Ethylenic Reactant Contains An Oxygen Atom Patents (Class 525/298)
  • Patent number: 5374681
    Abstract: Polyacetals useful as reduced-phosphate or phosphate-free detergent and cleaner additives are obtainable by cationically initiated polyaddition of(a) divinyl ethers and(b) dihydroxy compounds and also, optionally,(c) monohydroxy compoundsand have K values of from 8 to 100.
    Type: Grant
    Filed: January 5, 1994
    Date of Patent: December 20, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Richard Baur, Volker Schwendemann, Hans-Ulrich Jaeger, Johannes Perner
  • Patent number: 5367003
    Abstract: Environmentally friendly, disposable, degradable and/or recyclable plastic articles are made from water soluble, miscible, high molecular weight, thermoplastic, polymeric resin blends that are comprised by weight of about 65% to 95% high molecular weight water soluble thermoplastic resin having an inverse solubility characteristic and about 35% to 5% of at least one of certain high molecular weight thermoplastic polymers that are functionally compatible (miscible) with the inversely soluble resin. The articles are insoluble when used for their intended purposes, but become soluble when exposed to tepid or cool water and degradable when buried in a land fill or compost. The inversely soluble resin comprises high molecular weight poly(ethylene oxide). The compatible polymer is selected from the group consisting of Nylon 11, Nylon 12, polycaprolactone, polycaprolactone, polyethylene-co-acrylic acid, polyethylene-co-methacrylic acid, polyethylene-co-vinylacetate and polyethylene-co-vinylalcohol.
    Type: Grant
    Filed: June 18, 1993
    Date of Patent: November 22, 1994
    Inventor: Robert J. Petcavich
  • Patent number: 5360880
    Abstract: Polymerisable materials produced by the reaction of a pyrrole and an unsaturated or polymerisable aldehyde, preferably a beta-unsaturated aldehyde.Polymers made from the above-described polymerisable material and copolymers formed from the said material and at least one other polymerisable monomer of a known type.Such polymers and copolymers may be used for the production of films, coatings and other structures.
    Type: Grant
    Filed: March 5, 1993
    Date of Patent: November 1, 1994
    Assignees: The Australian National University, The Acton and Memtec Ltd.
    Inventors: Richard M. Pashley, Timothy J. Senden, Richard A. Morris, James T. Guthrie, Wei D. He
  • Patent number: 5326823
    Abstract: A fluorochemical graft copolymer comprising: a base polymer comprising polymerized units derived from monomers having terminal olefinic double bonds, having grafted thereto a plurality of polyfluoropolyether groups, Also disclosed is a process for preparing such a graft copolymer, and a method for reducing the surface energy of a polymer comprising polymerized units derived from monomers having terminal olefinic double bonds.
    Type: Grant
    Filed: June 23, 1993
    Date of Patent: July 5, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Richard J. Rolando, Anthony B. Clinch
  • Patent number: 5310810
    Abstract: An improved process for the preparation of segmented copolymers of polyolefins and poly(methacrylates) is disclosed.
    Type: Grant
    Filed: March 16, 1993
    Date of Patent: May 10, 1994
    Assignee: Rohm and Haas Company
    Inventors: John Natoli, Min-Yin Chang
  • Patent number: 5302661
    Abstract: A composition which contains thermosettable monomers from which continuous products can be made without using continuous carrier material, the composition containing bismaleimide monomers and a thermoplastic polymer having a high molecular weight.Products made from a composition of the present invention are suitable for use in those fields where good temperature resistance, good fire resistance and/or good corrosion and solvent resistance are required in addition to good mechanical properties. Examples are cable sheathing, fire-resistant clothing, asbestos substitutes, high-temperature filters, aircraft interiors, precursors for carbon fiber , food packagings (for example, for use in a microwave oven), capacitor films and filament winding products.
    Type: Grant
    Filed: December 16, 1991
    Date of Patent: April 12, 1994
    Assignee: DSM N.V.
    Inventor: Cornelius W. M. Bastiaansen
  • Patent number: 5286799
    Abstract: A process for the preparation of an alkenyl-substituted succinic anhydride wherein the alkenyl substituent has a number average molecular weight of from about 500 to 5000 and the average number of succinic groups per alkenyl group is greater than 1.2 which comprises:(a) reacting a polyolefin having an alkylvinylidene isomer content of less than about 10 percent and a number average molecular weight of about 500 to 5000 with maleic anhydride in the presence of a free radical initiator at a temperature in the range of about 100.degree. C. to 220.degree. C. to provide a mixture of alkenyl succinic anhydride having an average of greater than 1.2 succinic groups per alkenyl group and unreacted polyolefin, wherein the conversion of polyolefin is from about 30 to about 65 percent, and(b) reacting the mixture of alkenyl succinic anhydride and unreacted polyolefin with maleic anhydride at a temperature in the range of about 200.degree. C. to 250.degree. C.
