Abstract: A composition is described that includes oxides of zirconium, cerium and another rare earth different from cerium, having a cerium oxide content not exceeding 50 wt % and, after calcination at 1000° C. for 6 hours, a maximal reducibility temperature not exceeding 500° C. and a specific surface of at least 45 m2/g. The composition can be prepared according to a method that includes continuously reacting a mixture that includes compounds of zirconium, cerium and another rare earth having a basic compound for a residence time not exceeding 100 milliseconds, wherein the precipitate is heated and contacted with a surfactant before calcination.

Abstract: A zirconium-based mixed oxide or zirconium-based mixed hydroxide which is capable of (a) at least 90% v/v conversion of naphthalene at atmospheric pressure at a temperature in the range 600-700° C. using a residence time of about 0.3 seconds, and/or (b) providing an initial heat of adsorption of ammonia of greater than 150 kJ/mol when measured by ammonia flowing gas microcalorimetry. Also, a method for purifying gas produced from the gasification of carbonaceous materials, comprising the step of bringing the gas into contact with such mixed oxides or mixed hydroxides.

Abstract: A catalyst for the manufacture of alkylene oxide, for example ethylene oxide, by the vapor-phase epoxidation of alkene containing impregnated silver and at least one efficiency-enhancing promoter on an inert, refractory solid support, said support incorporating a sufficient amount of zirconium component (present and remaining substantially as zirconium silicate) as to enhance at least one of catalyst activity, efficiency and stability as compared to a similar catalyst which does not contain the zirconium component.

Abstract: A process is described for producing a powder batch comprises a plurality of particles, wherein the particles include (a) a first catalytically active component comprising at least one transition metal or a compound thereof; (b) a second component different from said first component and capable of removing oxygen from, or releasing oxygen to, an exhaust gas stream; and (c) a third component different from said first and second components and comprising a refractory support. The process comprises providing a precursor medium comprising a liquid vehicle and a precursor to al least one of said components (a) to (c) and heating droplets of said precursor medium carried in a gas stream to remove at least part of the liquid vehicle and chemically convert said precursor to said at least one component.

Abstract: Provided are improved regenerable SOx trap formulations for on-board vehicle applications. The regenerable sulfur trap formulations reduce the rate of sulfur poisoning of a downstream nitrogen storage reduction (NSR) catalyst trap in exhaust gas cleaning systems for combustion engines by adsorbing SOx as metal sulfate under lean exhaust conditions and desorbing the accumulated SOx under rich exhaust conditions. The regenerable sulfur oxides trap catalyst compositions include a metal (M) oxide, wherein M is selected from Cu, Fe, Mn, Ag, Co and combinations thereof and a metal (M)-La—Zr oxide, wherein M is selected from Cu, Fe, Mn, Ag, Co and combinations thereof. In addition, provided are improved exhaust gas cleaning systems and methods for treating exhaust gas from a combustion source that include a hydrogen generation system, a regenerable sulfur oxides trap, and a regenerable nitrogen storage reduction (NSR) catalyst trap.

Abstract: A nickel-based catalyst is provided for reducing carbon monoxide, hydrocarbon emissions, and nitrogen oxides from vehicle exhausts. The catalyst is impregnated directly onto a carrier which is non-reactive with nickel. The nickel is contained on said carrier at a loading of between about 2 to about 20 wt %. When used in a vehicle exhaust gas treatment system, the catalyst provides improved efficiency in reducing CO, HC, and NOx emissions over the use of conventional three-way-catalysts.

Abstract: A catalyst system includes a first catalytic composition and a second catalytic composition. The first catalytic composition includes a homogeneous solid mixture, which includes a first catalytic material disposed on a first substrate. The pores of the solid mixture have an average diameter of greater than about 45 nanometers. The second catalytic composition includes at least one of a zeolite or a second catalytic material disposed on a second substrate. The second catalytic material includes an element selected from the group that includes tungsten, titanium, and vanadium.

