With Non -c=x Containing Reactant Patents (Class 521/173)
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Patent number: 12162976Abstract: Isopropylidenediphenol-based polyether polyols, processes for their production, foams produced using such isopropylidenediphenol-based polyether polyols, such as PUR-PIR rigid foams, as well as to processes for producing such foams. The polyether polyols have an internal block comprising polymerized ethylene oxide moieties and an external cap comprising polymerized propylene oxide moieties.Type: GrantFiled: February 14, 2022Date of Patent: December 10, 2024Assignee: Covestro LLCInventors: Sharlene A. Lewis, Anthony R. Loveday, Eric M. Rexrode
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Patent number: 12104006Abstract: Polyol blends, isocyanate-reactive compositions, polyurethane foam-forming compositions, methods of producing polyurethane foams, polyurethane foams produced from such compositions and made by such methods. The polyol blends, isocyanate-reactive compositions and polyurethane foam-forming compositions include an isopropylidenediphenol-based polyether polyol in combination with another polyol.Type: GrantFiled: June 29, 2022Date of Patent: October 1, 2024Assignee: Covestro LLCInventors: Brandon Parks, Sharlene Lewis, Tony Loveday, Ted Frick
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Patent number: 12098234Abstract: A stable polyol pre-mix composition comprises a blowing agent, a polyol, a surfactant, and a catalyst composition comprising an oxygen-containing amine catalyst and a metallic salt. The oxygen-containing amine catalyst may be, for example, one or more of an alkanol amine, an ether amine, or a morpholine group-containing compound such as, for example, 2-(2-dimethylaminoethoxy)ethanol or N,N,N?-trimethylaminoethyl-ethanolamine. The metallic salt may be, for example, alkali earth carboxylates, alkali carboxylates, and carboxylates of metals selected form the group consisting of zinc (Zn), cobalt (Co), tin (Sn), cerium (Ce), lanthanum (La), aluminum (Al), vanadium (V), manganese (Mn), copper (Cu), nickel (Ni), iron (Fe), titanium (Ti), zirconium (Zr), chromium (Cr), scandium (Sc), calcium (Ca), magnesium (Mg), strontium (Sr), and barium (Ba).Type: GrantFiled: March 29, 2021Date of Patent: September 24, 2024Assignee: Arkema Inc.Inventors: Benjamin Bin Chen, Joseph S. Costa, Laurent T. Abbas, Haiming Liu, Sri R. Seshadri, William D. Honnick
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Patent number: 11827737Abstract: A novel thermoplastic polyurethane composition is disclosed which comprise the reaction product of a polyisocyanate component, a polyol component, wherein the polyol component comprises a polyester comprising the reaction product of triethylene glycol and/or tetraethylene glycol with a diacid having 6 carbon atoms or fewer, and, optionally, a chain extender component.Type: GrantFiled: November 7, 2018Date of Patent: November 28, 2023Assignee: Lubrizol Advanced Materials, Inc.Inventors: Julius Farkas, Charles P. Jacobs
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Patent number: 11813763Abstract: A razor blade including a blade body, an expanded coating structure arranged on a surface of the blade body so as to cover the blade body at least partially, the expanded coating structure including one or more expanded polymer microspheres, at least one of the one or more expanded polymer microspheres including a gas encapsulated within a hollow thermoplastic polymer shell.Type: GrantFiled: November 19, 2020Date of Patent: November 14, 2023Assignee: BIC VIOLEX SINGLE MEMBER S.A.Inventors: George Kanakaris, Christos Ampatis
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Patent number: 11787897Abstract: Described herein is a method for producing a PU foam insole, including the following steps of: (1) pouring the raw materials used to form a PU foam into a mould, reacting to obtain a PU sheet, where the height of the mould cavity is from about 1.0 to about 1.6 times of the total thickness of two finished insoles; (2) splitting the PU sheet into two halves in the horizontal direction to obtain two pieces of PU insole material, where one surface of the material has open pores, and the other surface of the material has a skin; and (3) attaching a piece of fabric onto the surface having open pores of the material obtained in step (2). Also described herein is a PU foam insole produced by the method.Type: GrantFiled: December 4, 2018Date of Patent: October 17, 2023Assignee: BASF SEInventors: Zhen Peng Liang, Yun Bang Zhong
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Patent number: 11708515Abstract: The invention relates to an adhesive dual-component composition based on polyurethane, comprising an —NCO component and an —OH component such that: the —NCO component is a composition comprising: A) at least one polyurethane prepolymer comprising at least two NCO terminal groups obtained by the polyaddition reaction of at least one dissymmetric diisocyanate monomer and at least one diol, and B) at least one triisocyanate selected from isocyanurates, biurets, diisocyanate and triol adducts, and the mixtures thereof; the —OH component is a composition comprising at least one polyol; at least one of the polyols or diols is selected from polyether polyols (or polyether diols); at least one of the polyols or diols is selected from polyester polyols (or polyester diols); and the weight ratio of the quantity of polyether polyol(s) to the quantity of polyester polyol(s), defined as r4, ranges from 0.6 to 2.2.Type: GrantFiled: July 7, 2017Date of Patent: July 25, 2023Assignee: BOSTIK SAInventors: Francis Pardal, Guillaume Michaud, Aurélien Wiegand, David Penet
