Of Group I (i.e., Alkali, Ag, Au Or Cu) Patents (Class 502/344)
  • Publication number: 20100240530
    Abstract: The present invention relates to a method for producing a metallic coating material to coat the surface of matrices with a metal, and it is an object of the invention to provide a method for producing a metallic coating material for which there is no concern that metallic powder will scatter or ignite at the time of production, and which is excellent in productivity not requiring any cumbersome process such as burning at a high temperature, etc., and is excellent in decorative features and functionality such as a catalyzing action. With the method for producing a metallic coating material according to the present invention, a metallic layer that coats the surface of the matrices with the metallic powder is formed by the mechanical alloying of matrices formed by any of ceramic, mineral, metal, synthetic resin, or a mixed material thereof, and metallic powder.
    Type: Application
    Filed: March 22, 2007
    Publication date: September 23, 2010
    Applicants: T.N.G. Technologies Co., Ltd.
    Inventor: Kiichirou Sumi
  • Patent number: 7799298
    Abstract: The invention relates to a catalyst arrangement for purifying the exhaust gases of internal combustion engines operated under lean conditions. It is proposed that a thinwalled, porous carrier be coated on one side with a nitrogen oxide storage catalyst and on the other side with an SCR catalyst. When the exhaust gas is passed through the catalytic coatings and the support material, a significant improvement in the nitrogen oxide conversion is achieved compared to a series arrangement of the catalysts on separate carriers. Wall flow filters have been found to be useful as thin-walled carriers.
    Type: Grant
    Filed: July 29, 2004
    Date of Patent: September 21, 2010
    Assignee: Umicore AG & Co. KG
    Inventors: Marcus Pfeifer, Nicola Soeger, Yvonne Demel, Tobias Kuhl, Paul Christian Spurk, Jürgen Gieshoff, Egbert Lox, Thomas Kreuzer
  • Patent number: 7799727
    Abstract: A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: September 21, 2010
    Assignee: UOP LLC
    Inventors: Dean E. Rende, James E. Rekoske, Jeffery C. Bricker, Jeffrey L. Boike, Masao Takayama, Kouji Hara, Nobuyuki Aoi
  • Patent number: 7799732
    Abstract: A method of producing composite particles of titanium dioxide and a compound inactive as a photocatalyst, comprising the steps of preparing a water based slurry of pH 3 to 5 comprising titanium dioxide, preparing a water based solution comprising a compound inactive as a photocatalyst, and reacting the slurry and the water based solution together at a pH within a range from 4 to 10 is provided, together with highly active photocatalyst particles produced using such a method, and potential uses of such photocatalyst particles.
    Type: Grant
    Filed: June 19, 2008
    Date of Patent: September 21, 2010
    Assignee: Showa Denko K.K.
    Inventors: Jun Tanaka, Masayuki Sanbayashi, Yoshinori Ueyoshi, Hiroyuki Hagihara
  • Publication number: 20100233053
    Abstract: A method is provided. The method comprises reacting a reactive solution and a templating agent to form a gel; and calcining the gel to form a catalyst composition comprising homogeneous solid mixture. The homogenous solid mixture contains (i) at least one catalytic metal and (ii) at least one metal inorganic network. The templating agent comprises an octylphenol ethoxylate having a structure [I]: wherein “n” is an integer having a value of about 8 to 20. A catalyst composition prepared using the templating agent having a structure [1] is also provided.
    Type: Application
    Filed: May 28, 2010
    Publication date: September 16, 2010
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Larry Neil Lewis, Oltea Puica Siclovan, Dan Hancu, Ashish Balkrishna Mhadeshwar, Ming Yin
  • Patent number: 7794679
    Abstract: The invention provides a catalyst for catalytically reducing nitrogen oxides in diesel engine exhaust gas by use of unburnt carbon contained in the diesel engine exhaust gas as a reducing agent, the catalyst comprising: (a) an acid zeolite, or (b) an alkali metal- and/or alkaline earth metal-containing zeolite, or (c) a rare earth metal-containing zeolite, or (d) a zeolite containing at least one transition metal selected from Fe, Co, Ni and Cu.
    Type: Grant
    Filed: January 11, 2008
    Date of Patent: September 14, 2010
    Assignee: Honda Motor Co., Ltd.
    Inventors: Tadao Nakatsuji, Naoki Oya, Naohiro Sato
  • Publication number: 20100226845
    Abstract: Hopcalite-type catalysts for oxidation of CO are formed by preparing a mixed-metal oxide precursor by firstly preparing a solution of a mixture of metal precursor compounds in a solvent, followed by contacting the solution with a supercritical antisolvent to precipitate the mixed-metal oxide precursor. A mixed-metal oxide may then be prepared from the precursor by oxidation, for example by calcination. The mixed-metal oxide is then collected and optionally activated for use as a catalyst. The activated or calcined catalyst contains a nano-structured mixed-phase composition comprising phase-separated intimately mixed nanoparticles of copper and manganese oxide.
