Zeolite Patents (Class 502/64)
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Publication number: 20120006724Abstract: Provided are hydrocracking catalysts comprising a cracking component and a hydrogenation component, wherein, for example: the cracking component comprises at least one molecular sieve present in an amount ranging from 0% to 20% by weight relative to the total weight of the catalyst and at least one amorphous silica-alumina present in an amount ranging from 20% to 60% by weight relative to the total weight of the catalyst; the hydrogenation component comprises at least one hydrogenation metal present in a total amount ranging from 34% to 75% by weight calculated by the mass of oxides, relative to the total weight of the catalyst; and the hydrocracking catalyst has a specific surface area ranging from 150 m2/g to 350 m2/g and a pore volume ranging from 0.20 cm3/g to 0.50 cm3/g, such as from 0.30 cm3/g to 0.45 cm3/g, and the product (M×S) of the percentage amount of the total mass of the hydrogenation metal (M) and the specific surface area (S) is equal to or more than 100 m2/g, i.e., M×S?100 m2/g.Type: ApplicationFiled: July 6, 2011Publication date: January 12, 2012Inventors: Yanze Du, Minghua Guan, Fenglai Wang, Chang Liu
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Patent number: 8092903Abstract: A shaped body, particularly a sorbent shaped body, made of microporous and mesoporous adsorbents and of composite adsorbents is provided for, which shaped body employs a reduced proportion of binding agents. The binding agent added to the shaped body solidifies under the application of force, under which force non-uniformly distributed cavities are formed. The proportion of binding agent on the support forming the wall of the shaped body is higher than the proportion of binding agent inside the shaped body. By using modified alumosilicates and/or aluminum silicates with fluidic action during materials exchange and heat exchange, the shaped body provides for high space-time yields while storing heat and cold.Type: GrantFiled: July 9, 2004Date of Patent: January 10, 2012Assignee: PBB GbRInventors: Helmut Stach, Peter Muenn, Jan Mugele
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Patent number: 8084383Abstract: The present invention is directed to certain catalyst compositions and processes that are capable of reducing sulfur compounds normally found as part of the gasoline fraction streams of fluid catalytic cracking processes. The present invention is a cracking catalyst composition comprising a zeolite in combination with a Lewis Acid containing component, wherein the cracking catalyst composition comprises 0.2% Na2O or less. It has been found that sulfur compounds in hydrocarbon feeds to fluid catalytic cracking processes can be reduced by at least 15% compared to the same composition, which does not comprise the aforementioned Lewis Acid containing component.Type: GrantFiled: March 16, 2004Date of Patent: December 27, 2011Assignee: W.R. Grace & Co.-Conn.Inventors: Ruizhong Hu, Xinjin Zhao, Richard Franklin Wormsbecher, Michael Scott Ziebarth
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Patent number: 8062987Abstract: A zeolite catalyst that may be used in aromatic alkylation is prepared by treating a zeolite with a phosphorus compound. The phosphorus-treated zeolite is calcined and contacted with liquid water, whereby an amount of phosphorus is removed from the phosphorus-treated zeolite. The phosphorus-treated zeolite is then heated. A method of preparing an aromatic product may also be carried out by contacting the prepared zeolite catalyst with an aromatic alkylation feed of an aromatic compound and an alkylating agent under reaction conditions suitable for aromatic alkylation.Type: GrantFiled: October 5, 2009Date of Patent: November 22, 2011Assignee: Saudi Basic Industries CorporationInventors: Ashim Kumar Ghosh, Neeta Kulkarni, Pamela Harvey
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Publication number: 20110282122Abstract: One exemplary embodiment can be a molecular sieve. The molecular sieve can include one or more crystals. The molecular sieve can have an external surface area of no more than about 20 m2/g.Type: ApplicationFiled: May 14, 2010Publication date: November 17, 2011Applicant: UOP, LLCInventors: Hui Wang, Paula L. Bogdan, Richard R. Willis
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Patent number: 8048198Abstract: The present invention discloses a new type of high performance mixed matrix membranes (MMMs) and methods for making and using the same. The MMMs comprise a continuous polymer matrix and at least two types of molecular sieves dispersed therein. The continuous polymer matrix in the MMM contains at least one type of polymer. The MMM in the form of a dense film, asymmetric flat sheet membrane or otherwise prepared exhibits simultaneously improved selectivity and permeability for gas separations compared to polymer membranes made from a continuous polymer matrix without any molecular sieves or with only one type of molecular sieve. MMMs of the present invention are suitable for a wide range of gas, vapor, and liquid separations such as alcohol/water, CO2/CH4, H2/CH4, O2/N2, CO2/N2, olefin/paraffin, iso/normal paraffins, and other light gases separations.Type: GrantFiled: November 8, 2007Date of Patent: November 1, 2011Assignee: UOP LLCInventors: Chunqing Liu, David A. Lesch, Stephen T. Wilson
