-xh Reactant Contains A C=x Group, E.g., Carboxylic Acid Ester, Etc. Patents (Class 521/172)
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Patent number: 12258459Abstract: A process and composition is described for the inclusion of polyether polyols in concentrations greater than 10% loading on the B-side formulation with a catalyst package less than 1% loading on the B-side formulation. In one specific example, the use of glycerin as a fluorine ion scavenger is utilized to improve performance of the polyurethane systems through a twelve-month shelf life.Type: GrantFiled: September 10, 2021Date of Patent: March 25, 2025Assignee: ICP CONSTRUCTION, INC.Inventors: Andrew P. Shinko, Anthony J. Taylor
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Patent number: 12024607Abstract: A battery module comprising an electric cell and a potting compound associated with the electric cell. The potting compound is formed of a flame retardant component; a first component having an isocyanate reactive compound and water; and a second component having an isocyanate compound. The potting compound is a foam.Type: GrantFiled: January 20, 2023Date of Patent: July 2, 2024Assignee: H.B. Fuller CompanyInventor: Albert M. Giorgini
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Patent number: 11920017Abstract: A method of a polyurethane foam includes the following steps of: (1) simultaneously pumping a mixed solution prepared from hydrogen peroxide, an organic acid, a catalyst and a stabilizer and a vegetable oil into a first microstructured reactor of a micro-channel modular reaction device for reacting to obtain a reaction solution containing epoxidized vegetable oil; (2) simultaneously pumping the reaction solution containing the epoxidized vegetable oil obtained from the step (1) and a compound of formula III into a second microstructured reactor of the micro-channel modular reaction device for reaction to obtain a vegetable oil polyol; and (3) reacting the vegetable oil polyol prepared from the step (2) with a foam stabilizer, a cyclohexylamine, an isocyanate and a foaming agent cyclopentane for foaming so as to prepare a rigid polyurethane foam.Type: GrantFiled: April 12, 2021Date of Patent: March 5, 2024Assignee: NANJING TECH UNIVERSITYInventors: Kai Guo, Zheng Fang, Chengkou Liu, Ning Zhu, Jingjing Meng, Junjie Tao, Xin Hu, Xin Li, Chuanhong Qiu, Pingkai Ouyang
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Patent number: 11905358Abstract: The invention relates to highly filled urethane systems, methods of making the urethane systems, and their use in commercial applications. More particularly, the invention includes urethane systems with a substantial amount of mineral filler that have acceptable cure kinetics and mechanical properties. The urethane systems include an isocyanate component, a polyol component, and a mineral filler that, in certain embodiments, is selected from talc, mica, calcium carbonate and mixtures or blends thereof.Type: GrantFiled: November 13, 2020Date of Patent: February 20, 2024Assignee: STOCKMEIER URETHANES USA, INC.Inventors: Michael Hugh Quinn, Gabrielle Lynn Hamner
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Patent number: 11655328Abstract: A method of producing a closed-cell and rigid foam. The method comprises reacting an isocyanate composition including one or more polyisocyanates and a polyol composition including one or more polyols including one or more aromatic polyester polyols having a hydroxyl functionality of greater than 2 and one or more physical and/or chemical blowing agents including methylal to form a closed-cell and rigid foam configured to retain at least 85% of an initial volume of the closed-cell and rigid foam when exposed to about 97% relative humidity at about 70° C. for at least seven or more days.Type: GrantFiled: September 2, 2020Date of Patent: May 23, 2023Assignee: Ventrex Systems, LLCInventor: Ibrahim Sendijarevic
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Patent number: 11634532Abstract: Provided is a material having an excellent sound-absorbing performance which can be easily applied to the desired area at the operation site and which can effectively prevent sound leakage. The material includes an open-cell soft polyurethane foam prepared from a 2-part reactive urethane resin composition prepared from a polyisocyanate component and a polyol-containing component, wherein the polyol-containing component comprises a polyol component, catalysts, a foam stabilizer, an amine compound having primary or secondary amino groups, and carbon dioxide; wherein an average sound absorption coefficient of said polyurethane foam is 30% or more, measured in accordance with JIS A 1405-2:2007 for 63 hertz to 5000 hertz; and the length of liquid-dripping is within 300 mm.Type: GrantFiled: April 29, 2022Date of Patent: April 25, 2023Assignees: Mazda Motor Corporation, Nihon Tokushu Toryo Co., Ltd., Covestro Deutschland AGInventors: Shinsuke Kataoka, Eiichi Kawase, Masanori Takasaki, Yuji Watanabe, Hirofumi Takeuchi, Shinichiro Sado, Hiroaki Ido, Shinji Nishikawa, Saeko Kinami, Kazuki Murata
