Process Of Forming A Composition Of An Ethylenically Unsaturated Reactant Or Ethylenically Unsaturated Polymer Admixed With Nonreactive Material (nrm) And A Polyester Whose Polymer Backbone Was Derived Through The Direct Formation Of The Ester Linkage, E.g., Polyethylene Terephthalate, Polycaprolactone, Etc., Or Product Thereof Patents (Class 523/500)
  • Publication number: 20080233395
    Abstract: Artificial polyester hair, which retains fiber physical properties of general polyester fibers such as heat resistance and a degree of strength and elongation, are excellent in the setting property, transparency and touch feeling, and has excellent flame retardancy, is provided. The flame retardant artificial polyester hair, which retains fiber properties such as heat resistance and a degree of strength and elongation and is excellent in suitability for setting, transparency and touch feeling, is characterized by being obtained by melt-spinning a composition obtained by melt-kneading a polyester together with a bromine-containing flame retardant, the bromine-containing flame retardant having a melting point of 160 to 320° C. and a 5% loss on heat temperature of 220 to 450° C. or the bromine-containing flame retardant being a mixture of a bromine-containing flame retardant (b1) having a 5% loss on heat temperature of 220 to 310° C.
    Type: Application
    Filed: March 18, 2005
    Publication date: September 25, 2008
    Applicant: KANEKA CORPORATION
    Inventor: Toshiyuki Masuda
  • Publication number: 20080214701
    Abstract: Use of thermoplastic molding compositions comprising A) from 10 to 99.9% by weight of polyethylene terephthalate, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type; where x is at least 1.1 and y is at least 2.1, or a mixture of these C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%, for production of fibers or of liquid containers.
    Type: Application
    Filed: July 13, 2006
    Publication date: September 4, 2008
    Applicant: BASF Aktiengesellschaft
    Inventors: Axel Wilms, Bernd Bruchmann, Andreas Eipper, Joachim Strauch
  • Patent number: 7256223
    Abstract: Polymeric materials and products, including sheet flooring materials prepared from the polymeric materials, and processes for preparing the polymeric materials, are disclosed. The polymeric materials include a polylactic acid-based polymer in combination with plasticizer and a compatibilizer, and optionally include a filler. The polymeric material can include between about 30 to about 50 percent by weight polyvinyl chloride, polyethylene glycol, polyglycolide, ethylene vinyl acetate, polycarbonate, polycaprolactone, polyhydroxyalkanoates, or polyolefins modified with polar groups, for example, ionomers. The plasticizer is typically an epoxidized vegetable oil or esterified and epoxidized vegetable oil and is typically present in an amount of between about 10 and about 50% by weight. In some embodiments, the compatibilizer is a polyolefin modified with one or more polar functional groups, and is typically present in an amount of between about 5 and about 10% by weight.
    Type: Grant
    Filed: January 10, 2005
    Date of Patent: August 14, 2007
    Assignee: Michigan State University, Board of Trustees
    Inventors: Amar K. Mohanty, Lawrence T. Drzal, Brian P. Rook, Manjusri Misra
  • Patent number: 7238842
    Abstract: A mutant hydrolase optionally fused to a protein of interest is provided. The mutant hydrolase is capable of forming a bond with a substrate for the corresponding nonmutant (wild-type) hydrolase which is more stable than the bond formed between the wild-type hydrolase and the substrate. Substrates for hydrolases comprising one or more functional groups are also provided, as well as methods of using the mutant hydrolase and the substrates of the invention. Also provided is a fusion protein capable of forming a stable bond with a substrate and cells which express the fusion protein.
    Type: Grant
    Filed: January 30, 2004
    Date of Patent: July 3, 2007
    Assignee: Promega Corporation
    Inventors: Keith V. Wood, Dieter Klaubert, Georgyi V. Los, Robert F. Bulleit, Mark McDougall, Chad Zimprich
  • Patent number: 7157505
    Abstract: Novel, rapidly drying, low volatile organic compound (VOC), minimal dot gain coatings, (including lithographic ink and varnish systems) are herein described. These systems dry sufficiently rapidly, that their usage eliminates ink drying speed as the rate limiting factor in most lithographic printing applications. In addition to providing enhanced drying rates as compared with their conventional counterparts, the rapid drying, low/no VOC lithographic coating systems of the instant invention can provide the user with significant improvement in dried film rub resistance.
    Type: Grant
    Filed: September 3, 2003
    Date of Patent: January 2, 2007
    Assignee: Vocfree, Inc.
