Free Carbon Containing Patents (Class 502/416)
  • Patent number: 6547861
    Abstract: Trace impurities such as organic compounds and carbon monoxide in reactive fluids such as ammonia, hydrogen chloride, hydrogen bromide, and chlorine are reduced to sub-ppb levels using gas purifying systems that contain a preconditioned ultra-low emission (P-ULE) carbon. P-ULE is capable of removing impurities from a reactive fluid down to parts-per-billion (ppb) and sub-ppb levels without concurrently emitting other impurities such as moisture or carbon dioxide into the purified reactive fluid. The P-ULE carbon is prepared by heating a carbon material to temperatures from 300° to about 800° C. in an ultra-dry, inert gas stream, to produce an ultra-low emission (ULE) carbon material, subjecting the ULE carbon to a second activation process under a reactive gas atmosphere to produce a P-ULE carbon and storing the P-ULE carbon in an environment that minimizes contamination of the P-ULE prior to its use in a gas purifier system.
    Type: Grant
    Filed: February 6, 2001
    Date of Patent: April 15, 2003
    Assignee: Matheson Tri-Gas,, Inc.
    Inventors: Hans H. Funke, Dan Fraenkel, Virginia H. Houlding
  • Patent number: 6544648
    Abstract: A carbon based material produced from the consolidation of amorphous carbon by elevated temperature compression. The material having unique chemical and physical characteristics that lend themselves to a broad range of applications such as in electrical, electrochemical and structural fields.
    Type: Grant
    Filed: September 28, 2000
    Date of Patent: April 8, 2003
    Assignee: Reticle, Inc.
    Inventors: Carl C. Nesbitt, Xiaowei Sun
  • Patent number: 6537947
    Abstract: Activated carbons derived from low-density lignocellulosic agricultural waste, and for use in absorption of metals, are prepared utilizing carbon dioxide or steam activation at 800° C. to 950° C. for 3 to 12 hours and subsequent oxidation with air at 260° C. to 400° C. for 3 to 6 hours. Granular carbons are formed by the inclusion of a preliminary two-step process involving the admixture of a binder selected from molasses, coal tar or wood tar to form pellets, briquettes or extrudates and converting them into a char under an inert atmosphere at 700° C. to 750° C. for 1 to 2 hours.
    Type: Grant
    Filed: April 11, 1997
    Date of Patent: March 25, 2003
    Assignees: The United States of America as represented by the Secretary of Agriculture, Board of Supervisors of Louisiana State Univ. of Agricultural & Mechanical College
    Inventors: Mitchell M. Johns, Christopher A. Toles, Wayne E. Marshall
  • Publication number: 20030054957
    Abstract: A process for the preparation of nanoscale particulate material is described comprising: (i) combining one or more functional material to be precipitated as nanoscale particles and one or more surface active material in a compressed CO2 phase with a density of at least 0.1 g/cc, where the functional material is substantially insoluble in the compressed CO2 in the absence of the surfactant, the surfactant comprises a compressed CO2-philic portion and a functional material-philic portion, and the compressed CO2 phase, functional material and surfactant interact to form an aggregated system having a continuous compressed CO2 phase and a plurality of aggregates comprising surfactant and functional material molecules of average diameter less than 10 nanometers dispersed therein; and (ii) rapidly depressurizing the compressed CO2 phase thereby precipitating the dispersed functional and surfactant materials in the form of composite particles of average diameter from 0.5 to less than 10 nanometers.
    Type: Application
    Filed: July 11, 2002
    Publication date: March 20, 2003
    Inventors: Glen C. Irvin, Ramesh Jagannathan, Seshadri Jagannathan, Suresh Sunderrajan, David D. Tuschel, William C. Lenhart, David J. Nelson
  • Publication number: 20030041734
    Abstract: Trace impurities such as organic compounds and carbon monoxide are reduced to sub-ppb levels in gases such as nitrogen, helium and argon, by gas purifying systems that contain an ultra-low emission (ULE) carbon material. Ultra-low emission (ULE) carbon materials is capable of removing impurities from a gas stream down to parts-per-billion (ppb) and sub-ppb levels without concurrently emitting other impurities such as moisture or carbon dioxide to the purified gas stream. The carbon material is superactivated by heating the carbon to temperatures between 300-800° C. in an ultra-dry, inert gas stream. The ultra-low emission (ULE) carbon material is handled and stored in an environment that minimizes contamination from moisture and other oxygenated species in order to maintain its ppb and sub-ppb impurity removal and low emission properties.