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Patent number: 11594773Abstract: A battery module comprising an electric cell and a potting compound associated with the electric cell. The potting compound is formed of a flame retardant component; a first component having an isocyanate reactive compound and water; and a second component having an isocyanate compound. The potting compound is a foam.Type: GrantFiled: May 21, 2021Date of Patent: February 28, 2023Assignee: H.B. Fuller CompanyInventor: Albert M. Giorgini
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Patent number: 11566145Abstract: Polyurethane coating compositions are disclosed that include an isocyanate-reactive component that includes a polycyclic polyether polyol that is the reaction product of a reaction mixture that includes a polycyclic polyol starter, and an alkylene oxide, as well as an isocyanate-functional component that includes a non-aromatic polyisocyanate. The polyurethane coating compositions may be particularly useful as a gel coat in the manufacture of glass fiber reinforced plastics.Type: GrantFiled: April 3, 2019Date of Patent: January 31, 2023Assignee: COVESTRO LLCInventors: Anthony R. Loveday, Jack R. Reese, Rick L. Adkins, David P. Zielinski, James A. Thompson-Colón, Alan D. Bushmire, Liang Chen, Chen Xu
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Patent number: 11229719Abstract: A wound dressing layer may include an open-cell foam. The foam may have a 50% compression force deflection of not more than about 4.8 kPa. The foam may also have a density of at least 24 kg/m3. The foam may exhibit a density increase of a factor of at least 12 at about ?75 mmHg.Type: GrantFiled: January 3, 2018Date of Patent: January 25, 2022Assignee: KCI Licensing, Inc.Inventors: Christopher Brian Locke, Timothy Mark Robinson
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Patent number: 11180605Abstract: A rigid foam or a composition allowing a rigid foam to be obtained, including a polyester polyol or a polymer including a polyester polyol, the polyester polyol being obtained by a first polycondensation (a) of a C3 to C8 sugar alcohol Z and two identical or different C4 to C36 diacids Y and Y? and a second polycondensation (b) of the product obtained in (a) with two identical or different C2 to C12 diols X and X?.Type: GrantFiled: August 24, 2017Date of Patent: November 23, 2021Assignees: TEREOS STARCH & SWEETENERS BELGIUM, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, SOCIÉTÉSOPREMA SAS, UNIVERSITÉDE STRASBOURGInventors: Pierre Etienne Bindschedler, Alexandru Sarbu, Stephanie Laurichesse, Remi Perrin, Pierre Furtwengler, Luc Avérous, Andreas Redl
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Patent number: 10968327Abstract: Disclosed are methods for formulating a polyisocyanurate foam-forming composition with good low temperature insulation performance. The polyisocyanurate foam-forming composition includes: a) an organic polyisocyanate, b) a polyol composition comprising at least one polyester polyol with a nominal hydroxyl functionality of at least 2.0, c) a blowing agent composition present in an amount sufficient to produce foam having a density of less than 1.85 lb/ft3 and comprising: (1) a hydrocarbon having an atmospheric pressure boiling point of at least 68° F. (20° C.), and (2) water, d) a trimerization catalyst, e) a flame retardant, and f) a silicone surface-active agent.Type: GrantFiled: August 27, 2018Date of Patent: April 6, 2021Assignee: Covestro LLCInventor: George Combs
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Patent number: 10907007Abstract: The invention relates to a method for producing polyurethane foams by reacting the following components A a polyol component containing A1 40 to 100 parts by weight of polyether carbonate polyol with a hydroxyl number according to DIN 53240-1 June 2013 of 20 mg KOH/g to 120 mg KOH/g, A2 0 to 60 parts by weight of polyether polyol with a hydroxyl number according to DIN 53240-1 June 2013 of 20 mg KOH/g to 250 mg KOH/g and an ethylene oxide content of 0 to 60 wt. %, wherein polyether polyol A2 is free from carbonate units, B B1 a catalyst and B2 optionally auxiliary and additional materials, C water and/or physical blowing agents with D di- and/or polyisocyanates, wherein the production occurs at a characteristic value of 90 to 120, characterised in that the component A contains a component A5 of 0.05 to 10.00 parts by weight of polyester polyol, in relation to the sum of the parts by weight of the components A1+A2=100 parts by weight, said polyester polyol containing units derived from malonic acid.Type: GrantFiled: March 4, 2019Date of Patent: February 2, 2021Assignee: Covestro Intellectual Property GMBH & Co. KGInventors: Persefoni Hilken, Stefan Lindner, Michael Schedler, Hartmut Nefzger, Michael Baecker
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Patent number: 10906220Abstract: A method and a system for producing a luminescent 3D radar-module cover for a radiator grille of a motor vehicle. A three-dimensional structure including an optical conductor is produced from a light-dispersing first plastic material in separate method steps using a first injection mold. The three-dimensional structure is metallized and metal-coated. A subsequent separation of the gating takes place. A cover element is produced from a second plastic material using a second injection mold, which at least partially covers the metallized three-dimensional structure in a planar manner in a position of use. A contour of the three-dimensional structure is left free. The gating is subsequently severed. The three-dimensional structure is metallized together with the cover element disposed thereon and is embedded in a third plastic material with the aid of a third injection mold while molding a mount for a radar module and fastening points on the molded component.Type: GrantFiled: January 25, 2018Date of Patent: February 2, 2021Assignee: Robert Bosch GmbHInventor: Stephan Geise