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Patent number: 8043989Abstract: A system is provided for desulfurizing a hydrocarbon fuel containing a light amount of methanol and a slight amount of water. The desulfurization system uses a Y-type zeolite-based desulfurizing agent containing at least copper arranged upstream of the system and an X-type zeolite-based desulfurizing agent containing at least silver arranged downstream of the system and thus can maintain desulfurization effect for a long period of time.Type: GrantFiled: March 4, 2009Date of Patent: October 25, 2011Assignee: Nippon Oil CorporationInventors: Yoshiyuki Nagayasu, Atsushi Segawa, Kazunori Miyazawa, Yoshihiro Kobori
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Patent number: 8043988Abstract: The invention relates to a FAU-type zeolite membrane that comprises a FAU-type zeolite crystal layer incorporated in the surface porosity of at least one selected face of a porous substrate, in which the ratio between the thickness of said zeolite layer incorporated in the surface porosity of said selected face of the substrate and the total thickness of said zeolite layer is at least 70%. It also relates to processes for preparation and application of these membranes.Type: GrantFiled: July 23, 2008Date of Patent: October 25, 2011Assignee: IFP Energies NouvellesInventors: Florent Guillou, Gerhard Pirngruber, Loïc Rouleau, Valentin Valtchev
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Patent number: 8030240Abstract: Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include at least two zeolites, including a zeolite with a low silica to alumina ratio. The catalysts may be combined with a low surface binder, or alternatively the catalysts as formulated may have a high ratio of zeolite surface area to external surface area.Type: GrantFiled: December 18, 2008Date of Patent: October 4, 2011Assignee: ExxonMobil Research and Engineering CompanyInventors: Christine N. Elia, Mohan Kalyanaraman, Lei Zhang, Michel A. Daage, Darden Sinclair, Valery Sokolovskii, David M. Lowe, Jun Han, Nicholas Ohler, Daniel M. Giaquinta, Anthony F. Volpe, Jr.
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Patent number: 8029662Abstract: The disclosed sorbents are for adsorbing sulfur compounds, particularly sulfur-containing aromatic compounds, from liquid hydrocarbon fuels such as gasoline, cracked gasoline, diesel, high sulfur liquid fossil fuels, ultra-low sulfur fuel (ULSF) in fuel cell applications, and mixtures thereof. The sorbent compositions comprise one or more silicates having one or more metal nitrates admixed together. The one or more metal nitrates include iron (II) or (III), zinc (II), cadmium (II) and mercury (II) nitrate. The method of preparing and using the sorbents is also provided.Type: GrantFiled: June 6, 2008Date of Patent: October 4, 2011Assignee: The United States of America as represented by the Administrator of the Environmental Protection AgencyInventors: Rajender S. Varma, Yuhong Ju, Subhas Sikdar
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Patent number: 8030239Abstract: Disclosed herein is a catalyst for xylene isomerization, including: a carrier including a zeolite, having a molar ratio of silica to alumina of 20˜100, impregnated with or mixed with a metal salt (I) having an amount of a metal component of 0.05˜5.0 wt % relative to a zeolite, and an inorganic binder, in which an amount of the zeolite is 10˜90 wt % based on the total amount of the carrier, wherein the carrier is supported with a VIII group metal such that an amount of the VIII group metal is 0.001˜3.0 wt % based on a total amount of the catalyst, or is supported with the VII group metal additionally supported with tin, bismuth or lead such that an amount of the tin, bismuth or lead is 0.01-5.0 wt % based on the total amount of the catalyst, and a method of producing the catalyst.Type: GrantFiled: November 16, 2007Date of Patent: October 4, 2011Assignee: SK Energy Co., Ltd.Inventors: Seung Hoon Oh, Sang Il Lee, Kyeong Hak Seong, Jong Hyung Lee, Kyung Jong Oh
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Patent number: 8030238Abstract: The present invention relates to a new zeolite having a beta-type crystalline structure, characterized by a distribution of the Lewis acid sites and Brønsted acid sites corresponding to a molar ratio [Lewis sites] [Brønsted sites] equal to or higher than 1.5. This new zeolite is useful in preparation processes of alkylated aromatic hydrocarbons through the alkylation and/or transalkylation of aromatic compounds. The preparation method of the new zeolite is also object of the present invention.Type: GrantFiled: June 21, 2005Date of Patent: October 4, 2011Assignees: Polimeri Europa S.p.A., Eni S.p.A.Inventors: Guido Spano′, Stefano Ramello, Gianni Girotti, Franco Rivetti, Angela Carati