    Type: Application
    Filed: December 1, 2005
    Publication date: September 9, 2010
    Inventors: Graham John Hutchings, Stuart Hamilton Taylor, Jonathan Keith Bartley
  • Publication number: 20100222213
    Abstract: A honeycomb structure includes aluminum titanate, cell walls, and pore portions. The cell walls extend along a longitudinal direction of the honeycomb structure to define cells between the cell walls. The pore portions have an average pore diameter of about 10 ?m to about 20 ?m. A length of a longest pore portion among the pore portions in a binary image including substrate portions and the pore portions is about 8 times or less of the average pore diameter. The binary image is converted from a microscopic image of a cross section of the cell walls in parallel with the longitudinal direction. The length is measured along a line drawn in a direction perpendicular to a thickness direction of the cell walls.
    Type: Application
    Filed: April 8, 2010
    Publication date: September 2, 2010
    Applicant: IBIDEN CO., LTD.
    Inventors: Kazushige OHNO, Kazunori Yamayose
  • Publication number: 20100216634
    Abstract: A method for manufacturing a honeycomb structure includes molding a wet mixture containing an aluminum titanate powdery material to form a honeycomb molded body. The aluminum titanate powdery material contains about 40% to about 60% by mass of Al2O3, about 30% to about 50% by mass of TiO2, and about 1% to about 15% by mass of (MgO+SiO2). The honeycomb molded body has cells provided substantially in parallel with one another in a longitudinal direction of the honeycomb molded body. The honeycomb molded body is fired at a temperature of about 1200° C. to about 1700° C.
    Type: Application
    Filed: March 23, 2010
    Publication date: August 26, 2010
    Applicant: IBIDEN CO., LTD.
    Inventors: Kazushige OHNO, Kazunori Yamayose
  • Publication number: 20100204039
    Abstract: The exhaust gas-purifying catalyst includes at least one of a first composite oxide represented by a formula A(Al2-xBx)O4 and a second composite oxide represented by a formula (Al2-yCy)O3, wherein element A is a divalent transition metal other than platinum-group elements, each of elements B and C is a transition metal other than platinum-group elements, x satisfies 0<x<2, and y satisfies 0<y<2.
    Type: Application
    Filed: April 22, 2010
    Publication date: August 12, 2010
    Applicants: CATALER CORPORATION, DIAHATSU MOTOR CO., LTD.
    Inventors: Satoshi MATSUEDA, Mareo Kimura, Hiroto Yoshida, Keiichi Narita, Hirohisa Tanaka, Mari Uenishi, Masashi Taniguchi
  • Patent number: 7772149
    Abstract: A Cr trapping agent is disposed so that it contacts with constituting components of the substrate containing Cr. As the Cr trapping agent, an element or Ag is used, wherein the element is stronger in basicity than alkali metals or alkaline earth metals. Since the Cr trapping agent prevents transfer of Cr towards the alkali metals or alkaline earth metals, the reaction between Cr and alkali metals or alkaline earth metals is prevented.
    Type: Grant
    Filed: December 6, 2006
    Date of Patent: August 10, 2010
    Assignees: Hitachi, Ltd., Honda Motor Co., Ltd., Nippon Steel Materials Co., Ltd.
    Inventors: Masato Kaneeda, Hidehiro Iizuka, Norihiro Shinotsuka, Masahiro Sakanushi, Kimihiro Tokushima, Hiroki Hosoe, Masayuki Kasuya, Toshio Iwasaki, Shogo Konya
  • Patent number: 7772150
    Abstract: A method to prepare porous medium decorated with nanoparticles involves contacting a suspension of nanoparticles in an ionic liquid with a porous medium such that the particles diffuse into the pores of the medium followed by heating the resulting composition to a temperature equal to or greater than the thermal decomposition temperature of the ionic liquid resulting in the removal of the liquid portion of the suspension. The nanoparticles can be a metal, an alloy, or a metal compound. The resulting compositions can be used as catalysts, sensors, or separators.
    Type: Grant
    Filed: May 1, 2007
    Date of Patent: August 10, 2010
    Assignee: UT-Battelle, LLC
    Inventors: Gabriel M. Vieth, Nancy J. Dudney, Sheng Dai
  • Publication number: 20100197481
    Abstract: Use of physical vapor deposition methodologies to deposit nanoscale gold on activating support media makes the use of catalytically active gold dramatically easier and opens the door to significant improvements associated with developing, making, and using gold-based, catalytic systems. The present invention, therefore, relates to novel features, ingredients, and formulations of gold-based, heterogeneous catalyst systems generally comprising nanoscale gold deposited onto a nanoporous support.