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Patent number: 10793666Abstract: A polyisocyanate composition includes an isocyanurate derivative of xylylene diisocyanate, and a biuret derivative of aliphatic polyisocyanate.Type: GrantFiled: June 8, 2016Date of Patent: October 6, 2020Assignee: MITSUI CHEMICALS, INC.Inventors: Shirou Honma, Kazuyuki Fukuda, Hideaki Otsuka, Tsutomu Yoshida, Toshiaki Moriya, Tatsuya Nakashima
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Patent number: 10723831Abstract: A polyol component b) comprising: 20 to 40 wt % of polyetherester polyols B) having a functionality of 3.8 to 4.8, an OH number of 380 to 440 mg KOH/g and a fatty acid and/or fatty acid ester content of 8 to 17 wt %, based on the weight of polyetherester polyols B); 20 to 40 wt % of polyether polyols C) having a functionality of 3.7 to 4 and an OH number of 300 to 420 mg KOH/g; 20 to 40 wt % of one or more polyether polyols D) having a functionality of 4.5 to 6.5 and an OH number of 400 to 520 mg KOH/g; 0.5 to 5.5 wt % of catalysts E), 0.1 to 5 wt % of further auxiliaries and/or added-substance materials F), 0.5 to 5 wt % of water G); and also rigid polyurethane foams obtained therewith and use thereof for insulation and refrigeration applications.Type: GrantFiled: October 26, 2016Date of Patent: July 28, 2020Assignee: BASF SEInventors: Sebastian Koch, Michele Gatti, Mark Elbing, Christian Koenig, Johann Klassen
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Patent number: 10662287Abstract: The present invention refers to a formulation suitable for the manufacture of a pressure sensitive adhesive, said formulation comprising: a) 40-95 wt % of polyalkylene carbonate having a number average molecular weight higher than 17.000 Da; b) 5-60 wt % of a polyether carbonate polyol having CO2 groups randomly incorporated in the chemical structure thereof, wherein the content of CO2 ranges from 0.5 to 40 wt %, based on the total weight of the polyether carbonate polyol; and c) optionally, less than 30 wt % of a tackifying resin, provided that said formulation does not contain any reticulating agent.Type: GrantFiled: August 3, 2016Date of Patent: May 26, 2020Assignee: REPSOL, S.A.Inventors: Carolina Ruiz Orta, Laura Marín Perales, Sonia Segura Fernández, Rafael Polo Abad, María Dolores Blanco González, Román Galdámez Peña, Mónica García Ruiz, José Miguel Martín Martínez, Andrés Jesús Yáñez Pacios
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Patent number: 10604624Abstract: Provided is a method for producing poly(alkylene carbonate)polyol, and specifically, a method for producing poly(alkylene carbonate)polyol having carbonate, ester, and ether bonds by mixing a Salen-based catalyst and a double metal cyanide catalyst.Type: GrantFiled: February 21, 2017Date of Patent: March 31, 2020Assignee: SK Innovation Co., Ltd.Inventors: Sudevan Sujith, Je Ho Lee
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Patent number: 10577454Abstract: A formulation system contains: (a) a pre-polymer reaction product of a polymeric isocyanate and a polyether polyol, where: (i) the polymeric isocyanate contains five weight-percent or more methylene diphenyl diisocyanate; (ii) the polymeric isocyanate has a functionality of 3.0 or less; (iii) the polyether polyol is present in the pre-polymer at a concentration of one to 25 weight-percent; (iv) the polyol has an equivalent weight of 50 to 500 grams per equivalent; (v) the —NCO concentration of the pre-polymer is 15 to 31 weight-percent; (vi) the pre-polymer is free of isocyanate trimers; (b) a polyester polyol component containing 10 to 25 weight-percent of free glycol; and (c) a blowing agent that contains less than five weight-percent water; where the ratio of pre-polymer and polyester result in foam having a trimer content of 12 to 22 weight-percent, and an —NCO index of more than 300 and less than 700.Type: GrantFiled: October 19, 2016Date of Patent: March 3, 2020Inventors: Kshitish A. Patankar, Mark F. Sonnenschein, Steven P. Crain, Christina A. Rhoton
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Patent number: 10538615Abstract: A fiber-reinforced rigid polyurethane foam composite railway sleeper with high fiber content and a manufacturing method thereof. The railway sleeper is formed by bonding a plurality of fiber-reinforced rigid polyurethane foam composite boards with high fiber content by a binder, and the outer surface of the railway sleeper is provided with an anticorrosive paint film. The fiber-reinforced rigid polyurethane foam composite boards with high fiber content include a polyurethane resin as a matrix material and a fiber as a reinforcing material. The problem of insufficient impregnation of the polyurethane and the fiber is solved by using a plurality of technical means such as using a mixed polyether polyol having a low hydroxyl value and a low functionality, using a coupling agent, etc., thus a fiber-reinforced rigid polyurethane foam composite product having a density higher than 840 kg/m3 and a fiber content greater than 60% is manufactured.Type: GrantFiled: August 14, 2017Date of Patent: January 21, 2020Assignees: RAILWAY ENGINEERING RESEARCH INSTITUTE OF CHINA ACADEMY OF RAILWAY SCIENCES CORPORATION LIMITED, CHINA ACADEMY OF RAILWAY SCIENCES CORPORATION LIMITEDInventors: Bin Niu, Zhibin Zeng, Yonghua Su, Tibo Zhao