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Publication number: 20110237423Abstract: The zeolite structure is a porous zeolite structure constituted of a formed article obtained by extruding a zeolite raw material containing zeolite particles and an inorganic binding material including at least basic aluminum chloride, a ratio P1 (P1=V2/V1×100) of a volume V2 of the inorganic binding material in the zeolite structure with respect to a volume V1 of the zeolite structure is from 10 to 50 vol %, and a relation of equation (1) is satisfied: P2/P1?1.0 ??(1), in which P1 is the ratio of the volume V2 of the inorganic binding material in the zeolite structure with respect to the volume V1 of the zeolite structure and P2 (P2=Vb/Va×100) is a ratio of volumes Vb of pores having pore diameters of 0.003 to 0.03 ?m with respect to the whole pore volume Va of the zeolite structure.Type: ApplicationFiled: March 17, 2011Publication date: September 29, 2011Applicant: NGK Insulators, Ltd.Inventors: Yoshio KIKUCHI, Haruo Otsuka
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Publication number: 20110237426Abstract: The manufacturing method includes a mixing step of mixing a plurality of zeolite particles, an inorganic binding material and an organic binder, to prepare a zeolite raw material; a forming step of extruding the zeolite raw material to obtain a formed zeolite article; and a firing step of firing the formed zeolite article to prepare the zeolite structure, the mixing step uses the inorganic binding material containing at least one type of silica sol selected from the group consisting of acid silica sol, silica sol containing silica particles coated with alumina, cationic silica sol, silica sol containing string-like silica particles, and silica sol containing bead-like silica particles, and a content ratio of silica particles contained in the silica sol selected from the group is from 10 to 30 mass % with respect to 100 mass % of the zeolite particles.Type: ApplicationFiled: March 21, 2011Publication date: September 29, 2011Applicant: NGK Industries, Ltd.Inventors: Yoshio Kikuchi, Haruo Otsuka
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Publication number: 20110236271Abstract: The zeolite structure includes a zeolite material containing a plurality of zeolite particles and an inorganic binding material which binds the zeolite particles to one another, the plurality of zeolite particles include fine zeolite particles having a small average particle diameter and coarse zeolite particles which have an average particle diameter of three or more times the average particle diameter of the fine zeolite particles and which are not an agglomerated material of primary particles, a ratio of volumes of the coarse zeolite particles with respect to the whole volume of the plurality of zeolite particles is from 40 to 90 vol %, in the zeolite material, a ratio of a volume of the inorganic binding material is from 5 to 50 vol %, and a zeolite raw material containing the plurality of zeolite particles and the inorganic binding material is extruded to form a zeolite structure.Type: ApplicationFiled: March 17, 2011Publication date: September 29, 2011Applicant: NGK Insulators, Ltd.Inventors: Yoshio KIKUCHI, Haruo OTSUKA
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Publication number: 20110230333Abstract: A new catalyst and method of preparing the catalyst is presented. The catalyst is a molecular sieve used for cracking olefins, and has improved selectivity to increase propylene yields and to reduce the amount of aromatics and methane produced. The catalyst been ion-exchanged to reduce the alkali composition in the catalyst.Type: ApplicationFiled: March 16, 2010Publication date: September 22, 2011Applicant: UOP LLCInventors: Timur V. Voskoboynikov, Michael H. Quick, John J. Senetar
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Publication number: 20110224068Abstract: This invention relates to the composition, method of making and use of a fluidized catalytic cracking (“FCC”) catalyst that is comprised of a new Y zeolite which exhibits an exceptionally low small mesoporous peak around the 40 ? (angstrom) range as determined by nitrogen adsorption measurements. FCC catalysts made from this new zeolite exhibit improved rates of heavy oil cracking heavy oil bottoms conversions and gasoline conversions. The fluidized catalytic cracking catalysts herein are particularly useful in fluidized catalytic cracking (“FCC”) processes for conversion of heavy hydrocarbon feedstocks such as gas oils and vacuum tower bottoms.Type: ApplicationFiled: February 17, 2011Publication date: September 15, 2011Applicant: W.R. Grace & Co.-Conn.Inventors: Edward T. Habib, JR., Ruizhong Hu, Terry G. Roberie, Jianxin Jason Wu, William A. Wachter, Colin L. Beswick
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Publication number: 20110224067Abstract: This invention comprises USY zeolite prepared by treating a USY zeolite under hydrothermal conditions after forming the USY zeolite from heat treating ammonium exchanged zeolite Y, e g, by calcination. When this invention is used in a FCC catalyst, a significant improvement of activity and selectivity in the fluid catalytic cracking (FCC) performance is observed, compared to FCC catalysts containing conventional USY zeolite. The process used to make the invention is efficient and comprises treating the USY zeolite in an exchange bath under the aforementioned hydrothermal conditions. The surface of the resulting USY zeolite has a molar ratio of alumina to silica that is higher than that seen in the bulk USY zeolite and has a unique structure as viewed by SEM and TEM.Type: ApplicationFiled: December 17, 2009Publication date: September 15, 2011Inventors: Richard Franklin Wormsbecher, Wu-Cheng Cheng, Michael Wallace, Wilson Suarez, Yuying Shu