    Type: Application
    Filed: April 8, 2010
    Publication date: August 5, 2010
    Inventors: LARRY A. BREY, Thomas E. Wood, Gina M. Buccellato, Marvin E. Jones, Craig S. Chamberlain, Allen R. Siedle
  • Publication number: 20100190638
    Abstract: A method for producing a shell catalyst comprising a porous catalyst support shaped body with an outer shell containing at least one transition metal in metal form. To provide a shell catalyst with a relatively small shell thickness, a device is set up to circulate the catalyst support shaped bodies by means of process gases with a reductive effect. The device is charged with catalyst support shaped bodies that are circulated by means of a process gas with a reductive effect, an outer shell of the catalyst support shaped bodies is impregnated with a transition-metal precursor compound by spraying the circulating catalyst support shaped bodies with a solution containing the transition-metal precursor compound, the metal component of the transition-metal precursor compound is converted into the metal form by reduction by means of the process gas, and the catalyst support shaped bodies sprayed with the solution are dried.
    Type: Application
    Filed: May 30, 2008
    Publication date: July 29, 2010
    Applicant: Sud-Chemie AG
    Inventors: Alfred Hagemeyer, Gerhard Mestl, Peter Scheck, Silvia Neumann
  • Publication number: 20100189615
    Abstract: Described are catalyst composites containing mechanically fused components, methods of making the catalyst composites, and methods of using the catalyst composites such as in pollution abatement applications. The catalyst composites contain a core and a shell at least substantially covering the core, the shell mechanically fused to the core and comprising particles mechanically fused to each other, wherein a size ratio of the core to particles of the shell is at least about 10:1.
    Type: Application
    Filed: January 29, 2009
    Publication date: July 29, 2010
    Applicant: BASF CATALYSTS LLC
    Inventor: Gary Gramiccioni
  • Publication number: 20100179053
    Abstract: A metal oxide nanotube-supported gold catalyst and a preparing method thereof are disclosed. The metal oxide nanotube-supported gold catalyst includes a metal oxide support and a plurality of gold particles loaded into the metal oxide support, and there are at least two gold species with different oxidation states are loaded into the metal oxide support. The preparing method of the metal oxide nanotube-supported gold catalyst includes the deposition of the gold particles on the surface of the metal oxide nanotubes by using an ion exchange reaction.
    Type: Application
    Filed: September 7, 2009
    Publication date: July 15, 2010
    Applicant: NATIONAL CHANGHUA UNIVERSITY OF EDUCATION
    Inventors: Chiu-Hsun LIN, Jui-Ying TSAI
  • Publication number: 20100167917
    Abstract: Method for producing a hydrogen storage material that includes a metal hydride and a non-hydrogenated material and that is doped with a metal as a catalyst, includes; mixing a catalyst precursor, which includes the metal, with the non-hydrogenated material so as to provide a first mixture; agitating the first mixture; thermally treating the first mixture so as to form a composite of the non-hydrogenated material and the metal; mixing the composite with the metal hydride so as to provide a second mixture; and grinding the second mixture so as to provide the hydrogen storage material.
    Type: Application
    Filed: July 27, 2006
    Publication date: July 1, 2010
    Applicant: FORSCHUNGSZENTRUM KARLSRUHE GMBH
    Inventors: Maximilian Fichtner, Christoph Frommen
  • Patent number: 7744763
    Abstract: A composition comprising a vanadium oxide compound and an alkali metal promoter loaded onto a porous support material is disclosed. Methods of making and using the composition to remove heavy metals or heavy metal containing compounds from a fluid stream are also provided. Such methods are particularly useful in the removal of mercury and mercury compounds from flue gas streams produced from the combustion of hydrocarbon-containing materials such as coal and petroleum fuels.
    Type: Grant
    Filed: July 17, 2008
    Date of Patent: June 29, 2010
    Assignee: ConocoPhillips Company
    Inventors: Joseph B. Cross, Glenn W. Dodwell, Marvin M. Johnson, Edward L. Sughrue, II, Jianhua Yao
  • Patent number: 7741499
    Abstract: There is provided a catalyst carrier comprising a refractory inorganic material having a sodium solubilization rate no greater than 5 ppmw/5 minutes. There is further a catalyst comprising a refractory inorganic material carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and one or more catalytically reactive metals deposited on said carrier. There is also provided a catalyst suitable for the vapor phase production of alkylene oxide from olefins and oxygen comprising an alumina-based carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and catalytically reactive silver deposited on said carrier.
    Type: Grant
    Filed: May 9, 2007
    Date of Patent: June 22, 2010
    Assignee: Shell Oil Company
    Inventor: John Robert Lockemeyer
  • Publication number: 20100152497
    Abstract: Improved methods of introducing promoters to catalysts are described. The present invention provides a convenient method of uniformly distributing a catalyst promoter, to provide for intimate contact between the promoter and the active catalyst sites. This intimate contact can enhance the activity and/or product selectivity of the promoted catalyst. In some embodiments, the method includes reacting an alkali metal with an alcohol in a non-aqueous medium, contacting the resulting solution with a starting catalyst, and depositing the alkali metal onto the starting catalyst to form an alkali-promoted catalyst.
    Type: Application
    Filed: December 9, 2009
    Publication date: June 17, 2010
    Applicant: Range Fuels, Inc.