    Type: Grant
    Filed: July 23, 1992
    Date of Patent: February 15, 1994
    Assignee: Chevron Research and Technology Company
    Inventors: James J. Harrison, William R. Ruhe, Jr.
  • Patent number: 5281674
    Abstract: A crosslinkable resin composition containing:(A) from 10% to 90% by weight of a thermoplastic resin component,(B) from 90% to 10% by weight of a curable resin component, comprising, expressed by reference to the curable resin (100%),(i) 50% to 95% of a (meth)acryloyl derivative, and(ii) 50% to 5% of a (meth)allyloxy derivative, and(C) from 0% to 30% by weight of a plasticiser for the thermoplastic resin component, is disclosed.Also a new crosslinked resin layer and a process for the manufacture of the new crosslinked resin layer on a substrate are described.The crosslinked resin layer herein exhibits a desirable balance between flexibility, resistance to stain and resistance to scuff properties, in combination with outstanding mechanical and chemical properties.The crosslinkable resin composition is particularly suitable for coating application of various substrates such as flooring materials, wall covering materials, coils, wires, and various shaped articles e.g. cars, containers and metallic profiles.
    Type: Grant
    Filed: June 16, 1992
    Date of Patent: January 25, 1994
    Assignee: Monsanto Company
    Inventors: Adolf A. Klaiber, Johannes F. H. Courtier, Daniel Gaeckle
  • Patent number: 5266635
    Abstract: Hydrogenated styrene/diene block copolymers having grafted p-hydroxystyrene groups improve the low temperature impact strength of polycarbonates when the phenolic groups are reacted with the polycarbonates.
    Type: Grant
    Filed: February 26, 1993
    Date of Patent: November 30, 1993
    Assignee: Shell Oil Company
    Inventor: John D. Wilkey
  • Patent number: 5262075
    Abstract: Multifunctional viscosity index improver additives for oleaginous composition comprising reaction products of (i)(a) ethylene-alpha-olefin copolymers grafted with (i)(b) carboxylic acid material, further reacted with (ii) at least one of polyamine, polyol, about C.sub.30 -C.sub.400 hydrocarbyl substituted carboxylic acid component together with polyol, or said carboxylic acid component together with polyamine, wherein the copolymer (i)(a) comprises intramolecularly heterogeneous copolymer chains containing at least one crystallizable segment of methylene units and at least one low crystallinity ethylene-alpha-olefin copolymer segment, and wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of M.sub.w /M.sub.n of less than 2 and a ratio of M.sub.n /M.sub.w of less than 1.8.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: November 16, 1993
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, John E. Johnston, Mark J. Struglinski
  • Patent number: 5260383
    Abstract: A process for preparing linear block and three arm star block copolymers having blocks of polyisobutylene and blocks of anionically polymerizable monomers comprises mixing a first solution of a polyisobutylene having a number average molecular weight of from about 4,000 to about 60,000 and having from 1 to 3 terminal allylic halogens with a second solution of a living alkali metal terminated polymer having a number average molecular weight of from about 4,000 to about 60,000 in relative proportions at a temperature of from about 10.degree. C. to about 80.degree. C. for a period of time of from about 30 minutes to about 24 hours whereby a significant amount of linear block or three arm star block copolymer is formed. A polyisobutylene having from 1 to 3 terminal allylic halogens is provided and a process for preparing said polyisobutylene.
    Type: Grant
    Filed: April 17, 1991
    Date of Patent: November 9, 1993
    Assignee: Polysar Rubber Corporation
    Inventor: Akhtar Osman
  • Patent number: 5254667
    Abstract: New macromers useful for the preparation of white, stable, high solids, low viscosity vinyl graft polymer polyol dispersions and processes for the manufacture of the macromers are disclosed.
    Type: Grant
    Filed: July 10, 1989
    Date of Patent: October 19, 1993
    Assignee: BASF Corporation
    Inventor: John E. Davis
  • Patent number: 5252675
    Abstract: Disclosed is a multiplex ethylene copolymer comprising (a) 50 to 94.8 mole % of units derived from ethylene, which are represented by the following formula (I):--CH.sub.2 --CH.sub.2 -- (I)(b) 5 to 45 mole % of units derived from a monomer selected from alkyl acrylates, alkyl methacrylates, vinyl carboxylates and isopropenyl carboxylates, which are represented by the following formula (II): ##STR1## wherein R.sub.1 stands for a hydrogen atom or a methyl group, and X is ##STR2## (in which R.sub.2 and R.sub.3 stand for an alkyl group having 1 to 10 carbon atoms),and (c) 0.2 to 5 mole % of units derived from a monomer having a radical-polymerizable ethylenic double bond and at least one carbon-to-carbon double bond which is different from a double bond of an aromatic nucleus. This ethylene copolymer can be easily cured, and the cured copolymer is a rubber having excellent oil resistance and heat resistance.
