Composition Wherein Two Or More Polymers Or A Polymer And A Reactant All Contain More Than One 1,2-epoxy Group, Or Product Thereof Patents (Class 523/427)
  • Publication number: 20090131547
    Abstract: An alicyclic diepoxy compound (A) represented by formula (I) is produced in high purity and high yield at low cost, by epoxidizing the corresponding alicyclic diolefin compound with an organic percarboxylic acid. The curable epoxy resin composition has high reactivity for various curing agents, low viscosity, and excellent workability. A cured product thereof shows useful physical properties for uses in coatings, inks, adhesives, sealants, and encapsulants, etc. It is of extremely high quality as an epoxy resin composition for the encapsulation of electronic parts. A stabilizer for an electrical insulating oil (the alicyclic diepoxy compound or an electrical insulting oil containing the compound) is low in acid value, and the stabilizer improves the properties of the insulating oil. A cured product obtained by curing a casting epoxy resin composition for electrical insulation has excellent properties such as high bending strength, high Tg, and low permittivity.
    Type: Application
    Filed: December 5, 2008
    Publication date: May 21, 2009
    Inventors: Hisashi Maeshima, Hideyuki Takai
  • Patent number: 7521120
    Abstract: Provided are a non-halogen flame retardant epoxy resin composition comprising (A) a silicon-containing, phosphorus-modified epoxy resin, (B) a multifunctional epoxy resin, (C) a mixed curing agent of an amine curing agent and a phenolic curing agent and (D) a metal hydrate inorganic flame retardant, and a prepreg and copper-clad laminate using the same. The epoxy resin composition in accordance with the present invention exhibits excellent flame retardancy without use of a halogen flame retardant, and also advantageously provides well-balanced various physical properties which are to be required in copper-clad laminates, such as higher heat resistance and copper peel strength, and lead heat-resistant characteristics after moisture absorption.
    Type: Grant
    Filed: November 22, 2005
    Date of Patent: April 21, 2009
    Assignee: LG Chem, Ltd.
    Inventors: Mok Yong Jung, Eunhae Koo
  • Publication number: 20090096114
    Abstract: An epoxy resin composition for encapsulating a semiconductor chip according to this invention comprises (A) a crystalline epoxy resin, (B) a phenol resin represented by general formula (1): wherein R1 and R2 are independently hydrogen or alkyl having 1 to 4 carbon atoms and two or more R1s or two or more R2s are the same or different; a is integer of 0 to 4; b is integer of 0 to 4; c is integer of 0 to 3; and n is average and is number of 0 to 10, (C) a (co)polymer containing butadiene-derived structural unit or its derivative, and (D) an inorganic filler in the amount of 80 wt % to 95 wt % both inclusive in the total epoxy resin composition.
    Type: Application
    Filed: November 13, 2008
    Publication date: April 16, 2009
    Inventors: Takahiro Kotani, Hidetoshi Seki, Masakatsu Maeda, Kazuya Shigeno, Yoshinori Nishitani
  • Publication number: 20090026425
    Abstract: The invention provides a composition comprising a polyester amide acid (A) obtained by reacting a tetracarboxylic dianhydride (a1), a diamine (a2) and a multivalent hydroxy compound (a3); a pigment (B); and an epoxy resin (C), which is most suitable for an ink-jet ink composition for a color filter.
    Type: Application
    Filed: July 25, 2008
    Publication date: January 29, 2009
    Applicant: CHISSO CORPORATION
    Inventors: Hiroyuki SATOU, Yoshihiro DEYAMA, Akira YAMAUCHI
  • Patent number: 7456230
    Abstract: The present invention provides a cationically photocurable epoxy resin composition, which contains (a) an epoxy resin component comprising an alicyclic epoxy resin and an aromatic-ring containing epoxy resin, (b) a cationic photoinitiator component, and (c) a filler selected from oxides, hydroxides and carbonates containing a Group II element. This composition exhibits improved adhesive strength to a glass such as an alkali glass, particularly a sodium-containing glass, or a metal.
    Type: Grant
    Filed: May 7, 2003
    Date of Patent: November 25, 2008
    Assignee: Henkel Corporation
    Inventors: Yoke Ai Gan, Chunfu Chen, Kazuyo Terada
  • Publication number: 20080285247
    Abstract: This invention relates to the thermosetting resin compositions useful for mounting onto a circuit board semiconductor devices, such as chip size or chip scale packages (“CSPs”), ball grid arrays (“BGAs”), land grid arrays (“LGAs”) and the like, each of which having a semiconductor chip, such as large scale integration (“LSI”), on a carrier substrate. Similarly, the compositions are useful for mounting onto circuit board semiconductor chips themselves. Reaction products of the compositions of this invention are controllably reworkable when subjected to appropriate conditions. And significantly, unlike many commercial rapid curing underfill sealants (“snap cure underfills”), the inventive compositions possess an exotherm under 300 J/g or demonstrate package stability at 55° C. for 7 days, and therefore do not require special packaging to be transported by air courier, or special approval from international transportation authorities, such as the U.S. Department of Transportation, to permit such air transport.
