Composition Wherein Two Or More Polymers Or A Polymer And A Reactant All Contain More Than One 1,2-epoxy Group, Or Product Thereof Patents (Class 523/427)
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Patent number: 8535796Abstract: A polymerizable composite composition comprising a) a hydrolysate and/or condensate of at least one hydrolysable alkylsilane having at least one alkyl group, at least one hydrolysable arylsilane having at least one aryl group or at least one hydrolysable alkylarylsilane having at least one alkylaryl group, and at least one hydrolysable silane containing an epoxy group, b) at least one organic compound having at least 2 epoxy groups, and c) a cationic initiator, is suitable to provide, upon curing, substrates with a patterned coating or patterned molded articles. The patterned coatings and molded articles obtained show high relaxation ability, high chemical resistance and mechanical stability. Micropatterns can be obtained with high stability of shape.Type: GrantFiled: January 20, 2006Date of Patent: September 17, 2013Assignees: Leibniz-Institut fuer Neue Materialien Gemeinnuetzige GmbH, Canon Kabushiki KaishaInventors: Carsten Becker-Willinger, Pamela Kalmes, Helmut Schmidt, Etsuko Hino, Mitsutoshi Noguchi, Yoshikazu Saito, Norio Ohkuma
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Publication number: 20130236670Abstract: A composition for vulcanizing adhesion, comprises a rubber (a), at least one compound (b) selected from the group consisting of salts of 1,8-diazabicyclo(5.4.0) undecene-7, salts of 1,5-diazabicyclo(4.3.0)-nonene-5, 1,8-diazabicyclo(5.4.0) undecene-7, and 1,5-diazabicyclo(4.3.0)-nonene-5, and at least one water-carrying substance (c) selected from water-absorbed substances and hydrated substances.Type: ApplicationFiled: November 10, 2011Publication date: September 12, 2013Applicant: DAISO CO., LTD.Inventors: Koshiro Hamaguchi, Motoki Kitagawa, Toyofumi Otaka, Taro Ozaki, Yoritaka Yasuda
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Publication number: 20130237643Abstract: The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.Type: ApplicationFiled: April 22, 2013Publication date: September 12, 2013Applicant: DSM IP ASSETS B.V.Inventors: Wendell Wayne CATTRON, Steven Robert SCHMID, Edward Joseph MURPHY, John Monroe ZIMMERMAN, Anthony Joseph TORTORELLO
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Publication number: 20130237642Abstract: A thermosettable (curable) epoxy resin composition including (A) a residual oligomeric product; wherein the residual oligomeric product comprises a polyfunctional aliphatic or cycloaliphatic epoxy resin which has been isolated from an epoxy resin product formed as a result of an epoxidation process comprising the reaction of (i) an aliphatic or cycloaliphatic hydroxyl-containing material with (ii) an epihalohydrin, (iii) a basic-acting substance, (iv) a non-Lewis acid catalyst, and (V) optionally one or more solvents; (B) an epoxy curing material comprising (i) an epoxy resin curing agent, (ii) an epoxy resin catalyst, or both an epoxy resin curing agent (i) and an epoxy resin catalyst (ii); and (C) optionally, an epoxy resin compound other than the aliphatic or cycloaliphatic polyfunctional epoxy resin (A). A thermoset may also be made from the above thermosettable composition.Type: ApplicationFiled: August 31, 2011Publication date: September 12, 2013Applicant: Dow Global Technologies LLCInventor: Robert E. Hefner, JR.