    Type: Application
    Filed: October 2, 2002
    Publication date: March 6, 2003
    Inventors: Hans H. Funke, Dan Fraenkel, Virginia H. Houlding
  • Patent number: 6521200
    Abstract: A process for the recovery of sulphur trioxide, solutions of sulphuric acid, or organic derivatives thereof, using organic compounds and/or supercritical fluids, and catalyst. The process comprises the steps of passing a mixture of SO2 and an oxygen-containing gas over an activated carbon catalyst at a temperature of at least 15° C. and preferably at a pressure of 1-200 atmospheres, and stripping the activated carbon with either (i) a liquid organic compound selected from the group consisting of ketones, ethers, decalin, tetrahydrofurans, sulpholanes, glymes and formamides and which is non-reactive with sulphur trioxide or sulphuric acid, or (ii) a liquid organic compound capable of forming organic sulphates or sulphonates by reaction with sulphur trioxide or sulphuric acid. The process may be used to obtain sulphuric acid, or organic sulphates or sulphonates.
    Type: Grant
    Filed: November 7, 2000
    Date of Patent: February 18, 2003
    Assignee: University of Waterloo
    Inventors: Peter Lewis Silveston, Robert Ross Hudgins, Radu Valentin Vladea
  • Patent number: 6517906
    Abstract: A composite contains substrate fibers, and an activated organic coating, on the substrate fibers. The activated organic coating is formed at a low temperature, making possible the use of substrate fibers have a softening or decomposition temperature of at most 500° C.
    Type: Grant
    Filed: June 21, 2000
    Date of Patent: February 11, 2003
    Assignee: Board of Trustees of University of Illinois
    Inventors: James Economy, Christian Mangun, Zhongren Yue
  • Publication number: 20030024390
    Abstract: Trace impurities such as organic compounds in an inert, non-reactive or reactive liquid such as ammonia, hydrogen chloride, hydrogen bromide, and chlorine are reduced by at least a factor of 5 using liquid purifying systems that contain an ultra-low emission (ULE) carbon. The moisture level of the purified reactive liquid is only slightly higher than that of the contaminated liquid.
    Type: Application
    Filed: August 9, 2002
    Publication date: February 6, 2003
    Inventors: Hans H. Funke, Robert Torres, Carrie L. Wyse
  • Publication number: 20030024394
    Abstract: Trace impurities such as organic compounds and carbon monoxide in reactive fluids such as ammonia, hydrogen chloride, hydrogen bromide, and chlorine are reduced to sub-ppb levels using gas purifying systems that contain a preconditioned ultra-low emission (P-ULE) carbon. P-ULE is capable of removing impurities from a reactive fluid down to parts-per-billion (ppb) and sub-ppb levels without concurrently emitting other impurities such as moisture or carbon dioxide into the purified reactive fluid. The P-ULE carbon is prepared by heating a carbon material to temperatures from 300° C. to about 800° C. in an ultra-dry, inert gas stream, to produce an ultra-low emission (ULE) carbon material, subjecting the ULE carbon to a second activation process under a reactive gas atmosphere to produce a P-ULE carbon and storing the P-ULE carbon in an environment that minimizes contamination of the P-ULE prior to its use in a gas purifier system.
    Type: Application
    Filed: October 2, 2002
    Publication date: February 6, 2003
    Inventors: Hans H. Funke, Dan Fraenkel, Virginia H. Houlding
  • Patent number: 6514906
    Abstract: A carbonaceous char is provided having a reduced inherent carbon catalytic activity. The char is derived from one or more of the following: wood, nutshell, fruitstone, peat, lignite, sub-bituminous coal, bituminous coal, semi-anthracite coal, anthracite coal and organic polymers, and has an inherent or “MOD 12” t-¾ time equal to or greater than 125 minutes or a maximum delta T less than or equal to 20° C. The MOD 12 t-¾ time is equal to the elapsed time required for 0.250 grams of said carbonaceous char, pulverized, to decompose from ambient temperature and under adiabatic conditions three-fourths of 0.42 moles of hydrogen peroxide contained in 150 mL of an aqueous solution containing a buffer having a pH of about 12. The maximum delta T is the absolute temperature difference between ambient temperature and the maximum temperature achieved by the hydrogen peroxide decomposition wherein the carbonaceous char has been inertly calcined at temperatures above 700° C.
    Type: Grant
    Filed: May 14, 1998
    Date of Patent: February 4, 2003
    Assignee: Calgon Carbon Corporation
    Inventor: Richard A. Hayden
  • Patent number: 6514907
    Abstract: A bromine-impregnated activated carbon wherein the contents of any alkali metal, any alkali earth metal and iron are not higher than 0.3 wt % and the content of bromine is not lower than 3 wt %, with respect to the weight of a material activated carbon. The bromine-impregnated activated carbon has improved adsorption characteristics to the alkyl sulfides, which have not been sufficiently removed by activated carbons prepared by the conventional techniques. Further, variations in the absorption characteristics can be reduced and the activated carbon can exhibit a stable performance in removing the alkyl sulfides.
    Type: Grant
    Filed: July 24, 1998
    Date of Patent: February 4, 2003
    Assignee: Takeda Chemical Industries, Ltd.