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Patent number: 10323115Abstract: A bio-polyol composition and a bio-polyurethane foam are provided. The bio-polyol composition includes polyol, a surface-modified lignin, and a surfactant represented by formula 1. wherein R is represented by CnH2n+1, n is an integer of 0 to 3; x/y is between 5 and 13; a is an integer of 1 to 100; b is an integer of 1 to 100.Type: GrantFiled: September 23, 2016Date of Patent: June 18, 2019Assignee: Industrial Technology Research InstituteInventors: Wen-Pin Chuang, Yi-Che Su, Yun-Ya Huang, Yuung-Ching Sheen, Chao-Chieh Chiang
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Patent number: 10239985Abstract: This invention relates to polymer polyols comprising the free-radical polymerization product of a base polyol, at least one ethylenically unsaturated monomer, and, optionally, a preformed stabilizer, in the presence of at least one free-radical polymerization initiator and at least one chain transfer agent, in which the base polyol is a natural oil. A process for preparing these polymer polyols is also described. The present invention also relates to a polyurethane foam prepared from these polymer polyols and to a process for the preparation of these polyurethane foams.Type: GrantFiled: December 23, 2008Date of Patent: March 26, 2019Assignee: COVESTRO LLCInventors: Rick L. Adkins, Stanley L. Hager, Brian L. Neal, Jack R. Reese, Jiong England, Micah N. Moore
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Patent number: 10202482Abstract: A viscoelastic polyurethane foam formed from a polyisocyanate and a polyol composition comprising palm olein-based polyol in an amount of 10% to 35% by weight of the total polyol composition and petroleum-based polyol in an amount of 65% to 90% by weight of the total polyol composition. The dissipation energy of the viscoelastic polyurethane foam is between 0.01 J to 0.30 J as calculated based on a hysteresis loop normalized a density of 40.80 kg/m3. This shows that the viscoelastic foam produced has an improved dampening property. The introduction of palm olein-based polyol into the production of viscoelastic foam does not affect the support factors and mechanical properties of the foam produced. The viscoelastic foams can be produced using an amount of up to 35% of palm olein-based polyol derived from palm olein or up to 25% of palm olein-based polyol derived from a mixture of palm olein and soybean oil by weight of total composition without any adjustment in the catalyst package.Type: GrantFiled: June 10, 2015Date of Patent: February 12, 2019Assignee: MALAYSIAN PALM OIL BOARDInventors: Nurul 'ain Binti Hanzah, Tuan Noor Maznee Binti Tuan Ismail, Mohd. Norhisham Bin Sattar, Kosheela Devi A/P Poo Palam, Norhayati Binti Mohd. Noor, Srihanum Binti Adnan, Zailan Bin Abu Bakar, Mohd. Azmil Bin Mohd. Noor, Yeong Shoot Kian, Hazimah Binti Abu Hassan
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Patent number: 10174151Abstract: The present invention relates to a method for producing polyether carbonate polyols, wherein: (i) in a first step, (a) carbon dioxide and propylene oxide or (b) carbon dioxide and a mixture of propylene oxide and at least one further alkylene oxide in a ratio by weight of >90:10 are attached to one or more H-functional starting substances in the presence of at least one DMC catalyst; (ii) in a second step, the reaction mixture obtained from step (i) is (ii-1) first chain-lengthened with a mixture containing propylene oxide (PO) and ethylene oxide (EO) in a PO/EO ratio by weight of 90/10 to 20/80 in the presence of at least one DMC catalyst.Type: GrantFiled: February 17, 2017Date of Patent: January 8, 2019Assignee: COVESTRO DEUTSCHLAND AGInventors: Joerg Hofmann, Norbert Hahn
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Patent number: 10087277Abstract: Polyurethane foam is formed by foaming raw materials that includes either an aliphatic isocyanate or a melamine derivative, a urethane emulsion, and an anionic foam stabilizer. The compression set (JIS K6401) of the polyurethane foam, specifically, the compression set (JIS K6401) after the polyurethane foam being allowed to stand for 22 hours in a state of 50% compression under condition of 70° C., is 40% or less. By this, it is possible to obtain polyurethane foam that is low density, pliable and resistant to collapse, i.e., polyurethane foam having high recovery properties.Type: GrantFiled: September 11, 2015Date of Patent: October 2, 2018Assignee: INOAC CORPORATIONInventors: Sora Bang, Natsuki Ayukyo, Joann Mokyinteng