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Patent number: 8524857Abstract: A new class of compounds, namely diamino alcohols, is described, along with a process for their production and their use as hardeners, or curing agents, for epoxy resin systems, some of which have high glass transition temperatures, Tgs, such as greater than about 120° C.Type: GrantFiled: December 15, 2010Date of Patent: September 3, 2013Assignees: Dow Global Technologies LLC, ANGUS Chemical CompanyInventors: Asghar Akber Peera, Ian Tomlinson
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Patent number: 8524807Abstract: Compounds VB of the formula (I) or (II), said compounds being particularly suitable as curing agents for epoxide resins. The compounds can be produced easily and rapidly. They can be used in the form of aqueous curing agents and form stabile aqueous emulsions in particular. This facilitates the formulation of ECC compounds for use primarily as coatings.Type: GrantFiled: June 12, 2009Date of Patent: September 3, 2013Assignee: Sika Technology AGInventor: Pierre-André Bütikofer
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Patent number: 8519091Abstract: The present invention provides curing agent compositions comprising the reaction product of polyalkyleneamine compounds and polyalkylene polyether polyol modified polyepoxide resins. Amine-epoxy compositions and thick layer compositions produced from these amine-epoxy compositions are also disclosed.Type: GrantFiled: April 10, 2007Date of Patent: August 27, 2013Assignee: Air Products and Chemicals, Inc.Inventor: Williams René Edouard Raymond
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Patent number: 8518208Abstract: Thermosetting adhesive compositions formed from an epoxy resin containing nano-sized core-shell particles, one or more thermoplastic toughening agent containing an amine-terminated polyethersulfone, and at least one multi-functional epoxy resin, together with at least one amine curing agent to allow full cure of the adhesive composition up to 400° F. are provided herein. Such compositions are useful for forming adhesive films that can bond composite/metal/honeycomb structures for aerospace including bonding of aircraft leading or trailing edges, acoustic nacelle structures, horizontal and vertical tail, and various other structures, as well as for other high performance industrial applications.Type: GrantFiled: August 26, 2010Date of Patent: August 27, 2013Assignee: Cytec Technology Corp.Inventor: Dalip Kohli
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Publication number: 20130217805Abstract: An epoxy resin composition containing an epoxy resin [A1], epoxy resin [B1], epoxy resin [C1] and curing agent [D] wherein [A1] is a bisphenol-type epoxy resin with a softening point of 90° C. or more, [B1] is a tri- or higher functional amine-type epoxy resin, [C1] is a bisphenol F-type epoxy resin with a number average molecular weight of 450 or less, and the epoxy resins [A1] to [C1] satisfy the following contents per 100 parts by mass of total epoxy resin content: [A1] 20 to 50 parts by mass, [B1] 30 to 50 parts by mass and [C1] 10 to 40 parts. The present invention provides low-viscosity epoxy resin compositions that are excellent in impregnating reinforcing fibers and capable of producing cured resins with excellent modulus and toughness, as well as prepregs and fiber-reinforced composite materials based on those epoxy resin compositions.Type: ApplicationFiled: September 26, 2011Publication date: August 22, 2013Applicant: TORAY INDUSTRIES, INC.Inventors: Mami Hayashi, Takayuki Fujiwara, Jun Misumi, Kenichi Yoshioka
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Publication number: 20130206333Abstract: A solid, dry to the touch at ambient temperature, heat curable, generally non-foaming structural adhesive that exhibits shape memory characteristics. The adhesive can be cured at an elevated temperature and contains a high molecular weight polymeric constituent that can be oriented such that at an elevated temperature below the curing temperature the material will shrink in one plane while increasing its thickness at a temperature in the range of from above the elevated temperature to below the curing temperature.Type: ApplicationFiled: July 26, 2011Publication date: August 15, 2013Applicant: ZEPHYROS, INC.Inventor: Michael Czaplicki