    Inventors: Yoshio Tsutsumi, Teruo Fukui, Katsuya Noguchi, Takashi Kobayashi, Ayako Kobayashi, Tsuyoshi Yoshidome
  • Patent number: 6503655
    Abstract: A thin, flat, and porous carbon gas diffusion electrode having a side in contact with a supply of gas and a side in contact with an electrolyte, comprises a pyrolysis product of a composite of an organic aerogel or xerogel and a reinforcing skeleton consisting at least in part of organic material. The porosity of the carbon gas diffusion electrode according to the invention can be regulated at will while the surface of the electrode is smooth.
    Type: Grant
    Filed: May 19, 2000
    Date of Patent: January 7, 2003
    Assignee: Siemens Aktiengesellschaft
    Inventors: Raino Petricevic, Jochen Fricke, Rainer Leuschner, Matthias Lipinski
  • Publication number: 20030003289
    Abstract: The invention concerns a composite material comprising activated carbon and expanded graphite. The material is a block wherein the activated carbon is homogeneously and uniformly distributed in the form of microporous particles. The texture of said particles is characterised by a microporous volume W0 ranging between 0.1 cm3g−1and 1.5 cm3g−1 and a mean pore dimension L0 ranging between 2 Å and 30 Å, the activated carbon particles have substantially the same texture wherever they are located in the composite material, the thermal conductivity levels of the material range between 1 and 100 Wm−1K−1. Said material is obtained by heat treatment of a mixture of expanded graphite and an activated carbon precursor in the presence of an activating temperature and for a time interval sufficient to obtain a wear rate of the activated carbon precursor ranging between 5 and 70 % by mass.
    Type: Application
    Filed: July 26, 2002
    Publication date: January 2, 2003
    Inventors: Xavier Py, Emmanuel Daguerre, Vincent Goetz, Bernard Spinner
  • Patent number: 6500984
    Abstract: A method is disclosed for producing phosgene which in one embodiment comprises contacting in at least one reactor a mixture comprising carbon monoxide and chlorine sequentially with a first catalyst followed by contacting the resulting gaseous reaction mixture comprising phosgene with at least one second catalyst of higher relative activity than a first catalyst. In another embodiment a method is disclosed for producing phosgene which comprises contacting in at least one reactor a mixture comprising carbon monoxide and chlorine with at least one catalyst bed comprising a first catalyst wherein at least a portion of said first catalyst is diluted with a second catalyst of higher relative activity than a first catalyst.
    Type: Grant
    Filed: January 25, 2002
    Date of Patent: December 31, 2002
    Assignee: General Electric Company
    Inventors: Francis Anthony Via, Grigorii Lev Soloveichlk, Philip George Kosky, Walter Vladimir Cicha
  • Patent number: 6475411
    Abstract: A method of making an adsorbent carbon fiber based monolith having improved methane gas storage capabilities is disclosed. Additionally, the monolithic nature of the storage carbon allows it to exhibit greater thermal conductivity than conventional granular activated carbon or powdered activated carbon storage beds. The storage of methane gas is achieved through the process of physical adsorption in the micropores that are developed in the structure of the adsorbent monolith. The disclosed monolith is capable of storing greater than 150 V/V of methane [i.e., >150 STP (101.325 KPa, 298K) volumes of methane per unit volume of storage vessel internal volume] at a pressure of 3.5 MPa (500 psi).
    Type: Grant
    Filed: July 26, 2000
    Date of Patent: November 5, 2002
    Assignee: Ut-Battelle, LLC
    Inventors: Timothy D. Burchell, Michael R. Rogers
  • Patent number: 6472343
    Abstract: A new shaped activated carbon and the method of its manufacture are disclosed. The invention resides in the crosslinking of a polymeric cellulose, such as sodium carboxymethylcellulose (CMC), within the carbon bodies after they are shaped, employing the CMC as a binder for the activated carbon. The approach to attain product mechanical strength and water stability by crosslinking rather than high temperature heat treatment is not obvious from the prior art teaching. The crosslinking reaction occurs at temperatures below 270° C. In addition, this new binder technology produces shaped carbon bodies having key properties beyond the best level that has been accomplished with other binders.
    Type: Grant
    Filed: April 11, 2001
    Date of Patent: October 29, 2002
    Assignee: Westvaco Corporation
    Inventors: Peter D. A. McCrae, Tiejun Zhang, David R. B. Walker
  • Publication number: 20020148784
    Abstract: An activated carbon composition is disclosed, which includes an activated carbon and a carboxylic acid containing compound. The activated carbon composition is prepared by immersing an activated carbon in an aqueous solution of a carboxylic acid containing compound. The activated carbon composition is used for purifying aqueous solutions by providing a bed of the activated carbon composition and passing the aqueous solution through the bed of the activated carbon composition. The aqueous solution is passed through the bed such that the flow of the aqueous solution to be purified into the bed and the flow of purified aqueous solution from the bed has a pH differential less than ±1 pH.