    Inventor: Gerald Sugerman
  • Patent number: 6916936
    Abstract: A method is provided for carrying out depolymerization of a polymer containing electrophilic linkages in the presence of a catalyst and a nucleophilic reagent, wherein production of undesirable byproducts resulting from polymer degradation is minimized. The reaction can be carried out at a temperature of 80° C. or less, and generally involves the use of an organic, nonmetallic catalyst, thereby ensuring that the depolymerization product(s) are substantially free of metal contaminants. In an exemplary depolymerization method, the catalyst is a carbene compound such as an N-heterocyclic carbene, or is a precursor to a carbene compound. The method provides an important alternative to current recycling techniques such as those used in the degradation of polyesters, polyamides, and the like.
    Type: Grant
    Filed: January 30, 2003
    Date of Patent: July 12, 2005
    Assignee: International Business Machines Corporation
    Inventors: James Lupton Hedrick, Pinar Kilickiran, Gregory Walker Nyce, Robert M. Waymouth
  • Patent number: 6911546
    Abstract: A method is provided for carrying out depolymerization of a polymer containing electrophilic linkages in the presence of a catalyst and a nucleophilic reagent, wherein production of undesirable byproducts resulting from polymer degradation is minimized. The reaction can be carried out at a temperature of 80° C. or less, and generally involves the use of an organic, nonmetallic catalyst, thereby ensuring that the depolymerization product(s) are substantially free of metal contaminants. In an exemplary depolymerization method, the catalyst is a carbene compound such as an N-heterocyclic carbene, or is a precursor to a carbene compound. The method provides an important alternative to current recycling techniques such as those used in the degradation of polyesters, polyamides, and the like.
    Type: Grant
    Filed: December 26, 2002
    Date of Patent: June 28, 2005
    Assignee: International Business Machines Corporation
    Inventors: James Lupton Hedrick, Pinar Kilickiran, Gregory Walker Nyce, Robert M. Waymouth
  • Patent number: 6869985
    Abstract: Polymeric materials and products, including sheet flooring materials prepared from the polymeric materials, and processes for preparing the polymeric materials, are disclosed. The polymeric materials include a polylactic acid-based polymer in combination with plasticizer and a compatibilizer, and optionally include a filler. The polymeric material can include between about 30 to about 50 percent by weight polyvinyl chloride, polyethylene glycol, polyglycolide, ethylene vinyl acetate, polycarbonate, polycaprolactone, polyhydroxyalkanoates, or polyolefins modified with polar groups, for example, ionomers. The plasticizer is typically an epoxidized vegetable oil or esterified and epoxidized vegetable oil and is typically present in an amount of between about 10 and about 50% by weight. In some embodiments, the compatibilizer is a polyolefin modified with one or more polar functional groups, and is typically present in an amount of between about 5 and about 10% by weight.
    Type: Grant
    Filed: November 26, 2002
    Date of Patent: March 22, 2005
    Assignee: AWI Licensing Company
    Inventors: Amar Kumar Mohanty, Lawrence T. Drzal, Brian P. Rook, Manjusri Misra
  • Publication number: 20040238556
    Abstract: Flexible filler for filling cracks, gaps or holes in masonry or a rendered finish on masonry, comprising a mixture of an acrylic caulk bulked up with a finely divided particulate material of a size to match the roughness of the surface around the crack gap or hole to be filled. The caulk and particulate material are mixed thoroughly to form a homogeneous mixture which is packed into a cylindrical cartridge having a nozzle through which the mixture can be forced when needed.
    Type: Application
    Filed: March 12, 2004
    Publication date: December 2, 2004
    Inventor: Kevin Griff George
  • Publication number: 20040209094
    Abstract: A conformable oriented polymeric film comprising a layer of copolyester derived from: (i) one or more diol(s); (ii) an aromatic dicarboxylic acid; and (iii) one or more aliphatic dicarboxylic acid(s) of the general formula CnH2n(COOH)2 wherein n is 2 to 8, wherein the aromatic dicarboxylic acid is present in the copolyester in an amount of from 60 to 85 mole % based on the total amount of dicarboxylic acid components in the copolyester, wherein the copolyester is a random or alternating copolyester, and wherein after deformation by subjecting and maintaining the film to 7% strain, the stress within the film immediately after deformation dissipates to a residual value of less than 60% of the original value within 10 minutes of said deformation; and use thereof as a conformable medium for signage, advertising, graphic art and other display applications or as an overlaminate for such media.
    Type: Application
    Filed: June 9, 2004
    Publication date: October 21, 2004
    Inventor: Duncan Henry MacKerron
  • Patent number: 6803393
    Abstract: Multicomponent system curable thermally and with actinic radiation, comprising A) an isocyanate-reactive binder comprising A1) at least one unsaturated polyester whose molecule contains on average at least one group that can be activated with actinic radiation, of the formulae I, II and/or III wherein n is an integer from 1 to 10; and A2) at least one binder, different than (A1), whose molecule comprises on average at least two isocyanate-reactive functional groups, and/or A3) at least one binder, different than (A1), whose molecule comprises on average at least one isocyanate-reactive functional group and at least one reactive functional group having at least one bond that can be activated with actinic radiation, and B) a crosslinker comprising B1) at least one polyisocyanate and/or B2) at least one polyisocyanate whose molecule comprises on average at least one reactive functional group having at least one bond that can be activated with actinic radiation.