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Patent number: 8501876Abstract: The invention relates to a glass printing ink and a glass printing lacquer comprising at least one pigment, at least one photoinitiator and at least two resins. One resin is an epoxy resin having an average molecular weight based on bisphenol A, diluted in a UV hardening monomer. Another resin is a resin which contains free functional amino, hydroxy, epoxy, acid, acid anhydride and/or acrylate groups. The invention also relates to the use of the glass printing ink and glass printing lacquer when printing a glass substrate and to a method for printing a glass substrate.Type: GrantFiled: October 20, 2004Date of Patent: August 6, 2013Assignee: Marabuwerke GmbH & Co. KGInventors: Saskia Lehmann, Wolfgang Schaefer
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EPOXY RESIN HARDENER COMPOSITIONS AND EPOXY RESIN COMPOSITIONS CONTAINING SUCH HARDENER COMPOSITIONS
Publication number: 20130184378Abstract: An epoxy resin hardener composition including a reaction product of (i) a compound having at least one vicinal epoxy group, and (ii) an amino alcohol; an epoxy resin composition including the epoxy resin hardener composition and a compound having at least one vicinal epoxy group; and a powder coating composition including particles of the epoxy resin hardener composition and particles of a compound having at least one vicinal epoxy group.Type: ApplicationFiled: March 4, 2013Publication date: July 18, 2013Applicant: DOW GLOBAL TECHNOLOGIES LLCInventor: Dow Global Technologies LLC -
Patent number: 8486518Abstract: An epoxy resin composition suitably used for a prepreg which can complete curing in a short time even at a low temperature and secure a sufficient usable period under preservation at room temperature, in comparison with conventional epoxy resin compositions. An epoxy resin composition comprising at least one of an epoxy resin, an amine compound having at least one sulfur atom in the molecule thereof, and a reaction product of an epoxy resin and an amine compound having at least one sulfur atom in the molecule thereof, and an amine compound having at least one sulfur atom in the molecule thereof, and a urea compound and a dicyandiamide, wherein each of the contents of the sulfur atom and the urea compound in the epoxy resin composition is respectively 0.2 to 7% by mass and 1 to 15% by mass.Type: GrantFiled: March 27, 2008Date of Patent: July 16, 2013Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Tsuneo Takano, Akitada Yanase, Tadashi Sakai, Kiharu Numata, Akihiro Ito, Masato Taguchi, Junichi Muramatsu, Kazuya Goto, Kazuki Koga
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Publication number: 20130178559Abstract: The resin-reinforcing fiber of the preset invention is a fiber surface-treated with an epoxidized polydiene resin. The fiber is preferably carbon fiber or glass fiber. The fiber-reinforced resin composite material of the present invention comprises the resin-reinforcing fiber and a matrix resin. The matrix resin is preferably an epoxy thermosetting resin. The resin-reinforcing fiber of the present invention can improve the absorbed energy up to the maximum load (elastic energy) of a fiber-reinforced resin composite material and the absorbed energy after the maximum load (propagation energy) thereof at the same time.Type: ApplicationFiled: September 14, 2011Publication date: July 11, 2013Applicant: DAICEL CORPORATIONInventors: Asami Nakai, Misao Mori
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Publication number: 20130165550Abstract: Coating compositions are disclosed that include corrosion resisting particles such that the coating composition can exhibit corrosion resistance properties. Also disclosed are substrates at least partially coated with a coating deposited from such a composition and multi-component composite coatings, wherein at least one coating later is deposited from such a coating composition. Methods and apparatus for making ultrafine solid particles are also disclosed.Type: ApplicationFiled: February 19, 2013Publication date: June 27, 2013Applicant: PPG Industries Ohio, Inc.Inventor: PPG Industries Ohio, Inc.
