst particles.

Abstract: The invention relates to a method for producing hydrogen silanes of general formula RnCl3-nSiH by converting chlorosilanes of general formula RnCl4-nSi, where R, in both formulas simultaneously and independently of each other, is a hydrogen atom, an optionally substituted or unsubstituted hydrocarbon radical having 1 to 18 carbon atoms, and n can have the value of 1-3, and hydrogen gas in the presence of a catalytic quantity (K): zinc and/or an alloy comprising zinc on a metal oxide carrier.

Abstract: A catalyst for hydrogenating aldehydes to alcohols includes a combination of copper oxide and zinc oxide and promoters including one or more alkaline earth metal promoters and/or one or more transition metal promoters. The promoters may be combined with copper oxide and zinc oxide after formation of a copper/zinc precursor material.

Abstract: A catalyst system is disclosed for catalytic pyrolysis of a solid biomass material. The system comprises an oxide, silicate or carbonate of a metal or a metalloid. The specific combined meso and macro surface area of the system is in the range of from 1 m2/g to 100 m2/g. When used in a catalytic process the system provides a high oil yield and a low coke yield. The liquid has a relatively low oxygen content.

Abstract: The present invention relates to a process for producing hydrogenolysis products of polyhydric alcohols with a good selectivity and a high yield, as well as hydrogenolysis catalysts used in the production process. The present invention provides (1) a process for producing a hydrogenolysis product of a polyhydric alcohol which includes the step of reacting the polyhydric alcohol with hydrogen in the presence of a catalyst containing a copper component, wherein the catalyst is a catalyst (A) containing the copper component, an iron component and an aluminum component, or a catalyst (B) containing the copper component and a silicon component; and (2) a hydrogenolysis catalyst for polyhydric alcohols which includes a copper component, an iron component and an aluminum component, and (3) a hydrogenolysis catalyst for polyhydric alcohols which includes a copper component and a silicon component.

Abstract: A catalyst charge for ammonia oxidation, including the Andrussow process, comprises a first stage ammonia oxidation catalyst capable of oxidizing 20 to 99% of designed ammonia throughput, to produce a first stage product gas comprising unreacted ammonia, oxygen and nitrogen oxides, and a second stage ammonia oxidation catalyst capable of completing the oxidation of unreacted ammonia. Low levels of nitrous oxide are produced an extended campaign lengths may be seen.

Abstract: A new chromium-containing fluorination catalyst is described. The catalyst comprises an amount of zinc that promotes activity. The zinc is contained in aggregates which have a size across their largest dimension of up to 1 micron. The aggregates are distributed throughout at least the surface region of the catalyst and greater than 40 weight % of the aggregates contain a concentration of zinc that is within ±1 weight % of the modal concentration of zinc in those aggregates.

Abstract: A simple, room-temperature method of producing zinc oxide nanoparticles was established by reacting zinc nitrate hexahydrate and cyclohexylamine (CHA) in either aqueous or EtOHic medium. Particles of polyhedra morphology were obtained for zinc oxide, prepared in EtOH (ZnOE), while an irregular spherical morphology, mixed with some chunky particles forzinc oxide prepared in water (ZnOW). The results indicate that there are significant morphological differences between ZnOE and ZnOW. ZnOE showed a regular polyhedral shape, while spherical and chunky particles were observed for ZnOW. The morphology was crucial in enhancing the cyanide ion photocatalytic degradation efficiency of ZnOE by a factor of 1.5 in comparison to the efficiency of ZnOW at equivalent loading of 0.02 ZnO nanoparticles wt %. Increasing the loading wt % of ZnOE from 0.01 to 0.07 led to an increase in the photocatalytic degradation efficiency from 67% to 90% after 45 minutes and a doubling of the first-order rate constant (k).

Abstract: Disclosed is a sterilizing catalyst, a sterilizing device and a sterilizing system, the sterilizing catalyst includes a metal lattice including a metal oxide, and an oxygen vacancy-inducing metal that is integrated or encompassed within the metal lattice. The metal oxide is an oxide of a divalent or multivalent metal. The oxygen vacancy-inducing metal has an oxidation number lower than that of the divalent or multivalent metal.

Abstract: A catalyst composition includes a catalytic metal secured to a porous substrate. The substrate has pores that are templated. The catalyst composition is prepared by a process that includes the steps of mixing a catalytic metal salt, a templating agent, and water to form a mixture, adding a substrate precursor to the mixture to form a slurry, and calcining the slurry to form a substrate having a porous template that is capable of supporting the catalyst composition.

Abstract: [PROBLEMS] To provide a material for producing a bioabsorbable material in which it is easy to remove a metal zinc catalyst from a bioabsorbable polymer such as a polymer of lactide or a polymer of lactide and caprolactone and it is easy to recycle the removed powdery metal zinc catalyst, and to provide a bioabsorbable material produced from the material for producing a bioabsorbable material. [MEANS FOR SOLVING PROBLEMS] A material for producing a bioabsorbable material including a three-dimensionally shaped metal zinc polymerization catalyst and a bioabsorbable polymer such as a polymer of lactide or a polymer of lactide and caprolactone; and a process for producing a material for producing a bioabsorbable material, characterized in that in the process for producing a bioabsorbable polymer by polymerization, a three-dimensionally shaped metal zinc catalyst is used as a polymerization catalyst.

Abstract: This invention provides a photocatalyst material, which can be produced at low cost without using platinum, particularly a visible light response-type photocatalyst material, a material having a photocatalyst mechanism not possessed by the conventional photocatalyst material, a process for producing the material, and a method for decomposing a contaminant using the material. The photocatalyst material comprises a) an oxide of a first metal and b) an aqua complex salt of a second metal. In this case, for the oxide of a first metal, the redox potential of a conduction band lower end in the oxide is on a rather negative side than 0.2 V (a value as measured at pH=0, vs. reference electrode potential). For the aqua complex salt of a second metal, the redox potential of a second metal ion in the aqua complex salt is on a rather negative side than 3.0 V (a value as measured at pH=0, vs. reference electrode potential).

Abstract: Highly uniform cluster based nanocatalysts supported on technologically relevant supports were synthesized for reactions of top industrial relevance. The Pt-cluster based catalysts outperformed the very best reported ODHP catalyst in both activity (by up to two orders of magnitude higher turn-over frequencies) and in selectivity. The results clearly demonstrate that highly dispersed ultra-small Pt clusters precisely localized on high-surface area supports can lead to affordable new catalysts for highly efficient and economic propene production, including considerably simplified separation of the final product. The combined GISAXS-mass spectrometry provides an excellent tool to monitor the evolution of size and shape of nanocatalyst at action under realistic conditions. Also provided are sub-nanometer gold and sub-nanometer to few nm size-selected silver catalysts which possess size dependent tunable catalytic properties in the epoxidation of alkenes.