Plural Oxygens Double Bonded Directly To Ring Carbons Of The Hetero Ring Which Are Adjacent To The Ring Nitrogen Patents (Class 508/287)
  • Patent number: 5872082
    Abstract: A method of increasing the static coefficient of friction of an oleaginous composition, such as an ATF, comprising adding to a major portion of an oil of lubricating viscosity a friction increasing amount of an oil soluble friction increasing reaction product comprising (a) an oil soluble substituted or unsubstituted, saturated or unsaturated, branched hydrocarbyl group containing from about 12 to about 50 total carbon atoms, (b) a linking group, and (c) a nitrogen-containing polar group, wherein the polar group contains at least one nitrogen atom and, optionally, contains at least one atom selected from the group consisting of boron, oxygen and sulfur atoms, and wherein the polar group is linked to the branched hydrocarbyl group through the linking group.
    Type: Grant
    Filed: October 21, 1997
    Date of Patent: February 16, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Raymond Frederick Watts, Ricardo Alfredo Bloch, Antonio Gutierrez, Roger Keith Nibert, Jack Ryer
  • Patent number: 5861363
    Abstract: A lubricating oil composition for internal combustion engines giving improved soot dispersancy. That lubricating oil composition has a mixture of borated and carbonated polyalkylene succinimides derived from different molecular weight polyalkylenes. The molecular weight of the polyalkylenes from which the carbonated polyalkylene succinimide is derived is at least 300 greater than the molecular weight of the polyalkylenes from which the borated polyalkylene succinimide is derived.
    Type: Grant
    Filed: January 29, 1998
    Date of Patent: January 19, 1999
    Assignee: Chevron Chemical Company LLC
    Inventors: William W. Willis, Jr., Robert L. Freerks
  • Patent number: 5792729
    Abstract: A terpolymer having an average M.sub.n of from 600 to 100,000 is obtained by the terpolymerization of a 1-olefin having from 10 to 30 carbon atoms, maleic anhydride, and a 1,1 -disubstituted polyisobutylene having an average M.sub.n of from 500 to 5,000.
    Type: Grant
    Filed: August 20, 1996
    Date of Patent: August 11, 1998
    Assignee: Chevron Chemical Corporation
    Inventors: James J. Harrison, William R. Ruhe, Jr.
  • Patent number: 5789355
    Abstract: This invention relates to low volatility 5W20, 5W30, 10W40, 10W50, 15W40 or 15W50 multigrade oils for crankcase lubrication of gasoline and diesel engines, the oils comprising:a) basestock having an average basestock neutral number of not less than 105 for a 5W multigrade, not less than 145 for a 10W multigrade and not less than 200 for a 15W multigrade,b) a detergent inhibitor package including an ashless dispersant comprising an oil soluble polymeric hydrocarbon backbone having functional groups in which the hydrocarbon backbone is derived from an ethylene alpha-olefin (EAO) copolymer or alpha-olefin homo- or copolymer having an M.sub.n of from 500 to 7000, and preferably having >30% of terminal vinylidene unsaturation, andc) a viscosity modifier.These multigrade crankcase oils provide better volatility with reduced use or even without the need for expensive light neutral basestocks or non-conventional lubricant basestocks, while at the same time providing adequate control of sludge and varnish.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: August 4, 1998
    Assignee: Exxon Chemical Limited
    Inventors: David Robert Adams, Paul Brice
  • Patent number: 5789356
    Abstract: The present invention provides functional fluid compositions containing a major portion of oil of lubricating viscosity and a novel and synergistic combination of an acylated nitrogen-containing compound having an olefinic substituent averaging in carbon number from 20 to 60 and at least one ashless detergent/dispersant.
    Type: Grant
    Filed: February 11, 1997
    Date of Patent: August 4, 1998
    Assignee: Exxon Chemical Patents Inc
    Inventor: George Mortimer Tiffany, III
  • Patent number: 5783528
    Abstract: An improved lubricant is provided by combining ester lubricants with alkylated polyaromatic lubricants. This combination provides a lubricant that exhibits the oxidation/varnish control of alkylated naphthenics, while at the same time providing the high temperature stability of the ester-type lubricants. A wide variety of ester lubricants can be used such as polyol esters, dimeracid esters and the like. Preferably, the alkylated aromatic lubricant has a viscosity greater than 25 up to 220 cSt measured at 40.degree. C. Greases can also be formed using this combination.
    Type: Grant
    Filed: January 7, 1997
    Date of Patent: July 21, 1998
    Assignee: Diversey Lever, Inc.
    Inventor: Douglas Rodenberg
  • Patent number: 5767045
    Abstract: Hydraulic fluid compositions and additive concentrates are described that provide improved wet filtrability. The additive components comprise a mixture formed from at least (a) a zinc dihydrocarbyl dithiophosphate anti-wear agent, (b) a succinimide compound, and optionally (c) one or more alkali metal or alkaline earth metal-containing detergents.