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Publication number: 20130165549Abstract: The invention pertains to a printing form and a process for preparing the printing form from a solvent-free curable composition that includes, in prescribed relative amounts, an epoxy novolac resin; a bisphenol-A epoxy resin or a bisphenol-F epoxy resin; a monofunctional reactive diluent; a multifunctional reactive diluent; and a stoichiometric amount of an amine curing agent. The ratio of the epoxy novolac resin to the bisphenol epoxy resin is 1:3 to 3:1 by weight. The process includes applying the curable composition to a supporting substrate to form a layer, curing the layer at one or more temperatures in a temperature range, and engraving to form at least one cell in the cured layer. The process prepares printing forms, particularly gravure printing forms, having a cured resin composition layer that is engravable, resistant to solvent inks and to mechanical wear, and capable of printing gravure-quality images.Type: ApplicationFiled: December 18, 2012Publication date: June 27, 2013Applicant: E I DU PONT DE NEMOURS AND COMPANYInventor: E I DU PONT DE NEMOURS AND COMPANY
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Publication number: 20130158159Abstract: The present invention relates to stable, zero or low VOC epoxy-containing polysiloxane oligomer compositions that provide for a high degree of chemical resistance to compositions containing organic resins, while at the same time, maintaining or improving the flexibility of these organic resin-containing compositions, to processes for preparing epoxy-containing polysiloxane oligomer compositions, and to uses in coatings, sealants, adhesives, and composites containing the same.Type: ApplicationFiled: December 19, 2011Publication date: June 20, 2013Applicant: MOMENTIVE PERFORMANCE MATERIALS INC.Inventors: Narayana Padmanabha Iyer, Lesley Hwang, Vikram Kumar, Christian Geismann, Constantine Kondos, Shiu-Chin Su
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Publication number: 20130148304Abstract: The present invention relates to an epoxy resin composition for electronic parts encapsulation, including the following components (A) to (E), (A) an epoxy resin having an ICI viscosity of from 0.008 to 0.1 Pa·s and an epoxy equivalent of from 100 to 200 g/eq; (B) a phenol resin having an ICI viscosity of from 0.008 to 0.1 Pa·s and a hydroxyl-group equivalent of from 100 to 200 g/eq; (C) a curing accelerator; (D) an inorganic filler; and (E) a silicone compound, in which the component (D) is contained in an amount of from 82 to 88 wt % of the whole of the epoxy resin composition, the component (E) is contained in an amount of from 5 to 15 wt % of the whole of organic components in the epoxy resin composition, and the epoxy resin composition has a gelation time of 15 to 25 seconds.Type: ApplicationFiled: September 14, 2012Publication date: June 13, 2013Applicant: NITTO DENKO CORPORATIONInventors: Yuya KITAGAWA, Mitsuaki FUSUMADA, Aya MIZUSHIMA, Koki NAKAMURA, Yuta ONO
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Patent number: 8450433Abstract: Provided are a resin composition for the manufacture of marble chips including a halogenated epoxy resin binder and showing high heat resistance, high chemical resistance, high impact resistance, high specific gravity and high transparency, a marble chip manufacturing method using the resin composition and an artificial marble made from marble chips.Type: GrantFiled: August 13, 2010Date of Patent: May 28, 2013Inventor: Young-Min Kim
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Patent number: 8445590Abstract: A composite prepared using a thermosettable epoxy resin composition having, as components: (1) an epoxy resin; (2) an epoxidized cycloaliphatic dicyclopentadiene phenolic resin; (3) an optional epoxidized bisphenol-A novolac resin; (4) an optional oligomeric butadiene; (5) an optional organic solvent; and (6) an alkylphenol novolac resin, the alkylphenol novolac resin serving as a curing agent. The composite so prepared may have good physical properties and superior a electrical properties as compared to conventional composites, such as laminates. The prepregs used to make the laminates may have a better surface appearance as well.Type: GrantFiled: April 9, 2012Date of Patent: May 21, 2013Assignee: Momentive Specialty Chemicals Inc.Inventor: Charles David Shirrell
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Publication number: 20130122766Abstract: Embodiments of the present disclosure include a curable composition including an epoxy compound selected from the group consisting of aromatic epoxy compounds, alicyclic epoxy compounds, aliphatic epoxy compounds, and combinations thereof, a curing agent selected from the group consisting of novolacs, amines, anhydrides, carboxylic acids, phenols, thiols, and combinations thereof, and a phosphono-methyl-glycine.Type: ApplicationFiled: July 19, 2011Publication date: May 16, 2013Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Sudhakar Balijepalli, Michael J. Mullins, Irina Graf, Raymond J. Thibault, Ashwin Bharadwaj, Anteneh Worku
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Patent number: 8440746Abstract: Curable, one-package, stable adhesive compositions are provided comprising: (a) a resin component comprising a polyepoxide, (b) a polyamine having at least two primary amine, secondary amine, and/or ketimine functional groups; and (c) a curing component comprising dicyandiamide and an accelerator. At least a portion of the polyepoxide in the resin component is reacted with carboxy-terminated butadiene acrylonitrile polymer. The accelerator comprises a reaction product comprising a renewable polyol, a diisocyanate, and a dialkyl monoamine containing alkyl groups with at least two carbon atoms each. The compositions are suitable for use as adhesive compositions over a wide temperature range.Type: GrantFiled: December 2, 2010Date of Patent: May 14, 2013Assignee: PPG Industries Ohio, IncInventors: Shanti Swarup, Masayuki Nakajima, Umesh C. Desai, Tien-Chieh Chao, Charles M. Kania, Britt Minch
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Publication number: 20130115442Abstract: A structural adhesive composition that is suitable for high-strength bonding of metals and aerospace structural materials. In one embodiment, the structural adhesive composition based on a two-part system, which is curable at or below 200° F. (93° C.). The two-part system is composed of a resinous part (A) and a catalyst part (B), which may be stored separately at room temperature until they are ready to be used. The resinous part (A) includes at least two different multifunctional epoxy resins, toughening components, and inorganic filler particles. The catalyst part (B) includes an aliphatic or cyclic amine compound as a curing agent and inorganic filler. In another embodiment, the structural adhesive composition is based on a one-part system, which includes the components of the resinous part (A) mixed with a latent amine curing agent. The one-part system may further include an imidazole and/or an aliphatic amine.Type: ApplicationFiled: October 16, 2012Publication date: May 9, 2013Applicant: CYTEC TECHNOLOGY CORP.Inventor: Cytec Technology Corp
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Publication number: 20130105209Abstract: An inorganic filler containing (1) from 50 to 60 parts by weight of SiO2; (2) from 5 to 20 parts by weight of Al2O3; (3) from 0 to 10 parts by weight of CaO; (4) from 15 to 30 parts by weight of B2O3; (5) from 0 to 5 parts by weight of MgO; (6) from 0 to 1 parts by weight of Na2O, K2O or a combination of both; and (7) from 0 to 5 parts by weight of TiO2; based on a total weight of the filler, and having a maximum particle diameter below 100 ?m is introduced. A resin composition containing the inorganic filler and application in printed circuit boards are also introduced. A laminate prepared by the inorganic filler provides a good drilling function, a good dielectric performance and a good high frequency transmission function in high frequency transmission printed circuit board.Type: ApplicationFiled: November 1, 2012Publication date: May 2, 2013Applicant: ELITE ELECTRONIC MATERIAL (KUNSHAN) CO., LTD.Inventor: Elite Electronic Material (Kunshan) CO., LTD.