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Patent number: 10047188Abstract: Disclosed are high strength polyurethane foam compositions and methods of making them. In one aspect, the inventive polyurethane foams include strength enhancing additives comprising one or more polycarbonate polyols derived from the copolymerization of CO2 and one or more epoxides. In one aspect, the inventive methods include the step of substituting a portion of the polyether polyol in the B-side of a foam formulation with one or more polycarbonate polyols derived from the copolymerization of CO2 and one or more epoxides.Type: GrantFiled: December 2, 2016Date of Patent: August 14, 2018Assignee: Saudi Aramco Technologies CompanyInventors: Scott D. Allen, Vahid Sendijarevic, Aisa Sendijarevic
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Patent number: 9840602Abstract: A process for forming a conventional flexible polyurethane foam includes providing a polyol component including a PIPA polyol that is a dispersion having a solids content from 10% to 75 wt %, based on a total weight of the PIPA polyol, providing an isocyanate component that includes at least one polyisocyanate, providing an additive component that includes a catalyst, and forming a reaction mixture including the polyol component, the isocyanate component, and the additive component to form a flexible polyurethane foam with a resiliency value below 45%. The reaction mixture has an isocyanate index from 90 to 150.Type: GrantFiled: September 11, 2014Date of Patent: December 12, 2017Assignee: Dow Global Technologies LLCInventors: Paul A. Cookson, Irena Amici-Kroutilova, Alberto Lora Lamia, Francois Casati
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Patent number: 9765477Abstract: Textiles backed with a polyurethane cushion are produced by applying a layer of frothed polyurethane-forming mixture to a surface of the textile. The mixture contains both water and a physical blowing agent. The layer expands due to the action of the water and the physical blowing agent and cures to form an attached cushion having a density of 176 g/L or less.Type: GrantFiled: August 12, 2014Date of Patent: September 19, 2017Assignee: Dow Global Technologies LLCInventor: David J. Honkomp
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Patent number: 9701836Abstract: An aqueous emulsion resin for producing memory foam and a method for manufacturing memory foam products are revealed. The emulsion resin mainly includes 38˜58% hydrophilic polyurethane(PU) prepolymer, 8˜22% aqueous emulsion polymer and 8˜20% polyether polyol. The PU prepolymer includes 40˜70% polyether polyol and 30˜60% isocyanate while the molecular weight of polyether polyol is ranging from 60 to 1800. The polyether polyol contains at least 40 mol % amount of ether group and the amount of ether group is 18˜99.9%. The hydrophilic emulsion resin features on good vibration absorption, even pressure relief, moisture absorption, heat absorption, and low temperature resistance. While in contact with bodies, users feel cool and dry. Moreover, the resin will not become rigid at the temperature lower than 10° C. The comfort of the foam is improved and the applications of the foam are increased.Type: GrantFiled: November 23, 2012Date of Patent: July 11, 2017Assignee: Isotech Products IncorporatedInventor: Yu-Ting Chen
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Patent number: 9605106Abstract: The present invention relates to a method for producing a polyester polyol having a concentration of ether groups in the range from 9.0 mol/kg of polyester polyol to 22 mol/kg polyester polyol, characterized in that (i) in a first step (A) isophthalic acid, optionally in the form of a C1-C4 alkyl ester, and/or terephthalic acid, optionally in the form of a C1-C4 alkyl ester, is reacted with (B) oligoethylene glycol of the formula H—(OCH2CH2)n—OH having a numerical average number of oxyethylene groups n in the range from 3.0 to 9.0, in the presence of at least one catalyst selected from the group made up of tin(II) salts, bismuth(II) salts, and titanium tetraalkoxylates, at a temperature in the range from 160° C. to 240° C.Type: GrantFiled: May 18, 2010Date of Patent: March 28, 2017Assignee: Covestro Deutschland AGInventors: Hartmut Nefzger, Erika Bauer, Johannes Van De Braak, Jürgen Schlossmacher, Silvia Kasperek
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Patent number: 9421605Abstract: An object is to propose a mold release agent improving the state of a mold surface by repeating casting cycle so as to extend the life of the metal mold actively, and a casting method using the mold release agent. A water-soluble mold release agent applied on a mold surface of a metal mold contains organic acid or organic acid salt which is reducing and ligand, wherein concentration of a total thereof is not less than 0.01 wt % in using concentration and is not more than a fixed concentration which is stability limit of emulsion of the mold release agent in undiluted concentration. Construction weight ratio of the organic acid or organic acid salt which is reducing and the ligand is in the range from 99/1 to 30/70.Type: GrantFiled: October 23, 2006Date of Patent: August 23, 2016Assignee: Toyota Jidosha Kabushiki KaishaInventors: Yuichi Furukawa, Toshio Uchida, Setsuyu Hayakawa
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Patent number: 9371410Abstract: Polyurethane systems that cure similarly to systems based on mercury catalysts contain 1,4-butanediol and a zinc carboxylate catalyst. These systems cure and develop green strength similarly to systems based on mercury catalysts. These systems are especially useful in making insulated pipe joints for subsea pipeline installations.Type: GrantFiled: September 16, 2013Date of Patent: June 21, 2016Assignee: Dow Global Technologies LLCInventors: Amber Stephenson, Eric Rexrode
