Abstract: Compositions and methods for cleaning, solvating, and/or removing plastic resins and polymers or other contaminants from manufactured articles or manufacturing equipment, particularly in the production of optical lenses. The compositions contain at least one nitrogen containing compound as well as other optional solvents and additives. The compositions can be contacted with a surface to be cleaned in a number of ways and under a number of conditions depending on the manufacturing or processing variables present.
Type:
Grant
Filed:
September 3, 1998
Date of Patent:
January 25, 2000
Assignee:
Kyzen Corporation
Inventors:
Kyle J. Doyel, Michael L. Bixenman, Scotty S. Sengsavang, Kristie L. Gholson, Patricia D. Overstreet, Arthur J. Thompson, Valerie G. Porter
Abstract: Hard surfaces such as tile, metal, glass, etc. typically in hospitality locations can be cleaned to a bright, shiny, residue-free appearance using a process comprising cleaning the surface with a first cleaning composition and removing the resulting cleaner residue with a finish cleaner composition. The finish cleaner composition removes all trace of soil and cleaner from the first step and dries to a bright, shiny, spot-free, streak-free, and film-free appearance without a need for a final wipe step.
Abstract: Inexpensive paint stripper compositions containing neither chlorinated nor alkaline solvents and well adapted for removing paints such as glycerophtalic, alkyd-urethane or arylic urethane paints on a variety of substrates, e.g. wood and metal substrates comprise (a) 1 to 99% by volume of an aprotic polar solvent chosen from the group comprising: dimethyl sulfoxide, dimethyl formamide, N-methylpyrrolidone, N-methylmorpholine, .gamma.-butyrolactone, acetonitrile and mixtures thereof; and (b) 99 to 1% by volume of an ether selected from the family of ethers having a flash point higher than 0.degree. C., a molar volume less than 160 and a molecule that includes one or several methoxy groups.
Abstract: Stripping compositions based on a polar aprotic solvent, an ether and water. The composition is characterized in that it comprises at least the following: 1) a polar aprotic solvent, especially dimethyl sulfoxide (DMSO) or N-methyl pyrrolidinone (NMP); 2) an ether chosen from anisole and tetrahydrofuran (THF); 3) water.
Abstract: A paint-stripping composition comprises, on a weight basis, at least 20% of a benzyl alcohol, together with 5-30% of methylene chloride, 1-10% of hydrogen peroxide and 10-60% of water. The composition may also include auxiliary ingredients such as thickeners, evaporation retardants, surfactants, pH control agents, accelerators, corrosion inhibitors, preservatives, coloring agents, and fragrances.
Type:
Grant
Filed:
December 19, 1997
Date of Patent:
November 23, 1999
Assignee:
Gage Products Company
Inventors:
Stephen R. Summerfield, Matthew W. Clark, Neil R. Wilson, Michael E. Moore, Thomas A. Vivian, Scott A. Hofacker
Abstract: A terpene-free hard surface cleaning composition containing: (a) a nonionic surfactant; (b) an anionic surfactant; (c) a primary solvent consisting of a C.sub.6 -C.sub.14 methyl ester; (d) a short-chain cosurfactant; and (e) water, all weights being based on the total weight of the composition.
Type:
Grant
Filed:
February 8, 1999
Date of Patent:
November 23, 1999
Assignee:
Henkel Corporation
Inventors:
Stephen F. Gross, Martin J. Barabash, J. Frederick Hessel
Abstract: A cleaning composition comprising at least one low molecular weight polyorganosiloxane selected from the group consisting of straight chain polydiorganosiloxane represented by a general formula: ##STR1## (wherein R.sup.1 is an organic group of single valence substituted by the same or different group or unsubstituted, and l is an integer from 0 to 5), and cyclic polydiorganosiloxane represented by a general formula: ##STR2## (wherein R.sup.1 is an organic group of single valence substituted by the same or different group or unsubstituted, and m is an integer from 3 to 7). To use it as a water system cleaning agent, polyoxyalkylene group containing polyorganosiloxane, a surfactant, and water are additionally mixed. Accordingly, a cleaning effect free from environmental destruction and contamination, equivalent to flon containing cleaning agents, and satisfactorily stable in terms of dispersion as a water system cleaning agent can be obtained.