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Patent number: 11292867Abstract: A polyurethane foam material having the following properties: Compression hardness at 10% (according to ISO 3386/1) higher than 60 kPa and lower than 120 kPa; Free rise density in the range 40-80 kg/m3 (according to ISO 845); Flexural modulus (according to ISO 1209-2) in range 0.95-2 MPa.Type: GrantFiled: August 22, 2017Date of Patent: April 5, 2022Assignee: HUNTSMAN INTERNATIONAL LLCInventors: Raf Elen, Luc Van Essche
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Patent number: 9023908Abstract: The present invention relates to a method for adsorbing and/or absorbing oil, by bringing oil into contact with a polyurethane sponge with excellent mechanical properties.Type: GrantFiled: May 24, 2011Date of Patent: May 5, 2015Assignee: BASF SEInventors: Nils Mohmeyer, Ralf Fritz, Bernd Bruchmann, Anna Cristadoro, Marcus Leberfinger, Antje van der Net
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Patent number: 8980422Abstract: A polyurethane/polyisocyanurate foam is obtainable from the reaction of A) a polyol component comprising A1) an aromatic polyester polyol, A2) a polyether polyol started on a carbohydrate polyol and A3) a polyether polyol started on ethylene glycol, wherein the total hydroxyl number of the polyol component A) is from ?150 mg KOH/g to ?300 mg KOH/g; with B) a polyisocyanate component, wherein the equivalent ratio of NCO groups to the sum of the hydrogen atoms reactive towards NCO groups is from ?110:100 to ?200:100. This foam has improved adhesion properties to facings and is suitable for the production of composite elements without requiring the use of an additional adhesion promoter.Type: GrantFiled: November 9, 2010Date of Patent: March 17, 2015Assignee: Bayer MaterialScience AGInventors: Rolf Roers, Torsten Heinemann, Maria Dolors Mateu
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Patent number: 8940803Abstract: The present invention relates to a rigid polyurethane foam which can be obtained by mixing (a) isocyanates, (b) compounds having groups which are reactive toward isocyanates, (c) blowing agents comprising water, (d) catalysts and optionally (e) further additives to form a reaction mixture, applying the reaction mixture to a reinforcing material and curing the reaction mixture, where the isocyanates (a) have a viscosity of not more than 500 mPas at 25° C. and the compounds (b) having groups which are reactive toward isocyanates comprise a polyetherol (b1) having a functionality of 4 or more and a viscosity at 25° C. of 10 000 mPas or less, a polyetherol (b2) having a functionality of 3.5 or less and a viscosity at 25° C. of 600 mPas or less, a polyesterol (b3) having a viscosity at 25° C. of 2000 mPas or less, chain extenders (b4) comprising at least 30% secondary OH groups and optionally a crosslinker (b5).Type: GrantFiled: December 3, 2009Date of Patent: January 27, 2015Assignee: BASF SEInventors: Marco Balbo Block, Cheul Hyeon Hwang
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Publication number: 20150025164Abstract: The present invention relates to polyurethane rigid foams formulations. More particularly, the present invention relates to polyurethane rigid foams formulations, prepared from aromatic polyester polyols, which show improved compressive strength. The formulations include an isocyanate reacting mixture, at least one polymeric diphenylmethane diisocyanate, having a functionality of at least 2.7, and at least one blowing agent; such that the stoichiometric index of the polyisocyanate to the isocyanate reacting mixture is 1.0-1.8.Type: ApplicationFiled: August 24, 2012Publication date: January 22, 2015Applicant: Dow Global Technologies LLCInventors: Paolo Golini, Maurizio Guandalini
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Publication number: 20140370267Abstract: The present invention relates to a polyurethane/polyisocyanurate foam with improved dimensional stability. It relates further to the use thereof in the production of metal composite elements, to metal composite elements produced therewith, and to a method for producing metal composite elements.Type: ApplicationFiled: January 30, 2013Publication date: December 18, 2014Applicant: Bayer Intellectual Property GmbHInventors: Rolf Roers, Torsten Hagen, Rene Abels, Inge Tinnefeld, Walter Schindler
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Patent number: 8901189Abstract: A foam article, for use in a seat such as a seat cushion, includes an open cell, polyurethane foam material that includes a plant oil-based polyol material content greater than five percent and is produced from the reaction of a base polyol formulation blend including at least a portion of a plant oil-based polyol, a copolymer polyol including at least a portion of a plant oil-based polyol, water, a cross-linking agent, a catalyst, cell opener and a surfactant that are reacted with an isocyanate material for producing the seat cushion having performance specifications that are equivalent or better than the performance characteristics for a traditional petroleum oil-based polyol material seat cushion.Type: GrantFiled: October 30, 2007Date of Patent: December 2, 2014Assignee: Johnsons Controls Technology CompanyInventors: Patricia J. McClarren, Ryoko Yamasaki, James T. McEvoy, Terry M. McRoberts, William W. Li