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Patent number: 9353234Abstract: The invention relates to rigid polyurethane foams obtainable by reaction of A) organic or modified organic polyisocyanates or mixtures thereof, B) compounds having two or more isocyanate-reactive hydrogen atoms in the presence of C) optionally further polyester polyols, D) optionally polyetherol polyols, E) optionally flame retardants, F) one or more blowing agents, G) catalysts, and H) optionally further auxiliaries and/or additives, wherein component B) comprises the reaction product of a1) 15 to 40 wt % of one or more polyols or polyamines having an average functionality of 2.5 to 8, a2) 2 to 30 wt % of one or more fatty acids and/or fatty acid monoesters, a3) 35 to 70 wt % of one or more alkylene oxides of 2 to 4 carbon atoms.Type: GrantFiled: February 28, 2013Date of Patent: May 31, 2016Assignee: BASF SEInventors: Olaf Jacobmeier, Gunnar Kampf, Christian Koenig
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Patent number: 9315612Abstract: A composite material includes, in an exemplary embodiment a polyurethane foam and a plurality of inorganic particles dispersed therein. The polyurethane foam is formed from a reaction mixture that includes a first polyether polyol having a first molecular weight and a functionality of about 3 or less, a second polyether polyol having a second molecular weight less than the first molecular weight and a functionality of greater than about 3, and at least one isocyanate. The ratio of an amount of the first polyol in the reaction mixture to an amount of the second polyol in the reaction mixture is between about 1:1 to about 5:1.Type: GrantFiled: July 27, 2005Date of Patent: April 19, 2016Assignee: CertainTeed CorporationInventor: Fyodor A. Shutov
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Patent number: 9296856Abstract: The present invention relates to predominantly open-cell, cold-deformable, rigid polyurethane foams which possess a uniform cell structure with similar cell sizes and similar physical properties, more particularly a similar open-cell content. These foams are suitable for producing automotive interior trim, more particularly roof linings and pillar trim.Type: GrantFiled: March 24, 2014Date of Patent: March 29, 2016Assignee: Covestro Deutschland AGInventors: Lutz Bohnke, Joern Beaujean, Rolf Albach
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Patent number: 9238711Abstract: The present invention relates to a process for the preparation of a hydroxy-amino polymer, comprising the steps: a) reacting an H-functional starter compound carrying at least one Zerewitinoff-active H atom with an unsaturated cyclic carboxylic acid anhydride to give a carboxyl-group-carrying prepolymer, b) reacting the carboxyl-group-carrying prepolymer with at least one epoxide compound to give a hydroxyl-group-carrying prepolymer, c) adding a primary amine and/or ammonia to the double bond of the hydroxyl-group-carrying prepolymer obtained according to step b) to give the hydroxy-amino polymer, wherein the ratio of the amount of carboxylic acid anhydride to the number of Zerewitinoff-active H atoms of the H-functional starter compound is so chosen that almost all the Zerewitinoff-active H atoms of the H-functional starter compound are reacted.Type: GrantFiled: December 17, 2012Date of Patent: January 19, 2016Assignee: Bayer Intellectual Property GmbHInventors: Jorg Hofmann, Klaus Lorenz, Hartmut Nefzger
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Patent number: 9164466Abstract: A cleaning blade includes a portion which comes in contact with a member to be cleaned, and the portion is configured of a member containing polyurethane rubber having a structure derived from polyester polyol in which a first diol component having 10 or more carbon atoms and a second diol component having 5 or less carbon atoms are condensed with dicarboxylic acid at a molar ratio (first diol component/second diol component) of 50/50 to 80/20, a structure derived from polyisocyanate, and a structure derived from a triol.Type: GrantFiled: May 1, 2014Date of Patent: October 20, 2015Assignee: FUJI XEROX CO., LTD.Inventors: Daisuke Tano, Yu Nakamura, Masato Ono, Noriaki Kojima, Tsutomu Sugimoto, Hiroaki Akamatsu, Yoshinori Takahashi, Kei Tanaka
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Patent number: 9163137Abstract: A nanocomposite can include a polyolefin composition having at least one polyolefin. The polyolefin composition can have a multimodal molecular weight distribution, such as a bimodal molecular weight distribution. The nanocomposite can also include at least 5% by weight of nanoparticles, relative to a total weight of the nanocomposite. The nanoparticles can be carbon nanoparticles, silicon nanoparticles, or SiC nanoparticles. A nanocomposite masterbatch can be prepared by melt blending the polyolefin composition with the nanoparticles. A polyolefin resin can be prepared by blending the nanocomposite with a polyolefin. Formed articles can include the polyolefin resin.Type: GrantFiled: October 15, 2012Date of Patent: October 20, 2015Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Claire Bouvy, Olivier Lhost, Marc Dupire, Pascal Navez, Joseph DelHalle, Zineb Mekhalif, Simon Detriche