Abstract: The present invention is directed to a composition for stripping coatings from a surface, the composition including:a. A solvent mixture composed of a phenyl substituted alkyl alcohol and an alkyl or aryl glycol ether or an alkyl or aromatic alcohol;b. A coupler composed of a salt formed from a water soluble organic amine and an acid comprising at least one C7-C18 ethoxylated anionic surfactant;c. Optionally water.The use of the C7-C18 ethoxylated anionic surfactant provides a stripper which can be diluted in water of various compositions yet provide an effective stripping/cleaning agent.
Abstract: A process for selectively removing an aluminide-containing coating from the surface of a metal-based substrate is disclosed. It includes the following steps:(a) contacting the surface of the substrate with at least one stripping composition to degrade the coating without severely pitting the substrate, wherein the stripping composition is selected from the group consisting of: (i) aliphatic or aromatic sulfonic acids; (ii) a solution of an inorganic acid and an organic solvent; and (iii) sulfuric acid or an aqueous solution of sulfuric acid; and then(b) removing the degraded coating without damaging the substrate.
Abstract: A method is provided to render non-hazardous surface soil which is contaminated with lead compounds. The soil is treated by applying an aqueous composition comprising hydrogen peroxide, ammonium hydroxide, nitric acid and acetic acid and allowing said composition to migrate through the soil.
Type:
Grant
Filed:
December 24, 1997
Date of Patent:
November 2, 1999
Inventors:
Joseph Zelez, Anthony Peter Balestrieri, Robert Howard
Abstract: A cleaning and dusting composition, particularly useful as a treatment for dusting implements such as a cloth or feather duster, comprised of a high quality natural wax in an alcohol solution. In the preferred embodiment, a near-saturated solution of lanolin in denatured ethyl alcohol is employed to provide a rapidly drying, non-smear, low residue, and safe dusting treatment composition.
Abstract: There is disclosed a cleaning liquid for producing a semiconductor device which comprises (A) fluorine-containing compound; (B) water-soluble or water-miscible organic solvent; and (C) inorganic acid and/or organic acid, optionally, further comprises (D) quaternary ammonium salt or (D') a specific organic carboxylic acid ammonium salt and/or an organic carboxylic acid amine salt; as well as a process for producing a semiconductor device by forming a resist pattern on a substrate equipped on the surface with an insulating film layer or a metallic electroconductive layer, forming a via hole or electric wiring by dry etching, removing the resist pattern by ashing treatment with oxygen plasma; and effecting an cleaning treatment with the above cleaning liquid. The above cleaning liquid and production process can readily remove the deposit polymer formed in the case of dry etching without impairing metallic film and insulating film.
Abstract: Compositions and methods for removal of polymeric coatings from nonporous surfaces are provided. The method comprises the mixing of two stock solutions, a peroxide/acid solution and an alkaline solution, and immediate application to the surface to be stripped of coating. The applied mixture produces a controlled peroxide oxidation reaction causing the coating to become softened-to-release. A further step of washing or blowing with water, air, cornstarch, or plastic media will remove the softened-to-release coating. The two stock solutions are stable to storage and, when in use, are continuously mixed in a volume so as to control reaction rate, pH, corrosivity of the coating remover, and reaction rate with the coating.
Type:
Grant
Filed:
September 26, 1997
Date of Patent:
September 21, 1999
Assignee:
Eldorado Chemical Co., Inc.
Inventors:
Pat E. Smith, John M. Jasper, William R. Zinnecker, Joe R. Fredricksen
Abstract: This invention provides graffiti removers for removing permanent ink stains from painted surfaces. The graffiti removers include an active solvent for dissolving the stains, which are organic in nature, an optional secondary solvent for concentrated attack on the stain without being adversely affected by dilution with water, an emollient for maintaining a uniform dispersion of particulates in the remover and on the graffiti-stained painted surfaces, and an amorphous, particulate, mildly abrasive filler for imbibing the solvents, the filler being selected to permit the slow release of the active solvent.
Abstract: An alkaline degreasing solution containing 0.01 to 3 g/l of alkali silicate calculated as Si concentration, and 0.01 to 10 g/l of a nonionic surfactant having an HLB value (=20.times.Mw/M, where Mw represents the weight of a hydrophilic group part and M represents the molecular weight of the surfactant) of 5 to 11 and a structure being expressed in the following general formula (I), with a pH value of at least 9.5:R--O--(EO).sub.m (AO).sub.n H (I)where R represents alkyl group, EO represents ethylene oxide group, AO represents alkylene oxide group (propylene oxide group and/or butylene oxide group), m represents an addition molar number of EO which is an integer of 3 to 7, n represents an addition molar number of AO which is an integer of 1 to 6, and m and n satisfy the relation of n<m.ltoreq.3n.