    Type: Application
    Filed: October 24, 2006
    Publication date: November 20, 2008
    Applicant: Henkel Corporation
    Inventors: Qing Ji, Chew B. Chan, Hwang K. Yun, Renzhe Zhao, Weitong Shi
  • Patent number: 7446136
    Abstract: A cure system including a compatiblized and passivated refectory solid dispersed within a low temperature liquid curing agent is provided. An adhesive system including the cure system is provided, and an associated method. A device including the cured adhesive system is provided.
    Type: Grant
    Filed: June 23, 2005
    Date of Patent: November 4, 2008
    Assignee: Momentive Performance Materials Inc.
    Inventor: Slawomir Rubinsztajn
  • Patent number: 7405246
    Abstract: A cure system including a compatiblized and passivated refectory solid dispersed within a low temperature liquid curing agent is provided. An adhesive system including the cure system is provided, and an associated method. A device including the cured adhesive system is provided.
    Type: Grant
    Filed: June 23, 2005
    Date of Patent: July 29, 2008
    Assignee: Momentive Performance Materials Inc.
    Inventor: Slawomir Rubinsztajn
  • Patent number: 7390858
    Abstract: The present invention provides coating compositions that include an epoxy-modified fatty acid ester resin, an oxirane-functional resin different from the epoxy-modified fatty acid ester resin, a carboxyl functional polyester resin, and an alkyl acid phosphate.
    Type: Grant
    Filed: October 18, 2005
    Date of Patent: June 24, 2008
    Assignee: Valspar Sourcing, Inc.
    Inventor: Donna Jean Knouse
  • Patent number: 7381359
    Abstract: An encapsulant is described for an optoelectronic device or optical component, which provides a coefficient of thermal expansion of less than 50 ppm/° C., with a variation of less than ±30%, and further provides an optical transmittance of at least 20% at a wavelength in the range of 400 to 900 nm, at an encapsulant thickness of about 1 mm. The encapsulant includes a filler consisting essentially of glass particles having diameters smaller than 500 ?m, being essentially free of titania and lead oxide, and having a refractive index in the range of 1.48 to 1.60, with a variance of less than about 0.001.
    Type: Grant
    Filed: October 14, 2004
    Date of Patent: June 3, 2008
    Assignee: Yazaki Corporation
    Inventors: Yongan Yan, Douglas Meyers, Mark Morris, D. Laurence Meixner, Satyabrata Raychaudhuri
  • Patent number: 7345102
    Abstract: An epoxy resin composition for encapsulating optical semiconductor element, comprising the following (A) to (D): (A) an epoxy resin component comprising a novolak type epoxy resin having at least one of the biphenyl skeleton and naphthalene skeleton in one molecule in an amount of from 50 to 100% by weight of the total weight of the epoxy resin component, (B) a curing agent component comprising a novolak type phenol resin having at least one of the biphenyl skeleton and naphthalene skeleton in one molecule in an amount of from 50 to 100% by weight of the total weight of the curing agent component, (C) an organic phosphorus flame retarder, and (D) a curing catalyst, wherein the content of an organic phosphorus flame retarder as (C) is from 1.5 to 10% by weight based on the total weight of the epoxy resin composition.
    Type: Grant
    Filed: October 15, 2004
    Date of Patent: March 18, 2008
    Assignee: Nitto Denko Corporation
    Inventors: Hisataka Ito, Shinya Ota, Yuji Tada
  • Patent number: 7311972
    Abstract: An encapsulant is described for an optoelectronic device or optical component, which provides a coefficient of thermal expansion of less than 50 ppm/° C., with a variation of less than ±30%, and further provides an optical transmittance of at least 20% at a wavelength in the range of 400 to 900 nm, at an encapsulant thickness of about 1 mm. The encapsulant includes a filler consisting essentially of glass particles having diameters smaller than 500 ?m, being essentially free of titania and lead oxide, and having a refractive index in the range of 1.48 to 1.60, with a variance of less than about 0.001.
    Type: Grant
    Filed: October 14, 2004
    Date of Patent: December 25, 2007
    Assignee: Yazaki Corporation
    Inventors: Yongan Yan, Douglas Meyers, Mark Morris, D. Laurence Meixner, Satyabrata Raychaudhuri
  • Patent number: 7304102
    Abstract: An encapsulant for use with opto-electronic devices and optical components incorporates a filler made from a glass that has been processed into particle form and heated to a predetermined temperature for a predetermined time, along with an epoxy having an index of refraction matched to that of the glass and heated to a predetermined temperature for a predetermined time, to prevent settling of the filler particles after mixing the filler particles with the epoxy, and thereby obtaining uniform dispersion of the particles within the epoxy. The encapsulant provides for high light transmittance, and its coefficient of thermal expansion can be varied by varying the amount of filler without substantially altering the optical properties of the encapsulant. The coefficient of thermal expansion variation within the encapsulant preferably is less than 30%, due to uniform dispersion of the filler particles within the epoxy.