    Inventor: Ronald C. STITES
  • Patent number: 7732367
    Abstract: A catalyst for oxidation of unsaturated and/or saturated aldehyde to unsaturated acids is disclosed where the catalyst including at least molybdenum (Mo), phosphorus (P), vanadium (V), bismuth (Bi), and a first component selected from the group consisting of potassium (K), rubidium (Rb), cesium (Cs), thallium (Tl), or mixtures or combinations thereof, where the catalyst has at least 57% medium pores and a nitric acid to molybdenum mole ratio of at least 0.5:1 or at least 6.0:1 moles of HNO3 per mole of Mo12. Methods for making and using such catalysts are also disclosed.
    Type: Grant
    Filed: July 25, 2005
    Date of Patent: June 8, 2010
    Assignee: Saudi Basic Industries Corporation
    Inventors: Scott A. Stevenson, Wugeng Liang, James W. Kauffman, Lixia Cai, Angie McGuffey, Joseph R. Linzer
  • Patent number: 7727931
    Abstract: Use of physical vapor deposition methodologies to deposit nanoscale gold on activating support media makes the use of catalytically active gold dramatically easier and opens the door to significant improvements associated with developing, making, and using gold-based, catalytic systems. The present invention, therefore, relates to novel features, ingredients, and formulations of gold-based, heterogeneous catalyst systems generally comprising nanoscale gold deposited onto a nanoporous support.
    Type: Grant
    Filed: September 23, 2004
    Date of Patent: June 1, 2010
    Assignee: 3M Innovative Properties Company
    Inventors: Larry A. Brey, Thomas E. Wood, Gina M. Buccellato, Marvin E. Jones, Craig S. Chamberlain, Allen R. Siedle
  • Patent number: 7722845
    Abstract: Catalysts, methods, and systems for treating diesel engine exhaust streams are described. In one or more embodiments, the catalyst comprises platinum, a second metal from one of the groups VB, VIB, VIIB, VIIIB, IB, or IIB of the periodic table, a refractory metal oxide, and a zeolite, the oxidation catalyst already being effective to remove ammonia at temperatures less than about 300° C. and exhibiting no significant decrease in ammonia oxidation efficiency upon hydrothermal aging. A method aspect includes first passing a vehicle's engine exhaust stream through a NOx abatement catalyst; and passing the exhaust stream exiting the NOx abatement catalyst and containing ammonia through the ammonia oxidation catalyst. Systems including such catalysts are also provided.
    Type: Grant
    Filed: February 27, 2008
    Date of Patent: May 25, 2010
    Assignee: Basf Corporation
    Inventors: Matthew T. Caudle, Martin Deiterle, Stanley A. Roth, Wen-Mei Xue
  • Publication number: 20100120611
    Abstract: The invention relates to catalytically active components for thermal ionization detectors for the detection of compounds containing halogen which have an improved structure as well as to a manufacturing method for an oxide ceramic sintering material for the components. It is the object of the invention to manufacture catalytically active components for thermal ionization detectors for gas chromatographic applications which are thermally, mechanically and chemically stable in the long term and which have increased sensitivity to the materials to be detected. In this respect, the sintering material should be adjustable in a controllable manner in the ideal parameter required for the detector. It is proposed in accordance with the invention to use an oxide ceramic sintering material for the components which comprises a crystalline phase and an amorphous glass phase, with it being essential to the invention that the amorphous glass phase is formed with 0.1 to 20% by weight of a cesium compound.
    Type: Application
    Filed: July 30, 2007
    Publication date: May 13, 2010
    Applicant: FRAUNHOFER-GESELLSCHAFT ZUR FORDERUNG DER ANGEWANDTEN FORSCHUNG E.V.
    Inventors: Viktar Sauchuk, Peter Otschik, Klaus Eichler, Mihails Kusnezoff
  • Patent number: 7713908
    Abstract: A method of producing a porous composite metal oxide comprising the steps of: dispersing first metal oxide powder, which is an aggregate of primary particles each with a diameter of not larger than 50 nm, in a dispersion medium by use of microbeads each with a diameter of not larger than 150 ?m, thus obtaining first metal oxide particles, which are 1 nm to 50 nm in average particle diameter, and not less than 80% by mass of which are not larger than 75 nm in diameter; dispersing and mixing up, in a dispersion medium, the first metal oxide particles and second metal oxide powder, which is an aggregate of primary particles each with a diameter of not larger than 50 nm, and which is not larger than 200 nm in average particle diameter, thus obtaining a homogeneously-dispersed solution in which the first metal oxide particles and second metal oxide particles are homogeneously dispersed; and drying the homogeneously-dispersed solution, thus obtaining a porous composite metal oxide.
    Type: Grant
    Filed: August 29, 2005
    Date of Patent: May 11, 2010
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Toshio Yamamoto, Akihiko Suda, Akira Morikawa, Kae Yamamura, Hirotaka Yonekura
  • Patent number: 7713907
    Abstract: The invention provides a method for depositing catalytic clusters on a surface, the method comprising confining the surface to a controlled atmosphere; contacting the surface with catalyst containing vapor for a first period of time; removing the vapor from the controlled atmosphere; and contacting the surface with a reducing agent for a second period of time so as to produce catalyst-containing nucleation sites.
