With Nitrogen-containing Reactant, Or Wherein The Poly 1,2-epoxy Reactant Contains A Nitrogen Atom Patents (Class 525/113)
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Patent number: 8101689Abstract: The shape memory polymers disclosed are a reaction product of at least one reagent containing two active amino-hydrogen or two active phenolic-hydrogen with at least one multifunctional cross linking reagent which contains at least three or more active amino- or phenolic-hydrogen or is a reagent containing at least three glycidyl ether moieties which is then further mixed with at least one diglycidyl ether reagent whereupon the resulting mixture is cured and has a glass transition temperature higher than 00 C. This reaction creates crosslinking between the monomers and polymers such that during polymerization they form a crosslinked thermoset network.Type: GrantFiled: December 15, 2006Date of Patent: January 24, 2012Assignee: Cornerstone Research Group, Inc.Inventors: Tat Hung Tong, Benjamin J. Vining, Richard D. Hreha, Thomas J. Barnell
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Publication number: 20110305863Abstract: Provided is a thermoplastic resin composition in which a modified rubber excellent in low temperature resistance is dispersedly added in a polyamide resin matrix to improve the low temperature resistance (cyclic fatigue resistance) of the polyamide resin, the composition maintaining its fluidity even at a high content of modified rubber, thus allowing film formation, and exhibiting excellent low temperature resistance. The thermoplastic resin composition includes a polyamide resin (A) and a modified rubber (B) having an acid anhydride group or an epoxy group and is characterized in that the modified rubber (B) having an acid anhydride group or an epoxy group is modified with a hydrogen bonding compound (C) having a functional group reacting with an acid anhydride group or an epoxy group and a functional group capable of hydrogen bonding with an amide bond or a hydroxyl group.Type: ApplicationFiled: March 4, 2010Publication date: December 15, 2011Applicant: The Yokohama Rubber Co., Ltd.Inventor: Naoyuki Morooka
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Patent number: 8067484Abstract: A curing agent for epoxy resins that is comprised of the reaction product of an amine, an epoxy resin, and an elastomer-epoxy adduct; compositions containing the curing agent and an epoxy resin; the compositions are useful in electronic displays, circuit boards, semi conductor devices, flip chips and other applications.Type: GrantFiled: April 19, 2010Date of Patent: November 29, 2011Assignee: Trillion Science, Inc.Inventors: Yurong Ying, John J. McNamara, Jing Liang, Rong-Chang Liang
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Publication number: 20110274843Abstract: Crosslinker-accelerator system for the thermal crosslinking of polyacrylates with functional groups suitable for entering into linking reactions with cyclic ethers, more particularly epoxide groups or oxetane groups, comprising at least one substance containing epoxide or oxetane grouops (crosslinker) and at least one substance with an accelerating action for the linking reaction at a temperature below the melting temperature of the polyacrylate (accelerator).Type: ApplicationFiled: October 16, 2009Publication date: November 10, 2011Applicant: TESA AKTIENGESELLSCHAFTInventors: Norbert Grittner, Sven Hansen, Alexander Prenzel, Stephan Zöllner
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Patent number: 8053533Abstract: A solvent-free polyimide silicone resin composition, and a cured product thereof, includes (A) a polyimide silicone resin having recurring units having a specific type of structure and having a weight average molecular weight of 5,000 to 150,000, (B) an epoxy resin, and (C) an epoxy resin curing agent wherein the resin composition having a fluidity at 25° C. and is free of a solvent.Type: GrantFiled: August 26, 2009Date of Patent: November 8, 2011Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Yoshinori Yoneda, Michihiro Sugo
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Patent number: 8026310Abstract: A low temperature curable coating powder comprising an epoxy functional resin is cured with styrene maleimide in combination with at least one other curing agent such as dicyandiamide, imidazole, or an imidazole adduct. The combination of three curing agents such styrene maleimide, dicyandiamide, and an imidazole or imidazole adduct is useful for achieving gloss control. The coating powder may be curable at temperatures of 300° F. or lower. The coating of heat-sensitive and non-conductive substrates is facilitated with use of such coating powder, although other substrates, such as metal may be coated in accordance with the invention.Type: GrantFiled: June 23, 2008Date of Patent: September 27, 2011Assignee: Alpha Coating Technologies, IncInventor: Jeno Muthiah