    Type: Grant
    Filed: December 11, 2002
    Date of Patent: October 12, 2004
    Assignee: BASF Coatings AG
    Inventors: Rainer Blum, Maxime Allard
  • Publication number: 20040176503
    Abstract: The present invention provides a compound and process for manufacturing thickened sheet-molding compounds wherein a thermoset molding resin is partially crosslinked by irradiation with high-energy electrons. In this process, the structure of the resin is changed from a viscous liquid to a viscoelastic gel, which acts like a thickened molding compound.
    Type: Application
    Filed: December 2, 2003
    Publication date: September 9, 2004
    Applicant: Kent State University
    Inventors: Michael A. Czayka, Carlos Vargas-Aburto, Roberto M. Uribe
  • Patent number: 6780942
    Abstract: The present invention relates to a method of forming porous particles comprising preparing a mixture of an organic phase and an aqueous phase comprising an unsaturated polyester, a water immiscible organic solvent, at least one organic-soluble ethylenically unsaturated monomer, and initiator, subjecting said mixture to high energy emulsification, initiating crosslinking of said polyester after emulsification, removing said water immiscible organic solvent to recover porous polyester particles.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: August 24, 2004
    Assignee: Eastman Kodak Company
    Inventors: Jeffrey W. Leon, Jeanne E. Kaeding, Robert E. Mccovick
  • Patent number: 6780923
    Abstract: A molding compound contains a reinforcing fiber, a non-fibrous filler, and an unsaturated polyester resin. The unsaturated polyester resin contains an unsaturated monomer as well as a polyester polymer. The polymer is a unsaturated polyester made from a hydroxyl component and a carboxylic component. The hydroxyl component contains both a monomeric diol or triol, and a polymeric polyol. The polymeric polyol is a hydroxyl-terminated polymer such as polyether or polyester diols or triols. The carboxylic component can be provided by an unsaturated carboxylic diacid, an unsaturated carboxylic anhydride, an unsaturated carboxylic diester or mixtures thereof. Molded articles are provided by compression or extrusion molding of a molding compound as described above. The articles are characterized by improved crack resistance, toughness, and surface appearance.
    Type: Grant
    Filed: November 8, 2001
    Date of Patent: August 24, 2004
    Assignee: ThyssenKrupp Budd Company
    Inventors: Probir K. Guha, Michael J. Siwajek, Robert C. Yen
  • Patent number: 6774193
    Abstract: Stabilized pre-promoted unsaturated polymer resin systems that include a tertiary aromatic amine cure promoter. The stabilized curable resins systems can include a vinyl ester resin.
    Type: Grant
    Filed: July 17, 2002
    Date of Patent: August 10, 2004
    Assignees: Albemarle Corporation, The University of Southern Mississippi
    Inventors: John Gabriel Santobianco, Robson F. Storey, Rajamani Nagarajan
  • Patent number: 6767987
    Abstract: This invention provides a hydroxyalkyl(meth)acrylate composition modified by a small amount of lactones in which a proportion of monomers having two or more continuous chains of lactone is less than 50% (area % by GPC). This invention also provides methods for synthesizing such a composition. This invention also provides an acrylic polyol resin comprising the hydroxyalkyl(meth)acrylate composition, a carboxylic group-containing acrylate composition modified by a small amount of lactones, and a polyester unsaturated monomer modified by a small amount of lactones. Uses of these materials in curable resins, coating compositions, and finishing agents are also provided.
    Type: Grant
    Filed: October 12, 2001
    Date of Patent: July 27, 2004
    Assignee: Daicel Chemical Industries, Ltd.
    Inventor: Akira Okazaki
  • Patent number: 6767971
    Abstract: A molding composition comprising a fibrous material, a crystalline unsaturated polyester, a non-crystalline unsaturated polyester, and a radical generator, and a molded article obtained by molding the molding composition are disclosed.
    Type: Grant
    Filed: August 22, 2000
    Date of Patent: July 27, 2004
    Assignee: Kao Corporation
    Inventors: Takashi Yamaguchi, Kuniyasu Kawabe
  • Publication number: 20040127605
    Abstract: A pressurized paint product that includes an aerosol paint composition disposed in a container. The aerosol paint composition includes volatile organic solvents, an acrylic modified alkyd resin, an acrylic chlorinated polyolefin resin, propellant, and a colorant.
    Type: Application
    Filed: August 8, 2003
    Publication date: July 1, 2004
    Inventor: Patricia L. Redding
  • Patent number: 6740731
    Abstract: The present invention is directed to a method for reducing waste accumulation by using an environmentally degradable disposable material. The disposable material, which includes a hydroxycarboxylic acid-containing polymer, degrades hydrolytically during operative and disposal stages in a controlled manner such that the disposal degradation rate of the material is accelerated relative to the operative degradation rate of the material.