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Patent number: 8895636Abstract: Rigid polyurethane foams or rigid polyisocyanurate foams with low brittleness are produced by the reaction of polyisocyanate polyetherester polyols based on aromatic dicarboxylic acids obtained by esterification of a dicarboxylic acid composition containing aromatic dicarboxylic acids and aliphatic dicarboxylic acids, fatty acids, aliphatic or cycloaliphatic diols having 2 to 18 carbon atoms or alkoxylates thereof, and a polyether polyol having a functionality of not less than 2.Type: GrantFiled: December 31, 2012Date of Patent: November 25, 2014Assignee: BASF SEInventor: Gunnar Kampf
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Patent number: 8865785Abstract: A polishing pad capable of maintaining a high level of dimensional stability upon moisture absorption or water absorption and providing high polishing rate includes a polishing layer of a polyurethane foam having fine cells, wherein the polyurethane foam includes a cured product of a reaction of (1) an isocyanate-terminated prepolymer (A) that includes an isocyanate monomer, a high molecular weight polyol (a), and a low molecular weight polyol, (2) an isocyanate-terminated prepolymer (B) that includes a polymerized diisocyanate and a polyethylene glycol with a number average molecular weight of 200 to 1,000, and (3) a chain extender.Type: GrantFiled: March 13, 2008Date of Patent: October 21, 2014Assignee: Toyo Tire & Rubber Co., Ltd.Inventor: Yoshiyuki Nakai
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Patent number: 8865782Abstract: A fire-resistant polyurethane foam is provided. A hydroxyl-containing inorganic fire retardant is premixed with a polyisocyanate and a polyol, respectively, to form two premixtures. Then, the two premixtures are mixed for reaction to form a fire-resistant polyurethane foam. Preferably, a combination of different particle sizes of the fire retardant is employed to maximize the amount of the fire retardant and increase the fire resistance of the foam.Type: GrantFiled: November 6, 2013Date of Patent: October 21, 2014Assignee: Industrial Technology Research InstituteInventors: Po-Ju Chen, Sung-Jeng Jong, Ren-Kuen Chang, Chin-Shang Hsu, Jer-Young Chen, Yih-Her Chang, Chei Kao
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Patent number: 8846776Abstract: Composite materials and methods for their preparation are described herein. The composite materials include a polyurethane made from the reaction of an isocyanate and a mixture of polyols, and coal ash (e.g., fly ash). The mixture of polyols comprises at least two polyols including a high hydroxyl number polyol having a hydroxyl number greater than 250 and comprising from about 1% to about 25% by weight of the total polyol content used to form the polyurethane, and a low hydroxyl number polyol having a hydroxyl number of 250 or lower. The coal ash is present in amounts from about 40% to about 90% by weight of the composite material. Also described is a method of preparing a composite material, including mixing an isocyanate, a mixture of at least two polyols, coal ash (e.g., fly ash), and a catalyst.Type: GrantFiled: August 12, 2010Date of Patent: September 30, 2014Assignee: Boral IP Holdings LLCInventors: Ronald M. Herrington, Kengqing Jian
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Publication number: 20140242313Abstract: A cavity between inner and outer walls of an open-box-shaped mould is filled with a polyurethane reaction mixture, containing an isocyanate and an emulsion of an isocyanate-reactive composition with three polyols and a blowing agent, which is cured to a polyurethane containing polymer. The inner and outer wall are a fixed distance from one another and each wall comprises a bottom and sides. The mixture is fed through an inlet in the bottom of the outer wall. Before filling the cavity, the mould is turned downwards so that the mixture foams upwards, filling the cavity. The three polyols are polyether polyol obtained by adding an epoxy to carbohydrates or difunctional or higher-functional alcohols; polyether polyol obtained by adding an epoxy to an aromatic amine; and polyester polyether polyol obtained by adding an epoxy to the esterification product of an aromatic dicarboxylic acid derivative and a difunctional or higher-functional alcohol.Type: ApplicationFiled: February 20, 2014Publication date: August 28, 2014Applicant: BAYER MATERIALSCIENCE AGInventors: Stephanie VOGEL, Reinhard ALBERS, Michael LOOF, Frank OTTO
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Publication number: 20140213679Abstract: The invention relates to stable emulsions for the production of foams based on isocyanates, comprising at least three polyols A1a, A1b and A1c and at least one physical blowing agent T, wherein A1a is a polyether polyol, obtained by the addition of epoxies to starter compounds selected from carbohydrates and difunctional or higher-functional alcohols, A1b is a polyether polyol started on an aromatic amine and A1c is a polyester polyether polyol, obtained by the addition of epoxies to the esterification product of an aromatic dicarboxylic acid derivative and a difunctional or higher-functional alcohol. The invention further relates to a method for producing foams by reactions of such emulsions with isocyanates and to the foams obtainable in this way and their use for insulating purposes.Type: ApplicationFiled: August 22, 2012Publication date: July 31, 2014Applicant: Bayer Intellectual Property GmbHInventors: Reinhard Albers, Torsten Heinemann, Stephanie Vogel, Thomas Heidelmann, Frank Otto