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Patent number: 7981963Abstract: In a semiconductor device, the topmost wiring layer of the package board is formed from an insulation material in which the elongation at break is 20% or higher and Young's modulus is 1 GPa or less when the temperature is 10 to 30° C. This insulation material contains a reactive elastomer that reacts with epoxy resin or an epoxy resin curing agent; an epoxy resin; an epoxy resin curing agent; and a crosslinked styrene-butadiene rubber having a double bond and a hydroxyl group, a carboxylic group, or another polar group. It is therefore possible to provide a semiconductor device that has a wiring board in which the connection reliability in relation to temperature cycles is high and the adhesiveness between the insulation layer and the electroless copper plating layer is also high.Type: GrantFiled: April 10, 2007Date of Patent: July 19, 2011Assignee: NEC CorporationInventors: Yukihiro Kiuchi, Masahiro Ishibashi, Yoshitaka Kyogoku, Masatoshi Iji
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Patent number: 7951879Abstract: Embodiments relate to viscosifiers that are terminated polymers that have functional terminal groups. The polymers being pre-extended by polyepoxides and being reacted to give polymers that are terminated by other functional groups. The viscosifiers have a low content in educts or educt descendants that deteriorate the properties of compositions and considerably reduce or even exclude the formation of high-molecular addition products so that the products obtained have low viscosity and good storage stability.Type: GrantFiled: December 21, 2007Date of Patent: May 31, 2011Assignee: Sika Technology AGInventors: Andreas Kramer, Jan Olaf Schulenburg, Jürgen Finter
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Patent number: 7932322Abstract: The invention relates to viscosifiers, especially terminated polymers that have functional terminal groups, said polymers being pre-extended by polyamines, polymercaptans, (poly)aminoalcohols, (poly)mercaptoalcohols or (poly)aminomercaptans and being reacted to give polymers that are terminated by other functional groups. The viscosifiers have a low content in educts or educt descendants that deteriorate the properties of compositions. They are also charaterized in that the formation of high-molecular addition products is considerably reduced or even excluded so that products obtained have low viscosity and good storage stability. The epoxy-terminated polymer of formula (I) is especially preferred.Type: GrantFiled: December 21, 2007Date of Patent: April 26, 2011Assignee: Sika Technology AGInventors: Andreas Kramer, Jan Olaf Schulenburg, Jürgen Finter, Norman Blank
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Patent number: 7927691Abstract: A prepreg composite material that includes a fiber layer and a resin comprising a thermoset resin component, a curing agent and a fibrous micropulp. The micropulp component is an aramid fiber having a volume average length of from 0.01 to 100 micrometers. The prepreg is useful in composite panel construction for minimizing fluid permeation into the cured structure. This prepreg is particularly suitable for making honeycomb sandwich panels. Film adhesives, liquid and paste resins containing aramid fiber micropulp are also disclosed.Type: GrantFiled: April 3, 2009Date of Patent: April 19, 2011Assignee: E.I. du Pont de Nemours and CompanyInventors: Subhotosh Khan, Halvar Young Loken
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Patent number: 7915344Abstract: Viscosifiers, especially terminated polymers that have functional terminal groups, the polymers being pre-extended by polyols and being reacted to give polymers that are terminated by other functional groups, are produced. The viscosifiers have a low content in educts or educt descendants that deteriorate the properties of compositions. The formation of high-molecular addition products is considerably reduced or even excluded so that the products obtained have low viscosity and good storage stability. The epoxy-terminated polymer of formula (I) is especially preferred.Type: GrantFiled: December 21, 2007Date of Patent: March 29, 2011Assignee: Sika Technology AGInventors: Andreas Kramer, Jan Olaf Schulenburg
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Publication number: 20110067813Abstract: A heat-curing epoxy resin composition that includes an epoxy resin, a curing agent, an accelerator, and an optional toughener. The epoxy resin compositions are suitable in particular for use as bodyshell adhesives and for preparation of structural foams. An accelerator of formula (I) results in increased impact strength the of heat-curing epoxy resin compositions.Type: ApplicationFiled: May 28, 2009Publication date: March 24, 2011Applicant: SIKA TECHNOLOGY AGInventors: Andreas Kramer, Karsten Frick
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Patent number: 7910656Abstract: The invention relates to an epoxy adhesive composition comprising a) a first epoxy resin, b) a second epoxy resin modified with an acrylonitrile-butadiene rubber, the latter comprising on average less than about 25 weight percent acrylonitrile, and c) a toughener. The total amount of component b) and component c) is higher than about 30 percent based on the total weight of the composition, and the weight ratio of component c) to component b) is greater than about 1:1. The invention further relates to the use of said epoxy adhesive composition for the assembly of parts of a vehicle. It also relates to a vehicle, parts of which are assembled by said epoxy adhesive composition.Type: GrantFiled: March 11, 2005Date of Patent: March 22, 2011Assignee: Dow Global Technologies LLCInventors: Andreas Lutz, Cathy Grossnickel, Karsten Frick