    Type: Grant
    Filed: February 12, 2001
    Date of Patent: May 25, 2004
    Assignee: Cargill Dow Polymers LLC
    Inventors: Donald M. Bigg, Richard G. Sinclair, Edward S. Lipinsky, John H. Litchfield, Billy R. Allen
  • Patent number: 6710106
    Abstract: A molding composition comprising an aggregate [Component (A)], a linear unsaturated polyester [Component (B)] and/or linear unsaturated polyester polyamide [Component (C)], and a radical generator [Component [D]), characterized in that each of Component (B) and Component (C) comprises a specific alkylene oxide adduct of bisphenol A in an amount of from 3 to 50 mol % based on the total amount of constituent monomers of each of Component (B) and Component (C) and a molded article obtained by molding the composition.
    Type: Grant
    Filed: February 2, 2001
    Date of Patent: March 23, 2004
    Assignee: Kao Corporation
    Inventors: Takashi Yamaguchi, Katsutoshi Aoki, Kuniyasu Kawabe
  • Publication number: 20040039087
    Abstract: An unsaturated polyester compound having an ethylenically unsatureated group in its terminal and hydroxymethyl group in its side chain is obtained by the reaction of (a) a compound containing at least two oxetane rings in its molecule with (b) a compound containing at least two carboxyl groups in its molecule and (c) an unsaturated monocarboxylic acid in the presence of a reaction promotor in such a proportion that the ratio of said compound (b) to said compound (a) falls in the range of 0.1<(b)/(a)<1. BY further reacting (d) a polybasic acid anhydride with the resultant unsaturated polyester compound (A′), there is obtained an actinic energy ray-curable resin which is soluble in an aqueous alkaline solution. A photocurable and/or thermosetting composition is obtained by mixing the unsaturated polyester compound (A′) and/or the actinic energy ray-curable resin with a polymerization initiator (B).
    Type: Application
    Filed: August 14, 2003
    Publication date: February 26, 2004
    Inventors: Tadatomi Nishikubo, Atsushi Kameyama, Masaki Sasaki, Masatoshi Kusama
  • Patent number: 6673273
    Abstract: Electrolyte compositions for use in cells and batteries that include a crosslinked solid ionically conductive polymer having urethane groups, urea groups, thiocarbamate groups, or combinations thereof, particles, and a salt. Certain electrolyte compositions include a liquid thereby forming a gel electrolyte composition.
    Type: Grant
    Filed: October 24, 2001
    Date of Patent: January 6, 2004
    Assignee: 3M Innovative Properties Company
    Inventors: Dinh Ba Le, Jerome Edward Scanlan, Ravindra L. Arudi
  • Patent number: 6663969
    Abstract: A heat conductive adhesive film, wherein a magnetic field is applied to a film composition comprising boron nitride powder for orientating and solidifying the boron nitride powder in the composition in a given direction, an manufacturing method thereof, and an electronic component, characterized by that a heat radiating element and a heat conductive member are adhered by a heat conductive adhesive film wherein boron nitride powder is orientated in a given direction, presenting a high heat conductivity, an excellent heat radiation, and a good electric insulation and a high peeling-off strength.
    Type: Grant
    Filed: August 2, 2001
    Date of Patent: December 16, 2003
    Assignee: Polymatech Co., Ltd.
    Inventors: Tobita Masayuki, Shinya Tateda, Tsuneh isa Kimura, Masahumi Yamato
  • Patent number: 6664316
    Abstract: A cross-linkable polyester resin composition for use with a reinforcing element for reinforcing rock and other structures, comprises: (a) from 10 to 45% of a cross-linkable unsaturated polyester resin, (b) from 40 to 90% of a filter and (c) from 1 to 15% of an ethylenically unsaturated monomer copolymerizable with the polyester, the percentages being by weight based on the total weight of (a), (b) and (c), the composition being solid but permitting insertion and rotation of a reinforcing element to cause mixing of the composition with a cross-linking catalyst to form a hard mass. Composition will cold cure when mixed with catalyst preferably the monomer has higher flash point than styrene. Advantage of the solid composition is that it does not need to be enclosed within frangible sheath as in the prior art.
    Type: Grant
    Filed: January 16, 1998
    Date of Patent: December 16, 2003
    Assignee: Fosroc Mining International Limited
    Inventor: Duncan Hywel-Evans
  • Publication number: 20030104743
    Abstract: A molding composition including reactive high-volatility monomeric groups, such as acrylics, at least one primary thermal initiator and at least one secondary thermal initiator is described. Molding process using molding compositions including reactive high-volatility monomeric groups are also described.