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Patent number: 8791168Abstract: A viscoelastic polyurethane foam is the reaction product of at least one natural oil derived polyol and at least one aromatic compound having an average of more than one isocyanate group. A viscoelastic polyurethane foam has an air flow of at least about 0.5 l/s, wherein the foam is formed in the substantial absence of copolymer polyol and has not (yet) been mechanically reticulated and is preferably prepared using at least one natural oil derived polyol, more preferably in an amount of at least about 20 weight percent of the polyols used. A process of preparing a viscoelastic foam, comprises steps of (A) forming a reaction mixture including at least one polyol, at least one polyisocyanate, water, at least one catalyst wherein a the polyol comprises at least one natural oil derived polyol; and (B) subjecting the reaction mixture to conditions sufficient to result in the reaction mixture to expand and cure to form a viscoelastic polyurethane foam.Type: GrantFiled: September 7, 2007Date of Patent: July 29, 2014Assignees: Dow Global Technologies, Dow Brasil Sudeste Industrial LtdaInventors: David A. Babb, Bernard E. Obi, Robert E. O'Neill, Alvaro Pauperio-Neto
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Publication number: 20140206786Abstract: Described is a method for using a trialkyl phosphate as a smoke suppressant in a polyurethane foam. The trialkyl phosphate having at least one alkyl group with two carbon atoms is included in the polyurethane foam, which has an absence of halogenated flame retardants.Type: ApplicationFiled: September 29, 2011Publication date: July 24, 2014Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: JianPing Xu, Yudong Qi, Luca Lotti, Xiang Y. Tai
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Publication number: 20140179812Abstract: A rigid polyurethane foam includes the reaction product of an isocyanate and an isocyanate reactive component in the presence of a blowing agent. The isocyanate reactive component includes an aromatic polyester polyol, a rigid polyol, and an aliphatic polyester polyol. The rigid polyurethane foam has a tensile adhesion of greater than 35 kPa (5 psi) when disposed on a metal substrate or a polyester, polyurethane, or epoxy coated metal substrate, each having a substrate temperature of greater than 41° C. (105° F.), and tested in accordance with ASTM D1623-09. A method of forming a composite article comprising a substrate and the rigid polyurethane foam includes the steps of combining the isocyanate reactive component and the isocyanate in the presence of the blowing agent to form a reaction mixture and applying the reaction mixture to the substrate having a substrate temperature of greater than 41° C. (105° F.) to form the composite article.Type: ApplicationFiled: December 20, 2013Publication date: June 26, 2014Applicant: BASF SEInventor: Michael L. JACKSON
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Publication number: 20140162006Abstract: The invention relates to a method for producing a water-blown polyurethane/polyisocyanurate rigid foam material that can be sprayed, by reacting a mixture comprising an aromatic polyester polyol, a first, comparatively short-chain aliphatic polyether polyol, a second, comparatively long-chain aliphatic polyether polyol, an isocyanate component, a blowing agent having water at least as a main component, and a catalyst component. The invention further relates to a rigid foam produced according to the method according to the invention, a composite material composed of said rigid foam and a pipe, and to the use of such a composite material for transporting liquid or gaseous media.Type: ApplicationFiled: July 16, 2012Publication date: June 12, 2014Applicant: Bayer Intellectual Property GmbHInventors: Reinhard Albers, Patrick Klasen, Horst-Heinrich Schneider, Stephanie Vogel
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Patent number: 8735460Abstract: The invention relates to a foamed isocyanate-based polymer derived from a reaction mixture comprising an isocyanate, an active hydrogen-containing compound, a blowing agent and a highly branched polysaccharide which is derivatized with at least two esters of different length. Further the invention relates to a mix and a process for the production of isocyanate-based polymer. The mix for the production of a foamed isocyanate-based polymer comprises a mixture of the derivatized polysaccharide of the invention and an active hydrogen-containing compound. The process for producing a foamed isocyanate-based polymer comprises the steps of: contacting an isocyanate, an active hydrogen-containing compound, the derivatized highly branched polysaccharide of the invention and a blowing agent to form a reaction mixture and expanding the reaction mixture to produce the foamed isocyanate-based polymer.Type: GrantFiled: January 9, 2009Date of Patent: May 27, 2014Assignee: Dupont Nutrition Bioscience APSInventors: Kenneth Knoblock, Charles Nichols, James O'Connor