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Patent number: 9045610Abstract: The present composite structural article is a material which is in a plate-like shape and has mutually adhered fibers, and a foam that is arranged in a gap among fibers and is adhered to the fibers. The fibers are oriented from one surface side toward the other surface side thereof, and the content of the foam is in the range from 7% to 68% by weight based on 100% by weight of the total of fibers, foam and adhesive agent. The foam has preferably a size so as to pass through a sieve having an opening of 19 mm according to JIS Z8801.Type: GrantFiled: June 1, 2011Date of Patent: June 2, 2015Assignee: TOYOTA BOSHOKU KABUSHIKI KAISHAInventors: Nobukazu Ueno, Ryou Ando
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Patent number: 9023910Abstract: A process for producing a polyurethane shoe sole having an article density of 100 to 350 g/L and being made from an organic polyisocyanate, a polyol, a blowing agent consisting of water, and optionally a crosslinking and/or chain-extending agent, a catalyst, and other auxiliaries and/or additives. First, polyisocyanate, polyol and any crosslinking and/or chain-extending agent are mixed and reacted at a temperature of 110° C. to 180° C. to give a prepolymer having polyisocyanate groups. Second, the isocyanate-terminated prepolymer obtained and any remaining polyisocyanate are mixed with any remaining polyol, blowing agent comprising water, and any remaining crosslinking and/or chain-extending agent and also any catalyst and other auxiliaries and/or additives are introduced into a mold and allowed to fully react to give a polyurethane shoe sole.Type: GrantFiled: January 18, 2013Date of Patent: May 5, 2015Assignee: BASF SEInventors: Heinrich Bollmann, Andre Kamm, Anand G. Huprikar, Ulrich Holwitt
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Patent number: 9023908Abstract: The present invention relates to a method for adsorbing and/or absorbing oil, by bringing oil into contact with a polyurethane sponge with excellent mechanical properties.Type: GrantFiled: May 24, 2011Date of Patent: May 5, 2015Assignee: BASF SEInventors: Nils Mohmeyer, Ralf Fritz, Bernd Bruchmann, Anna Cristadoro, Marcus Leberfinger, Antje van der Net
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Patent number: 8980965Abstract: To provide a method for producing a low-odor polyester-type flexible polyurethane foam which is excellent in formability and free from scorch in the interior of the foam, and further discharges substantially no volatile amine compound from a product, in the production of a polyester-type flexible polyurethane foam, and to provide a catalyst composition to be used for the production method.Type: GrantFiled: October 23, 2008Date of Patent: March 17, 2015Assignee: Tosoh CorporationInventor: Yoshihiro Takahashi
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Publication number: 20150057388Abstract: The invention relates to an antistatic polyurethane which comprises an antistatic additive comprising an ionic liquid and a process for producing such an antistatic polymer. The invention further relates to an antistatic shoe sole comprising an antistatic polyurethane according to the invention and the use of an ionic liquid as antistatic additive for polyurethane.Type: ApplicationFiled: July 30, 2014Publication date: February 26, 2015Applicant: BASF SEInventors: Gitta Egbers, Marco Ortalda, Markus Templin
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Publication number: 20150057384Abstract: A method for producing polyurethane foams by reacting at least one organic isocyanate moiety, at least one polyol, a blowing agent consisting of halogen-containing (fluorine-containing) olefins and at least a siloxane of formula (I) R, R1, R2, R4, a, b, c, and d are defined herein, as well as compositions made by said method are described.Type: ApplicationFiled: November 4, 2014Publication date: February 26, 2015Applicant: EVONIK DEGUSSA GMBHInventors: Martin GLOS, Carsten SCHILLER, Christian EILBRACHT
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Publication number: 20150051304Abstract: Aromatic polyester polyols with high functionality, moderate viscosity, and high aromatic content suitable as the sole polyol in the production of polyurethane foams without the use of any polyether polyols are disclosed. This unique combination of properties makes them suit for use as the sole polyol in the production of polyurethane foams. With reduction of flame retardants, these foams based on sole aromatic polyol can have E-84 class one fire properties. The aromatic polyester polyols of this invention are characterized as having a functionality of greater than 2.8 while having a moderate viscosity ranging from 4,000-10,000 cps @ 25 C. A typical high functional polyester polyol of the present invention has a hydroxyl number in the range of 320-400, viscosity of 4,000-10,000 cps @ 25 C, functionality of greater than 2.8 and percent phenyl content greater than 14.75.Type: ApplicationFiled: April 2, 2013Publication date: February 19, 2015Inventor: David J. Shieh