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Patent number: 8008223Abstract: One aspect of the present invention relates to mesostructured zeolites. The invention also relates to a method of preparing mesostructured zeolites, as well as using them as cracking catalysts for organic compounds and degradation catalysts for polymers.Type: GrantFiled: April 25, 2005Date of Patent: August 30, 2011Assignee: Massachusetts Institute of TechnologyInventor: Javier Garcia-Martinez
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Publication number: 20110207598Abstract: Disclosed is a metal-supported catalyst produced by (a) preparing a dispersion of crystalline silicoaluminophosphate particles; (b) mixing an aqueous active ingredient metal compound solution into the dispersion; (c) spray-drying the mixture; (d) washing the spray-dried product and (e) heat-treating (calcining) the washed product at 400 to 900° C. Also disclosed is an aluminum phosphate-modified metal-supported crystalline silicoaluminophosphate catalyst having a content of aluminum phosphate in the catalyst of 0.1 to 40% by weight in terms of Al2O3+P2O5 based on the metal-supported crystalline silicoaluminophosphate particles.Type: ApplicationFiled: December 17, 2010Publication date: August 25, 2011Applicant: JGC CATALYSTS AND CHEMICALS LTD.Inventors: Tomohiro Mitsui, Yuka Morishita, Takaki Mizuno, Tsuguo Koyanagi
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Patent number: 8002970Abstract: The present invention concerns doped catalysts on a mixed zeolite/alumino-silicate support with a low macropore content, and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table and a doping element in a controlled quantity selected from phosphorus, boron and silicon, and a support based on zeolite Y defined by a lattice parameter a of the unit cell in the range 24.40×10?10 m to 24.15×10?10 m and silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).Type: GrantFiled: December 13, 2005Date of Patent: August 23, 2011Assignee: IFP Energies NouvellesInventors: Patrick Euzen, Patrick Bourges, Christophe Gueret, Carole Bobin, Alexandra Chaumonnot, Hugues Dulot
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Patent number: 8003566Abstract: A method of preparing a catalyst support is described comprising washing a precipitated metal oxide material with water and/or an aqueous solution of acid and/or base such that contaminant levels in said precipitated metal oxide are reduced. The method may be applied to precipitated alumina materials to reduce contaminants selected from sulphur, chlorine, Group 1 A and Group 2A metals. The catalyst supports may be used to prepare catalysts for the Fischer-Tropsch synthesis of hydrocarbons.Type: GrantFiled: March 21, 2006Date of Patent: August 23, 2011Assignee: Johnson Matthey PLCInventors: John Leonello Casci, Elizabeth Margaret Holt, Adel Fay Neale
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Publication number: 20110192766Abstract: A supported catalyst comprises a zeolite having a silica to alumina molar ratio of 500 or less, a first metal oxide binder having a crystallite size greater than 200 ? and a second metal oxide binder having a crystallite size less than 100 ?, wherein the second metal oxide binder is present in an amount less than 15 wt % of the total weight of the catalyst.Type: ApplicationFiled: February 7, 2011Publication date: August 11, 2011Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Stephen J. McCarthy, Wenyih F. Lai, Darryl Donald Lacy, Robert Ellis Kay
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Patent number: 7994085Abstract: A material with a hierarchical porosity is described, constituted by at least two spherical elementary particles, each of said spherical particles comprising zeolitic nanocrystals having a pore size in the range 0.2 to 2 nm and a matrix based on silicon oxide, which is mesostructured, having a pore size in the range 1.5 to 30 nm and having amorphous walls with a thickness in the range 1 to 20 nm, said spherical elementary particles having a maximum diameter of 10 ?m. the matrix based on silicon oxide may contain aluminium. The preparation of said material is also described.Type: GrantFiled: June 24, 2005Date of Patent: August 9, 2011Assignee: IFP Energies NouvellesInventors: Alexandra Chaumonnot, Aurélie Coupe, Clément Sanchez, Patrick Euzen, Cédric Boissiere, David Grosso
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Publication number: 20110190562Abstract: A catalyst is described which comprises at least one IZM-2 zeolite, at least one matrix and at least one metal selected from metals from groups VIII, VIB and VIIB, said zeolite having a chemical composition expressed as the anhydrous base in terms of moles of oxides by the following general formula: XO2:aY2O3:bM2/nO, in which X represents at least one tetravalent element, Y represents at least one trivalent element and M is at least one alkali metal and/or alkaline-earth metal with valency n, a and b respectively representing the number of moles of Y2O3 and M2/nO; and a is in the range 0.001 to 0.5 and b is in the range 0 to 1.Type: ApplicationFiled: July 21, 2009Publication date: August 4, 2011Applicant: IFP Energies NouvellesInventors: Emmanuelle Guillon, Nicolas Cadran, Sylvie Maury, Amandine Cabiac