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Publication number: 20110048637Abstract: Thermosetting adhesive compositions formed from an epoxy resin containing nano-sized core-shell particles, one or more thermoplastic toughening agent containing an amine-terminated polyethersulfone, and at least one multi-functional epoxy resin, together with at least one amine curing agent to allow full cure of the adhesive composition up to 400° F. are provided herein. Such compositions are useful for forming adhesive films that can bond composite/metal/honeycomb structures for aerospace including bonding of aircraft leading or trailing edges, acoustic nacelle structures, horizontal and vertical tail, and various other structures, as well as for other high performance industrial applications.Type: ApplicationFiled: August 26, 2010Publication date: March 3, 2011Applicant: CYTEC TECHNOLOGY CORP.Inventor: Dalip KOHLI
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Publication number: 20100324174Abstract: Disclosed are a thermoplastic resin composition which has a reduced tendency to mold staining while being shaped and a high flowability, and a shaped article which, when used as a lamp component, has good surface appearance and generates little volatiles by the heat of the lamp. Specifically disclosed are a thermoplastic resin composition containing a polyester resin (A), a cresol novolac epoxy resin (B), and a vinyl cyanide-aromatic vinyl copolymer containing epoxy group (C), and a shaped article shaped therefrom, wherein the cresol novolac epoxy resin (B) and the vinyl cyanide-aromatic vinyl copolymer containing epoxy group (C) are compounded in amounts of 0.01 to 3 parts by mass and 2 to 12 parts by mass, respectively, relative to 100 parts by mass of the polyester resin (A).Type: ApplicationFiled: July 1, 2008Publication date: December 23, 2010Applicant: Mitsubishi Rayon Co., Ltd.Inventor: Haruo Ueda
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Patent number: 7847026Abstract: A blend of epoxy resins includes a) an epoxy resin composition derived from the reaction of a liquid epoxy resin, a carboxyl terminated butadiene (CTB), and a carboxyl terminated polybutadiene-acrylonitrile (CTBN) and/or a random and terminal carboxyl functional polybutadiene-acrylonitrile (CTBNX), and b) unreacted epoxy resin. The carboxyl terminated butadiene is miscible with the unreacted epoxy resin and does not separate therefrom even upon aging. Upon cure as with a latent cure agent, a toughened epoxy resin is produced having unexpected good low temperature properties such as peel strength.Type: GrantFiled: June 20, 2008Date of Patent: December 7, 2010Assignee: Emerald Specialty Polymers, LLC.Inventors: Roert J. Bertsch, Jeremy J. Pasatta
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Patent number: 7834091Abstract: The present invention relates to a two-component epoxy adhesive composition comprising a) a first component comprising a first epoxy resin and a second epoxy resin, the second epoxy resin being flexibilized by an elastomer, and b) a second component comprising at least one amine compound with one or more primary and/or secondary amino groups, said amine compound having a molecular weight of less than 450 g/mol. The ratio of the total number of amino groups of the amine compound to the total number of epoxy groups of the epoxy resins is 0.01:1 to 0.5:1. The mixing of the two components a) and b) results in a wash-off resistant composition. Said wash-off resistant composition results upon heat-curing in a crash-stable structural adhesive.Type: GrantFiled: October 16, 2008Date of Patent: November 16, 2010Assignee: Dow Global Technologies Inc.Inventors: Karsten Frick, Andreas Lutz, Isabell Wipf
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Publication number: 20100222480Abstract: Disclosed is a toughened film forming agent for use in a fiber sizing, a finish coating or a binder composition, where the toughened film forming agent includes a film fowling polymer and a toughening agent both dispersed in water. The toughening agent may be core shell polymers, rubber, thermoplastic materials, nanomaterials, nanofibers, including any combination or subset thereof. The film forming polymer may be epoxy resins, polyurethane resins, epoxy-polyurethane resins, polyester resins, epoxy-polyester resins, polyvinylacetate resins, polypropylene resins, including any combination or subset thereof.Type: ApplicationFiled: February 26, 2010Publication date: September 2, 2010Inventors: Walter Henry Christiansen, III, Carlton E. Ash, Paul W. Langemeier
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Patent number: 7776440Abstract: A spring with high durability has a coating film composed of an epoxy resin powder coating containing softening agent which contains an epoxy resin and a softening agent comprising a thermoplastic resin for improving impact resistance of the coating film. A method of coating a spring with high durability comprises a coating step of making an epoxy resin powder coating containing softening agent which contains an epoxy resin and a softening agent comprising a thermoplastic resin for improving impact resistance of a coating film adhere to a surface on which the coating film is formed, and a baking step of baking the epoxy resin powder coating containing softening agent adhered to the surface.Type: GrantFiled: January 26, 2007Date of Patent: August 17, 2010Assignees: Chuo Hatsujo Kabushiki Kaisha, Rock Paint Co., Ltd.Inventors: Yasuhiko Kunita, Takayuki Sakakibara, Masami Wakita, Yuichi Kondo, Norio Sawatari