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Patent number: 8686058Abstract: Embodiments of the present invention disclose viscoelastic foams having a renewable natural resource contents of between about 1 and about 25 wt % of the foam. The foams may have a ratio of elastic modulus (E?) at 20° C. to 25% compression force deflection (CFD) of 25 to 125.Type: GrantFiled: July 15, 2009Date of Patent: April 1, 2014Assignee: Dow Global Technologies LLCInventors: Bernard E. Obi, Alan K. Schrock, Rogelio R. Gamboa, Asjad Shafi
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Patent number: 8686057Abstract: Polyurethane polymers are made from a reaction mixture that contains a polyisocyanate, a hydroxylmethyl-containing fatty acid or ester, and another polyol, polyamine or aminoalcohol. The carboxylic acid or ester group on the hydroxymethyl-containing fatty acid or ester are capable of engaging in a variety of reactions with the polyisocyanate and/or amine or hydroxyl groups present in the reaction mixture. This allows for good quality, high molecular weight polymers to be produced even though the hydroxymethyl-containing fatty acid or ester tends to be a low functionality material.Type: GrantFiled: October 24, 2005Date of Patent: April 1, 2014Assignee: Dow Global Technologies LLCInventors: Hanno R. Van der Wal, Camiel F. Bartelink
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Patent number: 8673991Abstract: The two-part curable polyurethane foam resin composition uses little or no petroleum-derived raw materials but a plant-derived raw material so that the biomass ratio can be improved, the load on the environment can be reduced, and excellent physical characteristics can be exhibited. The two-part curable polyurethane foam resin composition includes a main agent that contains an isocyanate-terminated urethane prepolymer (A) and a curing agent that contains an isocyanate-reactive compound (B), water (C), and a catalyst (D), in which a polyol component used in (A) and (B) uses a castor oil polyol (b1) having 1.5 to 2.3 functional groups on average and a polyol (b2) prepared by addition polymerization of lactone to polytetramethylene glycol and/or polytetramethylene glycol (b3), the ratio (b1)/(b2) and/or (b3)=15/85 to 60/40 on a mass basis, and a content of the castor oil polyol (b1) is 10 to 45% by mass.Type: GrantFiled: March 22, 2011Date of Patent: March 18, 2014Assignee: DIC CorporationInventors: Tomoaki Shinchi, Hiroshi Suzaki
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Patent number: 8642670Abstract: The present invention relates to an open-cell polyurethane foam comprising polyester and polyether structures and having a density of 70 to 300 g/L, 1 to 20 cells/cm, a rebound intensity greater than 30%, an elongation at break of greater than 200%, a tear propagation resistance of greater than 1.2 N/mm and a tensile strength of greater than 200 kPa. The present invention further relates to a process for producing inventive open-cell polyurethane sponges and to the use thereof as a pipe cleaning sponge.Type: GrantFiled: March 13, 2009Date of Patent: February 4, 2014Assignee: BASF SEInventors: Nils Mohmeyer, Ralf Fritz, Annika Habicht, Daniela Tepe, Frank Prissok, Michael Harms, Bernd Bruchmann, Daniel Schoenfelder, Daniel Freidank, Andreas Emge, Andrea Eisenhardt
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Patent number: 8637584Abstract: An isocyanate reactive composition for making a polyurethane foam includes a tertiary amine urethane catalyst comprising a di(C1-C4)alkyl fatty alkyl amine and a polyester polyol. The use of one or more of fatty alkyl tertiary amine serves to reduce hydrolysis of the polyester polyol in the isocyanate reactive composition.Type: GrantFiled: May 25, 2007Date of Patent: January 28, 2014Assignee: Air Products and Chemicals, Inc.Inventors: Gary Dale Andrew, Juan Jesus Burdeniuc, Goran Zarkov
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Patent number: 8604093Abstract: A fire-resistant polyurethane foam is provided. A hydroxyl-containing inorganic fire retardant is premixed with a polyisocyanate and a polyol, respectively, to form two premixtures. Then, the two premixtures are mixed for reaction to form a fire-resistant polyurethane foam. Preferably, a combination of different particle sizes of the fire retardant is employed to maximize the amount of the fire retardant and increase the fire resistance of the foam.Type: GrantFiled: October 8, 2010Date of Patent: December 10, 2013Assignee: Industrial Technology Research InstituteInventors: Po-Ju Chen, Sung-Jeng Jong, Ren-Kuen Chang, Chin-Shang Hsu, Jer-Young Chen, Yih-Her Chang, Chei Kao
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Patent number: 8598297Abstract: Prepolymers are prepared by a reaction of a polyisocyanate and a hydroxylmethyl containing polyester polyol derived from a fatty acid. The prepolymers can be prepared having isocyanate, hydroxyl, or a variety of other reactive functional groups. The prepolymers are useful in making polyurethanes and other polymers, or a crosslinking agents.Type: GrantFiled: October 24, 2005Date of Patent: December 3, 2013Assignee: Dow Global Technologies LLCInventors: Erdem Bedri, Debkumar Bhattacharjee, John N. Argyropoulos