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Publication number: 20110185625Abstract: Solid mixed catalysts and methods for use in conversion of triglycerides and free fatty acids to biodiesel are described. A batch or continuous process may be used with the catalysts for transesterification of triglycerides with an alkyl alcohol to produce corresponding mono carboxylic acid esters and glycerol in high yields and purity. Similarly, alkyl and aryl carboxylic acids and free fatty acids are also converted to corresponding alkyl esters. The described catalysts are thermostable, long lasting, and highly active.Type: ApplicationFiled: August 20, 2009Publication date: August 4, 2011Applicant: SBI Fine Chemicals Inc.Inventors: Inder Pal Singh, Shradha Singh, Ritesh Patel, Bharat Mistry, Manish Mehta, Peter Omolo Otieno
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Patent number: 7982083Abstract: A catalyst is described which comprises at least one zeolite with structure type EUO, at least one zeolite having channels the opening to which is defined by a ring of 10 oxygen atoms (10 MR), at least one zeolite having channels the opening to which is defined by a ring of 12 oxygen atoms (12 MR) and at least one porous mineral matrix. Said catalyst optionally also contains at least one group VIII metal. The catalyst of the invention is used in a process for isomerizing a feed comprising aromatic compounds containing 8 carbon atoms per molecule.Type: GrantFiled: December 1, 2006Date of Patent: July 19, 2011Assignee: IFP Energies NouvellesInventors: Emmanuelle Guillon, Eric Sanchez, Sylvie Lacombe
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Publication number: 20110172479Abstract: The present invention is for a catalyst, a process for making the catalyst and a process for using the catalyst in aromatization of alkanes having three to five carbon atoms per molecule, such as propane, to aromatics, such as benzene, toluene and xylene. The catalyst is an aluminum-silicon zeolite having a silicon to aluminum atomic ratio (Si:Al) greater than 15:1, such as MFI or ZSM-5, on which germanium, aluminum and a noble metal, such as platinum, have been deposited. The catalyst may be bound with magnesia, alumina, titania, zirconia, thoria, silica, boria or mixtures thereof. The aluminum and germanium may be deposited simultaneously on the zeolite.Type: ApplicationFiled: January 14, 2010Publication date: July 14, 2011Applicant: Saudi Basic Industries CorporationInventors: Scott Stevenson, Gopalakrishnan G. Juttu, Michael Mier, Robin J. Bates, Dustin Farmer, Scott Mitchell, Alla K. Khanmamedova
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Patent number: 7977274Abstract: The invention pertains to a catalyst useful for the epoxidation of an olefin. More particularly, the invention pertains to an improved catalyst useful for the epoxidation of ethylene to ethylene oxide. The catalyst has improved selectivity in the epoxidation process. The catalyst comprises a solid support having a surface, which has a first mode of pores which have a diameter ranging from about 0.01 ?m to about 5 ?m and having a differential pore volume peak in the range of from about 0.01 ?m to about 5 ?m. The surface then has a second mode of pores, different from the first mode of pores, which second mode of pores have a diameter ranging from about 1 ?m to about 20 ?m and have a differential pore volume peak in the range of from about 1 ?m to about 20 ?m.Type: GrantFiled: September 29, 2006Date of Patent: July 12, 2011Assignee: SD Lizenzverwertungsgesellschaft mbH & Co. KGInventor: Christian Gueckel
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Patent number: 7977523Abstract: A catalyst, useful in the preparation of isoolefins and containing 0.1 to 20% by mass of an alkali metal oxide, an alkaline earth metal oxide and mixtures thereof; 0.1 to 99% by mass of aluminum oxide; and 0.1 to 99% by mass of silicon dioxide, is prepared by a) treating an aluminosilicate with an aqueous alkali metal salt solution, an alkaline earth metal salt solution and mixtures thereof, under acidic conditions, to obtain a treated aluminosilicate; and b) calcining the treated aluminosilicate, to obtain the catalyst.Type: GrantFiled: August 10, 2007Date of Patent: July 12, 2011Assignee: Evonik Oxeno GmbHInventors: Horst-Werner Zanthoff, Dietrich Maschmeyer, Thomas Quandt, Franz Nierlich, Silvia Santiago Fernandez, Stephan Houbrechts, Georg Skillas, Kurt-Alfred Gaudschun
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Publication number: 20110163006Abstract: The present invention concerns a new cracking process, preferably a fluid catalytic process, characterized in that it is carried out in the presence of a catalyst containing ERS-10 zeolite. The invention also relates to a new catalytic composition containing said ERS-10 zeolite, which can be used as catalyst in catalytic cracking processes, in particular in fluid catalytic cracking processes (FCC).Type: ApplicationFiled: May 28, 2009Publication date: July 7, 2011Applicant: ENI S.P.AInventors: Giuseppe Bellussi, Roberto Millini, Caterina Rizzo, Daniele Colombo