    Type: Application
    Filed: February 6, 2001
    Publication date: October 17, 2002
    Applicant: Envirotrol, Inc.
    Inventors: Robert G. Roodman, Jack Smiley, J. Michael Havelka, Robert Scherrer
  • Patent number: 6448002
    Abstract: Disclosed is a method to detect clinically relevant mutations of the DNA sequence of the KI-ras oncogene in stool DNA, its use and a testkit based thereon for early diagnosis of tumors, especially tumors of the pancreas and the colon. According to the invention, the method of detection is distinguished by extraction of genomic DNA from stool samples in a series of cleaning operations designed to eliminate inhibitor substances, and by base-complementary hybridization reaction by adding six different oligonucleotides with a defined complementarity to the clinically relevant mutated sequence fragments of the KI-ras gene.
    Type: Grant
    Filed: May 14, 1999
    Date of Patent: September 10, 2002
    Assignee: Invitek GmbH
    Inventors: Timo Hillebrand, Hans-Christoph Berndt, Peter Bendzko
  • Patent number: 6436872
    Abstract: An oxygen-absorbing composition containing particulate annealed electrolytically reduced iron of between about 100 mesh and 325 mesh in an amount of about up to 63% by weight, a salt such as sodium chloride in an amount by weight of about up to 3.5%, and a water-supplying component comprising activated carbon. with liquid water therein of a mesh size of between about 20 mesh and 50 mesh in an amount by weight of up to about 85% in an envelope which will resist the passage of liquid water out of the envelope but will permit flow of oxygen into the envelope at a satisfactory rate.
    Type: Grant
    Filed: May 2, 2001
    Date of Patent: August 20, 2002
    Assignee: Multisorb Technologies, Inc.
    Inventor: George E. McKedy
  • Patent number: 6432176
    Abstract: A closed storage reservoir has at least one feed and discharge line for compressed gas and, in its interior, a gas flow control system which connects the feed and discharge line to a solid filling for storing the compressed gas in the interior. To ensure the highest possible specific storage capacity of the device and to enable the device to be used as a tank system for a fuel cell, the solid filling comprises carbon nanostructures which are joined to form larger, cohesive conglomerates. A device for measuring the filling level of the compressed gas in the storage vessel may be a device for measuring the nuclear magnetic resonance or a device for measuring the mass flow rates of the compressed gas. A temperature sensor and a heating/cooling device having an inlet connection piece and an outlet connection piece for a heating/cooling medium and a cooling passage connected to the connection pieces are provided in order to set a defined temperature in the storage vessel.
    Type: Grant
    Filed: June 13, 2001
    Date of Patent: August 13, 2002
    Assignee: Mannesmann AG
    Inventors: Holger Klos, Walter Schütz
  • Publication number: 20020103081
    Abstract: An activated carbon molded body, more particularly in honeycomb form and for use as an adsorption filter, can be produced from a mixture including activated carbon, water, novolak powder, clay, cellulose ether, liquid starch, wax, polyacrylamide and soap, by a procedure involving thoroughly mixing the constituents, extruding the mixture to form a monolithic molded body and cutting same to size, drying the body and effecting pyrolysis thereof. The adsorption filter produced therefrom can be regenerated by electrical heating under specified conditions.
    Type: Application
    Filed: January 31, 2002
    Publication date: August 1, 2002
    Applicant: Helsa-Werke Helmut Sandler GmbH & Co. KG.
    Inventor: Thomas Wolff
  • Patent number: 6425941
    Abstract: The present invention is directed to an activated carbon composition that is resistant to oxidation and the activated carbon bed fires that can result from uncontrolled oxidation of the activated carbon bed. The activated carbon composition of the present invention includes from about 0.0001-25 wt. % of an antioxidant and from about 75-99.9999 wt. % activated carbon including any and all other impregnants and moisture. The presence of the antioxidant on the surface of the activated carbon inhibits uncontrolled oxidation and the activated carbon bed fires that can result. A method of removing solvents from a solvent-laden gas is also disclosed. The method includes passing the solvent-laden gas through an activated carbon bed, which contains the activated carbon composition described above.
    Type: Grant
    Filed: August 17, 2000
    Date of Patent: July 30, 2002
    Assignee: Envirotrol, Inc.
    Inventor: Robert G. Roodman
  • Patent number: 6425946
    Abstract: Trace impurities such as organic compounds and carbon monoxide are reduced to sub-ppb levels in gases such as nitrogen, helium and argon, by gas purifying systems that contain an ultra-low emission (ULE) carbon material. Ultra-low emission (ULE) carbon materials can be made from commercially available carbon materials in the form of pellets, extrudates and beads and is capable of removing impurities from a gas stream down to parts-per-billion (ppb) and sub-ppb levels without concurrently emitting other impurities such as moisture or carbon dioxide to the purified gas stream. The carbon material is superactivated by heating the carbon to temperatures from 300° to about 800° degrees C. in an ultra-dry, inert gas stream. The ultra-low emission (ULE) carbon material is handled and stored in an environment that minimizes contamination from moisture and other oxygenated species in order to maintain its ppb and sub-ppb impurity removal and low emission properties.