    Type: Grant
    Filed: March 5, 2007
    Date of Patent: May 11, 2010
    Assignee: UChicago Argonne, LLC
    Inventors: Jeffrey W. Elam, Michael J. Pellin, Peter C. Stair
  • Patent number: 7713909
    Abstract: A catalyzed Diesel soot filter and process. The Diesel soot filter incorporates a porous filter element coated with a catalytic agent so that Diesel soot from Diesel exhaust gas is deposited into contact with the catalytic agent when Diesel exhaust gas is passed through the porous filter element and so that the ignition temperature or oxidation temperature of the deposited Diesel soot is reduced. The catalytic agent is a mixture of alkali metal and cerium oxides. The mole ratio of alkali metal to cerium of the catalytic agent is in the range of from 0.5 to 5.
    Type: Grant
    Filed: October 13, 2005
    Date of Patent: May 11, 2010
    Inventors: Fuhe Mao, Cheng G. Li, Robin Ziebarth
  • Patent number: 7709414
    Abstract: An engine exhaust catalyst exhibits improved CO oxidation performance relative to conventional engine exhaust catalysts and includes a first supported catalyst comprising platinum and a second supported catalyst comprising palladium and gold species in close contact. The first supported catalyst may be a platinum catalyst, a platinum—palladium catalyst, or a platinum catalyst promoted with bismuth, and the second supported catalyst preferably has a palladium to gold weight ratio of about 0.85:1.0. To improve aged catalyst performance, the first and second supported catalysts are coated onto different layers, zones, or monoliths of the substrate for the engine exhaust catalyst.
    Type: Grant
    Filed: January 17, 2007
    Date of Patent: May 4, 2010
    Assignee: NanoStellar, Inc.
    Inventors: Kyle L. Fujdala, Timothy J. Truex, Jifei Jia
  • Patent number: 7709410
    Abstract: The invention relates to Group 1 metal/silica gel compositions comprising silica gel and an alkali metal or an alkali metal alloy. The compositions of the inventions are described as Stage 0, I, II, and III materials. These materials differ in their preparation and chemical reactivity. Each successive stage may be prepared directly using the methods described below or from an earlier stage material. Stage 0 materials may, for example, be prepared using liquid alloys of Na and K which are rapidly absorbed by silica gel (porous SiO2) under isothermal conditions, preferably at or just above room temperature, to form loose black powders that retain much of the reducing ability of the parent metals. When the low melting Group 1 metals are absorbed into the silica gel, a mild exothermic reaction produces Stage I material, loose black powders that are indefinitely stable in dry air. Subsequent heating to 400° C. produces Stage II materials, which are also loose black powders. Further heating above 400° C.
    Type: Grant
    Filed: August 11, 2008
    Date of Patent: May 4, 2010
    Assignee: SiGNa Chemistry, Inc.
    Inventors: Michael Lefenfeld, James L. Dye
  • Publication number: 20100105548
    Abstract: An electrocatalyst is described. The electrocatalyst includes a core of a non-noble metal or non-noble metal alloy; and a continuous shell of a noble metal or noble metal alloy on the core, the continuous shell being at least two monolayers of the noble metal or noble metal alloy. Methods for making the electrocatalyst are also described.
    Type: Application
    Filed: October 24, 2008
    Publication date: April 29, 2010
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
    Inventors: Junliang Zhang, Frederick T. Wagner, Zhongyi Liu, Michael K. Carpenter
  • Patent number: 7704916
    Abstract: A compound of formula (Na0.33A0.66)2B2O7-? wherein A is one or more metals chosen from the lanthanide metals; B is one or more metals chosen from Ti, Sn, Ge, Ru, Mn, Ir, Os and Pb; and ? is a number in the range 0-1 is disclosed. Water gas shift catalysts comprising precious metals such as gold dispersed on the (Na0.33A0.66)2B2O7-? compound are also disclosed.
    Type: Grant
    Filed: September 7, 2005
    Date of Patent: April 27, 2010
    Assignee: Johnson Matthey PLC
    Inventors: Janet Mary Fisher, David Thompsett, Richard Ian Walton, Christopher Stuart Wright
  • Patent number: 7704919
    Abstract: The invention relates to gold-coated particles useful as fuel cell electrocatalysts. The particles are composed of an electrocatalytically active core at least partially encapsulated by an outer shell of gold or gold alloy. The invention more particularly relates to such particles having a noble metal-containing core, and more particularly, a platinum or platinum alloy core. In other embodiments, the invention relates to fuel cells containing these electrocatalysts and methods for generating electrical energy therefrom.