    Type: Grant
    Filed: December 7, 2004
    Date of Patent: December 4, 2007
    Assignee: Yazaki Corporation
    Inventors: Yongan Yan, Douglas Evan Meyers, Mark Allen Morris, D. Laurence Meixner, Satyabrata Raychaudhuri
  • Patent number: 7294660
    Abstract: An epoxy resin composition which comprises 100 parts by weight of an epoxy resin and 1 to 800 parts by weight of an aluminum borate whisker having an average fiber diameter of 0.25 ?m or less. The epoxy resin composition contains a large amount of the aluminum borate whisker being dispersed uniformly therein, is excellent in mechanical strength, and is suppressed with respect to the anisotropy of a mechanical property due to the direction of application.
    Type: Grant
    Filed: June 6, 2003
    Date of Patent: November 13, 2007
    Assignee: Asahi Denka Co., Ltd.
    Inventors: Seiichi Saito, Yoshihiro Fukuda, Takahiro Mori, Yoshinori Takahata
  • Patent number: 7288606
    Abstract: A casting resin compound as an assembly and encapsulation material for electronic and optoelectronic component parts, modules and components, for example for casting out optoelectronic components on the basis of acid anhydride-curable epoxy compounds, particularly bisphenol A-diglycidyl ether, contains multi-functional epoxy novolak resins, particularly an epoxy cresol novolak. This casting resin compound exhibits a clearly increased glass transition temperature, is suitable for mass-production, exhibits no health deteriorations, and supplies SMT-capable products that can be utilized in the automotive sector.
    Type: Grant
    Filed: December 16, 2005
    Date of Patent: October 30, 2007
    Assignee: Osram GmbH
    Inventors: Klaus Höhn, Günter Waitl, Karlheinz Arndt
  • Patent number: 7179552
    Abstract: Resin compositions which comprise the following components (A) to (E) are useful for interlayer insulation of a multilayer printed wiring board: (A) an epoxy resin having 2 or more epoxy group in one molecule and which exists in a liquid state at a temperature of 20° C.; (B) an aromatic epoxy resin having 3 or more epoxy groups in one molecule and an epoxy equivalent of 200 or less; (C) a phenol type curing agent; (D) one or more resins selected from the group consisting of a phenoxy resin, a polyvinyl acetal resin, a polyamide resin, a polyamideimide resin, and mixtures thereof, and having a glass transition temperature of 100° C. or more; and (E) an inorganic filler.
    Type: Grant
    Filed: May 20, 2004
    Date of Patent: February 20, 2007
    Assignee: Ajinomoto Co., Inc.
    Inventors: Shigeo Nakamura, Kenji Kawai
  • Patent number: 7105614
    Abstract: A curable epoxy resin composition comprising at least: (A) a crystalline epoxy resin, (B) a phenol resin, and (C) a silicone resin composed of epoxy-containing organic groups and phenyl groups that define an average unit formula of this component. Component (C) is used in an amount of 0.1 to 500 parts by weight for 100 parts by weight of the sum of weights of components (A) and (B). The composition of the invention is suitable for transfer and injection molding and may find use as a curable epoxy resin composition for sealing parts of electrical and electronic devices.
    Type: Grant
    Filed: June 28, 2002
    Date of Patent: September 12, 2006
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Yoshitsugu Morita, Hiroshi Ueki, Koji Nakanishi, Haruhiko Furukawa
  • Patent number: 7098276
    Abstract: An epoxy resin composition which can be used as a semiconductor encapsulating resin and in which the improvement of flame retardancy can be attained by suitably adapting a crosslinked structure itself of a cured article without using any flame retardant material and without particularly highly filling an inorganic filler. The epoxy resin composition includes an epoxy resin (A), a phenolic resin (B), an inorganic filler (C) and a curing accelerator (D), wherein a flexural modulus E (kgf/mm2) at 240±20% C of a cured article obtained by curing the composition is a value satisfying 0.015 W+4.1?E?0.27 W+21.8 in the case of 30?W<60, or a value satisfying 0.30 W?13?E?3.7 W?184 in the case of 60?W?95 wherein W (wt %) is a content of the inorganic filler (C) in the cured article. The cured article of this composition forms a foamed layer during thermal decomposition or at ignition to exert flame retardancy.
    Type: Grant
    Filed: October 20, 1999
    Date of Patent: August 29, 2006
    Assignees: NEC Corporation, Sumitomo Bakelite Company
    Inventors: Yukihiro Kiuchi, Masatoshi Iji, Katsushi Terajima, Isao Katayama, Yasuo Matsui, Ken Oota
  • Patent number: 7070861
    Abstract: A flame retardant epoxy resin composition containing (A) a phenolic novolak type epoxy resin including a phenolic novolak type epoxy resin of the following formula (1) and/or formula (2) in a total of at least 50 wt %: (wherein, n is 0 or a positive integer) (wherein, n is 0 or a positive integer) (B) a bisphenol type epoxy resin not containing a halogen, (C) an inorganic filler, and (D) an organic flame retardant. A prepreg and a fiber-reinforced composite using this epoxy resin composition.