    Type: Application
    Filed: June 26, 2002
    Publication date: June 5, 2003
    Inventors: Rolf Thomas Weberg, Lawrence J. Simmons, Richard Reid Gleason
  • Patent number: 6562902
    Abstract: A thermoplastic molding composition comprises, based on the total of components A to C and, if desired, D and E, which in total give 100% by weight, a) as component A, from 10 to 98% by weight of at least one aromatic polyester, b) as component B, from 1 to 50% by weight of at least one particulate graft copolymer whose soft phase has a glass transition temperature below 0° C.
    Type: Grant
    Filed: March 28, 2001
    Date of Patent: May 13, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Fischer, Manfred Knoll, Christophe Ginss, Stephan Berz
  • Publication number: 20020164480
    Abstract: Electrical cable having at least one conducting element, at least one polyolefin-based insulating covering layer, in which said insulating covering layer has at least one voltage stabilizer, said voltage stabilizer being a benzophenone substituted with at least one group selected from alkyl, arylalkyl and alkylaryl wherein said group: a) is linked to a phenyl ring of the benzophenone directly or via an oxygen bridge (—O—); b) contains, optionally, one or more oxygen bridges (—O—); and c) is optionally linked to a phenyl ring of at least one or other benzophenone group, provided that when said at least one group is an alkyl, optionally substituted, the carbon atom of said alkyl which is directly linked to a phenyl ring of said benzophenone is tertiary. A polyolefin-based insulating composition having at least one voltage stabilizer as described above.
    Type: Application
    Filed: January 25, 2002
    Publication date: November 7, 2002
    Inventors: Luca Martinotto, Franco Peruzzotti, Marcello Del Brenna
  • Patent number: 6384110
    Abstract: A distinctive graft copolymer is made by dissolving an oil-modified polyurethane resin in various vinyl monomers (methyl methacrylate, styrene, etc.). The monomer/oil-modified polyurethane solution is then miniemulsion polymerized to form a latex consisting of submicron particles of polymer with the oil-modified polyurethane grafted onto the polymer backbone. The latex can be applied to a substrate, which on drying forms a polymeric film with good film properties. The latex can be used in a latex paint formulation in place of an acrylate, acetate or styrene-divinyl benzene latex. In this way it is possible to produce water-borne oil-modified polyurethane coatings which combine the properties of an oil-based polyurethane coating with easy application and cleanup. The coating will beneficially lack organic solvent exposure of typical standard oil-modified polyurethane coatings.
    Type: Grant
    Filed: May 14, 1999
    Date of Patent: May 7, 2002
    Assignee: Georgia Tech Research Corporation
    Inventors: Jan Gooch, Hai Dong, F. Joseph Shork
  • Patent number: 6380281
    Abstract: A distinctive graft copolymer is made by dissolving an unsaturated polyester resin in various vinyl monomers (methyl methacrylate, styrene, etc.). The monomer/unsaturated polyester solution is then miniemulsion polymerized to form a latex consisting of submicron particles of polymer with the polyester grafted onto the polymer backbone. The latex can be applied to a substrate, which on drying forms a polymeric film with good film properties. The latex can be used in a latex paint formulation in place of an acrylate, acetate or styrene-divinyl benzene latex. In this way it is possible to produce water-borne unsaturated polyester coatings which combine the film hardness properties of an unsaturated polyester coating with easy application and cleanup. The coating will beneficially lack organic solvent exposure of typical polyester coatings.
    Type: Grant
    Filed: May 14, 1999
    Date of Patent: April 30, 2002
    Assignee: Georgia Tech Research Corporation
    Inventors: Jan Gooch, John Tsavalas, F. Joseph Shork
  • Patent number: 6369135
    Abstract: A distinctive graft copolymer is made by dissolving an alkyd resin in various vinyl monomers (methyl methacrylate, styrene, etc.). The monomer/alkyd solution is then miniemulsion polymerized to form a latex consisting of submicron particles of polymer with the alkyd grafted onto the polymer backbone. The latex can be applied to a substrate, which on drying forms a polymeric film with good film properties. The latex can be used in a latex paint formulation in place of an acrylate, acetate or styrene-divinyl benzene latex. In this way it is possible to produce water-borne alkyd coatings which combine the film hardness properties of an oil-based alkyd coating with easy application and cleanup. The coating will beneficially lack organic solvent exposure of typical standard latex coatings.
    Type: Grant
    Filed: August 13, 1996
    Date of Patent: April 9, 2002
    Assignee: Georgia Tech Research Corporation
    Inventors: F. Joseph Schork, Jan W. Gooch, Gary W. Poehlein, Shou-Ting Wang
  • Patent number: 6344503
    Abstract: A method is disclosed for the preparation of a water-based graft copolymer of a carboxyl functional polyester and an ethylenically unsaturated monomer having a low level of volatile organic compounds.