    Type: Grant
    Filed: August 1, 2005
    Date of Patent: April 27, 2010
    Assignee: Brookhaven Science Associates, LLC
    Inventors: Radoslav Adzic, Junliang Zhang
  • Patent number: 7704474
    Abstract: The invention relates to a method for the catalytic decomposition of N2O in a gas containing N2O in the presence of a catalyst, wherein the catalyst comprises a zeolite that has been loaded with a first metal selected from the group of noble metals consisting of ruthenium, rhodium, silver, rhenium, osmium, iridium, platinum and gold, and with a second metal selected from the group of transition metals consisting of chromium, manganese, iron cobalt, nickel and copper, and wherein the loading of the zeolite with metals has been obtained by first loading the zeolite with the noble metal and then with the transition metal, as well as a catalyst for this method and a method for the preparation of this catalyst.
    Type: Grant
    Filed: May 17, 2005
    Date of Patent: April 27, 2010
    Assignee: Stichting Energieonderzoek Centrum Nederland
    Inventors: Johannis Alouisius Zacharias Pieterse, Rudolf Willem Van Den Brink
  • Publication number: 20100099012
    Abstract: Transition metal nanostructures coated with a contiguous, conformal submonolayer-to-multilayer noble metal film and their method of manufacture are described. The manufacturing process involves the initial formation of suitably sized transition metal or alloy nanostructures which may be nanorods, nanobars, or nanowires. A monolayer of a non-noble metal is deposited onto the surface of the nanostructures by underpotential deposition. This is followed by the galvanic displacement of the non-noble metal by a second metal to yield a conformal coating of a monolayer of the second metal on the surface of the nanostructures. The replacement of atoms of the first metal by atoms of the second metal is an irreversible and spontaneous redox reaction which involves the replacement of a non noble metal by a more noble metal. The process can be controlled and repeated to obtain the desired film coverage.
    Type: Application
    Filed: October 19, 2009
    Publication date: April 22, 2010
    Applicant: Brookhaven Science Associates, LLC
    Inventor: Radoslav Adzic
  • Publication number: 20100096618
    Abstract: A catalyst particle for use in growth of elongated nanostructures, such as e.g. nanowires, is provided. The catalyst particle comprises a catalyst compound for catalyzing growth of an elongated nanostructure comprising a nanostructure material without substantially dissolving in the nanostructure material and at least one dopant element for doping the elongated nanostructure during growth by substantially completely dissolving in the nanostructure material. A method for forming an elongated nanostructure, e.g. nanowire, on a substrate using the catalyst particle is also provided. The method allows controlling dopant concentration in the elongated nanostructures, e.g. nanowires, and allows elongated nanostructures with a low dopant concentration of lower than 1017 atoms/cm3 to be obtained.
    Type: Application
    Filed: December 19, 2007
    Publication date: April 22, 2010
    Applicant: Interuniversitair Microelektronica Centrum (IMEC)
    Inventors: Francesca Iacopi, Philippe M. Vereecken
  • Patent number: 7691776
    Abstract: The invention relates to an oxidic catalyst containing cesium and tungsten for the synthesis of alkyl mercaptans from alkanols and hydrogen sulfide, and to a process for the production of this catalyst, wherein the molar ratio of cesium to tungsten is <2:1.
    Type: Grant
    Filed: August 14, 2009
    Date of Patent: April 6, 2010
    Assignee: Evonik Degussa GmbH
    Inventors: Hubert Redlingshöfer, Christoph Weckbecker, Andreas Dörflein, Michael Rückriegel
  • Patent number: 7691777
    Abstract: An oxidation catalyst for purifying an exhaust gas, which can provide an excellent catalyst activity at lower temperatures for particulates and high boiling point hydrocarbons in an exhaust gas of an internal combustion engine, is provided. The oxidation catalyst for purifying an exhaust gas is composed of a composite metal oxide represented by the general formula: Y1-xAgxMnO3, wherein 0.01?x?0.15. The composite metal oxide is represented by the general formula: Y1-xAgxMn1-yAyO3, wherein A is one metal selected from the group consisting of Ti, Nb, Ta and Ru, and 0.005?y?0.2.
    Type: Grant
    Filed: October 18, 2007
    Date of Patent: April 6, 2010
    Assignee: Honda Motor Co., Ltd.
    Inventors: Yuji Isogai, Kiyoshi Tanaami
  • Publication number: 20100081569
    Abstract: The invention relates to a coating material having catalytic activity for reducing the combustion temperature of soot and organic substances. It also relates to the use of the coating material. In order to create a catalytically active coating material with which an abrasion-proof coating suitable also for optical applications can be produced for the combustion of soot and organic substances, it is proposed within the scope of the invention that the coating material contains at least 20 and less than 50 wt. % of compounds of subgroup metals or of elements of the third and fourth main groups, and between 10 and 80 wt. % of alkali or alkaline earth compounds, the molar proportion of alkali or alkaline earth compounds being higher than the molar proportion of compounds of subgroup metals or of elements of the third and fourth main groups.