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: July 4, 2006
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Masato Taguchi, Yasushi Suzumura, Tadayoshi Saitou, Akihiro Itou
  • Patent number: 7064157
    Abstract: The present invention relates to a phosphorus-containing epoxy resin, which is an epoxy resin modified with a side chain having a reactive phosphorus-containing compound. Also, the present invention relates to a flame-retardant resin composition, which comprises: (1) the phosphorus-containing epoxy resin, (2) a halogen-free hardener having a reactive hydrogen capable of reacting with the epoxy group in epoxy resin, and (3) a hardener promoter. The flame-retardant resin composition described above has improved excellent heat resistance and flame retardant property, and is especially suitable for adhesive laminates, composite materials, printed circuit boards, adhesive material for copper foils, and is suitable for IC packaging materials.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: June 20, 2006
    Assignee: Chang Chun Plastics Co., Ltd.
    Inventors: Kuen Yuan Hwang, Hong-Hsing Chen, An Pang Tu, Huan-Chang Chao
  • Patent number: 7056978
    Abstract: A curable underfill encapsulant composition which is especially useful in the no-flow underfill encapsulation process. The composition contains an epoxy resin, a fluxing agent, a linear polyanhydride, a core shell polymer and a catalyst. In an alternative embodiment, the composition also contains a linear anhydride. Various additives, such as surfactants and coupling agents may also be added to the composition.
    Type: Grant
    Filed: November 6, 2002
    Date of Patent: June 6, 2006
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Jayesh P. Shah
  • Patent number: 7037586
    Abstract: The present invention relates to a film for a circuit board characterized in that the following A layer is adjacent to the following B layer is disclosed in the present application. A circuit board excellent in adhesion strength of a conductor layer can easily be produced by using this film. A layer: a heat-resistant resin layer with a thickness of from 2 to 250 ?m which layer is made of a heat-resistant resin having a glass transition point of 200° C. or more or a decomposition temperature of 300° C. or more, and B layer: a roughenable cured resin layer with a thickness of from 5 to 20 ?m which layer is made of a cured product of a thermosetting resin composition containing at least component (a) of an epoxy resin having two or more epoxy groups in a molecule and component (b) of an epoxy curing agent, the cured product being capable of roughening with an oxidizing agent.
    Type: Grant
    Filed: January 12, 2004
    Date of Patent: May 2, 2006
    Assignee: Ajinomoto Co., Inc.
    Inventors: Tadahiko Yokota, Shigeo Nakamura
  • Patent number: 7009008
    Abstract: A casting resin compound as an assembly and encapsulation material for electronic and optoelectronic component parts, modules and components, for example for casting out optoelectronic components on the basis of acid anhydride-curable epoxy compounds, particularly bisphenol A-diglycidyl ether, contains multi-functional epoxy novolak resins, particularly an epoxy cresol novolak. This casting resin compound exhibits a clearly increased glass transition temperature, is suitable for mass-production, exhibits no health deteriorations, and supplies SMT-capable products that can be utilized in the automotive sector.
    Type: Grant
    Filed: August 4, 2000
    Date of Patent: March 7, 2006
    Assignee: Osram GmbH
    Inventors: Klaus Höhn, Günter Waitl, Karlheinz Arndt
  • Patent number: 7005185
    Abstract: An epoxy composition includes an epoxy resin, a latent curing agent, and a catalyst. The composition includes two epoxide groups per molecule, and the latent curing agent is preferably a dicyanopolyamide, and most preferably dicyandiamide. The catalyst includes 2,4-toluene bis dimethyl urea, preferably in a concentration exceeding 70% by weight. The composition can be used in prepregs. The relative concentrations of the epoxy resin, curing agent, and catalyst are selected to achieve desired properties, including specific curing times and temperatures, and glass transition temperatures that enable a cured resin composition to be removed from a mold after being heated to its curing temperature, without being cooled. Exemplary formulations have reduced cure times, at both high and low curing temperatures, as compared to prior art formulations.
    Type: Grant
    Filed: November 27, 2002
    Date of Patent: February 28, 2006
    Assignee: Toray Composites (America), Inc.
    Inventors: Wei (Helen) Li, Kishio Miwa
  • Patent number: 6955739
    Abstract: The invention provides a method for adhering two substrates comprising: providing an adhesive film having a first surface and a second surface; irradiating the adhesive film with ultraviolet radiation to provide an activated adhesive film having a first activated surface and a second activated surface; cooling the activated adhesive film either while irradiating or immediately after irradiating the film; contacting the first activated surface with a first substrate; contacting the second activated surface with a second substrate; and applying heat and pressure to the first and second substrates to cure the activated adhesive film and to bond the substrates to one another.