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Publication number: 20130109784Abstract: The invention relates to aqueous radiation-hardenable epoxy acrylate dispersions comprising (a) an epoxy acrylate resin (P*) with at least two acrylate groups per molecule, wherein at 25 degrees Celsius, said epoxy acrylate resin is not self-disperging in water; and (b) a dispergator (D*) with at least one acrylate group per molecule, wherein said dispersions can be produced by converting, in a first step (i), in the presence of a catalyst if need be, one or several compounds (A) selected from the group of non-ionic compounds having a HLB value of less than 12, and containing at least two oxirane groups per molecule, with one or several compounds (B) selected from the group of non-ionic compounds having a HLB value in the range from 12 to 20, and which contain at least one h-acid group (ZH) per molecule. The compounds (A) and (B) are employed at an equivalence ratio EpO (A):ZH (B) in the range from 1.Type: ApplicationFiled: September 13, 2010Publication date: May 2, 2013Inventors: Juergen Baro, Laurence Druene, Paul Birnbrich, Hans-Josef Thomas
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Publication number: 20130108875Abstract: An inorganic filler containing (1) from 62 to 80 parts by weight of SiO2; (2) from 0 to 10 parts of weight of Al2O3; (3) from 20 to 30 parts by weight of B2O3; and (4) from 0 to 5 parts by weight of Na2O or K2O or a combination of both; based on a total weight of the filler, and the inorganic filler having a maximum particle diameter below 100 ?m is introduced. A resin composition containing the inorganic filler and applied for manufacturing printed circuit boards is also introduced, and a laminate prepared by the inorganic filler provides a good drilling function and a good dielectric performance. The laminate manufactured by adopting the inorganic filler is used for manufacturing high frequency transmission printed circuit board with a good high frequency transmission function.Type: ApplicationFiled: November 1, 2012Publication date: May 2, 2013Applicant: ELITE ELECTRONIC MATERIAL (KUNSHAN) CO., LTD.Inventor: Elite Electronic Material (Kunshan) CO., LTD.
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Patent number: 8431224Abstract: Disclosed is a halogen-free resin composition for printed wiring board production, which is remarkably reduced in quality deterioration due to moisture absorption of a semi-cured resin film (layer). Also disclosed is a copper film with resin or the like. The resin composition is characterized by containing a component A (one or more resins selected from the group consisting of bisphenol-A epoxy resins, bisphenol-F epoxy resins and bisphenol-AD epoxy resins, which have an epoxy equivalent of not more than 200, while being in a liquid state at 25 DEG C.), a component B (a linear polymer having a crosslinkable functional group), a component C (a crosslinking agent), a component D (an imidazole-based epoxy resin curing agent) and a component E (a phosphorus-containing epoxy resin). The resin composition is also characterized by containing 0.5-3.0% by weight of phosphorus atoms per 100% by weight of the resin composition. In the copper foil with resin, a resin layer is formed by using the resin composition.Type: GrantFiled: March 21, 2008Date of Patent: April 30, 2013Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Tetsuro Sato, Toshifumi Matsushima
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Publication number: 20130098676Abstract: A two part, curable, epoxy composition useful for potting or sealing electrical devices for use in hazardous locations. Cured reaction products of the epoxy composition meet most or all UL 674 requirements and are useful to seal apertures in electrical equipment. Equipment sealed with the disclosed compositions can meet the UL 674 requirement.Type: ApplicationFiled: December 13, 2012Publication date: April 25, 2013Applicant: Henkel CorporationInventor: Henkel Corporation
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Publication number: 20130082547Abstract: There are provided a sealing resin composition for a hard disk drive (HDD) motor and a HDD motor fabricated by using the same. The sealing resin composition includes 40 to 80 parts by weight of epichlorohydrin-4,4-isopropylidene diphenol resin; 5 to 20 parts by weight of acrylated ester; and 5 to 15 parts by weight of acrylated epoxy. The sealing resin composition containing a UV curable epoxy resin is used as a sealing material of the adhering part of the FPC of the HDD motor, whereby generation of outgas in the adhering part may be reduced.Type: ApplicationFiled: December 20, 2011Publication date: April 4, 2013Inventors: Kun Kim, Myung Hwa Choi, Sang Hyun Kwon, Hyung Kyu Kim
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Publication number: 20130064658Abstract: A lining for a compressor case in use with a gas turbine engine compressor is provided. The compressor includes a compressor casing, which is generally comprised of a first and second half. Inside the casing is a plurality of vanes attached to a plurality of vane bands. The vane bands are affixed to the interior of the compressor casing. A lining, comprising a carbon fiber reinforced-type material is applied to the interior of the compressor casing over the vane bands. The lining allows a minimal clearance to be between the lining and wheel blade tips spinning within the compressor casing. The carbon fiber in the lining allows the lining to withstand a high number of temperature cycles due to the use of the compressor and the gas turbine engine.Type: ApplicationFiled: May 31, 2011Publication date: March 14, 2013Inventor: Craig Rookstool