    Type: Grant
    Filed: November 26, 1991
    Date of Patent: October 12, 1993
    Assignee: Showa Denko K.K.
    Inventors: Yoshihiro Moteki, Toshiyuki Iwashita, Hitoshi Funada, Naotoshi Watanabe
  • Patent number: 5247024
    Abstract: An improved process for the preparation of segmented copolymers of polyolefins and poly(methacrylates) is disclosed.
    Type: Grant
    Filed: June 15, 1992
    Date of Patent: September 21, 1993
    Assignee: Rohm and Haas Company
    Inventors: John Natoli, Min-Yin Chang
  • Patent number: 5238994
    Abstract: A process for improving the size distribution of granules formed during synthesis of polyvinyl butyral which involves delaying addition of surfactant to the reaction medium in which the polyvinyl butyral is being formed until after gel break. The surfactant is usually polyacrylic acid or a copolymer of acrylic acid with up to 20 weight percent of one or more copolymerized monomers, in an amount effective to counteract excessive agglomeration of the polyvinyl butyral granules.
    Type: Grant
    Filed: September 9, 1991
    Date of Patent: August 24, 1993
    Assignee: Monsanto Company
    Inventor: Nandlal S. Reejhsinghani
  • Patent number: 5202386
    Abstract: Organic (co)polymers, including saturated (co)polymers, are modified by contacting them with an organic peroxide and decomposing the peroxide. Use is made of an organic peroxide having the general formula R--(O--O--CHR.sup.1 --CR.sup.2 .dbd.CR.sup.3 R.sup.4)N, wherein N is 1, 2 or 3; R.sup.1 is H, C.sub.1 -C.sub.4 alkyl or C.sub.2 -C.sub.4 alkylene; R.sup.2, R.sup.3 and R.sup.4 are, independently, H or C.sub.1 -C.sub.4 alkyl; two of the substituents R.sup.1 -R.sup.4 together may form C.sub.3 -C.sub.12 alkylene; and, when N is 1, R is an optionally hydroxyl substituted C.sub.4 -C.sub.18 T.alkyl, P-menth-8-yl, C.sub.5 -C.sub.18 T.alkenyl, 1-vinylcyclohexyl or a group of the formula: --C(CH.sub.3)2--C.sub.6 HJ(5--M)--R.sup.5 (M), wherein M is 0, 1 or 2 and R.sup.5 is isopropenyl or 2-hydroxyisopropyl; when N is 2, R is a C.sub.8 -C.sub.12 alkylene or alkynylene group having a tertiary structure at both ends, or a group having the formula --(C)CH.sub.3)2)2--C.sub.6 H(4--X)--R.sup.
    Type: Grant
    Filed: May 22, 1991
    Date of Patent: April 13, 1993
    Assignee: Akzo NV
    Inventors: Andreas H. Hogt, John Meijer, Peter Hope, Jernej Jelenic
  • Patent number: 5179160
    Abstract: There is here provided a thermoplastic resin composition which comprises (I) 50 to 99% by weight of a polyamide resin, and (II) 50 to 1% by weight of a multi-phase structure thermoplastic resin which is composed of 5 to 95% by weight of at least one ethylene copolymer selected from the group consisting of epoxy group-containing ethylene copolymers, ethylene-unsaturated carboxylic acids, alkyl ester copolymers and metallic salts of the ethylene-unsaturated carboxylic acids, and ethylene-vinyl ester copolymers, and 95 to 5% by weight of a vinyl polymer or copolymer obtained from at least one vinyl monomer, either of both the components possessing a dispersion phase where each particle has a diameter of 0.001 to 10 .mu.m. A method for preparing the above-mentioned thermoplastic resin composition is also provided here.
    Type: Grant
    Filed: August 17, 1988
    Date of Patent: January 12, 1993
    Assignees: Nippon Petrochemicals Co., Ltd., Nippon Oil & Fats Co., Ltd.
    Inventors: Yuichi Orikasa, Suehiro Sakazume
  • Patent number: 5177152
    Abstract: The present invention pertains to a crosslinkable binder resin comprising an acrylate copolymer backbone having as pendant groups water soluble half esters of dicarboxylic acid and crosslinkable olefinic groups which contain an activated ethylenic unsaturation, such as (meth)acryloyl groups. The (meth)acryloyl groups can be crosslinked by polyfunctional crosslinking agents such as amino or blocked amino crosslinkers. The water-soluble half esters preferably are formed by the reaction of pendant hydroxy groups with unsaturated cyclic anhydrides (the unsaturation providing an additional crosslinking site). The (meth)acryloyl groups preferably are formed by the reaction of pendant epoxy groups with (meth)acrylic acid or derivatives thereof.