    Type: Grant
    Filed: December 26, 2000
    Date of Patent: July 30, 2002
    Assignee: Matheson Tri-Gas, Inc.
    Inventors: Hans H. Funke, Dan Fraenkel, Virginia H. Houlding
  • Publication number: 20020078825
    Abstract: Trace impurities such as organic compounds and carbon monoxide are reduced to sub-ppb levels in gases such as nitrogen, helium and argon, by gas purifying systems that contain an ultra-low emission (ULE) carbon material. Ultra-low emission (ULE) carbon materials can be made from commercially available carbon materials in the form of pellets, extrudates and beads and is capable of removing impurities from a gas stream down to parts-per-billion (ppb) and sub-ppb levels without concurrently emitting other impurities such as moisture or carbon dioxide to the purified gas stream. The carbon material is superactivated by heating the carbon to temperatures from 300° to about 800° degrees C. in an ultra-dry, inert gas stream. The ultra-low emission (ULE) carbon material is handled and stored in an environment that minimizes contamination from moisture and other oxygenated species in order to maintain its ppb and sub-ppb impurity removal and low emission properties.
    Type: Application
    Filed: December 26, 2000
    Publication date: June 27, 2002
    Inventors: Hans H. Funke, Dan Fraenkel, Virginia Houlding
  • Publication number: 20020082168
    Abstract: An activated carbon-metal oxide matrix is disclosed. The activated carbon-metal oxide matrix may by obtained by a method including the steps of: preoxidizing a carbon material, grinding the preoxidized carbon material; mixing the ground preoxidized material with a metal oxide to form a carbon mixture; extruding the carbon mixture; carbonizing and activating the extrudate. The activated carbon-metal oxide matrix may be used to remove odorous compounds, acidic gases, and volatile organic compounds from a gas.
    Type: Application
    Filed: December 11, 2001
    Publication date: June 27, 2002
    Inventors: James Richard Graham, Cheng Jian Yuan
  • Publication number: 20020074294
    Abstract: Disclosed is a method of removing hormone(s) from a liquid, the method comprising contacting the liquid with a filter comprising activated carbon fibers.
    Type: Application
    Filed: December 14, 2000
    Publication date: June 20, 2002
    Inventors: Mario E. Tremblay, Dimitris I. Collias
  • Patent number: 6402961
    Abstract: A process for preparing epoxysilanes by reacting a hydrogensilane with an allyl glycidyl ether in the presence of a catalyst and working up the crude product obtained, where the catalyst is removed from the crude product and the crude product is subsequently distilled.
    Type: Grant
    Filed: July 21, 2000
    Date of Patent: June 11, 2002
    Assignee: Degussa AG
    Inventors: Stefan Bade, Uwe Schoen, Hartwig Rauleder
  • Patent number: 6399823
    Abstract: A method is disclosed for producing phosgene which in one embodiment comprises contacting in at least one reactor a mixture comprising carbon monoxide and chlorine sequentially with a first catalyst followed by contacting the resulting gaseous reaction mixture comprising phosgene with at least one second catalyst of higher relative activity than a first catalyst. In another embodiment a method is disclosed for producing phosgene which comprises contacting in at least one reactor a mixture comprising carbon monoxide and chlorine with at least one catalyst bed comprising a first catalyst wherein at least a portion of said first catalyst is diluted with a second catalyst of higher relative activity than a first catalyst.
    Type: Grant
    Filed: April 30, 2001
    Date of Patent: June 4, 2002
    Assignee: General Electric Company
    Inventors: Francis Anthony Via, Grigorii Lev Soloveichik, Philip George Kosky, Walter Vladimir Cicha
  • Patent number: 6395678
    Abstract: A bead is provided which comprises or consists essentially of activated carbon immobilized by crosslinked poly(carboxylic acid) binder, sodium silicate binder, or polyamine binder. The bead is effective to remove metal and other ionic contaminants from dilute aqueous solutions. A method of making metal-ion sorbing beads is provided, comprising combining activated carbon, and binder solution (preferably in a pin mixer where it is whipped), forming wet beads, and heating and drying the beads. The binder solution is preferably poly(acrylic acid) and glycerol dissolved in water and the wet beads formed from such binder solution are preferably heated and crosslinked in a convection oven.