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Patent number: 7772334Abstract: A crosslinker for polymerizing a film-forming material including an alkyl or aromatic compound comprising at least two functional groups reactive with a film-forming resin and at least one pendent group having a nonionic metal coordinating structure. Coating compositions can include a film-forming material and the crosslinker. The coating compositions can be used to coat a substrate, such as a metal substrate. Applied coating layers on substrates can be cured to form coating films.Type: GrantFiled: October 26, 2006Date of Patent: August 10, 2010Assignee: BASF Coatings GmbHInventors: Timothy S. December, Sergio Gonzalez, Günther Ott, Karl-Heinz Grosse-Brinkhaus
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Patent number: 7737199Abstract: An epoxy adhesive composition of an epoxy resin, an epoxy terminated liquid rubber, filler, and an amine curing package for said epoxy resin is disclosed. Advantageously, a short chain diol will be incorporated into the adhesive in order to enhance reactivity and strength build. Advantageously, a mixture of amines will be used in the curative including multifunctional aliphatic amines that improve adhesion and strength build; tertiary amines which are used to enhance adhesion and strength build, polyamides which can be used to provide flexibility; and amine-terminated rubbers (ATBN) which can improve toughness and impact resistance to the cured system. The preferred short chain diol is glycerin. Surfaces of adherends are joined with the dried residue of the epoxy adhesive composition by applying the epoxy resin composition to one or both surfaces, joining the surfaces, and applying pressure, optionally with heating.Type: GrantFiled: February 15, 2007Date of Patent: June 15, 2010Assignee: Ashland Licensing & Intellectual Property LLCInventor: Michael J. Barker
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Publication number: 20100144929Abstract: A synthetic-rubber-based composition that consists of a low-molecular-weight rubber selected from polybutadiene comprising about 75% to about 92% cis-1,4 units, sulfur, a vulcanization accelerator, and an active filler wherein the sulfur, accelerator, and active filler are each present in the form of powder having a particular particle-size range. Additionally, this composition may be used to form coatings and rubber concretes.Type: ApplicationFiled: December 4, 2008Publication date: June 10, 2010Inventor: Oleg Figovsky
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Publication number: 20100104864Abstract: Crosslinker/accelerator system for thermally crosslinking polyacrylates with functional groups that are adapted to react with epoxy groups in a crosslinking reaction, comprising at least one epoxy group-containing substance and at least one substance that accelerates the crosslinking reaction at a temperature below the melting temperature of the polyacrylate.Type: ApplicationFiled: March 18, 2008Publication date: April 29, 2010Applicant: TESA SEInventors: Stephan Zöllner, Kay Brandes, Sven Hansen, Esther Von Possel
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Patent number: 7674859Abstract: An adhesive sheet which can actualize a high package reliability wherein there is no separation at the adhesive interface and no package cracking, in a package in which a semiconductor chip being reduced in thickness is mounted under severe reflow conditions after exposure to a hot and humid environment. The adhesive sheet includes a base material and, formed thereon, an adhesive layer having an adhesive composition including an acrylic copolymer (A) containing 20 to 95% by weight of a structural unit derived from a benzyl (meth)acrylate, an epoxy thermosetting resin (B), and a thermosetting agent (C).Type: GrantFiled: June 24, 2008Date of Patent: March 9, 2010Assignee: Lintec CorporationInventors: Naoya Saiki, Isao Ichikawa, Hironori Shizuhata
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Publication number: 20090226729Abstract: A high-solids anticorrosive coating composition which comprises a main ingredient (A) comprising an epoxy resin (a1) and a hardener ingredient (B) comprising an alicyclic amine hardener (b1) and/or a Mannich type hardener (b2), the ingredient (A) and/or the ingredient (B) containing at least either of an additive (a2) selected among epoxidized reactive diluents and modified epoxy resins and a coating film modifier (ab) selected among petroleum resins, xylene resins, coumarone resins, terpene phenol resins and vinyl chloride copolymers. The high-solids anticorrosive coating composition especially of the rapidly curable type is characterized by containing a high-boiling organic solvent having a boiling point exceeding 150° C. and containing substantially no organic solvent having a boiling point of 150° C. or lower.Type: ApplicationFiled: August 10, 2005Publication date: September 10, 2009Applicant: CHUGOKU MARINE PAINTS, LTD.Inventors: Jyunji Niimoto, Soushi Kanameda, Tomohisa Sumida, Yukio Miyachi, Hideyuki Tanaka