    Type: Grant
    Filed: January 31, 1992
    Date of Patent: January 5, 1993
    Assignee: Akzo N.V.
    Inventors: Gerardus J. W. M. Maters, Tamme Bartels
  • Patent number: 5167848
    Abstract: Oil soluble grafted ethylene-alpha-olefin copolymer useful as a viscosity modifier for oleaginous compositions comprising:(i) backbone copolymer of ethylene and at least one other alpha-olefin monomer, said copolymer comprising intramolecularly heterogeneous copolymer chains containing at least one crystallizable segment of methylene units and at least one low crysallinity ethylene-alpha-olefin copolymer segment, wherein said at least one crystallizable segment comprises at least about 10 weight percent of said copolymer chain and contains at least about 57 weight percent ethylene, wherein said low crystallinity segment contains not greater than about 53 weight percent ethylene, and wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of M.sub.w /M.sub.n of less than 2 and a ratio of M.sub.w /M.sub.w of less than 1.
    Type: Grant
    Filed: May 30, 1989
    Date of Patent: December 1, 1992
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, Mark J. Struglinski, John E. Johnston
  • Patent number: 5157087
    Abstract: Novel organic peroxides of the general formula ##STR1## wherein p=0 or 1 and n=1, 2, 3 or 4 are described. These peroxides are excellently suitable for use in the preparation of epoxide groups-containing (co)polymers. Also described are shaped objects obtained by using (co)polymers thus modified.
    Type: Grant
    Filed: April 29, 1991
    Date of Patent: October 20, 1992
    Assignee: Akzo N.V.
    Inventors: Andreas H. Hogt, John Meijer, Johannes P. J. Verlaan
  • Patent number: 5132371
    Abstract: A methacrylimide-containing polymer comprising a polymer (A) comprised of 5-100 weight % of units represented by the formula (I): ##STR1## wherein R is H or C1-20 hydrocarbon group, and 0-95 weight % of units derived from an ethylenic monomer, wherein a polymer derived from at least one ethylenic monomer has been grafted onto the polymer (A). The methacrylimide-containing polymer is used as a blend with another thermoplastic polymer.
    Type: Grant
    Filed: December 11, 1989
    Date of Patent: July 21, 1992
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Isao Sasaki, Kozi Nishida, Masaharu Fujimoto
  • Patent number: 5100966
    Abstract: The present invention pertains to a crosslinkable binder resin comprising an acrylate copolymer backbone having as pendant groups water soluble half esters of dicarboxylic acid and crosslinkable olefinic groups which contain an activated ethylenic unsaturation, such as (meth)acryloyl groups. The (meth)acryloyl groups can be crosslinked by polyfunctional crosslinking agents such as amino or blocked amino crosslinkers. The water-soluble half esters preferably are formed by the reaction of pendant hydroxy groups with unsaturated cyclic anhydrides (the unsaturation providing an additional crosslinking site). The (meth)acryloyl groups preferably are formed by the reaction of pendant epoxy groups with (meth)acrylic acid or derivatives thereof.
    Type: Grant
    Filed: August 7, 1989
    Date of Patent: March 31, 1992
    Assignee: Akzo NV
    Inventors: Gerardus J. W. M. Maters, Tamme Bartels
  • Patent number: 5096971
    Abstract: An adsorbent for optical resolution obtained by graft polymerizing an optically active vinyl monomer of the formula: ##STR1## wherein X is --CONH--, --COO-- or --NHCOO--, R.sup.1 is a hydrogen atom or a methyl group, and each of R.sup.2 to R.sup.4 which are different from one another, is a hydrogen atom, a hydrocarbon group or an alkoxycarbonyl group, or R.sup.2 and R.sup.3 together form a ring, to a crosslinked polymer carrier having groups to which said monomer is graft polymerizable.
    Type: Grant
    Filed: October 20, 1989
    Date of Patent: March 17, 1992
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Takashi Nishikaji, Hideaki Kiniwa, Tsunehiko Kurata
  • Patent number: 5093429
    Abstract: Disclosed is a multiplex ethylene coplymer comprising (a) 50 to 94.8 mole % of units derived from ethylene, which are represented by the following formula (I):--CH.sub.2 --CH.sub.2 -- (I)(b) 5 to 45 mole % of units derived from a monomer selected from alkyl acrylates, alkyl methacrylates, vinyl carboxylates and isopropenyl carboxylates, which are represented by the following formula (II): ##STR1## wherein R.sub.1 stands for a hydrogen atom or a methyl group, and X is ##STR2## in which R.sub.2 and R.sub.3 stand for an alkyl group having 1 to 10 carbon atoms), and (c) 0.2 to 5 mole % of units derived from a monomer having a radical-polymerizable ethylenic double bond and at least one carbon-to-carbon double bond which is different from a double bond of an aromatic nucleus. This ethylene copolymer can be easily cured, and the cured copolymer is a rubber having excellent oil resistance and heat resistance.