    Type: Grant
    Filed: September 29, 1999
    Date of Patent: February 5, 2002
    Assignee: BP Corporation North America Inc.
    Inventors: Asare Nkansah, Catherine T. McKee, Ajaykumar Desai, Maria Curry-Nkansah
  • Patent number: 6344502
    Abstract: A non-aqueous dispersion of a polymer in a non-polar hydrocarbon. The polymer is produced by a free-radical addition polymerization reaction of a group of monomers including at least one polar monomer and at least one amine-functional monomer which takes place in the presence of an alkyd resin.
    Type: Grant
    Filed: July 16, 1999
    Date of Patent: February 5, 2002
    Assignee: The Sherwin-Williams Company
    Inventors: John R. Babjak, Liza A. Capino, John D. Kraan, Mohamad D. Shalati, Susan L. Smith, Demetri L. Vallion, Richard S. Valpey, III, Thomas W. Yokoyama
  • Patent number: 6339115
    Abstract: A molding composition comprising (A) a fibrous material, (B) a nonlinear unsaturated polyester and/or (C) a nonlinear unsaturated polyester-polyamide, and (D) a radical generator, and a molded article obtained therefrom.
    Type: Grant
    Filed: August 4, 2000
    Date of Patent: January 15, 2002
    Assignee: Kao Corporation
    Inventors: Katsutoshi Aoki, Takashi Yamaguchi, Kuniyasu Kawabe
  • Patent number: 6316523
    Abstract: An adhesive composition for surgical use including an &agr;-cyanoacrylate adhesive composition with a polymer characteristic for biodegrading and bioabsorbing the adhesive into the body of a living organism. It is preferred that the polymer is a co-polymer of DL-lactic acid and &egr;-caprolactone or a co-polymer of DL-lactic acid, ethylene glycol and &egr;-caprolactone, or a co-polymer of ethylene glycol and &egr;-caprolactone.
    Type: Grant
    Filed: March 31, 1999
    Date of Patent: November 13, 2001
    Assignee: BMG Inc.
    Inventors: Suong-Hyu Hyon, Naoki Nakajima
  • Publication number: 20010025067
    Abstract: Method for on-mold surface coating fiberglass-reinforced molded articles during their manufacture with environmentally friendly and physiologically safe thermosetting unsaturated polyester on-mold coating powders which serve as replacements for liquid gel coats. The thermosetting coating powders employed are adapted to cure at low temperatures to avoid causing thermal damage to the heat sensitive plastic molds which must be reused over and over again, and to cure in the presence of atmospheric oxygen to enable over coating with liquid fill resins and fiberglass, which constitute the bulk of the finished article, without having the fill resins bleed through the powder coating film and detrimentally affect the overall quality of the surface finish.
    Type: Application
    Filed: March 16, 2001
    Publication date: September 27, 2001
    Inventors: Edward G. Nicholl, Navin B. Shah
  • Patent number: 6288146
    Abstract: The invention concerns the use of monomer-free, saturated and unsaturated polyester resins, or mixtures of saturated and unsaturated polyester resins, containing structural units of the general formulae (I) and/or (II), in which n =1-10, as low-emission binders for coatings.
    Type: Grant
    Filed: October 26, 1998
    Date of Patent: September 11, 2001
    Assignee: Basf Aktiengesellschaft
    Inventors: Rainer Blum, Thomas Loerzer
  • Patent number: 6280846
    Abstract: Curable compositions for making fibre-reinforcement structural composites such as GRP comprise an unsaturated polyester resin base, a co-polymerizable monomer and preferably, one or more performance-enhancing additives. Thixotropy is endowed by 5% by weight or less of an organic amide.
    Type: Grant
    Filed: August 20, 1999
    Date of Patent: August 28, 2001
    Assignee: Cray Valley Limited
    Inventors: Paul Darby, Paul Sutton
  • Patent number: 6255367
    Abstract: Novel modifying agents contain a sharply-melting crystalline polymer ingredient, preferably a side chain crystalline (SCC) ingredient, and an active chemical ingredient. Such modifying agents, especially when in the form of particles, can be placed in contact with a matrix, will not modify the mix below the crystalline melting point Tp, but will rapidly modify the matrix above Tp. The active chemical ingredient can react with the matrix, catalyze a reaction of the matrix, or inhibit a reaction of the matrix. Particularly useful compositions are polymer precursors which are storage-stable at low temperatures but which are rapidly converted to crosslinked resins when heated to temperatures above Tp, optionally in the presence of light.
    Type: Grant
    Filed: December 16, 1998
    Date of Patent: July 3, 2001
    Assignee: Landec Corporation
    Inventors: Steven P. Bitler, Ray F. Stewart
  • Patent number: 6221935
    Abstract: A resin concrete composition and its molded article are provided, the resin concrete, even with a reduced resin content, having an excellent flowability, which is an important property in a molding operation, and necessitating no shrinkage reduction agent, and the molded article having no cracks and being highly strong. The resin concrete composition comprises (A) a resin composition containing (a) an unsaturated polyester of an unsaturated acid, a di- and/or trialkylene glycol, and dicyclopentadiene and (b) a polymerizable unsaturated monomer, (B) an aggregate, and (C) a filler.