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Publication number: 20090203279Abstract: A vinyl-compound-based resin composition containing a terminal vinyl compound (a) of a bifunctional phenylene ether oligomer having a polyphenylene ether skeleton, a specific maleimide compound (b), a naphthol aralkyl type cyanate ester resin (c) and a naphthalene-skeleton-modified novolak type epoxy resin (d) for a high-multilayer and high-frequency printed wiring board, which resin composition is excellent in varnish shelf life at low temperature and does not show a decrease in multilayer moldability, heat resistance after moisture absorption, electrical characteristics and peel strength even in a winter period and for a long period of time, and a prepreg, a metal-foil-clad laminate and a resin sheet each of which uses the above resin composition.Type: ApplicationFiled: February 11, 2009Publication date: August 13, 2009Inventors: Kenichi Mori, Syouichi Itoh
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Publication number: 20090182061Abstract: A first object of the invention consists of a process for manufacturing comb polymers having a principal (meth)acrylic chain and polyoxyalkylated lateral groupings, obtained by drying of a solution containing at least one homopolymer of (meth)acrylic acid and/or at least one copolymer of (meth)acrylic acid with at least one other monomer, followed by functionalisation of the said intermediate dry product by esterification with at least one alcoxy polyoxyalkylene glycol, and/or amidification with at least one alcoxy polyoxyalkylene amine, or ethoxylation with at least one alkylene oxide. The intermediate dry products and the final comb polymers (in the dry state or when they are put into aqueous solution) also constitute objects of the invention. Lastly, formulations containing mineral or organic matter and using the above-mentioned polymers constitute a final object of the invention.Type: ApplicationFiled: May 4, 2007Publication date: July 16, 2009Applicant: COATEX S.A.S.Inventors: Jean Moro, Jean-Marc Suau, Yves Kensicher
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Patent number: 7528195Abstract: A dampening material is presented with a carboxy-terminated butadiene nitrile (CTBN) as a dampening element. The glass transition temperature of the CTBN is generally at room temperature. The material is a two-component system with micro-scale phase segregation. The CTBN is reacted into an epoxy resin at a high temperature and cooled to allow the epoxy to react with a curing agent. A phase segregation occurs between the epoxy and the CTBN as the epoxy gels/cures. The extent of phase separation in the reaction is controlled by cross-linking and gelling. The rubbery component of CTBN phase segregates and forms discrete, spherical domains. Because the glass transition temperature of the rubbery domains is in the operational temperature range of interest, the composite is capable of absorbing acoustic energy. A high modulus allows a larger amount of acoustic energy to enter the composite where it is absorbed by the rubbery CTBN component.Type: GrantFiled: December 11, 2006Date of Patent: May 5, 2009Assignee: The United States of America as represented by the Secretary of the NavyInventor: Thomas S. Ramotowski
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Patent number: 7511098Abstract: The present invention provides hardenable coating compositions, comprising: a first compound selected from the group consisting of polyacids, polyanhydrides, salts thereof and mixtures thereof, and a second compound having two or more active hydrogen groups. When used as a roll coating composition, the first compound preferably has a low average molecular weight and an acid number greater than about 100. The hardenable coating composition preferably has an extended open time and can be rapidly cured to a substantially tack-free state in less than about one minute at 200° C. Coated articles and methods of coating are also provided.Type: GrantFiled: July 11, 2001Date of Patent: March 31, 2009Assignee: Valspar Sourcing, Inc.Inventors: Jeffrey Niederst, John H. Mazza, Mike A. Lucarelli, William H. McCarty, Thomas R. Mallen
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Patent number: 7511097Abstract: The present invention relates to a two-component epoxy adhesive composition comprising a) a first component comprising a first epoxy resin and a second epoxy resin, the second epoxy resin being flexibilized by an elastomer, and b) a second component comprising at least one amine compound with one or more primary and/or secondary amino groups, said amine compound having a molecular weight of less than 450 g/mol. The ratio of the total number of amino groups of the amine compound to the total number of epoxy groups of the epoxy resins is 0.01:1 to 0.5:1. The mixing of the two components a) and b) results in a wash-off resistant composition. Said wash-off resistant composition results upon heat-curing in a crash-stable structural adhesive.Type: GrantFiled: February 28, 2006Date of Patent: March 31, 2009Assignee: Dow Global Technologies, Inc.Inventors: Karsten Frick, Andreas Lutz, Isabell Wipf