    Type: Grant
    Filed: May 24, 2002
    Date of Patent: October 18, 2005
    Assignee: 3M Innovative Properties Company
    Inventors: Hiroaki Yamaguchi, Tetsu Kitamura
  • Patent number: 6936664
    Abstract: The present invention discloses reworkable epoxy compositions suitable for encapsulation of and underfill for electronic components comprising (a) a curable epoxy component which is the reaction product of an epoxidized 1-alkenyl ether or 1-cycloalkenyl ether and a polycarboxylic acid, the reaction product being substantially free of unreacted acid or acid impurities; and (b) a curing agent for the epoxy component, wherein the reaction products of the epoxy composition are reworkable. The cured epoxy compositions of this invention contain thermally labile weak ?-alkoxy ester linkages which provide for the reworkable aspect of the invention.
    Type: Grant
    Filed: October 4, 2001
    Date of Patent: August 30, 2005
    Assignee: Henkel Corporation
    Inventors: John G. Woods, Susanne D. Morrill, Jianzhao Wang, Brendan J. Kneafsey
  • Patent number: 6919420
    Abstract: Reworkable thermoset acid-cleavable acetal and ketal based epoxy oligomers can be B-staged into a tack free state. Compositions containing the epoxy oligomers are employed in a reworkable assembly such as a wafer-level underfilled microelectronic package.
    Type: Grant
    Filed: December 5, 2002
    Date of Patent: July 19, 2005
    Assignee: International Business Machines Corporation
    Inventors: Stephen Leslie Buchwalter, Claudius Feger, Gareth Hougham, Nancy LaBianca, Hosadurga Shobha
  • Patent number: 6902689
    Abstract: The invention encompasses epoxies, epoxy systems, and methods of forming conductive adhesive connections between electrical nodes. An epoxy contains: a) a liquid mixture of a hardener and a base epoxy; and b) a concentration of an ionic salt within the liquid mixture, the concentration of the ionic salt being high enough that a 15 mil length sample of the liquid mixture having cross-sectional dimensions of 50 mil by 2 mil would have a resistance of less than about 100 ohms along its length.
    Type: Grant
    Filed: April 26, 2001
    Date of Patent: June 7, 2005
    Assignee: Micron Technology, Inc.
    Inventors: Rickie C. Lake, Krishna Kumar
  • Patent number: 6881769
    Abstract: Matting agent for thermally curable systems, especially for powder coating compositions, that comprise at least, one carboxyl-containing polymer as binder and at least one epoxy-group-containing compound as cross-linking agent, wherein the matting agent comprises at least the following constituents: (a) a metal salt or a metal complex of an organic compound, the metal being selected from the group magnesium, calcium, strontium, barium, zinc, aluminium, tin and antimony, and (b) a polymerisation product of monomers, the monomers including epoxy-group-containing monomers and the epoxy value of the polymerisation product being from 0.1 to 8 equivalents of epoxy groups, and overall the ratio of epoxy equivalents of component (b) to metal equivalents of component (a) being from 0.2 to 120.
    Type: Grant
    Filed: March 7, 2000
    Date of Patent: April 19, 2005
    Assignee: Huntsman Advanced Materials Americas Inc.
    Inventors: Carmelina Grob, Christoph Rickert, Daniel Künzi
  • Patent number: 6881768
    Abstract: A tile grout composition and method of using the tile grout composition to grout set tiles are provided. The tile grout composition is a water-based epoxy grout composition which has excellent stain and chemical resistant properties and is workable and easy to clean up after grouting the tiles. The grout composition employs a water dispersible epoxy polymer and a water compatible polyamine epoxy resin adduct as the curing agent in combination with a water repellent component. For colored grouts, a color coated filler such as sand is employed to obtain the enhanced tile grout properties. Luminescent and fluorescent additives and sparkle additives may be used in the grout to provide special visual effects in the light or dark.
    Type: Grant
    Filed: January 9, 2003
    Date of Patent: April 19, 2005
    Assignee: Laticrete International, Inc.
    Inventor: Rezvan Rooshenas
  • Patent number: 6844379
    Abstract: Compositions having high moisture resistance and flexibility comprise an organic component and a filler. The organic component comprises a long-chain cycloaliphatic epoxy resin, a short-chain cycloaliphatic epoxy resin, a cyanate ester, and a Lewis acid catalyst. Preferably the organic component further comprises a Bronsted acid co-catalyst and/or a flexibilizing modifier. The compositions are useful in various semiconductor applications, including as die attach adhesives, underfills, encapsulants, via fills, prepreg binders, polymer solder masks and polymer bumps on flip chip or BGA assemblies.
    Type: Grant
    Filed: November 19, 2002
    Date of Patent: January 18, 2005
    Assignee: Honeywell International Inc.
    Inventors: Xiao-Qi Zhou, Henry Wevick, Nancy Iwamoto, Shao Wei Li, Alan Grieve
  • Patent number: 6805958
    Abstract: The present invention provides an epoxy resin composition containing (A) an epoxy resin having two or more epoxy groups in one molecule, (B) a phenolic curing agent, (C) a phenoxy resin containing a bisphenol S skeleton and having a weight average molecular weight of 5,000 to 100,000, and (D) a curing accelerator, wherein the epoxy resin (A) contains a phosphorus atom, and wherein 5 to 50 parts by weight of the phenoxy resin (C) and 0.05 to 10 parts by weight of the curing accelerator (D) are mixed with 100 parts by weight in total of the epoxy resin (A) and the phenolic curing agent (B).