Abstract: A catalyst for treating exhaust gases containing nitrogen monoxide, carbon monoxide and volatile organic compounds includes a plurality of layers, an upper layer of which has an active component contained uniformly therein and a lower layer of which has no active component contained therein. The catalyst is obtained through the steps of: forming the lower layer by coating the surface of substrate with a slurry of a porous inorganic compound, followed by drying; and forming the upper layer, which is to be the top surface of the catalyst, by coating the surface of the lower layer with a slurry of a porous inorganic compound that has the active component composed of one or more precious metals supported thereon, followed by drying. The oxidation power of the resulting catalyst is enhanced without increasing the amount of precious metal supported thereon.

Abstract: A nanocomposite particle, its use as a catalyst, and a method of making it are disclosed. The nanocomposite particle comprises titanium dioxide nanoparticles, metal oxide nanoparticles, and a surface stabilizer. The metal oxide nanoparticles are formed hydrothermally in the presence of the titanium dioxide nanoparticles. The nanocomposite particle is an effective catalyst support, particularly for DeNOx catalyst applications.

Abstract: Catalyzed soot filters comprising a wall flow monolith having a washcoat comprising an alkali base metal composite disposed on the monolith. Methods of manufacturing and using catalyzed soot filters and diesel engine exhaust emission treatment systems are also disclosed.

Abstract: An exhaust gas purifying catalyst 1 has a catalyst substrate 3 and catalyst coating layers 5, 7 that are formed on the catalyst substrate 3 and contain (a) Rh, (b) Pt, (c) an alkali metal or alkaline earth element, and (d) an inorganic oxide. The catalyst coating layers 5, 7 has a layered structure including an inside layer 5 where the component (a) is substantially locally existing, and an outside layer 7 where the component (b) is substantially locally existing. The inside layer 5 also contains a zirconia oxide.

Abstract: An exhaust gas purifying catalyst (1) according to the present invention includes noble metal particles (6), a first compound (7) supporting the noble metal particles (6), and a second compound (9) disposed not in contact with the noble metal particles (6) and having an oxygen storage capacity. An average distance between the first compound (7) and the second compound (9) is between 5 nm and 300 nm.

Abstract: The invention relates to a catalyst for the reaction of formaldehyde with a carboxylic acid or ester to produce an ethylenically unsaturated carboxylic acid or ester, preferably ?, ? ethylenically unsaturated carboxylic acids or ester. The catalyst includes a metal oxide having at least two types of metal cations, M1 and M2, wherein M1 is at least one metal selected from group 3 or 4 in the 4th to 6th periods of the periodic table, group 13 in the 3rd to 5th periods of the periodic table, or the remaining elements in the lanthanide series and M2 is at least one metal selected from group 5 in the 5th or 6th periods of the periodic table or group 15 in the 4th or 5th periods of the periodic table. The production includes reacting formaldehyde with a carboxylic acid or esterin the presence of the catalyst effective to catalyse the reaction.

Abstract: The present invention relates to a catalyst for hydrocarbon steam cracking, a method of preparing the same, and a method of preparing olefin by the hydrocarbon steam cracking by using the catalyst, and more specifically, to a catalyst for hydrocarbon steam cracking for preparing light olefin including an oxide catalyst (0.5?j?120, 1?k?50, A is transition metal, and x is a number corresponding to the atomic values of Cr, Zr, and A and values of j and k) represented by CrZrjAkOx, wherein the composite catalyst is a type that has an outer radius r2 of 0.5R to 0.96R (where R is a radius of a cracking reaction tube), a thickness (t; r2?r1) of 2 to 6 mm, and a length h of 0.5r2 to 10r2, a method of preparing the same, and a method of preparing light olefins by using the same.

Abstract: Disclosed herein are photocatalyst powder and a production method thereof, and by having photocatalyst particles corn binded without reduction of a specific surface area, the reduction of the specific surface area is nearly none while the pores are developed, as well as the absorption rate with respect to light is superior, the method of producing photocatalyst powder includes forming initial photocatalyst powder by molding nanoparticles of photocatalyst substance into a certain shape through extrusion, and splitting the initial photocatalyst powder into a plurality of photocatalyst powder by injecting the initial photocatalyst powder into a predetermined splitting solution, the initial photocatalyst powder being split into the plurality of photocatalyst powder by the predetermined spliting solution.