    Type: Grant
    Filed: September 1, 1999
    Date of Patent: May 28, 2002
    Assignee: Aero-Terra-Aqua Technologies Corporation
    Inventors: Bobby L. Summers, Jr., Karen L. Bennett, Scott A. Foster
  • Publication number: 20020052293
    Abstract: A carbon material for electric double layer capacitor electrodes which is obtained by a heat treatment and an activation treatment of a material pitch having a softening point in a range of 150 to 350° C., a ratio of amounts by atom of hydrogen to carbon (H/C) in a range of 0.50 to 0.90 and a content of optically anisotropic components of 50% or greater. The material pitch is preferably a synthetic pitch obtained by polymerizing a condensed polycyclic hydrocarbon such as naphthalene, methylnaphthalene, anthracene, phenanthrene, acenaphthene, acenaphthylene and pyrene in the presence of an ultra-strong acid catalyst such as a hydrogen fluoride-boron trifluoride complex. Electric double layer capacitors having a high electrode density and a high electrostatic capacity per unit volume can be constructed using the carbon material.
    Type: Application
    Filed: September 12, 2001
    Publication date: May 2, 2002
    Inventors: Hirotaka Tsuruya, Koichi Kanno, Hitoshi Sakamoto, Yuzuru Takahashi
  • Publication number: 20020048144
    Abstract: An activated carbon which is prepared from granular isotropic pitch.
    Type: Application
    Filed: July 25, 2001
    Publication date: April 25, 2002
    Applicant: Kuraray Co., Ltd. Kurashiki-shi Japan
    Inventors: Nozomu Sugo, Hideharu Iwasaki, Goki Uehara
  • Patent number: 6368504
    Abstract: An activated carbon block filter including a unique bonded carbon mixture. The carbon mixture preferably includes a mean particle diameter in the range of about 60 microns to about 80 microns and a particle size distribution having less than 10% by weight of particles larger than 140 mesh and less than 10% by weight of particles smaller than 500 mesh. More preferably, the carbon mixture includes a mean particle diameter in the range of about 65 microns to about 75 microns. Even more preferably, the carbon mixture includes a mean particle diameter of about 70 microns and a particle size distribution having less than 7% by weight of particles larger than 140 mesh and less than 7.5% by weight of particles smaller than 500 mesh.
    Type: Grant
    Filed: November 6, 2000
    Date of Patent: April 9, 2002
    Assignee: Alticor Inc.
    Inventors: Roy W. Kuennen, Karen J. VanderKooi, Roy M. Taylor, Jr., Kenneth E. Conrad
  • Patent number: 6361666
    Abstract: A gas diffusion electrode made of carbon, a process for producing an electrode and a carbonizable composite are provided. Thin, flat, porous gas diffusion electrodes made of carbon, which have a smooth surface and in which the porosity can be regulated at will, are obtained by pyrolysis of a composite of an organic polymer having a spatial globular structure (SGS polymer) and a reinforcing skeleton formed at least in part of organic material.
    Type: Grant
    Filed: May 19, 2000
    Date of Patent: March 26, 2002
    Assignee: Siemens Aktiengesellschaft
    Inventors: Matthias Lipinski, Rainer Leuschner
  • Publication number: 20020025290
    Abstract: A carbon dioxide and water adsorbent comprises a carbonized and activated precursor material having first functional sites that adsorb carbon dioxide and second functional sites that adsorb water independently of the first functional sites. The adsorbent is characterized by a total pore volume of between about 1.50 to 2.50 cm3/g, a median pore diameter between about 0.5 to 1.2 nm, and a BET surface area between about 2000 to 2500 m2/g.
    Type: Application
    Filed: January 24, 2001
    Publication date: February 28, 2002
    Applicant: Honeywell International , Inc.
    Inventor: Chin-Hsiung Chang
  • Patent number: 6350520
    Abstract: A carbon based material produced from the consolidation of amorphous carbon by elevated temperature compression. The material having unique chemical and physical characteristics that lend themselves to a broad range of applications such as in electrical, electrochemical and structural fields.
    Type: Grant
    Filed: August 2, 1999
    Date of Patent: February 26, 2002
    Assignee: Reticle, Inc.
    Inventors: Carl C. Nesbitt, Xiaowei Sun
  • Publication number: 20020020292
    Abstract: A method for producing high capacity gas-storage microporous sorbents involves precursor carbonization under relatively severe heat-treatment conditions, normally followed by activation using a cyclic chemisorption-desorption process.
    Type: Application
    Filed: July 6, 2001
    Publication date: February 21, 2002
    Inventors: Marek A. Wojtowicz, Michael A. Serio, Eric M. Suuberg
  • Publication number: 20020010092
    Abstract: Activated carbon for electric double-layer capacitor has a high electrostatic capacity density. An area rate of edge faces in a surface (including inner surfaces of fine bores) of the activated carbon for an electric double-layer capacitor is equal to or higher than 20%.