    Type: Grant
    Filed: July 20, 1999
    Date of Patent: April 24, 2001
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Yoshitomi Hashimoto, Toshio Kanai, Yutaka Furuya
  • Patent number: 6203911
    Abstract: A molding composition including reactive high-volatility monomeric groups, such as acrylics, at least one primary thermal initiator and at least one secondary thermal initiator is described. Molding processs using molding compositions including reactive high-volatility monomeric groups are also described.
    Type: Grant
    Filed: June 17, 1998
    Date of Patent: March 20, 2001
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Rolf Thomas Weberg, Lawrence J. Simmons, Richard Reid Gleason
  • Patent number: 6133337
    Abstract: The invention relates to the use of reactive prepolymeric organic compounds, containing structural units having at least one readily abstractable hydrogen with a bond energy of not more than 397 kJ/-mol and having at least one ethylenic double bond, for crosslinking, with or without free-radical initiators, by means of heat, high-energy radiation or heat and high-energy radiation.
    Type: Grant
    Filed: September 30, 1998
    Date of Patent: October 17, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Blum, Thomas Loerzer, Gunther Hegemann, Gunther Baumgarten
  • Patent number: 6100316
    Abstract: The invention relates to radiation-curable coating materials which compriseA a synthetic resin containing from 1.5 to 5 mol/kg, preferably from 3.6 to 4.5 mol/kg, of ethylenically unsaturated double bonds of which not more than 10% are vinyl groups, or a mixture of such synthetic resins, andB a compound of the general formula Ar--O--R.sub.1 --O--CO--CR.sub.2 .dbd.CH.sub.2, where Ar is an optionally substituted aryl radical, R.sub.1 is an alkylene radical having 1 to 6 carbon atoms and R.sub.2 is a hydrogen atom or an alkyl radical having 1 to 3 carbon atoms, or a mixture of such compounds,from 10 to 70% by weight of the total quantity of A and B comprising component A and from 30 to 90% by weight of the total quantity of A and B comprising component B.
    Type: Grant
    Filed: January 6, 1997
    Date of Patent: August 8, 2000
    Assignee: BASF Coatings AG
    Inventor: Martin Lobert
  • Patent number: 6087444
    Abstract: A water reducible polyurethane resin for use in coating compositions is provided with humidity resistance at relatively low cost by employing a urethane prepolymer which is the reaction product of (i) a polyisocyanate, (ii) a polyhydroxy compound which is the reaction product of an organic acid and an epoxy compound, at least one of which includes a hydrocarbon group of at least six carbon atoms, and (iii) a monomer having an anionic group and functionality reactive with isocyanate. Preferred embodiments employ C.sub.36 dimer diacid and the propylene oxide ester of neodecanoic acid to make the polyhydroxy compound.
    Type: Grant
    Filed: September 20, 1996
    Date of Patent: July 11, 2000
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Shanti Swarup, Anbazhagan Natesh, Gina M. Terrago, Cathy A. Taylor
  • Patent number: 6051633
    Abstract: This invention relates to high solids, low VOC, low viscosity, filterable, non-gritty non-aqueous dispersions, and coating compositions containing said non-aqueous dispersions.
    Type: Grant
    Filed: November 25, 1997
    Date of Patent: April 18, 2000
    Assignee: The Sherwin-Williams Company
    Inventors: Richard F. Tomko, Madhukar Rao, Mohamad D. Shalati, John D. Kraan
  • Patent number: 6015551
    Abstract: The disclosure relates to a copolymer obtainable by radically initiated polymerization of the following: A) 70-99.9 wt. % an olefinically unsaturated C.sub.3 -C.sub.5 monocarboxylic acid, an olefinically unsaturated C.sub.4 -C.sub.8 dicarboxylic acid or its anhydride, or a mixture of such carboxylic acids; with B) 0.1-30 wt. % one or more multiply olefinically unsaturated carboxylic acid derivatives of formula (I)Z--Y--(CHR.sup.3 --CH.sub.2 --X).sub.n --R.sup.4 (I)in which Z is a vinyl or allyl group or structure (a), ##STR1## R.sup.1, R.sup.2 are hydrogen or methyl, R.sup.3 is hydrogen, methyl or ethyl, R.sup.4 is a singly or multiply olefinically unsaturated alkenyl or cycloalkenyl group or a singly or doubly olefinically unsaturated arylalkylene group, X is oxygen or NH, Y is oxygen, NH or N-alkyl, n is a number between 0 and 50; and C) 0-29.9 wt. % other copolymerizable monomers. The proposed copolymer can be used as a thickener or dispergent for aqueous systems.