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Publication number: 20130065986Abstract: A curable resin composition essentially includes an epoxy compound (A) having an oxycyclohexane skeleton including a cyclohexane ring and an epoxy group bound thereto through a single bond; an alicyclic epoxy compound (B) having two or more alicyclic epoxy groups per molecule; at least one bisphenol diepoxy compound (C) selected from bisphenol-A epoxy resins and bisphenol-F epoxy resins; a polyglycidyl ether of an aliphatic polyhydric alcohol (D); and a curing agent (E). The curable resin composition can give a cured article which has extremely superior moisture resistance, and, when used typically as an LED sealant, does not cause reduction in luminous flux even under hot and humid conditions. The cured article also has satisfactory cracking resistance and thermal stability in heat cycles.Type: ApplicationFiled: July 20, 2011Publication date: March 14, 2013Applicant: DAICEL CORPORATIONInventor: Atsushi Sato
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Publication number: 20130056151Abstract: The present invention relates to heat-curable compositions containing a mixture of reactive epoxy resins that contains, based on the mass of all epoxy resins, a) at least 10 wt % of an epoxy group-containing reaction product of epichlorohydrin with polypropylene glycol which has an epoxy equivalent weight of at least 250 g/eq, and b) at least 10 wt % of an epoxy group-containing reaction product of epichlorohydrin with a novolac resin which has an epoxy equivalent weight of at least 175 g/eq, and at least one latent hardener.Type: ApplicationFiled: November 5, 2012Publication date: March 7, 2013Applicant: Henkel AG & Co. KGaAInventor: Henkel AG & Co. KGaA
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Publication number: 20130035419Abstract: The present invention refers to a method of dispersing carbon nanotubes in a thermosetting resin. The method comprises: (a) contacting the carbon nanotubes with a dispersant in a solvent to form a dispersion mixture, wherein the dispersant is a graft polymer comprising a polymeric backbone and a side chain grafted to the polymeric backbone; and (b) adding the thermosetting resin to the dispersion solution to form a resin blend. The present invention also refers to a composition used for the method.Type: ApplicationFiled: February 9, 2011Publication date: February 7, 2013Applicant: NANYANG TECHNOLOGICAL UNIVERSITYInventors: Bee Eng Mary Chan, Wei Yuan, Junluo Feng, Zaher Judeh
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Patent number: 8362116Abstract: A low dielectric resin varnish composition for laminated printed circuit boards, wherein the resin composition includes (A) Dicyclo-pentadiene-Phenolic Novolac resin (abbreviated as DCPD-PN); or (B) at least one kind of dicyclopentadiene Phenolic Novolac Epoxy resins(DCPD-PNE, referred to as Resin 1); or (C) a novel Dicyclopentadiene-Dihydrobenzoxazine resin (DCPD-BX, referred to as Resin 2); and (D) Flame retardant agent, curing agent and accelerating agent solutions.Type: GrantFiled: March 15, 2010Date of Patent: January 29, 2013Assignee: Nan Ya Plastics CorporationInventors: Ming Jen Tzou, June Che Lu, Yi Cheng Lin
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Publication number: 20130020118Abstract: Provided is a resin composition for an adhesive comprising a polyurethane resin containing a carboxyl group, having specific range of an acid value having specific range of a number average molecular weight and having specific range of a glass transition temperature a polyester resin having specific range of a number average molecular weight and having specific range of a glass transition temperature; an epoxy resin containing a nitrogen atom; and an epoxy resin having a dicyclopentadiene skeleton, in which a content rate of the polyurethane resin to a sum of the polyurethane resin and the polyester resin is 70 to 95 percent by mass, a content rate of the total epoxy resin contained in the resin composition to the sum of the polyurethane resin and the polyester resin is 5 to 30 percent by mass.Type: ApplicationFiled: April 12, 2011Publication date: January 24, 2013Inventors: Takeshi Ito, Shintaro Nanbara, Hiroko Asada, Yuto Tanikawa, Hideaki Tanaka, Yoichi Kenmotsu
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Publication number: 20130012088Abstract: There are provided a cyanate ester resin composition for highly multilayered printed wiring boards for high-frequency applications which exhibits excellent heat resistance and dielectric characteristics and which can yield moldings with an excellent surface appearance, a prepreg prepared using the same, and a metal foil-clad laminated sheet. The resin composition comprises (a) a cyanate ester resin having two or more cyanate groups in the molecule, (b) a bisphenol A epoxy resin having two or more epoxy groups in the molecule, (c) a novolak epoxy resin having two or more epoxy groups in the molecule, (d) a brominated polycarbonate oligomer, (e) a low polymer of styrene and/or a substituted styrene, (f) spherical silica particles having a mean particle diameter of 3 ?m or less, and (g) a wetting and dispersing agent.Type: ApplicationFiled: January 6, 2011Publication date: January 10, 2013Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Akifumi Tiba, Satoshi Yoshinaka