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Publication number: 20150018444Abstract: There are provided ester polyols prepared from the esterification of ozone acids and branched primary polyols. There are also provided ester polyol esters prepared from an ester polyol of the invention and further esterifying the ester polyol with at least one carboxylic acid to produce at least one ester polyol ester. There are also provided rigid or flexible foams prepared using the ester polyols and/or ester polyol esters of the invention. There is also provided a coating prepared from the ester polyols and/or ester polyols esters of the invention.Type: ApplicationFiled: February 28, 2013Publication date: January 15, 2015Inventors: Daniel B. Garbark, Herman Paul Benecke
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Patent number: 8927614Abstract: The invention relates to a process for producing polyurethanes by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups, wherein the compounds b) having at least two hydrogen atoms which are reactive toward isocyanate groups comprise at least one polyether alcohol b1) which has been prepared by reaction of an aromatic amine b1a) with propylene oxide using an amine b1b) which is different from b1a) as catalyst.Type: GrantFiled: April 22, 2011Date of Patent: January 6, 2015Assignee: BASF SEInventors: Marc Fricke, Markus Schütte, Sirus Zarbakhsh, Johann Klassen
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Patent number: 8927079Abstract: Nanoporous three-dimensional networks of polyurethane particles, e.g., polyurethane aerogels, and methods of preparation are presented herein. Such nanoporous networks may include polyurethane particles made up of linked polyisocyanate and polyol monomers. In some cases, greater than about 95% of the linkages between the polyisocyanate monomers and the polyol monomers are urethane linkages. To prepare such networks, a mixture including polyisocyanate monomers (e.g., diisocyanates, triisocyanates), polyol monomers (diols, triols), and a solvent is provided. The polyisocyanate and polyol monomers may be aliphatic or aromatic. A polyurethane catalyst is added to the mixture causing formation of linkages between the polyisocyanate monomers and the polyol monomers. Phase separation of particles from the reaction medium can be controlled to enable formation of polyurethane networks with desirable nanomorphologies, specific surface area, and mechanical properties.Type: GrantFiled: November 28, 2012Date of Patent: January 6, 2015Inventors: Nicholas Leventis, Chariklia Sotiriou-Leventis, Chakkaravarthy Chidambareswarapattar
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Patent number: 8916620Abstract: A method for improving the thermal stability of polyurethane-modified polyisocyanurate (PU-PIR) foams is provided. Moreover, a process for producing the PU-PIR foams exhibiting improved thermal stability is provided. The foams have incorporated therein a high molecular weight ammonium polyphosphate (APP). APP is employed as a partial or complete substitute for flame retardants conventionally employed in PU-PIR foams. The foams of the invention exhibit excellent and improved thermal stability characteristics as compared to foams to which no APP has been added.Type: GrantFiled: August 21, 2012Date of Patent: December 23, 2014Assignee: Stepan CompanyInventors: Warren A. Kaplan, Angelo R. Gabbianelli, David J. Norberg
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Patent number: 8912245Abstract: The present invention discloses low viscosity aromatic polyester polyols suitable for blending with other polyols or other materials mutually compatible with the polyester polyols to achieve polyurethane and polyisocyanurate products. In particular the present invention discloses polyester polyols comprising the reaction of: A) an aromatic component comprising at 80 mole percent or greater of terephthalic acid; B) polyethylene glycol having a molecular weight from 150 to 1000; and C) a glycol different from the glycol of B); wherein A, B, and C are present in the reaction on a percent weight bases of 20 to 60 weight percent A); 40 to 75 weight percent of B); and 0 to 40 weight percent of C).Type: GrantFiled: June 28, 2013Date of Patent: December 16, 2014Assignee: Dow Global Technologies LLCInventor: Giuseppe Lista
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Patent number: 8901189Abstract: A foam article, for use in a seat such as a seat cushion, includes an open cell, polyurethane foam material that includes a plant oil-based polyol material content greater than five percent and is produced from the reaction of a base polyol formulation blend including at least a portion of a plant oil-based polyol, a copolymer polyol including at least a portion of a plant oil-based polyol, water, a cross-linking agent, a catalyst, cell opener and a surfactant that are reacted with an isocyanate material for producing the seat cushion having performance specifications that are equivalent or better than the performance characteristics for a traditional petroleum oil-based polyol material seat cushion.Type: GrantFiled: October 30, 2007Date of Patent: December 2, 2014Assignee: Johnsons Controls Technology CompanyInventors: Patricia J. McClarren, Ryoko Yamasaki, James T. McEvoy, Terry M. McRoberts, William W. Li