    Type: Grant
    Filed: February 15, 1990
    Date of Patent: March 3, 1992
    Assignee: Showa Denko K.K.
    Inventors: Yoshihiro Moteki, Toshiyuki Iwashita, Hitoshi Funada, Naotoshi Watanabe
  • Patent number: 5037892
    Abstract: Organic (co)polymers, including saturated (co)polymers, are modified by contacting them with an organic peroxide and decomposing the peroxide. Use is made of an organic peroxide having the general formula: R--(O--O--CHR.sup.1 --CR.sup.2 .dbd.CR.sup.3 R.sup.4)N, wherein N is 1, 2 or 3; R.sup.1 is H, C.sub.1 -C.sub.4 alkyl or C.sub.2 -C.sub.4 alkylene; R.sup.2, R.sup.3 and R.sup.4 are, independently, H or C.sub.1 -C.sub.4 alkyl; two of the substituents R.sup.1 -R.sup.4 together may form C.sub.3 -C.sub.12 alkylene; and, when N is 1, R is an optionally hydroxyl substituted C.sub.4 -C.sub.18 T.alkyl, P-menth-8-yl, C.sub.5 -C.sub.18 T.alkenyl, 1-vinylcyclohexyl or a group of the formula: --C(CH.sub.3)2--C.sub.6 HJ(5--M)--R.sup.5 (M), wherein M is 0, 1 or 2 and R.sup.5 is isopropenyl or 2-hydroxyisopropyl; when N is 2, R is a C.sub.8 -C.sub.12 alkylene or alkynylene group having a tertiary structure at both ends, or a group having the formula: --(C)CH.sub.3)2)2--C.sub.6 H(4--X)--R.sup.
    Type: Grant
    Filed: December 13, 1988
    Date of Patent: August 6, 1991
    Assignee: Akzo N.V.
    Inventors: Andreas H. Hogt, John Meijer, Peter Hope, Jernej Jelenic
  • Patent number: 5004762
    Abstract: Radiation curable compositions useful as coatings for wood, metal, glass, fabric, paper, fiber and plastics are made from homopolymers of 4-acetoxystyrene or homopolymers of 4-hydroxystyrene blended with ethylenically unsaturated compounds.
    Type: Grant
    Filed: November 22, 1989
    Date of Patent: April 2, 1991
    Assignee: Hoechst Celanese Corp.
    Inventor: Balaram Gupta
  • Patent number: 4985506
    Abstract: Oxidatively cross-linkable, water dilutable binders suitable for lacquers, coating compositions and sealing compounds are modified co-polymers of olefinically unsaturated compounds, having a molecular weight of 6000 to 160,000 and having for each 100 grams of solids content, a total of from60 to 250 milliequivalents of chemically incorporated carboxyl groups, of which from 10 to 100% are neutralized thereby rendering the product dilutable in water andfrom 15 to 50% by weight of chemically incorporated moieties corresponding to the formula--O--RwhereinR represents an olefinically monounsaturated or polyunsaturated aliphatic hydrocarbon having a molecular weight above 166 and containing from 12 to 22 carbon atoms, are prepared by:(a) preparing a co-polymer having a molecular weight from 5000 to 80,000, determined by gel permeation chromatography, and having intramolecular carboxylic acid anhydride units corresponding to the formula ##STR1## and an anhydride equivalent weight of from 240 to 1960 by a radically i
    Type: Grant
    Filed: June 26, 1989
    Date of Patent: January 15, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Harald Blum, Peter Hohlein, Michael Sonntag, Wolfgang Wellner
  • Patent number: 4959428
    Abstract: A process for emulsion-polymerizing unsaturated monomer(s) is disclosed. When a hydrazine derivative having at least two hydrazine residues per molecule is added to the polymer dispersion obtained by said emulsion polymerization process, a polymer dispersion composition capable of forming a film which is excellent in blocking resistance, adhesiveness to an alkyd resin film, water-resistant adhesiveness to an alkyd resin film and water-resistant anti-whitening can be obtained.
    Type: Grant
    Filed: August 17, 1988
    Date of Patent: September 25, 1990
    Assignee: Mitsubishi Yuka Badische Company, Ltd.
    Inventors: Tadashi Abe, Masahiro Aoki, Takeo Tsukamoto
  • Patent number: 4923956
    Abstract: Resin compositions obtained by causing copolymerization of particular radical (co-and/or) polymerizable organic peroxide and vinyl monomer in particular propylene polymers and that it is a best way to use an aqueous suspension in the manufacture.
    Type: Grant
    Filed: April 21, 1988
    Date of Patent: May 8, 1990
    Assignee: Nippon Oil and Fats Co., Ltd.