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Publication number: 20130005855Abstract: Disclosed is a carbon-fiber-reinforced composite material that is suitable for use as a construction material and exhibits high mechanical strength in harsh usage environments such as low-temperature environments and high-temperature moisture-absorbing environments. Also disclosed are an epoxy resin composition for producing the aforementioned carbon-fiber-rein-forced composite material and a prepreg obtained through the use of said epoxy resin composition. Said epoxy resin composition comprises at least the following constituents, by mass with respect to the total mass of the composition: (A) between 20% and 80% of an epoxy resin having the structure represented by formula (1); and (B) between 10% and 50% of an epoxy resin that has at least two ring structures with four or more members each and also has one amine glycidyl or ether glycidyl directly connected to a ring structure.Type: ApplicationFiled: December 24, 2010Publication date: January 3, 2013Inventors: Atsuhito Arai, Hiroaki Sakata, Hiroshi Taiko, Michiya Ishikawa, Hidetoshi Kato, Jiro Nakatani
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Publication number: 20120315412Abstract: A thermochromic ink contains scented microcapsules.Type: ApplicationFiled: May 14, 2012Publication date: December 13, 2012Inventors: Terrill Scott Clayton, Timothy J. Owen
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Publication number: 20120308729Abstract: The invention relates to an aqueously dispersible epoxy resin E, comprising building blocks derived from an aliphatic polyether polyol A, an epoxy resin B having at least two epoxide groups per molecule, an epoxy resin B? having at least two epoxide groups per molecule, which may be identical to B, or different from B, an epoxy-functional fatty acid ester D, and an aromatic polyol C, a process for the preparation thereof, and a method of use thereof.Type: ApplicationFiled: November 22, 2010Publication date: December 6, 2012Applicant: Cytec Austria GmbHInventors: Thomas Fischer, Elfriede Prucher
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Publication number: 20120302667Abstract: An epoxy resin composition for encapsulating a semiconductor device includes a curing agent, a curing accelerator, inorganic fillers, and an epoxy resin, the epoxy resin including a first resin represented by Formula 1: wherein R1 and R2 are each independently hydrogen or a C1 to C4 linear or branched alkyl group, and n is a value from 1 to 9 on average.Type: ApplicationFiled: May 23, 2012Publication date: November 29, 2012Applicant: CHEIL INDUSTRIES, INC.Inventors: Seung HAN, Ju Mi KIM, Sung Su PARK, Eun Jung LEE
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Publication number: 20120299216Abstract: An adhesive adapted to enable spray delivery and seamless polymerization during epoxy resin vacuum infusion techniques.Type: ApplicationFiled: July 1, 2011Publication date: November 29, 2012Applicant: WESTECH AEROSOL CORPORATIONInventors: David W. Carnahan, Robert R. Yuodelis, James C. Manlove
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Publication number: 20120296012Abstract: Formulations containing a mixture of an epoxy resin and an ionic liquid or an adduct of an epoxy resin and an ionic liquid which may initiate curing of the epoxy resin, the mixture having nano-materials dispersed or dissolved therein. These formulations can be used for the preparation of nanocomposites. Methods of preparing nanocomposites by curing a dispersion of nano-materials in a mixture of an epoxy resin and an ionic liquid or an adduct of an epoxy resin and an ionic liquid which may initiate curing of the epoxy resin. Nanocomposites comprising a cured product formed by curing an epoxy resin with an ionic liquid or an adduct of an epoxy resin and an ionic liquid having nano-materials dispersed or dissolved therein. Embodiments of the invention permit manufacture of nanocomposites having relatively high fracture toughness, relatively high loadings of nano-materials and the ability to tailor the properties of the nano-composites.Type: ApplicationFiled: February 4, 2011Publication date: November 22, 2012Applicant: DREXEL UNIVERSITYInventors: Giuseppe R. Palmese, Arianna L. Watters
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Patent number: 8309631Abstract: It is an object of the present invention to provide a fiber reinforced composite material combining good properties such as toughness and impact resistance and to provide an epoxy resin composition to obtain this. This object is achieved by the an epoxy resin composition comprising the following [A], [B], [C], and [D]: [A] a diglycidyl ether-type epoxy resin having a molecular weight of 1,500 or more; [B] an epoxy resin in which an SP value of a structural unit thereof is greater by 1.5 to 6.5 than an SP value of a structural unit of [A]; [C] a diglycidyl ether-type epoxy resin having a molecular weight of 500 to 1,200; and [D] an epoxy resin curing agent, in a ratio that satisfies the following formulas (1) to (4): 0.2?A/(A+B+C+E)?0.6;??(1), 0.2?B/(A+B+C+E)?0.6;??(2), 0.15?C/(A+B+C+E)?0.4; and??(3), 0?E/(A+B+C+E)?0.2,??(4) wherein A, B, and C represent weights of [A], [B], and [C], respectively, and E represents a weight of an epoxy resin other than [A], [B], and [C].Type: GrantFiled: February 26, 2009Date of Patent: November 13, 2012Assignee: Toray Industries, Inc.Inventors: Nobuyuki Tomioka, Shiro Honda, Yuki Mitsutsuji, Maki Mizuki, Takayuki Imaoka