    Type: Application
    Filed: December 27, 2000
    Publication date: January 24, 2002
    Inventors: Morinobu Endoh, Minoru Noguchi, Naohiko Oki, Shigeki Oyama
  • Publication number: 20020010093
    Abstract: The invention relates to a process for the manufacture of improved active charcoal exhibiting a high resistance to sulphur-comprising products, such as H2S, COS and mercaptans; to the improved active charcoal thus obtained; and to a process for the purification of a gas stream comprising sulphur-comprising compounds. The gas to be treated is air, nitrogen, hydrogen produced by reforming or cracking of alcohols, of ammonia or of hydrocarbons, natural gas, combustion gas or fermentation gas.
    Type: Application
    Filed: March 7, 2001
    Publication date: January 24, 2002
    Applicant: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Christian Monereau, Serge Moreau
  • Patent number: 6337302
    Abstract: Purified carbon black carried by a screw conveyer, while being subject to preheating treatment, is transported to a microwave heating zone where it is heated to a temperature between 250° C. and 400° C. and subsequently, it is sent into a flow-type steam activation furnace there under the passage of steam and at a temperature inside the furnace maintained at 700° C. to 900° C. the carbon black is heated and activated to form a powdery activated carbon. This novel method for the production of activated carbon with high added value from carbon black is a continuous process of high productivity especially suitable for carbon black recovered from the heating and splitting decomposition processes of waste tires, waste plastics and the like.
    Type: Grant
    Filed: May 30, 2000
    Date of Patent: January 8, 2002
    Inventors: Chien-Lang Teng, Feng-Sung Wang
  • Patent number: 6332916
    Abstract: Activated carbon filters containing transition metals, are prepared by (a) exchanging the transition metal with a cellulose ion exchange material to produce a cellulose material containing the transition metal; (b) charring of the product of (a); activating the product of (b) to form an activated carbon filter having a pore network throughout; and removing surface carbon substantially throughout the pore network of the filter formed in (c). Methods of filtering an atmosphere containing a gaseous contaminant by passing the contaminated atmosphere through a filter made by this process are described.
    Type: Grant
    Filed: February 28, 2000
    Date of Patent: December 25, 2001
    Assignee: The Secretary of State for Defence in Her Brittanic Majesty's Government of the United Kingdom of Great Britain and Northern Ireland
    Inventors: Matthew J Chinn, Paul R Norman, Philip A Barnes, Elizabeth A Dawson
  • Patent number: 6329316
    Abstract: A granular active carbon for natural-gas occlusion is disclosed which can occlude natural gas at a relatively low pressure and has a high natural-gas occlusion capacity. The granular active carbon for natural-gas occlusion has first and second pores for the occlusion of constituent gas molecules of natural gas. The first pores each has a diameter d1, satisfying 2d<d1≦2.5d, while the second pores each has a diameter d2 satisfying 5d<d2≦6d, wherein d is the diameter of the constituent gas molecules.
    Type: Grant
    Filed: January 29, 1999
    Date of Patent: December 11, 2001
    Assignee: Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Ogasa, Yusaku Sakata, Akinori Muto
  • Publication number: 20010031904
    Abstract: The present invention provides a device, compositions and methods for reducing the volatility of radioactive waste comprising; a receptacle having an open end said open end having a means for affixing a lid securely to said receptacle, a absorbent matrix comprising a humectant, a pH-stabilizing agent and an adsorbent material said matrix insertable into said receptacle and a lid for sealing the receptacle. Radioactive waste is deposited into the receptacle during use and the receptacle is sealed and disposed of safely.
    Type: Application
    Filed: December 8, 2000
    Publication date: October 18, 2001
    Inventor: Mark Fitchmun
  • Publication number: 20010029401
    Abstract: A driving system using an intercalation substance as a novel mechanochemical system includes an actuator using the intercalation substance and driven by exchange of solutions or by changing concentration of a solution, and a solution supplier that supplies the actuator with the driving solution or solutions. The actuator is composed of one or more cylindrical or fiber-shaped elements each extending in the expanding and contracting direction of the intercalation substance, or one or more film-shaped or plate-shaped elements each having a major surface extending vertically of the expanding and contracting direction of the intercalation substance. The driving system is used as artificial muscle, for example.
    Type: Application
    Filed: December 19, 2000
    Publication date: October 11, 2001
    Inventors: Yuichi Ishida, Naomi Nagasawa, Masayuki Suzuki, Takaaki Ami, Teiichiro Nishimura
  • Publication number: 20010027164
    Abstract: A CO2 adsorbent that enhances the CO2 recovery rate in the CO2 separation and recovery process is provided. The CO2 adsorbent is made of active carbon and/or molecular sieve carbon with a large specific surface area. The active carbon and/or molecular sieve carbon has micropores and/or mesopores 200 Å or less in size and penetrating pores formed by the micropores and/or mesopores connecting with one another. All or part of surfaces of inner passages through which a gas flows and of terminal pores are covered directly with a polar liquid or polar solid without a reaction layer there between.