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Publication number: 20130310477Abstract: The present invention is a polyol composition (A) for the production of polyurethane resins which comprises a compound (a1) having a vinyl-polymerizable functional group represented by general formula (I) and a strength improver (a2) represented by general formula (II). In general formula (I), R is hydrogen, C1-15 alkyl, or C6-21 aryl. In general formula (II), R1 is a residue derived from an active-hydrogen-containing compound by removing one active hydrogen atom; Y is a residue derived from an at least divalent aromatic polycarboxylic acid (f) by removing the carboxyl groups; a is an integer satisfying the relationship: 1?a?(the number of substituents on the aromatic ring?1); Z is a residue derived from an at least m-valent active-hydrogen-containing compound by removing the m active hydrogen atoms; and m is an integer of 1 to 10.Type: ApplicationFiled: August 22, 2011Publication date: November 21, 2013Applicant: SANYO CHEMICAL INDUSTRIES, LTD.Inventors: Katsuya Uchida, Koji Kabu, Kei Sasaki, Tomohisa Hirano
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Patent number: 8575226Abstract: A building material composite that includes a building substrate at least partially lined with a urethane material. The urethane material of the present invention is typically the reaction product of an A-side that includes an isocyanate and a B-side that typically includes: a blown vegetable oil, a cross-linking agent, and a catalyst; a blown vegetable oil and a multifunctional alcohol; or an esterified polyol and a catalyst where the esterified polyol is typically the reaction product of a first polyol and a blown vegetable oil.Type: GrantFiled: January 25, 2005Date of Patent: November 5, 2013Assignee: Rhino Linings CorporationInventors: Thomas M. Kurth, Richard A. Kurth, Robert B. Turner, Les P. Kreifels
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Publication number: 20130261204Abstract: A premix composition includes polyether polyol and a blowing agent, wherein the polyether polyol is a copolymer of propylene oxide and trimethylolpropane, a copolymer of propylene oxide, ethylene oxide and trimethylolpropane, a copolymer of propylene oxide, ethylene oxide and glycerol, or combinations thereof. A foaming composition which is obtained by mixing the premix composition with diisocyanate.Type: ApplicationFiled: March 29, 2012Publication date: October 3, 2013Inventor: Chien-Chang CHEN
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Publication number: 20130261205Abstract: The present invention relates to a process for the preparation of polyricinoleic acid ester polyols having primary hydroxyl end groups. It furthermore relates to polyricinoleic acid ester polyols obtainable according to the invention and polyurethane polymers prepared using these polyols. The process comprises the steps: a) polycondensation of ricinoleic acid until a hydroxyl number of >0 mg of KOH/g to <60 mg of KOH/g is reached; and b) reaction of the product obtained in step a) or of a secondary product of the product obtained in step a) comprising carboxyl groups with an epoxide of the general formula (I), wherein R1 represents hydrogen, an alkyl radical or an aryl radical, with the proviso that >80% by weight to <100% by weight, based on the total amount of the epoxide (I) employed, is ethylene oxide and the reaction is carried out in the presence of an amine as the catalyst.Type: ApplicationFiled: November 18, 2011Publication date: October 3, 2013Applicant: Bater Intellectual Property GmbHInventors: Hartmut Nefzger, Jörg Hofmann, Erika Bauer, Bert Klesczewski, Klaus Lorenz
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Publication number: 20130251980Abstract: Embodiments of the invention provide for polyurethane or polyisocyanurate foam formulations. The formulations include a formulated polyol, a polyisocyanate, and a blowing agent such that the stoichiometric index of the polyisocyanate to the formulated polyol is above 250. The formulated polyol includes (i) from about 20 to about 60 percent by weight of an aromatic polyester polyol, (ii) from about 10 to about 30 percent by weight of a Novolac-type polyether polyol, and (iii) from about 5 to about 40 percent by weight of a polyether polyol including a sucrose- or sorbitol-initiated polyol. Components (i), (ii), and (iii) are selected so that the formulated polyol as a whole has an average functionality of at least about 2.4.Type: ApplicationFiled: December 15, 2011Publication date: September 26, 2013Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Luigi Pellacani, Paolo Golini, Peter Keller
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Publication number: 20130237624Abstract: The present invention relates to a method for producing flexible polyurethane foams, wherein a polyol component which comprises polyricinoleic acid esters is used as starting substance. The flexible polyurethane foams according to the invention have a bulk density according to DIN EN ISO 3386-1-98 in the range of ?10 kg/m3 to ?150 kg/m3, preferably ?20 kg/m3 to ?70 kg/m3, and in general their compressive strength according to DIN EN ISO 3386-1-98 is in the range of ?0.5 kPa to ?20 kPa (at 40% deformation and 4th cycle). The polyricinoleic acid esters are obtainable by the reaction of ricinoleic acid with an alcohol component which comprises mono- and/or polyhydric alcohols with a molecular mass of ?32 g/mol to ?400 g/mol, the reaction being carried out at least in part in the presence of a catalyst.Type: ApplicationFiled: November 18, 2011Publication date: September 12, 2013Applicant: BAYER INTELLECTUAL PROPERTY GMBHInventors: Bert Klesczewski, Gundolf Jacobs, Sven Meyer-Ahrens, Hartmut Nefzger