    Inventors: Yasuo Moriya, Nobuyoshi Suzuki, Hiroshi Goto
  • Patent number: 4853445
    Abstract: In the suspension polymerization of styrene monomers in water using suitable suspension stabilizers, the only modifier needed has been found to be organotin compounds in amounts from 10 to 1000 ppm based on monomer. The product beads have a narrow bead size distribution.
    Type: Grant
    Filed: May 21, 1987
    Date of Patent: August 1, 1989
    Assignee: Arco Chemical Technology, Inc.
    Inventors: Bernard H. Meyer, Joseph C. Kinslow, Paul E. Arch, D. Harper Meek
  • Patent number: 4841002
    Abstract: Compositions have melting points below 100.degree. C. which are useful in the formation of resins by reaction with polyphenolic compounds consisting of a mixture of more than two compounds having the formula ##STR1## wherein A represents a cyclic or acyclic aliphatic or substituted cyclic or acyclic aliphatic moiety having from 1 to 20 carbon atoms or an aromatic mono- or multi-nuclear or aliphatic substituted aryl residue having from 6 to 20 carbon atoms,R independently represents H, CH.sub.3, CH.sub.2 CH.sub.3 or C.sub.6 H.sub.5,R.sup.1 independently represents H or CH.sub.3,R.sup.2 independently represents H or CH.sub.3, andx represents an integer from 0 to 2are described.
    Type: Grant
    Filed: November 8, 1988
    Date of Patent: June 20, 1989
    Assignee: Ashland Oil, Inc
    Inventors: Billy M. Culbertson, Omar Tiba
  • Patent number: 4839446
    Abstract: A polymerizable thermosetting composition which is a flowable liquid at moderate temperatures which comprises a mixture of:(A) from about 75% to about 95% by weight of a mixture of:(1) from about 80% to about 20% by weight of a bisoxazoline and(2) from about 20% to about 80% by weight of a polyphenolic compound and(B) from about 5% to about 25% by weight of at least one member selected from the group consisting of a monooxazoline and a monooxazine,a method for forming thermoset products therefrom and the novel thermoset products resulting from said method are described.
    Type: Grant
    Filed: August 8, 1988
    Date of Patent: June 13, 1989
    Assignee: Ashland Oil, Inc.
    Inventors: Billy M. Culbertson, Omar Tiba
  • Patent number: 4839431
    Abstract: Elastomeric homopolymers and copolymers comprising at least one active group containing an alkali metal atom are chemically treated to incorporate at least one conjugated diolefin linkage. The chemical treatment consists of reacting the living polymers with 2,3-ethylenically unsaturated aldehyde or ketone and then converting the reaction product thus obtained to the corresponding alcohol and dehydrating the alcohol to produce the conjugated diolefin linkage. The chemically treated elastomeric homopolymers and copolymers are useful in any of the applications known in the prior art for the corresponding untreated homopolymers and copolymers. Moreover, the chemically treated elastomeric polymers may be reacted with an unsaturated monomeric dienophile through a 4+2 Diels Alder addition reaction and a polymer then grafted onto the chemically treated elastomeric polymer or the chemically treated elastomeric polymer may be reacted directly with another (different) polymer containing at least one dienophile group.
    Type: Grant
    Filed: December 31, 1986
    Date of Patent: June 13, 1989
    Assignee: Shell Oil Company
    Inventor: Antonius A. Broekhuis
  • Patent number: 4833209
    Abstract: This disclosure relates to a process for cross-linking polymers, e.g. polyethylene, or degrading polymers, e.g. polypropylene, using peroxides having at least one carbon-carbon double bond in the molecule, e.g. 1-(t-butyl peroxy isopropyl)-3-isopropenylbenzene.Incorporation of the peroxides into the polymer may be carried out at relatively high temperatures without the risk of premature decomposition of the peroxide, thus allowing easy processability of the polymer mass prior to cross-linking or degradation. The polymeric end products obtained are odorless and do not display blooming.
    Type: Grant
    Filed: March 28, 1988
    Date of Patent: May 23, 1989
    Assignee: AKZO N.V.
    Inventors: Wilhelmus M. Beijleveld, Johannes P. J. Verlaan
  • Patent number: 4826923
    Abstract: Metal drier moderated to provide compositions of extended pot life by at least one compound of niobium, zirconium, titanium, tungsten, boron, silicon, phosphorus or aluminum. Coating compositions of free radical polymerizable compounds and moderated metal drier exhibit lower propensity to yellowing.