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Patent number: 7972394Abstract: A method of operating a methanation reactor to reduce carbon monoxide concentration in a reformate stream in a fuel cell reformer. The reactor includes a flowpath with a noble metal catalyst supported by a ceramic support such that the reactor preferentially converts carbon monoxide via methanation over that of carbon dioxide. The reduced level of carbon monoxide present in the reformate stream after passing through the methanation reactor reduces the likelihood of poisoning of the catalyst used on the fuel cell anode.Type: GrantFiled: August 11, 2006Date of Patent: July 5, 2011Assignee: GM Global Technology Operations LLCInventors: Mark Robert Feaviour, Julia Margaret Rowe
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Publication number: 20110160508Abstract: A catalytic composition and method for methane dehydroaromatisation, the catalytic composition comprising a catalyst metal active for methane dehydroaromatisation, a zeolite having pores with diameters of at least 10 non-oxygen frame-work atoms, and silicon carbide, and in which the method comprises contacting a methane-containing feedstock with said catalytic composition to produce one or more aromatic compounds and hydrogen.Type: ApplicationFiled: May 21, 2008Publication date: June 30, 2011Inventors: Ding Ma, Lijun Gu, Xinhe Bao, Wenjie Shen, Martin Philip Atkins
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Publication number: 20110152065Abstract: A method for producing an oil binding agent, using highly porous natural siliceous material and organic-containing remaining material, wherein the highly porous natural siliceous material having an initial grain size of between 4 and 10 mm is mixed with the organic-containing remaining material and the mixture is calcined at a temperature between 520 and 550° C. and then comminuted to a grain size spectrum substantially ranging between 4 and 0.Type: ApplicationFiled: March 9, 2009Publication date: June 23, 2011Inventor: Franz-Josef Philipp
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Publication number: 20110144400Abstract: The invention relates to a material which is suited as a carrier for catalysts in the dehydrogenation of alkanes and in the oxidative dehydrogenation of alkanes and which is made of an oxide ceramic foam and may contain combinations of the substances aluminium oxide, calcium oxide, silicon dioxide, tin oxide, zirconium dioxide, calcium aluminate, zinc aluminate, silicon carbide, and which is impregnated with one or several suitable catalytically active materials, by which the flow resistance of the catalyst decreases to a considerable degree and the accessibility of the catalytically active material improves significantly and the thermal and mechanical stability of the material increases. The invention also relates to a process for the manufacture of the material and a process for the dehydrogenation of alkanes by using the material according to the invention.Type: ApplicationFiled: July 28, 2009Publication date: June 16, 2011Applicant: UHDE GMBHInventors: Muhammad Iqbal Mian, Max Heinritz-Adrian, Oliver Noll, Domenico Pavone, Sascha Wenzel
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Publication number: 20110143919Abstract: A catalyst is present for use in an olefin cracking process. The catalyst is a zeolite that has been loaded with an alkaline earth metal. The alkaline earth metal loaded catalyst has an increased steaming tolerance and increases the useful life of the catalyst during the cracking process and the regeneration cycle.Type: ApplicationFiled: December 16, 2009Publication date: June 16, 2011Applicant: UOP LLCInventors: Timur V. Voskoboynikov, Aleksey Y. Pelekh, John J. Senetar
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Publication number: 20110138789Abstract: An apparatus and method for treating diesel exhaust gases are described. The system consists of two functionalities, the first being a selective catalytic reduction (SCR) catalyst system and the second being a capture material for capturing catalyst components that have appreciable volatility under extreme exposure conditions. The SCR catalyst component is typically based on a majority phase of titania, with added minority-phase catalyst components comprising of one or more of the oxides of vanadium, silicon, tungsten, molybdenum, iron, cerium, phosphorous, copper and/or manganese vanadia. The capture material typically comprises a majority phase of high surface area oxides such as silica-stabilized titania, alumina, or stabilized alumina, for example, wherein the capture material maintains a low total fractional monolayer coverage of minority phase oxides for the duration of the extreme exposure.Type: ApplicationFiled: December 15, 2009Publication date: June 16, 2011Inventor: David M. Chapman