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Patent number: 8530533Abstract: The present invention relates to a rigid polyurethane foam comprising reinforcing materials which can be obtained by mixing (a) isocyanates which have a viscosity at 25° C. of less than 500 mPas with (b) compounds having groups which are reactive toward isocyanates, (c) blowing agents comprising water, (d) catalysts and, if appropriate, (e) further additives to form a reaction mixture and applying the reaction mixture to a reinforcing material, wherein the compounds (b) having groups which are reactive toward isocyanates comprise a polyetherol (b1) having a functionality of 4 or more and a viscosity at 25° C. of 10 000 mPas or less and a polyetherol (b2) having a functionality of 3 or less and a viscosity at 25° C. of 500 mPas or less. The present invention further relates to a process for producing such rigid polyurethane foams and the use of the rigid polyurethane foams for the insulation of liquefied natural gas tanks.Type: GrantFiled: January 2, 2008Date of Patent: September 10, 2013Assignee: BASF SEInventors: Pit Lehmann, Katrin Thane, Cheul Hyeon Hwang
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Publication number: 20130197115Abstract: The present invention relates to a process for producing rigid polyurethane foams by reaction of a) at least one organic polyisocyanate with b) at least one polyol component in the presence of a blowing agent mixture comprising water and halogenated alkenes, wherein the amount of water is at least 1.40 mol/kg of polyol component b) and the amount of halogenated alkene is at most 2.00 mol/kg of polyol component b), and also to the use of such a blowing agent mixture for producing corresponding rigid polyurethane foams and for increasing the adherence and reducing the thermal conductivity of corresponding rigid polyurethane foams. The present invention further relates to a rigid polyurethane foam obtainable by the process of the present invention.Type: ApplicationFiled: July 30, 2012Publication date: August 1, 2013Applicant: BASF SEInventors: Christiane GIESKER, Markus Schuette, Patrick Lax, Jörg Krogmann
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Publication number: 20130190419Abstract: Rigid polyurethane foams or rigid polyisocyanurate foams with low brittleness are produced by the reaction of polyisocyanate polyetherester polyols based on aromatic dicarboxylic acids obtained by esterification of a dicarboxylic acid composition containing aromatic dicarboxylic acids and aliphatic dicarboxylic acids, fatty acids, aliphatic or cycloaliphatic diols having 2 to 18 carbon atoms or alkoxylates thereof, and a polyether polyol having a functionality of not less than 2.Type: ApplicationFiled: December 31, 2012Publication date: July 25, 2013Inventor: Gunnar KAMPF
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Publication number: 20130184369Abstract: The present invention relates to a process for preparing rigid polyurethane foams or rigid polyisocyanurate foams by using certain polyetherester polyols B) based on aromatic dicarboxylic acids, optionally further polyester polyols C), which differ from those of component B), and polyether polyols D), wherein the mass ratio of total components B) and optionally C) to component D) is less than 1.6. The present invention also relates to the rigid foams thus obtainable and to their use for producing sandwich elements having rigid or flexible outer layers. The present invention further relates to the underlying polyol components.Type: ApplicationFiled: January 14, 2013Publication date: July 18, 2013Inventor: Gunnar KAMPF
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Patent number: 8476329Abstract: A bioresin composition is used to form a rigid polyurethane article that includes a first and a second biopolyol and is substantially free of aprotic solvents that chemically decompose in the presence of water. The first biopolyol includes a natural oil component. The second biopolyol includes the reaction product of a natural carbohydrate and an alkylene oxide. The rigid polyurethane foam article includes the reaction product of the bioresin composition and an isocyanate which are reacted in the presence of a chemical blowing agent.Type: GrantFiled: June 9, 2010Date of Patent: July 2, 2013Assignee: BASF SEInventors: Christopher M. Tanguay, Patrick J. Watters, John P. Erickson, Eric W. Banks
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Patent number: 8476328Abstract: A method for manufacturing a polishing pad that has high level of optical detection accuracy and is prevented from causing slurry leak from between the polishing region and the light-transmitting region includes preparing a cell-dispersed urethane composition by a mechanical foaming method; placing a light-transmitting region at a predetermined position on a face material or a belt conveyor, continuously discharging the cell-dispersed urethane composition onto part of the face material or the belt conveyor where the light-transmitting region is not placed; placing another face material or belt conveyor on the discharged cell-dispersed urethane composition; curing the cell-dispersed urethane composition to form a polishing region including a polyurethane foam, so that a polishing sheet is prepared; applying a coating composition containing an aliphatic and/or alicyclic polyisocyanate to one side of the polishing sheet and curing the coating composition to form water-impermeable film; and cutting the polishingType: GrantFiled: February 26, 2009Date of Patent: July 2, 2013Assignee: Toyo Tire & Rubber Co., LtdInventors: Junji Hirose, Takeshi Fukuda