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Patent number: 8309632Abstract: The invention provides an epoxy nanocomposite material for dental therapy, which can be applied to direct or indirect clinical restoration, dental core-post system, and dental brace etc. The epoxy nanocomposite filling material provided by the invention can be polymerized with various curing agents to form the polymer with low shrinkage.Type: GrantFiled: February 5, 2010Date of Patent: November 13, 2012Assignee: National Taiwan UniversityInventors: Wei-Fang Su, Sheng-Hao Hsu, Yun-Yuan Tai, Min-Huey Chen
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Carbon/epoxy resin composition and method of producing a carbon-epoxy dielectric film using the same
Patent number: 8304473Abstract: A carbon/epoxy resin composition and a method of producing a carbon-epoxy dielectric using the same. The carbon/epoxy resin composition includes about 45 volume percent (volume %) to about 50 volume % of an epoxy composition, the epoxy composition including a bisphenol-based epoxy compound and an alicyclic epoxy compound, based on a total volume of the carbon/epoxy resin composition, about 2.0 volume % to about 3.1 volume % of carbon black, based on a total volume of the carbon/epoxy resin composition, about 80 parts by volume to about 104 parts by volume of an acid anhydride-based curing agent, based on 100 parts by volume of the epoxy composition, and about 1 part by volume to about 3 parts by volume of a tertiary alkylamine-based curing catalyst, based on 100 parts by volume of the epoxy composition.Type: GrantFiled: July 27, 2009Date of Patent: November 6, 2012Assignees: Samsung Electronics Co., Ltd., Samsung Electro-Mechanics Co., Ltd.Inventors: Yoo-Seong Yang, Eun-Sung Lee, Sang-Soo Jee, Soon-Jae Kwon -
Patent number: 8278401Abstract: This invention relates to curable sealants that provide low moisture permeability and good adhesive strength after cure. The composition comprises an aromatic compound having meta-substituted reactive groups and a cationic or radical initiator.Type: GrantFiled: March 29, 2006Date of Patent: October 2, 2012Assignee: Henkel AG & Co. KGaAInventors: Shengqian Kong, Sarah E. Grieshaber
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Publication number: 20120238668Abstract: A curable resin composition including (I) at least one thermoset resin composition; and (II) at least one hardener; wherein the powder coating has a balance of properties including a combination of high glass transition temperature and low water absorption.Type: ApplicationFiled: November 10, 2010Publication date: September 20, 2012Inventors: Guillaume Metral, Bernd Hoevel, Joseph Gan, Michael J. Mullins, Robert E. Hefner, JR.
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Patent number: 8263216Abstract: Disclosed is a fiber-reinforced composite material that is high in heat resistance and strength while being low in the content of volatile matter that volatilizes during curing. Also disclosed are an epoxy resin composition for production thereof, and a prepreg produced from the epoxy resin composition. Specifically the invention provides an epoxy resin composition comprising: [A] an epoxy resin comprising two or more ring structures each consisting of four or more members, and at least one amine type or ether type glycidyl group directly connected to the ring structures, [B] a tri- or more-functional epoxy resin, and [C] a curing agent, and also provides a prepreg produced by impregnating reinforcing fiber with the epoxy resin composition and a fiber-reinforced composite material produced by curing the prepreg.Type: GrantFiled: January 13, 2010Date of Patent: September 11, 2012Assignee: Toray Industries, Inc.Inventors: Atsuhito Arai, Hiroaki Sakata, Kenichi Yoshioka, Hiroshi Taiko, Jiro Nakatani, Kotaro Ono, Michiya Ishikawa
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Publication number: 20120220684Abstract: Disclosed is a curable formulation comprising a resin; all, or a substantial part, of which comprises one or more fatty acid esters, or their derivatives, obtained from plant oils. Due to the high viscosity of known curable resin materials, and in particular cationically photocurable and thermally curable resins epoxy resins, reactive diluents are conventionally added in order to reduce viscosity and render them suitable for certain methods of application, such as flexography and inkjet printing. However, if an excessive amount of reactive diluent is added to a formulation, the concentration of resin may be so low as to prevent a formulation from curing to form a cured, cross-linked material with acceptable properties. Thus the minimum viscosity of known formulations is limited by the amount of low viscosity reactive diluent which may be added to comparatively high viscosity resins.Type: ApplicationFiled: September 7, 2010Publication date: August 30, 2012Inventors: Ian Bryson, Jiaqian Li, Ian Malcom MacKinnon, Jinglan Zhang
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Publication number: 20120211161Abstract: Structural adhesives are prepared from an elastomeric toughener that contains urethane and/or urea groups, and have terminal isocyanate groups that are capped with ketoxime compound. The adhesives have very good storage stability and cure to form cured adhesives that have good lap shear and impact peel strengths, even at ?40° C.Type: ApplicationFiled: October 11, 2010Publication date: August 23, 2012Inventors: Andreas Lutz, Daniel Schneider