Abstract: The present invention details a process for producing a catalyst powder. The steps of the process include preparing catalyst slurry, drying, pyrolyzing, and calcining the catalyst slurry to obtain a calcined catalyst powder. The catalyst slurry comprises a catalyst, a liquid carrier, a templating agent, and a catalyst substrate. The catalyst slurry is dried to obtain a raw catalyst powder. The raw catalyst powder is heated in a first controlled atmosphere to obtain a pyrolyzed catalyst powder and the pyrolyzed catalyst powder is calcined in a second controlled atmosphere to obtain a calcined catalyst powder. A method of fabricating a catalyst surface and catalytic converter using the prepared catalyst powder is also illustrated.

Abstract: The present invention is directed to a catalyst suitable for catalyzing a Fischer-Tropsch reaction, said catalyst comprising cobalt metal supported on zinc-oxide and an amount of zirconium(IV)oxide and/or aluminum oxide of between 0.5 and 2.5 wt. % calculated as metal, based on the weight of the calcined catalyst.

Abstract: A composite material includes an aggregate which contains a first metal particle constituting a core and second metal oxide particulates surrounding the first metal particle and having an average primary particle diameter ranging from 1 to 100 nm.

Abstract: Nanowires useful as heterogeneous catalysts are provided. The nanowire catalysts are useful in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons. Related methods for use and manufacture of the same are also disclosed.

Abstract: A first layer of a catalyst material is formed on a substrate and heat treated to form a first plurality of nanoparticles. A second layer of a catalyst material is then formed over the substrate and the first plurality of nanoparticles and heat treated to form a second plurality of nanoparticles. The first layer of nanoparticles is advantageously not affected by the deposition or heat treatment of the second layer of catalyst material, for example being pinned or immobilised, optionally by oxidation, before formation of the second layer.

Abstract: A gas fired catalytic heater is provided that foregoes the need for an electrical heating element to provide the activation energy for the hydrocarbon catalyst pad. An alcohol self-igniting catalyst pad is used to provide the activation energy to the hydrocarbon catalyst pad thereby removing dependence of the heater on an outside electrical energy source to initiate start-up of the heater. The catalyst pad includes a flexible wash coat; a noble metal dispersed on the wash coat; an anti-sintering element saturating the wash coat; and a catalyst promoter saturating the wash coat.

Abstract: A shell catalyst for the preparation of vinyl acetate monomer, comprising an oxidic porous catalyst support with an outer shell, containing metallic Pd and Au, wherein the framework structure of the porous catalyst support contains hafnium oxide units. This shell catalyst is suitable for the preparation of VAM and is characterized by a relatively high activity and VAM selectivity and maintains this activity and selectivity over relatively long service lives. Also, processes for the preparation and use of the shell catalyst.

Abstract: A non-noble metal based catalyst includes a compound represented by Formula 1: ZraMbOxNy??[Formula 1] where M is at least one element selected from Group 4 elements through Group 12 elements, a is a number in the range of about 1 to about 8, b is a number in the range of 1 to 8, x is a number in the range of about 0.2 to about 32, and y is a number in the range of about 0.2 to about 16. A fuel cell electrode and fuel cell may be formed using the non-noble metal based catalyst.

Abstract: The inventive composition, according to a first embodiment, consists essentially of a cerium oxide and a zirconium oxide in an atomic ratio Ce/Zr of at least 1. According to a second embodiment, said composition is based on cerium oxide, zirconium oxide with an atomic ratio Ce/Zr of at least 1 and at least one rare earth oxide other than cerium. After calcination at 1100° C., said composition has a specific surface of at least 9 m2/g in the second embodiment. The inventive composition can be used as a catalyst especially for the treatment of waste gases from internal combustion engines.

Abstract: According to the present invention, the catalyst performance of a chelate catalyst comprising a complex of a macrocyclic compound such as a porphyrin derivative is improved. Also, the following method is provided: a method for preparing a fuel cell electrode catalyst comprising a nitrogen-containing metal complex in which a metallic element is coordinated with a macrocyclic organic compound, such method comprising the steps of: adding tin oxalate to the nitrogen-containing metal complex; and baking a mixture of the nitrogen-containing metal complex and tin oxalate in an inert gas atmosphere, wherein elution of metal tin is carried out via acid treatment.