    Type: Application
    Filed: December 19, 2000
    Publication date: October 4, 2001
    Inventors: Akira Ishida, Kazuo Ohsumi, Hideki Hyuga
  • Patent number: 6294501
    Abstract: A carbon dioxide adsorbent comprises a carbonized, shaped precursor material, with such material being characterized by a total micropore volume of at least about 0.525 cm3/g and a median pore diameter of at least about 0.439 nm, whereby the material has a carbon dioxide capacity of at least about 28.6% g/g at a carbon dioxide partial pressure of about 6 mm Hg and a temperature of about 196° K. Also provided is a method of making a carbon dioxide adsorbent, which includes the steps of polymerizing a monomer to produce a precursor material; shaping the precursor material to produce a shaped precursor material; and carbonizing the shaped precursor material to produce the adsorbent, whereby the adsorbent is characterized by a carbon dioxide capacity of at least about 28.6% g/g at a carbon dioxide partial pressure of about 6 mm Hg and a temperature of about 196° K.
    Type: Grant
    Filed: March 2, 1999
    Date of Patent: September 25, 2001
    Assignee: AlliedSignal Inc.
    Inventor: Chin-Hsiung Chang
  • Publication number: 20010023232
    Abstract: An oxygen-absorbing composition containing particulate annealed electrolytically reduced iron of between about 100 mesh and 325 mesh in an amount of about up to 63% by weight, a salt such as sodium chloride in an amount by weight of about up to 3.5%, and a water-supplying component comprising activated carbon with liquid water therein of a mesh size of between about 20 mesh and 50 mesh in an amount by weight of up to about 85% in an envelope which will resist the passage of liquid water out of the envelope but will permit flow of oxygen into the envelope at a satisfactory rate.
    Type: Application
    Filed: May 2, 2001
    Publication date: September 20, 2001
    Inventor: George E. McKedy
  • Patent number: 6290753
    Abstract: In a method for storing hydrogen in a carbon material containing microstructures in the form of cones with cone angles being multiples of 60°, the carbon material is introduced in a reaction vessel which is evacuated while the carbon material is kept at a temperature of 295-800 K, after which pure hydrogen gas is introduced in the reaction vessel, the carbon material being exposed to a hydrogen gas pressure in the range of 300-7600 torr such that the hydrogen gas is absorbed in the carbon material, and after which the reaction vessel is left at the ambient temperature with the carbon material under a fixed hydrogen gas pressure. For use the hydrogen is released in the form of a gas from the carbon material either at ambient temperature or by heating the carbon material in the reaction vessel.
    Type: Grant
    Filed: September 22, 1999
    Date of Patent: September 18, 2001
    Assignee: Institutt for energiteknikk
    Inventors: Arnulf Julius Maeland, Arne Torbjørn Skjeltorp
  • Publication number: 20010019994
    Abstract: An oxygen storage adsorbent at cryogenic temperatures that will remove carbon dioxide and water comprises a carbonized precursor material having functional sites that adsorb and store oxygen and that evolve oxygen upon adsorbing carbon dioxide and water. The adsorbent is characterized by a total pore volume of between about 0.5 to 0.6 cm3/g, a median pore diameter between about 0.42 to 0.46 nm, and a BET surface area between about 1000 to 1200 m2/g.
    Type: Application
    Filed: March 23, 2001
    Publication date: September 6, 2001
    Applicant: Honeywell International, Inc.,
    Inventor: Chin-Hsiung Chang
  • Patent number: 6277780
    Abstract: Disclosed is a method for preparing a phosphorus treated activated carbon composition suitable for use as a catalyst support, a catalyst, and an adsorbent. The invention method involves treating (e., mixing or impregnating) an activated carbon material having a surface area greater than 100 m2/g with a phosphorus-containing compound, drying, and heating to a temperature of from 450° C. to about 1200° C., wherein the resulting composition is characterized by a phosphorus compound combined with the carbon in an amount of from above 2.5% to about 10% phosphorus, based on the weight of the composition.
    Type: Grant
    Filed: August 9, 1994
    Date of Patent: August 21, 2001
    Assignee: Westvaco Corporation
    Inventors: Robert K. Beckler, James R. Miller
  • Patent number: 6277783
    Abstract: A method is provided for purifying a crude N-acetyl-para-aminophenol (APAP) containing color bodies or their precursors, the method comprising: a) forming a hot aqueous solution of the crude APAP; and b) subsequently contacting the hot solution with an acid washed adsorbent carbon, e.g., an activated carbon, which acid washed carbon, prior to such contact, has been pretreated by contacting it with an aqueous solution of a reducing sulfite.
    Type: Grant
    Filed: July 30, 1999
    Date of Patent: August 21, 2001
    Assignee: BASF Corporation
    Inventors: Olan Stanley Fruchey, Edward G. Zey, Larry O. Wheeler