Abstract: A "stickie" remover cleaning composition consists of aliphatic petroleum distillate, d-limonene, and an aliphatic dibasic acid ester mixture containing approximately 59% dimethyl glutarate, 21% dimethyl adipate, and 20% dimethyl succinate for use in paper mill production. "Stickies" are resinous type organic materials predominately commonly found in de-inked secondary fiber. Secondary fiber is pulp derived from telephone books, computer paper, etc., and are more common in de-inked secondary fiber than in virgin pulp.
Abstract: A stripping and/or cleaning composition is disclosed, which contains, by volume: (a) 1 to 90% of at least one C.sub.1 -C.sub.4 dialkyl ester of at least one C.sub.4 -C.sub.6 aliphatic diacid; and (b) 99 to 1% of at least one ether selected from the group consisting of ethers with a flash point above 5.degree. C., at least one methoxy group per molecule and a molecular weight of less than 200.
Abstract: A non-aqueous negative photoresist stripping composition which consists essentially of about 40 to 80% by weight of an alkylnaphthalene solvent, about 5 to 20% by weight of an alkyl phenol which provides a corrosion inhibitory effect, about 5 to 20% by weight of a linear monoalkylbenzene sulfonic acid which is a surfactant and about 1 to 10% by weight of a dialkylbenzene sulfonic acid. There is further provided a process for removing coatings from a photoresist with the compositions of the invention.
Abstract: Compositions and methods for removal of polymeric coatings from nonporous surfaces are provided. The method comprises the mixing of two stock solutions, a peroxide/acid solution and an alkaline solution, and immediate application to the surface to be stripped of coating. The applied mixture produces a controlled peroxide oxidation reaction causing the coating to become softened-to-release. A further step of washing or blowing with water, air, cornstarch, or plastic media will remove the softened-to-release coating. The two stock solutions are stable to storage and, when in use, are continuously mixed in a volume so as to control reaction rate, pH, corrosivity of the coating remover, and reaction rate with the coating.
Type:
Grant
Filed:
October 27, 1995
Date of Patent:
November 3, 1998
Assignee:
Eldorado Chemical Co., Inc.
Inventors:
Pat E. Smith, John M. Jasper, William R. Zinnecker, Joe R. Fredricksen
Abstract: A floor stripper composition is provided, having a pH-value above 9.0, and comprising a soap, water and a glycine-N,N-diacetic acid compound, which is preferably methylglycine diacetic acid (MGDA). The diacetic acid is desirably in the form of a divalent metal complex thereof. A process is also provided for removing a zinc containing acrylate polymer film from a floor surface, wherein a floor stripper composition of the invention is applied. A good floor stripper performance could be obtained with this composition owing to its low foaming behaviour.
Abstract: An improved aqueous liquid composition for power washing of paint masks contains: organic film-forming polymer, preferably polyacrylamide; inorganic salts, preferably a combination of alkali metal pyrophosphate, metaborate, and tetraborate; and dissolved organic molecules that (i) are hydrocarbons except for having hydroxyl substituents and, optionally, having one or more other types of substituents selected from halogen atoms, keto groups, and aldehydo groups and (ii) have a number ratio of oxygen atoms to carbon atoms that is at least 0.5; and, optionally but preferably, free boric acid.
Abstract: Insoluble polymer formed during the distillation of N-vinylformamide is removed by contacting the insoluble polymer with an aqueous weakly basis solution in a closed system at elevated temperature. Polymer (up to 50 wt % polymer gel or 5.5 wt % dry polymer in reaction mixture) is treated with an aqueous solution of an amine, alkanolamine or weak inorganic base having a concentration of at least 1 molar. Solvents like alcohols, glycol ethers or amides may be added as a cosolvent in an amount of from 0 to about 85% by weight.
Abstract: Methods and compositions useful for removing a titanium dioxide-containing material located on a surface, for example, a surface of a piece of process equipment, are disclosed. In one embodiment, the present methods provide for contacting the titanium dioxide-containing material located on the surface with a composition comprising at least about 20% by weight of water, an acid component in an amount effective to reduce the adhesion between the titanium dioxide-containing material and the surface; and an organic component in an amount effective to disperse the titanium dioxide-containing material in the composition.