Abstract: A new type of solid acid catalyst, which promises better catalytic performance than conventionally prepared supported metal oxides due to its precisely synthesized nanostructure has been described. The catalyst is nanoparticulate in form and is comprised of monolayers of tungstated zirconia of the formula, WOxZryO4-2y made by impregnating a support with zirconium and tungsten. The support catalyst is further characterized in having a tugsten monolayer between greater than 0001 W/nm2 to about 30 W/nm2.

Abstract: A catalyst which remediates hydrocarbon fuel combustion exhaust, including a non-PGM containing aerogel which catalyzes the oxidation of carbon monoxide and hydrocarbons and the reduction of nitrogen oxides present in the exhaust, a catalytic converter made therefrom, and a method for the production thereof is disclosed.

Abstract: The present invention provides an improved fluidized catalytic cracking process coupled with a two stage regeneration process in which the activity of the circulating catalyst is independently controlled for cracking hydrocarbon feedstocks or the vapors at low severity to produce maximum light cycle oil/distillate in one riser whilst cracking recycle streams comprising heavy cycle oil (HCO), light cracked naphtha (LCN) etc. in a second riser operating at high severity to produce LPG.

Abstract: Through innovative design of a titanium dioxide coated metal reflector, which uses the negative space of a U-shaped ultraviolet lamp, maximum airborne chemical, vapor and/or odor abatement through photochemical reaction, yet eliminates most UV irradiation obstruction emanating from the lamp, thereby insuring maximum germicidal effect.

Abstract: Ceria-coated aerogels can include an aerogel support material having a stabilized ceria coating thereon. The ceria coating can be formed by solution or vapor deposition of alcogels or aerogels. Additional catalytic metal species can also be incorporated into the coating to form multi-metallic compounds having improved catalytic activity. Further, the ceria coated aerogels retain high surface areas at elevated temperatures. Thus, improvements in catalytic activity and thermal stability can be achieved using these ceria-coated composite aerogels.

Abstract: This invention relates to crystalline boehmitic aluminas the crystallites of which exhibit unusual dimensional differences in the space directions 020 and 120. This invention further relates to a method for preparing such aluminas and the follow-up products obtained therefrom by calcination.

Abstract: The present invention relates to oxygen storage components for catalytic converters for automobile exhaust systems, particularly for those with petrol-driven engines. In accordance with the present invention there is provided a ceria containing mixed oxide suitable as an oxygen storage material having a ceria content in the range 10 to 80% by weight and at least one metal oxide in an amount of less than 0.5% by weight, wherein the metal is selected from the first row transition elements and the group IVB elements of the periodic table. The inventions also provides an oxygen storage material for catalytic converters for automobile exhaust systems comprising an oxide of the present invention.

Abstract: Especially physically stable metal oxide catalyst supports are prepared by suspending a metal oxide in a continuous phase, activating by fine dispersion, coagulation to a viscoelastic mass, shaping, drying, and calcining. The catalyst support thus prepared may be treated with catalytic agents to produce supported catalysts for olefin oxidation.

Abstract: The present invention is directed to a granulate having photocatalytic activity, comprising particles of an inorganic particulate material coated with a photocatalytically active compound for introducing photocatalytic activity into or on building materials. The invention is further related to the manufacture of such a granulate and its use into or on building materials such as cement, concrete, gypsum and/or limestone and water-based coatings or paints for reducing an accumulation and growth of microorganisms and environmental polluting substances on these materials and thus reducing the tendency of fouling, while the brilliance of the color is maintained and the quality of the air is improved.

Abstract: A method of preparing a catalyst coating solution may realize high purification performance by preventing the active surface of a catalyst from being reduced, and may greatly improve the durability of a catalyst by preventing soot from directly coming into contact with a catalyst layer containing a precious metal so that the catalyst layer can continuously exhibit proper purification performance. A method of manufacturing a catalyst body using the catalyst coating solution, and a catalyst body manufactured by the method are also described.