    Type: Grant
    Filed: December 2, 1996
    Date of Patent: June 16, 1998
    Assignee: Ethyl Petroleum Additives Limited
    Inventor: Helen T. Ryan
  • Patent number: 5753597
    Abstract: A polysuccinimide composition is prepared by reacting a mixture of a copolymer of a first unsaturated acidic reagent and a 1,1-disubstituted olefin; a copolymer of a second unsaturated acidic reagent and a 1-olefin, and a polyamine under reactive conditions; then treating the reaction product with either a cyclic carbonate or a linear mono- or polycarbonate or boron compound under reactive conditions. The two unsaturated acidic reagents can be the same or different. The mixture contains from 0.1 to 1.5 equivalents of polyamine per equivalent of acidic groups of the first and second copolymers.
    Type: Grant
    Filed: August 20, 1996
    Date of Patent: May 19, 1998
    Assignee: Chevron Chemical Company
    Inventors: James J. Harrison, William R. Ruhe, Jr.
  • Patent number: 5726132
    Abstract: This invention relates to compositions for improving fuel efficiency in internal combustion engines. The composition comprises a lubricant having an oil of lubricating viscosity and (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate.
    Type: Grant
    Filed: February 28, 1997
    Date of Patent: March 10, 1998
    Assignee: The Lubrizol Corporation
    Inventors: Stephen H. Roby, James A. Supp, John S. Manka, William D. Abraham
  • Patent number: 5705458
    Abstract: This invention relates to a composition, comprising: (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), G.sup.1 and G.sup.2 are independently R, OR, SR or NRR wherein each R is independently a hydrocarbyl group, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a phosphorus compound. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate. These compositions are useful in providing lubricating compositions and functional fluids with enhanced antiwear properties.
    Type: Grant
    Filed: October 24, 1996
    Date of Patent: January 6, 1998
    Assignee: The Lubrizol Corporation
    Inventors: Stephen H. Roby, James A. Supp, William D. Abraham, John S. Manka
  • Patent number: 5674820
    Abstract: This invention relates to a composition, comprising: (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms, In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof, In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxytic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate. These compositions are useful in providing lubricating compositions and functional fluids with enhanced antiwear properties.
    Type: Grant
    Filed: September 5, 1996
    Date of Patent: October 7, 1997
    Assignee: The Lubrizol Corporation
    Inventors: John S. Manka, William D. Abraham, Stephen H. Roby, James A. Supp, Craig D. Tipton
  • Patent number: 5614480
    Abstract: A lubricating oil composition is described which comprises a major amount of an oil of lubricating viscosity and(A) at least about 1% by weight of at least one carboxylic derivative composition produced by reacting(A-1) at least one substituted succinic acylating agent containing at least about 50 carbon atoms in the substituent with(A-2) from about 0.5 equivalent up to about 2 moles, per equivalent of acylating agent (A-1), of at least one amine compound characterized by the presence within its structure of at least one HN<group; and(B) at least one alkali metal overbased salt of a hydrocarbyl-substituted carboxylic acid or a mixture of a hydrocarbyl carboxylic acid and a hydrocarbyl-substituted sulfonic acid having a metal ratio of greater than 2 in an amount sufficient to provide at least about 0.
    Type: Grant
    Filed: July 25, 1994
    Date of Patent: March 25, 1997
    Assignee: The Lubrizol Corporation
    Inventors: Mary F. Salomon, Kirk E. Davis, Jack L. Karn, John Cahoon
  • Patent number: 5567342
    Abstract: An internal combustion engine lubricating oil composition adapted for used with a maintenance-free system of engine and having excellent properties including oxidation stability, resistance against sludge formation and ability to clean the engine. The composition is characterized in that it comprises ingredients (A) through (D) below as essential components on the basis of total amount of composition and the total base number of the composition is between 2.0 and 6.0 mgKOH/g: (A) a specific alkaline earth metal type cleaning agent, (B) zinc dialkyldithiophosphate expressed by a specific general formula (1), (C) a succinic acid imide type ashless dispersant and (D) a phenol type and/or amine type ashless antioxidant.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: October 22, 1996
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Kiyoshi Inoue, Masakuni Hirata
  • Patent number: 5562867
    Abstract: A biodegradable two-cycle oil composition which comprises a C.sub.13 oxo alcohol adipate in admixture with a dispersant and a lubricity agent; it is especially useful for outboard marine engines.
    Type: Grant
    Filed: June 28, 1995
    Date of Patent: October 8, 1996
    Assignee: Exxon Chemical Patents Inc
    Inventors: George M. Tiffany, III, Beth A. Morgan, George C. L'Heureux, Lewis H. Gaines, William H. Stover
  • Patent number: 5561103
    Abstract: Compositions of matter containing self condensation reaction products of alkylthio alkanols and dispersants which are found to have utility in lubricating/functional fluids.
    Type: Grant
    Filed: September 25, 1995
    Date of Patent: October 1, 1996
    Assignee: The Lubrizol Corporation
    Inventor: Craig D. Tipton