Type:
Grant
Filed:
June 17, 1996
Date of Patent:
June 9, 1998
Assignee:
Dober Chemical Corporation
Inventors:
Daniel J. Dobrez, Mark R. Lalinsky, Robert J. Rybarski
Abstract: A cleaning composition for paint delivery systems includes 3-90% of an organic solvent which may comprise one or more aromatic hydrocarbons, aliphatic hydrocarbons and aliphatic esters. The composition also includes between 0.5 and 30% of a hydroxy carboxylic acid such as glycolic acid, as well as a coupling agent which may comprise one or more alcohols, glycols or glycol ethers.
Abstract: Inexpensive paint stripper compositions containing neither chlorinated nor alkaline solvents and well adapted for removing paints such as glycerophtalic, alkyd-urethane or acrylic urethane paints on a variety of substrates, e.g. wood and metal substrates comprise (a) 1 to 99% by volume of an aprotic polar solvent chosen from the group comprising: dimethyl sulfoxide, dimethyl formamide, N-methylpyrrolidone, N-methylmorpholine, .gamma.-butyrolactone, acetonitrile and mixtures thereof; and (b) 99 to 1% by volume of an ether selected from the family of ethers having a flash point higher than 0.degree. C. a molar volume less than 160 and a molecule that includes one or several methoxy groups.
Abstract: Stripping action of an alkaline paint stripper is improved when ammonia is partially or completely replaced with ammonium bicarbonate or chemical equivalent thereof which decomposes into ammonia and carbon dioxide. A benzyl alcohol solvent system containing at least ammonium bicarbonate is preferably a water-in-oil emulsion emulsified with oleic hydroxyethyl imidazoline and thickened with hydroxypropyl cellulose or hydroxypropyl methylcellulose. A mixture of ammonium carbamate and ammonium bicarbonate identified as ammonium carbonate is the preferred activator for this alkaline paint stripper. Improved stripping can also be provided by reacting ammonium bicarbonate and ammonia in situ within the water-in-oil emulsion.
Abstract: A method is provided, to render non-hazardous, surfaces which are coated with lead-based paints. A composition comprising an aqueous mixture of hydrogen peroxide, ammonium hydroxide, nitric acid and acetic acid is poured on the surface and, after a time, water is poured onto the surface to remove the lead-based paint. The method is effective on surfaces which may be comprised of wood, metal, concrete, wallboard or plaster without destroying the integrity of these surfaces.
Type:
Grant
Filed:
February 9, 1996
Date of Patent:
April 21, 1998
Inventors:
Joseph Zelez, Anthony Peter Balestrieri, Robert Howard
Abstract: A method for preparing an environmentally safe composition free of chlorinated solvents which is non-flammable, fully biodegradable, and low odor and the use of such composition for the removal of various coatings from metal substrates. The composition comprises a water-based mixture of one or more high boiling, high flash aromatic solvent(s), a peroxide generating agent, and a hydroxycarboxylic acid. It can be prepared as a liquid and used as such for immersion/dipping operations or as a thick paste "cling type" material when optimal application requires a thin film. These can be applied by spraying or brushing.
Abstract: Process for cleaning equipment and equipment cleaner for implementing the process.The invention relates to a process for cleaning equipment contaminated with lacquer residues, in which the lacquer residues are removed with a solvent mixture and an equipment cleaner based on a solvent mixture for implementing the process. The solvent mixture containsA) 15-35 wt. % of one or more glycol ethers of the general formula IOH--(CH.sub.2 --CH.sub.2 --O).sub.m --R.sub.1 Iwhere R.sub.1 =C.sub.1-4 -alkyl and m=1 or 2 andB) 65-85 wt. % of one or more aliphatic ketones of the general formula II ##STR1## where R.sub.2=C.sub.1-3 -alkyl and R.sub.3 =C.sub.1-3 -alkyl and R.sub.2 and R.sub.3 may be identical or different.