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Patent number: 7498384Abstract: Multi-component epoxy-amine primer systems are disclosed, which comprise an amine component that comprises a polythioether. Also disclosed are substrates coated with such primer systems as well as methods for coating substrates with such primer systems.Type: GrantFiled: February 2, 2006Date of Patent: March 3, 2009Assignee: PPG Industries Ohio, Inc.Inventors: John A. Walker, Scott C. Peterson
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Patent number: 7488785Abstract: Compositions containing (a) a liquid epoxy resin, (b) an aliphatic or cycloaliphatic primary monoamine and/or an aliphatic or cycloaliphatic disecondary diamine, (c) a latent curing agent for the epoxy resin (a) which does not react until temperatures above 70° C. (measured by means of DSC at a heating rate of 10° C./min), (d) a photopolymerizable compound and (e) a photoinitiator, the ratio of the number of equivalents of epoxy groups to that of polymerizable groups being 1:0.01 to 1:0.7, are suitable as impregnating resins.Type: GrantFiled: April 5, 2007Date of Patent: February 10, 2009Assignee: Huntsman Advanced Materials Americas Inc.Inventor: Frans Setiabudi
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Publication number: 20090029059Abstract: A two-part epoxy composition is provided that comprises a first part having a mixture of an epoxy resin and an anhydride, and a second part having a curing agent. Also provided is a method for making a substantially bis-?-glycol free epoxy resin for two-part epoxy compositions, and a method for applying a two-part epoxy composition to a system of water piping.Type: ApplicationFiled: July 26, 2007Publication date: January 29, 2009Inventors: David L. Stanley, David J. Dunn
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Patent number: 7470755Abstract: Multi-component epoxy-amine primer systems are disclosed, which include an epoxy component and an amine component that includes a mercaptan terminated material. At least one of the epoxy component and the amine component includes a sulfur-containing polymer. Also disclosed are substrates coated with such primer systems as well as methods for coating substrates with such primer systems.Type: GrantFiled: November 29, 2005Date of Patent: December 30, 2008Assignee: PRC-DeSoto International, Inc.Inventors: Siamanto Abrami, Jorge Camargo
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Publication number: 20080318005Abstract: Methods for fabricating a random graft PS-r-PEO copolymer and its use as a neutral wetting layer in the fabrication of sublithographic, nanoscale arrays of elements including openings and linear microchannels utilizing self-assembling block copolymers, and films and devices formed from these methods are provided. In some embodiments, the films can be used as a template or mask to etch openings in an underlying material layer.Type: ApplicationFiled: June 19, 2007Publication date: December 25, 2008Inventor: Dan B. Millward
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Patent number: 7465477Abstract: This invention concerns an epoxy coating for use as a non-skid surface for applications such as the deck of an aircraft carrier. The epoxy coating can be formulated from (a) an amine curing agent, (b) an epoxide-containing toughening agent such as a polysulfide and/or a polythioether, (c) an epoxy resin, (d) a rubber toughening agent, and (e) an optional fire retardant, a glass fiber thixotrope and impact toughening agent, an optional pigment, an optional corrosion inhibitor, an optional moisture penetration inhibitor, an optional ultraviolet light stabilizer, an optional abrasive aggregate, or a combination thereof.Type: GrantFiled: May 2, 2006Date of Patent: December 16, 2008Assignee: Texas Research International, Inc.Inventors: George P. Hansen, Rock A. Rushing, John W. Bulluck, Joshua B. Lightfoot, Brad A. Rix
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Patent number: 7435767Abstract: This invention concerns an epoxy coating for use as a non-skid surface for applications such as the deck of an aircraft carrier. The epoxy coating can be formulated from (a) an amine curing agent, (b) an epoxide-containing toughening agent such as a polysulfide and/or a polythioether, (c) an epoxy resin, (d) a rubber toughening agent, and (e) an optional fire retardant, a glass fiber thixotrope and impact toughening agent, an optional pigment, an optional corrosion inhibitor, an optional moisture penetration inhibitor, an optional ultraviolet light stabilizer, an optional abrasive aggregate, or a combination thereof.Type: GrantFiled: May 2, 2006Date of Patent: October 14, 2008Assignee: Texas Research International, Inc.Inventors: George P. Hansen, Rock A. Rushing, John W. Bulluck, Joshua B. Lightfoot, Brad A. Rix