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: October 19, 2004
    Assignee: Ajinomoto Co., Inc.
    Inventors: Shigeo Nakamura, Tadahiko Yokota
  • Patent number: 6770965
    Abstract: A wiring substrate includes (1) an insulating substrate having an opening, or a core substrate and a build-up layer wherein at least one of the core substrate and the build-up layer has an opening, (2) at least one electronic part disposed in the opening, and (3) an embedding resin comprising a thermoplastic resin, an acid anhydride curing agent, a curing accelerator, and a filler, wherein the embedding resin shows a viscosity of not higher than 85 Pa·s in a shear rate of 8.4 s−1 after allowing to stand for 24 hours at 25° C.±1° C.
    Type: Grant
    Filed: December 27, 2001
    Date of Patent: August 3, 2004
    Assignee: NGK Spark Plug Co., Ltd.
    Inventors: Hiroki Takeuchi, Toshifumi Kojima, Kazushige Ohbayashi, Hisahito Kashima
  • Patent number: 6686402
    Abstract: This invention relates to foundry binder systems, which will cure in the presence of sulfur dioxide and a free radical initiator, comprising (a) an epoxy novolac resin; (b) preferably a bisphenol F; (c) an acrylate; and (d) an effective amount of a free radical initiator. The foundry binder systems are used for making foundry mixes. The foundry mixes are used to make foundry shapes (such as cores and molds) which are used to make metal castings.
    Type: Grant
    Filed: September 27, 2001
    Date of Patent: February 3, 2004
    Assignee: Ashland Inc.
    Inventors: Wayne D. Woodson, H. Randall Shriver
  • Patent number: 6684936
    Abstract: This invention relates to erosion resistant foundry binder systems, which will cure in the presence of sulfur dioxide and a free radical initiator, comprising (a) an epoxy resin; (b) a multifunctonal acrylate; (c) a phenolic resin that is soluble in (a) and (b); and (d) an effective amount of a free radical initiator. The foundry binder systems are used for making foundry mixes. The foundry mixes are used to make foundry shapes (such as cores and molds) which are used to make metal castings.
    Type: Grant
    Filed: April 10, 2002
    Date of Patent: February 3, 2004
    Assignee: Ashland Inc.
    Inventors: Wayne D. Woodson, James J. Archibald, H. Randall Shriver
  • Patent number: 6620510
    Abstract: An epoxy resin composition giving a cured resin plate which, after 60 hour standing at 150° C. and at the saturated vapor pressure, has a water absorption of 3.5% by weight or lower; a prepreg which comprises the epoxy resin composition and reinforcing fibers; and a fiber-reinforced resin roll which is 1) a laminate comprising fiber-reinforced resin layers each comprising reinforcing fibers and a matrix resin, wherein the matrix resin is a resin composition giving a cured resin plate which, after 60 hour standing at 150° C. and at the saturated vapor pressure, has a water absorption of 3.5% by weight or lower; or 2) a laminate comprising (i) at least one fiber-reinforced resin layer comprising long reinforcing fibers having an elastic modulus of 600˜800 Gpa and a resin composition and (ii) at least one fiber-reinforced resin layer comprising long reinforcing fibers having an elastic modulus of 140˜300 Gpa and a resin composition.
    Type: Grant
    Filed: June 25, 2001
    Date of Patent: September 16, 2003
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Masato Taguchi, Hisao Koba, Yutaka Yamaguchi
  • Patent number: 6613438
    Abstract: The invention relates to a one-component epoxy resin adhesive which is elasticated with silicone rubber and whose open joint time is adaptable to whichever production process it is being used in by the concentration of UV initiator and/or the duration and/or intensity of UV activation and which is therefore particularly suitable for automatable manufacturing processes, since the workpieces after initial fixing require no additional mounts even during thermal aftercuring. This adhesive is preferentially suitable for the extensive adhesive bonding of permanent magnets, such as in the assembly of a permasyn motor, for example.
    Type: Grant
    Filed: July 26, 2001
    Date of Patent: September 2, 2003
    Assignee: Siemens Aktiengesellschaft
    Inventors: Peter Hein, Winfried Plundrich, Ralf Wilcke, Ernst Wipfelder
  • Patent number: 6607825
    Abstract: As a technique capable of stably providing various metal film adhered bodies for printed circuit boards having an excellent peel strength even in the wiring having higher density and higher pattern accuracy and other industrial parts, there are provided adhesive, adhesive layer and metal film adhered body in which a mixed resin consisting of a thermoplastic resin and an uncured thermosetting resin including a resin substituted at a part of its functional group with a photosensitive group and/or an uncured photosensitive resin is used as a heat-resistant resin matrix constituting the adhesive and further a cured homogeneous resin composite forming a quasi-homogeneous compatible structure, co-continuous phase structure or spherical domain structure is used as a heat-resistant resin matrix of the adhesive layer.