Type:
Grant
Filed:
January 11, 1996
Date of Patent:
December 23, 1997
Assignee:
Herberts Gesellschaft mit beschrankter Haftung
Inventors:
Wolfgang Stricker, Udo Hellmann, Werner Stephan
Abstract: A solvent that will remove all types of commercially available water soluble polymers by breaking the covalent bonds within the polymer molecules such that these polymers can then be removed from all surfaces and equipment completely and safely by washing away with water.The solvent consists of (in a 21/2 gallon concentrated solution) 4% of ammonium chloride, 29% of ammonium hydroxide, and 67% water.
Abstract: The present invention generally relates to the formation of organic gels by dissolving organic gelling agents in organic solvents. The aryl cyclohexanol gelling agents employed in this invention are not structurally related to previously known gellation agents and they exhibit potent gellation activity, for example, from 0.2-5%, by weight, of gelling agent is able to immobilize a variety of organic solvents. The gels formed range from optically transparent to slightly translucent, and complete fluidity can be restored by either increasing the temperature (reversible) or by chemical treatment (irreversible).
Abstract: An advantageous effective cleaning solvent consisting essentially, according to one embodiment, of methyl ethyl ketone, methyl isobutyl ketone, isopropyl alcohol, toluene and n-butyl acetate, in certain ranges of proportions. Water also is included to aid in reducing the vapor pressure of the solvent. The composite vapor pressure of the solvent, at 20.degree. C., neglecting the vapor pressure contribution of water, is not greater than 35 mm of mercury. The invention solvent is particularly effective as a paint cleaner, e.g. for cleaning paint guns.
Type:
Grant
Filed:
March 7, 1996
Date of Patent:
October 14, 1997
Assignee:
McDonnell Douglas Corporation
Inventors:
John M. Locklin, Paul A. Hatcher, Mervin A. Danforth
Abstract: The present invention is drawn toward compositions and methods of using same, the compositions comprising (in diluted form):a) an effective amount of a phenyl substituted alkyl alcohol having a water solubility of at least 0.1 weight percent (preferably benzyl alcohol);b) a coupler; andc) water,wherein the amount of the coupler is at least 3.0 times the amount necessary to completely solubilize the phenyl substituted alkyl alcohol in the water. Preferred couplers are the salt of a monofunctional water-soluble amine and an organic acid comprising at least one water-insoluble organic acid having from 6-10 carbon atoms. Methods of removing coatings such as standard urethane/acrylic sealer finishes from floors using the inventive compositions are also described.
Type:
Grant
Filed:
November 18, 1994
Date of Patent:
June 10, 1997
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Francis J. Koreltz, James A. McDonell, Fidelis C. Onwumere, Toshihiro Funabiki
Abstract: A composition for removing paint, particularly graffiti, is described which contains an alkylene carbonate, which may be propylene carbonate, butylene carbonate or mixtures thereof; propylene glycol as a hydrotrope, and a polypropylene glycol having a molecular weight of at least 200. In one embodiment, the composition also contains a hydroxyalkylcellulose thickener, for example, at least 0.5 volume percent hydroxymethylcellulose may be present. In another embodiment, the composition contains no N-methylpyrrolidone, amine, DMSO, isocetyl alcohol or surfactant, unlike some prior graffiti-removing compositions.
Abstract: Solvent formulations used in thinning oil-based resins and in cleaning equipment contaminated with oil-based resins include mixtures of constituents with low-, or no-toxicity and flash points generally considered to be above flammability levels. The formulations are compatible with such resins and further have drying characteristics suitable for most users. The solvating power and drying characteristics of these formulations are equivalent to turpentine and mineral spirits, but without the safety concerns associated with those thinners. The formulation components of the present invention include propylene glycol ethers comprising no more than 60% by weight of the solvent mixture, no more than 10% by weight of an isoalkane compound, and no more than 30% by weight of an oxidizing oil, and no more than 30% by weight of an odor-masking compound, preferably d-limonene.
Abstract: A method and composition for clean up of an oil based composition using an aqueous solution. The clean up composition includes 5-60% by weight of a solubility controlling component exhibiting pH dependent water solubility behavior and 30-95% by weight of a diluent. The method includes applying the clean up composition to the oil based composition and cleaning the same with an aqueous solution having a wash pH falling within the pH levels at which the solubility controlling component is water washable.
Abstract: The invention teaches an aqueous stripping composition that is essentially free of any hydroxylamine compounds. The composition is an aqueous mixture of an alkanolamine, tetraalkylammonium hydroxide, and an inhibitor. The composition is particularly useful for cleaning substrates containing organic residues.