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Publication number: 20110139682Abstract: The present invention relates to a mesopore material of a catalyst for upgrading acid-containing crude oil. Said mesopore material is an amorphous material containing alkaline earth oxide, silica and alumina, and has an anhydrous chemical formula of (0-0.3)Na2O.(1-50)MO.(6-58)Al2O3.(40-92)SiO2, based on the weight percent of the oxides, wherein M is one or more selected from Mg, Ca and Ba. Said mesopore material has a specific surface area of 200-400 m2/g, a pore volume of 0.5-2.0 ml/g, an average pore diameter of 8-20 nm, and a most probable pore size of 5-15 nm. The present invention further relates to a process for manufacturing said mesopore material and the use thereof. The catalyst prepared from the mesopore material provided in the present invention is suitable for the catalytic upgrading of inferior acid-containing crude oil and for the removal of organic acids, carbon residues and metals in the crude oil, and thus has very good economic benefits.Type: ApplicationFiled: January 9, 2009Publication date: June 16, 2011Applicant: CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Jun Long, Jiushun Zhang, Huiping Tian, Yuxia Zhu
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Patent number: 7960307Abstract: A sulfur reduction catalyst useful to reduce the levels of sulfur in a cracked gasoline product comprises a metal vanadate compound. The metal vanadate compound can be supported on a molecular sieve such as a zeolite in which the metal vanadate compound is primarily located on the exterior surface of the pore structure of the zeolite and on the surface of any matrix material used to bind or support the zeolite.Type: GrantFiled: March 6, 2007Date of Patent: June 14, 2011Assignee: BASF CorporationInventors: Xingtao Gao, James Fu
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Patent number: 7960304Abstract: A catalyst composition comprises (a) a MCM-22 family molecular sieve; and (b) a binder, wherein the MCM-22 family molecular sieve is characterized by an average crystal agglomerate size of less than or equal to 16 microns. The catalyst composition may further have a second molecular sieve having a Constraint Index of less than 12, e.g., less than 2. Examples of molecular sieve useful for this disclosure are a MCM-22 family molecular sieve, zeolite Y, and zeolite Beta. The catalyst composition may be used for the process of alkylation or transalkylation of an alkylatable aromatic compound with an alkylating agent.Type: GrantFiled: April 26, 2010Date of Patent: June 14, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Christine N. Elia, Frederick Y. Lo, Michael C. Clark, C. Morris Smith, Mohan Kalyanaraman
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Publication number: 20110130579Abstract: A process for the preparation of a catalyst for the use in a hydrocarbon conversion reaction, said catalyst containing a titanium zeolite and carbonaceous material, the catalyst containing said carbonaceous material in an amount of from 0.01 to 0.5% by weight based on the total weight of titanium zeolite contained in the catalyst, the process comprising (i) preparing a catalyst containing the titanium zeolite and (ii) depositing carbonaceous material on the catalyst according to (i) in an amount of from 0.01 to 0.5% by weight based on the total weight of titanium zeolite contained in the catalyst by contacting said catalyst, prior to using the catalyst in said hydrocarbon conversion reaction, with a fluid containing at least one hydrocarbon in an inert atmosphere, to obtain the carbonaceous material containing catalyst, wherein in (ii), the catalyst is not contacted with an oxygen containing gas.Type: ApplicationFiled: November 26, 2010Publication date: June 2, 2011Applicants: BASF SE, The Dow Chemical CompanyInventors: Ulrich MÜLLER, Peter Rudolf, Georg Krug, Rainer Senk
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Patent number: 7951742Abstract: A gas stream containing nitrous oxide and ammonia is contacted with a catalyst composition containing a zeolite. N2O is reduced to N2 and H2O at low temperatures in a highly efficient manner. Ammonia-mediated reduction of nitrous oxide can be effectuated from gas streams having N2O concentrations as low as 1%. The gas stream may also contact a catalytic composition selective for the reduction of NOx. In this way, N2O and NOx treatment may be effectuated in a single process stream.Type: GrantFiled: September 11, 2008Date of Patent: May 31, 2011Assignee: BASF CorporationInventors: James Chen, Pascaline Tran, Michael Durilla, Stanley Mack
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Publication number: 20110124933Abstract: The present invention relates to a catalyst for dehydroaromatizing C1-C4-aliphatics, said catalyst being obtainable by twice treating a zeolite from the group of MFI and MWW with NH4-containing mixtures, in each case with subsequent drying and calcination. The catalyst comprises molybdenum and, if appropriate, as further elements, Cu, Ni, Fe, Co, Mn, Cr, Nb, Ta, Zr, V, Zn and/or Ga. The present invention further provides a process for dehydroaromatizing a mixture comprising C1-C4-aliphatics by conversion in the presence of the catalyst.Type: ApplicationFiled: April 8, 2009Publication date: May 26, 2011Applicant: BASF SEInventors: Frank Kiesslich, Joana Coelho Tsou, Bilge Yilmaz, Sebastian Ahrens, Thomas Heidemann, Veronika Will, Christian Bechtold