    Type: Grant
    Filed: May 13, 1987
    Date of Patent: May 2, 1989
    Assignee: Monsanto Company
    Inventor: Christopher J. Hardiman
  • Patent number: 4816520
    Abstract: The terminally functionalized polymers are prepared from living polymers obtained by anionic polymerization of olefinically unsaturated monomers by reacting the living polymers first with capping reagents comprising nitrogen compounds of the general formulae I to VII: ##STR1## where R.sup.1 and R.sup.4 are each H, alkyl cycloalkyl or aryl, R.sup.2, R.sup.3 and R.sup.5 are each alkyl, cycloalkyl or aryl and A is a substituted or unsubstituted bridge which, in addition to the C members, can also contain N or O members and ##STR2## where R.sup.6 and R.sup.7 are each alkyl or aryl, A is a single-membered substituted or unsubstituted carbon bridge and B is a 2- to 12-membered bridge of which at least those members adjacent to the nitrogen atom comprise --C(R.sup.8, R.sup.9) radicals, where R.sup.8 and R.sup.9 can be identical or different and are H, alkyl, cycloalkyl or aryl, and the nonadjacent members can be not only --C(R.sup.8, R.sup.
    Type: Grant
    Filed: November 12, 1987
    Date of Patent: March 28, 1989
    Assignee: Basf Aktiengesellschaft
    Inventor: Klaus Bronstert
  • Patent number: 4810757
    Abstract: Metal drier moderated to provide compositions of extended pot life by at least one molybdenum compound. Coating compositions of free radical polymerizable compounds and moderated metal drier exhibit lower propensity to yellowing.
    Type: Grant
    Filed: May 13, 1987
    Date of Patent: March 7, 1989
    Assignee: Monsanto Company
    Inventors: Christopher J. Hardiman, Gary R. Bowers
  • Patent number: 4801457
    Abstract: A therapeutic composition comprising a therapeutic macromolecular agent incorporated in cross-linked polyacetal.
    Type: Grant
    Filed: October 7, 1987
    Date of Patent: January 31, 1989
    Assignee: Sandoz Pharm. Corp.
    Inventors: Jorge Heller, Donald W. H. Penhale
  • Patent number: 4782129
    Abstract: An ultraviolet-curable coating composition adapted for the buffer coating of optical glass fiber consists essentially of an acrylate-capped polyurethane in admixture with at least about 25% of its weight of liquid monoethylenically unsaturated monomer having a low glass transition temperature below about 0.degree. C. The acrylate-capped polyurethane is based on a generally linear polyurethane which is the reaction product of organic diisocyanate with a stoichiometric deficiency of a modified diol, this modified diol being the diester reaction product of polyoxytetramethylene glycol having a molecular weight of from about 200 to about 2000 with a stoichiometric deficiency of a long chain ester-forming hydrocarbon-substituted dicarboxylic acid or ester-forming substitution product thereof.
    Type: Grant
    Filed: January 4, 1988
    Date of Patent: November 1, 1988
    Assignee: DeSoto, Inc.
    Inventors: Elias P. Moschovis, Joseph J. Stanton, Clive J. Coady
  • Patent number: 4774293
    Abstract: This disclosure relates to a process for cross-linking polymers, e.g. polyethylene, or degrading polymers, e.g. polypropylene, using peroxides having at least one carbon-carbon double bond in the molecule, e.g. 1-(t-butyl peroxy isopropyl)-3-isopropenylbenzene.Incorporation of the peroxides into the polymer may be carried out at relatively high temperatures without the risk of premature decomposition of the peroxide, thus allowing easy processability of the polymer mass prior to cross-linking or degradation. The polymeric end products obtained are odorless and do not display blooming.
    Type: Grant
    Filed: June 2, 1986
    Date of Patent: September 27, 1988
    Assignee: Akzo N.V.
    Inventors: Wilhelmus M. Beijleveld, Johannes P. J. Verlaan
  • Patent number: 4739017
    Abstract: A retro Diels Alder assisted polymer grafting process in which a Diels Alder adduct is mixed with a polyolefin or polyvinyl polymer substrate and thermally decomposed to form an ethylenically unsaturated monomer which grafts onto the polymer substrate. The monomer conforms generally to the formula R.sub.1 R.sub.2 C.dbd.CHR.sub.3 in which R.sub.1 is hydrogen, methyl or ethyl, R.sub.2 is hydrogen, methyl, ethyl or vinyl and R.sub.3 is a hydroxyl, carboxyl, cyano, formyl, acetyl or propanoyl. The Diels Alder adduct substantially decomposes at a temperature of about 120.degree.-300.degree. C., but does not substantially decompose below about 120.degree. C. The polymer substrate is preferably high-density polyethylene, low density polyethylene, linear low density polyethylene, ethylene-propylene rubber, polypropylene, polystyrene or styrene-butadiene block copolymers. The grafting is induced by, for example, heat, catalyst and/or high shear conditions.
    Type: Grant
    Filed: June 6, 1986
    Date of Patent: April 19, 1988
    Assignee: The Dow Chemical Company
    Inventors: Ricky L. Tabor, Paul L. Neill, Bradley L. Davis
  • Patent number: 4701497
    Abstract: A process for producing a novel photosensitive resin having cinnamic groups, comprising reacting a polyallylamine represented by the general formula (I) ##STR1## (wherein n is at least 10) or an inorganic acid salt thereof with a compound having a cinnamic group in the presence of a solvent. The process is free from drawbacks as experienced in the production of a conventional photosensitive resin (e.g. polyvinyl cinnamate), such as formation of by-products during the polymerization of a monomer (e.g. vinyl cinnamate).