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Patent number: 7435451Abstract: This invention concerns an epoxy coating for use as a non-skid surface for applications such as the deck of an aircraft carrier. The epoxy coating can be formulated from (a) an amine curing agent, (b) an epoxide-containing toughening agent such as a polysulfide and/or a polythioether, (c) an epoxy resin, (d) a rubber toughening agent, and (e) an optional fire retardant, a glass fiber thixotrope and impact toughening agent, an optional pigment, an optional corrosion inhibitor, an optional moisture penetration inhibitor, an optional ultraviolet light stabilizer, an optional abrasive aggregate, or a combination thereof.Type: GrantFiled: May 2, 2006Date of Patent: October 14, 2008Assignee: Texas Research International, Inc.Inventors: George P. Hansen, Rock A. Rushing, John W. Bulluck, Joshua B. Lightfoot, Brad A. Rix
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Patent number: 7432333Abstract: Low-cure powder coating compositions are disclosed, comprising at least one epoxy-containing resin and/or at least one siloxane-containing resin, and at least one material having the structure wherein R1 is an organic radical having 6 to 25 carbon atoms; each R2 is independently a multivalent hydrocarbon group having 1 to 20 carbon atoms; Y is each R3 and R4 are independently alkyl or aryl groups having 1 to 8 carbon atoms; each Z is independently oxygen or nitrogen; R5 is absent when Z is oxygen and R5 is hydrogen, an alkyl or aryl group having 1 to 20 carbon atoms, or (Y)a—R2— when Z is nitrogen; a and b are integers; a is at least 1; b is 1 to 3; and (b) at least one epoxy-containing resin and/or at least one siloxane-containing resin. The material can optionally be reacted with an acidic hydrogen-containing compound. Some compositions are curable without using crosslinking agents or accelerators.Type: GrantFiled: June 7, 2006Date of Patent: October 7, 2008Assignee: PPG Industries Ohio, Inc.Inventors: Shawn P. Duffy, Anthony M. Chasser, Ronald R. Ambrose
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Patent number: 7432335Abstract: There are provided a composition for functioning as an effective additive for epoxy resin that is solid at room temperature and has high storage stability, and a method thereof. The composition of the present invention is a basic silane coupling agent organic carboxylate composition obtained by first synthesizing an organic carboxylate of a basic silane coupling agent by reacting a basic silane coupling agent and an organic carboxylic acid, and subsequently heating and mixing the organic carboxylate of the basic silane coupling agent with a compound exhibiting good affinity for the basic silane coupling agent or organic carboxylic acid and having a softening point or melting point of 40° C. or greater.Type: GrantFiled: June 1, 2006Date of Patent: October 7, 2008Assignee: Nikko Materials Co., Ltd.Inventors: Masashi Kumagai, Takashi Ouchi, Katsuyuki Tsuchida
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Patent number: 7423096Abstract: An underfill composition includes a thermosetting resin and a thermally cleavable component that releases sulfonic acid upon thermal activation. The underfill composition is applied to flip-chip technology during no-flow underfill mounting of the flip-chip to a mounting substrate. The mounting substrate can be further mounted on a board. A process includes formation of the underfill composition. A method includes assembly of the underfill composition with the flip-chip, and further can include assembly of the mounting substrate to a board. A computing system is also included that uses the underfill composition.Type: GrantFiled: September 29, 2004Date of Patent: September 9, 2008Assignee: Intel CorporationInventor: Saikumar Jayaraman
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Publication number: 20080199717Abstract: An epoxy adhesive composition of an epoxy resin, an epoxy terminated liquid rubber, filler, and an amine curing package for said epoxy resin is disclosed. Advantageously, a short chain diol will be incorporated into the adhesive in order to enhance reactivity and strength build. Advantageously, a mixture of amines will be used in the curative including multifunctional aliphatic amines that improve adhesion and strength build; tertiary amines which are used to enhance adhesion and strength build, polyamides which can be used to provide flexibility; and amine-terminated rubbers (ATBN) which can improve toughness and impact resistance to the cured system. The preferred short chain diol is glycerin. Surfaces of adherends are joined with the dried residue of the epoxy adhesive composition by applying the epoxy resin composition to one or both surfaces, joining the surfaces, and applying pressure, optionally with heating.Type: ApplicationFiled: February 15, 2007Publication date: August 21, 2008Inventor: Michael J. Barker
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Patent number: 7323521Abstract: Comb polymers prepared by reacting an epoxy resin and a lactone are disclosed. These comb polymers find particular application as additives for powder coating compositions, to improve various performance properties thereof. Powder coating composition comprising the described comb polymers are also disclosed.Type: GrantFiled: March 19, 2004Date of Patent: January 29, 2008Assignee: PP6 Industries Ohio, Inc.Inventors: Michael J. Ziegler, Anthony M. Chasser, Jackie L. Kulfan