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Publication number: 20130102697Abstract: The two-part curable polyurethane foam resin composition uses little or no petroleum-derived raw materials but a plant-derived raw material so that the biomass ratio can be improved, the load on the environment can be reduced, and excellent physical characteristics can be exhibited. The two-part curable polyurethane foam resin composition includes a main agent that contains an isocyanate-terminated urethane prepolymer (A) and a curing agent that contains an isocyanate-reactive compound (B), water (C), and a catalyst (D), in which a polyol component used in (A) and (B) uses a castor oil polyol (b1) having 1.5 to 2.3 functional groups on average and a polyol (b2) prepared by addition polymerization of lactone to polytetramethylene glycol and/or polytetramethylene glycol (b3), the ratio (b1)/(b2) and/or (b3)=15/85 to 60/40 on a mass basis, and a content of the castor oil polyol (b1) is 10 to 45% by mass.Type: ApplicationFiled: March 22, 2011Publication date: April 25, 2013Applicant: DIC CORPORATIONInventors: Tomoaki Shinchi, Hiroshi Suzaki
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Patent number: 8426482Abstract: Invention relates to a process for producing viscoelastic flexible polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups, wherein as b) a mixture of bi) from 25 to 70% by weight of a hydroxyl-comprising natural oil or fat or a reaction product of a hydroxyl-comprising natural oil or fat with alkylene oxides, bii) from 3 to 30% by weight of at least one polyether having a hydroxyl number of from 100 to 800 mg KOH/g and a functionality of 3-5 selected from the group consisting of polyether prepared by addition of alkylene oxides onto an amine, biii) 20-50% by weight of at least one polyether alcohol having a hydroxyl number of from 10 to 80 mg KOH/g and a functionality of 2-5, where the proportion of ethylene oxide is 5-25% by weight, based on the weight of the polyether alcohol, and at least part of the ethylene oxide is added on at the end of the polyether chain, biv) >0-8% by weight of at least one polyether alcohType: GrantFiled: October 19, 2009Date of Patent: April 23, 2013Assignee: BASF SEInventors: Ansgar Frericks, Heinz-Dieter Lutter, Edmund Stadler, Heinz-Juergen Schroeder, Kirsten Simon, Andre Meyer, Franck Pomeris
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Patent number: 8399532Abstract: Embodiments of the disclosure include aromatic polyol compositions, resin blend compositions, and spray foam compositions.Type: GrantFiled: May 18, 2010Date of Patent: March 19, 2013Assignee: Invista North America S.A R.L.Inventor: David K. Mulkey
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Patent number: 8318827Abstract: The invention described herein relates to an essentially closed-cell two-component polyurethane foam containing an pesticide, which upon curing provides a barrier to insect infestation.Type: GrantFiled: March 27, 2009Date of Patent: November 27, 2012Assignee: Fomo Products, Inc.Inventor: Anthony J. Taylor
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Patent number: 8318821Abstract: Provided is a process for producing a rigid foamed synthetic resin, wherein, as a blowing agent, a hydrocarbon compound and water are used, and a rigid foamed synthetic resin provided with dimensional stability, heat insulating properties, and possibly reduced weight can be obtained. The process involves reacting a polyol (P) with a polyisocyanate (I) in the presence of a blowing agent, a foam stabilizer and a catalyst, wherein the blowing agent has at least a C2-8 hydrocarbon compound and water; the polyol (P) has a specific polyesterpolyol (A), a specific polyetherpolyol (B), and a polymer-dispersed polyol (Z) having fine polymer particles (M) dispersed; and the isocyanate index of the polyol (P) and the polyisocyanate (I) is over 200 and at most 400.Type: GrantFiled: October 29, 2010Date of Patent: November 27, 2012Assignee: Asahi Glass Company, LimitedInventors: Yuko Hayashi, Hiroshi Wada
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Patent number: 8318822Abstract: It is an object of the invention to provide a vibration damping and sound absorbing material containing a plant-derived polyol which material largely contributes a decrease of environmental load and has excellent vibration damping and sound absorbing properties, and it is another object of the invention to provide a production process of the material. Specifically, disclosed is a vibration damping and sound absorbing material which is suitably used for cars. A vibration damping and sound absorbing material comprises a polyurethane foam which comprises, as raw materials, a polyol and/or a polymer-dispersed polyol in which polymer fine particles obtainable by polymerizing an unsaturated bond-containing compound are dispersed in a polyol, and water, a catalyst and a polyisocyanate, wherein the polyol comprises (A) a plant-derived polyol produced using a raw material obtainable by a plant.Type: GrantFiled: April 21, 2008Date of Patent: November 27, 2012Assignee: Mitsui Chemicals, Inc.Inventors: Kazuto Usaka, Kouichi Sano, Hiroyuki Utsumi