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Publication number: 20110119990Abstract: The present invention relates to the processing of hydrocarbon-containing feedstreams in the presence of an interstitial metal hydride comprised of at least one chemical element selected from Groups 3-11 (including the lanthanides, atomic numbers 58 to 71), and at least one chemical element selected from Groups 13-15 from the IUPAC Periodic Table of Elements. These interstitial metal hydrides, their catalysts and processes using these interstitial metal hydrides and catalysts of the present invention improve overall hydrogenation, product conversion, as well as sulfur reduction in hydrocarbon feedstreams.Type: ApplicationFiled: November 17, 2010Publication date: May 26, 2011Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANHYInventors: Pallassana S. Venkataraman, Gordon F. Stuntz, Jonathan M. McConnachie, Faiz Pourarian
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Patent number: 7947621Abstract: This invention provides a process for manufacturing a catalyst with a desired attrition index, comprising the steps of selecting at least one molecular sieve having a morphology and size index (MSI) of from 1 to about 1000 to secure said desired attrition index of said catalyst.Type: GrantFiled: January 12, 2007Date of Patent: May 24, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Yun-feng Chang, Machteld Maria Mertens, Stephen N. Vaughn
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Publication number: 20110118425Abstract: The present invention is a mixture comprising by weight 0.01 to 30% of at least one medium or large pore crystalline silicoaluminate, silicoaluminophosphate materials or silicoaluminate mesoporous molecular sieves (co-catalyst) (A) for respectively 99.99 to 70% of at least a MeAPO molecular sieve. Preferably the proportion of (A) is 1 to 15% for respectively 99 to 85% of MeAPO molecular sieves. MeAPO molecular sieves having CHA (SAPO-34) or AEI (SAPO-18) structure or mixture thereof are the most preferable. Si is the most desirable metal in MeAPO. The present invention also relates to catalysts consisting of the above mixture or comprising the above mixture.Type: ApplicationFiled: January 23, 2009Publication date: May 19, 2011Applicant: TOTAL PETROCHEMICALS RESEARCH FELUYInventors: Nikolai Nesterenko, Walter Vermeiren, Sander Van Donk
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Publication number: 20110118107Abstract: Methods for enhancing the mesoporosity of a zeolite-containing material. Such methods may comprise contacting a composite shaped article containing at least one zeolite and at least one non-zeolitic material with at least one pH controlling agent and at least one surfactant. Such methods may be performed under conditions sufficient to increase the pore volume of at least one 10 angstrom subset of mesoporosity.Type: ApplicationFiled: October 19, 2010Publication date: May 19, 2011Applicant: RIVE TECHNOLOGY, INC.Inventors: Javier Garcia-Martinez, Lawrence B. Dight, Barry K. Speronello
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Publication number: 20110118108Abstract: A honeycomb structural body includes honeycomb units that are pillar-shaped and bound together. Each of the honeycomb units includes plural cells, phosphate-based zeolite, and a first inorganic binder. The plural cells extend from a first end face to a second end face in a longitudinal direction of each of the honeycomb units. The plural cells are defined by cell walls. The mat members are interposed between the honeycomb units and include a first inorganic fiber.Type: ApplicationFiled: September 28, 2010Publication date: May 19, 2011Applicant: IBIDEN CO., LTD.Inventors: Hiroki SATO, Hikaru Yoshida, Takehiro Umemoto
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Publication number: 20110116989Abstract: A honeycomb structural body includes a honeycomb unit having a plurality of through holes defined by partition walls and arranged in a longitudinal direction of the honeycomb unit and having macro-pores having an average pore diameter approximately 0.1 ?m or more and approximately 0.3 ?m or less. The macro-pores have a porosity approximately 30% or more and approximately 40% or less. The honeycomb unit includes a phosphate group zeolite and an inorganic binder.Type: ApplicationFiled: October 25, 2010Publication date: May 19, 2011Applicant: IBIDEN CO., LTD.Inventors: Yosuke MATSUKAWA, Shinnosuke Goto
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Publication number: 20110116982Abstract: A honeycomb structure includes at least one honeycomb unit. The at least one honeycomb unit has a plurality of through holes defined by partition walls along a longitudinal direction of the honeycomb unit. The honeycomb unit includes zeolite, an inorganic binder, and a noble metal catalyst. The noble metal catalyst is supported in a region of the honeycomb unit. The region extends from one end portion of the honeycomb unit in the longitudinal direction over approximately 1.5% or more to approximately 20% or less of an overall length of the honeycomb unit in the longitudinal direction.Type: ApplicationFiled: September 27, 2010Publication date: May 19, 2011Applicant: IBIDEN CO., LTD.Inventors: Masafumi Kunieda, Ken Yoshimura, Toshiyuki Miyashita