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Patent number: 7230052Abstract: A composition useful as a matrix for fiber-reinforced composites possesses a viscosity at 25° C. of no more than 1000 mPa·s and provides a cured product displaying a breaking elongation of at least 5%. The composition comprises (A) at least one of a bisphenol epoxy resin (A1) and a phenol novolak epoxy resin (A2), a polyvalent epoxy resin formed from a mononuclear aromatic backbone (B), an aromatic amine curing agent (C), and a rubber (D).Type: GrantFiled: December 21, 2004Date of Patent: June 12, 2007Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Takashi Kaneko, Kazutami Mitani
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Patent number: 7217771Abstract: Compositions containing: (a) a liquid epoxy resin; (b) an aliphatic or cycloaliphatic primary monoamine and/or an aliphatic or cycloaliphatic disecondary diamine; (c) a latent curing agent for the epoxy resin (a) which does not react until temperatures above 70° C. (measured by means of DSC at a heating rate of 10° C./min); (d) a photopolymerizable compound; and (e) a photoinitiator; the ratio of the number of equivalents of epoxy groups to that of photopolymerizable groups being 1:0.01 to 1:0.7, are suitable as impregnating resins.Type: GrantFiled: July 29, 2002Date of Patent: May 15, 2007Assignee: Huntsman Advanced Materials Americas Inc.Inventor: Frans Setiabudi
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Patent number: 7193016Abstract: In accordance with the present invention, there are provided toughening agents which are useful for improving the performance properties of epoxy-based adhesive formulations. For example, epoxidized polybutylacrylates have been found to be useful toughening agents of component level underfill adhesive compositions. Invention materials are generally liquid rubbers which provided improved fracture toughness while maintaining satisfactory capillary flow properties. Invention materials can be synthesized in neat (solventless) reactions from readily available low-cost raw materials and isolated in high yields. They have a branched telechelic structure with terminal epoxide functional groups. The polyacrylate is typically obtained as a mixture of epoxidized polymer, chain extended polyoligomer and unreacted monomer. Invention materials are compatible with common epoxy formulations and may be used without purification.Type: GrantFiled: October 27, 2003Date of Patent: March 20, 2007Assignee: Henkel CorporationInventors: John G. Woods, Mark M. Konarski, Kyra M. Kozak, Yuhshi Luh
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Patent number: 7144630Abstract: The present invention relates to improved compositions for aqueous adhesives and aqueous primers that increase the durability of composites made by adhering elastomers to metal.Type: GrantFiled: January 23, 2003Date of Patent: December 5, 2006Assignee: Rohm and Haas CompanyInventors: Peter James Jazenski, Paul Anthony Dorrington, Dean Edward Hoy, Lipa Leon Roitman
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Patent number: 7108919Abstract: Reactive, non-isocyanate coating compositions prepared by mixing epoxy, tertiary amine, anhydride, hydroxy- and, optionally, acid functional compounds, a system of making the coating composition, a method of coating the composition on a substrate and a substrate coated with the composition.Type: GrantFiled: February 27, 2002Date of Patent: September 19, 2006Inventors: Mohamad Deeb Shalati, James Henry McBee, Ferry Ludovicus Thys, William Jay DeGooyer
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Patent number: 7094845Abstract: There is provided a composition for functioning as an effective additive for an epoxy resin that is a solid at room temperature and has a high storage stability, and a method thereof. The composition of the present invention is a basic silane coupling agent organic carboxylate composition obtained by first synthesizing an organic carboxylate of a basic silane coupling agent by reacting a basic silane coupling agent and an organic carboxylic acid, and subsequently heating and mixing the organic carboxylate of the basic silane coupling agent with a compound exhibiting a good affinity for the basic silane coupling agent or organic carboxylic acid and having a softening point or melting point of 40° C. or greater.Type: GrantFiled: August 27, 2002Date of Patent: August 22, 2006Assignee: Nikko Materials Co., Ltd.Inventors: Masashi Kumagai, Takashi Ouchi, Katsuyuki Tsuchida
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Patent number: RE39615Abstract: The invention relates to an adhesive composition, comprising: (A) at least one phenolic resole resin; and (B) the product made by reacting (B-1) at least one difunctional epoxy resin, with (B-2) at least one compound represented by the formula wherein in Formulae (I) and (II): G, T and Q are each independently functional groups selected from the group consisting of COOH, OH, SH, NH2, NHR1, (NHC(?NH))mNH2, R2COOH, NR12, C(O)NHR1, R2NR12, R2OH, R2SH, R2NH2 and R2NHR1, wherein R1 is a hydrocarbon group, R2 is an alkylene or alkylidene group and m is a number in the range of 1 to about 4; T can also be R1, OR1 or SO2C6H4—NH2; and Q can also be H. The invention also relates to copper foils having the foregoing adhesive composition adhered to at least one side thereof to enhance the adhesion between said foils and dielectric substrates.Type: GrantFiled: October 17, 2002Date of Patent: May 8, 2007Assignee: Nikko Materials USA, Inc.Inventor: Charles A. Poutasse