Abstract: Provided is a catalyst for fuel reformation that causes carbon monoxide contained in hydrogen gas, which is produced from a variety of hydrocarbon fuels, to react with hydrogen and thereby to be transformed into methane, while inhibiting methanation of carbon dioxide contained in the hydrogen gas. The selective CO methanation catalyst includes at least one of a halogen, an inorganic acid, and a metal oxo-acid adsorbed or bonded as a carbon dioxide reaction inhibitor to a carbon monoxide methanation active component.

Abstract: Systems and methods for the maintenance of active chromium-based catalysts and their use in polymerization processes are described. In one embodiment, a system for the introduction of multiple polymerization components to activate a chromium based catalyst within a mix tank is described. Other described features may include materials and methods to purify the liquid medium of a catalyst slurry so that the catalyst slurry maintains a high level of activity. The active chromium-based catalyst may provide polyolefins with a number of desirable properties in a reliable, consistent, and predictable manner.

Abstract: The invention relates to a particle blend comprising mainly or consisting of an oxide phase of the pseudo-brookite type comprising at least titanium and aluminum, said blend being obtained from at least two particle size fractions, namely a coarse particle size fraction, the median diameter d50 of which is greater than 12 microns, and a fine particle size fraction, the median diameter d50 of which is between 0.5 and 3 microns, the mass ratio of said coarse fraction to said fine fraction being between 1.5 and 20, limits inclusive, and the ratio of the median diameter of the coarse fraction to that of the fine fraction being greater than 12.

Abstract: It is provided that the catalyst shows a high activity in an ammonia decomposition reaction and can efficiently decompose ammonia into hydrogen and nitrogen. The catalyst for decomposing ammonia of the present invention comprises at least one element (component (A)) selected from the elements of groups 6 to 10 of the long-form periodic table, and an oxide and/or complex oxide of at least one element (component (B)) selected from the elements of groups 2 to 5 and groups 12 to 15 of the long-form periodic table, wherein the calculated specific surface area (S2) of the component (A) is 20 m2/g or larger, and the ratio (S2/S1) of the calculated specific surface area (S2) of the component (A) to the specific surface area (S1) of the catalyst per se is 0.15 to 0.85.

Abstract: A composite oxide is provided which has large oxygen absorption and desorption over a wide temperature range, in particular in a higher temperature range of not lower than 700° C. and/or in a lower temperature range of not higher than 400° C. The composite oxide contains oxygen, R composed of at least one of Ce and Pr, and Zr at a particular ratio, and optionally a particular ratio of M composed of at least one element selected from alkaline earth metals and the like.

Abstract: A supported oxidation catalyst includes a support having a metal oxide or metal salt, and mixed metal particles thereon. The mixed metal particles include first particles including a palladium compound, and second particles including a precious metal group (PMG) metal or PMG metal compound, wherein the PMG metal is not palladium. The oxidation catalyst may also be used as a gas sensor.

Abstract: An article for treating a gas containing nitrogen oxides having a monolith substrate loaded with a catalytic composition containing at least one catalytic component consisting of (i) at least one transition metal dispersed on a mixed oxide or composite oxide or a mixture thereof as support material consisting of cerium and zirconium; or (ii) cerium oxide and zirconium oxide as single oxides or a composite oxide thereof or a mixture of the single oxides and the composite oxide dispersed on an inert oxide support material, wherein at least one transition metal is dispersed thereon, wherein the at least one transition metal is selected from the group consisting of a metal from Group VIB, IB, IVA, VB, VIIB, and VIII and mixtures of any two or more thereof, provided that at least one selected transition metal is tungsten, wherein the catalytic composition is disposed on said monolith substrate.

Abstract: A catalyst system comprising a first catalytic composition comprising a first catalytic material disposed on a metal inorganic support; wherein the metal inorganic support has pores; and at least one promoting metal. The catalyst system further comprises a second catalytic composition comprising, (i) a zeolite, or (ii) a first catalytic material disposed on a first substrate, the first catalytic material comprising an element selected from the group consisting of tungsten, titanium, and vanadium. The catalyst system may further comprise a third catalytic composition. The catalyst system may further comprise a delivery system configured to deliver a reductant and optionally a co-reductant. A catalyst system comprising a first catalytic composition, the second catalytic composition, and the third catalytic composition is also provided. An exhaust system comprising the catalyst systems described herein is also provided.