    Type: Grant
    Filed: June 2, 1998
    Date of Patent: January 18, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Christian Schade, Hans-Ulrich Wekel, Axel Sanner, Karin Sperling
  • Patent number: 6001891
    Abstract: A biodegradable aliphatic polyester elastomer which has rubber-like elasticity, hardness of 80 or less in accordance with ASTM D 676-58T, and elastic modulus from 1.times.10.sup.5 Pa to 1.times.10.sup.8 Pa at 25.degree. C., and decomposes with ease in the natural environment, under composting conditions or under hydrolysis conditions. The biodegradable aliphatic elastomer can be obtained by crosslinking aliphatic polyester containing aliphatic unsaturated polybasic acid as a polymer constituting ingredient and having a weight average molecular weight of 15,000 or more.
    Type: Grant
    Filed: May 29, 1997
    Date of Patent: December 14, 1999
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Chojiro Higuchi, Masatoshi Takagi, Takeshi Kashima, Masanobu Ajioka, Yuji Terado
  • Patent number: 5932344
    Abstract: A cement retarder which comprises a saturated or unsaturated polyester obtained by a reaction of a polycarboxylic acid component comprising a polycarboxylic acid having 2 to 6 carbon atoms in the main chain or its derivative, and a polyol component containing a polyhydric alcohol having 2 to 4 carbon atoms or its condensate, wherein:(a) the saturated polyester has a weight average molecular weight of about 300 to about 50,000; or(b) the unsaturated polyester has a weight average molecular weight of about 500 to about 25,000; or(c) the polyhydric alcohol used to obtain the saturated or unsaturated polyester is a condensate of a C.sub.2-4 alkylene glycol; or(d) the saturated polyester is a polyester obtained by the use of a condensate of a C.sub.2-4 alkylene glycol and has a weight average molecular weight of about 300 to about 50,000; or(e) the unsaturated polyester is a polyester obtained by the use of a condensate of a C.sub.
    Type: Grant
    Filed: October 7, 1996
    Date of Patent: August 3, 1999
    Assignee: Daicel-Huels Ltd.
    Inventors: Yoshiyuki Ikemoto, Toru Ikuta
  • Patent number: 5932638
    Abstract: The present invention provides adhesive compositions which include free radical polymerizable compounds and a redox catalyst system to accelerate polymerization thereof. The redox catalyst includes an aniline derivative substituted in the para position by halogen as an accelerator. The use of para-halogenated aniline derivatives as an accelerator in the cure of free radical polymerizable compounds results in good bond strength and greatly improved surface cure of the adhesive composition.
    Type: Grant
    Filed: September 29, 1997
    Date of Patent: August 3, 1999
    Assignee: Lord Corporation
    Inventors: Robin F. Righettini, Terrence H. Dawdy
  • Patent number: 5929197
    Abstract: The present invention relates to a process for preparing acylsuccinic acid polyesters by reactingA) a polyester, which is the reaction product oi) maleic acid, maleic acid esters, maleic anhydride, fumaric acid and/or fumaric acid esters and optionally other diacids, monoacids or their derivatives withii) diols and optionally monofunctional alcohols,wherein the molar ratio of diols to diacids and their derivatives is 0.667:1 to 1.5:1, and the molar ratio of maleic acid and its derivatives+ fumaric acid and its derivatives to other diacids and their derivatives is greater than 0.15:1, and the molar ratio of monofunctional compounds to difunctional compounds is less than 0.4:1, withB) aliphatic C.sub.2 -C.sub.22 aldehydes and/or cycloaliphatic C.sub.6 -C.sub.20 aldehydes,in the presence of 0.2 to 10 % by weight (based on the weight of polyester) of free radical initiators at a temperature of 60 to 160.degree. C.
    Type: Grant
    Filed: July 7, 1997
    Date of Patent: July 27, 1999
    Assignee: Bayer Aktiengesellschaft
    Inventors: Burkhard Kohler, Rolf-Volker Meyer
  • Patent number: 5911914
    Abstract: The present invention provide a liquid crystal polyester represented by the formula I ##STR1## wherein A is ##STR2## B is ##STR3## R.sub.1 and R.sub.2, independently to each other, are hydrogen, halogen or C.sub.1 -C.sub.3 alkyl, andR.sub.3 and R.sub.4, independently to each other, are hydrogen, halogen or C.sub.1 -C.sub.3 alkyl,which is prepared by using aliphatic fumaric acid as diacid.The liquid crystal polyester according to the present invention can be prepared in a simple manner, processed directly without separate modification and used in the form of high strength fiber and plastic.
    Type: Grant
    Filed: February 5, 1996
    Date of Patent: June 15, 1999
    Assignee: Korean Research Institute of Chemical Technology
    Inventor: Young Wook Park