    Type: Application
    Filed: April 1, 2008
    Publication date: April 1, 2010
    Inventors: Stefan Sepeur, Frank Gross, Gerald Frenzer
  • Publication number: 20100076208
    Abstract: A process and catalyst for the hydro-oxidation of an olefin having three or more carbon atoms, such as propylene, to form an olefin oxide, such as propylene oxide. The process involves contacting the olefin with oxygen in the presence of hydrogen and a hydro-oxidation catalyst under reaction conditions; the catalyst comprising gold nanoparticles deposited on a nanoporous titanium-containing support, prepared by depositing a gold-ligand cluster complex onto the support to form a catalyst precursor, and then heating and/or chemically treating the catalyst precursor to form the hydro-oxidation catalyst composition. The hydro-oxidation catalyst exhibits stabilized catalyst activity, enhanced lifetime, and improved hydrogen efficiency.
    Type: Application
    Filed: November 7, 2007
    Publication date: March 25, 2010
    Inventors: Sandeep S. Dhingra, Rick C. Schroden, Keith J. Watson, David G. Barton, Robert G. Bowman, Larry N. Ito, David L. Trent, Heiko Weiner
  • Publication number: 20100075842
    Abstract: Disclosed herein is a method of producing a catalyst for storing nitrogen oxides, including: supporting a potassium oxide on alumina, which serves as a support, and then calcining the alumina supported with the potassium oxide at a high temperature, thus chemically bonding potassium oxide with the alumina. The method is advantageous in that a catalyst for storing nitrogen oxides, having high nitrogen oxide storage capacity and excellent hydrothermal stability, can be produced at low cost through a simple process.
    Type: Application
    Filed: November 19, 2006
    Publication date: March 25, 2010
    Inventors: Hyun-Sik Han, Gon Seo, Young-San Yoo, Se-Min Park
  • Publication number: 20100065420
    Abstract: An electrode for effective ozone production in an electrochemical cell uses a modified electrode design which adopts a novel catalytic component. The catalytic component has a number of elements selected from various metals and metalloids, and is applied to a substrate in multiple coatings or layers. The catalytic component forms a catalytic surface which is at least partially disrupted by the presence of an element which is relatively inactive with respect to oxygen evolution.
    Type: Application
    Filed: June 19, 2007
    Publication date: March 18, 2010
    Applicant: CLARIZON LIMITED
    Inventors: Paul Andrew Christensen, Wen Feng Lin
  • Publication number: 20100069233
    Abstract: Nanomaterials of the JT phase of the titanium oxide TiO2-x, where 0?x?1 having as a building block a crystalline structure with an orthorhombic symmetry and described by at least one of the space groups 59 Pmmn, 63 Amma, 71 Immm or 63 Bmmb. These nanomaterials are in the form of nanofibers, nanowires, nanorods, nanoscrolls and/or nanotubes. The nanomaterials are obtained from a hydrogen titanate and/or a mixed sodium and hydrogen titanate precursor compound that is isostructural to the JT crystalline structure. The titanates are the hydrogenated, the protonated, the hydrated and/or the alkalinized phases of the JT crystalline phase that are obtained from titanium compounds such as titanium oxide with an anatase crystalline structure, amorphous titanium oxide, and titanium oxide with a rutile crystalline structure, and/or directly from the rutile mineral and/or from ilmenite.
    Type: Application
    Filed: November 23, 2009
    Publication date: March 18, 2010
    Applicant: INSTITUTO MEXICANO DEL PETROLEO
    Inventors: Jose Antonio Toledo Antonio, Carlos Angeles Chavez, Maria Antonia Cortes Jacome, Fernando Alvarez Ramirez, Yosadara Ruiz Morales, Gerardo Ferrat Torres, Luis Francisco Flores Ortiz, Esteban Lopez Salinas, Marcelo Lozada y Cassou
  • Patent number: 7674743
    Abstract: This catalyst system simultaneously removes ammonia and enhances net NOx conversion by placing an NH3—SCR catalyst formulation downstream of a lean NOx trap. By doing so, the NH3—SCR catalyst adsorbs the ammonia from the upstream lean NOx trap generated during the rich pulses. The stored ammonia then reacts with the NOx emitted from the upstream lean NOx trap-enhancing the net NOx conversion rate significantly, while depleting the stored ammonia. By combining the lean NOx trap with the NH3—SCR catalyst, the system allows for the reduction or elimination of NH3 and NOx slip, reduction in NOx spikes and thus an improved net NOx conversion during lean and rich operation.
    Type: Grant
    Filed: December 1, 2008
    Date of Patent: March 9, 2010
    Assignee: Ford Global Technologies, LLC
    Inventors: Haren Sakarai Gandhi, John Vito Cavataio, Robert Henry Hammerle, Yisun Cheng
  • Publication number: 20100056360
    Abstract: Magnetic mesoporous materials as chemical catalyst and methods of making magnetic mesoporous materials as catalyst are provided. The mesoporous materials have mesopores. The mesoporous materials can contain magnetic nanoparticles in wall of the mesoporous material and chemical catalysts in the mesopores. The mesoporous material continaing magnetic nanoparticles and catalysts can be used in a chemical reaction as a catalyst. The mesoporous materials can be removed after the chemical reaction by applying a magnetic field to the chemical reaction medium to isolate the mesoporous materials containing magnetic nanoparticles.