    Type: Grant
    Filed: August 22, 1997
    Date of Patent: August 19, 2003
    Assignee: Ibiden Co., Ltd.
    Inventors: Dong Dong Wang, Motoo Asai
  • Publication number: 20030125422
    Abstract: A method for manufacture of particles for powder coating is disclosed in which the particles are prepared from a suspension obtained from a mixture of a thermosetting resin solution and an aqueous solution containing a water-soluble polymer.
    Type: Application
    Filed: November 15, 2002
    Publication date: July 3, 2003
    Applicant: Nippon Paint Co., Ltd.
    Inventors: Haruhiko Satoh, Yutaka Harada, Atsushi Yamada
  • Patent number: 6518331
    Abstract: A multilayer printed circuit board having resinous insulating layers and conductor layers alternately superposed on a circuit board with ample adhesive strength, a method for the production thereof, and a curable resin composition useful for the formation of resinous insulating layers are disclosed. The manufacture of the multilayer printed circuit board is accomplished by applying the curable resin composition to the surface of conductor layer of the circuit board, thermally curing the applied layer thereby forming resinous insulating layer, then boring a through-hole in the circuit board, treating the resinous insulating layer with a coarsening agent thereby imparting undulating coarsened surface thereto, subsequently coating the surface of resinous insulating layer and the inner surface of the through-hole with a conductor layer as by electroless plating, and thereafter forming a prescribed circuit pattern in the conductor layer.
    Type: Grant
    Filed: December 5, 2000
    Date of Patent: February 11, 2003
    Assignee: Taiyo Ink Manufacturing Co., Ltd.
    Inventors: Akio Sekimoto, Shinichi Yamada
  • Patent number: 6506820
    Abstract: A method for manufacture of particles for powder coating is disclosed in which the particles are prepared from a suspension obtained from a mixture of a thermosetting resin solution and an aqueous solution containing a water-soluble polymer. The thermosetting resin solution contains A resin, B resin and an organic solvent wherein: (a) 0.5≦{(SP value of the A resin)−(SP value of the B resin)}≧1.5; (b) {(Tg of the A resin)−(Tg of the B resin)}≧10° C.; (C) 40° C.≦(Tg of the A resin)≦100° C., and, 20° C.≦(Tg of the B resin)≦50° C.; and (d) 5/95≦(a ratio in solids weight of the A resin to B resin)≦50/50.
    Type: Grant
    Filed: April 14, 1999
    Date of Patent: January 14, 2003
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Haruhiko Satoh, Yutaka Harada, Atsushi Yamada
  • Patent number: 6492483
    Abstract: The present invention discloses a continuous process and the associated system for upstaging liquid epoxy resins to produce resins with higher molecular weight. The process comprises passing continuously (i) a liquid epoxy resin having a first molecular weight, (ii) a catalyst and (iii) a compound having at least one active hydrogen or reactive functional group capable of reacting with the liquid epoxy resin in the presence of the catalyst, flow through one or more reaction chambers and under conditions effective to produce a stream comprising an upstaged epoxy resin product having a second molecular weight. The second molecular weight is higher than the first molecular weight.
    Type: Grant
    Filed: December 21, 1999
    Date of Patent: December 10, 2002
    Assignee: Resolution Performance Products LLC
    Inventors: Simon Ming-Kung Li, Harry Frank, Rupert R. Dominguez
  • Patent number: 6489380
    Abstract: Compositions having high moisture resistance and flexibility comprise an organic component and a filler. The organic component comprises a long-chain cycloaliphatic epoxy resin, a short-chain cycloaliphatic epoxy resin, a cyanate ester, and a Lewis acid catalyst. Preferably the organic component further comprises a Bronsted acid co-catalyst and/or a flexibilizing modifier. The compositions are useful in various semiconductor applications, including as die attach adhesives, underfills, encapsulants, via fills, prepreg binders, polymer solder masks and polymer bumps on flip chip or BGA assemblies.
    Type: Grant
    Filed: April 27, 2000
    Date of Patent: December 3, 2002
    Assignee: Johnson Matthey Electronics, Inc.
    Inventors: Xiao-Qi Zhou, Henry Wevick, Nancy E. Iwamoto, Shao Wei Li, Alan Grieve
  • Patent number: 6489042
    Abstract: An electronic circuit device comprising at least one substrate having a photoimageable covercoat, comprising at least 95 weight percent of at least one epoxy-modified aromatic vinyl-conjugated diene block copolymer and a catalyst comprising an onium salt selected from a triarylsulfonium salt and a diaryliodonium salt, wherein the covercoat is formed by solvent coating or extrusion and then heat laminated onto at least a portion of the substrate.