Abstract: The present invention provides a method for producing a catalyst for use in preferential carbon monoxide oxidation, which catalyst has a high preferential carbon monoxide oxidation activity and a high methanation activity with respect to the carbon monoxide contained in hydrogen gas, can thus stably reduce the carbon monoxide concentration to an extremely lower level and comprises porous inorganic oxide support particles and, on the basis of the mass thereof, 0.01 to 10 percent by mass of ruthenium and 0.01 to 1 percent by mass of platinum, loaded on the support. The method comprises (1) a step of loading 30 to 70 percent of the total amount of ruthenium to be loaded, on the support particles by a competitive adsorption method and (2) a step of loading the rest of the total amount of ruthenium to be loaded and the total amount of platinum to be loaded, on the ruthenium-loaded support particles produced in step (1) without using a competitive adsorption agent.

Abstract: The invention concerns a homogeneous bed of particles of a catalyst, said catalyst comprising at least one amorphous matrix, at least one noble metal, at least one additional metal M and at least one halogen, and in which, for a catalyst particle, CPt is the local concentration of noble metal Pt; CM is the local concentration of additional metal M; CX is the local concentration of halogen; said catalyst being in the form of a homogeneous bed of particles, in which across the diameter of the particle, at least 70% of the values CPt/CM or CPt/CX differ from the mean local ratio by at most 30%, and in which the mole ratio M/Pt in the catalyst is in the range 1.8 to 6.

Abstract: Extruded isomerization catalysts comprising MgO, a metal silicate clay binder and a stabilizer and methods of forming such isomerization catalysts are disclosed. Also disclosed are isomerization catalysts that exhibit a fresh isomerization rate and an aged isomerization rate that is at least 50% of the fresh isomerization rate. Embodiments of the isomerization catalysts disclosed herein include metal silicate clay binders that include a layered structure and metal silicate. The metal silicate clay binder may be present in an amount in the range from about 5 wt % to about 20 wt %. Exemplary stabilizers include one or more of ZrO2, tetravalent rare earth metal and a trivalent rare earth metal. Stabilizers may be present in an amount up to about 40 wt %. One or more improved properties, such as piece crush strength and isomerization performance, are exhibited by the catalyst article.

Abstract: A low sidestream smoke cigarette comprises a conventional tobacco rod, and a combustible treatment paper having a sidestream smoke treatment composition. The treatment composition comprises in combination, an oxygen storage and donor metal oxide oxidation catalyst and an essentially non-combustible finely divided porous particulate adjunct for said catalyst.

Abstract: The noble metal fine particle supported catalyst of the present invention includes a substrate, and a porous membrane formed on the substrate. The porous membrane contains support particles, noble metal fine particles, and an inorganic binder. In the porous membrane, the noble metal fine particles are supported on surfaces of the support particles, and the support particles form secondary particles each having a porous structure. The porous membrane is formed by binding, with the inorganic binder, the secondary particles formed of the support particles so that a gap is present at least partly between the secondary particles adjacent to each other.

Abstract: An exhaust gas purification catalyst, which is suitable as a three way catalyst for efficiently purifying carbon monoxide (CO), hydrocarbons (HC), and nitrogen oxides (NOx) in exhaust gas discharged from a gasoline automobile and exhaust gas purification apparatus using the same and an exhaust gas purification method. <The upper layer> A catalyst composition having an activated metal (A), a heat resistant inorganic oxide (B) and a cerium-zirconium-type composite oxide (C) containing a pyrochlore phase in a crystal structure, wherein the activated metal (A) is rhodium. <The lower layer> A catalyst composition having an activated metal (A), a heat resistant inorganic oxide (B) and a cerium-containing oxide (C?) having a cubic crystal and/or tetragonal crystal structure as a major crystal structure, wherein the activated metal (A) is palladium, or palladium and platinum.

Abstract: Disclosed herein is a catalyst for producing biodiesel, including a carrier having water resistance and an active component supported on the carrier and used in a hydrotreating reaction or a decarboxylation reaction. Since the catalyst for producing biodiesel includes a carrier having strong water resistance, the deactivation of the catalyst due to the water produced through a process of producing HBD can be prevented, thus remarkably improving the long term stability of a catalyst.