    Type: Application
    Filed: August 29, 2008
    Publication date: March 4, 2010
    Inventor: Kwangyeol Lee
  • Publication number: 20100056363
    Abstract: Disclosed is a method of processing a polycrystalline nanoparticle. The method includes exposing a polycrystalline nanoparticle that includes at least two metal oxide crystallites bonded to each other to a chemical composition that includes a catalyst in order to at least partially separate the at least two metal oxide crystallites of the polycrystalline nanoparticle at an interface thereof.
    Type: Application
    Filed: August 29, 2008
    Publication date: March 4, 2010
    Inventor: Kwangyeol Lee
  • Publication number: 20100056362
    Abstract: A substrate, such as a glass, glass ceramic, ceramic or metal substrate, is provided with a thermocatalytically active coating on at least a part of the substrate surface. The thermocatalytic coating contains an inorganic lithium salt or organic lithium-containing compound in an amount that is equivalent to not less than 2 wt. % of lithium ions, based on total coating weight. The thermocatalytic coating has a glass, glass solder or sol-gel matrix in which the lithium salt or organic lithium-containing compound is introduced. Optional barrier and IR-reflecting layers are arranged between the substrate surface and the thermocatalytically active coating.
    Type: Application
    Filed: August 21, 2009
    Publication date: March 4, 2010
    Inventors: Inka Henze, Hrabanus Hack, Gerhard Weber, Hans-Joachim Schmitt, Wolfgang Schmidbauer, Torsten Gabelmann
  • Publication number: 20100056839
    Abstract: A process for the production of propylene, the process including: contacting ethylene and a hydrocarbon stream comprising 1-butene and 2-butene with a bifunctional isomerization-metathesis catalyst to concurrently isomerizes 1-butene to 2-butene and to form a metathesis product comprising propylene; wherein the bifunctional isomerization-metathesis catalyst comprises: a catalyst compound may include at least one element selected from tungsten, tantalum, niobium, molybdenum, nickel, palladium, osmium, iridium, rhodium, vanadium, ruthenium, and rhenium for providing metathesis activity on a support comprising at least one element from Group IA, IIA, IIB, and IIIA of the Periodic Table of the Elements; wherein an exposed surface area of the support provides both isomerization activity for the isomerization of 1-butene to 2-butene; and reactive sites for the adsorption of catalyst compound poisons.
    Type: Application
    Filed: September 4, 2009
    Publication date: March 4, 2010
    Applicants: LUMMUS TECHNOLOGY INC., BASF CATALYSTS LLC
    Inventors: Bala Ramachandran, Sukwon Choi, Robert J. Gartside, Shane Kleindienst, Wolfgang Ruettinger, Saeed Alerasool
  • Patent number: 7670986
    Abstract: A manganese dioxide catalyst for hydrolysing organic nitrites which bear readily oxidizable groups such as thiol or thioether groups to the corresponding carboxamides, and to a process for preparing the catalyst and to its use for hydrolysing organic nitrites.
    Type: Grant
    Filed: October 5, 2006
    Date of Patent: March 2, 2010
    Assignee: Degussa AG
    Inventors: Horst Weigel, Axel Ronneburg, Christoph Weckbecker
  • Patent number: 7670985
    Abstract: The invention provides an activated carbon supported cobalt based catalyst for directly converting of synthesis gas to mixed linear alpha-alcohols and paraffins, comprising cobalt, an activated carbon carrier, a metal promoter which is at least one selected from the group consisting of a zirconium component, a lanthanum component, a cerium component, a chromium component, a vanadium component, a titanium component, a manganese component, a rhenium component, a potassium component, a ruthenium component, a magnesium component and a mixture thereof, wherein the cobalt and the promoter are deposited on the activated carbon carrier or substantially uniformly dispersed therein, and the metal promoter is present in the form of a metal, an oxide or a combination thereof.
    Type: Grant
    Filed: August 9, 2007
    Date of Patent: March 2, 2010
    Assignees: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, CNOOC New Energy Investment Co., Ltd.
    Inventors: Yunjie Ding, Hejun Zhu, Tao Wang, Guiping Jiao, Yuan Lv
  • Publication number: 20100048392
    Abstract: A catalyst for purifying exhaust gases includes a substrate, and projections. The substrate is provided with straight-flow gas-flow passages. The projections protrude from the straight-flow gas-flow passages in a height of 50 ?m or more, and include a precipitate, which is composed of at least one catalytic ingredient selected from the group consisting of alkali metals and alkaline-earth metals.
    Type: Application
    Filed: June 20, 2006
    Publication date: February 25, 2010
    Applicants: TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATION
    Inventors: Seiji Okawara, Takayuki Endo