    Type: Grant
    Filed: October 18, 2001
    Date of Patent: December 3, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Ronald L. Imken, Robert S. Clough
  • Patent number: 6486235
    Abstract: A halogen-tree, flame-retardant insulating epoxy resin composition which comprises (1) an epoxy resin, (2) a curing agent for the epoxy resin, (3) a phosphate of a resorcinol type, (4) aluminum hydroxide, and (5) a cure accelerator for the epoxy resin. The composition displays necessary flame retardant properties and sufficient insulating properties after the formation of an insulating layer in a circuit board, withstands a plating process, and does not cause the bleedout of the insulation layer formed. A circuit board with flame retardant properties comprising insulation layers formed of the epoxy resin composition is also disclosed.
    Type: Grant
    Filed: December 7, 2000
    Date of Patent: November 26, 2002
    Assignee: Fujitsu Limited
    Inventors: Nawalage Florence Cooray, Koji Tsukamoto, Takeshi Ishitsuka
  • Patent number: 6469074
    Abstract: Disclosed is a liquid epoxy resin composition for sealing a semiconductor device which comprises (A) a cyanic acid ester, (B) an epoxy resin, (C) an inorganic filler, (D) a metal chelate and/or a metal salt, and at least one of (E1) an acid anhydride, (E2) a dihydrazide compound and (F) a silicone resin gel, wherein at least one of components A and B is liquid at room temperature, component E1 is liquid at room temperature, and the weight ratio of component C to the total weight of the composition, the weight ratio of component A to component B, and the weight ratio of component E1, E2 or F to the total weight of the composition except component C each ranges a specific ratio.
    Type: Grant
    Filed: May 25, 2000
    Date of Patent: October 22, 2002
    Assignee: Matsushita Electric Works, Ltd.
    Inventors: Hirohisa Hino, Taro Fukui, Kenji Kitamura, Shinji Hashimoto, Naoki Kanagawa
  • Patent number: 6458917
    Abstract: An optical resin prepared by curing a polymerizable composition comprising a (thio)epoxy compound having at least one intramolecular disulfide bond exhibits a considerably high refractive index while maintaining good optical properties and a high Abbe number. In addition, the above polymerizable composition to which is added primary and/or secondary amines as an yellowing inhibitor in a proportion of 0.001 to 0.5 of the total molar number of NH2 and NH groups in the amines to the total molar number of thioepoxy and epoxy groups in the (thio)epoxy compound having at least one intramolecular disulfide bond, can provide a transparent resin in which yellowing and reduction in heat resistance associated therewith are adequately prevented while maintaining a high refractive index.
    Type: Grant
    Filed: August 1, 2001
    Date of Patent: October 1, 2002
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hiroyuki Morijiri, Seiichi Kobayashi, Koju Okazaki, Chitoshi Shimakawa, Akinori Ryu, Yoshinobu Kanemura
  • Patent number: 6459358
    Abstract: A current limiting PTC device (10) has two electrodes (14) with a thin film of electric conducting polymer material (20) disposed between the electrodes, the polymer material (20) having superior flexibility and short circuit performance, where the polymer material contains short chain aliphatic diepoxide, conductive filler particles, curing agent, and, preferably, a minor amount of bisphenol A epoxy resin.
    Type: Grant
    Filed: September 27, 1999
    Date of Patent: October 1, 2002
    Assignee: Eaton Corporation
    Inventors: John Joseph Shea, Miomir B. Djordjevic, William Kingston Hanna
  • Patent number: 6423367
    Abstract: An electronic circuit device comprises a resin composition including 90 to 100 weight percent of a curable epoxy-modified aromatic vinyl-conjugated diene block copolymer, optionally up to 10 weight percent of an epoxy resin, and an effective amount of an epoxy curative, the weight percent of the copolymer and epoxy resin being based on the weight of the epoxy bearing material exclusive of curative. The resin composition can be used as an electronic adhesive, covercoat, or encapsulant. The electronic circuit device exhibits superior heat and moisture insensitivity, including the absence of voiding and delamination of the cured resin compostion from its substrate under conditions of 85° C. and 85% relative humidity for 168 hours followed by a temperature of 220° C. for 10 to 40 seconds.
    Type: Grant
    Filed: July 27, 2001
    Date of Patent: July 23, 2002
    Assignee: 3M Innovative Properties Company
    Inventor: Robert Steven Clough
  • Patent number: 6417322
    Abstract: The room temperature polymerizable composition comprises at least one polymerizable monomer having at least one episulfide functionality and an effective amount of at least one (alkoxyphenyl)phosphine polymerization catalyst.
    Type: Grant
    Filed: September 25, 2000
    Date of Patent: July 9, 2002
    Assignee: Essilor International Compagnie General d'Optique
    Inventors: Aref Ben Ahmed Jallouli, Gabriel Keita, Steven Weber, Yassin Turshani
  • Patent number: 5150841
    Abstract: A battery operated hand-held dispenser which operates efficiently at lower power levels than prior art devices. The dispenser as included therein has spray, foam or stream, dispensing capabilities coupled with pump mechanisms, vent mechanisms and positive closures.
    Type: Grant
    Filed: May 23, 1991
    Date of Patent: September 29, 1992
    Assignee: DowBrands Inc.
    Inventors: Scott A. Silvenis, Paul B. Monaghan, Arthur A. Massucco, Richard H. Spencer, William R. Gagne