    Type: Grant
    Filed: July 3, 1986
    Date of Patent: October 20, 1987
    Assignee: Nitto Boseki Co., Limited
    Inventors: Hajime Serizawa, Keizo Ogihara, Kiyoshi Shimizu, Susumu Harada
  • Patent number: 4699970
    Abstract: The process for preparing a polymeric composition at improved rate comprising reacting an oxazoline compound and a phenolic compound in the presence of a catalytic amount of a phosphorous acid ester is described.
    Type: Grant
    Filed: June 30, 1986
    Date of Patent: October 13, 1987
    Assignee: Ashland Oil, Inc.
    Inventors: Omar Tiba, Billy M. Culbertson
  • Patent number: 4670308
    Abstract: A process for coating a substrate with a film comprising an .alpha.,.beta.-ethylenically unsaturated compound, a .beta.,.gamma.-unsaturated ether activator compound, an effective amount of a free radical polymerization initiator, and, optionally, a catalytic amount of metal drier. The components are applied to the substrate and the coated substrate is then placed in an atmosphere substantially free of oxygen until the coating has cured to a substantially tack-free condition.
    Type: Grant
    Filed: April 22, 1986
    Date of Patent: June 2, 1987
    Assignee: Monsanto Company
    Inventor: Jerome W. Knapczyk
  • Patent number: 4640958
    Abstract: A new coupling agent has been disclosed which is acryloyl chloride. This coupling agent undergoes anionic polymerization through the acrylate unsaturation rather than anionic attack at the acid chloride.
    Type: Grant
    Filed: August 21, 1985
    Date of Patent: February 3, 1987
    Assignee: Atlantic Richfield Company
    Inventor: Paul A. Mancinelli
  • Patent number: 4590101
    Abstract: A process for coating a substrate with a film of cured polymer in which a mixture of a poly (.alpha., .beta.-ethylenically unsaturated) oligomer, a polyallyloxy activator compound containing an effective amount of a free radical polymerization initiator and a catalytic amount of metal drier is prepared, the admixture is applied to the substrate in an air or oxygen rich atmosphere and the coated substrate is then placed in an atmosphere substantially free of oxygen until the coating has cured to a substantially tack-free condition.
    Type: Grant
    Filed: July 19, 1985
    Date of Patent: May 20, 1986
    Assignee: Monsanto Company
    Inventor: Jerome W. Knapczyk
  • Patent number: 4559382
    Abstract: Poly(vinyl chloride) resin compositions containing an ethylenically-unsaturated compound having carbonylamino or thiocarbonylamino groups. These compositions are readily convertible at low temperatures to crosslinked polymers and are radiation-curable to dimensionally stable articles and films that are clear and that do not exude oily materials.
    Type: Grant
    Filed: June 6, 1983
    Date of Patent: December 17, 1985
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: John A. Martens, Brian H. Williams
  • Patent number: 4556686
    Abstract: Improved stable crosslinked dispersion which is further stabilized with butylated melamine formaldehyde resin. The dispersion to which the improvement of the invention applies is formed by addition polymerization of selected monomers in the presence of an organic liquid which is a solvent for the monomers, but a non-solvent for the polymer and a polymeric dispersion stabilizer having solvated and non-solvated segments.
    Type: Grant
    Filed: June 20, 1985
    Date of Patent: December 3, 1985
    Assignee: Ford Motor Company
    Inventor: Stanley K. Horvath
  • Patent number: 4442261
    Abstract: The method and production of macromolecular monomers from cationically polymerizable monomers and vinyl-substituted hydrocarbon halides is disclosed. These cationically polymerizable monomers may react in the presence of a catalyst with the hydrocarbon halide to produce a macromer retaining a polymerizable headgroup. This compound may be used in a variety of copolymerization processes with a variety of copolymerizable monomers to form graft copolymers.
    Type: Grant
    Filed: January 11, 1982
    Date of Patent: April 10, 1984
    Assignee: The University of Akron
    Inventors: Joseph P. Kennedy, Kurt C. Frisch, Jr.
  • Patent number: 4426480
    Abstract: Organo siloxanes which, in conjunction with organic peroxides, serve as vulcanizing or crosslinking agents for polymers, prepared by reacting a fatty alcohol, water and methylvinyldichlorosilane or a mixture of methylvinyldichlorosilane and dimethyldichlorosilane.
    Type: Grant
    Filed: February 17, 1983
    Date of Patent: January 17, 1984
    Assignee: Union Carbide Corporation
    Inventor: Herbert E. Petty